T1 . T! lll‘ll h It IIIT T l l i MW 129 480 HTHS THE EFFECT OF SALT ON THE COMPRESSIVE STRENGTH 3-1- ': RM?“ '7” P . 0F SUPER-CEMENT CONCRETE THESIS FOR DEGREE OF 3. s. w‘w WW wwr‘ WILLIAM ORSEN'V‘AN SIESEN v v- .- .a—r 1—.wumme-rxm "’ T972 6 . ' Uri—w— w‘ 1 It} #1" " \ THESIS THE EFFECT OF SALT ON THE CCHPRCSCIVE STRENGTH” OF SUPERrCEfiENT CONCRETE. A THESIS SUBMITTED TO THE FACULTY OF THE MICHIGAN STATE COLLEGE WILLIAM CRSEN_XAH GIESEN CANDIDATE FOR THE DEGREE OF BACHELOR OF SCIENCE JUNE 1926. In order to keep concrete from freezing when poured’\ in the winter months, it has been the custom to add common salt (NaCl) to the mixing water. The addition of the salt lowered the freezing point to a considerable degree depend- ing on how much salt was added. The effect upon the.comr pressive strength of the resulting concrete has been inves- tigated and found to be detrimental. The object of this investigation was to find out the effect, if any, Then salt was added to a concrete made of _ “Super Cement" as manufactured.by the Peerless Cement Com. pany. Obviously, a test of this kind consisted of making a number of test specimens containing various prOportions of salt and testing them at different ages. The first problem confronting the investigator is at What time to make the tests. As it is generally accepted that tensile strength of concrete bears some relation to the compressive strength, a piolet tension test was made. TL -' ‘E’ u.», .__ ‘ Man-um The method.of making the above test was as follows: A set of briquettes was made of the neat cement with enough water to bring the resulting neatznortar to its normal cons sistency. The briquettes were molded in the molds specified, and.by the methods as laid down by the American Society for Testing Materials. These briquettes wereebroken at the fol- ‘lowing intervals of time: 6 hours, 15 hours, 1, 2, 3, H, 5, 6, 7 days. Using the results of these tests a curve was plotted using tensile strength as an ordinate and.age of iilel-{Mfij specimen as an abscissa. (See Plate II) From an inspection of this curve it was decided to break the compression speci- mens at the following ages: 15 hours, 1, 2, 3, H, 5, 6 and 7 days. The materials used in making the compression Specimens were as near as possible what the average user of concrete has available. The aggregate consisted of land run gravel. Enough was selected to make the entire set ofmspecimens. This gravel was spread on the floor until it was thoroughly dried out when it was stored in containers until used. The silt content of this aggregate was determined.by washing on a 200 mesh sieve and found to be 1.0%. A sieve analysis was made according to the method as described in.Hool & Johnson's "Concrete Engineer's Hand Book." For the sieve analysis curve (See plate I). The cement was new'Peerless “Super" which was packed in paper bags of 1/u barrel capacity each. The water was tap water from the college water supply system. «huh-”M The Spit (YaCl) used was table salt made