4=AMENOPYRtDiNE AS A STANDARD EN
ACIDIMETRY

‘hasig §or i'ha Degree 9! M. 5.
MICH§GA§~§ NATE COLLEGE

Ciayton E. Van Ha?!
$954

'71 -------

 

I ""RARY

Mn . gan State
University

 

 

 

haw-BMW AS A STAEDARD 13 NEW!

Glam 8. In [on

u ABSTRACT

M‘M to u:- School. of arm Sud... o: mum-a
suu 0011ch 03 ANN" a! Appnod 80m
h partial “Inn-Int of tho "mu
“: than an!” of

warm (I $012363
Depart-Int at Chantry

tou- 1953

‘W, W

Clayton E. Van 3:11

THE; SIS ABLTEEfiT

1'90 known proportion 01' h-uimpmdim Mk. 1% aux-ecu" :- a
Cunard in «14mm. Th1- thuil include: In mniuguuon of
Izmthotio mm for m p-optntun of h-wtnomfidim and an evaluation
of no papal-t1” u s ltandard for minnow.

Tho Locum ind Scbidt reaction. am not applicable for the synthesis
of L-ninopmzum. tho change a: h-mfid;-lp3fltiin1m dichloride with
solution. containing potmlull hydroxide, «dim: hydroxidl , ”calm
Wat, or Iodin- carbonate result! in my poor yields. Mops-1'1-
dino can be ”patted {m mixtures by Item diotmntion tron an alkaline
column. A very gun product in obtained.

“Mafia!!! ”tuned many or the "Wu 0: a standard for
an in midi-eta. flu mtg-mutual: of homimpyridm 11th a wrong
acid in Itoiohimotrio and mthyl Nd indicator ohmgeu 001m- nt thy
equivalence point. The indicator blank is null and easily determined.
Kamila agree to within om part per thousand with vaults obtain“! min;
tn 0th» standards, potusim mid phthalato tad IOEUJI cabana".
hdninopyfldino u not hwy-00mm, and can-hon dioxido bu an affect on
the titration. Wm ha- : definite vapor pressure which cause-
lubltuztial loss“ on prolonged heating. This pmperty also enables
pin-Hiatus: by NblMtiOn. Manama-1M!» my be recent-ed 08:11:;
am omictlly.

Th0 one uJor disadvantage of h-aminopyridinc in tho {an that it
u not moiety unillhle.

Wssnsrmmnwmmx

61w. 3. Yum

A 73313

X1813 C $13803

MM .3 aha-um

1951s

flu-I'M“.

PAGE

1. mm“.OCOOOIOIOOO..00....00000000000009...0.00.00...

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n. mWOOOOOOCOCOOOOOOOOOOOOOOOOQOOOOOOIDIOOOOI0......

3.. 2‘. ma1“ O: hWOOOCOOOOOOOOOOOOOOO
10 mm m or mmmOOOOIOOOOOOOOOOC

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n.W of 1mm.
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13. Proud:- by than, um 50‘ Mal-1.
WWCOOOCC0.00....OOOOOOIOOOOOOOOOOO.
a. Papa-cum by new“! fl‘h 3“ sum
WMOOOOOOOODOIOIOODOOCIOOOOOOOOOO...
d. 1'39"qu w clump Ink 191
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o. I'll-pantie- kw clamp an m an.
arm

0.0....0COO...OCOOOOUOOOIOOOOOOOO

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3 R fi‘R‘FES’ES‘t‘Ki‘B?’ # (33 $3

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3. Wanna-yaw

sumammumuwmnmma
mm,umuthum,uhumaum
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mutant-ulna»... manor-COMM!”
mWflcbdfltWWWMu,uWn-o
augmmum-uumumfimmum
”wam-wm-ummmucmtymtw
Whmum.

Anmnmvotmnwmdommu
mmmumrmu—amwww
mmmuamncwummmunma
cm. tummuanummaam
“mummuumn magnum-ma
memummtymummmw,
dwutwmmmuquaMmmol-m
mafiatwthnmtuudamuulMd‘Wl-b-
nun-aim“).

rothcunm-mnwmm-
”numb-onto.

thmuhouqhom.
hon-yt-

Luau-u "mum.

LBWMW spun-uh.
h. Itmmgumm-m.

F

5.!tmnmmuw.

6. :uhmabcomorungmamwtm
by «mush. tut. at m “nativity.

Lit-baldnotbouhwmpuuutmqm

a. mfia‘n‘mwuumMnmfly
W.

meanWMhuMM
Mink-WMMQIM. Mfldomhnwuh
uw-m,mmm,mwmu,mm
uw.mw,mm.mm,
m, m1m,uwutmnm. II III-
amumm,mmmmmmm
Mud-nu. Infidwmmm-u,mu
mgummmwmpuwwvmmra
mmmnummuum.

Imumwmmu,m,mmuun
widower-mm. Ignatius-income.“
www.mumumhufimuw. Yarn-p10,
quuwuuamu-amum; m
mmummmuimmumumum
jut-I. muawmucmwuman-u
Mp. mwmummmuw
(WWumnwuumuuQ-uuu
mum. nwu.m¢mmmum~ummum
amummm. .

Mmmmumummmbmm
matcmaommxmxwmmnrm,m

awamummamwmmum.
Ammmmflchdsfitmch-m
humucmwuumbmnwm.
“mmmutmmuamm
mmwmummuvumw. lat-tunn-
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mm. Yb‘mmmhmmauhnmum
mnMamam-amumwhw
mama-m, madman-cm.“-
”mammummmumu
“mqmuuumwmv.

I. haw-um

ummmwmgmmmaa
Mun-W. Wan-numbn-
unawmgmuflsn. Inuit-Immunisation“:-
thuanu-uwm.m.u1m.w
amuuuxm“«25°C.»..uduuukuo). I:
1952,A1bmw.vdutumpl.d94iuhwu
amu'd1.6310‘tw§(2). nmm.'mwmm
:qdéanm‘uwtwfivmuaua
1.1810"

Wumuwumummuub
mum-Mom... mummmmm

«wax-mgmmmmmmuuumn
to‘c,u1:nnancb1mm1.mufiunmncfl'cJfl.
Wmamuupmaxsy‘c.muuuma
m-uummw, hw.Wu-m
ammmca'e..~Wu-uuuma
a’c.
:mummm-mmuamum
MuumttmuMunmdot-mm
Manama-M. maxim-«amm‘m
m¢mmquummmmumu
nwmmmmtmnmmwum
thmtummdwcounm.
tmummmmmmew-o,”
the-unalumutuvgaum.

