consoumnon BEHAVIOR V * . or . , V ‘ HIGH ASH PULP. AND PAPERMILLF’V SLUDGES * Thesis for the Degree of Ph.fD.’ 7 MiCHiGAN STATE UNIVERSITY JOHN MATHEW F’ALOORTHEKKATHIL 19??! 0-...- ‘ _-—..' . LIBRARY Michigan State University This is to certify that the thesis entitled CONSOLIDATION BEHAVIOR OF HIGH ASH PULP AND PAPERMILL SLUDGES presented by John Mathew Paloorthekkathil has been accepted towards fulfillment of the requirements for Eh.D. degreein Civil Engineering .73 . (2:) ‘ C\ «M83 I‘VLQ d «g\\ Major professor Date V‘LQ“ 2343\.\’Z‘ 0-7639 ABSTRACT CONSOLIDATION BEHAVIOR OF HIGH ASH PULP AND PAPER MILL SLUDGES By John Mathew Paloorthekkathil Dev010pment of design methods for efficient and safe disposal of dewatered high ash pulp and papermill sludges in land fills requires in- formation on stress-strain—time relationships which can be used to pre- dict volume change and time rate of settlement in these materials. A study to investigate the consolidation behavior of these materials was made on one integrated pulp and papermill sludge and on two dif- ferent secondary papermill sludges. Different series of one-dimen- sional compression tests, either conventional or using back pressures, were run to study the influence of load history, initial solids content, degree of saturation, varied organic contents, admixtures of lime or fly ash, and temperature. Studies for the influence of the variables were conducted on secon- dary fibrernlll sludges. The organic content of the sludge was altered by washing the sludge material through a U.S. Standard No. If) sieve and recombining in selected proportions the retained material with the material passing the sieve. Samples with different initial solid contents John Mathew Paloorthekkathil were obtained by centrifuging the same sludge for different lengths of time. Back pressure, which could dissolve air trapped in the sludge, provided a means of considering the influence of degree of saturation. Combination of one secondary fibre mill sludge with lime or fly ash gave test samples which provided data on the influence of these admixtures on consolidation behavior. Influence of temperature was studied by running three tests at closely controlled temperatures of 380C, 220C and ()OC. Test results are discussed separately for the influence of each vari- able, but conclusions regarding the sludge behavior are presented in terms of (l) Pressure-Void Ratio Relationships (2) Time-Rate of Con- solidation and (3) Secondary Compression. l. The load increment ratio appears to have no influence on the void- ratio—log pressure relationships. The compression index shows a linear decrease with increase in initial solids content. With in- crease in organic content the compression index increases. This may be due to the compressibility of the organic particles in the sludge. Increase in temperature will decrease the equillibrium void ratio with no change in compression index. 2. Time rate of consolidation decreased with small load increment ratios, higher initial solids content, smaller organic contents and lower temperatures. Lime or fly ash admixtures increased the co- efficient of consolidation. Experimental excess pore-pressure John Mathew Paloorthekkathil dessipation curves suggest that severe limitations are imposed on the Terzaghi consolidation theory for prediction of settlement rates in sludge land fills. The peculiar shape of the compression curves at low load-increment ratios and high organic contents makes it difficult to apply conventional curve fitting methods. The rate of Secondary Compression per unit of pressure increased rapidly with decrease in load increment ratio and increased with higher temperatures. Higher initial solids content, smaller load increment ratios, larger organic contents, and warmer temperatures all contributed to more secondary compression. In summary, high ash pulp and papermill sludges are highly com- pressible and the consolidation behavior varies with composition, water content, field drainage conditions, loading rates and any admixtures. Careful consolidation tests which duplicate the particular field conditions are needed for accurate prediction of settlement in sludge land fills. Approved Major Professor Approved Department Chairman CONSOLIDATION BEHAVIOR OF HIGH ASH PULP AND PAPERMILL. SLUDGES By John Mathew Paloorthekkathil A THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of DOCTOR OF PHI LOSOPH Y Department of Civil Engineering 1972 ”x. <.. “s \ ~— 5;. DEDICATION To my loving mother A. ANNAMMA ii ACKNOWLEDGMENTS The writer wishes to express his sincere appreciation and gratitude to Dr. 0. B. Andersland under whose direction this research was per- formed, for his guidance, patience and encouragement. To the other members of the guidance committee: Dr. W. A. Bradley, Dr. R. R. Goughnour and Dr. M. M. Mortland, the writer expresses his thanks for their valuable suggestions and help. Sincere appreciation is also extended to National Council of the paper industry for air and stream improvement and the Division of En— gineering Research at Michigan State University for the financial assis- tance and other support which made this research possible. Finally, the writer wishes to express his appreciation to his wife Annamma for her patience and encouragement throughout this study. iii TABLE OF CONTENTS LIST OF TABLES . LIST OF FIGURES LIST or SYMBOLS Chapter III . I. II. .— b—- O . INTR ODUCTION Background Scope of Work . CONSOLIDATION CHARACTERISTICS OF SLUDGE AS DETERMINED FROM LITERATURE REVIEW PrOperties Which Influence Sludge Compressibility . . Z. l. 1. Sludge Composition . 2.1.2. Water Content . 2.1.3. Permeability. Application of Consolidation Theory to Sludges 2. 2.1. Consolidation Theory . . . . 2. 2.1.1. Soil Compressibility . 2. 2.1. 2. Rate of Consolidation. Z. 2. 2. Deviations From Theory for Organic Soils. . . . . . . . Z. 2. 2.1. Secondary Compression 2. 2. 2. Z. Admixtures of Lime or Flyash . Laboratory Analysis . . . . 2. 3.1. Sampling and Test Procedures . Z. 3. 2. Interpretation of Results and Practical Applications. SLUDGES STUDIED AND SAMPLE PREPARATION Secondary Fiber Mtll Sludges Integrated Pulp and Paper Mill Sludge 1V Page vi xi U'Irh-vh \l ll 11 ll I4 16 18 19 20 20 21 24 24 25 (((Ill‘lll/‘I‘ Chapter IV. VI. VII. 3. 3. Sample Preparation . 3.3 1 Natural Sludges . . 3. 3. 2. Different Organic Contents 3 3 3 Combinations With Lime of Flyash. LABORATORY EQUIPMENT AND TEST PROCEDURES . . 1 Consolidation Equipment . 2 Conventional Test Procedures . 3. Pressurized Consolidation Cell. 4 Special Test Procedures . ##vbub EXPERIMENTAL RESULTS Load Increment Ratio . Initial Solids Content Degree of Saturation Organic Content . . Lime or Flyash Admixtures Temperature . UWUWUWU'IU‘lU'I omewmt—v DISCUSSION AND INTERPRETATION OF RESULTS Load Increment Ratio . Initial Solids Content. Degree of Saturation. Organic Content. . . Lime or Flyash Admixtures Temperature . C‘O‘C‘OC‘O‘ O‘U'lv-bUONv-d SUMMARY AND CONCLUSIONS 1 Pressure-Void Ratio Relationships . Z. Time-Rate of Consolidation 3 Secondary Compression . \lxlxl BIBLIOGRAPHY . APPENDICES . A. Conventional Consolidation Data. B. Back Pressure Consolidation Data. Page 25 25 2f) 26 30 3O 3O ) La 3.3 39 39 39 4O 41 41 42 67- 67 6‘) 72 73 74 98 98 99 100 102 105 126 l[([‘l[l||l LIST OF TABLES Page Physical property and test method . . . . . . . . . 27 Physical properties of the sludge materials . . . . . 28 Properties of the lime and flyash . . . . . . . . . Z9 Consolidation test results for sludge 1-1-2 with different load increment ratios . . . . . . . . . . 57 Consolidation test results for sludge H-Z with different initial solid contents . . . . . . . . . . . 59 Consolidation test results for sludges D-1 and C-2. . 60 Consolidation test results for sludges H-2 and H-3 considering different back pressures . . . . . . . . 61 Consolidation test results for sludge 1-1-3 at different organic contents . . . . . . . . . . . 63 Consolidation test results for sludge H-Z with lime or flyash admixtures . . . . . . . . . . 65 Consolidation test results for sludge H-3 at different temperatures . . . . . . . . . . . . . 66 vi LIST OF FIGURES Figure Page 2. 1 Water retention curves, sludge H-Z (after Andersland and Laza, 1971). . . . . . . . . . . . 9 2. Z Permeability versus average head of water for sludge H-Z (after Andersland and Laza, 1971) . . . . . . . 10 2. 3 Volume-void relationships. (a) Initial condition. (b) Compressed condition . . . . . . . . . . . . . 12 2. 4 Diagram illustrating consolidation of a compressible layer of clay (after Terzaghi and Peck, 1967) . . . . 15 2. 5 Typical time-settlement relationship for peat (after MacFarlane, 1969) . . . . . . . . . . . . . l7 2. 6 Method of estimating preload requirement using time- settlement curves (after MacFarlane, 1969) . . . . . 24 4.1 Fixed-ring consolidation specimen container. . . . . 31 4. 2. Consolidation test apparatus. (a) Consolidation unit (left assembled, right disassembled.) (b) Load frame with consolidation unit. . . . . . . . . . . . . . . 35 4.3 Pressurized consolidation cell . . . . . . . . . . . 36 4. 4 Pressurized consolidation test apparatus. (a) Disassembled consolidation cell. (b) Consolidation cell, pressure gauges, timer, recording unit, and hook—up accessories. . . . . . . . . . . . . . . . 37 4. 5 Pressurized consolidation test apparatus layout . . . 38 5.1 Dial reading versus logarithm of time for sludge H-Z with different load increment ratios . . . . . . . . . 43 5. Z Void ratio versus logarithm of pressure for sludge H-Z with different load increment ratios. . . . . . . . . 44 5. 3 Dial reading versus logarithm of time for sludge H-Z with different solid contents . . . . . . . . . . . . 45 vii 6. .10 .11 .12 .13 .14 Typical dial reading versus IOgarithm of time curves for sludges H-3, D—1, and C-2 . Void ratio versus logarithm of pressure for sludge H—Z with different initial solid contents. Void ratio versus logarithm of pressure for natural sludges H-3, D—1, and C—2 Dial reading versus logarithm of time for sludge H-3 with and without back pressures. Void ratio versus logarithm of pressure for sludge H-3 with and without back pressures. Dial reading versus lOgarithm of time for sludge 1-1—3 with different organic contents Void ratio versus logarithm of pressure for sludge H-3 with different organic contents Dial reading versus logarithm of time for sludge H-Z combined with lime or flyash . . . . . . . . . . Void ratio versus logarithm of pressure for sludge H-Z combined with lime or flyash . Dial reading versus logarithm of time for sludge H-3 at different temperatures Void ratio versus logarithm of pressure for sludge H-3 at different temperatures. Coefficient of consolidation versus logarithm of pressure for sludge H—Z at two load increment ratios Compression index versus load increment ratio for sludge H-Z. Coefficient of permeability versus l0garithm of pressure for sludge H-Z with different load increment ratios . Primary compression ratio versus logarithm of pressure for sludge H—Z at two load increment ratios viii 46 47 48 49 50 51 SZ 53 54 55 56 77 78 79 78 6. .10 .11 .12 .13 .14a . 14b .15a .15b .16 .17 Coefficient of secondary compression per unit pressure versus logarithm of pressure for sludge H—Z . Initial solids content versus compression index for sludges H-2 and H-3 Coefficient of consolidation versus logarithm of pressure for sludge 1-1—2 with three initial solid contents Coefficient of compressibility versus void ratio for sludge 1-1-2 with three initial solid contents Coefficient of permeability versus lOgarithm of pressure for sludge 1-1-2 with three initial solid contents Primary compression ratio versus logarithm of pressure for sludge 1-1-2 with different initial solid contents Coefficient of consolidation versus logarithm of pressure for sludge 1-1-3 with different back pressures. Coefficient of permeability versus logarithm of pressure for sludge 1-1-3 with and without back pressures Coefficient of secondary compression versus logarithm of pressure for sludge H-3 with different back pressures Experimental and theoretical excess pore pressure dissipation at the undrained surface. (a) Sludge H—3, back pressure 234. 