THE COPOLYMERIZATEON OF STYRENE AND [TACORIC WDRIDE The“: for Hm Degree 0‘ M. 5. MICHIGAN STATE UNWERSITY Donald Arne Kangas 1958 . fiflESl: LIBRARY Michigan State University m oc-Pch-mzmimfi or mum my moclam amazing Wm» Emma Eabmttad tn the 81222601 6! Gamma swam of Iéflcmgan Statva Humanity of Agflcultum and Applied Scimwo in partial mum at £319 rmirwmta fer ' tiaa doma cf “$13732" (.1? 331.“? 27’. item'tmmt a: Chmfistz‘y 3:2?“ ‘4'?“ r» r . f\ “‘13 L La VA "5‘ «ax AC: -1K-K3a3g ,.¥.:ai ' The author wishes to «threat! his appreciation to 32:. my: smile far an interest, menses-amt and guidance in misting this project. fie 19 also inflated to The new (themes). COW tar manna than, any from regala: autism, to maple“ portion of this project and to iii-r. Killian Pavalich of the Po 1pm:- Research Laboratory for his invaluable assistance. Ilfliflllfllliinfl a"; auras: “rainy: a? SITJE az... max :51: mama :mld am Mags: mural ta the Selmel at 6mm“ 3mm of Eliefr'xigm 3M“ Univmity cf Agicaltm an: Applied.- shims in finial fulfillmt a: we requirwmzta for the firearm af 2mm: ( F 3?: 1353?; imrtamt at Ghexelatry Year 1955 ammod : Styrene: mi Hamel: new? So am eapalyem-iead 1:: Emma and in teetmlvix‘amnn 001m“ with bmaayl males at bin-awiaabamou max-1.10 catalyst. Tee mm at capalyeermum a: 1:3. m1. ram a: ”mu am: items-11a meg-and. m detammad 1n. the fan: mam, based an awkward mama cmmtmtima and the sweat a: when: to me. The rate! were few to be that emai- with We ta new m'weer ccmeatmum. The apparent first awe: mta mutant“ was calculate. for ma grams. 1 The cmltmn at the capclreers were also dammed, by the eats a: aislupzmnnaa at mama", by 33.li amlysio a! the capalyew, and by titration «1,: the aopclym by both patmtlceetdc and man {mm mm. a umber avenge mlmln: weight a: 23,!16: m fauna by the anions W mam far a copolner mm in lam-am column. binge average W Mafia. were ahmnad by the light Scattering metf'axi, far a W: W in benzene “lame the weight average mlacalar Wight no 155+,LCO. and far we capclmera pmpareé la tetrahyémmnn the weight "my wheeler 1&1;th was 50-,LC-C. 1v mm C? “$3333 Page Eminence I. W Cid EBOPCOQQCOcoccoacoauoaaoataoaooaaooooaacan... II. muaaoaaoooaaoauoaooaoeaaaaaoaaaoooaaaaoqaooaaoaooa I. mutual“ DWtk-n of Mam, Stym and 1mm Wimaooooaaoaoaaoaacaoauaoacaaaouaaaoaoaaao A. Wt“)?! 05' IWMQ mm, W! m on ”mt-Intimate..-cacaoaoaoaooaooaoaooaa 1. Rwanda 809M139 MWaaoaaoaaaaooaaoaaa 20 Catalyzed bmfimtifinaooaaaooaoaoaoaaoaam .3. 31M$ bWt-iGnaooaooooooaaoooaaa00at. B. 329?.th at laconic Anhyfiride, 2mm:- m an the Atld WHO-float.oaooacaooaaoaoaoooa 1. Back titration Of 8:13:38. Mouton-coon... 20 Direct titration Of Mid MMaacooooo ’- Titration Of Wthyi «tar............ Co Dmm Gt Emmia‘aoaoaooaoaaaaoaaacno»... 1. Hercurlc MGM” Waaaaona'amOIoaooo. 2. BW‘ Wfiflfloaaoooaocaaaoaaa0.00... D. Image of stream am Inmate Anhydrlcio 1n Waaooaoaocaoaaooaooaaaaaaoaauaacaaacoa II. (1090th at Styrene and laconic AMI-lea, fate or auction Swain-soc":aoaacoaaoaooaooococooaaaaooooao la PMMaoaaoat-aaoaaaoaaaooccoaoooaa"-00.00... 3. WWtiflnl and Rmuuuaoaooaumcouau 0. Order a: Reaction with Respect to MW and Itaaonic Anhylriée Cancentmuam..uu.uu.n.. Do Overall late Cr: 3L3E3$§$Plfifitimoooaaoaoooaaaoaaa ~11 UNITS“ “at! gamma: U 5:52;: TAM CF CGST'E‘T‘S .. Ccntimed Page III. Andy-1n of swam-Income We. Commas:- Cmitmaoaooaovoaoooaaaaooooaaaooaocaaooacocooaoaao 55 A. Elmtal W1. 0: ccpomocoooooooooooaoo I“: B. Potmtbeatrio and High Frequmcy fixation. at Styrene-Imus: Animirma Copalyml........... 10 5331‘!” mewaoaooaanacaaoooaooaaooao 2. 1h]: cater flmmootoooooacoooaoooaua IV. Eclacuhr weight of CWItaemde mum-1d. Copolyem 0......0.00.00....60....OOQOIIOOOOOO0.00000... A . Hulmlar weight at a emu-Imam“ mwndo " by In Cmtio Fm “Wooomoooao 1. Th. C-lzmagoaoooacacia-aoaaaaaoaucta 2. Emmooocaooooaaooooao-oaaocoaaooooo 3o )ieummt. 0: (£th PWoaooaoooo 8. blank: weight at Styma-Itacanic Writ}. CW" by ‘ Light Scattering: Hflimaoaooocoo 1. Light scattering pEeraooooooooaouo 2. Procedure [01' timing Wt‘ooooaoo 3. Outline of calculation: of molecular vaigl‘za from light. Owner-1n; ream-t flantlouaoooaaoatooaooococoaoaoooace-coo. h. E‘aclecnlar Weight WtW-aoaaacoaoa I. MIMI for Mtitative Betmaimfim of the f-‘kwnaaeati. . II. cmmuaa a: Styx-ma and Iueanla We, 3‘“ Smdifloouaoooaoooovmlaoaaaaoooaoaaaaaoaoaaoooaaaou 55 S? 57 57 63 66 69 7o 75 73 77 73 8? 91 93 m. W1m of says-madam marched. comma"... 1.0:; H. Molecular Edam or Emma-vitamin may Copol‘yumaoaoouoooaoooooooaaoaaaooooooactoo-000...”... 1C6 mmrmaacoaoooooaoooaaovooaoaoaoaacacao...aoaoaoaoaaaaaaoca 11C umumm CITED................................................ 13.2 v1 m enema-r s 137% i. Zia-'0 {a}. 3.1.}; I. mess; m: we” a: The study of styrene am}. masonic mtnmm capokmerlzatian has hm I. confining project in an. labs-zeta}? (1,2). ~ rue: immi- mfim have aim the napalm» ta "be at“ an alternathag mam-m: unit. structure mam- ta that few vim stem-ale mvénda «polymer (3.5.5). The was a: this we. was an «latex-cans: the mtm of the mommmaymmmatmrm Wmmumuummimummmeama Wm 13% In addition, mummg of mlecala: weight of m capalymm were we to éeaemine the influence of the aalvmt and catalyst a: the reaction. II. £16133 LWW ‘ Mimcmmmommmmw)m1mum (mu. macaw. 99$ W). Ana-thrm WmmmmmumH; 203W MWWHIWMWWWW,W mun-auctpolsmnumdmmwthumctamipi- Uhmthuflfimatum. 3.3a“ www.mmmmmm. 8...!ch quW(7)mmbymmaum mum-mam; hemmgc6546° . fizz-mm"). hMudfld(8)hymumdthmm (mmtqunlntmtml).mdwx-aflmm1t1mtortm ham. mmmmmmwonmpommwc; 6.m mwmmwwmflmmm urban“. mmmuwmmmwummrmt utmmtmmmtmxmummwtfimm mums». fluenm m,USPm. 35.1”” ”mu. ‘ .Ea‘ iAé- Luii I. mama-m mmmmma w :tmm, 3mm mmocmcnmm hmmammmmm,mm«nmmmum mammummmmmmmm, mmmmmmummmuwmmm «mWMmMaummmm. mm meMWthWMm— mum. mix-lam «mum (9-1.3). «martin Wan-Mon m), mumwdmmgmw (15). mammal-cu wW7).muauuthm(m).-nammumm mum-21). mmummwmmmmum mmummtwmmmmmm «mum-mm»)... LWufle-m traummamxbugmmmmmma mwmammummmmmuum m. n-cn-czw . (masochng. when“ MI ziflflmfia 9 01130063 unstimulmmtmmmmu. mo mammumdummumumm “mm mutation ‘8. camartm'i to mac cmorit'ia by asking ”dim chloride bafcra £1th of tha 1.1me acetic mm. r-iet‘hml in W to be the beat. :01va for the routine: and was W far the» ammucaa. In the can of 1mm flb‘Wfifififl wummmmmummmmwnmm mama-am (22), main: 11'. neormsal-v to flat mm tho mum wry]. titer of 1% acid berm pmaafiing with tho We mama motion. Egrmm‘gi 1n “carat-313‘ mfigfizm (amtximtely 0 .3 an.) W19 mfismlvadtaléml. ctbmzm, 5%.de «mum in! 30 m1. of mammal. Tim tcid m thm am with mm mm int-3W0 to t mamas: mt! paint. After 3; pm a: W manta kw! ham added the alumni m moved to “and for cam-Emit hear) 75 ml. of.“ “mm mam chin-11¢}. Caution were am and tho 1min umm: with mm mm Ewe-madam solution to A phmmmmm and point. m percent of atomic new and firmerma vars calculated :5 follow: &. 87 direct umuan of the mid. Percent man-mic acid I Pmm 1mm ant-minded ' * ““393“ r an 11.2 maymmmammum mmmflm mercuric: manta mum. {)5 § 1 Famed; income m?g*flrifi9 u ”1‘ ”353 teams: I mam AIS'YRI'B THIT'H‘ATICH BI $391.3 RIC AGF'EIVEE 2‘37." KID 9323313: Jimmie An? 3mm ample fifi‘ati’m e a. ‘ ‘ 125. c? vtzaatumtion Acid Mien Mun-r- ““ _::~ A‘ A“ :: r.~--tw_-+-‘:._ VA“ ~*‘ “fir‘w M M ‘4‘ ’4‘“: 1. than“ new 92.1.3 97.56 2. laconic W, We 3. 2?.53 109.1 3. 1mm Md” ml: 2 20.3? 101.3 WWA; ‘b M :W‘:“‘ “W'WZ. ‘1‘: “‘“‘::"t:‘*“::. f“ ‘t“““w“ 1# “1‘“ ZcCibWbmt-im. _ mo mum at angle-m 12213.9.th m be «mad by muma(u),pmvmmgngmmlmthodbywhmhmmw «mmaWofwmpmfilmbodmd. ma mummmewwmmmm “WCWWG.15@.)W¢£1WW, mammaafimémwmmmwmwmm. crater. WWtermtmwfimoonx. mmumtmwwmwmmmazu. mama-9mm. mmmmrwm Eflodwfiwmmommmmmm- mnmumm “thummmmw. sum Imam“! was: an in WW. 3339 pamt of .1me We mm"! mm u ram. Pam-mt income Inhy‘irwo 33m: Cm W: by this pmcacMra gave a. min: for sum mmmu o: 66.5%. 