‘. n 53" [“3
'3- “ ll ' -
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I II m 1'

madam-.nmmumammmum
mw,amuam~tuka6mmm
Wu.m“(w. TUMMM
wmmwmum-mmormn.
mm]; smckwMMb-munmmnh

.th,mua). uwmmnnnzuapoh
m,hum6mmhdmtmtmmdtmtm‘uw
with“. makomtmnth-uhommu
Wmmummbmmwum
mwmmwhu-Wm,n,mu'
mutant-amt”. MWWMWMW
mWMMm,I.mbom1mduh-W.

0. Warm

mmamuxuuwmmu
Wmumuiumwnnmm
madam. MuMde'k-umpmdmm
mommauhm-mommmuum
mum’s-no. I

11. mm

A. rummuW

1-W- - (

~ mrqummuh-Wuwo-un
”chums-uwwmmmmwmm
Mm. h‘thflourwnnddummm
MWdemo-omtm.mwm”
mmmuwmamW.-hm,
CWuZdaWh-umdnunammh
mmumfiwmam. mums-um
mm:mpamu~an1m. human-unann-
WdIWMH-OWM. sumac-un-
WhammwbthhQ—dun
“maqunnh-muuumaarcdn.
..hm,m;nm,ummhumuaum
awn-u. hhmwmunmw‘
nmuuwm-uu-mauno‘cuhhm
«pm-unnumuqu-huu
WthuMuthB’. flout-1631:“

‘mum—meumamxm).

mmWM-mwwmnmw
WWWhhMfifiW-utnw
nu-Wtammnlso'c. mawmw
hymn-um. mumwnutmunmwnmw-

mmdmmmmouuodmtmngmuw
Muduhymndonmdwmudunnmam. In.
amtummmmudmumnnm,mmm
mmmmmmmmmmmmmmwm
woman-1mm. annulmnbn‘thJSSOav-hpodn
any method for cloning tho handgun-1min- mum-u- (2). mad:
mmwwnmmmmumnm,mn
mudnuaoxywubmwmmu. htbmmlm
mamamwuwm-mwawwm
WW dama- Ilth mm nut- We tar
M‘W"). mumxmwmwmummm
Hahn-31M... immmrwfihomstund
Wmmawumowmummmww
«mean-am). meaumuum-h
MduMMMmflmnaMyuldah-uimfldm. flu
Wmnwmmmmmwnmuonum
mWMpyfldmlndpu-phthnumd. 1'1»me
«$110thde «upon-04131958. Vin-t, W3,
ummmmmmmdmu
mmummuwmmummwwwm
arm-(21).

kW.
Sum-elm tar tum-operation of “1305:311me mun-
gttodhmismk. Thom-0M Midmnmpnufiad

ulna-unmanmomuannnormmusm,
um,uum,~mmmummum
amounts-away). mmodmrommwthnumwm
um-tmwuwwmqua-nmmd '
Wu“. rummwmmmua
wwwntha-mumma.‘
mom'hmwmfim mam “mag“.co.
maum1
mlm.Mth1mw-®Mm

 

wmuuauMouu-awwmm.“
dem. amm‘muummmhu
mquWmc'muo-mw
17W. mummmwnmmmm
mmwumuu.rmmmumuumuu
human-tame. ” ‘

W3
W nu, sumac-amt. such-mace".
mm:- W, um mu m.
PW nu, ma m- vmpn emu: m, 33: 9.0..
8061- wanna, Ila-ck Eugen hum.
has... amt Rum bull. ’
sum an, Wont 01. august. ’51.

Apparatus
Sublet m

Prooodm'os

an pm (0.01.1 m1.) «Wt-emu); m’ (0.016
noio)ofoylmlvdroonomaddodtoISr-otpolyc
phntphorioucidintnoyonSOOnl. union-beak". Thom:
otimdnnullaandhoatodoloflqinlnoubathuptomo’c
W100” c., tho ovulation or hydrogen ohlwidovoo mm.
,umnmnmmummmmuemmam
nottakopluoamrhattng. human-«onto
mummmmmmmmmwwg
“mama-wanna. Tmnluttonuomm
“Wanna-both. mummuumpdmodu
deth‘bmhoufl-tom“. William“
www.mmmmmmdummua—mwm.
On'ooonng,om1tooo1:ldproo1p1tatOd.Thuntu-1dhuondun¢
mnm'c.mmmnuuw,mwngum
caution. Fwnmamwlidtho tmdyioldm,nomod.

Wmmubonmtonmdmmmwm
nmummw. ”“0.th
Md. - ‘

  

wmmmrummmammu
mmauwMum. Antoni-romant-
wmwmummwmmmu
Wu,uunmmtmnummhamn

WI.
I _
among”, .1?" m..oo,.n.
Iona-Ito!

www.myr-uwm.
sou- m,ww.

mm “.mhotci. W. 95%.
cmMm,lcnkWM.
Sou-mama: momma.

AMI

nutmmxmmumumduam
wm,:mm,uww,uem
oath.

mam:
Amu2.95au(omm)¢mw,nn.
ormnmw,uaon.umunuumu
so°o.-rommm~mu.azr-(o.ouuh)dud:-
utbhnflmflmdfiwm. lemma-1mm

amm‘mmmn. mummnmmma,
mmumuso'c.mmhom. Yuma-11m
umummmmmnnm. Thu-aim
Mnemmmwmmmumowu
www.mu. mqummmwn-pco-
u~:m—m,mm~~wuamumu
W. mumnmuwmmmwm
deuan-ummw. 0:de
Wumuamm,um~w. nun.
WWMHOMWMWWMM
seal-dam“. Mmumwummumm
Walnut-01. ‘

  

umwufimwemtuedumq
thmwmtuammmmm
mammal-mum. album,“
meummummudyu
muwmummumemuum
71M. mmmummu,mw1pnmu-
nun-1a.,uammmmpuwum
meummms

. '\
. \ l/

3 0 won. """"" I+Cl'
I \

I‘m"

/.., '

. t ”91-9.

