“Wu EEEE EE EEE EEEEEEEEEEEEE F350 ANALYSES 33L EROGR {3' OI“ ‘3f13’ 3-51-‘I 3., 'iwsr‘gm EV '1‘" I 3 z 3 ,I 0 (5'1”. 1-,-\ .. . '- I a 0 ga’& ‘ I a.“ \ _. f . K4 - o '. (“.3 1 W712 'n‘ .‘ia i". 7d." in . 3.15.. '. Q‘ C :6. c .0 w- . x ‘ J an ...... ' m ”51; 3 J“ .’ '. J I r {‘3 2’1; v” ‘ ). a P I J '1. Q B c l a 1: "mar.- :9“ 1.1!.“ ‘. m7; «#6 4.5.: A SONIC METHOD FOR PETROGRAPHIC ANALYSIS by Stephen Edward Tilmann A THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Department of Geology 197% ACKNOWLEDGMENTS To Dr. Hugh Bennett, my thesis advisor, for his patience and guidance; to Dr. Tom Vogel, for first arousing my curiosity in this subject, and his time spent with me in the field; to Dr. Bob Ehrlich, for giving me a perspec- tive; to Adrian Bass, for moral encouragment; and to those friends of mine in the Department, for making this exper- ience, I gratefully extend my acknowledgments. VOL. 73, NO. 35 JOURNAL OF GEOPHYSICAL RESEARCH A Sonic Method for Petrographic Analysis STEPHEN E. TILMANN AND HUGH F. BENNETT Department 0/ Geology, Michigan State University, East Lansing, Michigan 48824 A sonic method as a. tool for detecting and describing preferred crystallographic orienta- tion has been proposed by Bennett (1972). The Q ellipsoid is a theoretical surface whose magnitude for any direction is the sum of the squares of the three seismic wave phase ve- Iocities for that direction. The orientation of the ellipsoid relative to the sample is controlled by crystal orientation and structural effects of the sample. For completely isotropic samples the Q surface is a sphere; for anisotropic samples the Q surface is ellipsoidal. Sample homogeneity is testable by the closeness of fit of the velocity data. to the ellipsoidal surface. In this respect, crystal aggregates can be considered to behave as elastic long-wave equivalents to single crystals. The baraboo quartzite, a Grenville marble, and a. plastically deformed granite boulder are analyzed according to the Q ellipsoid technique. Optical analysis is per- formed on the quartzite and marble. The oriented Optical indicatrixes for the individually measured crystals are summed, an ellipsoidal surface characterizing the preferred crystal orientation direction of the sample thus being produced. For the quartzite, which is nearly isotropic, the optical surface and the sonic surface closely coincide. This situation is evidence that the sonic orientation accurately reflects the subtle crystallographic orientation. The marble displays a strong crystallographic orientation. as well as a pronounced micaceous layering. The orientation of the Q ellipsoid reflects the net effect of this structural fabric and the crystallographic fabric. The granitic boulder was plastically deformed into an ellipsoidal shape. The shape axes and the Q ellipsoid axes closely coincide, the indication being that the Q ellipsoid technique may be useful in describing regional tectonic forces. DECEMBER 10, 1973 The concept of the Q ellipsoid as a tool for detecting and describing preferred crystal- lographic orientations has been developed by Bennett [1972]. The purpose of this paper is to test this seismic model with empirical data gathered from several rock types The Q ellipsoid is a theoretical surface whose value for any particular direction is the sum of the squares of the three seismic wave type phase velocities in that direction. It has been proved that the principal axes of the Q ellipsoid always coincide with the optical indicatrix axes for a single crystal in the cubic through orthorhombic systems [Bennett, 1972]. For cubic crystals the Q surface reduces to a sphere. For uniaxial crystals the Q surface is an el- lipsoid of revolution, and for biaxial crystals the Q surface is a triaxial ellipsoid. If a crystal aggregate is considered as an elastic long-wave equivalent to a single crystal, then the locus of values, of which each value is the sum of the squares of the three seismic wave velocities for any particular di- rection, should be represented