by the Norton Salt Company. Throughout these tests, the amount of cement, water and aggregate were kept constant, the only variable being the amount of salt used. After many trials to obtain a workable mix which could be used to advantage, the following prepcr- tions were adopted: Parts by weight of Cement 10 I . n I. Water 6 e ' ” ' ' Aggregate 60 The cylinders were made with the following amounts of salt as eXpressed as a.percentage of the cement by weight used: 0%, 6%, 9%, 12% and 15%. As these cylinders were broken at the eight ages before stated, there would be eight cylinders of each percentage if only one were made. .To in— sure better results, four cylinders containing the same perb centage of salt were broken each time. Thus the number of cylinders made containing like amounts of salt were: hrs-=32. As it took some time to place the concrete in the molds, it was decided to mix up batches containing enough concrete to cast 16 cylinders at one time. By splitting each batch into two parts, as outlined above, the concrete could be placed in the mold in about fifteen minutes, and any tendency for the concrete to set up was avoided. The method of mixing used was as follows: The amounts of aggregate and.cement were carefully weighed and placed in a pile on a concrete floor. By the use of a shovel, the materials in the pile were thoroughly mixed dry. To accomplish this, the pile was shoveled over six times. Then the water was weighed out and the p33334weight of salt dissolved in it. After a hole had been made in the top of the pile of aggregate and cement, the water containp ing the dissolved salt was poured in the hole. With the aid of a garden hoe the dry mixture was worked into the hole until all of the free water was absorbed. Then the ens tire mass was worked thoroughly. After a search for a suitable mold, quart ice cream cartons were adopted. Molding and puddling were accom- plished in the usual manner, the mold retaining its shape, and when full struck off level with a trowel. In order to obtain an even base, the empty cartons were set on loose sand during molding and until set. After casting, the cylinders were allowed to set for a period of 15 hours, when the mold was removed and the cylinders placed in water to cure at normal temperature (500 r 750?) until the time of testing. The dimensions of the finished cylinders were: height, 6.5", diameter 3 1/3". The volume was 57% cubic inches and the cross sectional area 8.7 square inches. The testing of the cylinders was done in a "Riehle" 100,000 # compression machine. Before testing each cyline der was bedded in, and capped with Plaster of Paris to in- sure an even bearing on both ends. Each cylinder was compressed until it broke and the breaking stress adapted on the strength of the cylinder. For results of these tests, see data sheets 1, 2, 3, h, 5 and 6, also Plates III and IV. CONCLUSIONS: (1) That the addition of salt to a batch of concrete makes it much more workable. In fact, two batches of grout exactly alike except that one has about 5% salt added has altogether different characteristics. while the amount of water remains the same in both, the salted batch appears to have much more water in than the other. It is not known why this is true; rather it is suggested that it would.be a fit subject for further investigation. (2) The second and last conclusion is of fsr greater irpertance. 