0‘ ' 1/ \
. . I/
I‘m" 3"

ruwmm-mwuqmmmm
comma-mg. quh-me/WW 
Wuthv-mmm. CW
mmhnmuan—dw
”.mmnmmmnanm. W
mwmmmmmnmmmu
mm. _
mmmmmmmmmumuw
Without-am. m,thuyuoodmmnotbooor
mo,nuunmug-uu. Mm.uuotmum~
mmmmgwmumdw. Ions-n
mtimmmmWMQWuW,oow
umomw(m.mmm(m.
mmmmto(m}.
mmmmwwamw
mutton-om. mmmmmm
"Md”mmdhmm. loin-9,00).th
uthohlmtmudmouhodum.

   

but. " g _ . _ fl ,, _ ‘..'f..'.-.;.t.'.x o
the Why,” maid: md in tun Mann-n In
mmwmumummmtm.

I-‘ ‘1 §"' ..‘).‘,.. I

 

”unfit V _
' m.nmo..m¢,m.~mw.'

tantalumwmn.

imam.m.

'mt. '

mot-Wadd(mo.1l)

g -.

me(1.16m)dm-idmu300m
(aflm)¢’m1Mm-imm¢nynusoou.
tut-rank. maukmmammmmumw
m‘m'weom. mammal-1*»,mm '
twnawmfi,umpi~uucmwmu'
Mum-mmmmawmw.
m~wn.¢mmm~mummuuw
Wynn-51mm. maniac-Humumuu
o'mu-u-mummmnemw. rum

Mummuummcwmmum.
dichloride

rm W at WSW/nu nut ‘17 u- M
dam «:00 m- (m. :05 urn-(12$). m: w (m). a
n2 ann- (um negatively. 1.9. 171-111! c.

1h

Joana-dawnin- ruuomondod thutthoWh-wfldflpyb
mmummmmmxh-um.

lm,ttonbumfliudbyrua1utulmmmmmdro-
ohm-loam. meWR-pmdgmmw
maudhtthh—ainapyridim.
Pram: ‘ )

WNde-pmwmmmdl-
aladhm.n1.utbunincdnaulvdnuh1aiuatd. rap-Io:
MhAmWflWMWMOMM. Thom
mmmwummmwmuammm
ism-emu. mmuw-mmmunnomuu
«mwumnemnum. mum
tbaapautoduauunuutudaumtaadthuuaiudflrlhbm-uh
um'mmmm. Mun-mann-
mama-mum. twdbutohuthOp-audw
“mummmumnmumumu

. .

H. 11;.141,

fluWflWflu-flmwm
maul-ammonia» www.matia
ammuwum,mmmmmu

autbuo. mawgmm-mW
WM

 

Ci

Rouguntn 4 , -
h-Pyricmwridinia Wan, manned and pun-mod.
Potuuu um, aural: Rum ma. run-u.
» 3mm. item name crude.
lain L,
8od1u M, an: Ito-put w.
W add, new Wot! new. 365.
cm. m1: Rodd-It W.

tum-tun

' Wow.
WWW.
Asmmnakuqnippuddtbouadmadumm.

mum .

W" ..s... (on-u) er W WW
WuWNMd.aofiofimwm
hesmmmwuuumumm. Solo
memmmummuaummtuum. mum-u
mnnmmlflhoauadmtfluuauhadblakaam
rm. mmmmmmmummmumdu
170°c.numuu. WWfl.¢baudinmoum
odhutudadovuporutudtomnuutuabutb. rhodium
quutmmum-W. 21'me
Mamaumnmumma.pmuunmm.

16

Tmmnummmbinod,mgruotmtudod,ndm
Maud for a 1'01: mm. Thu ”Inf-ion via micron! ma! mpan’ad to
andlmlmmlluahnh. Onconligg,mihmmm
orb-Wp‘odpnmd. mm~.m6.m
mar-arm. Inwarumumuom. 1;.159'0.‘
rummnfiusoxmummmu
tin-drum. Wennw(0.nloh)-dw
WwW—wunsu.aagm
wmamummmmmw. new
ammuummm-mmunma‘
WmMaqu-maw‘m
Wmmmunmm. magma-mm
mandamus-mm. Amchm-OMH-g
W.
mmmwvuwmngahm(omuh)am
mummzmu.ussosmdnwm. roman
nmummonnmamngumumum
”1141’.
wtmmmwmmmmmmu
msmmmmmmummw. W
finw(odsflo)dWWrfi1fl-Wm
mumn.¢asmmummmmmmmmm
”nu-ammhm. rummmmuwamuuum,
mm with mmmwomu m,mmd, nun-perm

17

tom-outnumbuh.-flndryummomu§hflm
zoo .1. portion! of boiling china-cram. 1-1;:th extraction-
mcmbimdmmamwawnmmluonbm. nu 3.01m
mtbendiudmdhboningqum,m‘uaotionutnddod,m
tho solution boiled far I tax-11mm. Th- oohtian was filmed and '
'«upcudhtnmwlmoonm-bath. «mummmwum,
1.1 pun-(1.6%)“.memmm. .muwmm
tho ahlmtm mm m cm, puma, my: Mum
bummamamwtnmm. Thing-mm
Mtbubuw,h1hdammdthwpuqt§ortuh
mun-«.muwmauuummunm-m. comma
mmwm,o.hm (2.8%)otb-dmwudmmobtdndrmm
mmmymdk15mu03), mum‘s-gunman»
-mm,m,nammum. WWW
“mummwum-Muum. M‘mmm
Wmumaam-bm,mmwmmmp
mamammuwbumn-wwmtu 1am.
mmmmmmmmmumuwm. An
mum-10.1 y-m (5%)dh-m1mpyflflmmommmm
manna-Ham. . '
”121.4.qu dam-ud- m and an the am:
pwcodm. Thirty-Mam (0,11; I010) arm-Mind “it In add“
“130d,of1501patudnwmdo oolutionmdthumm
talcum. mm—mwmnmwmm

amt-mgrswxunmumnmun
mumwumugmm. rummu'
“WmdwuuWWuMMp-n
«magnum-m. rummmmw,
mwumumu,mmaunumm.u
mum. rumew-«mm
madmamwmmm.ny1mua.émmnm

 

Tmmmmwmummmsos
pen-811- hydro“.
Rum.

hMW am, Wm

Sodim was, Hank new and. PM.

