TED ERN'EUNI HEA§T AL-EcoMPQSITIONiJ lic£cRus3r Z ”TH EC 1 cs f :LATEPAL *nvmm ....._..... ,......;. .2... ......:..::. 7...: ... V... ‘ . 4.»; I... ..... .. f i..:a:...,...o a 4: “—..'1¢v.-oan’u--” .r.u._.i...l..: .:.::.: ‘ ‘ . y ‘ ~J ‘ m .. 3.5.1., .r........: . 5:... , 6.151% ... 1 . . 3.»... f .1 .t..~¢¢:42..¢k3 f...» I u .. rfi surrfiitwt. , $C§§~§2fi§ fixk...3 ‘(HESIt This is to certify that the thesis entitled LATE PALE OZOIC CRUSTAL COMPOSITION AND DYNAMICS IN THE SOUTHEASTERN UNITED STATES presented by Mary Walter Davis has been accepted towards fulfillment of the requirements for Ph. D. degree in GGOlOgV Major professor 0-7639 ABSTRACT LATE PALEOZOIC CRUSTAL COMPOSITION AND DYNAMICS IN THE SOUTHEASTERN UNITED STATES By Mary Walter Davis The Appalachian province has been the site of tectonic activity throughout the Paleozoic. This activity was a prelude to the rifting which occurred along the continental margin in the late Paleozoic or early Mesozoic. Each of these tectonic events included the uplift of crustal material, and the erosion and deposition of this material into nearby sedimentary basins. Determination of the petrologic character, location, and orientation of these uplifts should limit the range of theoretical models invoked to explain the rifting of continental masses. Although the roots of many of these uplifts are pre- served in the Piedmont and Blue Ridge, much of the infor— mation about these uplifts is avaliable only through petrologic and stratigraphic analysis of the sediments derived from them. The investigation described in this paper was designed to thus determine the petrology and tectonic history of a mid-Carboniferous uplift of the Mary Walter Davis central Appalachian region. The minerals and rock fragments present in the mid- Carboniferous sediments of the West Virginia and Virginia coal field indicate that these sediments were derived from a source terrane which included low and medium grade meta— morphic rocks, unmetamorphosed sediments, and intrusive and extrusive magmatic rocks. The distinct vertical composition- al zonation of these sediments suggests the progressive erosion of a single source terrane following a major epi- sode of uplift and magmatic emplacement. This terrane consisted of a batholithic complex surrounded by low and medium grade metamorphics, and capped by a sedimentary- volcanic cover. The limited vertical and lateral extent of batholith—derived detritus in the sediments suggests that this magmatic complex was relatively thin, and was nearly completely removed by erosion. The source terrane was one of three Carboniferous source terranes located along the eastern margin of the continent, and oriented at high angles to the present Appalachian trend. LATE PALEOZOIC CRUSTAL COMPOSITION AND DYNAMICS IN THE SOUTHEASTERN UNITED STATES By Mary Walter Davis A THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Department of Geology 1972 ACKNOWLEDGMENTS My sincere thanks go to Robert Ehrlich, not only for his assistance with this project, but for his friendship and encouragement through the years. John Ferm of the University of South Carolina was instrumental in obtaining the core samples, and served as field advisor. His interest and encouragement have been invaluable. This study would not have been possible without the cores provided by Consolidation Coal Company, and by (other firms which wish to remain anonymous. I am especially ggrateful to Nick Spanos, Jack Vonfeld, Gene Highlander, .Iim Yates, Chuck Mills, Jarrette Estep, George Denton, Fred IAllison, George Billings and Doug Prebble. Carl Steinfurth of Michigan State University provided exurberant assistance during most of the field work. Field tirne was also contributed by David Carpenter and Guy Paxigett of the University of South Carolina, who sometimes negglected their own work to help with mine. The West Vil?ginia Geologic and Economic Survey provided financial aSSistance for part of the field work. I would particularly like to thank the members of my COUHnittee--Thomas A. Vogel, Robert L. Anstey, James Fisher, ii iii and Sam B. Upchurch--for their assistance. The students and faculty of the Geology Department have provided a pleasant atmosphere and a good deal of moral support. It is hardly possible to summarize my gratitude to my parents, Norman and Esther Walter, in a few brief sentences. However, in connection with this research, I must at least thank them for providing a base of operations for the field work, and feeding many a hungry geologist I have brought their way. Of the many teachers who have helped and encouraged rne, Esten Davis, J. Attison McClanahan, and Bennett T. ESandefur deserve special mention and thanks. TABLE OF CONTENTS Page LIST OF TABLES . . . . . . . . . . . . . vi LIST OF FIGURES . . . . . . . . . . . . . vii INTRODUCTION 0 O O O O O O O O O O O O O l Pocahontas Coal Field . . . . . . . . . 3 LOCAL GEOLOGY O O O O O O O O O O O O O 5 £3AMPLING AND ANALYTICAL TECHNIQUES . . . . . . 7 iPETROLOGY . . . . . . . . . . . . . . . 11 Minerals . . . . . . . . . . ll Quartz o o o o o o o o o o o o 0 ll Feldspars . . . . . . . . . . . . l3 Micas . . . . . . . . . . . . 17 Rock Fragments. . . . . . . . . . . 21 Low Grade Metamorphic Fragments . . . 21 Sedimentary Fragments . . . . . . . 21 Plutonic Fragments . . . . . . . . 21 Volcanic Fragments . . . . . . . . 24 smary O O O O O O O O O O O O 224- COMPOSITIONAL VARIATION . . . . . . 26 Ubiquitous Components . . . . . . . 26 Restricted Components . . . . . . . 26 Petrologic Assemblages . . . . . . . . . 28 Sedimentary—Volcanic . . . . . . . . 28 Low-Medium Metamorphic. . . . . . . 28 Medium Metamorphic-Migmatitic . . . . . 29 Plutonic . . . . . . . . . . . . 29 Variation Within Cores . . . . . . . . . 29 Bear Wallow . . . . . . . . . . . 3O Erbacon . . . . . . . . . . . . 35 iv Ameagle and Kopperston Mtn. . . Welch . . . . . . . . . Summary. . . . . . . . . Composition at Other Sample Locations Big Ugly . . . . . . . . Charleston. . . . . . . . Mt. Alto O O O O O O O 0 Variation Through the Sample Array . INTERPRETATION OF COMPOSITIONAL VARIATION Drainage and Deposition. . . . . Source Terranes . . . . . . . Discussion of Models. Class A. . . Class B. . . Class C. . . . . Class D. . . . . O O O O O O 0 O O O O 0 Summary . . . . . . . . . LOCATION OF SOURCE TERRANE . . . . . LATE PALEOZOIC CRUSTAL DYNAMICS. . . Locations of Source Terranes . . . Petrology of Source Terranes . . . Paleotectonics. . . . . . CONCLUSIONS . . . . . . . . . LIST OF REFERENCES . . . . . . . . APPENDIX A. . . . . . . . . . . APPEMNX B. . . . . . . . Table Ala. Alb. A2. A3. LIST OF TABLES Bear Wallow #1: grain size and composition data . . . . . . . . Bear Wallow #2: grain size and composition data . . . . . . . . . Erbacon: grain size and composition data . Big Ugly: grain size and composition data . vi Page 81 82 83 8A Figure la. lb. 2a. 2b. 2c. 2d. 3a. 3b. 5a. 5b. LIST OF FIGURES Page Geographic locations of core and outcrop samples . . . . . . . . . . . . . . 8 Stratigraphic locations of core and outcrop samples relative to major coal horizons. Cross- section is along line AA' of Figure 1a . . . . 9 Photographs of mineral components: quartz. 100 X magnification . . . . . . . . . .12 Photographs of mineral components: plagioclase. 100 X magnification . . . . . . . . . .14 Photographs of mineral components: K—feldspar. 100 X magnification . . . . . . . . . .18 Photographs of mineral components: micas. 100 X magnification . . . . . . . . . .20 Photographs of rock fragment components: sedimentary and volcanic fragments. 100 X magnification . . . . . . . . . . . .22 Photographs of rock fragment components: metamorphic and plutonic fragments. 100 X magnification . . . . . . . . . . . .23 Petrologic assemblages . . . . . . . . .27 Bear Wallow: distribution of feldspar varieties in cores #1 and #2. Depths in feet are shown to the left of solid vertical lines; horizontal bars to the right of solid vertical lines indicate positions of samples . . . . . . .31 Bear Wallow #1: variation of grain size and quartz content with depth. Grain size is in phi units; quartz deviations are based on least squares regression line shown in Appendix A, Figure A1. . . . . . . . . . . . . .32 vii Figure 5c. 6a. 6b. 9a. 9b. 10. ll. 12. 138“ 13b. 13c. 13d. Viii Bear Wallow #2: variation of grain size and quartz content with depth, illustrated as in Figure 5b. . . . . . . . . . . . Erbacon: distribution of feldspar varieties. Depths in core and positions of samples illus- trated as in Figure 5a . . . . . . . . Erbacon: variation of grain size and quartz content with depth. Grain size is in phi units; quartz deviations are based on least squares regression line shown in Appendix A, Figure A2 Ameagle: distribution of feldspar varieties. Depths in core and positions of samples illus- trated as in Figure 5a; lithologic legend as in Figure 6a. . . . . . . . . . . . . Welch: distribution of feldspar varieties. Depths in core and positions of samples illus- trated as in Figure 5a; lithologic legend as in Figure 6a. . . . . . . . . . . . . Big Ugly: distribution of feldspar varieties. Depths in core and positions of samples illus- trated as in Figure 5a; lithologic legen (incomplete) as in Figure 6a . . . . . Big Ugly: variation of grain size and quartz content with depth. Grain size is in phi units; quartz deviations are based on least squares regression line shown in Appendix A, Figure A3 Compositional zonation of West Virginia coal field sediments. . . . . . . . . . . Possible source terrane models. Lithologic legend as in Figure 10 . . . . . . . . Possible combinations of source terrane models with drainage-deposition models, and resultant sediment compositional zonation . . . . . Development of Model A—l through time. Time I is oldest; Time IV is youngest. . . . Development of Model A-2 through time . . . Development of Model B through time . . . Development of Model C through time . . Page - 33 .36 . 37 . 38 , AO . 43 .44 .46 . 