0n inspection of the curves (Plate III & IV) will plainly show that salt very materially reduced the com— pressive strength of concrete in about the same preporticn as the amount of salt used. For that reason, the use of salt (Naol) should be looked on with suspicion. Protection of against frost should be obtained by the use of some other agent which will not lower the compressive strength of the resulting concrete, or better still by the preper and judicious use of mlamanders and covering materials. GIL- 0,311.! some i 1 - 1‘ 5:00 19.1. 54-2: 1'! - :2 2:15 run. 5.3-2: cylinder Time at Age of fetal brak- Adopted Unit honking breaking in; stress f total citrus breaking 5 per stress lupin. 1 6869 l.‘. 15 h. 453 as 33 2 54.26 ‘ 230 3 ' " 270 i ' " 3) A e Woo . a, % 6 5M ' G90 ’70 111 'I "‘ ' , 890 %- t . 1180 5:50 5.: 5 375: 2240 16 5-5020 ' 3250 11 ‘ " 3540 317: 3‘5 12 A ' . £60 # A A A 13 t . 3 days 4430 14 ”-25 ‘ 6000 an 4“ 15 : : 5m 1Q ---- 18 5-8.“ " 8210 7’55 916 19 : : 8480: Q 1470 A 22 5-8-26 * 8896 me 111‘ 23 ‘ " 12500 2‘ A . -........ A _ l A 28 I 5.9-“ " 13160 new 1315 2'! "‘ " 10550 g .. * 10950 , AA 3 ‘ e “y: 4520’ 30 5.16.25 ' 13050 31 " " 1.2900 mm 1525 is: " * 12459 A A .‘07, o-“* "4 C.‘ -O- 0-- ..‘4 -r‘. :. ‘0 "“c - . .o -0 ‘o . -_i.i. u. v . . v , .. .9 v - . ‘ -o - o . . "v.. r‘ t u e---‘-‘. ' ' 05-.--rb- . .’N"-oo.4 ‘-.-— A “ O 04--...- ‘l I C...--‘. . co--- -- I .._-... o- - .— b..O-'O ~ 0,.“ O‘--. ..’.' 9.-' O‘”" ‘4"' ’0‘“-.. I .I.. \ ‘.,._,.-. ‘- ufiai-‘.v.,."‘ .l.. . O-IlOa'---.._. .. r . «4.. ,‘ .- ..-00_-‘-‘. . 4 o . I.“ --..--c.~-.- i -—o—IO-‘..'.. ' c . 0-4--60- ‘--- -0 'O‘. c - _ h. , s .‘ 5" at“. '.¢.. -n,‘ 0"... his Erect 2. mm 1 mt Poured {1-16 . fi'fl 2:15 Pele Cylinder fine of £3. er 5:00 29.]. 5-1-26 5-7-26. fetal hruk- “up“ hit breaking in; stress total stru- breaking stress 1 C 5.1. 15 l. 1330 2 5-8-26 " 1320 1198 139 3 " " 1030 g_ " “ 113,0 A 5 . 1 . 2620 ‘. 5-8-25 " 2680 'l "’ " 21940 842 304 L A A A " " 2530 s 3 5.: 2 d. 5410 10 5-9-26. " 4980 ' ll : : 5410 5275 60’? 3; 5300 13 3 Li. 3 «I. 5300 14 540% " 7140 15 " " €910 €595 TE? 16 " " 7000 A 1'! 2:15 Pal. i t. 10440 18 5-11-26 " £000 19 " " 6010 I“: 915* an - - gas A AA 21 2:15 2.1. 5 1. sees 22 5-12-25 "’ 8080 23' " " 9280 8840 1020 24 - I: . ago A __ E 'e - e 39% 26 5-15-26 2? a e: 9510 91m 1980 23 " "‘ 10260 29 5:15 3.1: 7 d. 9310 30 5-14-26 " 11900 9590 1100 31 'i " 7620 El 4" ' A easel .r - v ~- . v u a. . - hr..- '1‘ ‘ c .- .4. o . c o .-O - u . w. § . o A ‘, q a --.¢.rd-‘0 O - O O y o O O l a Q a - 3 .4 0 J . ‘ a O o q - ¢ ‘ .- ‘fl'. ‘ .- '~ - o u a o a . .