Demons, um aoagent Grads.

[who A.

imam-m:
A 50011.naakoqu1ppoduth acumen»: mauam-uun.
Stem distillatinn «mm-stun.

Mn:

Immmgnowummuwww
amino-1‘. «m‘mw,ummw

19

mum..tmu~khuupwh§¢bm. rh-
Maummmumuum
’bau. mnmwmmnmmmmm
«Wanna-m. mmmme-lmu
mum-hmotmmgmm. non-Wm..-
bind, mndxmutma,ummm;tum.
m»mm~smrnwwoku;wm-mg
mum. metp-dpmnmum
memwmumod. iMdd)Jflfi(W)m
W.

It'd.

 

tbmwmm—mwammmu
mmmumamw. mmumu
Wumm,mmmumdlnm~
”main-mama.

Reagan: .

. WW. whim-1:30, W.
Ann-1. W, DI m, a). W." m.
Chm-«on, m mag-n m.

Bum, Ina-ck Busch but.

may. w, m may» cut.

lun- A.

Ana-nun ..
Asmn.nukcmduthummammu.
Stud-WWI”.

Pmchmt

TmdeWQWu-W(O.Muh)
"maumn.u2”muuwmmmmm
mmmm. mummmmson.d
Wammmmw,uummmmm
011W. rummmn m1.d,tuw,mmn1mu
mratodtoaputoonsstoubtth. MMWMMd
com-1 men an: so n1.paruonno:bo11mgmm.fmmm-
tmtmmmmmmdmmmdbmnonnnun
bath. fictnidmmlofl.

n. clung: with menial rum-om. m rep-mung tho ”In
rmummmmmumummmwmmuu
torn-d. '

mm: .
rWWuWWWW (0.25m)
swuwu.ammwm,umm
WIUCLOWI. fatty gr-Iflmmmu‘m
www.mmmma-Wuum
m,mnmozw=mm mutant-n-
mmhmuulmum,mhhulflmm

wmdmn m.uuma.mmabonmm. 'nn
mammmbm,maumanumut,
mm,udomaudhuud1mu. onmnngmmm,
3.6 gm (18s) a Inn-imam... mm.

  

wmmmomummmum
Wu. AmMMummwmw'b-dwmuu
Mawwwafiuum.

Roms
MW mm, W.
sedan- 0M Wm, Wt tau-Jamal Rum.
cm. m Rug-m and:
am when“, that mm but.
m, but Rum m.
Mt. A.

imam.
rtnman.mmn.mmwuumu
mung-m.

PM:
mm(omm)¢Wmen-nu

"mum-1.x.wmmmmum

wuunm. Lhcdbhckldflmuummm.

mmmmnum,mum,mm
mm. mmumummwuiumn.m'
«Wu-humm. mmm'm
WMWumc-uamm. lot-Ind
Wasps-m. mammmmmw
”Whmuummmmm.m«ow
bmmmuthfifl.mflmohhdm. Thou
mmmwmwumnamum.
lawman-ulna. .
thdanMI-WMMaM
mummmumqw

rm: ‘

Mm(o.zzm)¢WL-pwwww
”mummugmmmmumm
”Whom”. Abram-actuationwm.
rwmumwummummm
W‘wmammumumm.mumddu
WWW. mammauumwuwna
mm,ummmm-amu¢mm
Mmummm. mun-Wino“,
mm.u«mut,mmd,umuaum
sumo. mmummgawuwdw
III-W.

23

 

thwamWthmnm-dlm
mwm‘mtmw. Math-W
wmwdeWWA-mmhm
mmuwmwuutwmmwnrmx.

mm:
‘ ma: or W amuse a “mm-mm: bums

 

 

-t$¢.' 905m" 13- MWIJ‘.
A «mu. m“

35 p 595303 ls “cum 8 .
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32 . , 501 K03 10 Sta-W 3.6 .*
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32 a. sofimu ' 10 mm» 1.1;.
sandman! 15$
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50:. ”has 1: MW 3.12.
«10006.1.6fi
10¢. 291mm 10 muons: hymn
‘ - CW
Solar 295 m . m a. 06 I
¥ “1‘ “W. 13, .
m .‘. 22: Inca; 1 WA“ by It mu
- ' . cumin ‘
50:. ‘26 [3.60. 8 Bitumen 1.3 3.
«100°C. 631

 

 

‘muud

2h

rummmmmwmuwwmm
mmmuuumuammwumum
Why-Malacca“. Em,lumrauu1uduwbo
mmumuwmflnmm. sum.
mmnmwmmmmum,
mm-uuamumw. ace-m
“mu-om,m,‘rbm«WWMu
«swammmmaéfitmmwmmnnmm
“mummmuummmumm.
mmummmmqmm‘n-um;u'
mm,nmmm,mmfluuum
mmmnmb-Wmmmm.

 

mum‘mmumuwmmmam
m‘whmnmudmpmwdmmn-
an. uanqu-u

Manama-workman. mm
Wawmm,anaumdcmdw
mnumMoW,mmwMum-oun
om,uummdummmmuwuum.

25

gunmaorogumm‘ocmm ”16301“me
Mnamgmmwmdtwnamcwpwd
‘dthaliphmdnumym. Tbaa'boymlmdummtnm
went-mung“. .

mummumdmoabymomm: numuuua—
wmmmummmmuwmm
phthalato,-.lndt1h'a%ian¢£lnd1mcmm. amuse:
petunia: mamtholatemusod,mnfiunmdmm8¢uph,
mmoflmauwlonunmmidnmm. mum-
onfiomtoundvumonmidmm. AWW»
25°c.mmdmmm. mmemm
mmmmmmas'c.ufl'c..m¢m«mum
var-Maryland. ttuoWhWMtha-m
MMtlpph,maudmfifin-Wuflmby
mmmmmm-ummhmmwmm
(15>. mmmmmmwm.

mumuuoglwmmmmw
mammmumummmnuumu
«momma. mmmmmmmw
wmuummuummm run-ham
mmwmmmnmamuwmu
Mun-What“... m.mmm~omwu
amwmmmnmmm.

mmamu,mn,m,ummm
:wnmwmummwmngm
Mummpbthdauom.