by an ellipsoidal Copyright © 1973 by the American Geophysical Union. surface; i.e., the material behaves as a homoge- neous pseudosingle crystal. Further, the prin- cipal axes of this ellipsoid would be controlled by preferred crystallographic“ orientation and structural effects within the rock material [Ben- nett, 1972]. Thus, if the Q surface is ellipsoidal. then (1) the material is homogeneous and anisotropic, (2) the principal anisotropic direc- tions are described by the ellipsoid principal axes, and (3) the percent difference between the ellipsoid principal axes is a measure of the degree of elastic anisotropy, which is controlled by anisotropic crystal orientation and structural effects. , The concept of the Q ellipsoid need not be restricted to rock materials of a single phase. Indeed an advantage of the Q ellipsoid concept is that a multiphase material can be treated as a pseudosingle crystal in terms of elastic behavior and crystallographic orientation. It should be pointed out that the P wave velocity surface (also the S, and S. surfaces) need not conform to any simple geometric shape. For rock materials the three velocity surfaces could be controlled primarily by struc- tural effects. such as microfractures, and ap- 8463 8464 pear to be unrelated to any preferred crystal orientation within the material. This condition may be more noticeable where orientations are weak and contribute less to the anisotropy. Also, since the P wave or 8 wave velocity surfaces may be quite complex in shape, the maximum value chosen from just a few measurements may not be the true velocity surface maximum. MODEL The calculated value Q.’ of the Q ellipsoid for the ith direction is given by Qt = Qa’/P = (V12 ‘l" V:2 + V32).‘ (1) where p is the material density, V1 is the P wave velocity in the ith direction, and V, and V, are the velocities of the two orthogonally polarized shear waves for the ith direction [Ben- nett, 1972]. By defining a polarization plane as the plane that contains the propagation direction and shear wave particle motion, it can be stated that the two polarization planes are nearly orthogonal for any propagation direction. Thus the values of V, and V. can usually be measured uttambiguously for any 'particular direction [Tilmann and Bennett, 1973]. Since the density tetm is constant, it may be incorporated into the Q.’ term without affecting the shape or the orientation of the Q ellipsoid. Thus the calcu— lated value of the Q ellipsoid in the ith direction will be. referred to as Q,. ‘ The least squares value 01.3, of the Q ellipsoid for the ith direction is given by ' 2 2 2 QLS.‘ = It an “l" m,- aza + 7h 033 + 2mtnia23 + zniliasl ‘l' 2ltmia12 (2) where (ll, mi, 12.) are the directional cosines of the. ith direction relative to any orthogonal set of axes 2:, y, and 2. In practice the 1:, y, and z axes are conveniently chosen relative to the sample being analyzed. The or terms are the elements of a 3 X 3 symmetric ellipsoid ma- trix. The elements of the a matrix are determined by the least squares method outlined by Nye [1957]. This procedure is based on the matrix equation relating the Q. values to the directional cosine matrix 0 and the a matrix by Q=9a (3) TILMANN AND BENNETT: SONIC PETROGRAPHIC ANALYSIS The Q matrix elements are the measured Q( values from (1). The 0 matrix is constructed by using the l, m, and n coefficients of (2). The a matrix is then determined by solving (3) for a, resulting in a = (GM-'01) (4) This is the computational form for determin- ing the a matrix. (See Nye [1957, pp. 164- 165] for a more complete treatment of this procedure.) The principal axes of the Q ellipsoid are found by the successive approximation method [Nye, 1957]. The procedure entails successive relocation of a vector normal to the surface of the ellipsoid until it corresponds to the minor axis. By inverting the a matrix the major axis is similarly located. The intermediate axis is the cross product of the major and minor axes. By using these directional cosines of the