51 . 56 . 57 Figure 130 . 14. Al. A2. A3. AA. ix Development of Model D through time . . . Late Paleozoic tectonic patterns of the southeastern United States . . . . . . Bear Wallow: least squares regression relation between quartz + feldspar content and grain size. Core #1 shown by circles; core #2 shown by squares . . . . . . . . . . . Erbacon: least squares regression relation between quartz + feldspar content and grain size . . . . . . . . . . Big Ugly: least squares regression relation between quartz + feldspar content and grain size . . . . . . . . . . . . Relation between mica composition and stratigraphic distance above red and green shale facies (expressed as geographical distance from Bear Wallow . . . . . . . . . . . Page INTRODUCTION The Appalachian province, which extends from the Maritime provinces of Canada south to Alabama, was the site of tectonic activity throughout the Paleozoic. Each tectonic event included the uplift of crustal material, and the erosion and deposition of this material into nearby sedimentary basins. This pairing of uplifts and adjacent basins continued at least to the late Paleozoic or early Mesozoic, when rifting occurred along the continental margin. This tectonic activity was a prelude, then, to the major orogenic events affecting this portion of the conti- nent; late Paleozoic uplifts, in particular, may have been directly related to the rifting process. Thus determina— tion of the petrologic character, location, and orienta— tion of these uplifts should limit the range of theoreti— cal models invoked to explain the rifting of continental masses. Although the roots of many of these uplifts are preserved in the Piedmont and Blue Ridge, much of the information about these uplifts is available only through petrologic and stratigraphic analysis of the sediments derived from them. The locations and gross geometry of these uplifts can sometimes be outlined by sediment dis- persal patterns. The composition of detrital sediments provides information regarding the proximity and petro— logic character of the uplands, their internal structure, and the extent of uplift. Such information, as a whole, should also clarify the tectonic style of this region, and determine whether these orogenic regions of the Piedmont were periodically remobilized, or were uplifted and eroded in a single episode. Some of these techniques of reconstructing tectonic history from sediment analysis have been successfully applied in the late Paleozoic sediments of the Appalachian region. Devonian sediments of the Catskill complex (Allen and Friend, 1968) contain volcanic rock fragments and other shallow crustal material consistent with the erosion of newly uplifted terranes. Analysis of the compositional variation of mid—Carboniferous sediments in the Black Warrior basin of Alabama (Ehrlich, 1965; Davis and Ehrlich, 1972) demonstrated that they were eroded and transported northward from an east—west trending Ouachita structure; the roughly north—south trending Appalachian structure was not an active source of sediment in this area at this time. In the central Appalachian region, the depositional history and dispersal patterns of the Carboniferous sedi— ments of the Pocahontas coal field of West Virginia and Virginia indicate that they were derived from a localized source oriented at high angles to the present Appalachian trend. The investigation described in this paper was designed to determine the petrology and tectonic history of this source terrane. Pocahontas Coal Field One of the major depositional basins of the Carboni- ferous is the Pocahontas coal field region of West Virginia and Virginia. The basin contains graywacke sandstones, which are associated with coals, dark silts and shales, and orthoquartzitic sandstones; this sedimentary sequence seldom exceeds 3,000 feet in thickness throughout the basin. In the northwestern part of the basin this thick— ness encompasses strata ranging from Chester to Mononga— hela in age; but in the southeastern portion, this entire thickness is included in the lower Pottsville Pocahontas Group (White, 1903). The sandstone composition, and the rapid thinning of the sediments away from the basin, therefore indicate the rapid deposition of material eroded from a nearby source terrane; thus these sediments record a major orogenic event. Although these sediments have attracted a good deal cxf attention, because of their economic resources, most exeologic investigations have concerned mapping, resolu- tjxon of stratigraphic relations, and other problems related tC> coal quality and production. Little petrologic work has beeni done. However, preliminary examination had shown that 4 these sediments contain a great variety of minerals and rock fragments which should enable description, in some detail, of the source terrane petrology. In addition, evidence that these sediments were derived from a small source terrane suggests that it might be possible to relate large scale variation in sediment composition to the internal compositional geometry of the source terrane. Thus this investigation of the Pocahontas coal field region has several objectives. One is the determination of the variety of rock types present in the source. Another is the development of models for the internal structure of the source terrane, and the tectonic, erosional, and deposi— tional history of the uplift and its derived sediments. A third goal is the synthesis of these results with those of other workers to produce a reconstruction of the late Paleozoic tectonic history of the southeastern United States. LOCAL GEOLOGY The coal field region of West Virginia and Virginia is bounded on the east and south by the Appalachian fold belt, and to the northwest by the broad Cincinnati arch. Although the southeastern portion of the coal field sediment has been involved in the folding, most of it is exposed in the relatively flat—lying strata of the Appa— lachian plateau. The sediments of interest here are the coal measures, which contain coarse sandstones (sometimes conglomeratic), siltstones, dark shales, and coals. These sediments are underlain by an assemblage of red, green, and gray shales, with minor amounts of sandstone and limestone; this litho- logic assemblage (Mauch Chunk and Greenbrier) was used as a lower datum for sampling. It has been assigned to the Mississippian, and the overlying coal measures to the Pennsylvanian; but recent work in eastern Kentucky (Ferm, et al., 1971) has demonstrated that the red shale and Llimestone assemblage is simply the offshore facies of the filuvial—deltaic coal measures. The coal measures themselves are divided into strati— g1?aphic units first described by White (1903). Analysis Of' the depositional environments of these sediments (Ferm, 6 1971; Ferm and Cavaroc, 1968; Englund, 1972) has demon- strated the presence of several distinctive synchronous environments which transect the traditional litho-strat— graphic units. The present study establishes a composi— tional zonation within these sediments which cross-cuts both the traditional stratigraphic units and the deposi— tional units, thus providing a third framework within which these sediments may be described. SAMPLING AND ANALYTICAL TECHNIQUES Sampling was directed towards sandstones and conglo- merates, since the maximum variety of detrital components occurs in coarse—grained sediments. Samples were taken primarily from the sandstones of six continuous cores ranging from 800 to 2,000 feet in length. Outcrops near the core locations served to extend the vertical sections; other outcrop samples were taken in areas where cores were not available. These outcrop samples were collected only from recently exposed outcrops, since exposure to sub- aerial weathering quickly destroys or alters many minerals and rock fragments. The sample array covers all of the major facies in the basin and incorporates a number of well-known coal beds. The geographic and stratigraphic locations of the samples are shown in Figures 1a and lb. Compositional data was largely obtained from about 150 thin sections cut perpendicular to the bedding of the samples; additional rock chips and powdered samples were used for staining and X-ray analysis. Most routine microscope work was done on the flat stage. Quantitative compositional data was based, in most cases, on 100 point counts per thin section; grain size 7 _# Penna 0 Con ‘ OulcvoD M d Al é Q :’ . - - 0 mllIa 30 Vlrglnla 5 é \* MT ALTO \ Al O ‘ EHBACON CHARLESTON \°‘° 0° v I' o f. I glflla BIG uoLv ’° \~£ AMEAGLE ‘3“ o v'“ \ .0 A KOPPERSTON MTN Figure la.——Geographic locations samples. of core and outcrop .ma onswflm mo .<¢ osfla weoam ma coapoomummono .mcoufinon H600 n0mes on o>flpmamn mmamsem monopdo one onoo go mQOHpeooa oasgmnmflpenpmnu.na osswflm n u._—--u.. “ III.‘ __==/.J\ \ £0.03 ’0. .03 Ill! ' baom — coounbm — gauzoanox fix xiaua 522:. q l P gene—:50 «It 4 lO estimates were based on measurements of the apparent long axes of ten quartz (or feldspar) grains located along the point count traverses. Determination of plagioclase composition and twin types was based on the 5-axis universal stage methods described by Emmons (1943); some plagioclase and K—feldspar compositions were determined with the electron microprobe. The presence of K-feldspar was detected, in some cases, by staining of rock chips and thin sections according to the method of Bailey and Stevens (1960), and K-feldspar struc— tural state was determined by X—ray diffraction analysis (Wright and Stewart, 1968). Diffraction techniques (Borg and Smith, 1968) were of little use in the determination of plagioclase composition due to the wide range of compo- sitions present in these samples. PETROLOGY The samples contain a wide variety of minerals and rock fragments derived from igneous, metamorphic and sedimentary rocks (Figures 2 and 3). Although some of these detrital components, like quartz, are not distinctive of any particular rock type, many of them can only be derived from a limited range of source rocks. Thus an examination of the petrology of these sediments can lead to a descrip— tion of the variety of rock types present in the source terrane. Minerals Quartz The quartz in these sediments (Figure 2a) ranges from unstrained through polycrystalline to highly sheared and foliated. Clouds or trains of small inclusions are common; occasional grains show vermicular chlorite or rutile inclu- sions. Some of the quartz exhibits Bohm lamellae, which are generally indicative of a metamorphic origin (Hietanen, 1938). Although there have been attempts to relate quartz extinction types to petrogenesis, the only conclusion that Can be drawn is that the highly sheared types are most likely derived from metamorphic rocks (Blatt, 1967). ll l2 ‘\ Figure 2a.