26

Reagent-o
Potuaim mm mm, Bureau 0: mum-an. ample Io. 8h,
: Mm 99.971;
Mum Add mam, Baku: mama now, in lo. 3381,
Amy 100.031.. ‘
Phomlphtmdn Indie-tor, 0.1%.

.5ch 0.! gr- unplndpnuduacmxahmm that.
wmmmmmmman.mm
ummason.ammmmuptmumm
Imam. Immamuuyummnmmm
WdOqu-memmm
uwmuumw. mmumw-mw
mummmm¢awrwmuuapa¢
mum‘uM-umdmm. “mu-um».
manyumunguapmmmmummdm-a
mgummmmnmuumme-u
mums-nu. mumemmma-mcp
m. tummflmut0.01fl.mdbu-umm
mummotmmnmutrm. thin-dun!
WWMmWh‘rmn.

27

1.3L. 11
mmmzzmma mm WW3 ma MAW mm mm;

' ""V V ‘ w

 

 

 

0.1.: - _ _m.nam .\ -3" fl
0.8.157“ ‘ ' - -‘ - 3h.” ' * ' 0.1m
0.7m“ - ' ‘ 30.73 0.1m
0.812;" 3M9 0.21.1.
0.8133” . 32.33 0.1m
0.9319“ 39.86 ' 0.1m
0.9293” 39.19 0.1m
0.9323” * 19.90 am
0.9315!h 39.90 - 0.1.11.3
0.9309” ‘ 3mm. 0.1m
0.9291” - . 39.80 0.1m

Ami..- 0.11M
‘Bam'l Wane-Ii.

”Mandamus-9h.

ruuummmuwmwammaw
mammaormamzsamam-fi-mmmuu
mmmummm-mnwmummu
Manama-um. how's-W
“Mahmuhmmwdmmw
«mum. “mummmammmumm
um. hummmumwmmm

28

whwmumaummumuMc-n. The
mutummnwcmwmmwumuumm
«tannin. '

b.3173 III
57717713932571” 0 WWII: ACE ms 0.11m: I scam mROIIDE

 

 

 

171. an In. an I. m
179.07 35.77 0.1021
1.0.07 35.77 0.1021
1.0.51 35.78 0.1021
1.0.07 35.71 0.1021
1.0.07 35.71 0.1021
170.07 35.77 0.1021
10.07 ' 35.79 0.1022
1.0.07 35.77 0.1021
170.07. 35.77 0.1021
mm 15.79 0.1m:
Ammo 0.1021

 

Fri-a7 attach-d and: Indiu- «man was tho second “batsmen
lithwioh th- addm “man-dined, andthapmomnottolthotf
and Swan in (allowed (1h).

29

Reagents:
30cm. cm“ W, Wt Fri-Dry ma, ignited
{cf 2 m. at 285° c., any 9935400359;
WM W, 0.19.
W anon Indium, 0.0“.

W»

Baal-sumac”, OJuOJSn,mumm1y
“dammnhnadmmduumawmuw.
mmfifimphm-ammnmmmmuma
umw'mnmuu. “mamas-wan-
mwumummw'ummmmmu
chug-tom. IbMvuthfibofl-dnfwm, cooled”
”mm.umumummuww1mmhw
“flaw... Amumammwtmummg
«wofimawuzmen-mawumu
man-mmummimpmmumngdu
whtotbamoohr.th1mkm¢0.03d.ndhzmt
mtimmnpplhdhthomfluidmdhunutnum.
The mumurahun.

30

 

 

 

 

 

T553173 IV
mmmmmu or £713me 1.8113 mm 3m cmzrmzs
W "* ~ - A A» + _ j 2'!

a. 3.370. ‘ m. an ' ‘ ' I. am.
0.2396 ' was , 0.1m
c.2197. 7.0.51. . om
0.2293 1.1.25 ’ 0.1921
0.2260 1.1.76 0,1021
0.2182 ' 1.0.31 0.1021
0.2388 £77.11 > 0.1021
0.2669 ' 3.9.35 0.1070
0.2212 1.0.88 0.1021
0-2116 ' 39.11. cm
0.3330 38.51 0.1022

' 6mm 0.1021

 

 

rmmmmdmmwmuumwmm
thonrtm props-Mn groom. Ton "situates-131 uln-
Macho-h“. £n1t1n¢pdflot1fl°mmtmnd
ma'mmmpmuuxumam'mnmmw
link. .mmmmtmwmunw
byfiim-bchhbm'aw.

 

CW 7' mm...

cm ' 63.80 63.89 63.66 . 63.78

Barth-oat 6.10 6.39 6.18 6.3)

lime-h 29.77 29.96 29 .73 19.85
m

cm 100.00 100.217 ”.68 99.96

 

mummmummumuwdm
Iayutmmwufixwaa,mrm.umw (1).
.Mwmummmmww
w. m,quu-Mhaw
tan,thlnthhuumldhnpmto dun-“103nm.
MWmmuhmumm-hrmn.
mmm~mm,mwhuummm

 

 

Q tharrosnltl.
nan 71
mm a: mm. mm
W. *7. 9‘: v : 6 W Am].
mm 71-- PM ump- you"

t . ”.16

h « 19.10

I: 29.25

8 28.58

32

Mummmauummmmmmuu
W. tbs-Wh-Wmduw
wmmu‘MM.umW~W*
mmmmwmummm
Wmth‘m

m:
' Acmnmdmumhmfl.¢
zlnwmmsa.ao.1lmuumm 7mm
mmunmammauuwmm'
unu.¢mmpouuumumuun.cogl
sawdust» AMmMmMWdMfidll
“wwhwhwumnna.do.llmwum.
nwmwmuwmuucmm
WW. wmmwnth
mm-mumm. tumuwdwm
00.01315“.