- u _ . . - o 9 o a- c . - “‘0‘ o , v Q Q - - O C - ¢ 0 '7 -1 - - .0 r . - ‘ O a. o .4 d I '0 t . - o o O < v o O .1'0‘0' ..-. . g 0-0 -.--.- .- v .. 0 0 0---- O .- p 0‘... ovn'no — ¢-~O— -.——. _.— h“ Shout 30 mm ”SALT Pom ”J16 3:39 PJ. 4-30.26 * 17-32 2:30 2.1. “30-2: 0:11-13: 1'1. of Ag: of fatal “1- Adopt“ Unit W breaking in; strut total strut breaking strut 1 5:50 1.1. 15 h. 530 2 5-11-26 "‘ 650 612 70 5 " " I100 4 ' "‘ 550 .1 G 5-1-25 " 24.40 'I " " 1520 1718 198 8 A ’ " 1370 - T 5: 5 5:: 5. I: m ; 10 5-2-2! " 4350 11 " " 5250 “'15 550 g ‘ ‘ 6159' A A A A A x P . 4300 14 5-5-25 " 5940 15 " " 6950 51“ 105 16 ' " ‘ 7380 17 2:5 5]. 4 i. 5610- 18 5-41-26 "‘ 6500 19 " "‘ 5280 6412 745 _ " " 1500 A % ' o ‘0 ‘60 22 5-5-25 " 8700 23 : : 82m 812‘ 532 2‘ 5-6-26 " 6910 8488 9'15 2‘! " "' 8500 9318 ' 1370 MISS E 0’! 0-0 . l. _ .- ‘ , . ‘ . '-‘ 3' ”n w . o- . '0 O - .. . ‘-' , . ' ' V a , , .7 - ,. . . a o _ l J a . , _ . . . . , g , '-, a o » .. ‘ , - ‘ n H - ‘OdofiOOODO“--‘DOOCDU-O‘~J6-.‘Q'I--‘~v..c.-—o‘&“O—O-.‘--.—-SC-. .4“..---.-...¢o-o.n..-l. 1. mso«;¢on.-a¢n-t-~‘o.oo‘op->ous-oo .--"lI.-.F-.’--ufl,.-a‘-—‘4.O--.----‘I'““~‘-O-‘Jh'---.-0.0»... .,‘4,-,‘-..-,.‘...---_.._.oco-a:a..ta-‘oOJ--.0.»¢-d.cla&aA"OJoI-U% _.Q _ ",l 5 - '1 . u " .- v ba--s~.y--Aa----¢_-..to..-».....a.;---. .. nr- .09 La . . . -- .-- . , ‘ O, C C '— Ia .0 v .. um‘--'-O-.p.-IAOOOQJCo‘fi-.§.-v—u-v‘--~‘-nv...-~l-'Q---o.—O‘QC-4‘O . O O 0 , v o I \ _. .f'. ., 1.. a- -- I I .. -. O. “.4 4 . 5 ‘O.-.~v‘~fl,'-§r‘—"d-um.».—---5-.--OQ‘fuv-v. a~¢~nlqao.--.--—-na~‘-—ro .. . H . s ' -.--- orcuc a .y.. a a a - .7- . ‘4 . §-. a n - ‘0 a-vd04 . n v - ! n—oo . .0--.vo¢-o-o--cfi¢ his 8118“ 39 Beans #1410 3:30 PJ. 4-30-23 * 17-32 2:30 2.x. 4-30-23 2:11.10: fins 01 Ass 0! You). honk- Adopt“ Unit brushing basking in; stress total strsss making struts 2 5-1-20 " 600 512 70 5 " ' 100 t ' 2 5‘0 E 5:5 53: 5 E17 15E 6 5-1-26 " 2140 7 " " 1520 1718 198 8 ' " 1310 A f 5-: 5 53: E I: m. 10 5-2-28 't 4350 11 " ‘ 530 4875 560 I U 61 ‘ A ‘ :30 5 . 4300 14 5-5-26 " 5940 15 " : 6050 6102 105 “$2 243 812‘ 052 8488 975 ~ 0930 A 30 5-0-3 " 8200 51 ’ " 11100 9518 ' 1070 .3 " " £2101 - o - O I .o o -. —¢ , - .. a . A n . 1 ¢ . C 4 .- . - - a .0 o- 5-.- O n . .a g .- .. - ‘ . .- .- 9--. a. n - - .o .. -. p .- _ . l . o ‘ . -- . a c . ~ - . - a. - o .. - - . - . ~ o.- . . 9 u Pm #1410 GIIJIDIES"12"!£EI :lfi-Pslb $935-$5- Butn Sheet 4. '* 17-02 0 :00 2.1. 4-23-00 Gylinder- 11m0101’ Ag! 01' fatal httak- Adoptoi. Unit brauking; heatking: lug atrtss total atrtal L banking I struts 1 4-24 15 1. a0 2 7:15 1.1. "‘ 050 920 100 s z : 900 4 250 - f m T hylhr. 2070 0 0:10 PJ. 2990 2000 as 7 " " 2290 0 ' ' ‘ u T 43 W 00 10 4:15 0.1. . '* 5250 0300 015 11 ' ' 5900 léLi 5. —-;;. 501° .1 A 13 4-00 1 m: 0000 14 4:15 P. I. " mac 6010- 001 15 '- ' 5520 1 " - I' 0040- 1’0 :0: 1 a." 0700 10 25:00 0.1. * 5050 - 0014 092 10 : : 0000 in 4-20 “‘5 by: $0 a 25:00 0.1. ' 5210 23 * '* 0000: 0190 40‘ g; 0* * 0700 25 4-29 6 days 6126 a 5:00 PJ. ' 0410. 2': * ' 7000 0010 m g - I . 