Green World AN INDUSTRYWIDE PUBLICATION OF THE NEW JERSEY TURFGRASS ASSOCIATION Vol. 15 NO. 1 June 1985 Sulfur Its Activity in the Soil and Plants Roy Flannery and Ralph Engel Soil Sulfur Sulfur constitutes approximately 0.1 percent of the earth’s crust. It may be found in the mineral fraction of the soils as elemental sulfur, combined sulfur in metal sulfide ores and as combined sul­ fur in mineral sulfates. Plants take up the sulfate (SO4-2) form of sulfur from soils. Therefore, sulfur in lower oxida­ tion states, such as elemental sulfur, must be oxidized before it becomes available to plants. Elemental sulfur is converted to sulfate by biological oxida­ tion. The oxidation of elemental sulfur is affected by its particle size; particles smaller than 60-mesh are oxidized quite rapidly. Soil temperature between 86 and 100° F. favor oxidation of elemen­ tal sulfur. Sulfur oxidation is also fa­ vored by high soil moisture levels. Sulfur dioxide is chemically and bio­ logically converted to sulfate in soils. Sulfur dioxide reacts with water to form sulfurous acid which in turn reacts with soil constituents to form sulfite salts. The sulfite salts are oxidized to sulfates either chemically or biologically. Sulfur bacteria, Thiobacillus, oxidize elemen­ tal sulfur to sulfuric acid. Sulfur dioxide and water in the air are responsible for sulfuric acid that adds to the acidity of the soil and natural waters. This source of sulfur contributes to acid rain which is caused by approximately two parts sulfur dioxide and one part nitrous oxides. The end product in all sulfur reactions in soils is sulfate. In humid regions sul­ fate is often leached from the upper part of the soil profile, and it will accumulate in subsurface horizons. Under very high rainfall conditions, soluble sulfate salts can be completely removed from some medium to coarse textured soils. Many highly weathered soils in re­ gions of high rainfall contain appreci­ able quantities of absorbed sulfate in their subsoils. The most important con­ ditions favoring this adsorption are: Paul DesChamps (right) received the 1984 New Jersey Turfgrass Association Award at last December’s Expo Banquet. He is receiving congratulations from Dave McGhee, outgoing president of NJTA. Paul received this award for his enthusiasm, constructive ideas, and never ceasing support of turfgrass and NJTA. large amounts of clay; presence of hy­ drous iron and aluminum oxides; low soil pH; high sulfate concentration; slow or impeded movement of soil solution; and the presence of weakly-held anions such as nitrate and chloride. Liming and phosphate fertilization both reduce the soil’s ability to adsorb sulfate. Adsorb­ ed sulfate is an important source of sul­ fur for some plants that have deep root systems and long growing seasons, even though it may be less available than soluble sulfate. Soil properties can provide helpful clues about plant needs for sulfur fer­ tilization. Sulfur-deficient soils are usually low in organic matter, sandy in texture, and well drained. Total soil ni­ trogen and organic matter are closely re­ lated to total sulfur in soils. High nitro­ gen fertilization can change the nitrogen to sulfur ratio in soils and may lead to sulfur deficiencies over time. Plant Needs for Sulfur In the early sixties, sulfur deficiencies in plants had been identified in 13 states. By the end of the 1970’s the num­ ber had grown to 36. The problem may be even more widespread today. The northeast is considered to have less sul­ fur deficiency problems than most other parts of the country. Three major causes of reduced soil sulfur levels are: the reduction of inci­ dental sulfur in commonly applied fer­ tilizers, such as superphosphate; the re­ duction in atmospheric sulfur dioxide due to pollution control programs; and more intensive cropping programs which deplete soil sulfur levels more rapidly. Crop benefit from sulfur received lit­ tle consideration 25-50 years ago. Until the 1950’s, most fertilizers used in this country contained large amounts of sul- continued on page 3 Comments and Opinions . . Yours and Ours LETTERS WE ENJOY! The following are comments from a re­ cent letter written by Lynda Johnson of Pickseed. “Dear Dr. Engel: A while back you wrote an article on the mixability of ryegrass with Kentucky bluegrass. We found this article to be most useful but unfortunately it has been misplaced in our office. Would it be possible for use to receive another copy? It would be most ap­ preciated as it was a popular paper for reading and distribution. Thank you.” The article of reference was written by Gibeault, et al. and was reprinted in Green World (Vol. II #3 of 1981). The conclusion of the study was “mixes of Kentucky bluegrass and perennial ryegrass (a mix­ ture of Manhattan and Pennfine) practical­ ly eliminated ‘Fusarium blight’ activity”. Dr. Reed Funk of Rutgers University and Dr. William Meyer of Turf Seed, inc. have reported this same effect — a nice nat­ ural control of a problem! Dr. Ralph Engel Consulting Editor, “Green World” Dear Ralph, For sometime now I have intended to write this note letting you know how much I enjoy reading the issues of “Green World.” Yours has become one of the few publications that offer raw scientific data or research findings to the turfgrass professional. Most are di­ rectly applicable and useful. Your com­ ments are especially appreciated in that further thought is provoked — some­ thing that few of us do! Please express these thoughts and appreciation to powers that be within NJTA. Sincerely, Stephen G. Cadenelli, CGCS New Canan, Conn. Dec. 1984 Enhancing Roundup Research reports presented at the Northeastern Weed Control Conference in January 1985 indicated that, with the use of FRIGATE surfactant, the rate of ROUNDUP could be reduced consid­ erably and still obtain acceptable con­ trol. Ed Beste, University of Maryland, indicated that FRIGATE was the only ad­ ditive that enhanced ROUNDUP activity at 0.25 Lb Al/A (1/2 pint) adequately to provide full season suppression of ber- mudagrass. The spring treatment pro­ vided 90% Bermudagrass control. John Ahrens, Connecticut Agricul­ tural Experimentation Station, showed that ROUNDUP activity on rye was en­ hanced with the surfactant FRIGATE but not with X-77. His data show that rye kill at 0.28 Lb Al/A with 0.5% FRIGATE was equal to 0.56 Lb Al/A with no additive. Morrow of University of Maine show­ ed that FRIGATE improved ROUNDUP efficacy in the control of quackgrass and may have increased the yield of the oat crop following treatment. Bill Duke of Cornell University, how­ ever, indicated that there were some slight differences from adding FRIGATE but they were insignificant. How to find out if FRIGATE really does enhance ROUNDUP activity? Try it yourself. Cut the rate of ROUNDUP in half and add 0.5% v/v of FRIGATE to the spray tank. That’s 65 1/2 ounces of FRIGATE/gallon of water (don’t forget- to put the ROUNDUP in!). John A. Meade Extension Specialist in Weed Science Imagination was given to man to com­ pensate him for what he is not; a sense of humor to console him for what he is. Frances Bacon It is not hard to find the truth; what is hard is not to run away from it once you have found it. ” Etienne Gilson Not all those who are attempting to con­ duct successful business are profiteers. C. Coolidge It is well to think well; it is divine to act well. Horace Mann ABSTRACT: Effect of Acidity and N Source on the Growth and Thatch Ac­ cumulation of Tifgreen Bermudagrass in Florida from J. B. Saratin’s Study — Agron. Journal 77:33-36, 1985. Treatments were applied on a five- year-old Tifgreen bermudagrass turf growing on a loamy fine sand. Three N sources (Ammonium sulfate (Amm S), Isobutylidene diurea (IBDU) and ac­ tivated sewage sludge (SS) were ap­ plied. Clippings were collected every 45 days for growth rate and N uptake estimates and cores for thatch ac­ cumulation estimates were collected after each of three growing seasons. Maximum growth rates occurred at pH less than 4.0. Overall turfgrass quality was not significantly influenced by N source or frequency of application. Acidity promoted thatch accumulation, except in