 

mmmmummmm
“anwm. mama-4-
mummdumuuumnmm.
wmum-cmmums-tuna:-amm-«Hangman-um
Madnmhthplmnmcquhdmm. tob-
mmwdummm,mmmnmm

33

wumnmuumdumumu.
15111.31!!!“ .mmmmmmm

. H ‘

[1- /E ‘
m.»uWaw-mr@¢nmmm.m.

umuowmmmmmmu
2.61.711.

7.37.371:
thpnammm

 

s ' r (m 9!-

 

1.1 a 10" - Lo x 10" ‘ 5.8
17.0 x 10'. 5.6 I 10". “5.3
6.2316“ .' mono" 5.1

 

thwwmammmmmnmparmu
wammuuuu. IOWWWWIIMM
mmmmm.mmdwmmum

unmmumummmofiw. no
muouwmmummmuhmu

mwmumwmuummhyl.

AMI
munplnow,mm.mlwoddthofiuow
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mmuoxnmmwmww. whoa-«mum;-
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wum-amummmmmumpn.
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rumzmmuwmwmbnumn.¢
odd-Wu.flnnl. maumMu-mmwnm
AM... ummmumwmumm
www.mmwumwmuma
h-Wdhmw.

wmmmmmw-om
mommwmmmmumunm.
mmmmm-hmuwwwoum
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35

 

 

 

 

 

 

 

 

I2 I fl 7' I I
l I ._.4
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2 L.
l I I l L I I I
D 4 8 l2 l6 20 24 28 32

ML. OF ACID

FIGURE I. TITRATION OF 4-AMINOPYRIDINE WITH
HYDROCHLORIC ACID.

36

'3 I" I [WIQ 3%; A

umummumumu-unmnnw,
(3mm 51mg). mural. 4:31. :1» («'1th
mmnuwmhmum. mamas-naval
mum-sum”.

mm an.
m Imam 0mm or WE

 

 

 

 

my :1. a m: pl a I
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0.1 mm 9.1 3.9 x.) x In“

0.5 13.3: 9.1 u ,1.) a no"

 

 

mmmmnewmumm
wwmvdmflldxlfl‘uwwmuoh

kW-
mewuh—wmmmawmmwmmw
muwuanmummmmumdum
mmnmdmwmmuwuvuw.
mmurmnmm-nn,mmmmnnw
mummuwmam.

ALOOhOm’Il-flifimfihwldflfim
hapreflwilywmmwumwmflfldhl
moduummmhgm'uupuuum. rh-
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am I:
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‘ "I. 91.L.:~.Jz C '

'1 .4).an ammo: 0.0000 0.00 ,
2 43.0003. «0.0001 0.0000 0.00
g A 0.0000 ' 0.0000 omoo 0.00
0 . «0.01201 00.0001 - 0.0000 - ' 0.00
5 0.0000 0.0030 0.0000 0,00
6 0.0000 0.0000 _ 0.0300 0.00
7 «13.0001 -0~.0001 0.0000 0.00
8 43.0001 «(9.00011 0.0000 0.00
9 0.0000 0.0000 0.0000 ' 0.00
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53 «0.0007 0.0000 $.00”! «0.01
60 «0.0009 «0.0001 4.0008 -o.oa
95 «0.0011 . o0. -o.orns cogs

 

38

kW than no mmummmtmmu
wtmmmqummmuu.
mmumuomwmmmow—W.

 

Whamhmmuumw

talent-Munmmmmmflnn
taxman-mums. ummummum
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m.MOI
£1.0080u'unwlootmtm1deIflplad
mammaummmmmuuummé
ms’c.tcvm.wmuuu,mmwulom. n.
mammoth-mm. mnmufimmmw
armor. ' -.
mamumnxmmgmmaomméuudm
mmunimmumnms‘c. $201.3er
”(whoa-mm. C

39

1031.3 X . A
.1000 03 mm“: 105? 0.,

 

 

0.0m

1““‘

0.1010

A

To“). hunting tin . $6.5 haw.

 

o -- 1.0000 I . w .

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a 0.9021 0.010. 0.0656 1.71 6.0 0.11
9 0.9250 0.0170 0.0m6 I 1.00 0.19 0.20

10 0.9010 1.99 - 10.“ 0.10

200-110.th “3.10M”
Tot-Imus 010. ream
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c.3723 0.3m 30.90 99.01 0.10::
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0.3958 , 0.3950 01.11 ”.96 am

 

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c.3800 ,   0.3886 ' 00.0 . 99.95 0.10::
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to 0.3051 0.080" 00.13 _ 100.1 0.1020
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cm 0.3806 39.61 100.1 6.1020 I
0.3821. 0.3629 ' 39.85 100.1 0.1020
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W
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0.2m: XVI
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0.3822 0.3825 39.80 100.1 0.1020
0.369: 0.3891 38.81 100.1 0.1028
0.3m 0.3118 38.89 180.1 0.1020
0.3753 0.3758 . 39.11 100.1 0.1020
0.3m 0.3m 38.13 100.1 0.1000
8.3885 0.3851 . 80.01 100.: 0.1020
0.3791 0.38m ' 39.56 100.1 ' 0.1000
0.3828 0,3831 39.01 , 100.1 0.1020
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1:9

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0mm

5200050091011! (F SUBMD Manama;

yuan
Chase.