major, minor, and then intermediate axes in (2), the magnitude of these axes is easily determined. (Also see Nye [1957, pp. 165-168] for a more complete treatment of this procedure.) Comparison of the measured ellipsoidal values Q, and the calculated ellipsoidal values Q”, provides a test for sample homogeneity. The values of interest are, first, n 1/2 a; = [2 (Qt — Q;,,)2/n] (5) where Q,- is the measured ellipsoidal value in the ith direction (1), Q; is the arithmetic mean measured value, and n is the number of propaga- tion directions i measured; second, 0;. = [:2 (01.3. — est/n] (6) where Q”, is the calculated ellipsoidal value (2) in the ith direction; and, third, 0. = [2”: (Qt _ QI.S:‘)2/n] (7) The standard deviation 0: can be thought of as the deviation of the measured ellipsoidal values from the best-fit sphere to the measured values, 0;. is the deviation of the calculated ellipsoidal values from the best-fit sphere, and a, is the deviation between the measured and the calculated ellipsoidal values. If all the data TILMANN AND BENNETT: SONIC PETROGRAPHIC ANALYSIS points fall exactly on the ellipsoidal surface, then a, = 0, and 0;, = a; Sample homogeneity and elastic behavior as a pseudosingle crystal are indicated by the rela- tionship era-20;.>a. (8) Sample inhomogeneity is indicated by the re- lationship 6: > a. > 6;. (9) The inhomogeneity may be in the form of variance of the preferred crystal orientation within the sample or irregular compositional or structural differences within the sample. In- homogeneity is not consistent with the concept of elastic behavior as a pseudosingle crystal. TEST The baraboo quartzite, a Grenville marble, and a plastically deformed granitic boulder were analyzed according to the Q ellipsoid technique. The measuring apparatus used for determining the elastic velocities is described by Tilmann and Bennett [1973]. In addition, optical petrofabric analyses were performed on the quartzite and marble. The quartzite is an essentially pure quartz rock that has undergone slight metamorphism. In hand sample and thin section, no obvious structure was observed that would influence the elastic anisotropy. The marble comprises cal- cite and a well-defined micaceous layering. The granite boulder has been plastically deformed during metamorphism. The shape of the boulder is roughly that of a triaxial ellipsoid, with the minor axis normal to the plane of outcrop folia- tion. TABLE 1. Optical Ellipsoid Axes Magnitude Directional Cosines Symbol quartzite 41.98 (-0.986, 0.155, 0.058) hm 41.82 (0.161, 0.983, 0.087) mo 41.94 (0.043, -0.095, 0.995) Io humble 12.46 (0.398, -0.859, 0.322) Mb 12.10 (0.150, 0.285, 0.947) Mg 12.20 (0.965, 0.425, 0.015) I0 8465 Bamboo Ouuune a}; -1159 tonic optic 69,-1.601 M A . 0'e - .72s "I A (.3 I A o XIVP mu Fig. l. Equal-area projection of 200 quartz c axes for the baraboo quartzite. The direction of the observed maximum P wave velocity, the 0p- tical surface, and the sonic Q ellipsoid principal axes are also plotted, M, m, and I being the el- lipsoidal major, minor, and intermediate princi- pal axes, respectively. Close coincidence between the axes of the two surfaces indicates that the orientation of the Q ellipsoid describes the pre— ferred crystallographic orientation. Baraboo quartzite. The results of the optical petrofabric analysis on the quartzite are pre- sented in Figure 1. This diagram is an equal- area projection of the measured quartz c axes. This projection was not contoured in order to emphasize the diffuse nature of the orientation. The oriented optical indicatrixes of the indi- vidually measured crystals were summed in order to produce an ellipsoid analogous to an optical indicatrix surface. This ellipsoidal sur- face provides a convenient parameter that de- scribes the preferred crystallographic orienta- tion. The magnitude and directional cosines of the ellipsoidal axes are listed in Table l and are shown in Figure l. The three velocity measurements V1, V3, and V., which are referred to as a data set, were