3. Diract bmmtim. sun 0. thin? mum fer mummy. (£127thth of Wade Winn, which has been mad :0:- atyxma (1.0), 1! the €5.th mum by a solution a: Emma in wean acid. m 9:111:25! I. in mantel:- wig?w& “992$me 0.1; 33.) «mph of immmmm mmmwm directly tin-um with mm in acetic acid lolntion. “than mags color at mm mm indicates the: and, paint. The pamaxt of Masonic “mam m WW u tongue: rm 1mm urban? -9233 . human-Motmmmgmtmwdadwm accurately weighed «may 0.2; 9:.) m1. a! 1mm Wirifia, fiaich Ind hem dissolved in human WWmWWWMamlmmme and film potassim We salvation m aided. "ma inmate?! iodina was titrated with steward Mirna (:0 tidomlmta, um; aw taxation at; m Mater. mmmwiummmmmmmn fellows: Percent Maintain Writ?» w: The direct “tut-inn, madam (0.), we a V8139 for pm 1W mhyvnda a: 5.82:, while thin hack titration: a! ~m 11mins, mom 0:), we talus tar pair. 1W amafiride cf 5 .355. B. Winn. of thumb: mwmida, fietlmdn M m Acid mm my other motive calm in itacmfic mugs m which quanti- tative Man- m M based is the warms am. In «mum to tha m). m for GM WWW, by dim titration with Mam}: turgid—mo: mm, 115 “Nahum“ the mm of 1mm mamas with 03W hum Siam). and Ham (22) Mn W that t2» mmaeter is {amend instantaneously tad muhuvm a room mm mm & pram-m? was: and a cyclic anhydrido. 2.. Rack tin-tim- of new base. mm An ins-MW wished (mm: 0.2 can.) swim at 1W We in diswlmd in «atone. To thin minim meaddédxoo a}... of (3.12338 2! mm mm. and the nautical In mud on u? m bath: to boil eff tin mm. 71:90:1an mu then cooled and tho mesa new hydroxide m imam with fim'KEufl :m-‘iwimmc mic: aeration, to a phanclptifimlein ma: paint . ma {mo-mt of: itaccznio mas-ids m “mam as mum: Pmmt imam C“! 331 5 6 made m' 1511' main!“ we a value £51- pnro laconic aim-arms ¢£ 939-3630,. 2. Emmet titration of mid Martian. Pres-ammo in manta]: mm 035910 at 1% W34: (@9th 0.2 p.) m aimzm in bum. 25 mi. of amm- odntam-a ~wm,anaummplomhatwmumum,' term mm. Thadihuinimcm Wanna: mutt-2.113%, to s WMhfimlain and point: with stamina! coding: W. maporcenterimemic mmmmwu £9110!!! Mimi? II means immm D’EWSW‘EEQTICEE? F3351 113m T'I'fim’i‘fllfi . CF 373 ACID Fu'EISTICZJ ‘ small Pemmt mm mum- W ”‘3 W villi—Tm"? _ ‘ ““‘m: “T'V; '3“ ‘11.... 1mm acid _ 99.70 mm We, m1: 1 93.1;0 lacunae “midis, W 2 93.11: WW 3. fitmtinn of mmwthyl 33:341'. 1; I In» hm: mmfim, mun: admiridaa an be de‘fimfl by £2.th tbs 80mm eater e: the gimme acid with base. W: in meat-ate]: mmw mans a: itawxie Wigwam, (ammzimtal‘y 0.1; $90) , this asserted in (830331333 methane]. an? 121m mmlizad nth swarm almholic Wanna Mamida sciatica to n Mimi-33min mi point. mm mm M lbw-unis m‘im In than mum: as follows: 11.2 .. .3112 III mama.“ gammy“. rm "W; g «.3 a: W 34.3 Ezra; _.V . h.— .....I_..- .-_.; - , - L ‘_,__ _ ‘L. m 4 _._... v—y— v —rr w w— A ,‘r v .- W A - ‘ M A -_. T... M .1 ‘4' W “w - We . Pea-amt Itaconia AWQ m V “‘ L‘L—H‘““ A“ W “A“ ‘ “SHAW iv 3: 32-3; w. A _; g 7 “h“ v“ 1% field 9&,95 laconic made, m1: 1 99.5%} 1W «mm, mm: 2 £43.63 www.ms 1a,; .- $733323! CF 1:25.333 £31212?“ K”! mama? MM .-' FITS}? BI VAELLUB brings C? $3.41; @3311}! ~-'-----o-.--~ m- --“mwuvmrmmm¢1w-h~~m\swu-n...-~~.....~..u_«v‘ . ' V " Percent Imam Animh'kh M ‘ ALA ._;_._ LA‘ .A. 44._ .AA. _._.L A . M VT fl. w—r— 7.... LUnumtionthion 1.mrumiawetata.ou.soo..... 27.7 h.mh1nwbmmtim “urn-1.... 66.3- c.mmtmmumum...;.u. 0.8 «bwktumticncf «mean hmnino . . . >. 5.3 Zofithdmwmmn W ‘0 hack titration 0: 332333 M39 0 I o I a 93.30 mafia-ecttitmtim Qinogocntco 93.55 e. W $1.th caf the whammy!» cater 1(6- .31 C. Datamtica at Emma Quantitative methods fer 1:119 fiatmfim or am m but m m tho w'wlmic mtnmticm. 1% rib-3:30:13 far 613th ethylmic “mum In!" m mim b2," Stena (9), and mini-.5316 @313de for W by Lace (23). A dimet bmmimtim mum has m new by . ' Mg and Levin (10), while mum and Hams. (33) have dammed . «Wad mum of a new ems/ml applicatim. The mercuric teats“ motion (19.21) has me ham via-3913 used fer analysis at W¢ 1. fimnfie Acetate flatbed. mm mm“ used was 063th tin m an already has been dam-11w: in Scenes: 1, bl, except that it w mum to Malta tho mid before waving cut the umm. 2mm: An .0th weighed “ml: of W, (approximtfly 0.3 W m waived in L5 a1. banana, 25 :31. of m cm chinrwacndxs ml. awhfiaml. Weddinghmetmric mummmmmmmumtcrwmvs i1. 01' hMted audit»! chlariéa caution m added and the ample united with mam sodium We 39111th to : Wm at! point. fins paremt styren- m mm as my rat aux-min mutate Wad tar tho domticn or W m. a “in. or 95£2§. his-WWW. mmmmtmuwmmmwmmtmm Mfummcfmmmanmm. W WWWmmcuyuhwobm Whammyhl, tortmmmaomlyfll- Bet-h mflmmuad (a) M timticnto the micro: WWW mmumtm cf mam bromine, indoo- anr. The W flmm mlcuhtad as £611.01!!! (a) Direct titration! ml LBJ? H at Br 5.2 Parcmt. sigma d as. (1:) Back titanium of access tam-mm P, 't _ gblet};a§ 0 m1! um) (3. a! lie. at; _) maxim. w w(flw “WW fiat. 5.2 @143! mm on par: damn: nuns mean” (t), pave ulna. e! 98 .133, mm: pm (b), m «has at 99.5%. 141%? mm: c3 vmms ems": 2m 5W BI vmmm *Wt-airs c2? rzkmm 83ml. Pmmt Styrene “m”; :..w.w __.__ 1. hum-13 manta . 95-6 2. Dim bum umum 98.1 3. Buck “mm of m brawn. 99.5 D. Wtimdstmomdlmc mmmmuwu rwmotmmxmmemmmmuu -Wmtmronmscmmmmaobmgmu only“! of nah commit an applicable: 1. 59001110 ‘2th of We amp and teal amt. of ammo mutation. 2 o Detazfifiantion 0f Inimirida grouy Ind Iolcotiv. actuation detemucm tor W19. 3. 8m. maturation mmm for no}; W, ‘ tumult: was and thyme.- h. Salsa-tin mama-sum dotammmmen for W or imam;- memo, and tom W o: «m mmtm. thn of method. and far the mutual" damn» a: tweak: was nod mm, in the mainline Section, Wt. 1.23% W: Ia: total maturation were W10 for tumm was. We, than no no method mm. for menu minim-tum mum a: 1mm: W9. The” Wanna: ammo W1.3mdh. Earner, .Ipociflemmd tordetomining We LI mm. by dire“ “tram with bromine, and income We can In ashram-d “the“ Worm by titration of tha and function. Thou Mind. taro tried in the following Wt. I» We. in both humans and tatmlvdmhm solution» It!” rm tint moorings cobra: umbmmm mt mummmum, bmnact¢ynnucomvh1¢h mwmmmumbmmmum. Fox-thaws» «mm o: m m nude in tutuizwdrom‘n, but the man- ‘tnuonc: mm. mmtmmriwoutin tatnhydmmmno W by durum. m um um polymr mm. LBW 001nm 5W LIBS? W21. 1mm m‘mirido mazes Md. 2. tetrthyémm me! mane caution Menu mum-1a. 5mm Wm. C 06383 W310 mam own. “1‘: _‘—‘ - :w‘flm 1-15 II. WEMZATICN C]? 51123“! if. JAE-ID moo-2m AHHIISREZE, RATE CF Emcnm grams wmmammmiwmmonmcntu mm in n 101 ml. nth, rm carried on in hm ”hm. banana www.mmmumu,mnpmmmomuum WWW. Than“ or each wanna-1WD: WMMMmuWkun-W.tor tuba-mate! pow {mad and, trim” pom)... formal-mate: mummmumtm. awmumrm WW‘MDM mWWuanmWMtyormu. Mon WWMttbomthMMMw www.mdmmmdoofthopmmtmfian Wimmmarpomromummmmw- .umdetmmmmwnmu. 2210de otmowmmmdnommmoftmw. udwnmtmm Suction Human. cementumm uwnummwmwoortmmm. A. Procedun The wpolymrtutionl wort carried out in 0.1.1 clan Wt, ' under a nth-om atmosphere, an Huh t new lmpling device, u tech- nimo mm: W in thin labor-115917 for mung puma“: mum and «caribou by that“, 0111. g; g. (1,3...2h). In thin prawn: uu tho polymerisation. um «nixed out in l 1,63) m]... 17 that-necked mmd-bottomd nu}: with W [has Joint. fitted with m. conduit with «lam chlorido tub.“ tho top. 12.1.th inlet. filmmaker, and um unplug device. Tho Mk nu hated Wuonhthonmnoomnhotphu. fluwmtmm mmatmmmm,eo°ctormmm63°ctor Wm. mmwwmtdiuMeWmdtMmmwmt aulmvmmmwm,mmmmmwarthowmo um,mmmm,mmtmwomm1m whntmmmlvmtordlu. summmwuwnmo: mmmmmwmmmmmm. umuwmm mumwatrmmmmmmmdotmmm “mamas“,mmtommmmtmuammm “mmgtnmum. Anwlommmimodutolyuingtho mung device md than at appropriate Morals. W motion magma-mum. Inthomowhmmmm tho what and budge-WWW tha «my» fish. cumin m WdtmtlymodfitmuduMmhth. Tho thionl at Ityrm and tumult: Wanda momma” mmummmmSwmlfionumucthbmmm ~tiara“inauguratingttxopolsmwmu«mulling». $110001»th M0 in Whom tolvant could not be mulyud for start-mo u mtwmsthI—Dnmflmommmmmmuwm ohm by «12m... 51m. tho polymer precipitates from hm, it In. counted by marina on a Gown unmitigmhed, dried, and trauma. 8mm”, the polymer had to be precipitated rm W mun Donation by n manhunt. Xylem ml round to be a fitment: precipitant and m and for thin We. A man taco of unto:- m a» mum to mum“ m- precipitation. mm- mm; a ’W mi. of magma mum centrifugedmd trusted in. “In W a: dmdbad above for win obtained tron aopomm~ sum in human Iolvmt. mainlcopomermlutm mammmuhydmmnu bytmmdimnofmlvdmulctharto mommmm. This an 1 Inch {mar Mitt“, but mum thin as. a: «on We. of mm in tho groom. Capolymr amia- me mad; Wad with macaw-t utmtcrto Whamouotmmbefom We 3. Cmenndfiqu mmadmtmhuadinmrmwpomumm maumumwm.muammwmaumm metmmmumxmxnmmxmgnn. mmmwuebmnmnutmmmlau for tho unc- m outlined below um um m1. «muons. mranwugqubollmouod mama this nation: n,‘ uwcmmmnotmntwum, t. K. ammmutmemmmwuuwtm. t. 3,“:- mmummmmmn o: m. M: I mew. scour wwmtmticn oi imagine admiride. 