Chengdu

- Day. Change in Weight
at

 

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fleeting; ~ himifiszdi ' m
(3.0:) ' ’ 110$; Lu: £0.“ -. #3; .
0. 0.8988 W
M. 03.938 0.0010 0mm 0.20 0,20 0.80
1/2 o.h935 . 0.0003 0.0313 0.06 0.26 0.12
3/0 0.1326 0.0009 0.0022 0.15 _ 0.1.1. 0.21.
1 0.1017 0.8009 0.0031 0.18 0.63 0.13
2 0.18391: 0.0023 0.0051: 0.,” 1.09 0.21:
3 0.1.858 0.0036 0.5090 0.714 1.82 0.25
0 0,8808 0.0051; €3.me 1.11 2.01 0.28
5 0.8738 0.0066 0.0210 1.37 8.21. 0.21
8 0.0620 0.0096 0.0306 0.03 6.10 0.38
1 0.1.096 0.01146 0.0152 3.15 9.12 0.15
8 0.8355 ‘ 0.0110 0.0593 3.118 11.98 0.39
9 0.11133 0.0175 0.0768 10.02 15.52 0.185
10 0.39% 0.03.80 0.0951: RM 19.28 0.16
, * ...-......
tom name an . 56.5 mm-

 

 

Total 10a in mam-0.09514 are:

mamas-19.2
Ammewto

8 .

mt

 

3-2ch

:00»me traperoentaotpuritvcaloulatodmm
.mp1» at “1:10;:er titrated, The results are based on 022 said
3020081183! 0: 0.1021. 1 '

 

 

w _
100.1 ”.93 100 .3 100 .1

 

 

meumm-mammummm

Whammngo may or 99.9”. Prolongod hunting at 105' 0.
mmmmpmvumou. macaw»

53

ruuwupmtyotum gum-10100000100978. rho-0013.00 Imam-
pyridino, ”girdle” o: mm,had.pzruyo:100.n with room--
macaw»; an aunt. nu mom-ad 18-00mm bad a purity
«10044003111.» Watmmmmmaum-m
«1301.03.00.

Sam’s! mention. at hams-10m ”do use. tho original
M,dsohadtbmnr1ty,100.n. mmmam
mmmmmmumwmmmuuunm,
«wuuofb-uimidimmthadhuupmudwomufl
WtMMWMWHMWflGMd-m
W hfllnmmmmtbb-tnpynuumupnmd
hymn-Wonk. WuW0nanh-du
mmmmmwchwmm. fur-alum“
Wmubmpmmawummm
mar-bun.

rmn
m m mnxznmmon

1
r0

 

dam Pcrccut.
. ,. y n. In my I. __
W42!
0.38188 0.3852 h0.08 100.1 0.1000
0.3833 0.3836 39.92 100.1 0.1020
Two Walnut
0.3797 0.3801 39.55 100.1 0.1020

0.3855 0.3858 10.15 100.1 0.1020

.--." _ __. ¢ . -

5h

nowhotmmnawmmmatwnmuwm
mamaxmuoummmmmuuw
”mu. 0n mm 01m, 1h. lupin ha! a rum or 0J1 mg.
(0.081). Ann-190mm in" u no 00150-01- um.

nmmmmmmoah-mm,mmm
Wm,mmnurmumawmm,mor
mohmtwlfiydmfi,mflamumd, “spit-theta”
mttbdhounwnymmmofifi. mamas-mush
”1539mm

 

mthwtwhmditydwcmidWU-Sum
rebuimumcmhimdmhblom. momma
«mauumwamom.

ThWnnthbymmafin‘dth “d11-
Wmmmmmmw. tummy
mummuub-Wmmmmum
mvmum-upminymua,mmwum~.
ThuWthmmlaummm-uty
«emuaummpumoow. 01100001130030.0101.
wmmummnwmmunmmmmw
quOtOnIhuhi-mpmurmOOM.

55

TABLE XII
CWLRISOI W S'l‘ifiDLRDS

 

 

1.. V. ‘ fl

 

 

 

11.00, * m 00
MW
0.1001 0.1022 0.1mm 0.10205
0.1001 0.1001 0.1019” 0.1.020b
0.1021 0.1022 0.1020" 0.10201’
0.1001 0.1002 0.1010b 0.1020”
0.1001 0.1002 0.1000° 0.1010b
0.1001 0.1022 0.3.020“ 0.1019“
0.1020 0.1022 0.10200 0.1010b
0.1021 0.1032 0.10008I 0.100010
0.1021 0.1022 0.10100" 0.1000‘
0.1022 0.1020 0.1020“ 0.10206
0.1000‘1 0.1020"
0.10204 0.1.020“
0.1021 0.1022 0.1000 0.1000

 

1 w W W _J:: 11 J

1 Original recrystallized b-mimpyridim.
Recovered 10-03mm.

Lctu- propanum or nominal.

Doubly mama.

In 0033me

IVA-1391:1010. do» not. any at tho 1'0an" 0: o umdard
for m in midi-om. the man-Luca 0: Mammal-I 0111 a
.MugumumtohMMQudm quumdmm
n11: ulna Inky]. rod :0 In indicator. The indicator blank 1: .0011
and out]; 4601111106. Raul“ first 031-” to within a. part per 1000
0100 nun.- 00001000 .1113 m othu' «and-rm, penum- acid puma».
www.mhobtmdumzmopmu A
standard. Mailman-141m u no! hwy-0000p“ and urban dioxide ha- I.
ctr-ct on m 0100:0100 mum. Hmmm no a donut. vapor
pram- which emu 00!»th 1am on W hating. this
MYMWMIMBIbI «bu-«1a. ‘10-de
m be nomad can: no cue-10011:.

it tho mt tho Mama-101:0 u a» mum cannot-11:.
Baum, than an a m ot ”than for 1h pupa-anon. th- Lou-n
manhutmummmappluabh,mdthnclmupot
Mum‘s 010M. ”ml“ 111 wry poor 71010. The cop-ru-
‘muhmmmhmm‘mnuuw 0mm
product.

IV LITERATURE GEES)

57

1. We: 0: Agricultural emu. “0:11.101 Method- 01 511.11“:
of that “mutton: 01' 0:210:01 lip-10111001101 CW,‘ 7th Ed"
p. 13, “00016100 or 01110101 Agricultural Chat-to, Washington,
D. 0., 1950. ‘

2. Albert, 1., J. Ch... 500., 1376 (195.1).

3. Auden-tong 1).. 0., and Soccer, I. L, J. n. 611.. 300., 1;, 3110-2
19 9 . ' .

1.. cups, 0.,cm. 203th, n 11, 6117-9 (1902).