the presence of applied Ca. A higher pH and lower thatch readings oc­ curred with IBDU. Thatch accumulation was greater on plots receiving (Amm S). Editor's Comment: This supports find­ ings on cool-season grasses and shows a role for lime. OFFICERS OF THE N.J.T.A. Joe DeSantis, President Douglas Mosley, Vice President Ralph Engel, Secretary William Ritchie, Treasurer Dave McGhee, Past President Henry Indyk, Expo Chairman EXECUTIVE BOARD Samuel Leon Joseph Dodgson Richard Hurley Joseph W. Manning, Jr. James Stewart Robert Dobson William A. Nist John Poksay Ed Milewski Green World is published three times a year by the New Jersey Turfgrass Association, P.O. Box 231, New Brunswick, NJ 08903. Ralph Engel, con­ sulting editor; Veronica M. Malone, managing editor. Please address in­ quiries concerning advertising to William Nist, Lebanon Chemical Co., Dayton, NJ 08810. (201) 329-4011 Sulfur Activity continued from page 1 fur as impurities. Superphosphate and ammonium sulfate which contained 12 and 24 percent sulfur, respectively, were two of the most widely used nutrient sources of nitrogen and phosphorus in N-P-K fertilizers. When either or both of these fertilizers were used, sufficient amounts of sulfur were supplied at the same time to meet the crop’s sulfur need. These older fertilizer sources have been mostly replaced by more concen­ trated fertilizer sources containing much less sulfur. For example, concen­ trated superphosphate contains less than two percent sulfur and ammonium phosphates less than three percent. Am­ monium nitrate, urea and nitrogen solu­ tions normally contain very little or no sulfur. Plants need sulfur because it is a con­ stituent of several amino acids in­ cluding methionone and cystine which are essential components of plant and animal proteins. Sulfur is important in the formation of chlorophyll, even though sulfur does not occur in this substance. Visual symptoms may be used to de­ fect sulfur deficiency, but there are limi­ tations in using this approach. By the time sulfur-deficiency symptoms are evident, the yield and quality of crops may be seriously affected. Sulfur defi­ ciency shows as a yellowing similar to nitrogen deficiency, but in contrast to nitrogen, it is more evident in the new or top growth of the plant. Visually, it may be confused with iron and zinc deficiencies. Most plants should contain one unit of sulfur for every 12 to 15 units of ni­ trogen. Some experts suggest applying a five to one ratio of nitrogen to sulfur to maintain this balance. Plants need approximately as much sulfur as either phosphorus or magnesium. Many plants need 15 to 30 pounds per acre of sulfur per year for normal growth. This need­ ed sulfur may be derived from plant resi­ due decomposition, soil organic matter, atmospheric deposits and/or from various fertilizer sources. Editorial Comment: Dr. Flannery’s comments on sulfur in the soil and its role with plants are basic to better under­ standing of this element for turf and agriculture. The next issue of Green World will discuss effects of this element on the turfgrass plant and the sources that are available. REE Can You Tell The Difference? Reprinted from Green World 1982. These insects have similar size, movement and appearance. The big-eyed bug is a chinchbug predator. Look carefully at any populations before you treat for this Lou Vasvary pest either this month or next year. Predator Chinch Bugs Golf’s Hardest Shot — A mashie at 90 yards from the green — The ball was played against an oak tree, bounces back into a sand trap, hits a rock, bounces in the green and rolls into the cup. That shot was so difficult that I made it only once. Zeppo Marx Agriculture is America’s Oil. Monsanto Editorial Comment — This chinch bug item is a repeat of three years ago. Dry weather has caused some spots in turf to show an early and great abundance of the reddish young at the base of the plant. Their sucking weakens or can kill spots of turf. Worse is their potential for producing larger populations later in the season. Do not let the big-eyed bug trick you into