1% In mole {Rattan er ltwwflic anzzgnama in tha- mpolm-ar . I. A . a itacmnd amiwirida T31? u mm’EfimMI-m 33:}. :- 13312034. paltxdda biwao, 1- hwmmtymnitrila 1. Parent polymiation Irma the weight of W tamed Iron bmam Duration: Pmt polynemnion o . of 0‘; 13.2 Vt. 33mg, Whmlntigng ' a q - 9’ P. 3" Big-pm a - Farcem po.amar£..,gati..n a $4 (9%) 13.2 . 6mg 2. Pusan 90th m the weight of empower tanned from Wm mutton: Par-cast pom-flatten I W 13.3. ml. mum I‘mmt WM :- {0&8- Du'z '- 15.03 Lmhrmmtntmna! W, H; tortSnl. Align inhuman mum: R; n We! 80ml- calculation! R‘.W .Com 1;. am maximum or 1mm anim’n‘ide, :3” for a 5 :21. name: in Mme mlutim: . ELM—5'3 g hafJfl-“fi Small. calculations ’5' . W I 0.30),; 5. molar mutation of 1mm anhydrida, H3, in W continua A want-.1211. alumni. ma Was: 93 the claw layu- u'tar . W was or xylem m added to precipitnta mo W. s' . 13:1. 1mg) (m a: para) '1‘ m , _._.. Sm]; calculation: “n'W W .m; 6. Huh:- mmfiw or W, K1, in WNW aviation, tron durum. at polymer 1'0th and W. or 1W6 azfzyfirldu ' 31mph mum: at; «- wt (9.2;) ~ 112(0 .275) V I1 ”1 . 0.270 1. PM polynedntmn, from the rats of fimppmmnca or mmmma 21 Percent polymrmuon :- [103‘ (3.510 4,11) . 112 GE: 413)] 1.24m Staph calculation: Parent. Weston :- [103 (0.332 . 0.231) d- m m (0.313 It 0.185)] 1.13342 Parent polymrinunn - 36.555 8. Role fraction of laconic mmfirxde 1n the capolymer, Ha: I . Mon-H ' 31- . g1,» MR VII SIE~€RRI CF comnzmzamm 1; Initial " ‘ ' ‘ ‘ . . amt: a! e * ' ‘ Kind 9. Reaction was 26.10 7.56 bum 700.0 nae. 0.232 0.915 17.30 13.60 7.55 bases. sum yaw-0.11.3 0.916 2mm 26.10 was 2:2? 700.0 Bi}. 0.232 c.925 21:30 26.10 7&3 23W 702 bio-cm 0.159 0.925 mun-um maximums-momma thin actions 14.. I 1mm m‘vfixidc my I Wham BIO. (I M We bin-«o '- human-While 23 um: VIII mm or 5mm: er mums um ccsmsxmn or mum (In 1:1 SW! imam ankmirhfia copolynnriutica in human- aolvant by busy). pamxido catalyst.) .. .,.... -......q...-—*.r.—. funn- —v--' aura-m“. a—MAv-a—uwm- -. w» ......~, »- - -~..Ur‘ CID-M.“ v---'\ ‘Wn—lfA-IuJ’u-o- . Tim mui‘ccnc . {denim . 142113” mam 3‘ sum 14. M A - W11... a. o 0.332 0.313 *- 60 0.231 0485 0.5m: m 0.130 0.0537 0.523 1313 mm (fist-$3 6.5314 2m 0.532 0.029 0.510 350 0.610 0.015 0.511 soc . 0.008 . 730 . 0.506 «- h. «plum WM 0 0.330 6.310 - 15 0.318 (3.301; 30 0.285 0.23:. 0.576 60 0.221 0.176 0.550 150 0.065 0.060 0.521 2m 0.055 0.029 0.510 162 «- 0.016 . 2’4 Tam II. RATE OF PCLE‘EER NMTICE (In 131 “Wilma: Admit-ids Bonanza-nation in 8mm Solvent by W1 Pamxido um) 0 0.2 .- 60 36.5 36.8 120 68 .2 66.9 150 77 .8 76.9 210 86.3 83 .5 360 90.5 96.5 600 92 .3 '- 730 93 .7 a 5. Wu poly-urination O 0 .1 o 15 S .2 2 .6 30 15.6 15.8 60 ' 33 .2 33 .0 150 75.3 30 .5 21.0 86.2 .- 362 «s 100.2 25 QNV .6- \ mmxutié wSK 3m; Qam. Qm\ mad (3 -1 ‘0 “'3 Q0 59m / q .. i N O . mtmk$xw .s. x a .s H. >\ a QQxSQw wqmmth S Xm®hxhu NQ mmw tsfi hmtmkxxflg K8 TN. .. mtmkxsxm \..\ wkmSoS§\ aRV mutbkmeQOQQ as meQ L6 5. N.Q . 3 $6 a 0/; Oxfl/awo Q JD/OW 26 \mmfibSSN MER figure 2 QQQ 930 a». 9&4 com mom, 9% Qm< 9.3 Ow Q :QN . % mkmSQtQS 9 av d d o a 0 qubkthKhmoc 39$“ 5/ a w -I . \cmSKQqN km5®mq RACK anW 1.x a 3.3%“ . 4. m 16% 0 U + o q \ 56(ha mammtbfl S s a a . . . . n Xm®bth WNm‘ Y\ . mtmkmxm \.\ tQfimewEmwoofiw g8 m\ SQ 27 figU/‘E’ 3 Q3» \mofsgfit mEAN QQm. 09m. QVN Qm\ QN\ QQ di- p p b - u a % ,w ; QQQQQM, mtmwfimw S \w\\b\bm NQNQ tofbkikmkxanoxsb Y.\ n QOxmxm \..\ \wSmVoQob g8 QEEBRSOU A f Se, Q i V / UO/ZIJIOZ/ a/OM/ 6&6 és “Sm 28 m 1 RATE or nmrrmmca or mmz-zsm, camsrncn or m commm A... mm :9 m. «w? ’TIOH (101. Styx-unesluoonin Amwxwa Cope-lamenuum 1:: Banana Solvent with momma-isobutyronitrile Canaan.) Ww*w—n . -“'WWWF‘ -«--~ 1”,»... ‘w<--‘-g—l‘4n‘-‘-ll"M-.' . . n “w. n . . u.- . - yea”- ..--u¢.-r.--w-c-'n Percent E. n, H. mam-mum Hole Fraction Tim mm Cm. Bolu- Cum. from Ht. at Ll. in the mantel at Styx-m or 24 . “POW 0090mm- 0 _ 0.321 00309 1.5 ‘ 7 ’ 00233 5.7 . 15 0.291 0.259 11.0 0.57 30 0.231 0.203 2907 0053 16 0.175 0.160 15.2 0.50 60 0.1% 0.121.. 56.0 0.51 100 0.103 0.069 n.& 0.53 29 figU/E’ 4 . «WU\5Q\S\ WSR . QN\ . . om - p a q a ‘ db 0 O ’5 0 c .w‘ \ .O mtmxfixw 'l b0\*3\0% m§thmQ E \m%\b\~ob Oanm<fl toxxbwimkx®onxom .VQ .. mkmxkxm, \..\ mkmSEBE 93 mythkbmowbeQ QB 98% r \. Q 5x1 ‘3 (10/71 (MW/3300‘) 10/0” m 0‘ ‘é 30 59m 5 ah; \mmXbSKC mxtk D P I p d q d 4 QOQQQOW 43$}wa 36-3% a .Y.\ to\be\\m$%\oQo.v . 9%“. 9% 8m 8m 3m. 9% aw ow WQW NQAUQ bi .. mmxmkxwxw \..\ x0 ”\LGQ 53 Q a é 00/7sz/Jawfl/od % 4QQ\ 31 figure 6 «mmx3SE\ mxtum om nib-Q ‘3 m 4 +.//' O . . QSVQQQW QONQmQ S \waxbu oNcéQw. tofiONImE®oQou .VNNmkamxm \..\ km§®oo€b x0 QSXQOQEQU 3: 4? 6 Q‘ 'V 7 u0/_/ 904i a/OW 53. Q 3 C3 32 1313 II mm or crxmp¢mt'r2 c? zxwv‘m, cums ITICE 01" nm comma, 1:53 mm C? Hmrmzzumn (1:1 Styrmsltaoonic Numb-169 Cupolymriution 1n fatnbydmmrm Solvent with Bmcyl PM“ analyst. ) Pea-cant N. we. mz’m Kohl: m.’§1£m”§}°“ ”$1.: .Tm‘fi“ i1: £52251": 3:12.23“ka 9% u o 0.321 0.321 0.1 «- 21.0 0.259 0.235 13.6 mm 360 0.258 0.255 18.6 0.1m SAD 0.231 0.2% 25.6 0.155 720 0.211 0.226 30.9 0.1"” b. mum mm o 0.321 0.316 (:5 «- 60 0.306 0.311 3.9 0.300 2:» 0.27:: 0.275 15.0 OJJS has 0.236 0.21:; 23.8 0.506 726 0.228 0.228 29.1 0.500 950 0.210 0.2% 32.1: 0.166 1285 0.192 0.215 35 .9 0 Ash? 1500 0.198 0.198 33.2 .500 17150 - Gm 140.1; - mm - 0.133 um «- 33 figure 7 .V\ 1(3on MER 4b 4 4 . .w .\ G. o @5393, thQow Ikxxk S xw$§3u NQNQ toicNkaxNERQu .V\ .. mtmk%xh \..\ mkm$oto\< we mutbkbmoQbQQ as mqu { Q‘ UO/7ZDJ7lZ/QDUOQ JO/OW .rNS 4% 3h figure <9 ON m\ ®\ «WKBQQ\ WSR § 8 . \WQNXbu NW N% L Ox m. m % thQOW [KERN S \ .WxN .. WQQKMVW \u\ -flbeNtmkmonov Q3 .wxbnT . .o‘.\n \ <3 ‘5‘ Q N % 6 Q (10/7102/ aux/520d 0% T 6% 35 figure 9 wk \WK§QV\ WSR N\ 9 m.w.w o\\\.\éd o O o toiQoh Rik S *w\\h*hu NQme QQ\XBN\\m&\mVQQ\ou .b V \ o. mtm\\xw \..\ ngkwsifiv N5 tofiaoofxob .S§ .36 mi 'V '/ HOG/Dbi/ a/OW RELBZII Rim 0? DISAPPEARAHCE OF WKCIERS, cozmma 0F TIE canm, LR!) RATE CF Kanmmfl (.111 swszum Wide Comlymmuon in WWW Solvent with WWWymmm-uo Cum.) Percent. H , I n» 5013516“. nong'm. ”kW? fifm? AW# “3% A 39:9;A WWW”? g.“ “WW M 0 0.321 0.321 a» a. 35 0.319 0.318 0 .6 0.566 6n 0.310 0.312 3.0 0.1460- 350 0.279 0.281; 12.2 0.1958 22‘: 0.266 (3.262 17.7 (3.51? has 0.231 0.230 28.1. 0.562 600 0.135 0.211 35.1 0.1489 em 0.187 0.159 in...) 0.1M 1320. 0.151 0.166 19.8 0.13235 1680 0.11:0 0.151; 55.0 0.1;30 3? figure /0 «M‘SQQ\ MEK N\ 9 m o v. N P I D b D b D b q q .Vx O mtmth w to\\3\ow Rik . S \wafibu obeflw toficwtmkxkkoxou .V \ M. wtmkmwn, \.\\ WKWSOQO§ 9&0 WuQQKOQQ\Q\Oh9 E :K N L 5g figure L3 5/2375 Ora/er p/of for 5719/6/72 (aflccn/ruflun ) /./ 5/:y/‘Enei /.A. C0P0@.m€f’zaflonz BZOZ cara/ysf M 56/726/76 50/0/90” i L i 1 l 141 Q 2¢0 60 /20 /80 77me {mun/7‘65) figure /4 11,2 5/1575 Ora/er p/O/ for 5 fyre/ée Concenz‘raz‘lon , L 6/5-020 cu/O/ys/ //7 benzene 50/4/7900 1 9 ‘K 1 2? S O l s/ope ="/ /2< /0 #520.” I .\ g Q 69 /09 SfyI’EflQ COflCEflf/‘q//0/7 -14. A A 4 A L 1 L // Sfyrene .' / A. Capo/ymer/zail/on, 0 30 60 ”me (m/nufes) 90 1:3 u: «33ng wSR N\ Q\ Q Q V N 59 We /5 « u q q q q q d u q u q q 76mm, 9. Q\ RNVM wQ0\w QQ\\3\QWU\\\IN tx XW®CX§M NQNQ . QQ\\QN\km&\%\OQ\OU _\ \ \. mtmxhxn \..\ .tcfihxxtmutow mtmk$mm \QX xQQ xmthika au 94%}5‘ 5 Q \I 0/ in “I {r s u0/7z 02/74 uaJ 6/0) uh figure /6 .V\ \WKSQV\ USQ Tuww 93$“? 0&me QSXQQW KER S \thuSu QNCJQQ .CQ\\ON\xm&\%\QQ\8 .V \ “mtmkhxm \..\ «QQ\\\Q.\\ m\m UQQD WQMK$VW \Q\ um Q\Q KwEKQ INN WKQ Q \. 0/ i9 {ac/34.5719 6 \9 Q.‘ {1. '6 uO/ucuuua 31103 figure /7 Cancenfru 790(7 I 1\ Q U A93 M. .'\ A BANZ- Ora/er p/o7l for / r4 Concenfraf/Ofl, // Sfyrene: [/1 C0p0(umer/zahon, 32 02 cal/'a/‘us 7‘ m benzene so/u/mn s/Ope = 18.5 2r /0-55ec. ‘/ Q 60 /20 180 240 ”me /mmufes) figure /8 5/1571- Ora’en p/Of for [/1 Concenrru/mn , /.'