DRYING PEA BEANS INTERMITTENTLY AT lOO°F By Jew-kai yang AN ABSTRACT Submitted to the School of Agriculture of Michigan State University of Agriculture and Applied Science in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Department of Agricultural Engineering 1956 Approved by MW W N/w/fc. Abstract Jaw-kai Wang 1 The safe storage of pea beans requires that they be dried to about 15 percent (w.b.) moisture content. Since unfavorable weather conditions have frequently been encountered during the harvesting season, it is necessary that artificial drying be provided. Different from most farm products, pea beans tend to crack during the drying process, especially when heated air is used, and it is a challenging job to agricultural engineers to find a way to dry the product quickly and yet without excessive cracking. An attempt was made to give a mathematical analysis based on simplified conditions to illustrate the cracking problem. Also efforts have been directed to obtain experimental data to find a way to dry the product from about 20 percent (w.b.) moisture content, which is the usual moisture content when harvested, to about 15 percent (w. b.) moisture content effi- ciently but avoiding the commercial limit of cracking percentage. Based on the experimental data obtained, it is suggested that a drying process followed by a u-hour resting period, fol- lowed by another drying process, is a possible solution that can be used in practical drying. The first drying process proposed consists of: (l) a first heating period of 15 minutes during which the beans are heated with high humidity air so as no drying might take place, (2) a first drying period of 30 minutes in which heated air is used to remove moisture from the beans, Abstract Jaw-kai Wang 2 (3) a second heating period of 10 minutes during which the beans are reheated without change in moisture content, and (u) a second drying period of 30 minutes. The second drying process as proposed by the author utilizes the same procedure except that the drying period is shortened to 20 minutes each. By the above procedure, pea beans will be dried from 20 percent (w.b.) moisture content to 15 percent (w.b.) moisture content with a cracking percentage range from 1.3 to l.h percent. Since the actual drying time is less in the above procedure, less heat will be needed which can be generated from fuel oil or other heat sources. However, on the other hand, the resting period will likely cause some trouble in handling. Beans used in all tests were dry beans wetted artificially by nearly saturated heated air. Beans so treated may not possess the same drying characteristics as those that become wet in the field due to natural moisture and temperature con- ditions. It was found that the heating of pea beans by a nearly saturated heated air is not the cause of cracking of the skin. DRYING PEA BEANS INTERMITTENTLY AT 100°F By Jaw-kai Wang A THESIS Submitted to the School of Agriculture of Michigan State University of Agriculture and Applied Science in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Department of Agricultural Engineering 1956 amen .ll‘ll’l TABLE INTRODUCTION . . . . . . OBJECTIVE . . . . . . . . REVIEW OF LITERATURE . . . ANALYSIS OF PROBLEM . . . DESCRIPTION OF APPARATUS . PRESENTATION AND DISCUSSION Preparation of Samples OF CONTENTS 0 OF DATA Heating, Drying and Resting Period Tests and Testing Data SUMMARY AND CONCLUSION . SUGGESTIONS FOR FURTHER STUDY REFERENCES . . . . . . . PAGE 13 18 18 19 20 Al 1&5 LI ST OF FIGURES FIGURE . - PAGE 1. Assembly view of testing apparatus . . . . . . 1h 2. Sketch of drying box . . . . . . . . . . . 15 3. Top view of heater and air-steam.mixer . . . . 16 h. Sectional view of heater . . . . . . . . . . . 17 5. Temperature change of samples at first heating period . . . . . . . . . . . . . . . . . . . 29 6. Change of drying rate in first drying period . 30 7. Change in weight per 2000 grams of beans in the first 20 minutes of drying, samples at 20 percent (w.b.) . . . . . . . . . . . . . . . 31 8. Temperature change in first drying period . . . 32 9. Comparison of drying curves in a 20-minute drying period and when the heating period is BXClUded eeeeeeeeeeeeeeee 33 10. Temperature change of samples during second heatingperiod..........‘...... 3h. 11. Comparing drying curves between a 15(H)-20(D)- lO(H)-20(D) drying operation and the drying with heated air but without heating period . 35 12. Different drying processes compared with con- tiflUOUSdPyingeeeeeeeeeeeeeeee 36 13. Different drying processes, carefully controlled at the second heating period, compared with continuous drying . . . . . . . . . . . . . 