taken over nine directions. Each data set was rep- licated 4 times for each direction, the result 8466 TILMANN AND BENNETT: SONIC PETROGRAPHIC ANALYSIS TABLE 2 . Oi Values Propagation Direction Replicate 1 2 3 4 g 5 6 7 8 9 Quartzite (F a 50.11) 1 49.581 52.443 53.968 54.851 53.629 55.214 50.649 55.575 51.071 2 50.943 53.084 54.484 55.009 54.027 55.250 52.278 55.643 51.134 3 51.021 53.103 54.248 55.331 54.113 55.668 52.578 55.748 51.989 4 50.872 53.396 54.960 55.132 54.746 55.725 52.900 56.458 51.679 Marble (F I 64.75) 1 48.133 38.617 48.049 41.396 37.184 41.716 43.176 44.424 46.309 2 48.089 39.060 45.401 42.308 37.476 41.501 42.953 44.080 42.994 3 49.645 38.136 45.844 42.160 37.999 41.411 42.803 45.482 47.332 4 49.465 38.576 45.989 42.068 37.850 42.058 43.576 45.837 47.171 Granite (F I 73.20) 1 55.303 60.130 58.411 59.496 60.608 57.881 57.322 59.896 59.282 2 56.157 60.051 58.994 59.227 60.330 57.057 56.915 60.098 59.828 3 56.115 59.936 58.217 58.947 59.809 57.142 57.936 59.895 59.812 4 55.851 59.623 58.954 58.872 60.308 58.098 57.447 60.271 59.888 being 36 data sets. The order in which the data sets were measured was randomized. The Q,- values from these data sets were determined according to (1) and are listed in Table 2. The mean velocities for each direction (Table 3) were used in computing the Q ellipsoid. The magnitude and directional cosines of the least squares Q TAILS 3. Directional Cosinea and Hean Velocities Mean Velocity, kaisec ellipsoid axes are listed in Table 4 in the section on quartzite. The plot of these axes is shown in Figure 1. The mean Q,- values with their re- spective Q”, values are listed in Table 5. This table also presents the 0;, 0;" and a. values. The maximum P wave velocity observed Vp m is shown in Figure l. Grenville marble. The results of the optical petrofabric analysis on the marble are shown in Figure 2. Since the marble displayed a strong preferred orientation, the c axes, (0001), were contoured according to the Mellis method [Turner and Weiss, 1963]. The observed mica- ceous layering is in the N -S vertical plane. The c axes were space-averaged (Table 1, section on TABLE 4. Q Ellipsoid Axes Prepagatlon Direction Directional Cosine: V1 V2 V3 Guartaite 1 (l, 0, 0) 5.110 3.436 3.561 2 (0, l, 0) 5.206 3.659 3.537 3 (0, 0, 1) 5.332 3.598 3.611 4 {-0.602, 0.0, 0.800) 5.377 3.517 3.715 5 (0.574, 0.0, 0.819) 5.357 3.561 3.571 6 (0.0, -0.652, 0.758) 5.399 3.719 3.533 7 (-0.602, -0.800, 0.0) 5.261 3.548 3.440 8 (0.0, 0.663, 0.749) 5.389 3.668 3.655 9 (0.663, -0.749, 0.0) 5.325 3.553 3.239 Marble 1 (1, 0, 0) 5.575 3.059 2.897 2 (o, 1, 0) 4.711 2.335 2.392 3 (0, 0,.1) 5.387 2.852 3.026 4 (0.0, 0.707, 0.707) 5.028 2.792 2.985 5 (0.0, —0.707, 0.707) 4.634 2.799 2.885 6 (-0.707, 0.707, 0.0) 5.009 2.826 2.931 7 (0.707, 0.707, 0.0) 5.114 2.855 2.970 8 (-0.707, 0.0, 0.707) 5.273 3.029 2.823 9 (0.707, 0.0, 0.707) 5.397 3.019 2.773 Granite 1 (1, 0, 0) 5.684 3.425 3.438 2 (0, 1, 0) 5.882 3.505 3.612 3 (0, 0, 1) 5.775 3.498 3.614 4 (0.0, 0.623, 0.783) 5.819 3.544 3.555 5 (0.0, -0.643, 0.766) 5.931 3.543 3.540 6 (0.469, 0.0, 0.883) 5.728 3.571 3.461 7 (~O.530, 0.0, 0.848) 5.786 3.556 3.358 8 (0.415, 0.910, 0.0) 5.880 3.537 3.600 9 (-0.446, 0.895, 0.0) 5.860 3.507 3.614 Magnitude Directional Cosines Symbol Quartsite 56.010 (-0.097, -0.082, 0.992) Mg 50.539 (0.975, -0.184, 0.127) m8 53.243 (0.172, 0.979, 0.097) I5 Ahrble 48.048 (0.988, 0.088, 0.128) Mg 36.679 0.062, -0.970, 0.236) ms 44.947 {-0.145, 0.225, 0.964) 13 Granite 60.644 (-0.034, -0.995, 0.090) Mg 55.792 (0.994, 0.015, 0.112) ms 58.306 (-0.113, 0.079, 0.988) 1b 'I‘n.uANN AND BnNNm'r: SONIC Psmooaapmc ANALvsIs Tm 5. 0" Gui) and Deviatiai Values Quartaite' Marble? Propagation Granite‘ Direction at 059i: Q. t 013‘ 47.887 37.308 44.478 43.071 38.716 41.870 43.833 ”.NOM‘MNH one N . 