5 psi, load increment 243 to 250 psi Experimental and theoretical excess pore pressure dissipation at the undrained surface. (b) Sludge H-Z, back pressure 70 psi, load increment 99 to 127 psi. Extrapolation of compression index to the same solid content. Organic content versus compression index for sludge H-3 Coefficient of consolidation versus logarithm of pressure for sludge H—3 with different organic contents Coefficient of permeability versus lOgarithm of pressure for sludge 1-1-3 with different organic contents ix 80 81 81 82 83 83 84 85 84 86 87 88 88 89 90 6. .19 .20 .21 .22 .23 .24 .25 .26 Primary compression ratio versus logarithm of pressure for sludge 1-1-3 with different organic contents . Coefficient of consolidation versus logarithm of pressure for sludge H—Z combined with lime or flyash Coefficient of permeability versus lOgarithm of pressure for sludge H—Z combined with lime or flyash Primary compression ratio versus logarithm of pressure for sludge 1-1-2 combined with lime or flyash Coefficient of secondary compression versus logarithm of pressure for sludge H—Z combined with lime or flyash Coefficient of consolidation versus logarithm of pressure for sludge 1-1-3 at different temperatures . . . Coefficient of permeability versus logarithm of pressure for sludge 1-1-3 at different temperatures Primary compression ratio versus logarithm of pressure for sludge H-3 at different temperatures . . Coefficient of secondary compression versus lOgarithm of pressure for sludge 1-1-3 at different temperatures . 91 9?- 93 94 94 95 96 97 97 grew ”U LIST OF SYMBOLS cross-sectional area coefficient of compressibility compression index coefficient of secondary compression coefficient of consolidation void ratio thickness of stratum except when used in connection with consolidating layer. In this event H : thickness of half-closed layer or half-thickness of open layer hydraulic head hydraulic gradient coefficient of permeability length liquid limit coefficient of volume compressibility pressure plastic limit rate of flow primary compression ratio magnitude of primary compression settlement due to secondary compression shrinkage limit time time factor excess hydrostatic pressure xi U .3>-<< ql discharge velocity depth degree of consolidation volume unit weight of water increment viscosity effective normal stres s. xii CHAPTER I INTRODUCTION 1.1. Background The pulp and paper industry annually removes an estimated 2, 500, 000 dry tons of settled solids from their effluent streams (Gilles- pie, Mazzola, and Cellman, 1970):: These removed solids give a total sludge cake volume close to 200 million cubic yards. The composition of these solids is dependent on the type of manufacturing process and internal conservation steps practiced, but in general the solids include coating and filler pigments, fibers, and fines which escape the pulp or paper making process. The manufacturers of fine paper and heavily coated board produce sludges of high ash content which require landfill disposal. Superimposed upon this primary sludge problem are large amounts of waste biological solids that can be generated in certain types of secondary treatment. Land disposal of these settled solids and high ash sludges appears to be the most feasible approach currently available. Gillespie, Mazzola, and Gellman (1970) report that in excess of 1100 acres of land are used as sludge dispositories, representing a total investment of over 800, 000 dollars in land holdings for the mills reporting in a questionnaire survey. Landfills are not necessarily an inexpensive or troublefree means of sludge disposal. High handling costs, a growing public fervor for aesthetic con- siderations in waste handling practices, and the competition for disposal sites engendered by a growing overall solid wastes disposal problem place a premium on efficient and nuisance free operations which offer soxrie land reclamation potential. The National Council of the Paper Industry for Air and Stream Improvement has launched a three-phased research approach to the problem of landfill disposal of papermill waste solids. The first phase isNames and dates shown in parentheses refer to entries made alpha- betically in the bibliography. 2 involved a questionnaire survey of current land disposal practices (Gilles- pie; Mazzola, and (‘icllmam .1970). This survey showed that while many mills practicing land disposal are experiencing difficulties, it is possible to operate such systems to the advantage of the mill and the environment. The second phase involved a core sampling investigation of existing de- posits to measure certain soil mechanics related properties (Mazzola, 1969). Many of these existing sludge deposits were shown to be very unstable, of low shear strength, contained high water contents, and under load would experience large settlements. The third phase, for which this report is a part, seeks data on the shear strength, permeability, and consolidation behavior of high ash pulp and papermill sludges. Experi- mental data, methods of analysis, and test procedures developed for the sludge will contribute to the sound design of future sludge landfill disposal systems. 1. 2. Sc0pe of Work Development of design methods for efficient and safe disposal of dewatered high ash content pulp and papermill sludges in landfills requires information on stress-strain-time relationships which can be used to pre- dict volume change and settlement in these materials. The theory of con- solidation (Terzaghi, 1943) provides a theoretical basis for the research work reported herein. Test equipment and test techniques used draw on procedures and methods described in soil mechanics literature. The research results presented include experimental data on the consolidation behavior of two sludges used in an earlier report (Anders- land and Laza, 1971), one representative for an integrated pulp and paper- mill and the other for a secondary fiber mill. Some data on a third sludge from a different secondary fiber mill is included. Variables which in- fluence the consolidation behavior of organic soils are considered in this study on pulp and papermill sludges. They include (1) load increment ratio (or load history), (2) initial solids content (or water content), (3) degree of saturation, (4) organic content, (5) admixtures of lime or flyash, and (6) influence of temperature on certain consolidation parameters. The consolidation behavior of a given sludge is described in terms of certain measurable parameters. The coefficient of compressibility av describes the decrease in void ratio e per unit increase in pressure p. The compression index CC describes the same decrease in void ratio 2 3 with logarithm of pressure. Volume change may be computed when refer- ence is made to some initial void ratio e0 for the sludge element. When this volume change occurs only in the vertical dimension it is referred to as settlement. Prediction of the rate at which this settlement or volume change occurs requires data on the coefficient of consolidation Cv' Ex- perimental data including the coefficient of consolidation for any load increment, the coefficient of compressibility, and the void ratio (usually the average for any load increment), provide an indirect method for com- putation of the average coefficient of permeability k during any load increment. These parameters all refer to primary compression. Secondary compression is not dependent on dissipation of excess pore pres- sure and becomes most apparent after completion of primary compression. The coefficient of secondary compression may be defined in either of two ways. First, C(1 may be expressed in terms of change in void ratio over one cycle of the logarithmic scale on a plot of void ratio versus logarithm of time. Second, Ca-is the slope of the settlement-log time plot divided by the thickness of the sample at the beginning of the long-term or straight- line stage. The latter definition is used in reporting the experimental results for this study. The variables considered in this study influence these consolidation parameters. For example, the conventional consolidation test with a load increment ratio Ap/ : l and load duration of 24 hours gives an appreciable amount of secondary compression under each load increment. Lime or flyash admixtures will alter the sludge-water system to give different consolidation parameters. Temperature affects the permeability which in turn affects the coefficient of consolidation. Experimental data and a discussion of the effect of each variable on the consolidation behavior of sludge is included in this report. CHAPTER II CONSOLIDATION CHARACTERISTICS OF SLUDGE AS DETERMINED FROM LITERATURE REVIEW 2. 1. Properties Which Influence Sludge Compressibility Pulp and papermill sludges may be considered to be a skeleton of solid particles or fibers inclosing voids which may be filled with gas, with liquid, or with a combination of gas and liquid. If a sludge sample is placed under stress in such a way that its volume is decreased, three factors may contribute to this decrease in volume. They include compres— sion of the solid matter, compression of water and gas within the voids, and escape of water and air from the voids. Under loads usually encoun- tered in soil or sludge masses, the solid matter and pore water, being relatively incompressible, do not undergo appreciable volume change. For a completely saturated soil, it is sufficiently accurate to consider the decrease in volume of the mass as due entirely to escape of water from the voids. In a partially saturated soil or sludge mass the situation is much more complex, since a small amount of compressible gas within the pores may allow appreciable compression of the sample with no es- cape of pore water. Several properties which influence sludge compres- sibility and which are discussed below include sludge composition, water content, and permeability. 2. l. l. Sludge Composition Pulp and papermill sludges have the physical appearance of clay interwoven with cellulose fibers. The dewatered sludge exhibits a very soft consistency with color varying from grey to brown depending upon the paper making process involved. The solid content depends on the method used for dewatering and ranges from two to five percent for natural settling, 20 to 45 percent for vacuum filtering and up to 65 percent for mechanical pressing. This variability for a given process is dependent on the sludge composition. Gillespie, Gellman, and Janes (1970) defined "high ash sludges" as those which have a fixed solids content of 60 percent or greater. This fixed solids portion is mainly clay with small amounts of aluminum hydrate, titanium oxide, lime and iron. The remaining 4 5 portion is composed of cellulose, starch, resins, glue, ink, and small amounts of other organic compounds (Mazzola, 1969). The proportion of each is dependent upon the type of paper being produced and the internal methods being used to recover the fiber. The result is that the physical preperties of pulp and papermill sludges can show a wide variation. Various microorganisms are responsible for decomposition of the organic matter in soil or sludge. Waksman (NCASI Tech. Bull. No. 120) showed that cellulose decomposition is dependent on a favorable carbon- nitrogen ratio. In samples composed of garden soil, small amounts of a sand cellulose mixture, and one percent sludge, he observed 90 percent cellulose decomposition in 45, 50, and 80 days with carbon to available nitrogen ratios of 5:1, 10:1, and 550:1, respectively. Imshenetsky (1968) indicated that cellulose decomposition ceases when the available nitrogen content of a soil is below 1. 