/ 57‘yrene: [A capogmer/zafir'on, [9/54 020 60 7’06“ 7‘ /n benzene so/uf/on g ‘3‘ I .Q Q‘ ' 5/0,0e =‘/ 2x /0 «45662 ./ Cancer/790 f/on Q on 9 M. (a \\ N 0 20 40 60 80 7/3778 {M/nufeS) 116 h? w \ NWK3QV\ WER N\ Ox mV Q V N O 59m /9 73m, m-Q\xmzmanwo\o\w QQ\\3\QW .U\\r\K S xm\\b\6u NQ wa .to\\bN\\m$%\Qn\ou Y\ ..mtm\%xw \\\ atgxcxfitmutow ~“XV \Q\ x0\m\ \mvon {ka uo/7wu7zuayu09 '[7/7 60/ 11,8 figure 20 %\ «WKSQQ\ MSR N\ 0\ m 0 .V N d u d d u 4 3 u q 1 7me 0.. Q\ x %\nnmo~o\m QQQSQW KER S xm®hxcu QNG$RN “COSCNSmSmVQQSU . T \ .. mbmkmxm, \..\ .tofififi tmuteb .V.\ kox \Q\q kmka -x m,\\h\ QT .awq- uO/gnjfuaauog 'V 7 60/ flthfiaaf “£2.29: WWmfiadmemmw, 11‘th W Win!) 1: mm rm 23v: mm a! Lfiitdafiicn, a” u Mummmmmmmdmw Mg m tho M ate ”it“! (25.25“ :3. £33] ¢ {343]} at i inf-”2111' + mamas} + ra[315]a](%) [rl'f'f’ifl 4» 2 (Eryn 3.4—) m1] {3L3} 4-1:, h) ' {£13}? 1 51 a :3?“ a 1+ 1.3 n In,” ’3 " 3M1: '3 " kin/kn f .. 1‘”; It"; in: km in and kn " mm at. mm mm ,1 uMummmmmbm-ou unmammsmwmm.mm ammummmmmmmm‘. noun-(mummwmm. mmm H n lam-p. 1......deth W, momenta . W m n. .44!“ng 13*: ,v «grant _'_ mama) ~ wag)- 3215—}t o tn ((1: In I- Y}. (13,35).)” “1‘: (M) (mtxgo); ‘. (3,051.33, 1'? {a ‘31 t vim b, '- r331 b3 . 93"; *3 " ’18:. ‘g. :58. $311.- 18 a 11m: tarmticn of firm nth respect to the meter bivalv- tng bath m mcmtmtm, 91,. am Ea, and Q19 mom: réactiviw mu“, 1*; and x". The alopa cf tE-aia 1mg: 1:: a. inaction of the rate) of: initiation and tbs arose tantamtim emstant 9". Shme the mmtivity mu“ m Mom for that malamfiaaticm c! styrene and itaccnic WWO (2,28), from warts: pmimly £20113 in £11.13 hbcmtory, in but}: ham and Warfare“: savanna, the rats of palmsmucn am he minted (m the Mammd aquaticm ma values for batman Iolvmt 3:! them in Tale XIII and Figure 21. “We valuaa for ten-aa- max-cm Iolvmt. we aim in ”Kala XIV and Figure: 22. TAM XIII CWM RATE CF (Iii-{LIE ’"fiIEEflGE (Fm BeBet‘hfl Integrntad mum at 1:1 . 3 1W mmirme in Emma 301mm. r; c 0.615 3 r. I 9.80 TM ##1##— ‘m 3-4: :::L AL 7%; 44:: - ‘ ' luv—TA 1*: . [mm Ti 4» (ME-film Tim aw ~:~ - _:; _ 1mm I (151$:sz fl" u [b.f 2515 1. Wfl W0 “ta-13W (ml-1mm) 0 2.6a: 2.5? 15 a - 13 4-— 2.38 . 60 2.1a 2.39 120 2.29 at 1.33 . 2.16 130 1.93 «- 240 2.65 2.03 350 1.83 - 2. Rim-immune am 0 2.60 7 Cr 15 2.52 30 2.53; 3:5 2.51 60 2.32 m: 2.16 52 «wmxBSKQ mSR own QQm, QVN 03 Q N\ DQ figure 2/ 1 W q d m. . O .xwkifibu QNGHQQ o kw®6xbw NQ Mm \ smfi n 0 66 "v \rngow mtmwtwfl 5. ‘Y.\ uu§mkkkm,\u\ «QQ\\UN\km§%\0QQb x0 mbe \\C Km:Q ”750/ 29/ + 22 WWW .___ gflzl’qu} ‘QU’NJ 42W] {3 ME II? 0mm RATE”: OF MPCLISETEMEATICfi _ (Fm mam Integrated mm, 01’ 131 SW: laconic Azmardrida in Tshwmimmran Solmt.) r; I- c .1 r. I- 0.3 2. Em'vuobu‘bmitflh catalyst 15.3 15.5 16.3 1? .2 15.0 15.6 1'! .7 15.1; §§§§§3§30 5h «WKSQV\ MSR @ .3 N\ S Q .v. N 0 . . q ‘ . ‘ 4 Q‘\ .A 4 < o o c a $3 0 0 ‘ O o O ‘ g 0 1*.\ 2 e . r W O \w%\b\cw oNéfiQ IN % JQV < o xw \b.x\0u NQNm 90.0 n 0 x 3.0 nb ‘ tqfifiqw KER S .V\ ..w%m&%xw \.\ \tqibkamSmwonxob \o wch \\Q\m§Q lg) W/ 60/ I 2;,(ZZl/VJZW‘9/[WJ ([ZVVFQ/ + 2([7/V] é, SS m. ”WIS CF mnrfi*ubu{m A453 :2 'A' 0131.!”4 86:4 33211319 Sample: of tha Mwitacmc mmmhfids cspc‘lgm prapamé in MM“ mam XI-awmtmlnadto determine their mum. m 00901me were flat purified by Win We» .umwithbmmmgmm meternndmdriede-mm mammnemmmmumnmmm. mm mummwumndmuchumplum acumen: titrated 90th (1,29) and also with u h1g1 I‘m-m timber (2914,2934). A. 3.1mm Win at Ccpclymm 1343 mines. of summit Gas-mm in the) comma anal“ tram carried out kw Mom-Tech Walton-an, 31:02:19, mum. m Tabla IV. 3. PMW and m mey wwm a! Emma-Imam W“ W mwmmmmmwumtmwmawm {motion 0! Que “mania WM unit. The £1th m followed NW (1.29). and mm a}: high tramway tux-1mm. Wm ion ammunition m7 M an a. 3m pa mater, ‘equippad *flthflAuMa-mcmdnmwmdm. Waugh Mmy reading! m m m ; titrimtw which has ham W by Dr. 12mm: (294). Both mamas were taken aimltanmualy mthobmmdtmuflwMudWhyW.mtiond both method! In and. 55 313.31? mm or mmmmmmc gamma W5 $22924 42.4w 44mm m 330. yes 93.7 69.141 0.5714 Bun-a 3.0, no 93.? 67.624 0.619 M BIO. ya 100.2 69:“; 0.584 hm am. no 100.2 68.91 0.538 m bin-«o ya 11.0 69.52 0.570 hum law you 71.24 69.69 0.531 mm M up 11.14 67.92: 0.6% m nu. ya 13.6 68.10 0.608 I! no. at 3140 71.19 0.536 B! m. 1. 142.8 72.00 0.505 m m m 12.2 70.01 0.55? a! m in 514.0 70.16 0.946 m am no 514.0 63.30 0.6014 mm run-W ws’wm Manna-WW0 Id.uiwm magnuunmuiwwumm Q i'. ' . $.74 . . . . ‘... 5.1541. if 57 mmmmumummm. htmm ‘ , umwmmumu(wwymm).mm 13m. mmsmmummmm .mummmmummmm. mm mummmgmmumwummumw Wu“. utwwthuhtummwmmmid mammumlymmobwwwmmm Wuummmmdmwmmmm. mun-x WhmmuMWqufim-W 41W ' bmntcmo. “WWW W10. (WW03 Whudu' mama-mum mwmntmmw «nu-W mmtmmummummmm mummasmn.awsmm mum: Amammumwwmwmmm mmmmawmummMom. W Wanammmmnma.$.wmu wmmumunnmmmmrwamagmza. A W at the first: mamas a! ccpohrmer mmition amm- utian 11 1mm in me I"; '1. mf‘H‘SITIC’I (F 31' PCT "“ .JTICZE.“ Wang!" «3.. A. u 4.1.»!- “3.13 Ami“ III; III 59 III ‘13" TVS? SEPC‘LE :33 W 1!, 31519 Fmticn of I Icon-II In» ”'17:: solvent mm W animation Pfigfia Ifiefl 3mm» BIO. m 93 .1 0.576 0.575 ' Imam mo. yen m .2 0.561 0.555 W W was 11.6 0.572 a» Imam hm m 71.2. c. 32 0.555 1'23? 3!}. ya: 1.3.6 0,555 I. my mo. yea 31.0 c... .525 m nae. m 1.2.23 0.568 .505 215‘ w r» 12.2 .561 .. m W~ In! 534.9 5&6 .3535 m M: “D ‘93 .7 0.5732 4» Mm 310. no 156.2 0- .516 .. Bum W no 71.1; .538 .. m MM» m 93.0 0.232 - SW1» 229‘ I Wm M. a bunny]. Ma Bit-um o meWtIno ‘ ._4 A-.- w._. V—v‘w— w WI,- w m figure 23 /2 //I pofen f/Omefr/c ”fr/1790;? , 5 fyrene: /fl Colon/ymer I 92 % paymer/zec/ / 8202 emf m benzefle 50/41 f/on . A 76180615 Iowan/are 0.204850% 50/77/9/6 25.00 ml 0. 9966//V AM/I l 0 2468/0/2/4/6/8202224- m/ /7/C/ Q/Zgg/V. .r I 3.! 31‘ 61 figure 24 86 _ H/yé 5’6 gale/my ”/ra/Aon) Sfyrene .' / I4 €0,00/f/mer, 92 %/Do{7mer/zeo’, 8202 caf ' _ m benzene so/uf/on. ' A gaeous procedure 850L 0.20489/77. 5007/3/69. 25.00 ”7/, 0. 0966/A/. A/aO// 3‘ S 8 Q— 840- 3‘ Q m B b C\ 8 .. Lk - \Q .. 23 8:30 :1: - 82 1 1 1 1 011l1|11 0 2 4 68/0/2/4/6/6202224 ml HC/ 0/298 /V. figure 2 5 62 /2 p0 7‘60 f/omefr/c 77 frd 790/7 , // _ sfyrene .' /. A capo/ymer, 92 70 po/ymer/zeo/ 52 Q ca/a/ysz‘ 0 r- ] {same/79 50/u/m/7 9 .. 8 .- 7 .- 5 . 5 P //a//[1 6'5er procedure 0205? 9/77. jaw/9 /e 4 _ 25a0m/ 0,0966/M/VaO/7/ 3 _. 2 0 2 4 6 8 /0 /2 /4 /6 /820222¢ m/ HC/ O/ZQB/V. 63 figure 26 8’60 840 H95 Frequency Peed/n9 820 1 1 1 1 4 1 1 1 L 1 I; r 00 U. Q I H/y/z [reguerlcy ”frail/0r), 57‘yre/7e .' /,4. capo/ymer, 9.2 70 pee/merged) 8202 caf. m benzene so/u 790/7, I Haw/ff: e5 fer procedure 0.2057 9m. sump/e 25. 00 m/ 0. 0966/ AM/IOH 1' T 02468/0/2/4/6/8202224 m/ HC/ O/Zgg/V 6h figure 2 7 /2 H ll)~ p0 fen home. fr/C 7; fra f/on , 57/yre/7ex / A. cope/yme/j 920/0 po/ymer/Zeafl BZQCJX [De/728x762 Jo/af/Ofl, unexfrac fee/I x4 gueous procedure 0. / 908 gm. sump/e 25 00/271 QOQéé/M A/IOH L 1 l l L 2 4 6 8 /O /.2 /4 /6 /8 20 22 24 m/ //C/ Q/ZQcQ/V. 65 figure 25 _ #95 Frequency fifrO/z‘xorz, 57‘9/73/78 .‘ /. A. (0/00/7er r‘, ’ 850- 92 % po/ymer/Zeafl 8202 car? _ m [38/728/28 so/uf/en) unexfrucfea/ r by S \O C 840* Qw E3 U Q P Q) 3 C\ E Ayn/€0.15 procedure ‘4. 830* 0/9089/77. 50/77/242 X 25mm wow AZ/Vaufl Q h- 820- ° ' 1 L l l l a 1 A 1 0 2 4 6 8 /0 /2 /4- lb /8 20 22 24 m/ HC/ O/ZQB/V. I. 2. '1." XVIII- CEZQRRISCE G? W CF 333.1353 GP CCPGLIEM DCEWCSITIGH . .0. . Av “luv-“m, . - -~.h”mmW-Im‘¢~.u. -‘Iwar- .--.-w.-.-Mmmg*wvm ~QA I 1' .13, ' ‘ ‘ 5mm; MW Pom car-hm 301mm Cam than mum Anal. Win; _- _ ;MI:::: W Emma me. am 93.? 0.57:. 0.936 0.5420 W M. m 93 .7 _ MGM 0.9.;2 0.534; ammo M. are; 150.2 0.55:: 0.563 0.500 Bum M. no no.2 0.533 0.515 5.500 Banana bin-“o you 11.0 0510 (2.572 8.570 W bin—cm yes 71.1; 0.531 0.582 0.506 8mm bin-no no . 71.2. G .6134 6.533 0.550 m m. m 18.6 0.503 0.605 0.1m; m age. yes 31.0 was 0.52; can? W In. yea 252.3 0.505 0.53:8 0.520 m bin» you 12.2 0.557 0.551 3.3 III: M m 524.0 0.536 0.536 (”ISO w him an 53.0 6.6024 0.1m c.2430 mmmmn‘mw‘fiwfl 4;... mm 7.“ —-——- MW ._.LA LL..- mm m < ' ‘ "v wwv—v— mv—m a7 mummm WEIR}!!! CF m7“ am? 23338 EMITJLI. CCFCP' Ind mwmtdawmmbemmdbywot thy tannin; mm. (3.39). I.) 3mm b) m: m dabonfimtim a) may «1) W16 WW- 9) mm W 2) L1?