46:671 55.856 59.935 58.643 59.135 60.263 37.543 57.401 592702 55.753 60.558 38.528 38.777 59.910 57.919 37.747 59:501 marble), and the axes of the optical indicatrix type surface are plotted in Figure 2. Twelve velocity measurements in nine in- dependent directions were taken, and the Q,- values were calculated (Table 2). From the mean velocities (Table 3) the Q ellipsoid was deter- mined. The directional cosines and the magni- tudes of the ellipsoidal axes are listed in Table 4 in the motion on marble. The plot of these axes is shown in Figure 2. The Q. and Q“, values were derived as 0:, 0;” and a. were and are listed in Table 5. The observed maximum P wave velocity is shown in Figure 2. Granite boulder. Velocity measurements of the granite were used to compute the Q,- values (Table 2, section on granite). From the mean velocities (Table 3) the Q ellipsoid was deter- mined (Table 4, section on granite). The axes of the Q ellipsoid are plotted in Figure 3. The Q,- and Q”, values, along with 0:, 0;" and c,, are listed in Table 5. The observed maximum P wave velocity is plotted in Figure 3. The orientation of the Q ellipsoid relative to the boulder shape is shown in Figure 3. The axes orientation of the shape ellimoid was mea- sured to an estimated accuracy of 110°. It should be pointed out that for single crystals of quartz and calcite the representative optic and sonic surfaces are opposite in sign. Therefore in crystal aggregates a maximum optic axis might reasonably correspond to a minimum sonic axis. CONCLUsIONs For all samples investigated the calculated Qt values for each direction display an F value significant at the 0.01 confidence level (Table 2). This indicates that the quartzite, marble, 8467 and granite are seismically anisotropic. The sum of the squares of the three seismic wave type velocities over the nine measured directions describes an ellipsoidal surface and satisfies the conditions of equation 8 (Table 5). Thus the seismic anisotropy of the samples observed in Table 2 results from the behavior of the poly- crystalline material as an elastic long-wave equivalent to a single crystal. For the baraboo quartzite the Q ellipsoid axes and the optical indicatrix type surface axes closely coincide. The maximum angular separation between the principal axes of the two surfaces is 11° or less (Table 6). The optical surface is nearly spherical, the major and minor axes differing in magnitude by only 0.4%, com- pared with a difference of 2.2% in a single -a.us " ‘ . a. - 1.028 I A Fig. 2. Equal-area projection of 100 calcite c axes for the Grenville marble contoured by the Mellis method at intervals of l, 2, 3, and 4% of the axes per 1% area. Stipled areas denote 3% concentrations. Hatchured areas denote greater than 4% concentrations per 1% area. Micaeeous layering is in the N-S vertical plane. The ob- served maximum P wave velocity, optical surface, and Q ellipsoid principal axes are also plotted, M, m, and I being the major, minor, and inter- mediate axes, respectively, of the ellipsoidal sur- faces. Location of the sonic minor axis is the nesult of interaction between the structural fabric and the crystallographic fabric. 8468 Boulder Granite asaonm o: shape X a VP I“ Fig. 3. Projection of the Q ellipsoid and shape ellipsoid principal axes for the plastically de- formed granitic boulder. The observed maximum P wave velocity is also shown. Close coincidence between the ellipsoidal axes indicates that the Q ellipsoid technique may be useful in describing regional tectonic forces. quartz crystal. The near sphericity indicates a weak preferred crystallographic orientation. Statistical analysis of the scatter diagram of Figure 1 yields a correlation coefficient of r = 0.103 [Chayes, 1949]. Therefore the degree of orientation, as displayed in Figure l, is not significant at the 0.05 confidence level (rm : 0.200). It is interesting to note that the calcu- lated correlation coefficient is significant at the 0.10 confidence level (r.no = 0.100). The magni- tudes between the major and the minor sonic Q ellipsoid axes differ by 10%, compared with a difference of 18% for a single quartz crystal. We conclude from the study on this sample that the Q ellipsoid method readily detects pre- ferred crystal