2 percent. Other factors influencing decom- position include temperature, aeration, moisture content, pH, and the relative proportion of lignin. Mazzola (1969) examined core samples of sludge frmn deposits at eight different mills for various physical prOperties. No visual indi- cation of degradation of the fibrous material was apparent in sludges ex- tracted from depths ranging from 2 to 16 feet. Photomicrographs of fiber taken from one of the sites at depths of 2 and 12 feet representing deposit ages of l and 12 years, respectively, indicated that any decomposition was proceeding at a very slow rate. Mazzola (1969) attributed this very slow decomposition to the low nitrogen content of papermill wastes. Compressibility of soil is a function of the extent to which particles can shift positions by rolling and sliding. This rigidity of the soil skeleton is dependent on the structural arrangement of particles and on the degree to which adjacent particles are bonded together. Pulp and paper mill sludges vary in the amount of fibrous material present. A coarse fibrous structure may exhibit a different compressibility from a fine-fibrous or an amorphous-granular type sludge. MacFarlane (1969) reported 9i that fine-fibrous peats show the highest compressibility and the coarse? fibrous peats the least. 2. 1. 2. Water Content The water found in pulp and papermill sludges exists in three different phases (Gehm, 1959); (1) free water, (2) interstitial water, 6 and (i) water of imbihition. The free water will drain readily. Intersti- tial water is held by adsorption on hydrogel surfaces, as well as particle and fiber surfaces, and is difficult to remove. Water of imbibition, forming a part of the structure of colloidal sols, cannot be separated by mechani- cal methods. These sels consist of highly hydrated wood dust, fiber debris, ray cells, aluminum hydrate, starches, dextrins, resins and pro- teins, and are reSponsible for the gelatinous and thixotropic nature of the sludge mass. The addition of a small preportion of sols to a relatively free sludge mass will appreciably increase the water holding prOperties of the entire mass (NCASI Tech. Bull. No. 190). The water retention characteristics of a secondary fiber mill sludge is shown in Figure 2. 1. Water holding preperties of the sludge can be altered by changing the or- ganic content or by the addition of a lime admixture. Mazzola (1969) obtained field water contents at nine sludge sites. At three sites the sludge had been deposited without mechanical dewatering and at the remaining six sites the sludge had been subjected to either vacuum filtering or centrifugation before deposition. Variations in water content ranged from 46 to 740 percent with no samples taken below the ground water table. Mazzola (1969) noted that the water contents of the sludge deposits had changed very little with time. In examing the water content variation within a single deposit, Mazzola (1969) found a larger variation in the vertical direction as compared to the horizontal direction. This stratification would agree with changes in the manufacturing processes employed to produce different paper types. Consistency (Atterberg) limits are used to indicate the range of water contents in which a soil or sludge may be considered as a fluid, plastic, or solid. Terzaghi and Peck (1967) provide information on the relationship C N 0.009 (L - 10%) (2.1) c — w between liquid limit Lw and the compression index CC for clays of medium or low sensitivity. Application to pulp and papermill sludges having low fiber contents may be possible. 2. 1. 3. Permeability The physical structure and the arrangement of constituent parti- cles in sludge greatly affect the size and continuity of pores and/or capillaries. These differences plus incomplete saturation result in a wide range of permeabilities in pulp and papermill sludges. The effects of undissolved gas in peat show up particularly in consolidation test re- sults (MacFarlane, 1969). In laboratory consolidation tests, a large ini- tial compression and an indistinct completion of primary consolidation in time-compression curves reflect the presence of gas. Sludges containing sols tend to decrease permeability while the Open-meshed fibrous sludges are initially quite permeable. Other factors influencing the permeability include the solids content, the organic content, and the degree of con- solidation. The most widely used representation for flow is Darcy's Law (Terzaghi and Peck, 196 7; Lambe and Whitman, 1969) which is usually written in the form v:%:kéflb-:ki. (2.2) The rate of flow q is dependent upon a permeability constant k, the hy- draulic gradient i = %:h- , and the cross-sectional area A. The accuracy of the equation is generally dependent on the permeability k. For the permeability to be truly constant certain conditions must be satisfied or accounted for including (1) a completely saturated medium, (2) an incom- pressible fluid, (3) no change in void ratio in the porous medium, (4) low flow velocities, (5) a homogenous porous media, (6) a homogenous fluid, (7) continuous flow, and (8) steady state flow (Leonards, 1962; De Wiest, 1969). Examination of the above conditions in terms of the usual engineering problems reveals that items five through eight are insignificant since the laboratory determination of the permeability adequately takes them into account. In addition, the void size and configuration in ordinary soils is such that the flow velocities are normally small. Consolidation in- volves a change in void ratio, hence a change in permeability. The permeability of a consolidation specimen can be computed at each void ratio from test data (Lambe, 1951). Pulp and papermill sludges contain 8 undissolved gas in the pore fluid which was trapped during dewatering or which develops during slow decomposition. The effect of these gas bubbles on the permeability of a secondary fiber mill sludge is shown in Figure 2. 2 for low backpressures. Pretreatment of the sludge with a sterilant and a vacuum minimizes this effect. At low back pressures the natural pulp and papermill sludge re— quires a threshold hydraulic gradient to initiate flow. Andersland and Laza (1971) reported that for the secondary fiber mill sludge and zero back pressure, this gradient was as high as 11. 77 for some samples. This has a practical significance with regard to consolidation of sludge, since hydraulic gradients in field embankments can be less than unity. Mitchell and Younger (1966) indicated that the amount of consolidation will be decreased, since consolidation would cease when the excess pore pressure in a clay layer has decreased so as to give the threshold gradient throughout The coefficient of permeability is dependent on the temperature at which a permeability test is performed, because k is a function of the unit weight of water Yw and of the viscosity 7] (Terzaghi and Peck, 1967). Both of these quantities vary with temperature. The variation of yw is negligible in comparison to 1}, hence Terzaghi and Peck (1967) com- pute the value of k for any temperature by means of the equation. r] k:—-———-—k (2.3) T] 1 In this equation k corresponds to the coefficient of permeability at the test temperature 1and n 1 is the corresponding viscosity. Equation 2. 3 assumes that the coefficient of viscosity of water is independent of soil porosity. In clays temperature appears to have a greater influence on viscosity than it has in coarser soils. The average viscosity of the pore- water of clay appears to increase with decreasing pore space (Terzaghi and Peck, 1967). These facts exclude application of equation (2. 3) to clays and other very fine-grained soils. Equation (2. 3) may not be applica- ble to pulp and papermill sludges having high water retention properties. at m. water tension, 50 r )- 10 " l- 5 .— 1. O - ; AV 0. 5 "" \\ _ Q on 35% organic content 43% organic + 10% lime O. 1 j —_ 9057.1.1.i.i.iii...'i.“.‘ci O 40 80 120 160 200 water content, w % by wt. Figure 2. 1. Water retention curves,sludge H-Z. (after Andersland and Laza, 1971). 10 10, 0001’ 8 a u a (35093 °_8_o_3—g——no_g Q 8000-ll v“ V 7° E v ‘6 U 9, v °? V A ._. " 25. 770 solids x A o x 1’ 0 no pretreatments .. A E] sterilant and vacuum pretreated i; 4000.. o A sterilant pretreated E A v vacuum pretreated (U «u- E s 2000-~ ° 0) 0. Ju- o 04.:i:::::::4.::: 0 4O 80 120 160 200 240 280 average head, h, feet of water Figure 2. 2. Permeability versus average head of water for sludge H- 2. (after Andersland and Laza, 1971) ll 2. 2. Application of Consolidation Theory to Sludges 2. 2. 1. Consolidation Theory Consolidation theory involves setting up an equation from which the pressure and void ratio values may be computed at any point and at any time in a stratum of consolidating soil or sludge. From such an equation the change in overall thickness of the strata after any interval of time may be determined by integration or numerical computation. A number of assumptions are used in the theory. The basic theory as it may be applied to pulp and papermill sludges, required assumptions, and deviations from the theory for organic soils are outlined below. 2. 2. 1. 1. Soil Compressibility Consider the case where consolidation and volume change occurs only in the vertical direction (one-dimensional compression). Then, change in height A H per unit of original height Ho equals the change in volume AV per unit of original volume V0. (2. 4) AH AV V o It is convenient to express AV in terms of the void ratio e. From Figure 2. 3 and equation (2. 4), (2.5) This relationship is valid regardless of the mechanism causing volume change or of the degree of saturation of the sludge. The relationship between Ae and the change in effective normal stress A; is usually determined experimentally by one-dimensional consolidation tests. The slepe of the void ratio versus effective stress curve is called the coefficient of compressibility av. a :_ d (2.6) d}? (D The value of aV decreases as 0' is increased; however, for small values of A0", Ae : -a A; (2.7) V 12 at initial condition Figure 2. 3. V5011+€ ) —"S]V(1+2) LAV: V0 — V‘ l i . . ' ’ *- 1 ,. gas. I """—- ”“fiy *1 ‘ ' gas , V0; eovs f g i _ cIVs ‘— - _ p water ‘ V0 - «Silicol 1 ,, .__. ' Vsii‘ (21} \galQr I // /;,/";’/ W2 Vs /S°l'ds,/ ’4 V ?’s lids/i //_/// /1 S ”/11, ? V $011+?!) Volume -void ratio relationships. 6) compressed condition 1+8 13 Combining equations (2. 7) and (2. 5), a — All 7. u ——X-—cr (2.8) 0110 0 When A0‘ is so large that aV cannot be assumed constant, a v _. ClH -— 111T??- d0' (2. 9) o and av __ AH ZSdH -: 3‘le (10' (2.10) 0 av The term H? can be replaced with the coefficient of volume compres- 51b111ty mv, AH : S H. m d? (2.11) 1 v It is often convenient to plot the consolidation test data as e versus log Tr. The SIOpe of this curve is c = -—-d—e—— (2.12) C d(log E) where CC is called the compression index. It can be shown that 0.435 c a s ——:——E (2.13) 0" Substitution of equation (2. 12) into the differential form of equation (2. 5) gives C C —— dl‘i — Hlfi—FO— d (log 0‘) (2.14) If F0 is the initial pressure and d? the change in pressure, then _ _ __ _ 30 + d? d(log 0') : log (0'O + do) — log 00 : log -—_-_——— (2.15) 0 Substituting equation (2. 15) into equation (2. 14) gives CC 30 + a? (111 :— Fill—:1;— 10g ——:——— i O 0‘ O .16) to 14 and U (I O (. (r) I d; k' ( All SIIiT|0~10g-—-———- (2.17) These expressions are used for estimating the ultimate soil compressions due to one-dimensional volume changes. 2. 2. l. 2. Rate of Consolidation When the load on a layer of highly compressible porous saturated material such as pulp and papermill sludge is increased, the layer is compressed, and excess water drains out of it. This constitutes a process of consolidation. The added load per unit of area is known as the consoli- dation pressure. At the instant of application the consolidation pressure is carried almost entirely by the water in the voids of the sludge. The initial excess pressure in the water is almost exactly equal to the consoli- dation pressure. As time goes on this excess pore water pressure dissi- pates and the average effective pressure in the sludge increases. This process of consolidation is illustrated in Figure 2. 