“ muttering mm mm, csrynacopic prepaz'uu am and map datamismtmm m We We! a: the number at particle: in Minion, hmce, a maim- cm:- mloeuhr «at; hf. is obtained: fin £1333 £3313 thmrbwotmlmlea 2 E1311 2: 31. Hi I m night night. mm“ m a. polyaar wlutim, on the ether hand, is dapmam upon than an or one}: particle in Iolutian, hence, u might nugget” m1” , Night 18 01W ‘ ‘ ‘t , a a 93'“ ., :31 a Z F1133}. The may (21' a. pclymr minim is a. m 0013;111th madam or use, sham amt mm a. muwm' partials: in mum, “W3 In Why flange mlww weight 13 cbtainai- , W W Z H1331. a I c con-m Wmmcmwwm maplacmmwvaiffamt WWW wastes, 03:31 cf the 35m mgmvfll We; dif- twt tuna. Tao mm of 2.2m mamas mimic: night 1. an 13:61-- catwn at the W at tho ammum a: mlmhr night... In ammlthotwmmflmcréar :4. >1“; Hg. The mailman: weight». at than Wu or charms-1W W&,memWM¢n-bymmmm light muttering unmade. A. Human.- va’dght of Shrmecltacmic mmma WW by; s cm Fm Emmi 1. m- cm. The W and in $12.6 ayn’aawical 093.]. block type, decrement h: M and Find (30.32). 1m 0311 «mists of m skinless steal bloom, not: or which his mm moaned Bantam widget with avaumamlmmgmmmamaapmmmmm. The madam In W 13qu the tam blocks. Tho mater ridge at ”h block m mam Mam? um: km supporting ridge: no that the Wmchmdugbthmaunwmt. Pimmz-cpmvmw to 1mm propa- WC 0: the My. & Janka m widad tar mammal-mg: mamuminm thalamumcta W Wm. WM, mm m mm to be Mutants I}? imam. m1. Therein”, the mm.“ were man in In .1: mashed constant flatware mm mm ma emanate: insulated by Wit mummmxuithchemcloth. 1%.: upper parts lend to was «2.9111317 tubing, 1mm: we con- wtadvzithgmmdghu Joints. Thalwalofligddnammin the «5:111:17 tubing by m of a mam-mm. amour: pm mm: me man by we mm 91th .-' (.33), 1.0., the mlm‘umtowmmmgnmmmmutmmm mammtandjuatmadwacmtuprmm. Mashhad a: Want m and. in NW to tho Gym: mthod (31.31.). mmm,ofmhm,mwmmadtpltmm WMMom. Mmmmtanmd tmmmmm in; the can chums-I !m the bottom. 30th wheat and solution can: we” rinsed men}. that to am aermct maximum and W0 a: :1: mm. , 2. F ‘ '. The 0313ch and m‘mmticn 01‘ ski-2.6 eternal-mama man-am to be _ and far 032mm pressure mamasmm is mot isms-taut, an mocm 121 3)?er a truly iampanmala mzmmm damn” that mam of WW. Wmtarifla Mabmnwd (Kolmwhinhm * Mun. wimp”. gelatin, mm:- (neat, mm yam, metallic {an and poms m. calm“ mz-bm mm by dmuuting mmdimmumd for the” W3. Germain» mam too had in mm sanitation am aid not term A tight ass)... Thu pmodnra (35) w to paw w nahmnaa fellow. 71'; H. 8. P. Canadian m usad for casting tha films. Fifty ml. of 00W mu poured. into i brads flag, 1:5 can. in War, which was flatwamacmmcoozmmv. AMOJM'mpluedmr thorium dam; Comm bubble 1'6mequ W' or that Iolvmt. After drying, the common mm m “Rad my Immonngmduullodutar, fiatflmlbiu dwmmm mm rough «1m out or: tin film. an damning mm a: W a follows: we all. mutated m (35 3.) an W .- “mm with lawman mind. by bubbling the ”mammmm. EMMmrm,mud1-o tum water, aux: planed in the ammmg mm for hm hours, use. th taming and stirring. LM m mm mm {imitating mm mm film m mum-d mm). um. 11: M11106 131m: tom by ”mud.“ Ming; in 50-50 mmml, ethanol, 50-50 am}..- «mm {Wigwam ma WWWWm-mm and may 03.1mm! to dry at. 3. mm of auntie prams. C) swam-1mg NW. Vucpolam W in humans What with bin-.031 gamma-ta mm . 1:» mac gm of mama: minusc- of tha mum of WW@ tmmflfla cabana": fret: polymerization in bansma 71 muamMWthtMmm m. mmuummumnmmm mmmmamwmmmtwm,h.u mwmamgmzmm. WWW w 1! Chad dun, gummmcwmdummwd m, “mm n 5% mien.) mmmummummmm mtwmmma ‘6'.- E. 0 30 3In cummtiannfflmpolymrumfim nnwmshnt Tommmm Bulimia-m mam-mmumsammumcuvbwc mun;.mmumo£mpe3,wmnmutm Am, (1.... infinite mutton): is]. - g;- mmummcummmm.wmm unummmnmxm. 72 figure 29 «wKEQV\ wafik m.» S. aw Q S. m\ 3 .3 8 9 m. m a m. o - q 1 1 u 4 q q u - J q q - K.Q % U/ 3 a no 0/ IT . m/ mQQQ\\Em OQQQQ uh << Q ! 44 d o UJJ I I o .44 ...m,\ mo I Q kw H J r9 (0/ 3 .§ m/ w 0.35%..“ 3&6 n u /\ Q < <0 q q q a q 4 a O .o o o O JMN u .1 . , x . oQQNQNV S axotfi \meQQQxQM V\ ..m§mk%\h «Wkkhwwkq SXQSWQ mm 73 59W. 30 p/m‘ of WC agar/05% C J nyrene: / A Capo/7076f prepared m fienzene Jo/w‘m/z 20- /5» O O O #- /0~ 7T (‘5); ”0 5 r 0 l 1 1 0 0.05 0J0 0/5 0.20 Concenfraf/On, C, (gm/mace.) 7h TABLE XVII maul-Ion a? in ma cmmm or ssrmn-za-mcuuc mum-ants 911mm: ma mama ammr um; amazon. mum; mmmw 0.0989 1&8 1.16 11.? ' 0.0597 0.83 (2.65 10.9 Wtion o: in: ‘ [glo 011.0 0% 3 '- 3.1.79 3 10‘ m..m./°K/mlo r - 293°x fin- 23.0w 75 b) Strum-imam) larval-id. “polymer propuod in W.» rum Iolmt with bamoyl peroxide oat-.11». the osmotic pro-our. or on motonc Iolntion of the oopolymr or Mankiuoonio world. pm in tatnbydromm solution with b.3011 peroxide ably-at m W. 1310 malts of three moore- m m shown in Figure 31 when the W height “time, h, in plottod awn-t tin. or mine in tho amour. Bo «Isolation o! noloouhr might in and. boom» the height difference never ruched . constant union: but increased for n time And then duct-mud. B. nolooulnr b’oight or Btyrmo-Itwonio Amuydricio Copolynoru by 1. Light 3oattorin¢ Hathod Tho no of light mttoring from dilnto solution. or polymer. bu ban adapt-d to m dmmmtwn of their mm weight (36.31.38). The average molecular weight obtoinad in a flight “one. 3nd will ordinlrily have u cum-m ulna thou tho number average room by osmotic pm mm for untmtiomtod Implu. The light culturing oi' main-laconic mhydrido oopohmm m matured in “W. l. The Light Scattering Photomotar. A Whom: 113m. muttering photometer (39) m and to m the aunt of light mttarod by untono oolntion of thus I «qr-m and 1mm anhydrido oopolymn. m. comm components or the photometer an a) mercury are lump 76 figure3/ mnkb QV\ WSR mNsNaNNNQNmQS i FQQa Q . . 1 1 1 q 4 q q q q q Q\ _ 4 o .W/ .uumm\\&\m. aQ\\.Q U o 3 rm . 7 33 xr m/ e f a. J m 13m. 3 a W/ ./ 3 w AWN ( QQ\.\3\QW Kink t\ \omxhbfikavx Km$®0©®u “\\ nmaxwkkkw Mkbwwwkq u\\QR\m.Q 19m. 77 b) tilt-n, to Adjust intensity and to provide muocm'omtio light either 1.3583, blna, or 51.6QX, mm. o) n light tight dork box containing 1) mlo cell, 2) photometer, nomtod on o alibntod tam-table. d) wording 91mm”. nu ample ooll m amt-01ml” in flaps, to allow light to you out At w anal. without rotnotion. Tho tum-tabla mounting of tho photouotor panama the sum: or mattered light at 0°. 25°. 90°, and 135° tron the inoidmt light beta or at my denim angle. 2. Procedure (or asking W“. Th. mt or non, mttorod n angloo of 0°. 15°. 9o° and 135° from the incident boon I” named for six commutation: or each ”polymer hoopla in untonc wlutim in the following We. 'in mm nook Iolntion oi’ known oommtntion (approximtoly 1:21 ) ottbooopolymruoplotobomwod,nopropuod. ivoigbod quantity of purified and filtered «atom to. placed in the oomph call am tho Outta-d light as mounted at the several angles motioned. Incl-unto of flock collation var. oddod, with vigom stirring, by a spam. stirrer, weighing boron ma sitar such at of 113m. scatter- ing Wt! to mount for vaporization low or occtono. With nob ‘ odditioml inommt or stool: uoluticm the mttorod light m measured at tho moral Anglo. motioned obovo. The dock solution addition: mondobylvpodoroio gringo, equippedvitbn filter, tvoloyoroot "diary extra-«fine filter popor m and u filming medium. 78 3- (mum of calculstion of molecular weight from light «scattering Mus a) The limiting equation. The limiting mtion relating tho turbidity, ”I", of a polymer in solution on: tbs weight orange mlamflar weight, K, is: [13%.] 0" 7%.. (53)) o a concentration or polymer (gnJmlc) when! 3%.) a correction factor from the diaomotry P 6 W3, [%]o s a , amacm/w 3 7‘ Ko :10 I refrootivo index of the aolvent u the an lmgth used for tho mmmt. (cc/dc) . immontof change of refractive index tor change of polymer concentration. A . wave length at light (and B. a ivopdro's motor T, - T . T. T «- turbidity at 90° or the pom solution To 0 turbidity at 90° of aootono oolvont Fro: the uniting equation it can be sum tint a. plot of Ho/Ta . values for no): concentration of polymer against concentration of the polynsr m ho mum to are mmtrotion to and [no/7.1, . i’ns ulna or tbs flight mango molecular weight, 3', on than bo maul-tad. m- mpn- urge/70mm; c m- uch c: tho thus oopolyunusnrodmohominflmfiundmtodinhhlu xxx, xx, um xxx. 5) Rotrutivo indoor or wotons, 11.. m mm c: mm c: um um um. 1058.35 A? in W ot 25° was round from o plot or rofmtiu index ot tour ms Maths (MAJ), at 1.9.1;0 c. From tho nus sou-cs A nuns aim or, 53 1: m‘“/domo c. ' 3 19.130 _ 1&3ng . 