orientations. The close coincidence between the sonic and the optical surface axes in this nearly Optically isotropic sample is strong evidence that the sonic orientation accurately reflects subtle fabric orientation. The Grenville marble produces a Q ellipsoid whose principal axes describe the effects of structural and crystal fabric. To a first approxi- TILMANN AND BENNE'I'I‘I SONIC PETROGRAPHIC ANALYSIS mation this sample behaves as a layered mate- rial, the minimum velocities being normal to the micaceous layering [Postma, 1955]. This structural fabric would tend to locate the minor sonic axis at the west pole of Figure 2. The major optical surface axis corresponds to the minor sonic axis (Table 6). Thus the crystal fabric would tend to locate the minor sonic axis coincident with the major Optical surface axis. Interaction of these two fabrics would place the minor sonic axis between the west pole and the major optical surface axis. There- fore the observed location of the minor Q ellip- soid axis is as expected (Figure 2). The Q ellipsoid axes differ by 27%, compared with 39% for a single calcite crystal, a rather strongly anisotropic material being indicated. The principal shape axes and the Q ellipsoid axes of the granite boulder closely coincide (Figure 3). The multiphase granite behaves homogeneously as a pseudosingle crystal oriented in response to plastic deformation. Thus the Q ellipsoid technique may be useful in detecting and describing regional tectonic forces. For quartzite, marble, and granite the angles between the Q ellipsoid maximum axis and the observed maximum P wave velocity are 36°, 9°, and 45°, respectively (Table 3 and Table 4). For quartzite and marble the P wave velocity measured in the direction nearly coincident with the maximum Q ellipsoid axis was not the observed maximum P wave velocity. Thus the direction of the observed V, .m has not been a reliable indicator of the Q ellipsoid major prin— cipal axis. Indeed it is conceivable that the P wave could indicate sample isotropy, whereas the Q ellipsoid indicates seismic anisotropy [Bennett, 1972]. Therefore the use of the P wave velocity surface to determine preferred TABLE 6. Optical and Sonic Axes Separation Axes Separation Quartst'te msiMo 11° 8:mo 3° Marble )4on 21° I81m° 4° 'I‘ILMANN AND BENNETT: SONIC PETROGRAPHIC ANALYSIS crystallographic orientation must be made cau- tiously. The results of this study lead us to conclude that (1) the elastic behavior of these rock materials is testable and is shown to be that of a homogeneous pseudosingle crystal, (2) in the samples studied the. orientation of the sonic Q ellipsoid is controlled by preferred crystallo- graphic orientations of the materials and by structural effects, (3) weakly preferred orienta- tions are readily observable with the Q ellipsoid method, (4) the sonic Q ellipsoid technique is equally valid for single-phase or multiphase materials. and (5) the P wave velocity surface is not necessarily a reliable indicator of prin- cipal anisotropic directions. Acknowledgment. The authors wish to thank Thomas Vogel for his assistance throughout the course of this study. 8469 REFERENCES Bennnett, H. F., A simple seismic model for de- termining principal anisotropic direction, J. Geo- phys. Res, 77, 3078—3080, 1972. Chayes, F.. Statistical analysis of three-dimen- sional petrofabric diagrams, in Structural Pe- trology of Deformed Rocks, edited by H. W. Fairbairn, p. 317, Addison-Wesley, Reading, Mass, 1949. Nye, J. F., Physical Properties of Crystals, p. 164, Oxford at the Clarendon Press, London, 1957. Postma, G. W., Wave prOpagation in a stratified medium, Geophysics, 20, 780—806, 1955. Tilmann, S. E., and H. F. Bennett, Ultrasonic shear wave birefringence as a test of homo- geneous elastic anisotropy, J. GeOphys. Res, 78, 7623-7629, 1973. Turner, F. J., and L. E. Weiss, Structural Analysis of Metamorphic Tectonites, p. 62, McGraw-Hill, New York, 1963. (Received April 13, 1973; revised August 6, 1973.) 8 ”Willi/j] [1]]fillllflllllljljjlflllllES