4 where drainage is permitted through the top and bottom of a consolidating layer. For this case the initial excess hydrostatic head, represented by line de, equals the load per unit area divided by the unit weight of water, Ap/yw. As time goes on this head decreases in the form represented by curves C and C for times t and t respectively. The excess pres- l 2 l 2’ sure 1.1 : Y 11 (2.18) becomes equal to zero when consolidation is complete. The consolidation pressure has now become an effective stress. If consolidation pressure at any time is denoted by A0', equilibrium requires that Ad -_- A? + u (2.19) where ATT- represents that portion of the consolidation pressure which, at a given time, is transmitted from particle to particle and u equals the excess hydrostatic pressure. The equation governing the time rate of one-dimensional volume compression (Terzaghi and Peck, 1967) is consohdafing layer 15 drainage l 12 31/ - -- “4‘414‘144/ Figure 2. 4. drainage consolidating layer piezomctric tubes //11'/A/////////////’ drainage. Diagram illustrating consolidation of a compressible layer of clay (after Terzaghi and Peck, 1967). 16 where u equals the excess hydrostatic. pressure, t equals time following application of the consolidation pressure, z equals distance from the middle of the strata shown in Figure 2. 4, and cV represents the coeffi- cient of consolidation. Terzaghi and Peck (1967) give the hydraulic boun- dary conditions which must be satisfied for solution of this equation. Equation (2. 20) combined with the boundary conditions determines the degree of consolidation U % for a given time t. The equation for U % is U % : f(Tv) (2. 211 where cV _ 7 2 is a pure number called the time factor. At the drainage surface z equals H. Since the soil constants and the thickness of the compressible layer enter equation (2. 21) only in the combination represented by the dimen- sionless time factor Tv’ the value U % = f (Tv) is the same for every layer that consolidates under specified conditions of loading and drainage. It has been determined for every condition of practical importance by means of equation (2. 20) with the results presented in the form of graphs or tables (Terzaghi and Peck, I967; Leonards, 1962). Theory for two- and three- dimensional processes of consolidation is given by Terzaghi (1943) and Scott (1963). 2. 2. 2. Deviations From Theory for Organic Soils The basic assumptions made in applying the conventional consoli- dation theory to organic soils include: (1) homogenous material, (2) com- plete saturation, (3) negligible compressibility of the solid matter, (4) the validity of Darcy's law, and (5) constant preperties during each stage of consolidation. Application of consolidation theory to peat includes major deviations from assumptions three and five, compressibility of the solids and change in permeability under applied load. MacFarl' -.e (1969) indicates that these two anomalies account for the significant differences in consolidation behavior between organic and mineral soils. A typical laboratory time-settlement curve for peat is shown in Figure 2. 5. Initial compression, due primarily to compression of entrapped air, occurs on application of the load. Primary compression in peat occurs over a relatively short time interval. Secondary or long-term \. l7 .300. .ocwfiumhomfi .833 down pom mmsmsofimfiou .coEofi—uomumgfi HMUHEH .m .N 9.5th meadows. s. meg. oooo. coo. oo. o. H .6 Z... . q ...4... q .4..... a 2.4.. . . ....7.. 0.0 . _ _ _ M . a c _ . _ . n “ x03. :0 A _ acumEmflo :m .N mofimgmm » .v .o . u w _ H o _ m _ S _ . . I _ m .o . . . 5c. 31.. .o Emfimgwm .30... “ own. one .28.. Sen. £63.... oar. _ . m sequI ut quawapqag 18 compression is represented by the straight portion of the curve. Predic- tion of the rate of consolidation, as given by consolidation theory, appears to be limited to primary compression (MacFarlane, 1969). Adams (10(6) indicated that the compressibility of the solid material accounts for part of the continuous long-term compression, of peat. Secondary compression and the influence of admixtures on consolidation are described below. 2. Z. Z. 1. Secondary Compression In peat, secondary compression, which is not associated with pore pressure change, constitutes a moderate portion of the total settlement. Consolidation theory (Terzaghi and Peck, 1967; Leonards, 1962) does not account for secondary compression. MacFarlane (1969) gives the equation CO. 5.. = “T7? log10%- (2.23) o . for estimating settlement S(1 due to secondary compression within the time interval tO to t. The thickness of the compressible layer equals H, and Co is the coefficient of secondary compression expressed in terms of change in void ratio over one cycle of the logarithmic scale on a plot of void ratio e versus logarithm of time. The value of C(1 can be determined from laboratory tests or from field settlement data. Its determination in the laboratory is subject to how well test conditions represent probable field conditions. A second definition of the coefficient of secondary com- pression expresses CC1 as the slope of the ’settlement-log time .plot A H divided by the thickness H of the sample at the beginning of the long-term or straight-line stage (MacFarlane, 1969; Lambe and Whitman, 1969). For example J AHA/H - w A (2. 24) a loglnt , The latter definition is used for reporting the experimental results in this study. The physical mechanism causing secondary compression is not clearly understood, but there is evidence suggesting that Co is not a constant soil parameter (MacFarlane, 1969). The shear stress in soil 19 appears to be a major factor affecting its value. Lee (1968) indicates that secondary compression is a form of creep and attributes the accelera- tive type of secondary compression. to breaking of bonds and the decelera— tive type to a gradual expulsion of water (from pores of everdiminishing diameter). Soil creep theory (Andersland and Douglas, 1970; Mitchell, Campanella, and Singh, 1968) does describe time-dependent deformation for soils in terms of stress level, stress history, temperature, compo- sition, and soil structure. Mathematical analyses of primary and secondary consolidation have been made (Wahls, 1962) by combining equations (2. l7) and (Z. 23) but the accuracy of values assigned to CC and C(1 are still the major factor governing the precision of settlement predictions. 2. Z. 2.. Z. Admixtures of Lime or Flyash Efforts to improve the dewaterability of pulp and papermill sludges have considered the addition of flyash or lime to the material (NCASI Tech. Bull. No. 136, 158, 190). The question here is what effect do these admixtures have on the consolidation behavior of the sludge after placement in a landfill? Four basic reactions affect changes in the engi- neering prOperties of lime-soil mixtures (Thompson, 1966). Cation exchange, flocculation, and agglomeration are primarily responsible for alterations of plasticity, shrinkage, and workability characteristics. Pozzolanic reaction is the main contributor to strength although lime carbonation may contribute slightly. Organic matter greatly retards any lime-soil pozzolanic reaction. Limited information is available on the effect of lime or flyash admixtures on soil consolidation behavior. Ranganatham (1961) reported that when black cotton clay was treated with lime there was a marked increase in the coefficient of consolidation and a decrease in the recovery ratio. The increase in cV with lime treatment means a more rapid rate of consolidation for normal loading. An increase in the permeability when lime or flyash was added to pulp and papermill sludge (Andersland and Laza, 1971) would increase the coefficient of consolidation. Any pozzolanic action would tend to reduce or stop consolidation. Increase in shear strength of pulp and papermill sludges due to addition of lime or flyash was small (Andersland and Laza, 1971), hence pozzolanic reactions must be very limited. 20 2. 5. Laboratory Analysis Laboratory tests and analysis serve to illustrate the principles on which engineering judgment may be based or to set limits to the proba- ble behavior of a soil or a pulp and papermill sludge. This section re- views sampling and consolidation test procedures followed by interpretation of results and some practical applications. 2. 3. 1. Sampling and Test Procedures The principal sources of error in predicting ultimate settlements lies in the accuracy of the experimental determination of the compression index CC (or the coefficient of volume compressibility mv). For existing clay or peat deposits reasOnably undisturbed samples are cut as a block or cylindrical sample in an Open test pit. For greater depths thin-walled samplers with piston attachments have given fair success. Inside diameter of the samplers have normally been 2. 5 to 3. 0 inches. For the purpose of this study fresh sludge samples obtained at the mill site were used. Consolidation testingof clays and peat has generally followed conventional practice (Lambe, 1951) with certain modifications. Sample diameter has varied from 2. 5 to 12 inches. The conventional method implies a load increment ratio Ap/p : l and a load duration of 24 hours. Time-settlement curves are similar to that shown in Figure 2. 5 and may include an appreciable secondary compression for each load increment with organic soils. MacFarlane (1969) reports that the rate of secondary compression of peat is pr0portiona1 to the sample thickness. The Inagni- tude of secondary compression under each individual load increment will, therefore, have an effect on the rate of long-term compression on succes- sive load increments. For peat MacFarlane (1969) recommends that loads be applied as single increments covering the loading range desired. Compression readings should be taken over very short time intervals during the first few minutes of loading and then at longer intervals. Leonards and Ramiah (1959) noted. the change in shape of compression-time curves as the load- increment ratio was reduced and the corresponding reduction in cV values calculated from conventional curve fitting procedures (Lambe, 1951). Leonards and Altschaeffl (1964) reported that the Terzaghi theory predicts pore pressure dissipation only for a type I curve such as shown in Figure 2. 5 which was obtained with a load increment ratio equal to unity. 21 2. 3. 2. Interpretation of Results and Practical Applications Conventional curve fitting methods for interpreting consolidation tests on soils are given by Leonards (1962) and Lambe (1951). The details of the test, including load-increment ratio and duration, specimen size, type of consolidometer, temperature, and sample disturbance all affect the value of cV (Leonards and Ramiah, 1959). Since field load- increment ratios vary with depth, it is known that experimental values of cv obtained in the laboratory are subject to undetermined errors. MacFarlane (1969) reports that conventional curve-fitting methods for interpreting consolidation tests on peat or organic soils will not be possi- ble. He gives several empirical approaches which have been used with peat and which have met with some degree of success. For single increment tests, where the applied load has been made equal to the anticipated field loading, the magnitude and rate of the primary compression may be estimated as follows (MacFarlane, 1969): H fielde lab 0 o H lab 0 (2. 25) S field 0 H; field x t lab t field (2. 26) Hi lab 0 where t is the time for consolidation, Ho the initial peat thickness, S0 the initial compression, i the exponential parameter. Secondary compression would be estimated according to equation (2. 23). The total field settlement for any given time is then a summation of primary and secondary com- pression. This prediction of field settlement from laboratory tests on peat is essentially a direct extrapolation of laboratory thickness to field ’ thickness and assumes a linear rate of settlement with the logarithm of} time. For non-homogenous peat deposits or where mineral soil layers exist, this method will give only approximate predictions. Any shear or displacement strains would not be accounted for. Practical considerations include preloading and sand drains. Pre- loading has been used to overcome or partially eliminate the long-te rm compression in peat. A preload is applied of sufficient magnitude and duration to cause the compression of the peat which would normally occur under the prOposed design load over the expected life of the structure. 