-—Photographs of mineral components: quartz. 100 X magnification. l3 Feldspars The feldspars in these sediments include members of the plagioclase series, and several varieties of potassium feldspar. The twinning, composition and structural state of the feldspars are influenced by their petrogenetic environ— ment; thus these minerals are valuable in outlining the petrology of their source rocks. Plagioclase composition. The compositions of the plagioclases in these sediments range from high sodium albite to about Anuo. This compositional range may well reflect the range in the rocks of the source terrane. How— ever, since chemical instability of the plagioclases increases with increasing calcium content, it may be that more calcic plagioclase was present in the source, but has been destroyed by weathering and transport. The high sodium untwinned albite is a distinctive mineral of low grade metamorphic rocks (Winkler, 1967). The more calcic plagioclase occurs at higher grades of metamorphism, but there is no direct correlation between calcium content and metamorphic grade (Cannon, 1966). Such plagioclase may also be derived from the entire spectrum of igneous rocks; compositions in the albite to andesine range occur in granites and granodiorites. Plagioclase twinning. The plagioclase twin varieties include untwinned grains, and both simple (such as albite) and complex (such as Carlsbad-albite) twin types (Figure 2b). The process of transport tends to increase the number l4 TW/A/A/E ZOMED Figure 2b.——Photographs of mineral components: plagioclase. 100 X magnification. 15 of untwinned grains by breaking down twinned grains (Pittman, 1969); thus inferences about the source area are based solely on the variety of twin types present, not on their relative proportions. Untwinned plagioclase is often abundant in metamorphic rocks. As noted above, untwinned albite is characteristic of low grade metamorphism, but absence of twinning is a feature common to all grades. Plagioclase twinning occurs in several types: "normal”, of which albite is a common type; ”parallel”, of which Carlsbad, acline and pericline are common; and "complex”, with Carlsbad—albite the most common form. The normal and parallel twin types are sometimes referred to as simple twins. This leads to some confusion of terminology; the term ”simple” in this context refers to the nature of the twin law. The term is also used to refer to twins with only two individuals; thus a grain with albite twinning follows a simple twin law, but the twinning may be either simple or multiple. The term ”simple” will be used here only in reference to the twin laws. A genetic classification of twin types was suggested by Vance (1961). Growth (primary) twins form during crys- tallization from a melt, whereas deformation (secondary) twins form in response to post-crystallization pressure in faither magmatic or metamorphic rocks. However, Vance‘s <3riteria for recognition of growth twins really depend upon the presence of zoning, which is not common in these 16 sedimentary feldspars. A more useful classification, which is based on the optical-crystallographic nature of the twin laws, is that of Turner (1951) and Gorai (1951). They pointed out that the complex twins are confined to magmatic rocks, and Carls- bad twins are usually magmatic; the other simple twins may occur in either metamorphic or igneous rocks. Thus the presence of complexly twinned plagioclase in these sediments is a firm indication of a magmatic petrogenetic environment in the source. Plagioclase Zoning. Some of the plagioclase in the Pocahontas sediments is compositionally zoned, although this type is not common in these sediments. The scarcity of zoned plagioclase may be due to their destruction by weath- ering, since even in fresh samples of igneous material the cores of zoned plagioclase are often extensively serici- tized. Oscillatory zoned plagioclase occurs in volcanic or shallow intrusive igneous rocks (Vance, 1965). It occurs only rarely in metamorphic rocks, and in most such cases appears to be relict zoning which originally formed in a nhagmatic environment. The presence of such zoned plagio- Clxase in these sediments thus carries an important line of eViidence, for it indicates that at least some of the magma- ‘tiJ: material was shallowly emplaced. Potassium Feldspar. The sediments contain both twinned aJICi'U.‘ntwinned varieties, both of which are sometimes l7 perthitic (Figure 2c). The non—perthitic K-feldspar, particularly that with microcline twinning, is distinctive of low and medium grade metamorphic rocks with a high potassium content, such as metamorphosed arkoses or gray- wackes, or potassium—rich shales and siltstones (Winkler, 1967). The perthitic intergrowths of plagioclase in K—feld— spar can be classified as replacement or exsolution types. The replacement types are characterized by a large propor— tion of plagioclase to K-feldspar, and by the arrangement of the plagioclase in large, irregularly shaped veins and patches. The exsolution perthites contain a much smaller amount of plagioclase, which occurs in crystallographi- cally aligned blebs or stringers. Replacement perthites are formed by the replacement of K—feldspar by sodium-bearing vapor or by liquid plagio— clase (Higazy, 1949; Hutchinson, 1956). An alternative theory for their formation (Robertson, 1959) is the replace— ment of plagioclase by K-bearing vapors or solutions. The exsolution perthites result either from post— crystallization unmixing of the two feldspar phases (Tuttle, 1952) or from their simultaneous crystallization (Hogan, et al., 1971). Both types of perthites are characteristic of magmatic rocks. The micas found in these sediments include the potas- sium mica muscovite, and the iron—bearing micas chlorite l8 M/Eeoc / ' p59 7/—// 75 @579 74/99/72: Figure 2c.——Photographs of mineral components: K—feldspar. 100 X magnification. l9 and biotite. These are illustrated in Figure 2d. Muscovite. This is the most common mica in these sediments, and occurs in large, single-crystal flakes. This mineral is stable under a wide range of temperature and pressure conditions, and occurs in many potassium— bearing igneous and metamorphic rocks; thus its presence in these sediments carries little information. Chlorite. Chlorite usually occurs in these sediments in small, irregular chunks. This mineral is not abundant in igneous rocks, but is considered the diagnostic mineral reflecting the onset of metamorphism. It is stable at low grade (greenschist) conditions (Winkler, 1967); thus the presence of chlorite indicates metamorphic rocks of this grade in the source terrane. Biotite. The biotite content in these sediments is quite variable. Where it occurs in more than minor amounts, it is present in large books, or in coarse aggregates in combination with chlorite. The petrogenesis of this mineral is rather ambiguous, since it occurs in a variety of igneous and metamorphic rock types. However, under metamorphic conditions, biotite replaces chlorite at medium grade (amphibolite) conditions (Winkler, 1967). The mutual asso- ciation of chlorite and biotite in coarse fragments seems to indicate a metamorphic origin for this biotite. 2O (HA [9/75 Figure 2d.-—Photographs of mineral components: micas. 100 X magnification. 21 Rock Fragments Rock fragments are a major constituent of these sedi- ments, and provide additional information about the rock types of the source terrane. Metamorphic fragments are the most abundant, but volcanic, plutonic, and sedimentary fragments (Dicksenson, 1970) also occur. These are illus- trated in Figures 3a and 3b. Low Grade Metamorphic Fragments These fragments are characterized by a high percent— age of mica and a foliated texture (Figure 3b). They generally contain muscovite or chlorite, with varying amounts of quartz or feldspar. Some fragments contain much organic material, and are probably only slightly metamor- phosed shales and siltstones. Sedimentary Fragments The only fragments of this type usually seen in thin section are shale and limestone fragments (Figure 3a). These types, as well as siltstone and sandstone fragments, also occur as pebbles. It may be that some material identi— fied as ”polycrystalline quartz” in thin section is really sedimentary debris. Plutonic Fragments These are compositionally similar to the metamorphic fragments, but mica is much less abundant and the texture is equigranular (Figure 3b). Some of these fragments may be meta-sandstones, but the presence of granite pebbles in a few localities confirms the presence of magmatic rocks 22 SE mam EV "a0 ’1 rut , . l/OL CAM/C Figure 3a.-—Photographs of rock fragment components sedimentary and volcanic fragments. 100 X magnification. 23 p4 are/we Figure 3b.——Fhotographs of rock fragment components: metamorphic and plutonic fragments. 100 X magnification. 