1s357 2; It 25060 a no I 1.35523 113581 c) Lotemimtion of (Sn/do. Tits inormtol clung. of moths influx of tho oopolymr solu» tion for inoromtol ohongo in oopolmor oonoontntion no mound on the torn “stout stock ”Minions. A Edam-Pm diffcrmtitl rsfnotomtor (he) as used, fin readings vsrs mused for web Mornintion. m. calculation of own/do from tho coon-rod findings we ' sham below so . 2.4.9. no Ao An 1- mmtntim of polymer in solution gnJ . 130 k - 9.53m x lo” (a aomtamt) Ad - (drdi) - (co-m, o, and a, - reading: at 0° and 18o° for the polymer solution c,“ and c,“ . macicga at (P and 130° to: the solvent solution Acetone solvont pm- a rains for (elf-cf) c: 1.30, om: was mad for s11 thm staples. The! ralnoa of (Sn/do obtained are tatmlated in mm m. 6) Calculation of the value of tho constant 5. Thu nlns of tho mutant 3 can be oalmlntod tor wotono solu- tions of strum-1W0 anhyfirio‘a W using tho nation: 1-! . 3%. I grin/dc). 3 7\ go when no It 1.36523 cn/cc a 0.1903: mm. A. 14353.35 1 10.. on. no . 6.023 x lo" one” I then a :- 1.0275 x 1c?“Ii £394) E13 m' on} 0) Calculation of, "I", the turbidity values. The turbiditlas, T , at each concoutmtion of the copolynor in ‘ wanton. “lotion were calculated with this emanation: 1m" " . . , T F;- x ifh a: t o i” an intensity of 913° tattered light mg XVIII Ema-”“7103 CF Woe VALUE or mommccgm W ocngm SW31. 1. Cnmlmor Prmmtim Von ' “W 11,4, 0 oc/do ammo one. 2128.5 1.0372 x 10" 0.19033 no mo, 2014.5 1.01m. x 10‘" 0.19090 no bio-um 236.o 1.1792 x 10" 0.18963 Amen ulna or tin/do 1- 0.19032 nlJm. i°° - irttonsity of: C° light, no ooluta 10° . intomity c: incicm light initially, no cell Ia ." intmsity of mcmm light for each reading, no coll t . Sign] Lucas 3: 10"” 0.0 T. . T . T. T. - tummy c: the saints at 90° 1; :- Minty c: ccctccc oolrmt at 9o“ Manolo: T.mtaholatod form orthothroacopolamm mummxn,n,amm. 2) notomimtion of tho oorrootion motor, (We), from dimmotry WC, [2]“. m intonoity or light scottoroo at angles of 16° and 135° tron a paw-outimmnlotodtotm stupoondmootthopolymor-olo- ml“ in solution. The ulna for own}? zmo was calculated from this nation: 2“ . horiiooh no _ no 0 where 1., . intensity of mttorod light at 35° Ior tho polycar- solution (1‘90 " intmaity C“! WtWPM light at 145° for the acetone solvmt 1m . intensity of scattcmc 113m at 135° for on polymer solution “m’o I intannity of mattorod ligfit at 135° for tho acetone aolmt. 1121:; III MEET”! A31?) "1‘33? Sinus. (3 WIMmic 3331331123166 u Gugwlym PM in Bmume 5101th with Rmzmrl Penman 03W) 0 68.1100 :31. T. lie/T. 2“ 0.0253153 24.01.33 :3: 10“ 0.6708 x m" 1.1:; 0.0343711 1.0573 x 10" (2.7672 x 15"” 1.1:: 0.0631355 . 9.1.591 3: 1:“ (2.7397 x 19"” 1.13 6.632665 12.£2§5 3 16" (2.7539 x 10'“ 1.15 6.15935 1.3.5657 :10 10" 0.7513 x 113'” 1.19 .5 6.134355) 1.835%.» S a: 3.0"".I 0.7367 3: 10 1.17 ‘4 1— ...4 1...... ._ ._ A- ._ H A A. _.._ “1—; - ._. ‘v-v- w v- , y‘— . —.,— _ r W V M 5‘ warm H.11- mam-z 3-.- Emma (Emma—Immuic Anya-1:333 {Myanmar Prwad in 19mm 561m with Emmy). Par-m: 1&0 Catalan) O W :11. T. WT. 1” mousse c. 39 x 10" 2.6986 x 10“ 2.1.0 0.6:.7273 2.532s a 1:." 1.8813 x 10" 2.51 0.: 2362.53 3.5953 x 10" 1.5.171. x 10" 2.76 0.056%0 mass 3 m“ 1.6531 x 10"” 2.30 9.107551 5.9702 x 10" 1.8551 x 10"“ 2.7a 0.12:2.27 6.8232 x 10“ 1.9639 x 10" 2.52 “IVS-’32.. “m $.17.) LIE” w. ””5! mama (:5 WQ-Itaconic Aniryfirizi a chlatm 3' ml in TetraMmfux-un .A.--__ .A.._ ...__ A Solvent with Bimw-isobutyrcmw Catalyst ) M a .../m m. T. 30/7. 2.. 0.035975 Jam x 16“ 3.6933 x 10"” Ml. 0.063361 3.3.123 z 12-“ 24:56:. 15" 2.3.3:. mam? M719 1: 10“ 2.1873 x 10" 2.39 0.128033 6.0706 :- 2.3“ 2.1679 x mo" 2.52 c. ”5331 7.2770 x 19" 2.1911 x 10"” 2.53.. 0.1761293 9.61.61 3 10" 2.9968 x 10"” 2.59 “1‘: *MA * ‘ A—A 86 5.... 32 m. .6 «cu QQ\\§\%\ Au PtmfiauKXQMutoh V\ .Q N\ .Q Q\ .Q %Q .Q 60.. N. .WQ Q n 01% SQ SQQSSW meNQmQ Fmbu NQ wa o x l 0 d d d .Qx _ §$R$§ £8 .03 a m m fllfm . < D O C G. QN .0- D _ C u\fi.x\3\©wx&\\.\ \Hxfiw QNQ-W\Q . LQW; L .s.% .25be E bxmbxavskou V \ .. muwkmwh ka u 633%?» “\wb\ .68 wx0\Q\ 50/ X 54/9/1 £7 A plot at 2“ mm... min“ cancmtmtion, c, of the polymer 32mm 32:53th u. “night 1% match can be mctmyolated to new concmmum t0 gm [2)... the intrinsic magnum-y. The plots at Mumcmrthotm-Npowm.mmmflgam 33. Assuming that than polymer molecule. .3. pelyuiaperse com a value or mm m be tom: me published mks a: (22]....5 1W we) (37.3.3). is. 3101304313: weight mucus. I.) Emma-itaeenic an‘miérieu «gamer «maple med 1:: lemme wlvmt with My). pemadfie new mimic- ueight mm. [359...] I- 0.62.0" x 11.32:"5 T: o naming migrate-«yew ecu: [21‘s . 1.113 PAW) an LC? 1: . 3,, 1 [fi] 0 7‘! (33(6)) Fag II 1.57 .134:ng , correctmi for fiiflfi‘flMW b) Stmueuitacenie 3.12m 3.21.33 00130157111331“ Wm in tat-.mhydroc Min solvcmt with bmzayl pemvide ca PM , molecular weight calculaticn. a— . , - '3'; [Ta 0 2.00216 E K. ~som ‘3)“ . 207° (“(9’). 3.“ [3:] .- 3. (M F. ~na,om.nmmm. ”WWWWMhW mmmuuunn-Wummw m [3.] o I» 2.09me a; T- I. ~ 50.000 (1)“ . I." (“(00) c 2 .29 M We») 3. amm,mtwm 89 «QUOQ\\§W\ \U «toibkxtmutfiv 03 .30 NS 9.0 was 00.0 36 moo QOQQQW QONth a .28 46.6wa fl 4 4 a 4 T Q n. 0N n x 3 Q\xb\omfl\\\n\ xbu .0 m Q 0 L! O 3 +1 l.[ m Luv 0 O o 0 PW QOQQQQKQK ambumwwm meoxmub S r,\u$\\o0\ou .Vx\ .. mtmtfim. Pox . .u “3.3me “SN .kauubkkaflq x0 $5\Q\ is... GET AVERRGE rmma It. .flfiS CF 8Y1?“ ~..'..s "’E-ITACCHIC mm REE GCPOLTESIE FRCH LIGEH SCRI‘I'ZRIIIO *mTLX‘; W W __ TL :Eifwm Styme I. 1. _ a. W %£m Corrected for E Iv-unt. 906 Turbidity mm W m I: w I ..._. “ 32mm aw. 155,060 167 pm CBC?" . 3..“ '3 1'13! I c Qflh’rme 13...; -~-°E33.LRTIGE OF meet-11:0 AXE-if“. A1121 sm.m I-KARZEEES 14am for thc dmmticn or masonic We manner mule be based on motions of either the .ctlvlenic mantion or the acid Wide mums. Beth reaction: were mud maximum mwmdmxmmmwmmm mumnuhtioucmhmgbothcttmw.»thssiho nuutmmmmmmhewmnmmu: Wealth: mm; W. The numeric ”out. reaction is a rapid prccmc tar we do. Wmacmmmmmw. nmbcenccmly Wierutyrmcmlymmummrmwm(n)tom wwgmmmmummdiummuaimcum. It utmmcmmmmmmtommtoxnswm Romania vacated“ the extent. «£923. mu Ha nut-mun mu notified at mm “fiduciary (or mmumuamemmmmmo: mWwiionuiflzthoiW Wchmx-uim, vhichmlcumfiitlmfcrthoupecific mmamw far the mum 0! to“). mi of mutation. ' resumed thmmdtor museum-manna mflwtwfimtfiwmfcrimmummomm c: was. brown. mum. name.- the direct 1.1th at the mmumnmtmubmmmmcmum fiVQW alight medium a: bum 11c imamc We. The testbed for deiermmen cf Hermie aniwfirflc, with Ulrich W we not interfere, in the £3.th cf the said We mm. “the cream: tunable were three: a) «mm titration with here, i») back £1th at a misled. «we: or beau, or c) titration of mummy-mammal. rmmcumcmcxmumm uwmfimmchcncnummtew tepid. WW1:- and to am it-ucenie Wade «mutation independent c: the mamm. “Intercom-mum“ mmmwmmmmmnmmwmmwum can he and on ; «polymmuca mom. Wmmmdmmbchudmiu Widowmuon. mmw-mmtormmm anon. catalysed uranium and mercuric “mu mum can not ammfcrmwa imcwwrmammmm m now than. The direct mum meme (lid give auntie» hunmdwmmmmwmmtutm mm of m. mmtmtica withcee interference from 1mm ammo. Mommy. immune in an emu-notary oclvmt tor the anemia-tide, because 8 yellow color, termed on first caution of Wm, med m an: point. Wang and Levin (1c) have mortar that m calm were militiamen for the nether tame the we point been» Wefmite. 93 :1. mm: «1124111121 or 2*:2 :1: ram mascara Arm, Emir Warns were new ta 3* t? .e «Wmmetion oi‘ a 3.31 mole ntiootcmmi ifiomficafivfime. Mmcafimumetm acumen and We autumn. The We mm differed in tint the «spawn! momma in m,mmmmmmmmmmm. W M «W used were beeccyl peroxide.“ him-1mm entum... emyipmm in «Myme initiator ad it in known to new am Wed ewmm (Ms-116). mercies-c, its} «companion in no“ rim].