22 The magnitude of the preload would be limited by stability considerations which are largely governed by the rate of pore-water pressure dissipation. A method of estimating the magnitude and duration of the preload is shown in Figure 2. 6 for a fine fibrous peat 10 feet thick. Curve No. l is the field tithe-settlement curve based on the procedures outlined above. The remaining curves consider additional loads based on grade maintained and/or a surcharge load. Considerable field rebound has been observed in several field cases on removal of the preload (MacFarlane, 1969). Sand drains have been used in clay foundations to allow easier drainage for escaping water with a resulting acceleration of primary consolidation. They have been particularly useful in the preloading technique where the duration of the preload has been of economic impor- tance. For peats the initial or excess pore-water pressure period is generally very short. For this condition sand drains will not be effective. For secondary compression the use of sand drains will not be effec- tive because the rate of compression does not appear to be a function of length of the drainage paths. MacFarlane (1969) indicates that sand drains should not be ruled out for all peats or organic soils. Where tests have shown that the duration of the primary compression stage is apprecia- ble, when the length of drainage stage is appreciable, and where the length of drainage path (or thickness) is also large, sand drains can be effec- tive both in reducing construction pore pressures and in accelerating the primary stage of compression. .300. .ocm...mr..om2 .73me me>u5o EeEe...mm-eE.n mgms EeEm...s.oe.. wagons. mefimgfime .o posse? .0 .N musm.r.. 93c 5 meat 000.00. 000 .0. 000. 00. 0. 0.. L , o 4. ml, I II, I ¢ I 0., 0' I, II, I 'l I _ I I , I ’l. I I mummimom Lilli/I I: II +II I I I II t. 936 0.V 93v w. _ III, I'I'I it'll L I [III I ILTIII N. . 'IL" .4. _ 0’ WW. _ a . _ W / I. —/ u 3 _ / rd 2 . a t. / 0 .N m a _ an o. i mm®5.o.£.H .33. Jenn. 3.9.3.... 9...... ,0 .. omumnuusm $00. u 3080.30m 08.... .m L ownmxousm same i .noEeZuom mafia. .v owumnousm 050m .. oceanofizmm ecu... .m A 2.3238 333 2.. a. o .. Buchanaom 08.... .N .3. .3 c u unarmed—3m 08.... .. 0 CHAPT ER 111 SLUDGES STUDIED AND SAMPLE PREPARATION Two sludges used in this study are also described by Andersland and Laza (1971). These sludges were chosen so as to provide correlation with previous work and to provide some correlation with many of the sludges encountered within the pulp and paper industry. One sludge came from an integrated pulp and papermill, the other from a secondary fiber niill. The organic portion of the first was composed of long fiber cellulose material and some/ wood chips while that of the latter was made up entirely of small cellulose fibers. The remaining portions of both sludges were essentially the same, varying only in the relative amounts of constituent materials. Sonie data on a third sludge from a different secondary fiber mill is included. This chapter describes the three sludges and provides information on sample preparation for the consolidaton Specimens. 3. 1. Secondary Fiber Mill Sludges Both secondary fiber mill sludges were tested for their physical properties including specific gravity, consistency limits, and ash content. Test methods used for these prOperties are listed in Table 3. l. The physical properties of both sludges are given in Table 3. 2 including sam— ples modified by additions of lime or flyash. These sludges were grey in color. The solid contents as sampled at the mill are given in the last column of Table 3. 2. The symbols H or D will be used throughout this study to identify the two secondary fiber mill sludges. Numbers follow- ing these letter designations give the sample number. The sludge identi— fied as H best fits the definition of a high ash papermill sludge (Gillespie, Cellman, and Janos, 1970), hence it was used for the major part of the test program. The organic content in both sludges was of the same type consisting of short cellulose fibers. Sludge D with a higher organic content contained more long fibers. The admixtures used with sludge H-Z included a commercial lime and a flyash resulting from the incineration of coal and bark in power boilers at a secondary fiber mill. The lime, described in Table 3. 3, 24 25 is comparable to that used in the paper industry and was obtained from a local supplier. Properties of the flyash with information on particle size are included in Table 3. 3. 3. 2. Integrated Pulp and Paper Mill Sludge The integrated pulp and papermill sludge ranged from dark to light brown in color and contained some discrete particles of bark and wood chips with lengths up to 15 mm and diameter of 2 mm. The two sludge samples contained 30. 7 and 23. 9 percent solids by weight with ash contents of 48. 5 and 27. 4 percent, respectively. The symbol C will be used through- out this study to identify the integrated pulp and papermill sludge. The number following this letter designation gives the sample number. Physi- cal properties of this sludge are given in Table 3. 2. 3. 3. Sample Preparation Sample preparation for the consolidation tests involves procedures followed for the natural sludges, modification to different organic contents for sludge H-3, and combinations of sludge H-Z with admixtures of lime or flyash. 3. 3. 1. Natural Sludges Dewatered sludge obtained from the mills may range in consis- tency from fluid to serni-solid. Solid contents ranged from' 23. 9 to 30. 7 percent by weight with difference in consistency largely due to the fiber content. Sludge H with the lower organic content approximated a viscous fluid in behavior. For convenience in sample preparation this sludge was further dewatered in a centrifuge to about 35 percent solids. This dewatered material was remixed, formed into a soft ball, placed in a plastic bag and stored in a refrigerator for about 24 hours prior to sample preparation. This storage period helped insure a uniform water content throughout the sludge sample. Sludges C and D were prepared into con— solidation specimens without additional dewatering. The test Specimen was prepared by placing sludge material into the consolidometer ring by hand in uniform layers about l/4-inch in thickness. The ring was supported on a glass plate. Care was taken to insure that no space in the ring was left unfilled and that the sample was made as uniform as possible. The tOp face was shaved evenly. Initial specimen dimensions conformed to the ring size. The specimen and ring were weighed with the initial sample weight determined by 26 difference. Dry weights were obtained at the end of the consolidation test after oven drying. Next the saturated bottom porous stone was placed in the consolidation unit followed by the specimen and ring. The remaining steps depend on which consolidation unit was used and are explained in Chapter 4 under laboratory equipment and test procedures. 3. 3. 2. Different Organic Contents It was desired to alter the organic content of sludge H-3 without affecting the remaining constituents in order to simulate possible decom- position. Special procedures used involved washing the sludge material through a U. S. Standard No. 16 sieve (opening of 0. 0469 inches) and collecting both the wash water and the material remaining on the sieve. The wash water was placed in a closed container and allowed to stand un- disturbed for about four days permitting the suspended particles to settle out. Next the clear water was siphoned off and the remaining portion brought to a consistency of about 35 percent solids by weight using an International Model V, size 2 centrifuge for 30 minutes at 2500 rpm. An organic content determination was run on both the material collected on the sieve and that washed through. Using these known organic con- tents, mixtures were prepared to give a range of organic contents. These mixtures were checked for their organic contents which are given in Table 3. 2. Since the openings on the No. 16 sieve are larger than the individual particles and fibers within the sludge, this process was not one of selective separation. The material retained on the sieve appeared to contain a full range of fiber size, the same as that washed through. Hence the fiber size within the modified samples was comparable to that in the natural sludge samples. The mixing referred to above was done by hand until the materials appeared to be well dispersed, then completed with a Hobart Model A-200 electric mixer. Samples of the prepared mixtures were stored in sealed plastic bags in a refrigerator at about 350 F until preparation into consolidation specimens as described in Section 3. 3. l. 3. 3. 3. Combinations With Lime or Flyash Lime or flyash materials are sometimes used to improve the dewaterability of pulp and papermill sludges (NCASI Tech. Bull. 136, 158, 190). To provide information on how these admixtures influence sludge consolidation behavior samples were combined with lime or flyash 27 by hand mixing 10 percent by dry weight of the admixture with the sludge until it was well distributed throughout the sample. Mixing was completed using the Hobart mixer for four to five minutes. This material was then sealed in a plastic bag and returned to the refrigerator for 24 hours before preparation into consolidation specimens as described in Section 3. 3. 1. Table 3. 1. Physical PrOperty and Test Method Physical Property Test Method Consistency (Atterberg) limits Liquid limit ASTM D 423-66 Plastic limit and plasticity index ASTM D 424-59 Shrinkage factors ASTM D 427-61 Ash content ASTM D 586-63 Organic content Agronomy No. 9, Sec. 92-3. 3 Specific gravity ASTM D 854-58 .HZE um. moo-H530 owns? mo “Coucoo mpfiomm Simuozc: 3.3m Gum-£632 .m .Mnmm .oom .0 .02 >Eocouw< cw :oNLm ©0568 umoH ¢ .NNAWNN o 33.3. 852a “mu-N Eb: owns-:2... -- 3m sun: 0:33 -- 3m .38: 2%: -- BAN .wwmum .umoQ mosofiom 30m >3 Gdu mumoH. Joan-Sam .635? Sub Noam >umvcooom nu Q .N was _ monEMm .omvdfi HES-momma pad 35m woumuwoug nn 0 .m van .N .H mafia-How 6353 Swan .353 >udvcooom nn $- .Swo: mnmd can vamfimuovcdqu Noam down; 28 N .NN S .N N .8 - .NN o .3; .- .NNN To a .NN No 4 N .3 .- .sN N .NoN o .NS. No TON ONN N.$ Nd.- NéNN of: N.N¢N v1.0 am 4 s .S v .NN N .NHN N .NNN 33:8 Scams .N. No no .N N i. s .3 N .5; o .NHN snoucoo 3598 as om NN .N N .N N .NN .- .NN N Na 38-80 0888 .N. “N a .oN E .N w .3 s .3. N .2: a .3; Basso Scams a. 2. Num ON .N o .oN s .E TNN N .N: “NE .395 .N. S + 0888 .N. Na N .N N .2. o .3 N .2. N .st N .NNH 08: s S + 2530 .s Nu N. .NN Z .N 0 Nu H .3 s .NN o .9: N .N: “838 068.8 a. Na. Ni... N .NN 2 .N N N a .3 o .3 N .3 N .N.: Tm. £3 >9 one cm. 3 3 .3 unouaoo Knot-ohm “Coucoo ucmacoo w my. 1H m 5 mmvflom 330on vowcmmuo mnm< Nmfi-CS tau-Noumwmcoo Ho p Hm mfimfiuoumz owpsdm 9: mo mofiuomoum HoowmtEm .m .m 3an Table 3. 3. 29 Properties of the Lime and Flyash (after Andersland and Laza, 1971) 1113112 Brand Mississippi hydrated lime Source Massour, Missouri Specific gravity 3. 32 Available calcium hydroxide 97. 00 % Available calcium oxide 73. 4O % Available calcium carbonate 2. O4 % Total calcium oxide 74. 57 "/0 Total trace elements 1. 68 % Flyash Specific gravity 1. 92 Liquid limit 53. 2 Plastic limit 49. 7 Plasticity index 3. 5 Gradation, % passing by wt. *No. 100 sieve (o. 149 mm) 94 No. 200 sieve (0. 074 mm) 87 --.. (O. 020 mm) 14 * U. S. Standard sieve sizes. CHAPTER IV LABORATORY EQUIPMENT AND TEST PROCEDURES The consolidation test provides information concerning the amount and rate of volume change of a soil or sludge sample under load. An introduction and recommended procedure for the conventional consolidation test is given in Chapter IX of SOIL TESTING FOR ENGINEERS by T. William Lambe (1951). More recent methods (Lowe, Zaccheo, and Feldman, 1964) use a backpressure for reproducing field neutral pressures and minimizing the influence of entrapped air on consolidation behavior. This chapter provides information about the consolidation equipment and test procedures used for the pulp and papermill sludges. 