24 in the source. Volcanic Fragments These fragments are fine-grained; some are aphanitic, while others contain phenocrysts of quartz or feldspar or show devitrification textures (Figure 3a). Some silicified fragments occur as pebbles (and may be mistaken for chert pebbles in the field). Summary The minerals and rock fragments of the Pocahontas coal field sediments were derived from a heterogeneous source terrane composed of several rock types. These in- clude low to medium grade metamorphics, unmetamorphosed sediments, and extrusive and intrusive magmatic rocks. The presence of sedimentary and volcanic rocks in the source is inferred from the presence of fragments of these lithologies in the sediments. Low grade metamorphic rocks supplied albite, chlorite, and low grade metamorphic fragments; medium grade rocks supplied more calcic plagio- clase and biotite. Both grades probably contributed non- perthitic microcline to these sediments. The presence of magmatic rock types in the source is indicated by the presence of zoned and complexly twinned plagioclase in the sediments. Although some of these may be volcanic in origin, the presence of perthitic K-feldspar and coarse—grained granitic pebbles assures the presence of intrusive igneous material in the source. 25 This variety of source terrane lithologies is similar to that seen today in the Blue Ridge and Piedmont. How- ever, knowledge of this variety of rock types does not, in itself, allow description of the internal structure of the source terrane. This detrital assemblage could be produced by simultaneous erosion of these lithologic types from a heterogeneous, previously uplifted terrane which has been remobilized, or by progressive erosion through a vertical lithologic sequence of a previously inactive area. This question will be partially resolved in the following discussion of sediment compositional variation; the result will clarify the deformational history of the Piedmont. COMPOSITIONAL VARIATION The detrital components discussed above are not distributed uniformly through the sample array; they fall into several associations, which are illustrated in Figure 4. This variation might be attributed to a number of factors, ranging from simple variation in grain size to variation in the type of material being supplied from the source terrane. Ubiquitous Components Each sample generally contains plagioclase, musco— vite, chlorite, quartz, and volcanic and low grade metamor- phic rock fragments. These components are present through- out the sample array, and reflect the erosion of volcanic, low grade metamorphic, and intrusive magmatic rocks. This assemblage acts as an ever present background, upon which variations in the distributions of the other components are superimposed. Restricted Components The components which do not occur in all samples (Figure 4, center column) include microcline, perthitic K—feldspars, large books of biotite, and sedimentary rock 26 27 0_._._h<20_2l O.:an!<.-.m2 End-Om! 0.20.5...3 O_Ia¢02l >m «cau::n< 2.3559."— fat—0:235 + ++| +| 3.3552“. oaoeflzom 3.3505“. o_:ao.o> 02.020 32503.2 .ll omflogmaa utaac 28 fragments. Volcanic fragments, although they constitute part of the background assemblage, are most abundant when found with the sedimentary fragments. These variably distributed components, when combined with the background components, constitute distinct petrologic assemblages; each of these can only be derived from a limited set of source rocks. Petrologic Assemblages Sedimentary—Volcanic The sedimentary-volcanic assemblage contains the background components, an enhanced abundance of volcanic fragments, and sedimentary fragments. Since volcanic rocks form at the earth's surface, and unmetamorphosed sediments are most likely to occur at the surface, this assemblage 1 reflects the erosion of surficial or shallow crustal material. Low—Medium Metamorphic This assemblage contains non—perthitic microcline, 1 which is characteristic of metamorphic rocks with a high potassium content. Since the background assemblage also contains material eroded from metamorphic source rocks, the difference between these two assemblages is largely one of bulk composition. The potassium-poor background metamorphic material may have been derived from rather basic metavolcanics, or potassium-poor metasediments. 29 Medium Metamorphic-Migmatitic This assemblage is characterized by abundant coarse- grained biotite, biotite-chlorite aggregates, and non— perthitic untwinned K-feldspar. As noted above, biotite may be igneous in origin; but the intimate association with chlorite suggests a metamorphic origin. The amount of biotite present is from 5% to 15% of the total rock; taking into account the enhancement in quartz in sediments, the material which produced these sediments probably contained 30% to 50% biotite. This high biotite content would be most likely in metamorphic rather than magmatic rocks. The K—feldspar associated with this biotite indicates the presence of some magmatic material in the source rocks. Plutonic The plutonic assemblage contains perthitic K-feldspar, which is characteristic of intrusive magmatic environments. This assemblage usually occurs, in these sediments, in combination with the microcline-bearing low-medium meta— morphic assemblage; this probably reflects the commonly observed close association of these two petrogenetic environments in the source. Variation Within Cores The distribution of the petrologic assemblages through the sample array can be established by examining their distribution in individual cores. 30 Bear Wallow The core samples were taken from two cores spanning about the same stratigraphic interval; outcrop samples collected between Bear Wallow and Princeton (within twenty miles of the cores) served to extend the vertical section down to the red and green shale facies. The variation in feldspar varieties with depth is shown in Figure 5a. In both cores, plagioclase, which is a member of the background assemblage, occurs throughout the section. Microcline and perthitic K—feldspars, which charac— terize the low-medium metamorphic and plutonic assemblages, occur only in the upper portions of the cores. Outcrop samples (stratigraphically equivalent to and below the base of the cores) contain plagioclase and abundant sedimentary and volcanic rock fragments; thus these rocks contain the sedimentary-volcanic assemblage. The effect of grain size upon this compositional variation is negligible. First, since samples were initially restricted to the sandstones, grain size variation is minimal. Secondly, most of the assemblages are defined on the presence or absence of certain detrital components, not on their abundance. Thus grain size could only affect the distribution of these assemblages if grain size fell below the minimum stable size for these components. Thirdly, inspection of the grain size variation (Figures 5b and 5c) in comparison with the compositional variation shows no correlative trends. That is, the sandstones containing the 31 BEAR WALLOW --1 .-2 I o' 3I ! .5: 2| 2; C 0 500 ;| I . I . | El 3. I 2I 0 g z: 5 fl 3 5 a 3 ° '5 . .l _. 1000 8 3 '3 E .3 a I 1500 Figure 5a.--Bear Wallow: distribution of feldspar varieties in cores #1 and #2. Depths in feet are shown to the left of solid vertical lines; horizontal bars to the right of solid vertical lines indicate positions of samples. 32 BEAR WALLOW --1 Grain Size Quartz Dovlatlons 3 2 1 0 10 0 10 11, I I .L 1 l J I l I l 0 00 00 - .. + +4, 00 .9. 4. Figure 5b.-—Bear Wallow #1: variation of grain size and quartz content with depth. Grain size is in phi units; quartz deviations are based on least squares regression line shown in Appendix A, Figure Al. 33 BEAR WALLOW "2 Grain Slze Quartz Dovlatlono 3 2 1 0 r0 0’ 10 I I I I I L 1 I 4 I 00 ++ .00 -- — + 0 + O O -— + 0 + 0 + Figure 5c.--Bear Wallow #2: variation of grain size and quartz content with depth, illustrated as in Figure 5b. 34 background assemblage do not have a significantly different grain size than those containing the metamorphic and plutonic assemblages. The effect of depositional environment upon composi- tion must also be considered, since sands of the same grain size may be either orthoquartzites or graywackes, depending upon the depositional environment. The first step in assessing the effect of the environment is distinguishing between quartz—rich and quartz-poor sands of the same grain size; this is done by finding the least squares regression relation between quartz + feldspar content and grain size (Ehrlich, 1965; Davis and Ehrlich, 1972). This relation, for the Bear Wallow cores, is shown in Appendix A in Figure Al. Data points falling above the line are relatively quartz-rich for their grain size; those falling below the line are quartz-poor. The deviation of the observed quartz content from the expected quartz content (for the same grain size) may be expressed as a positive or negative number; these deviations are shown graphically in Figures 5b and 5c. As with grain size, there is no correlative trend between quartz deviations and the compositional variation. To summarize, the sequence of assemblages observed at this sample locality goes upwards from sedimentary—vol- canic, through the background assemblage, to the combined low—medium metamorphic and plutonic assemblage; this variation is not due to variation in grain size or 35 depositional environment. Thus the sequence apparently reflects variation in the type of material being supplied from the source terrane. Erbacon This section is based on a core which extends 1,300 feet from the surface down to the red and green shale facies. Compositional variation within this core is shown on Figure 6a. Plagioclase occurs throughout the core, but micro- cline is found only in the upper portion. Perthites are not present; thus this core contains the potassium—bearing metamorphic assemblage found in the Bear Wallow cores, but not the plutonic assemblage. Volcanic fragments and some sedimentary fragments occur in the lower part of the core. The sequence is similar to that found in the Bear Wallow cores, except that the uppermost K—feldspar assemblage is only metamorphic, rather than metamorphic and magmatic. As in the Bear Wallow cores, there is no apparent relation between grain size variation and the distribution of microcline (Figure 6b). Although the quartz deviations show a definite vertical pattern, the microcline-bearing zone includes both quartz-rich and quartz-poor portions of the core. Thus the compositional variation is not controlled by either grain size or depositional environment. Ameagle and Kopperston Mtn. This section consists of a core which includes 2,000 feet of section upwards from the red shale facies, and 36 ERBACON : g: 3| 0 0| a h 2 2| o 2 2 l a 500 2 I a 1000 LEGEND Sandstone Slltetone Coal __ :___ Shale _-_-- Shale --Red&Green Figure 6a.