37 1h. Figure showing comparison between drying curves of 17.62 percent (w.b.) sample and samples that have a resting period of h hours (17.22 percent) 38 LIST or FIGURES (Cont.) FIGURE PAGE 15. Total chan e in weight of a 17.62 percent sample at a 20(D -10(H)-20(D) drying operation compared to a sample that had a resting period of 3 or A hours eeeeeeeeeeeeeeeeeeee 39 16. Comparison between a 15(H)-20(D)-10(H)-20(D) drying Operation and a 15(H)-30(D)-10(H)-30(D) . . no LIST OF TABLES TABLE PAGE 1. Moisture Removed and Cracking Percentage of Different Drying Processes . . . . . . . . 25 2. Comparison of Moisture Removed and Cracking Percentages Between Samples Being Dried after Different Resting Periods and Samples at 17 percent (w.b.) Which Have Not Been Previously Dried O O O I O O O O O O O O O O O O O 27 ACKNOWLEDGMENTS The author wishes to express his deep gratitude to Dr. Carl W. Hall for his consultation, suggestions and comments in conducting the experiments and the preparation of this thesis. Sincere thanks is expressed to Dr. Arthur H. Farrall, Head of the Department of Agricultural Engineering, for his encouragement to the author. INTRODUCTION An increasing quantity of beans has been produced in the past years. It has become an important part of the agricul- tural production all over the world. But because unfavorable weather conditions are frequently encountered during the har- vesting season, the drying of beans is a serious problem. Beans are usually harvested at 20 percent (w.b.) moisture content and are usually stored at 15 percent (w.b.) moisture content. Excess moisture itself is not the direct cause of storage problems. However, excessive moisture provides one of the necessary conditions that are highly favorable to the development of undesirable organisms, both plant and animal. The removal of moisture or drying of agricultural products is generally classified into two main types: (1) natural drying in the field, (2) artificial drying. Utilization of the wind velocity, or fan-forced air with or without heat added are commonly used artificial means. During past years, more attention and emphasis have been given to the use of fan-forced heated air as a drying medium. Its dependability, and quick drying rate has won recognition from both the researchers and farmers. This is particularly true in an area like the United States where the agricultural production is dependent mostly upon mechanical power since less man power is available to handle the farm products. One factor that makes the drying of beans different than the drying of other small grains is its larger size and tender seed coat. Because of the size of beans, it is difficult to move the moisture content in the center portion efficiently and yet without excessive cracking on the surface of the beans. OBJECTIVE The chief interest was concerned with the drying of white pea beans containing excessive moisture for safe storage over a prolonged period. The main objective was to find a method of removing the excessive moisture from the pea beans quickly and still avoid excessive cracking. The problem has been analyzed from.a theoretical point of view and the experiment was performed under the guide of theoretical analysis. REVIEW OF LITERATURE Theoretically there are two types of moisture in the pea beans that must be removed in the drying process. As stated by R. H. Reed and George H. Dunganl, solids contain water in two general forms, namely: (1) free and capillary moisture is that moisture which is held between and on the particles or fibers of a material. This moisture does not generally affect the structure of the material to any great extent and its re- moval is relatively easy. (2) HygroscopicI or absorbed moisture is that moisture which a material will absorb if exposed to air containing water vapor. This moisture is intimately associated with the physical nature of the material and its removal may be accompanied by physical changes. The word "drying” is usually defined by researchers as the removal or evaporation of water from a certain.materia1. An evaporation process is governed by the law of evaporation, ”for a given condition of atmospheric movement, the rate of evaporation is proportional to the difference in vapor pres- sure between the liquid and the vapor of that liquid in the immediate vicinity"2. As we all know, beans that possess a certain moisture content will exert vapor pressure to the 3 and the problems connected with the drying surrounding air of grains might be approached from the standpoint of vapor pressure.h Referring toapsychrometric chart, we find that the heating of air has nothing to do with the vapor pressure of the air. Heating may change the relative humidity of air, its moisture- carrying ability, but the heating of air alone can not change the vapor pressure difference between the drying air and the pea beans to be dried, and no change in the rate of drying can be made by this method. The above statement is supported by most of the experiments conducted to date.5’6’7'8’9 And we might say it has been accepted by the majority of agricultural engineers