4. l. Consolidation Equipment Consolidation equipment consists of the soil container and a system for applying loads which are nearly constant. Consolidation specimen containers may be of either the fixed-ring or floating-ring type. The fixed- ring container is illustrated in Figure 4. l and was used in this study be- cause of the very soft initial condition of the sludges. A floating-ring would not receive sufficient support from the sludge during the early stages of the test. Figure 4. 2a shows a consolidation unit of the fixed- ring type and includes a sludge specimen which has been oven dried. Specimen preparation was described in Section 3. 3. l. The system for applying loads to the consolidation specimen may utilize a dead load and lever system or a hydraulic loading system. The dead load and lever system was used in this study. Figure 4. 2b shows part of the loading system with a consolidation unit. Vertical specimen deformation is shown by the dial gauge. 4. 2. Conventional Test Procedures Test procedures outlined by Lambe (1951) were followed in general with minor changes. For convenience in plotting dial reading versus square root of time curves, compression readings were taken at total elapsed times of 0, 1/4, 1/2, 1, 2 1/4, 4, 6 1/4, 9, 12 1/4, 16, 20 1/4, 25, 36, 49, 60, 120, 240, 480, and 1440 minutes. A 24-hour period 30 31 1 load stand i 2 ‘ pp . cover ‘ porousss gngffl'u / soil ”“9 Specimen ' J kw , L'porqu’s' stone. l hm Figure 4. 1. Fixed-ring consolidation specimen container. 32 was allowed for each load increment. This period was more than required for completion of primary consolidation but did provide a convenient and fixed time interval. A load increment ratio equal to one was used on all tests except those concerned with load history. For the ratio equal to unity, load increments of 1/4, 1/2, 1, 2, 4, 8, and I6 kg/sq cm were followed. 4. 3. Pressurized Consolidation Cell The pressurized consolidation cell permits application of a back- pressure so as to reproduce neutral pressures which may exist in the field and to reduce the effect of entrapped air on the soil or sludge consolida- tion behavior. In the case of pore pressure measurements the cell has the advantage of ensuring that air bubbles in the measuring system are largely eliminated. The Wykeham Farrance model HC 1 pressurized consolidation cell modified to use a linear displacement transducer for deformation measurement was used in this study. The cross-sectional and plan views of the cell are shown in Figure 4. 3. The pressurized consolidation test apparatus is shown in Figure 4. 4. Pressure sources including two nitrogen tanks were hooked up as shown schematically in Figure 4. 5. The ring container shown in Figure 4. 3 takes samples 3 inches in diameter by 3/4 inch high. The O-rings ensure that no nitrogen gas gets to the top of the sample. Drainage is permitted only through the lower porous stone as pressure is applied to the flexible rubber membrane on top of the sample. Pore water pressures may be measured through the small upper porous stone contained in the metal measuring area. A small polyethylene tube leads to valve C and a pressure transducer. The yoke transmits consolidation movement to the displacement transducer which is held vertically in the perspec chamber located under the consoli- dation chamber. 4. 4. Special Test Procedures The sludge sample is prepared in the same manner to that used for the conventional type cell (Section 3. 3. l). A handbook provided with the pressurized consolidation cell provides detailed information on prepa- ration of the apparatus, test procedures, and sample removal. These procedures were modified to permit use of the displacement transducer 33 for measurement of consolidation and to use the nitrogen pressure source. These procedures are summarized below. The lower porous stone shown in Figure 4. 3 was flooded with de- aired water using valves B1 and B2 as inlet and outlet. The sample ring containing the prepared sludge sample was placed on top of the lower porous stone and inside the lower O-ring. Care was taken to prOperly place the sample ring container and both O-rings. The t0p drainage lead connects valve C to the center spigot of the diaphragm. Next the sample was flooded with a small amount of de-aired water, about 1/8-in. in depth, before placement of the flexible rubber diaphragm. Valve C and V8 (Figure 4. 5) leading to the de-airing cell was Opened. Pushing lightly on the surface of the membrane simultaneously with application of suction forces air out followed by the water. This removes all air which may have been trapped between the diaphragm and the sludge surface. Next the top bar of the yoke was replaced making sure that the cen- ter screw was released to its full extent. Using the center screw located in the top bar the transducer core was adjusted to allow for its full linear range. The air release valve located at the top of the confining chamber was opened and this chamber was placed on the central boss of the center plate. To commence the test the two transducers were connected to their respective recording units which had been previously calibrated. The units were adjusted to the desired zero setting. Next valves V3, V5, A, V7, B1, and B2 (Figure 4. 5) were opened. The load pressure and back- pressure were applied from tank 2 in small increments using valve V2 allowing time for equalization at each stage. Depending on the test procedure to be followed pressures were increased to 20, 127 or 250 psi. The latter value equals the cell capacity. The sample was now permitted to stand with back pressure for about 70 hours. Volume change resulting from application of the pressure was recorded by the displace- ment transducer. Before starting the loading sequence valve V5 was closed, pressure from tank 1 was adjusted to the desired value, and valve V4 opened. For most tests where the backpressure used was equal to 20 or 127 psi, load was applied on tOp of the sample by adjusting valve V1. When the initial backpressure was 250 psi, loads were applied by reducing 34 the backpressure by increments while holding pressure on top of the sample constant. Tank 1 (Figure 4. 5) maintained pressure on the top sample surface while tank 2 provided the backpressure. Each increment was maintained for a 24-hour period while consolidation displacement and pore water pressures were recorded by means of the transducers. Recorders were reset before each load increment. An electric timer was used for convenience and as a check on chart speeds. The number of load increments was limited by the size of each increment and the 250 psi cell capacity. On completion of the test valves V1 and V2 were closed and V5 opened. The cell was slowly depressurized by Opening the air release valve. The sample was removed and both wet and oven dry weights were obtained. A11 consolidation tests were run at room temperature except those in which temperature was considered as a variable. For these tests the preSSurized consolidation cell was placed in an insulated box and warmer or colder temperatures were maintained either by adding heat by means of a light bulb or cooling by means of refrigeration. Test tempera- tures were maintained to better than i 0. 3 0C. 35 (b) Load frame with consolidation unit. Figure 4. 2. Consolidation test apparatus. l7 12___\ ll—_\ 10-——q Figure 4. 3. 36 16 I5 14 " O... a. -"7.'\ O 7". (_‘J‘, 9" .r C flh’fi'n fl #19 Pressurized consolidation cell. w 18 Sample Sample ring Porous stone Flexible rubber membrane Tapered internal ring Metal measuring area Upper porous stone Lower O-ring Sample ring container Upper O-ring Consolidation cell ring 12. Lock nuts 13. Tap drainage lead 14. Knurled nuts 15. Center screw 16. Air release valve 17. Clamping screws 18. Drainage plug 19. Displacement transducer esPH HUI-0 ~9 99s 0 m 37 '-u «on, ‘ . (b) Consolidation cell, pressure gauges, timer, recording unit, and hook- up accessories. Figure 4. 4. Pressurized consolidation test apparatus. 38 .39me maneueame ammo noflmpSOmcoo peumusmmoum .m .v ouswrw condom ousmmeum semoufiz g , NeodpmcMuH omsmO ousmmoum eudmmeum mm L dim/l :8 .4 Zoo mcwfimefl N H *7 coarse xceh. xceh. v g nSOmcoo m> Hm emsmu enemmoum . > m> 0.? oUNSOm hwy“? CHAPTER V EXPERIMENTAL RESULTS The experimental results include data showing how different varia- bles influence the consolidation behavior of pulp and papermill sludges. These variables include load increment ratio, initial solids content, degree of saturation, organic content, admixtures of lime or flyash, and temperature. The experimental data are summarized in Tables 5. l to 5. 7. Dial reading-logarithm of time curves for selected load incre- ments, and void ratio-logarithm of pressure curves are shown in Figures 5. 1 through 5. 14. Complete test data are given in Appendices A and B. 5. 1. Load Increment Ratio Load increment ratio refers to the magnitude of each successive load to the preceding total load for the consolidation test. When the load is applied in increments so that each increment equals the previous con- solidation pressure the load increment ratio equals unity. Typical dial reading-logarithm of time curves for sludge H-Z are shown in Figure 5. 1 for load increment ratios of l. O, 0. 75, O. 50, and 0. 25. Consolidation data are summarized in Table 5. 1 with Cv’ k, and r, based on the square root of time curve fitting method. All tests were started at an initial solids content close to 35. 5 percent. Average loads for the curves shown in Figure 5. l are fairly close ranging from 0. 344 to O. 549 kg per sq cm. The void ratio-logarithm of pressure curves‘in Figure 5. 2 are essentially parallel, hence the compressibility of sludge H-Z at a given stress appears to be unaffected by load increment ratio. Appendix A includes the eXperi- mental data for tests A-6, A-7, A-8, and A-9 with different load increment ratios. 5. 2. Initial Solids Content Initial solids content refers to the ratio of dry solids to the total wet weight of the sample in percent at the start of the consolidation test. Tests A-l, A-2, and A-5 on- sludge H-Z with initial solid contents of 36, 41. 5, and 48. 5 percent, respectively, were run in the conventional oedometer 39 40 using a load incrvnu-nt ratio of one. Consolidation data are summarized in Table 5. 2 with cv, k, and r based on the square root of time curve fitting method. Appendix A includes the experimental data for the typical dial reading-logarithm of time curves (load of 0. 5 to l. O kg/cmZ) shown in Figure 5. 3. The rate of consolidation appears to decrease with increase in solids content. Test A-5 with 41. 5 percent solids, run about 4 months after tests A-1 and A-2, gave a value for cv slightly greater than test A-Z with 48. 5 percent solids. This may have been caused by partial decomposition which reduced the pore space available for flow during the 4 months storage. Typical dial reading-logarithm of time curves for sludges H-3, D-1, and C-2 shown in Figure 5. 4 illustrate different shapes characteristic of the three materials. Sludge C-Z with the lowest initial solids content drains most readily and therefore has the largest coefficient of consoli- dation. Void ratio-logarithm of pressure curves in Figure 5. 5.for sludge H-Z shows that the compression index decreases with increase in solids content. This decrease in Cc with increase in solids content is also observed for natural sludges H-3, D-1, and C-2 shown in Figure 5. 6. 5. 3. Degree of Saturation The degree of saturation refers to the proportion of sludge pore volume occupied by water. The degree of saturation in laboratory samples varied from 96 to 99 percent after dewatering followed by careful hand placement in the consolidometer ring. High back pressures will dissolve the entrapped air thereby increasing the degree of saturation. The pres- surized consolidation cell was used in two ways. For test B-Z the sludge sample was subjected to a high back pressure (250 psi) with load appli- cation accomplished by incremental reductions in back pressure. For test B-5 the sludge sample was subjected to a lower back pressure 20 psi with load application accomplished by higher pressure increments on the flexible rubber membrane on top of the sample. Consolidation test re- sults for sludge H-3 are summarized in Table 5. 