-—Erbacon: distribution of feldspar varieties. Depths in core and positions of samples illustrated as in Figure 5a. 37 ERBACON Grain Size Quartz Deviations 3 2 1 0 10 Q 10 I l I J l I l J 1 I J .0 ++ . + e e - + O O -’ —- _ + 0 + e + 0 + 0 + 0 + e e e + 4. + Figure 6b.--Erbacon: variation of grain size and quartz content with depth. Grain size is in phi units; quartz deviations are based on least squares regression line shown in Appendix A, Figure A2. 38 500 — '—-t—. I. 'I l‘:' l" M I \ll 1 I .1! ! lll‘l I l l I 17!! e—o—a 3 . ' I . l ' I 1000 Plagioclase '1 £5 ()‘() IIIIIIIIIIIIIIII d-‘l— 2000 3.81 E Figure 7.--Ameagle: distribution of feldspar varieties. Depths in core and positions of samples illustrated as in Figure 5a; lithologic legend as in Figure 6a. 39 several hundred feet of section above this taken from outcrops on Kopperston Mtn. The lower part of the core contains the orthoquartzitic barrier beach facies. The core is composed entirely of the background assemblage, which contains plagioclase as the feldspar variety (Figure 7). (The absence of the sedimentary- volcanic assemblage at the base of this core may be due to the orthoquartzitic nature of the sandstones.) Samples from Kopperston Mtn., however, contain some microcline and perthitic K-feldspar, and thus belong to the same petrologic assemblage found in the top of the Bear Wallow cores. like the Bear Wallow cores, then, this section shows a vertical sequence from the background assemblage upwards into the metamorphic and plutonic assemblages. Welch This location includes a core which extends upwards from the red and green shale facies for about 1,000 feet; the upper 700 feet of this section is taken from outcrops a few miles away. Most of the core samples contain extensive calcite cement, which replaces some feldspars and rock fragments; thus quantitative grain size and compositional data were not obtained. The distribution of compositional assemblages in this section is shown on Figure 8. Like the Bear Wallow cores, the background zone is replaced upwards by the potassium feldspar metamorphic and plutonic assemblage; but in this section the background assemblage reappears in the upper 40 .—~—.——. 5C”) .1:::: ~—- _._.__ O 2 E I I E” I ‘t l 1000 I Elzl E'EI 3'; SH II I 1500 I I ’——-- Figure 8.—-Welch: distribution of feldspar varieties. Depths in core and positions of samples illustrated as in Figure 5a; lithologic legend as in Figure 6a. 41 part of the section. The extensive calcite replacement in the core makes it impossible to say whether the sedimentary- volcanic components are truly absent here, or if they have been diagenetically destroyed. Although complete grain size and compositional data are not available, it appears, by analogy with the other cores, that the compositional variation is not controlled by grain size or depositional environment. Summary The four vertical sections described above each contain a definite zonation of petrologic assemblages. Each of these presents essentially the same record—-an upward succession of material produced at increasing depth in the crust. Two cores contain a complete sequence from the sedimentary— volcanic assemblage through the background (volcanic and metamorphic) assemblage, and into the K-feldspar low- medium metamorphic and plutonic assemblages. (The other two sections lack the sedimentary-volcanic assemblage at the base; this may be due to destruction of these relatively soft fragments by a barrier-beach depositional environment, or by weathering and diagenesis.) Thus the record indicates, to a first approximation, progressive denudation of a source terrane rather than erosion of a compositionally heterogeneous uplift. 42 Composition at Other Sample Locations The remaining core and outcrop locations each show little vertical compositional variation. One of these, a core, encompasses the same stratigraphic interval as those previously described, and provides evidence of lateral changes in compositional facies. The outcrop samples occupy a stratigraphically higher portion of the section, and are compositionally different from any of the core samples. Big Ugly This section is contained in an 850 foot core (Figures 9a and 9b). The entire section is in the metamorphic- plutonic assemblage which contains perthites and non- perthitic microcline; in that respect it resembles the upper portions of the Bear Wallow, Welch, and Ameagle- Kopperston Mtn. sections. The perthites here are usually of the exsolution type, in contrast to the replacement type which is most abundant in the Bear Wallow samples. Charleston These are outcrop samples, taken over a small area but with little vertical control. The assemblage here is the biotite—rich, non—perthitic K—feldspar assemblage attributed to the erosion of a largely medium grade meta- morphic terrane. These samples also contain large, coarse- grained micaceous aggregates of chlorite, biotite and musco- vite. Some samples collected in this area by other workers contain small amounts of microcline, which characterizes the low-medium metamorphic assemblage; so it appears that 43 BIG UGLY Perthite Plagioclase 500 Microcline Figure 9a.-—Big Ugly: distribution of feldspar varieties. Depths in core and positions of samples illustrated as in Figure 5a; lithologic legend (incomplete) as in Figure 6a. 44 BIG UGLY Grain Size Quartz Deviations 3 2 1 0 1C) (I it) 0 + 0 + o + 0 + 0 + Q .Q — t 0 0 + + Figure 9b.—-Big Ugly: variation of grain size and quartz content with depth. Grain size is in phi units; quartz deviations are based on least squares regression line shown in Appendix A, Figure A3. 45 the Charleston area marks a transition between the meta— morphic and plutonic zones and the uppermost medium meta- morphic..migmatitic zone. Mt. Alto These outcrop samples contain the same biotite-rich K-feldspar assemblage as in the Charleston samples, but biotite is more abundant. (The increase in the amount of biotite relative to the other micas through the sample array is shown in Appendix A, Figure A4.) Variation Through the Sample Array The distribution of the petrologic assemblages through the sedimentary volume can be portrayed on a regional cross-section, drawn by projecting all sample locations into the AA' plane of Figure 1a. This section, which is shown in Figure 10, shows the sample locations and the distri- bution of the petrologic assemblages discussed above. The most prominant feature on the cross-section is a large wedge of plutonic and low-medium metamorphic detritus which includes major portions of the Bear Wallow, Welch, and Big Ugly cores, and pinches out northwards. Below this wedge is a zone of sedimentary, volcanic and metamorphic detritus, which becomes more K-rich in the Erbacon core. Above the plutonic material, at Charleston and Mt. Alto, the medium grade metamorphic and migmatitic assemblage occurs. Thus the large scale compositional pattern reflects 46 .mpcosfioom oaoflm Hsoo sflcfiwsfl> pmoz no coepscom HmQOHpHmomEoonr.oH ossman o.:ao.e>::aacei.ion HHH 0.83.0506! Situatioaii (a 0.C°ufl—‘ .. n 0:22:22 .. ( 02:35:02 Ease! )\ IolletI-I I IIIYIII‘IIIIII II IIIIIIII III I\( ().\ III II I\t( III. I It (1‘ II(I\II\I ‘1‘ (I I‘ I‘l.\ (I l I\ I.“ I It III II\ I It It |( tlx I( I II I\ I II II\ I .f I).\‘ 1‘ I It I! I! )\ II I II I I I I II ..I\ I\ It I\ I\ I ml. I (I. a I. i I. i i i .r i i I. )i .i .( l l .( .( 0.0.035‘ i It" )\)\ "(n(.l\nl\rl\l\)l’\’\).\l\( ,I\’\I\’\ ((i)\(tt)\ )\ (xi-I. (It/k :il. \ u. a v awn" )u‘ (8).. (I (Ii/\(t(\ ‘ \ \ h I|(|I\.ul\ I \I- I II I .l‘ .l\ I‘ It I\ nix I( \ I ((8 Iv. I \I III (((I‘..( ‘ ‘ \ ‘ \ ‘ (.(I‘ \c l I). .I I ) It i I ix ‘ \ h (z, |l It .1. It). ’ il‘ (I )\ \ \ \I\ |( I I )\ .l l. ’ I\ if ). K . |/.\ 2 )\ (It It I1 l I)\ 2 \/\ \/\ \/\ 2 (J\ (I I )\ I \I/\ I 2‘ |( \/\ )|\ |( I/\ a \II \/\ )\ I/\ \I/\ )I\ I/\ )r\ \/.\ )|\ )\ i/\ \I/u\ \l’\ \( ).\ Il‘ )\ ).\ )\ ).\ \II \I/ |( l/\ ’\ III\ )I\ )\ ).\ ).\ )I\ \I/r\ \’ )\ )\ )I \I‘ ) II\ I )u\ )\ \I/i\ Z )I )t )u‘ I." 2 2 \( \/\ \/\ z \I( \( .I/\ )\ 2 I( 2 ).\ II\ 2 )I\ \/|\ \I/\ )I\ 2 )\ \l\ 2 \l/\ )\ 02¢ a! )I\ )I \l‘ \ a a u I '3— I e . o a a I l I I i e I V I I C“: I I l r I I . counseooox . . . I t . . \()\\)I\\I/\ 222) 2(8\( ((88 ’0...’ 