that grain temperature is of greatest importance in affecting vapor pres- sure and is the greatest single factor in grain drying. Vapor pressure within a grain increases at an increasing rate as the grain temperature is increased. Grain moisture content also affects the vapor pressure but is of much less importance than grain temperature. At a certain temperature the vapor pressure exerted by the grains to the surroundings will change with a change in its moisture content up to approximately 20 percent, and for higher moisture content than that, the vapor pressure of the same grain will behave almost like a free water surface. As stated by F. C. Fentong,the principles of grain drying are: (1) grain absorbs or releases moisture because of the vapor pressure difference between the grain and the surrounding air. If the vapor pressure of the grain is higher than the vapor pressure in space surrounding the grain, moisture will flow out of the grain. If the reverse is true, moisture will flow into the grain. (2) The rate at which moisture is gained or lost is approximately proportional to the magnitude of the vapor pres- sure difference which prevails between the grain and the sur- rounding space. This rate is affected by the resistance to the movement of moisture vapor set up by the surface layers of the grain. Pea beans, like other hygroscOpic materials, have a ten- dency to maintain an equilibrium condition with the atmosphere in which they are exposed. An equilibrium moisture content of beans at a certain temperature and relative humidity might be obtained by maintenance of a constant temperature and humidity over a prolonged period. To remove moisture from beans, a non- equilibrium.condition of vapor pressures is artificially main- tained. The most effective way of doing this is to raise the vapor pressure of the beans by raising its temperature. Barre10 emphasizes the fact that pressure difference in drying with heated air are obtained by an increase in vapor pressure of the grain and not by a decrease in that of the surrounding air. In other words, the drying process is accomplished be- cause the heating of grain cause its temperature and therefore its vapor pressure to raise. Another important fact in drying should be noted. To evaporate water, a certain quantity of heat is needed. Evapor- ation from a free water surface requires approximately 1000 B.T.U. per pound of water evaporated; the exact amount will depend upon the temperature at which the evaporation takes place. Gallaher6 has worked out an equation to compute the amount of latent heat that will be needed to vaporize a pound of water from grain. In a drying process, a considerable amount of heat must be supplied to the grains, both to raise the grain temperature and to provide latent heat that is needed for evaporization. Kelly11 heated the grain directly and obtained a faster drying rate which he attributed to a greater vapor pressure difference between the inside and outside of the grain causing the moisture to move out. Kelly conceived that warming the inside of the grain caused the difference in vapor pressures. He found also that 57 to 60 percent of the drying took place in the first minute and that 43 percent of the total tempera- ture drop took place in the first minute. The drying rate slowed considerably as the temperature of the grain decreased. Several other reSearchers have tried some other methods, but usually the general practice is to use the air as a medium. to carry the heat to the grains and carry the evaporated vapor away simultaneously. ANALXSIS OF PROBLEM Since heat is needed in the drying process, the supplying of heat to the grain is evidently the predominant factor in designing an artificial drying method. In drying grains of large size like pea beans, the large size of beans makes it more difficult to transfer heat from the surrounding air to the whole kernel. Consider a cross-section of pea bean that is being dried artificially. Two ways have been used by researchers to supply heat to the grains for drying. One is to use heated air and the other is to heat the grains directly. In either way, the skin of the beans will receive heat first. The rise in temperature of the outer part will be the result of re- ceiving heat, and an increase in vapor pressure will be the result of temperature rise. The increase in vapor pressure will cause a difference in vapor pressure between the outer part of bean and the surrounding, and drying will begin. But at the same time, a difference in vapor pressure between the outer and inner part of the beans will be created by the ine creasing of vapor pressure in the outer part so that the movement of moisture at the beginning of the drying process must be both ways. Hygroscopic matter tends to shrink when it loses its moisture and the degree of shrinkage is dependant upon the amount of moisture lost. Thus, from