4 and three typical dial reading-logarithm of time curves are shown in Figure 5. 7. Results for test B-S are given in Table 5. 7. Consolidation tests which include a back pressure appear to give higher values for the coefficient of consolidation. Void ratio-logarithm of pressure curves in Figure 5. 8 show a smaller compression index for those tests which included a back pressure. Total compression appears to be reduced for those samples with a higher degree 41 of saturation because compression which occurs during application of the back pressure has not been included with the consolidation portion of the test. Experimental data for tests A-12, 13-2, and “-5 are given in Appendix H. 5. 4. Organic Content The organic content of sludge H-3 was altered by washing the sludge through a U. S. Standard No. 16 sieve with material passing recombined with material retained on the sieve so as to provide samples with four different organic contents. Details are given in Section 3. 3. 2. Physical properties of these recombined samples are given inTable 3. 2. Consoli- dation samples were dewatered to about equal initial solid contents by volume so as to minimize differences in consolidation behavior due to this variable. Volume rather than weight was chosen because samples with different organic contents have different specific gravities. Some diffi- culty was experienced in attempting to dewater the high organic content (67. 6%) sludge samples. The centrifuge was unable to exceed about 22. 8 percent by solid volume. Samples with 31. 3 percent organic matter required special care in handling since they would slip through the oedometer ring when the solid volume was reduced to about 23. 6 percent. Typical dial reading-logarithm of time curves in Figure 5. 9 illustrate the influence of organic content on consolidation. Void ratio- logarithm of pressure curves in Figure 5. 10 demonstrate that the com- pression index is influenced by organic content of the sludge. Experimen- tal results for tests A-13, A-14, A-15, and A-16, summarized in Table 5.5, in- clude cv, k, r, and Co for each organic content. Basic data for these tests are given in Appendix A. 5. 5 Lime or Flyash Admixtures Sludge H—2 was combined with lime or flyash (10 percent by dry weight) to determine what changes in consolidation behavior might occur. Tests A-4 and A-5 performed on samples with equal solid contents show that the addition of lime has altered the shape of the dial reading-logarithm of time curves in Figure 5. 11. The rate of consolidation is increased for combinations with either lime or flyash. Comparison of the void ratio- 1ogarithm of pressure curves for tests A-4 and A-5 in Figure 5. 12 show a small increase in the compression index. This change is smaller for the sludge-flyash combination as shown by tests A-2 and A-3. There may have been some pozzolanic reaction between the lime and sludge components 42 in sample A-4 as a small curvature is observed for the smaller pressures. The sample for test A-lO, tested eight months after mixing with lime, gave a value for CC less than when no admixture was used. Table 5. 6 gives a summary of test data with experimental results for tests A-Z, A-3, A-4, A-5, and A-lO given in Appendix A. 5. 6. Temperature Temperature influences the consolidation behavior of sludge pri- marily through a dependence of permeability on the viscosity of the pore fluid. Viscosity of the pore fluid is dependent on temperature. Permeability directly influences the coefficient of consolidation. Typical dial reading- 1ogarithm of time curves for the load increment of Z to 4 kg/cm2 shown in Figure 5. 13 give values for the coefficient of consolidation which are dependent on temperature. 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U 0 2. .o S .o S .o 0 0820 0000000090000 4004 ON 400 0N 4mm 0N 00000000 xomm 00000000 .03 3 0% .3. .03 3 .00 .3. .03 .3 .00 .2. 303 3080 00mm UowN UOQ Ohdudflavfi 3-2-2 00-0-: 00-0.70 Baa Tm m-m m-m .oz 030. 0003000040004. 0000000000 0< Tm $030 08 30300 ”.30. 80330880 .0 .m 038. CHAPTER VI DISCUSSION AND INTERPRETATION OF RESULTS This discussion and interpretation of results covers the consoli- dation behavior of those pulp and papermill sludges studied and how they are influenced by the different variables. Test variables include load increment ratio, initial solids content, degree of saturation, organic content, lime or flyash admixtures, and temperature 6. 1. Load Increment Ratio In normal routine consolidation testing of soils a load increment ratio of one is used, that is Ap/p = l where Ap is the load increment and p is the previous total load. This rate of loading can be quite different from that experienced by a soil or sludge element in a field deposit. Crawford (1964) reports that there is substantial field evidence that the prediction of consolidation settlement from laboratory tests is not always satisfactory. He indicates that much of the difficulty in predicting consoli- dation settlement from laboratory tests may be due to the great difference between rates of compression in the laboratory and in the field. Typical dial reading-logarithm of time curves shown for sludge H-Z in Figure 5. 1 illustrate that consolidation proceeds more slowly for the smaller load increments. A load increment ratio of l. 0 gives the curve characterized by the Terzaghi (1943) consolidation theory. It becomes difficult to sepa- rate primary and secondary compression using the intersection of the tangent and the asymptote to the curve for Ap/p : O. 25. Using the square root of time fitting method, values for the coefficient of consolidation were obtained at load increment ratios of l. O and O. 5. These values were plotted against logarithm of pressure in Figure 6. l. The smaller cV values correspond to the smaller load increment ratio. These results for sludge H-Z are similar to those reported for clay by Hamilton and Crawford (1959). The effect of load increment ratio on the pressure-void ratio relation for sludge H-Z is shown in Figure 5. Z. Use of fresh sludge from the papermill with special sample preparation means that any past 68 consolidation history is missing. Different initial void ratios appear to be responsible for small differences in the vertical location of the e-log p curves shown in Figure 5. Z. A small curvature at higher pressures for some of the curves appears to have been caused by limitations of the loading unit. The slope of the e—log p curves in Figure 5. 2 appear to be independent of the load increment ratio. This becomes readily apparent when CC is plotted against Ap/p as shown in Figure 6. Z. This means that the ultimate settlement in the field should be the same regard- less of the loading rate. Any influence of secondary compression on the e-log p relationship is not apparent for the 24-hour load duration used in this study. The 810pe of the rebound portion of the e-log p curves (swel- ling) appears to be slightly dependent on load increment ratio. The larger swelling index is shown (Figure 5. Z) for the smaller load increments. Dependence of the coefficient of consolidation on load increment ratio suggests that permeability will also depend on the pressure incre— ment. The Terzaghi (1943) theory of primary consolidation expresses the coefficient of permeability as C:v av Yw k : __1-+_'é_- .- (6.1) where c is the coefficient of consolidation for any load increment, v = 9—3-ng is the coefficient of compressibility, Yw is the unit weight of water, e is the average void ratio for any load increment, CC is the compression index, and p is the average pressure for any load increment. Computed values for permeability are shown plotted against the logarithm of pressure in Figure 6. 3 for three different load increment ratios. The smaller permeabilities correspond to the smaller load increments. The volume change during a given load increment comprises both primary and secondary compression. That compression described by the theory of consolidation is generally reported in terms of the primary compression ratio r. Values of r for sludge H-Z are plotted against the logarithm of pressure in Figure 6. 4 for two load increment ratios. It is apparent that a much greater pr0portion of the volume change occurs as secondary compression for the smaller load increment ratios, close to 50 percent for Ap/p equal to 0. 25. The rate of secondary compression is commonly expressed as the coefficient of secondary compression Ca. 69 This is the slope of the settlement-logarithm of time plot divided by the thickness of the consolidation sample at the beginning of the long-term or straight-line stage. Figure 6. 5 shows a plot of Cu per unit of pressure increment Ap versus the total effective pressure at the end of the incre- ment. It is apparent that the value of Ca/Ap increases rapidly with decreases in the load increment ratio. Leonards and Gerault (1961) indicated that if the load increment ratio in a field deposit varies with depth, the use of a constant value of Ca/Ap (as determined by any particular test procedure) can lead to substantial descrepancies in the predicted settlement rate. 6. 2. Initial Solids Content A description of pulp and papermill sludges generally makes refer- ence to the dry solids content. The dry solids content is related to water content which may be computed as 100 1] dry solids - (6' Z) W% =100[% W where w = WY- (100) is the water content in percent based on the dry weight of solids WS and the weight of water WW. It would be helpful if various consolidation properties of pulp and papermill sludges could be correlated with the water or solids content. These relations could per— mit preliminary estimates to be made of settlement but would not take the place of careful field and laboratory investigations. The e-log p curves in Figure 5. 5 show that the initial solids content influences the compression index. Figure 6. 6 shows that a linear relation- ship appears to exist between the compression index and initial solids content. Sludges H-2 and H-3 give different sloPes and intercepts which may be related to differences in sludge composition shown in Table 3. 2. The decrease in compression index with increase in solid content (lower w or lower e) has been observed for peat (MacFarlane, 1969) and natural clays (VanZelst, 1948). The rebound portion of the e-log p curves in Figure 5. 5 indicate that the swelling index is appreciably greater for the 36 percent solids content as compared to higher values. These data show the need for careful laboratory consolidation tests before attempting to predict ultimate settlement in a field sludge deposit. 70 Dial reading-logarithm of time curves in Figure 5. 3 show the greatest volume change for the lowest solids content as would be expected. This should give the larger coefficients of consolidation for the lower solids content which is the case as shown in Figure 6. 7. The square root of time fitting method was used to obtain cV values. Results from test A-S do not agree but when the delay in testing (about four months) is considered the reason may be slow decomposition. A slight change in color and a small change in workability had been observed. Gupta and Swartzendruber (1962) reported that growth of bacteria within quartz sand had been found to influence flow behavior. It is reasoned that decom- position is responsible for partial blockage of the pore Openings reducing the permeability. As load increments increased, larger initial hydraulic gradients gradually overcame the influence of the decomposition bringing these Cv values up to the level expected for the intermediate solids content. The coefficient of compressibility has been plotted against void ratio in Figure 6. 8 for sludge H-Z at three initial solid contents. A non-linear relation is shown to exist with values of av increasing more rapidly for the higher solid contents at lower void ratios. This behavior is similar to that reported for peat (MacFarlane, 1969). The relationship between permeability and log pressure in Figure 6. 