50.0 47 the variation, through time, in material supplied by the source terrane; this variation is also apparent in indivi- dual core sections. The Charleston and Mt. Alto samples demonstrate the influx, at a still later time, of material derived from a higher-grade metamorphic terrane. INTERPRETATION OF COMPOSITIONAL VARIATION The data presented thus far have demonstrated the presence of metamorphic rocks, unmetamorphosed sediments, and intrusive and extrusive magmatic rocks in the source terrane of the West Virginia Carboniferous sediments. It has also been shown that the distinctive petrologic assem- blages resulting from the erosion of these different rock types have been preserved in the large scale compositional variation in the resulting sediments. Perhaps the most simple conclusion is that, if this pattern were inverted, the vertical and lateral composi- tional variations would mirror those of the source terrane. That is, the sediment compositional pattern is a result of progressive denudation of a source terrane in which the major rock types occur in a vertical sequence. However, the possible effects of uplift, erosion, and depositional processes must be taken into consideration. In order to arrive at some acceptable models for the tectonic and depositional history of the area, a wide range of source terrane—erosion—deposition interactions was systematically evaluated. There are a number of combina— tions of source terrane geometries with drainage and depositional histories which could produce a compositional 1+8 49 zonation in the resulting sediments. However, many of these zonations would be inconsistent with that observed in the West Virginia sediments; models which produce such patterns may be discarded forthwith. In addition, some of those which produce acceptable compositional zonations are unrealistic in terms of their source terrane geometry and their tectonic, drainage, and depositional history. Drainage and Deposition The drainage and depositional patterns through time are classified here into two general categories, constant and variable. "Constant” patterns are those in which drain- age is established and maintained in more or less the same position through time. Although there will be some migration of depositional centers, particularly of deltaic lobes, this will not be on a scale large enough to produce the regional sediment compositional patterns. Under this type of system, the sediment compositional pattern will be, in inverted order, the same pattern as in that portion of the source terrane which is immediately upstream. "Variable" drainage and depositional patterns are those in which major shifts in drainage patterns or deposi- tional centers occur through time. These would be of such magnitude, for example, that rock types occurring in vertical sequence in the source would be deposited as lateral equivalents in the sediments. SO Source Terranes These two basic types of drainage—depositional histories can act upon a number of source terrane geome- tries, of which four general types are considered here (Figure ll). The first two types (A and B) involve a single primary uplift of the source terrane. The latter two (C and D) are more complex, and require several episodes of uplift, erosion, and rejuvenation. The two models of Class A have the major rock types restricted to generally horizontal layers. The sedimentary- volcanic cover occurs at the surface, and is underlain by low to medium grade metamorphics, which rest upon the zone of magmatic emplacement. This source terrane model is similar to that proposed by Hamilton and Myers (1967) for the Boulder batholith in particular, and for other batho— liths in general. The only difference between models A-l and A—2 is the lateral extent of the magmatic zone; that is, A—l represents uplift of the central portion of the batho— lith, whereas A-2 represents uplift of the marginal portion. The compositional geometries shown by these models could also be produced by a more complex history involving uplift, erosion of material down to the low-medium metamor- phic zone, and deposition of sediment on the eroded surface. Such a model would also require some volcanism associated with the second uplift to account for the asso- ciation of volcanic detritus, in the sediments, with sedi- mentary fragments. 51 Sou rco Terran. Models Figure ll.--Possible source terrane models. Lithologic legend as in Figure 10. 52 The B model presents the major rock types in the same sequence as the A models, except that the sequence is lateral rather than vertical. This model could be formed by doming and partial erosion of the sort of batholithic terrane shown in model A—l. The C model involves successive uplifts of small terranes consisting of the major rock types. This model is somewhat similar in appearance to the B model in that the greatest variation in rock type is lateral rather than vertical; however, the history of uplift is more complex. The D model is also a possible derivative of the A-l model; the terrane has undergone an episode of uplift and erosion, followed by deposition of the sedimentary cover (unconformably) on the old erosional surface. Discussion of Models Figure 12 illustrates potential combinations of these source terranes and drainage patterns. The sediment compo- sitional zonations resulting from these combinations are also shown; those which are inconsistent with the observed compositional zonation are rejected as unacceptable. The five models which remain are acceptable to a first approxi- mation; these are illustrated, in time sequence, in Figure 13. However, consideration of these models in more detail allows further reduction in the number of acceptable possibilities. 53 Drainage-Deposition Models Constant Variable llnaccentanle ”BENIN A-1 A ~~ Axgxnxtl’rx ~ ~ A‘2 * m A A A. I. “ i Y t * X. K ~ ~ ~ x i x x A 3 ~m~~~~~~ -~~~~~A "J‘Jtl 0 '0 ° unaccenlanlu Incanlanla E r 0 :1 B N h h 3 ° “MW"HMB 0 LI :3 “w ‘x O C N ”0' x x m ~~~ x x A~ ~~~lx¥ ~~ (at! IV D N ~ ~ A. I» g: 1‘} I ~ ~ ~ [It A y (\- ‘\ Figure l2.-—Possible combinations of source terrane models with drainage—deposition models, and resultant sediment compositional zonation. Class A 54 Since both of these models are variants of the same batholithic source terrane model, the major point of diff- erence between them is their drainage-depositional history. Model A—l requires some in order to concentrate southern portion of the has a constant drainage depositional history of shifting of the depositional centers the magmatic detritus into the sediment volume, whereas model A-2 pattern. The knowledge of the these sediments is not detailed enough at present to choose between these two models; thus we must regard both as equally acceptable. It would probably not be possible to determine whether these terranes had been previously uplifted and eroded. Since the postulated erosional depth in the previous episode is only through the original sedimentary cover, material produced by this erosion would not be distinctive enough to detect in the Class B sedimentary record. This model requires a series of rather drastic changes of the drainage and depositional patterns to pro- duce the sedimentary compositional zonation. This appears almost too fortuitous to be acceptable. The drainage-depositional pattern proposed by this model requires deposition of a considerable volume of sediment laterally equivalent to the volume of sediment considered here. If subsidence were uniform throughout the basin, then we would expect to find these lateral 55 .pmowQSoz we >H oSHB mpmooao mfl H mafia .msflp gmsosnp H|< Hobo: wo onEmoao>oQII.wma masmfim 56 .oEHp . smsos Sp m |< am 60: mo onSQOH o>oml {pma m sswa .m 57 .maflp gwsossp m Hoooz no pso8moao>omuu.oma osswflm 58 equivalents to be equally thick, coarse-grained, and dirty; however, the sediments of the basin thin to the north and south, so the required volume of sediment is not present. This implies that the model is simply incorrect, or that subsidence was not uniform throughout the basin. In the latter case, sediment not deposited directly into the basin would be bypassed and carried farther from the source. This model would also imply--if it forms by doming of a batholithic terrane—~some prior erosion which exposed the present surface. The eroded material would contain debris of all the major rock types. However, the sediments (Missi- ssippian) which contain this detritus are rather fine— grained, with some limestones. Therefore the initial stages of uplift (if the model is correct) would have been rather slow; the original character of the metamorphic and magmatic detritus would have been obscured by time spent in the soil profile, in transport, or in the depositional environment before burial. Class C This model involves the uplift and erosion of several source terranes, in succession, to produce the sedimentary compositional pattern. The principal objection to this model is that sediments were apparently dispersed radially outward from a small terrane (Ferm, 1971) perhaps only 100 miles across; this is comparable in size to many of the smallest active uplifts today. Thus it seems unlikely that four such distinct uplifts would occur in such a small area. 59 .oaap chOMSp o Hobo: no pCoEmoaobomln.©ma osswfim 60 Class D This model requires a complex tectonic history and a variable drainage—depositional history. As discussed above, the A-l and A—2 models could also have had such a tectonic history, but their drainage—depositional histories would be simpler. As with the A models, the evidence is not suffi- cient at present to determine whether or not the proposed depositional history is acceptable. If this terrane had been previously uplifted and eroded, there should be some evidence in the older Paleozoic (or Precambrian) sedimentary record, since magmatic and metamorphic detritus would have been eroded. Thus this aspect of this model may be tested as the petrology of these older sediments is known in more detail. This model would also imply, as does model B, some bypassing of sediment through the basin, and its deposition farther from the source. It seems unlikely that this bypassing would selectively remove some detrital components, whilst leaving others behind to produce the compositional zonation. Summary Of the ten original models proposed in Figure 12, five were rejected immediately because the sediment compo- sitional zonation they produced was inconsistent with that observed in the Pocahontas sediments. However, the sequence of events required to produce the five acceptable patterns 61 .osflp swsongp m Hoooz mo psoegoam>omuu.oma osswflm 62 is not equally likely in all five cases. Three of the five models represent source terranes which are similar to the batholith model of Hamilton and Myers (1967). Two of these (A—1 and A—2) are vertically stratified; the other (B) is laterally stratified. The two remaining models involve the rejuvenation of a previously uplifted terrane (Model D) or a sequence of small uplifts in various portions of a compositionally heterogeneous terrane (Model C). The latter two models are considered to be unlikely. The distinct uplift model (C) appears to involve too much localized tectonic activity for a source terrane of the