the above reasoning, it can be seen that the skin will tend to shrink more at the beginning of the drying process. But as the drying proceeds, the outer part, especially the skin, will be quite dry. This will be particularly true if we use forced air of a large quantity, because the internal resistance to the movement of moisture is always greater than that offered by the surface to surrounding. So, briefly, it can be said that throughout the drying process, there will exist a difference between the percent moisture contained by the outer and inner part of the beans. Since there is a discontinuity of matter between the skin and the kernel, the difference of moisture content will make these two parts to shrink differently. A mathematical analysis based on some simplifications and assumptions is presented as follows: (1) The product under investigation is of homogeneous material, (2) The product is assumed to have a spherical shape, (3) The change of'moisture content and temperature is assumed to be the same in the skin or the kernel. Consider a pea bean in perfect spherical shape, coated with its skin. Let will be 1£LM 10 contraction coefficient of the skin due to loss of moisture content, inch/percent of moisture loss per inch length of skin; thermal expansion coefficient of the skin, inch/degree of F-inch; modulus of elasticity of the skin, inch/lb. of force; Poisson's ratio of skin material; contraction coefficient of the kernel due to loss of moisture, inch/percent of moisture loss-inch; thermal expansion of the kernel of bean, inch/degree F-inch; modulus of elasticity of the kernel of bean; inch/lb. of force; Poisson's ratio of kernel material; temperature change, degree F/time unit; change in moisture content, percent degree F/ time unit. When the product is subject to both a temperature and a moisture content change, the combined coefficient of shrinkage cx,=1 ~(1 -dste T)(1 -otsmam) «W1 -—(1 '“kt AT)(1 -otkmAM) Consider the contraction of the kernel only.- In drying problems, since it is known that the skin shrinks more than the kernel, assume that 0‘s >°(k . 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',.&....L 7.1 .i.‘. .sL,L orvoioo..t .oybtv! , y . _ > , r r . , [1'4 1 < 1 .vo; oyvaL Q. ~ 0 o. . ...fiuu . . .F... wo... v... . . r.$ 1“. r7.. 4Vuo \Pox.? ...?é-QTov¢b+.\o|¢r.9 07-: li?’ tl$+.'b+t...v .;.Y ...».vuxonl1.$ 6.¢*xvauan‘svprOvu‘T64‘. v9-0: +4.» ‘¢... ...o§A.c.o .v.c o , 'I. ..¢« vv.. o . .... ...v .. . nu. .. .x...v A... 4...n .... .... iuuivi.vv. .vv. 6... .Vc.‘0594 fo.r1¢..+v.‘.oA9.$ o... a... o ... ..u. .... ...o . . . .. ... ..., .... .... .. a... ...L 1....v7ot4ott.. ..;t To" ‘... +..$ >4.0L....1o... +<.u $64. s3wY4 ¥ .r > _ k. . . y , p F ooom annals - amaten 1:310; #1 SUMMARY AND CONCLUSIONS Analytic investigation showed that the cracking of pea beans during the drying process is mainly due to unequal shrinkage because of moisture difference between the skin and inner part of the beans. It is the desire of the author to emphasize that although a quick drying rate might result in a moisture difference, a quick drying rate alone does not necessarily cause pea beans to crack. The above statement is supported by the data from.eXperi- ments. When heated beans were being dried, the drying rate was high at the beginning, but most cracking occurred at the latter part of the drying process when the drying rate was comparatively low. The vapor pressure is affected mainly by its temperature and less by its moisture content. The fact can be explained simply as follows: ‘ At the beginning of the drying process, the temperature of the inner part was high and the vapor pressure was high, thus when the skin started to lose its moisture the internal vapor pressure caused the moisture to move out and a differ- ence in moisture content resulted. But as the drying proceeded, the evaporation decreased the temperature in the inner part as well as the skin and the rate of moisture transfer lowered. Thus, a comparatively large difference in moisture content be- tween the skin and the inner part occurred. AZ It has been stated by previous investigation that a "case hardening effect" in the drying process prevented the moisture from moving out and thus reduced the drying rate. Again the author thought this effect could be explained by the heat and temperature relationship in a bean during the drying process. It has been said previously that the drying process al- ways consumed heat and lowered the temperature of the beans. But as the drying process proceeded further, the increase in temperature difference between the drying air and beans would certainly increase the heat transfer between them. Since the drying rate would be low at this time, the increasing heat transfer rate would cause the temperature of the skin to rise. It is clear, that such a rise in temperature would lower the vapor pressure difference between skin and kernel and therefore lower the moisture transfer rate. By occasional observations during the experiments it was found that no observable physical changes in various cross- sections of a bean could be detected by the naked eye. Beans were taken from test samples during various drying stages. A razor blade was used to out those beans into sections, but no physical changes were observed. Maddexahas reported the same findings although he used the term "case hardening". The results of those experiments conducted by the author are summarized into following items: a ‘L g,‘ \‘g‘! r3 ( e '\ -- ‘1 1 A ‘ 7'! I‘ v . \— C ', v I 4 A . 