- i'im crdermtienhinybo «Mac. by orange or «Mme. The dammit-ion a: him-1Com awommmwimowm tantrums (highbw) in! it! decemaitice in Mme of mlvmt change. The oopslymriu mummmmmummfi We. Tommio mammmmammmmmMmm Winn: 00.1va the «grammar were use me with Wimmmtrne u «We. mm «mm of the «polymer fume-.1 from a W of We . mm has been mural: steamed and a «power emaiuon mm m hem rem-name (531,512): err . ( "EEH', 55“.] i Wic- were {all we [‘3] m the mmantmtices of mm [14;] w: [32.] in the meme: name and .21. [:1 ,1: and era-13} are the cemmtmtium of the masters in an Laramie cf «pawn. 1:11.. «name! :3 and r. em the many:- reactie ty rat-ice and repreamt the rec-tie of reactivity cf 0. free mafia}. fumed {me (me mumm- with the cezreepczaling manner, We to the made}; of ”the tree 1mm]. with the ether W. tall (31) he: «gamed for an 113ml. «polymerisation teat the reactivity of the campers 13 indwaami c: the mum of the free radical.» In this ideal. me the mace medium! ratio: would be the mipmcul. at one weather and the value of their penance, r115, mm be equal. to cm. Hourmr, the usual. value {we fer rzr. in luau than one. 111 crimes «are, in mean am an new, the ulna u! r333 .Wm mere. Tim the critical product qr. my be team as. a macro cf the «Many to:- the manner: to alienate apex: entering the wpoiymfl. The nmiivity miles at star-me, I!” am theme We, 33., have been determined , from eupolyaarleatiunc previously curried cut in this 18120th (1,233). me Vance mm for «mum: in amaze culvert m r; a 0.91 r, «I 6.36 mu values fence for polgmazizatienc in teem-Mfume «Irene were: r; I- 0.10 r, . 0.3c 211'. I- 04:33 The: mluu m? thu pmreuct , 91:93, in bath cams Lw‘licatua a strong: animal 6! the: mac-steers he alternates in the} ccgalgtmar. Pae‘atmrm re}, that aka-mum; tauiazqr is atmngm' in bamma than in tutmfmmmm. Thu auburn cf the ulthmtfing underway in ccpclymr tomtian has baa: sum-21a. Lads, $512.30 and. MM (532) magma: scam dipole mer- notion m- omma: tenant-1a: bump" th- mnam. Cum (13 £655,520 have them that the tazzany W33 titanium 1:! p018: in origin. Thu We. mum: (Sfifié) has been derived on the M: «21' mm elm-3a! arising I‘m the polarization ct radicals and ammo WI and assuming that the cfmgu in the was for both the manual ms! the mm. In the with man of murmur ane— «late We that m mum II to mm or net the WW1“ fight proceed 32.5 a mania: or the two mm, whiz}: mum be this ranting spud”, team-.33 tn the W3 chin (SQ). Wt Ind 0.1110 (24,57) lawn damn. that this 1: possible in tho mu of flame and mm animal Which am am. (1) has fame Wane that W and “manic surgeries my cmhmdau in t 31313;: mm. W an m that the raw 01’ 120903323: fumm that tho mm in. that W fith mapuct to m assume mama e: a 1:1 mafia: of straw anti itaumic mama. For the four wipomamuam «38* as: studied first era}:- aways-o me was fame with Inspect to oath-aw atyrmu or 1mm caveman camautmtion, :9 03mm in Hm 13.26. Reaction rate constants were calculated {mm the alias-s of than linen and they are name in Table XXIII. Thu rat. must-anti var. wily eqml, whether basal or; the dia- appuunnuu or W or 1mm ammirieu manner, in each c: mu four War. Tho umcmtmticn c: a 1:3. mitt: of styrene And ituccnia m‘wfir‘afiu amid be Waited by firm ecmaztmticn c1“ 3 that monomer, and maternal: tho c105»: uppz-saimm of first. urcier dupeaclmcu with tweet to either mmnur would ixu‘ficats that the ccpoWrisation a! styram and lacuna mmiridu might. procuue gig the 1:]. amines: of the mm. The «1:13! of the rate cmntmtu, Tabla XXIII, and relative rates at copulymur fomtian, Rama 3:; , a; 811m: tint the copolynum'imtion a! W 1nd impede grammes was faster in barman, from which it. an precipitated, thus in tetm‘évlmmmn, in which it rammed in ”nation. The rat. constant, with claim:- bamcyl panama cr bit-aza- mummim as catalyst, was many was greater for Ware than for immemfumn solmt . Thu largo dfifuramu 1:1 tutu of 1:0th in am tum 3033th ml womanly the result. at a large diffuz‘meu in the mean rate mutant, kt’ m the we ashram-.8. Ccnsicihrim; the case at In): one W, x, the tutu u! puLmarlmtm, %, is fiutunrfinud {ma th-u renewing rate mania (215') a — TMZILE XXIII FIRST Chi-"13:21 R?ACTICR F3373 CCRSTAMS (1:1 Styrenmneconie wartime Cowman!) «’“‘.- -w‘----—W~~Ww"«mw wa'u-oWOWOMMAWm.wn—fimmwammwd*0..-l‘r~-. ‘ T33? bio-nae 13.0 3 JD 98 «wmthkQ MKQN 9% gm» . 9N» gem 3m. new mmx m3 figure 34 d‘ tQthw wQMNQmQ «Fob NQNQ wto\\bN\\o§\%\00\ou V \ ..m%m\%xw \.\ kg wabm\ *0 towC‘GQQQQV 3+ «‘3, [10/7/DZ/J3Wfl0fl 05 Q K9 0Q 09 P? a (“49* [31) kt. emmmanmmqummdmmuawm mm,unwwuuamormnuorpom¢nm9n max-Lounumu. amu'nummumm the ate at mention, at. or the «to constant at my“, RP, minerals}. ammuummmmumnu m:ummxvmmm Wmfiuotpolyw “IMMOMWIOIWWGMIMWIW Int-(smuaomtmmmpmmmummm mmumwmmmmm. Inbothmum mmtmnummdmmmmmmw uuowocxpmtmmbyomormmumm flames-mm. munn»mum-twuummwmmw mu WWW m with mm W «m n mmmwmmmm. mama-mum. mammaummwmmwm-mmdmm otthobwfiwmddoam. Witwatdmpmeatmamwmwpumm «mat-mm nu www.317mbymufl'l), tor the tour mmmtmmmmw,mamzz. whammutnn mmmmmmtmrwmmnmmmmvm. mmmmemmwmorrlmrumrmmnum III! or W and swam. in this comm. m, the point: .10 “mm tor mung-mam in mm me. was m previously determined mm at r; we r... {or @90th or am: and mm [amends in tmmmmran. The mmmmmmmmpgmm rm. unnltmoi‘nmd nrorpclmx‘nauena mmamm amawwxmcmmuoflmmmcuw We. The mum {and by mtnpohtm of the plot. or Wmmwm, Figumsnmé, tot-mummi (3.60 ml. {action at 1W0 wwxma. The new napalm cowo- siticm Minted from the values of r; and r” gravitas}: detest-Mme tar «Wm nlvmt is 0.51; ml. {mum inmate W0. Whom. the mm mm by «wwth to um was, new“ 9mu.mommmmaamoamwmh melamine-1y WW0: gamer. “tantrum tandem. mohmrmum in WWW solution «it: nut predict we Initial wpelyeor mitten fame in 1.111: study from the rate at dis- Wo! them. Telnet! er awnm «1.me on the Wine that an amtmpie exposition ecu-urn n 0.}; m1. mum laconic Wimp. In this we the eopolyw manna mm rectum to: ”102?. a 1 It as MW teamed mat the degree of :1th ms the m u Ihmfmthepmimavelueecf rlanérglethat: fir. ‘ 0003 1111 23238:: tram mum: were valved simltmemaly the foaming values were rounds I", II 0.33 r. - ¢.CB Using then. estimated value- fer 1', and r. the rate or disappear- can: of the women m minted true the 2:33am: integrated at. mum. mmthmmmmMmfim 35. Timpomu immuuatnightmemmsimm Figure 22. 1L2 mm in? 0mm RATE OF CLWLPSEIZ’ATEGH CF ’ g :1: «3.; 52m ITAGCHIC ATE} {II L- m "E (1min: r} In 0.38 and r. I- 0.08 in Wmmnn Solvent hath Sim-isolamymnitrm Catalan) (b mm" * MIMI)" Tim mm mm - (him!) 0 16.3 3" 10.1; 113.0 150 ' 9.8 230 10.7 1520 10.2 ace 9.5 “:w u “A.“ _-_ “A _—_A _.A__. r wry“ V—fi ‘7‘. V w. w “W 7‘" v—v _, ~—-—r r—V’W f 103 r A‘ figure 3 f) «kaQV\ w SR N 9 mV e v N Q q q 1 q q 4 q 1 a u 4 a m.Q I o O O IQ\ C .NV ix %Q.Q “0 390% h? mwsethnnhv SENSE“. K\\.\ S .Y\ 6:?me \..\ t9xb~§m$®oe®b mo mflbmwx \\exm§§ we] 50/ MW 2/,(Z‘W729/ ‘aylfl ([ZW]’9/*;I,([ {2' / [I III . acre-t. 317m: or meme-mascara mwme mmmm Tim ecmpoeition of cepclymer maples m detemlned after tint extracting the sax-@139 ccheuetiveh with bemmo in I. W actuator. This was done ta tree the ample: sz any residual 30mm. The emu merit beaten the «magnesium: {mm from titration mtiwda and that rm from clmtal emigrate me good for extracted amen. A «iii. fame was noted, Weaver, Ween the camitian o: Wotan} nan-91m detmined by the titratien mm and that calculated from 91.me Analysis. warmer, the cempceitiee o: the «polymer predicted from the rate of disappear-ems at mmm m the quite wfmt m that calmlated 2m culminate). amlyeia of the comm. Scam of the m why this ciiffemce in cepclymer ewmeiticn may have mourned are: a.) not an at the eepcknm was precipitated {me the advent. b) The mlymr pmfermtially “amine new of the ma all it w precipitated .. c) A fraction or the pelymr was wluble 1n bmem and was mad 1n the Soxhlet esctmc‘bien. :1) Trace! of was. such as W, affected the accuracy of timtim mum. Emu 01mm analysis cf the (mute ample gave 3. 