size postulated. Model D, which involves erosion through an unconformable sedimentary cover into metamorphic and magmatic material, could only be accepted if we assume bypassing of some of the eroded material through the basin. However, since the compositional zonation is based on the presence or absence of detrital components, rather than their relative abundance, it would seem fortuitous that the bypassing could be so efficient as to "censor” the deposi- tional record and thus produce the observed zonation. Of the batholithic models, Model B is also acceptable only if the bypassing mechanism is sufficient to create the compositional zones. Thus it, too, seems an unlikely possibility. Therefore, on the basis of these arguments, the author inclines toward a source terrane based on some 63 variant of the Hamilton and Myers batholithic model. If the batholithic model is correct, then at least one region of the Piedmont, which was previously tectonically stable, underwent a major episode of uplift shortly before and during the Carboniferous. Emplacement of magmatic material may have been associated with this tectonic event, or may have occurred earlier. Hamilton and Myers (1967) suggest that many batholiths are emplaced in connection with tectonic activity, and are eroded during the same tectonic episode. Portions of the Piedmont do contain mag- matic material which was formed at about this time (Fulla~ gar, 1971); hence the association of magmatic emplacement with this Carboniferous uplift is a possibility. Although the Piedmont contains magmatic intrusions of several ages, it may not be possible to find the speci- fic terrane which contributed to the Pocahontas sediments. The sediment composition variation apparently reflects erosional removal of a batholithic terrane, so the only remnants of this terrane may be sub—batholithic metamor- phic material. No doubt a major portion of the information regarding the development of the Piedmont cannot be found in the Piedmont itself, but must be extracted from the sedimentary record. LOCATION OF SOURCE TERRANE Analysis of sediment dispersal patterns (Ferm, 1971) has suggested location of the source terrane in Virginia or North Carolina, with sediments being shed radially northwest, west, and southwest. The extent of the source terrane, as measured along the present Appalachian trend, was probably less than 150 miles. Thus the terrane was either a small, ovoid terrane like the Black Hills, or was simply the western end of a linear trend such as the Ouachitas. The coincidence of the Cape Fear arch with the postulated location of the source terrane suggests that it may be a remnant of a linear terrane. The Appalachian folds bend in this region, with their trend changing from northeast in Alabama and Tennessee to nearly north in Virginia and West Virginia. This could be due to inter— ference during folding from a large, roughly east—west linear structure. Thus, the evidence suggests a linear structure nearly perpendicular to the present continental margin. If this is true, then it should be possible to find the equivalent "matching” Carboniferous structure in Europe or North Africa; such investigations, in turn, should lead to a reconstruction of the pre—drift tectonic 6A 65 pattern of Pangaea. Comparison of the Pocahontas sediments with those of the Black Warrior basin permits a more precise estimation of the location of the source terrane. In the Black Warrior sediments, the location of the source, and the variation in quartz content (corrected for grain size) with distance from the source, are known. The fluvial sediments (of the equi— valent low-medium metamorphic assemblage) at Bear Wallow are equivalent in quartz content to those about 100 miles from the source in the Black Warrior; thus the nearest portion of the Pocahontas source terrane was about this distance from Bear Wallow. This would place the westernmost end of this linear structure in south-central Virginia, just east of the North Carolina—Tennessee border. LATE PALEOZOIC CRUSTAL DYNAMICS The petrologic and tectonic character of a small portion of the late Paleozoic crust in eastern North Amer— ica has been described. These results, when combined with those of other workers in the region, permit a general re- construction of the eastern continental margin during this time. This reconstruction is based on two major lines of evidence: the locations of source terranes which were active at that time, and their petrologic character. Locations of Source Terranes The source terrane of the West Virginia Carbonifer— ous sediments was a linear terrane in the Virginia-North Carolina region, oriented perpendicular to the present continental margin. Another major Carboniferous detrital basin in the southeastern United States is the Black Warrior basin of Alabama and Mississippi. Ehrlich (1964) demonstrated, on the basis of sediment composition variation within the barrier beach facies, that the source of these sediments lay to the south, and was part of the Ouachita structural trend. Thus, this source was a linear, roughly east-west structure, definitely pre-dating any tectonic activity 66 Ill v, [A 67 along Appalachian trends in this region. A similar east-west structure may have existed in the Pennsylvania—New Jersey-New York area, supplying sediment to the anthracite coal basin. Aside from the sedimentolo- gical evidence for a source terrane, the Appalachian structures are strongly curved in this region (as they are in the area of the West Virginia source terrane); and there is some geophysical evidence (Drake, et al., 1963) for an east—west fault zone in the area of the proposed source structure. Petrology of Source Terranes The sediments of the Black Warrior basin (Davis and Ehrlich, 1972) contain abundant volcanic and low grade metamorphic fragments, but lack the suite of abundant pla- gioclase and K—feldspar so common in the West Virginia sediments. Either the source terrane for these sediments did not contain much intrusive magmatic material, or erosion never out deeply enough into the terrane to expose magmatic material. In either case, the presence of volcanic and low grade metamorphic material implies that this terrane, like that of the West Virginia sediments, was newly uplifted in the late Paleozoic. Preliminary work in the anthracite basin sediments shows the presence of volcanic and metamorphic fragments and a variety of feldspars. It thus appears that the terrane for these sediments was also a newly activated 68 uplift during the Carboniferous. Paleotectonics The paleogeography of the southeastern United States in Carboniferous time is shown on Figure 14. This pattern is only one of a set of tectonic patterns which existed through the Paleozoic; the distribution of Devonian high- lands and basins, for example, is rather different. Thus the Paleozoic tectonic history of this portion of the continent is really a mosaic of short-lived, localized uplifts. The occurrence of rifting during the late Paleozoic or early Mesozoic suggests that the tectonic pattern of the Carboniferous (and perhaps earlier periods) may have been directly related to the rifting process. In that case, understanding these tectonic events should clarify our understanding of the rifting of continents. 69 LEGEND " Uplift z Sediment Transport Direct ion Figure 14.-—Late Paleozoic tectonic patterns of the southeastern United States. CONCLUSIONS The Carboniferous sediments of the West Virginia coal field region were derived from a small source terrane in the Virginia-North Carolina area. The range of detrital components present in these sediments indicates that rock types present in the source included sediments, volcanics, shallow intrusives, and low and medium grade metamorphics. The distinct vertical compositional zonation of these sediments suggests progressive denudation of a single source terrane, rather than simultaneous erosion of several terranes with differing lithologies; thus these sediments were produced by erosion following a major tectonic event. On the whole, the large scale horizontal and vertical variations in sediment composition reflect a complex response to the composition and geometry of the source terrane, and the history of erosion, transport, and depo— sition. Although the data are not precise enough to pro- duce a unique genetic solution, only a few models are acceptable. All of these must include a relatively thin zone of plutonic material, since the plutonic detritus in the sediments is bounded both vertically and laterally by metamorphic detritus; this conclusion supports the model proposed by Hamilton and Myers (1967) for batholiths as 70 71 thin crustal features. The presence of plutonic and metamorphic material in the present—day Blue Ridge and Piedmont suggests that some remnants of this source terrane might still be preserved. However, the fact that these rock types are now exposed at the earth's surface means that considerable erosion of more shallow crustal material has taken place; the only evidence for the nature of this material lies in the eroded sedi- ments. Stratigraphic and petrologic analysis of sediments derived from other Carboniferous source terranes in east- ern North America indicates the presence of at least three major source terranes: one for the anthracite coal basin, the one discussed in this paper, and one for the Black Warrior basin. These were roughly linear, and oriented perpendicular to the present Appalachian trend. Each of these terranes contained metamorphic and magmatic material formed at shallow levels of the crust, and represented a primary episode of tectonic activity. Similar types of analysis in Europe and northern Africa should prove valuable in locating any correspond— ing matching terranes in those continents. Although these structures, and many other Paleozoic source terranes, may have been obscured or partially destroyed by subsequent tectonic activity, their presence should be recorded in the sediments derived from them. Thus the approach outlined in this study may be applied to the analysis of other terranes, 72 and should ultimately lead to a detailed reconstruction of the Paleozoic tectonic history of Pangaea. LIST OF REFERENCES LIST OF REFERENCES Allen, J. R. L. and Friend, P. F. Deposition of the Catskill facies, Appalachian region: with notes on some other Old Red Sandstone basins: Geological Society of America Special Paper 106, p. 21-74, 1968. Bailey, E. M. and Stevens, R. E. Selective staining of K-feldspar and plagioclase on rock slabs and thin sections: American Mineralogist, Vol. 45, p. 1020- 1025, 1960. Blatt, H. Original characteristics of clastic quartz grains: Journal of Sedimentary Petrology, Vol. 37, p. 401-424, 1967. Borg, I. Y. and Smith, D. K. Calculated powder patterns: I. Five plagioclases: American Mineralogist, Vol. 53, p. 1709-1723, 1968. Cannon, R. T. Plagioclase zoning and twinning in relation to the metamorphic history of some amphibolites and granulites: American Journal of Science, Vol. 264, p. 526-542, 1966. Davis, M. W. and Ehrlich, R. Late Paleozoic crustal compo— sition and dynamics in the southeastern United States: Geological Society of America Special Paper, in press, 1972. Dickinson, W. R. Interpreting detrital modes of graywacke and arkose: Journal of Sedimentary Petrology, Vol. 40, pr 695-707: 1970' Drake, C. L., Heirtzler, J. and Hirshman, J. Magnetic anomalies off eastern North America: Journal of Geophysical Research, Vol. 68, p. 5259—5275, 1963. 