0 'r1 A y z 1' \li ' . l 4 q " ' .‘0 J ', “J ‘ 1‘ _ . ., z ‘ ; ‘- . _ ‘ V" .' 3 i ‘0" >4 1 “‘ if ‘- r‘ ’ ‘ A. 4 .- 0 Or I “ ..- -' O r l- , ' C h .‘ ‘1 a J'_ _ . . . ,-. O .. 4 l, I _O O , r . 1 V" ;‘f“; ‘_ g, 0 fl} . \ ‘ . .t1 {‘1 (FL r. 4." -J Y. I" a J ‘- I ". 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" ' i n - r ~. v f, - q r7 K ‘1 g, .A I ‘ O ,3 '— I ,\ .. 5,. <‘ — V ‘ , L ' .. 1 ' . ‘ . \ _ D I. ..- ,. 7'} ,- 4" ‘ " ,— (‘ A ,. . \_‘ g ..A. .k . - . r .- ra + .‘ Hr) yr). - o 175:3 - ‘ ‘.a ,I - o F . ‘ ‘ . 1 u ‘ r. l“ " ,, t ‘ '4. . ‘J . ..‘ 'r' I ,-. , .-‘ J .3 v -, - N (I . . '1 ' _ " O 1 I y‘ . Y! '1 ' l‘i 'II C) "u .' r» r _ V! n , A i. ‘ - - .. i. |. ~ J . a. n ,‘V i _ . . _‘ , .2 4 I ‘ ‘.‘ Iva . L 1‘ 1 f.- f .1 .. ~‘LL _L.£«.l. L 1+ w; I ._ 4‘ ,' .- . a a . - . PM n ‘.J i L i :2 C I A .- l _ a l k.‘ \u ‘4 . I ’ ‘ ‘, w: “I :~ ‘ i‘.‘ C 'nba) fl 1" ‘.. - V ‘ ~ ' l. V a. .. .a \,r .. TTCHC ' 1.1. L'\‘_J l... E“ -- re .“‘\ ‘44 H V“ p o._' . $1 (I (J vxl L) _\ v‘\ ‘ ;.~ r- . A ‘V‘ 1 “r" f‘ ;’| f‘.‘ a O I 7"! __: r) 1‘ 1 rs ... . - \z .1. ‘ I a.) P ". 7" [fi 1 A . 1 ., ‘,'I‘ n \1 ‘IV‘Y‘IJ- ‘I Q‘_ ' 5n. . ‘ ' . ‘ » - 31..“ '."‘1’.‘ I Q r '4' ‘L k .1 ; r) o'— f, -‘ U ‘va- ‘1figr‘f I - -—A\). J SUGGESTIONS FOR FURTHER STUDY Through the experience gained from previous studies, further studies on this subject are needed. It was also felt that the results from the following recommended investigation would be of great help to illustrate both theoretically and practically the drying of pea beans as well as the drying problem as a whole. 1. A study on the physical properties like heat con- ductivity, tensile strength under different moisture contents, contraction coefficient due to the change of moisture content, thermal expansion coefficient etc., of the pea beans and other important farm products will be valuable for the understanding of the condition of farm products during the drying process. 2. Experiments should be conducted to obtain drying curves with or without the skin on the pea beans in order to acquire knowledge of the effect that the skin portion has on the drying of the farm products. 3. Future effort should be encouraged on the investiga- tion of a temperature measuring device to measure the tempera- ture distribution within the kernel of the farm.product which is to be dried, because of the important part heat has played in the drying problem and since temperature is the best measure- ment of heat. 1. 2. 9. 10. 11. 12. 45 REFERENCES Reed, R. H. and Dungan, George H. Drying Hybrid Seed Corn. Department of Agricultural Engineering, University of Illinois, Oct. 19h0. . Marks, Lionel S. Mechanical Engineer's Handbook. nth ed. McGraw-Hill Book Co., Inc., New York, pp. 1692-1699, l9h1. Hall, Carl W. Unpublished text book. Department of Agri- cultural Engineering,-Michigan State University, 1955. Fenton, F. C. Storage of grain sorghums. Agricultural Engineering, 22:185-188, May 19h1. Brandt, William.F. The Use of Ozonated Air for Excess Moisture Removal in Stored Grain. Unpublished Master's thesis, Michigan State University, 1952. Gallaher, George L. Fundamentals of Drying Agricultural Crops. Unpublished Master's thesis, Michigan State University, 1951. . Anon. The Drying of Wheat. National Research Council, Dominion of Canada, Report No. 2h:u2-hh, 1929. Maddex, Robert Leo. Drying White Pea Beans with Heated Air. Unpublished Master's thesis, Michigan State Univer- sity, 1953. Oxley, Thomas Alan. The Scientific Principles of Grain Stfigage. Northern Pub. Co., Liverpool, England, pp. 2-27, 19 . Barre, H. J. Vapor pressure in studying moisture transfer problems. Agricultural Engineering, l2:2u7-2h9, June, 1938. Kelly, C. F. Drying artificially heated wheat with unheated air. Agricultural Engineering gg:316-326, September, l9h1. Brown, Aubrey 1., and Marco, Salvetore M. Introduction to Heat Transfer. 2nd ed. McGraw-Hill Book Co., Inc., New York, 1951. A6 13. Hukill, W. V. Basic principles in drying corn and grain sogghums. ‘Agricultural Engineering, 22:53-5h, February, 19 . 1h. Brandt, W. F. and Hall, Carl W. Drying of Pea Beans with Heated and Recirculated Air. Research Project th. Agricultural Engineering Department, Michigan State University. Mimeographed. 1952. Date Due Demco-293 l