treatment. REE. NITROFORM I.B.D.U. S.C.U. And R O C K L A N D DOES IT ALL GRANULAR FLOWABLE AND TOTAL GRANULAR GRANULAR LIQUID SELECTIVE WETTABLE POWDERS INSECTICIDES LIQUID WETTABLE POWDERS FUNGICIDES FERTILIZERS COMBINATIONS OF WITH INSECTICIDES And PRE-EMERGENCE CRABGRASS KILLERS HERBICIDES Ask your supplier or write: ROCKLAND CHEMICAL CO., INC. Passaic Ave.. West Caldwell, N.J. Mystic KENTUCKY BLUEGRASS Mystic is so aggressive it rapidly fills in divot scars and fights Poa annua invasion making it ideal for use on golf course fairways and tees. It possesses the following characteristics: ★ Tolerant of close mowing (3/4 ") ★ Provides a dense and aggressive turf ★ Resists Poa annua invasion ★ Fine texture ★ Bright green color Mystic was evaluated at Rutgers University by Dr. Ralph Engel and Dr. C.R. Funk under the experi­ mental designation P-141. For more information contact your local Lofts distributor, or Lofts Seed, Inc. Bound Brook, NJ 08805 (201) 356-8700 LOFTS Sustaining Members April 1985 Superior Chemical Products, Inc. NOR-AM Chemical Co. Bert Jones Keystone Lawn Spray, Inc. Grass Roots, Inc. Leon’s Sod Farm A. Lombardi Landscaping Garden State Goodall Montco/Surf Side Dubrow’s Nurseries Farmstead Golf & Country Club JEP Sales, Inc. Rapp Sod Farms Reid Sod Farm Green Hill Turf Supply The English Gardeners, Inc. Florence Landscaping Service, Inc. Sweeney Seed Co. Don’s Touch Vaughan-Jacklin Corp. Aquashade, Inc. Metro Milorganite, Inc. Double Eagle Equipment Co. A-L Services, Inc. Seacoast Laboratories MacAndrews & Forbes Co. O.M. Scott & Sons Hoffman LaRoche, Inc. Chemlawn Corporation Brouwer Turf Equipment Burton Landscaping Chevron Chemical Co. Somerville Equipment Co. Grass Tech Green Grass Lawn Maintenance Storr Tractor Co. Wilfred MacDonald, Inc. National Chemsearch Fertl-Soil Co. Aabar, Inc. Jade Run Turf & Sod Farm D & J Landscaping Stanford Seed Co. Dow Chemical USA Garden Dynamics, Inc. Hummer Turfgrass Lofts Seed, Inc. Rockland Chemical Co., Inc. Garfield Williamson, Inc. Manasquan River Golf Club Newton Country Club Parkmaster The Professional for large areas. Of Ecology And Thistles I have been on a kick against Canada thistle. It started several years ago when the highway departments omitted mow­ ing or delayed mowing until seed had set and scattered in the wind. I wrote let­ ters of compaint on this which did not receive much understanding or con­ cerned action. Canada thistle and other thistles are becoming more frequent terrors on land­ scape sites. Canada thistle is not per­ sistent in closely-mowed, good turf cover. With higher cuts one well-timed mowing per season will control seed- heads efficiently. However, this plant will persist and spread by rhizomes in higher cut, utility-type turf. Dr. Reed Funk found spring applications over several seasons of our standard broad­ leaf herbicides for dandelions did not give control. Our grandparents’ genera­ tions fought this weed relentlessly. It is a costly nuisance to agricultural produc­ tion. Further increase of this or other thistles makes a bigger and more pain­ ful problem for the future. REE One of the greatest obstacles to suc­ cess is man's inability to put first things first. Charles Roth LEBANON PROFESSIONAL TURF PRODUCTS QUALITY HOMOGENOUS, FERTILIZERS The Toro' Parkmaster mows swaths from 30 inches to 18 1/2 feet wide -up to 80 acres a day. With a 7 or 9 unit hydraulically-controlled frame, it has a compact pattern of gangs for easy mowing, easy transporting. The Parkmaster is the mowing tractor built to take Spartan gangs. Comes with powerful gas or diesel engine with cab and roll over protection system (ROPS) optional. TORO Storr Tractor Co 3191 U S. Highway 22 Somerville, NJ 08876 201/722-9830 The Professionals That keep you cutting. Jocobsen Turfcat II GW 224 Wilfred MacDonald, Inc. 340 Main Avenue Clifton, NJ 07014 201-471-0244 •Jacobsen •Olathe •National •Gravely •Giant Vac •Broyhill •Cushman •Howard •FMC •Smithco •Terra-Care ALL WITHIN YOUR BUDGET ! LEBANON LEBANON CHEMICAL CORPORATION P.O. Box 189 Dayton, NJ 08810 P.O. Box 180 Lebanon, PA 17042