5. Chichib-bh A. E. and Zoidc, 0. 5., J. Rm. Pm. Chen. 300., Ag
1216-33 (1911’. 0. 1.. z. 1901-: (1915).

6. dun 383%! I. 3.. and Outbofl’, J., It... 0:00. can... 22. 068-73

7. Etna-t. 3.,“ Don. 14.. 30.. 59,. 681-92 (1915).

8.1:" 11.1. M101- 1. C. Ind‘L‘uthflJ. 8.1!. 10.1.01”. 2
15141050 .’ ’ ' ’ ' ‘2’

9. Hauntiyggi 3., 3nd Reynold” O. 11., J. Org. Chum, u, 12215-32

10. mm, H. 1., W, 0. 1. 1., Bright, 3. 1., and norm-a,
J. 1.. "Appuod Immune Analyse} Ind 1211., pp. 180-1.
John 311-] and 300-, In Kerk, 1953.

no W; ‘0’ Mb.) a; 239.159 (1902).

12. lump, 1., Km, 0., 11.1». 18.. 1-0., 21. 1172-8 (1921;).

13. 10011130, 1., and than, 0., 0.9., 95, 1019-56 (1931).

1k. Katha“, 1. IL, and Sudan, E. 3., ”tomcat of Quantum"
Inorganic W, 3rd Ed" P. 522-11, The Human 00.,
M lurk, 1952.

15. 1.1mm. 1. 11.. and 0mm, 9. 1., wanna-1- mg 1.1. 1,
211:! 2d,, p. 30, Inter-0101100 Publish", 1110., In lurk, 19M.

10. 1.01., n. 0., m Oman, I. 0., J. AI. 00-. 3..., 91. 19-81 (1905).
17. noun. 1. 4., J. on. chm, 19,. 518-51 (1953).

16. Sided“, I. 7., "The @3111“ Gimmick-y ct Ritz-0m“, p. 529. The
animal” has, Oxford, 1936.

19. Snydu', l. 1., Elna C. 'l'., and 1.110., D. 3., J. 5-. Chan. 500.,

20. trap-ch, L, Hannah" 15, 775-9 (1931:).

21.1%.“ J. P. am; 8. ladsohlatmm J. Roe. tr“. 011111.
1i, 100.5 (1950). ' ' ' ' '

V APPJDII

59

1381.11 1111
2118111031 (I h-MINOPIRIDIHE WITH 0.). II 310800310810 ACID
W

 

In. 801 p8 m. 301 1:8 111. 801 pH In. 801 113
0.00 10.60 20.0! 8.66 21.92 5.96 32.10 2.51
1.05 10.32 21.88 8.57 27.97 5.71. 32.60 2 .53
2.13 10.08 22.11 8.88 28.00 .81 33.10 2 .88

.05 9.92 3.013 8.37 28.08 .78 38.10 2 .80
.08 9.11 2 8.28 28.07 8.53 35.11 2.35
5.08 9.76 28.59 8.18 28.13 h. 26 36.11 2.28
6.08 9.68 25.11 8.11 28.20 h. 06 37.11 2.28
8.08 9. 9 26.60 8.00 28.29 3.83 .11 2.11
9.10 9.88 25.90 1.93 28.33 3.72 .11 2.18

10.08 9.36 26.10 1.89 28. 3.63 81.12 2.10

11.10 9.31 26.80 1.81 28.50 3.53 82 .13 2.01

12.08 9.23 16.61 7.73 28 .63 3.83 83.18 2.05

13.09 9.11 26.61 1.63 28. 80 3.33 58.18 2.03

111.09 2.11 27.09 1.50 25 .9! 3.20 135.15 2.00

15.09 9.03 27.35 7.33 89.33 3.01 86 .11 1.91

16.08 8.98 27.55 1.08 29.89 2.90 81.17 1.96

11.09 8.90 21.71 6.76 30.60 8.16 88.16 1.95

18.09 8 .83 21.81. 6.38 31.10 2. 68 89.16 1.93

12.02 8.75 27.89 6.18 31.60 2 .63 50.16 1.92

TERI-SID! G WOMDIHE WITH 0.5 I HYDROCHIDBIC ACID

T831722 XXIII

6‘;

 

 

161. 1101 p1 171. 101 pH :41. 201 pH 21. 201 .56
0.00 11.18 20.58 8.86 28.67 8.07 29.06 1.85
1.00 > 10.53 21.08 8 .38 28.72 3.77 30.06 1.76
2.01 18.23 21.58 8.30 28.75 3.56 31.06 1.68
3.01 10.08 22.06 8.21 28.80 3.37 32.06 1.62
8.01 9.92 22.55 8.12 28.85 3.26 33.06 1.57
5.02 9.79 23.05 7.96 28.89 3.16 38.06 1.53
6.02 9.69 23.55 7.79 28.95 3.06 35.09 1.87
7.03 9.60 23.71 7.73 25.06 2.95 36.07 1.88
8.03 9.51 23.88 7.68 25.16 2.86 37.07 1.80
9.08 9.82 23.90 7.62 25.26 2.76 38.07 1.37

18.08 9.38 23.99 7.53 25.36 2.67 9.07 1.33

11.08 9.25 28.05 7.88 25.86 2.63 0.07 1.30

11.011 9.17 217.15 1.173 25.56 2.56 81.08 1.27

13.08 9.02 28.28 7.33 25.66 2.33 82.08 1.25

18.08 8.15 28.29 7.29 25.76 2. 7 83.09 1.23

18.10 9.02 28.35 7.17 25.85 ‘ 2.85 88.09 1.20

15.08 8.95 28.39 7.06 25.96 2.80 85.10 1.18

16.08 6.87 28.88 6.96 26.06 2.37 86.11 1.17

17.08 8.77 28.50 6.77 26.56 2.23 87.11 1.16

16.08 8.65 28.55 6.63 27.06 2.18 88.11 1.15

19.08 6 55 28.59 6.33 27.56 2.06 89.12 1.13

20.08 28.63 5.88 28.06 1.97 50.12 1.11

8:83

 

l

Nan“ Clayton E. Van 3-11
Born: .8pr11 28, 1928 1.7abandnllpidl,'fl10h1‘ll

undo-3.6 Emu“ Grad Em High School , Grand 82m, 3101113221,
1936-1982

B Coll-go, Holland, Michigan,
19 19119

Michigan State College, Eat Lansing, 3108113201,
1952-19517

Degree. fields A. 3,, Kopo College, 191;?