73 74 Ehrlich, H. Evidence on relative ages of the Appalachian and Ouachita structural trends: Geological Society of America Special Paper 82, p. 299, 1964. Ehrlich, R. Quartz content-grain size relationship and location of source terrane: American Association of Pegroleum Geologists Bulletin, Vol. 49, Pt. 1, p. 399, 19 5. Emmons, R. C. The universal stage: Geological Society of America Memoir 8, 205 p., 1943. Englund, K. J. Sandstone distribution patterns in the Pocahontas Formation of southwest Virginia and southern West Virginia: Geological Society of America Special Paper, in press, 1972. Ferm, J. C. Carboniferous paleogeography and continental drift: Compte Rendu 7e Congres Intern. Strat., Geol. Carbonif., Krefeld, in press, 1971. Ferm, J. C. and Cavaroc, V. V. A nonmarine sedimentary model for the Allegheny rocks of West Virginia: Geological Society of America Special Paper 106, p. 1-19, 1968. Ferm, J. 0., Horne, J. C., Swinchatt, J. P. and Whaley, P. W. Carboniferous depositional environments in northeastern Kentucky: Guidebook for annual spring field conference, Geological Society of Kentucky, 1971. Fullagar, P. D. Age and origin of plutonic intrusions in the Piedmont of the southeastern Appalachians: Geolo ical Society of America Bulletin, Vol. 82, p. 28 5—2862, 1971. Gorai, M. Petrological studies on plagioclase twins: American Mineralogist, Vol. 36, p. 884-901, 1951. Hamilton, W. and Myers, W. B. The nature of batholiths: United States Geological Survey Professional Paper 554-0, 30 p., 1967. Hietanen, A. On the petrology of Finnish quartzites: Government Press, Helsinki, 1938. Higazy, R. A. Petrogenesis of perthite pegmatites in the Black Hills, South Dakota: Journal of Geology, Vol. 57, p. 555-581, 1949- 75 Hogan, L. M., Kraft, R. W. and Lemkey, F. D. Eutectic grains: in_Advances in Materials Research, Vol. 5, Wiley-Interscience, 499 p., 1971. Hutchinson, R. M. Structure and petrology of Enchanted Rock batholith, Llano and Gillespie Counties, Texas: Geological Society of America Bulletin, Vol. 67, p. 763—806, 1956. Pittman, E. D. Destruction of plagioclase twins by stream transport: Journal of Sedimentary Petrology, Vol. 39, p. 1432—1437, 1969. Robertson, F. Perthite formed by reorganization of albite from plagioclase during potash feldspar metasomatism: American Mineralogist, Vol. 44, p. 603—619, 1959. Turner, F. J. Observations on twin laws commonly exhibited by plagioclase in metamorphic rocks: American Mineralo— gist, V01. 36, p. 581—589, 1951. Tuttle, O. F. Origin of the contrasting mineralogy of extrusive and plutonic salic rocks: Journal of Geology, V01. 60, p. 106-124, 1952. Vance, J. A. Polysynthetic twinning in plagioclase: American Mineralogist, Vol. 46, p. 1097—1110, ,961. Vance, J. A. Zoning in igneous plagioclase: Journal of Geology, Vol. 73, p. 636-651, 1965. White, I. C. West Virginia Geological Survey, Volume II, 1903. Winkler, H. G. F. Petrogenesis of metamorphic rocks: Springer-Verlag New York, Inc., 237 p., 1967. Wright, T. L. and Stewart, D. B. X-ray and optical study of alkali feldspar: Parts I and II: American Mineralo— gist, v61. 53, p. 38-104, 1968. APPENDIX A APPENDIX A Graphs and Data Tables 77 1M IIHII WIlllHl O a .0 F a: I L. I H I 2 z . - .3 . ..II I&— ° . 0 ~ 2 N : I ‘ = ear ‘3' _. “'-‘ x=185 ¢ ' 7:671 =: I>=:#12 4 r'-'.72 a 2 1 liralll Slze, I Figure A1.——Bear Wallow: least squares regression relation between quartz + feldspar content and grain size. Core #1 shown by circles; core #2 shown by squares. a a [MIMI a a O C . O I a .. ?" ea» 0 L. . II a . . I " r~ '- I z . u. 0U :3 ‘- I I . N .o 2." - O : a “a i: 1.52 ¢ 7:721. 2 b=-15.9 r-.78 3 2 1 train SlzeJ Figure A2.--Erbacon: least squares regression relation between quartz + feldspar content and grain size. 79 e :2 [Hi lllill e 63 = S 6° : g: a a I I a a . u f‘ E . ' lb on = O N ‘9 . Z a O = = O a - “’ x=1.65¢ 7: 68 'I. a: b== -9.6€5 " .78 H II 3 2 l liraln sun, I Figure A3.--Big Ugly: least squares regression relation between quartz + feldspar content and grain size. 80 .Azoaaoz seem 809% oocmpmflo Hooflnmosmoow we commosmxov moflosn oamsm soosw one nos o>ono ooqppmflo ofismphwfipmnpm one Coflpflmomsoo some newspop coepmaomui.:< onsmflm Io:!.30..I3 boom So: oocouaa our om cc 0 0V ennoosnw + ONIONS + Oillolfl OS' Oiliolfl 07' 09' 81 Table Ala.-—Bear Wallow #1: grain size and composition data. EEEEIE. §l§2. 222322. Femspar 922212. 3156 .82 67 22 11 3158 1.58 60 10 30 3159 1.65 65 5 3O 3160a 1.55 74 6 2o 3160b 1.99 73 4 23 3161a 2.05 59 3 38 3161b 2.51 62 2 36 3162 1.76 64 3 33 3163 1.39 63 2 35 3164a 2.56 52 3 45 3164b 2.62 65 O 35 3165 2.51 67 5 28 3166 2.36 62 1 37 82 Table Alb.--Bear Wallow #2: grain size and composition data. 222222. §222. 922222 Feldspar 922222. 3167a 1.63 66 11 23 3167b 1.78 59 13 28 3168a 1.34 60 13 27 3168b 1.58 68 12 20 3169 1.48 59 6 35 3170 1.11 66 1 33 3171 1.72 74 1 25 3172 2.52 45 1 54 3173 1.34 60 6 34 3174 3.20 45 0 55 3175 3.10 44 2 54 3176 1.38 64 3 33 3177 1.53 63 4 33 3178 1.51 77 2 21 3179 1.30 64 2 34 83 Table A2.-—Erbacon: grain size and composition data. Sampl§_ s1§§_ Quartz Feldspar Others E-13-6 .90 8o 4 16 E-13—5 1.28 67 4 29 E—l3—4 1.32 73 5 22 E-13-2 1.39 7O 5 25 E-11-6 2.08 68 0 32 E-ll-4 1.37 82 2 16 E-ll-3 1.08 73 3 24 E-lO-l 1.14 76 0 24 E- 9—1 1.92 48 6 46 E- 8-2 2.55 54 5 41 r- 7-2 1.71 52 5 43 E- 7-1 1.60 56 2 42 r- 6-3 1.62 61 5 34 E- 6-2' 1.57 73 0 27 r- 6-2 1.41 70 2 28 M- 6—1 1.76 59 1 40 E— 5-1 1.16 82 1 17 E- 4—3 2.89 59 0 41 E— 4—1 1.20 78 0 22 E- 3-1 1.03 81 1 18 E- 2-2 1.39 78 0 22 E- 1—2 1.98 66 o 34 E— l-Ia 1.19 84 1 15 E- l-lb .71 89 0 11 84 Table A3.--Big Ugly: grain size and composition data. Sample Size 822322. Feldspar Others CH—7-2 .84 73 5 22 CH—7—l 1.08 66 2 32 CH-6-3 1.03 79 5 16 CH—6-2 .96 76 3 21 CH-6-l 1.49 72 0 28 CH-5-2 1.70 67 5 28 CH—5—l 1.49 59 8 33 CH-4—3 1.10 64 11 25 CH-4-2 1.07 54 7 39 CH-4-l 1.45 60 11 29 CH—3—3 2.43 57 3 40 CH-3-2 2.76 48 4 48 CH—3—1 1.86 58 2 40 CH-2—3 .96 75 5 20 CH-2—2 1.64 62 8 30 CH-2-l 3.90 54 0 44 CH-l—l 2.22 51 3 46 APPENDIX B APPENDIX B Sample Locations Cores The cores described in this study were generously supplied by several coal and gas firms in the coal field region. Some of these cores were drilled during explora- tion programs which are still in progress, so I do not feel at liberty to reveal their precise locations. The towns of Bear Wallow, Erbacon, Ameagle, and Welch are located near the core sites, and may be found on most road maps of West Virginia and Virginia. The Big Ugly core was named for the Big Ugly Public Hunting Area, which is located near the town of Leets, West Virginia. Outcrops Bear Wallow. Outcrop samples were taken from several locations. Samples identified as ”Jacob's Fork” were collected along Virginia Route 16, between the towns of Bishop and Jacob's Fork. Samples identified as ”Pocahontas” were taken from outcrops along Virginia Route 644, between Pocahontas, Virginia and Bramwell, West Virginia. Samples identified as ”Princeton” were collected on Interstate 77 south of Princeton, West Virginia. 86 nggh, Outcrop samples associated with the Welch core are named as ”Sewell”, after the coal of that name which is stripped from the hilltops near Welch. They were collected along West Virginia Route 16, from the top of Indian Ridge down to the junction of that road with U. S. 3oute 52, and along Route 52 down into the town of Welch. Kopperston Mtn. These samples were collected along West Virginia Route 85, on the high ridge above the town of Kopperston. Charleston. There are three localities represented in this set of samples. Location I is north of Charleston, on a short spur road which links the south end of Interstate 77 with U. S. Route 21. Location II was a graded hillside (now overgrown) on West Virginia Route 62 between Cross Lanes and Rock Branch. Location 111 is on Interstate 64, between the Nitro and Institute exits. Mt. Alto. These samples were collected along West Virginia Route 2, between the towns of Mt. Alto and Millwood. 11.17.171.11. . .....;..........;1 1.1 1 _ 1 -.....C....I . ..3. ... . 1 . f ...snbrm...ul.ww.ucvkfl AA: .. .1. ..2........1..=...§......2. 1. 3: b2... ... r . p . .1 1 . 1 . 1 . S 1 1 1 E .1 R , o . . 1. A .1 R . 1. mu . a L . .1 v 1 .1 .H . m S . 1 R 1 5' , 1 v. _ 1 1 N . I _ 1 U20 . . . . El 1 . 1 . . 1 W I. . 3 . w 1 . A'9 . . . . _ .1 .l 1 . ... 1 a l 1.3 . 1 . t 1J1 . . u. ‘ 1 . 1 . m. . 1 1 1. . .1 1 . . a. 1 1 v . 1 . . . A 1 . . y. . 1 . . . . . . 1 1 .1 . I . \.... 1.1:.“ .21.... ... . 1» :1. 1 .mxmu.n‘m..,r.