0010 as 4-00 2 Hay: 4000 - 50 5:00 PJ. ' 7210 m0 014 3-1 ' . 2030 £21 "“ " m 0 w -¢.--‘ 0 A- Q . *-'—oo ‘4 . O 'O- ‘ O O.. a '- A . a — O. c . ‘- .- ‘A d 0.0 y 'd t -c...‘ O O * o i 4 . - . O-vv O- a... t n D ‘ 1 v o o c - 0‘---- olm-vfl-o . it - - o a - . Q 4 - o 4- o o a - .- 9 ‘~ ‘ ‘ A .. a «- .o - . , a a O .0 a. .— c o- . ~ . b o J - ' A I - - 7. - h“ $18“ 5. mmfimr 1M 5:“ Pot. 0311“» 1'11: 0! Age 01 You]. brak- “opt“ Unit hating haunting 103 strut total struts honking street 1 6:45 1.1. 15 h. 170 2 4-30-25 " 510 200 31 3 " " 500 i " ' 28 '5‘ ’33: P.E"‘““"‘"“ifi1 0. 0 0-30-20 ' . I150 7 "‘ " 640 1'00 00 11 " "' “0 ; g 5:45 '. 2 i. 10 fi 10 5-1-20 " . 2'50 11 " " 2820 2040 38 " "‘ 0 - 13 3:45 P. 5 «I. 3590 14 5-2-26 " 4600- 15 . "‘ " 4420 4465 512 16 " " 5250 ' 41 18 0-0-20 " 5900 19 ’ "‘ 6200 01:0 605 g " " 6040' 1 A 1 21 . 5 .‘ 4600 22 5-4-20 5 m0 ' 23 " " 6660 5405 74'! a O U ~ A 25 3:00 P. 0 d. 5050 25 5-5-26 " 5.530 a? " " £880 (302 020 g "E " 7350 A A; A 5:00 P. t. 0000 5-5-25 "‘ 6400 " " 7000 we 05! ”338 F 'H—.-" ~ n- -“-O ‘ 0-. . ‘ c u a a q o A .4 0'- '7‘ 4 4 A o o - 7 . .0 ‘ O O "n -~ 0" - u r - ¢ - a .- -‘. .- .I. O“. o C 9-- 0-- -" Jud . --‘.... .fl -0 -- 0 J h o 07.. d O ' . c .. - a n n o L .1 _,. o - 5.51000” 'C...CQ'.Q TABLE SHOWING AVERAGE URI? MAKING smss 01' m DIEM mamas OI VARIOUS 10:: 151 1 2i. 5‘ ii. 5 64. 7 o 35; ' 111 ’ 355» ’ 455 ’ 916 ’ 1114 ' 1315’1525' 0 o o t o t t t 139 ’ 304 ' 60.7 ’ 78‘! ' 915 ’ 1020 ' 1050'1100’ I t 0 a o c t t '10 ’ 198 ’ 550 ’ 706 ' '5‘3 ’ 932 ’ 975.10%! 0 c t 0 t t 0 0 105 ’ 298 ’ 615 ‘ 691 ’ ‘92 ’ 655 ’ 784’ 814’ t o c 9 t 9 t a 31 ’ 80 ’ 32.6 ’ 512 ’ 665 ’ 74? ’ 728’ 889’ c o r t t a t a Y 1 -*-‘-.—.-‘ou—.-- -~--.--h'.'“-.'-~ov - ’9ka I'llL-fllk’ffll‘ JIHIE. yuL-L.r.MIC. -. .uan — ..‘ _.-I 9.. ~\.-.. 0'” ~- MiCHA/V/CAL AMA]. 6/5" (.7 (may! ; _ ' v1.4". 0/: A66R£GA7Z _ “mo w w a m. « b\b\h. ksvx h... 0‘ b m OX £5.ka 3000 ’01:. Scalp/e A 016 5/2: of per/Ic/c: " 0f 2 a / a 0:7 v.54 .3 \wak\ §~hkhh Q0 4. 4.7 0 5 .0. b§§\\\b\ “Kat“ .67604o8/5093 6211/ % 037.775.36.553: \h... \QK‘LAO‘O’I 7388./.0. \0 Uwv‘hes 9975“332 / 53 I6 3.ka kfihkhh. , ksx\.nb 05‘ \§Q~k\v\ 3000 289/ 272/ ZIflE [55/ I307 [/20 [0/0 855 252 0906 397 III5 6.] 000000000000 82688 ”\s\\u\03\° M5W535mhufll5w 5.2....synsmwwooowmo ll-l— a. CUR V5 uS'HOW/AK5 TEA’J/Af .51 7' RE 11/577! . A 015' 11.5177/701sz . NORfi/li C 0/1457! TA/YC)’ '1?! 700 m 300 L200 . 700 Fla/s: 227 - (Mensa samuuwns:nezn5%722ur{ok[SM47' auam~nsneswswzuzcsxwfimfirzvvswvmaaMoeszE' /500 W/voo ‘l300 , leao 1/00 1000 r’" ' .900 700 1£00 s“) 400 E / r/ «‘17 200 cared 4/ nor-”70 / kin/(Mfr: (‘0 “- 75°F} Age Of Specxmen 1h 09/: 2 3 4 5 6' 7 “LL—~53; --"”‘“"“'"""""’ ‘““ V ' ' ““":‘_'_"“"’ “*7“ i / fie/t li‘q'l " -II'I‘ f Jan! ‘ 9,: 6.944;; .941 gran/wag .: 'u/ '45- Q Q ‘0 Q Q Q \§§\ he §§Nx . . §%\\ 343% «$3.52 .5 w \VKSSVRG xxxmmmuxogsu >6 k 35. K0 «UWKKN Nix m\<\\: le mm: 35 flan 24 51 “L“h —‘n..‘kh——A- fl,“ M|CHIGAN STATE UNIVERSITY LIB HI 3 129313177 6341 RI iiil‘l‘m“ A"