11133181" faction of than“ made ten the arrtmcted samples, it was tame tint 1W anhyfiriée swimmer was 0.690% en the ccepolyzm WWMitat-m. WW1W Wu moot!» modbybmoutmtm, lime “manpolyaaamedtapclw 1% We mung thin mum which was carried m for long parted. or than .3 30° 0. races of mm much u 1mm mm hays prudently um ohm, in this label-gm, to meet tha mu w W 01' the titration methods «played (28), in determining the much of WW mm. W. 1% flu M W that. to find differences hm tho @0th mm rm :1th method: MWtMMIMdmemWW Owl-o 1C6 IV. HEMP! HEIGHT GP STYR'I‘WI'EACCHIC 1mm WSW The main» «mas Holman“ weight of polymer- hu‘ hm comm; datamamdbymotmtiommmmu. Mashhad“: Wfimmmm to am. the mlocuhrwim of: Whom“ mm oopclymr which had bean prepared in human: calm with buoyi W. «m. Tho umber W mlmm might round It. 23.060. Emu, the min pro-lure of tho napalm {if-W m Wuhan when: did wt «up: n comm «31mm mm. 1210 (name 1» height. W m two liquid larch, ”guru 31, mmummahm.mgammmgmum. mm indicate that the mm m M. m thy: 001:0in mic. Since the m mm I“ and tar mum“ of both come: m1” tha 60cm» in height with time would suggest that the oepolymer prawn-w nmmvmtmdmmlmrmm than that mm in bum Iolmt. Tho problem at much Mm”, which «1% W10 to polymer mimics, phantlmuummmmmmnuormlwmma wmdmmm mutant!” labs-attain“ mm mm (60-62). The difficult“! as grater for WM polymer mummmmmummmmz. 11th. W m “mum calvatt ti of 1m molacnlar weight, Wmafiuamompiamtmmmwmsmmmay to W tn: m avmgo miemhr weight. 1L7 himtaatm mimingd‘polmer untimhavobm W for tho “taming“ at m wig-ht “man W mm. mambmmumtormmmtm. mwumammmm.muumomma WWW mm madam. womuoamboohmm,rm manta-3w nan “munch... morning tho :1." mmummunm. mow-13m umpwmmm tron-90° mum mummmtorum. Wom,mmmmr fathomhpmndmbmoulmtmtutbomm pupa-ed In Wm ooh-us. mumammutim, F. mbowbfimt F - am A doom-ninth: who: Wtioumldbo mated to 1mm the average claw of polymerization. wherefore, the act tint tn. helm: “wt in higher far copolymro W 121 hamm- 001nm, m which thq m precipitated, than far the 00:30th propued in totruhydremnn mlvmt, in which they were Comb]... wmm tha prwim evidence or a «Wine morale in the rate ct copclymri- nmubmmmlmtduatogdmmomthonummcf “mum in I precipiutmg mm. mountain Wmmfimmfidfluflmmdew “polysa- mtmuthomoorulolvm. ThocmngomWéagx-«ot polymriutim, a, aims cm War, 1- mm .- remu- (as) a 103 a 03% M .1. 3; F F, hmcumcmmww,8umumtmw mtim,mflummmmtm Mammarmtmtmmtbmmfldfarwm 1n tmwmnm, MW, 11. has been reported (63) that both toluene sudéimnhnmmmmwwmmmfwboth umwmmwmhm men. Wax-9.3%» Wmummmmugmmmonmwommn WWW. “mum-Mamasumt Wmadmmflmnmgewmght,umrmmdm emmmvmrmmmhwm ' mmmotmmmmmntzlmrmmm wtummmtmnmmmummmmr mmmumwpom. mmwtzlflmmmmm by:M4ficflmflmottM1wm1mhrwdghtumlu,arumu mmmumwm. Lehinotnltomtmglmm mxmommdommuummummwwm :Wmmmmmmxymmmommnm. Poir- memalmdhhthaihapeotthawpohmmlm to wmmmu the man-mum actor. r"(e). Warm mammqurodbotoroawmueomluimmbodm. Mira-n- nor-,thowcrmmumflmmuuammuotmr in light ”than: mm. which had often been Wt ta 1C? We. rho pregame of dust Mich: would be impactod to afloat the éiasymatry value of. the low-at mlamflar weight. mp3.“ mm than the highsr mlm weigh 32:21:15.5». For these mm, the uncorrected values or the weight average melamin- wight we midsized ta be the mere accumta Wrath. (K 3313333021; CIJELUSIEfiS 1. Itascaie anhydrido mmtrstim can ha aster-finned 1n the mama 91‘ ”may by dimt utmticn with base . 2. 5%.er warmth: an be data-mm 1n the prams er lunatic mmhido by direct 1.1th with 23m in acetic ma, whm both mu m in hm ”hum. Tha method it mummy to mm aim meantth in tatmhyfircfmn mum of the We mm. 3. The at: of «:1..an a: 1:). male ratio of “mm and 1% W appmzimm first order dapmdema with respect to the mutation of similar monomer. The: apparmb first other mhmufammfmmmml W Saw it (33:3 3mm bemoyl pat-0mm 1.8 x 10"! 3mm bm-iwbntswnitfila 2.6 x m." 1'me bmcyl ma 9 ,0 x 10"” MW ‘himwmbutymitrno 13 .5 x 10.3 is. The Mu ”mg-a mlmular wigi'at, En, ct an untrutiomtad maple of DMD-inmate amends ccpolmw, mm with bmoyl W0 catalyst in bmmma aolutim, was mum. to be 23,660, by the «mom pram mathca . 5. Tim mm “m mm weights, E" or mm mm man a: mmmc Wcio oopclymorl, prepared an an. :m mt”, mm mm by than light mum-1n; mauled. rm valua- or E, m: HTM‘BLTPJE CITED LITERA'NRB am 1. a. n. W, H. a. Mo, woman at.“ mm» (1955). I. no In M)... G. H. W“ J. W. W WAJJ. m. (1957). 30 R. 30 ””3 II. 3. MI' mm M mm” W). he 8. R. Whit. a. M. W 8h“ NM” (19318). S. rommzom’ J0me“. mo'fl’ 20H: (”I-£5). 6.3. R. m. R. 3036“” Jo 39W, 40%. all...“ 116 (1992). 1. L. P. “one, ”Who in (fir-ate W.‘ 3:6 mm. D. c. new: ad 00., m. P. 289, 292. 80 a. W, J. “0 Chill. 300" m 3138 (1952). 9. x. a. 8m, “WM a! 0W W,“ wan, (1956), PP- 15'21‘0 10. ‘0 M and I. m, M. "0 Ohm... L31. ”a. a, 90 (mm. n. J. ncmwno 30W we”. Chm. We 36. 387mm. ' ’ '“' u. 1.. n. J. run-m, m. m. chum, an. m, 2, no (1933). 13. r. n. nun-no» and z. m, 4'. An. can. In... Q. ms (191:6). 1h. 0. I... can: t. J. m. an. m... a, mac (19w). :5. o. n. and. m. .3. M. m. u... n, 692 (m6). :5. n. m. a. n. a... so... a. mm mm. 11. x. x. mm and w. A. um, J. can. 8°C., 3060 (3.925). 18. a. Ioor and I. a. 8m, M. Ma. Am, 5,. 550 (1951). 19. a. r. m and x. l. m, m1. can... g. 1.191: mm. 20. a. P. W um! 30 ll. IMO; m. Chat. my 751 (191.3). a. a. w. m,‘m1. cm... g9, 92:. (19.9). 22. E. I. 513801 and n. I. ”can. J. Am. man. 300., Q, 1557 (192.7). 23. I. 8. Lace, ism, It. row”, Comm. and Buintivu,‘ , edited by n. 3. mm: a. 1. Bow, led (1952). pp. Jae-11.6. 21.. R. L. mu. me! 3. mm, '14me Email. for Plastics," 25' ,o J: Flo-17, W at POW 011M} 69mm PM. (1953). pp. m, 132 and 11.1, 199-203. 25. a. x. nun-u, am 9: mm Rmttm.‘ haw-nu, (1951.). p. 21.5 fl.x.a.m:.mmm.,mm(m). . 28. J. W, punk mum. 29. s. 3. mt“; L. mu... J. h. Chan. 30... n, 1633 (1951). 29.. v. r. 1.th m: A. Mck, mu. on... gg, 1690. (1956). 292:. 1.. 5. Jam and A. Molt. m. cm... 2;. 889. (1955). 30. A. Enlarger, Why-1m Remod- of Organic Chemistry} Vol. I, 2nd Ed... Inna-um (191.9). 99. hes-51.9. n. n. x. m and n. a. and. J. m. Chem. a. 59 (191.3). 32. w. R. Krishna as P. s. nor-y. a. An. Chan. Soc... 15. 1775 (1953). 33. r. J. F1917, J. u. Chem. 500.. fig. 372 (191.3). 32.. a. J. rump... J. m 3a., 2. 371 (1951). 35. a. 2. mm ma L. r. 3111:, J. Phys. Chm... 52. 1371. (192.1). 36. H. M, "Chantal Architecture,” «Mod by M and mu, moraine. (191‘s). Pp. 121-173. ”dd-“W "1.: teen 13’ f c. "udMO PM. (1956 . ppPBO, 31 andlngB. W W. 38. I. 8. 8%“ m ’0 DO”. J. ”a Ch“: 803.. ég} 159 (19%). . . . , . o o a u o . . . o \ - . n - u n , o . a o o . n . u . . . . n . - u . . . . . . - . . o . 39! BO ‘0 81.10.. H. rm m R. Bpaiaer, J. Opt. 5000 £30, El. 753 (1950). 1.0. n. A. Brice and a. ram, J. em. Soc. Am. 2;, 1033 (1951). ' 1.1. firm, mommmuwmume Comm-fl Eluviar Pm, (1950), page 356. ha. Intmuml cum M100, V01. 7. pp. 12 und 350 143. I". {My tad a. F. Steiner, J. Chm. Phys... 21. 1211 (1950). 2.3.. £6811», ”Physic“. (it-{$1116. Chametr-y,’ mama-31111. (1955) pp. 1.12. :32 . as. P. 5. W1. and x. Beau. J. Am. Chem. Soc... 552. 2299 (192.7). 1.5. P. D. Barth“ find 8. Altodml, J. An. Chm. 300... Q], 312 (191.5). £370 JG 60 W; J. Ch“. 500.. w 3707. be. c. 00 “W, H. To C'mmw 3M 80 811113, J. Jul. Ch”. Soc... 1;, 2661 (191.9). 1.9. r. a. mo and r. 14. Luis, J. An. ch... Soc" g. 1592. (19341.). 50. r. x. mm sad 0. wining, Chen. Rm... 3.5,. 191 (1950). 510 In To Vin, J. m. cm. 3%.. fig 2550 (19M). 52. ,0 )1. 10m, P. R. M mu. 1" mu, Jo LII. Chm. 3°C.. & 17131 (19155)- 53. x. Rea-kt, J. Polymer 5.31., L 1.55 (191.6). 53.. c. 0. Print. J. Polymer 5:11., 1, 83 (1936). 55. 1'. All": and C. C. Price, J. Polym Sci... _2_, 151 (191.7). 56. c. a. Price, J. Polymer 3a.. 2, 712 (191.8). 57. n. n. cam-cm n. 1.. man, J. Am. cm. 303., 12, 3953 (1953). 58. C. H. MOM M ‘i P. $1735.11”, Pmc. RW. 3060’ (140113011), 3223 220 (1955). "'“'" 59. R. a. w. Hex-rim and a. a. 3mm», Ram, 2.3, 335 (192.2). 1.13 {£0 P. w. Am 6114M. ‘- P1533, J. chW 861., as; 386 (1737). 61. J. In Garden and 3. 0. m3, Jo. Palmer 3010' 2-6" 255 (1937). 62. 2v. Béfcmwt, a. math and a. Heyefiwff, J. Palmer sci... 21.591 19S . 63. n. s. (3er m r. a. Eamo, Tums. Faraday 30.3., g, 328 (192.7). 2 _.: f. 1 :nfiwfi‘f‘v TYPT? RP? Date Due Demc0-293 "'TITIi‘fiQII7ILIEQ‘ilIJfiIfiifllflfflTLTll'I/lflflifflfiflifi'ES