9 for sludge H-Z at three initial solid contents is consistent with consoli- dation theory. Larger permeabilities are observed for lower initial solid contents. Larger pressures reduce the pore space available for flow with the consequent reduction in permeability. More primary consolidation at the lower solids content, as shown by Figure 6. 10, may be a result of the greater permeability. ' At higher solid contents a larger proportion of the total water content will be held by adsorption on particle and fiber surfaces which would contribute to more secondary compression. 6. 3. Degree of Saturation The degree of saturation influences soil consolidation rates for two reasons (Lowe III, et al. , 1964): (1) gas bubbles in partially saturated soil are highly compressible as compared to relatively incompressible water occupying the corresponding pore space, and (2) gas bubbles in partially saturated soil impede the flow of water thereby reducing the soil permeability. Variable head permeameter test data (Andersland and Laza, 1971) showed that gas bubbles entrapped within pulp and papermill 71 sludges have a very significant influence on sludge permeability. Increasing pressures reduce the bubble size according to Boyle's law and will dissolve entrapped air according to Henry's law (Bishop and Eldin, 1950). Per- meability is related to the coefficient of consolidation according to equation (6. l). Backpressures were applied for 70 hours before starting consoli- dation tests B-2 and B-5. During this time sample heights were reduced and new initial heights were recorded before start of the incremental loading. This initial reduction in void ratio may be reSponsible for dif- ferences in compressibility shown by SIOpes of the curves at a given pres- sure on Figure 5. 8. Total compression after start of the incremental loading was reduced as given by vertical differences in data points at the higher pressures. The swelling index was reduced for those samples which included a back pressure. , The values for the coefficient of permeability from Table 5. 4 plotted against logarithm of pressure in Figure 6. 11 show an increase when back pressures were used. It appears that a constant back pressure technique (test B-S) may be more effective in increasing the rate of consoli- dation. The increase in cv values correlate with the increase in permea- bility shown in Figure 6. 12. Similar observations were noted by Lowe III et a1. (1964) for an organic silt. Secondary compression rates appear to decrease when back pres- sures are used as shown by data in Figure 6. 13. No change in primary compression ratio was observed. Measurement of excess pore pressure dissipation at the undrained sample surface was attempted using the pressurized consolidation cell. Experimental results for sludges H-2 and H-3 are shown in Figure 6. 14. When small pressure increments were applied, most of the measured excess pore pressures generally dissipated more rapidly than those pre- dicted from the Terzaghi (1943) model. When about 80 percent dissipation was reached measured pore pressures dissipated more slowly as shown in Figure 6. 14a. Large pressure increments gave fair agreement be- tween experimental and theoretical pore pressure dissipation (Figure 6. 14b) up to about 70 percent when observed pore pressures dissipated more slowly. Hence calculation of the coefficient of'consolidation from compression- time curves using curve fitting procedures based on the Terzaghi model 72 appears to be meaningful only for high pressure increments and the initial 70 to 80 percent pore pressure dissipation. Field prediction of time-rate of settlement in sludge landfills may be limited to procedures described by MacFarlane (1969). 6. 4. Organic Content The mechanical change of organic content used for sludge H-3 was intended to give some insight as to possible changes in the consoli- dation behavior during decomposition. The experimental results discussed below go beyond this in providing a qualitative picture useful for organic soils and sludges produced at other organic contents. The void ratio-log pressure curves in Figure 5. 10 show that the compression index increases with organic content. The swelling index obtained from the rebound curves also increases with higher organic con- tents. Difficulty in preparing samples with exactly the same initial solid content by volume introduced some scatter when plotting Cc versus organic content. Compression indexes available for several solid con- tents by weight (test: A-ll, A-12, and A-l6) with the same organic content give a linear relationship as shown in Figure 6. 15a. Assuming that this linear relationship holds for organic contents of 31 and 50 percent, compression index values for the four organic contents are extrapolated to a solid content by volume of 22. 8 percent. These interpolated values for CC when plotted against organic content (Figure 6. 15b) suggest a linear re- lationship. Arman (1969) reported that the compression index for organic soils increased with increases in organic content. One of the basic assumptions in Terzaghi's (1943) consolidation theory is that soil parti- cles are incompressible. Compressibility of the organic fibers may be responsible for this change in compression index with organic content. The dial reading-logarithm of time curves in Figure 5. 9 illus- trate that the lower organic contents give the more typical S shape. Separation of primary and secondary consolidation using the intersection of the tangent and the asymptote to the curve is more distinct for the lower organic contents. This is in agreement with Arman (1969) who stated that the shape of the compression curve is dependent on both the organic content and the loading intensity. Changes in the compression curve also alter the coefficient of consolidation. Values for cv obtained by means of the square root of time method are shown in Figure 6. 16. A significant 73 increase in cV with increase in organic content is noted for the lower pressures. Higher permeabilities for higher organic contents shown in Figure 6. 17 appear to be responsible for the larger cv values. Increase in permeability with increase in organic fiber content has also been ob- served by Arman (1969) for organic soils and by Andersland and Laza (1971) using a variable head permeameter for pulp and papermill sludges. MacFarlane (1965) in his literature review reported that the permeability of peat decreased rapidly with compression. Increase in organic content appears to reduce the amount of pri- mary consolidation as shown in Figure 6. 18. Organic soils in general are noted for large secondary consolidation. MacFarlane (1969) reported that secondary compression may account for as much as 50 percent of the total settlement in peat. 6. 5. Lime or Flyash Admixtures Lime or flyash may be added to pulp and papermill sludges to improve their dewaterability (NCASI Tech. Bull. 136, 158, 190). Certain reactions with the sludge components will influence subsequent consoli- dation behavior. Lime-sludge reactions have been briefly reviewed in Section 2. Z. Z. 2. Values for the coefficient of consolidation given in Table 5. 6 are plotted against the logarithm of pressure in Figure 6. 19. A large increase in cV is shown for the lime-sludge combination at low pres- sures with the magnitude becoming less as pressures increase. A smaller improvement in eV is shown for the flyash-sludge combination. This in- crease in eV for sludge containing admixtures of lime or flyash will help accelerate the primary compression process in a sludge landfill. Less time will be needed to reach the ultimate settlement. A comparison of void ratio-logarithm of pressure curves for tests A-4 and A-5 in Figure 5. 12 show that sludge combinations with lime gave a small increase in compressibility resulting in a larger compression index. Tests A-2 and A-3 show that the flyash was less effective in increasing the compression index. These increases in Cc mean that ultimate settlements in a landfill should be greater for those sludges containing lime or flyash admixtures. Permeability data for combinations of sludge with lime or flyash are summarized in Table 5. 6. The plot of permeability versus logarithm of pressure in Figure 6. 20 shows a significant increase in k for the 74 sludge-lime combination at lower pressures. The magnitude of change decreases as pressures increase. The sludge-flyash combination shows a smaller increase in k. This increase in k correlates with the increase in cv shown in Figure 6. 1‘). Primary compression ratios for tests A-4 and A-5, given in Tables 5. 6 and 5. 2, are plotted against logarithm of pressure in Figure 6. 21. The addition of lime appears to reduce the amount of primary consolidation. Increase in pressure appears to reduce r for no lime and increase r with lime. The coefficient of secondary compression, plotted against logarithm 'of pressure in Figure 6. 22 shows a decrease when sludge is combined with lime. Experimental error masks out any influence of pressure on Ca' 6. 6. Temperature Pulp and papermill sludges placed in landfills may be subject to temperature change caused by energy released during sludge decomposi- tion. Temperature change will alter the consolidation behavior of the sludge. The Terzaghi (1943) theory for primary consolidation expresses the coeffi- cient of consolidation eV in terms of the coefficient of permeability k, the coefficient of compressibility av, the void ratio e, and the unit weight of water Yw’ Assuming that k is constant and using the average e for each load increment gives the equation c : k(l+e) . (6.5) V a VYW Corrections to k (Terzaghi and Peck, 1967) due to temperature related changes in viscosity are given by equation (2. 3). Thermal expansion of the soil or sludge components is a function of temperature. Campanella and Mitchell (1968) have shown that pore pressure changes are dependent on soil compressibility and the pore water volume change caused by a temperature change. They explain permanent volume decrease in terms of physico-chemical structural adjustments which are induced by tempera- ture variations. Typical dial reading-logarithm of time curves in Figure 5. 13 give values for the coefficient of consolidation which increase with higher temperatures. This is shown more clearly when cv values from Table 5. 7 are plotted against logarithm of pressure as shown in Figure 6. 23. 75 Finn (1951) indicated that cv may be corrected for change in viscosity of the pore fluid by the relation -- (6. 6) where the numbers refer to the appropriate temperatures. This relation- ship gives values of cV adjusted to 22 0C as shown by the dashed lines in Figure 6. 23. The derivation of equation (6. 6) is based on equation (2. 3) which assumes that the coefficient of viscosity of the water is independent of porosity, hence this fact may account for part of the difference between measured and adjusted values of cv in Figure 6. 23. Campanella and Mitchell (1968) have observed that the equilibrium void ratio for clay soils is dependent on temperature. The three loading curves in Figure 5. l4 and a given pressure illustrate this for the pulp and papermill sludge. When equilibrium void ratios and the small difference in unit weights of water are also accounted for, adjusted cv values appear to be in reasonable agreement with measured cv values. Consolidation tests are required to determine the equilibrium void ratio for a given temperature. Void ratio-log pressure curves in Figure 5. 14 are essentially parallel indicating that the compressibility of the sludge at a given stress is unaffected by temperature. Similar observations have been made by Campanella and Mitchell (1968) and Firm (1951) for clay soils. Figure 5. 14 shows that the higher the temperature, the lower the void ratio. Since the void ratio of all samples were essentially the same prior to the initial stress application, the successively lower void ratios must be due to the higher temperatures. Campanella and Mitchell (1968) noted the same behavior for saturated illite and explained that weaker soil structures at the higher temperatures must densify in order to carry the effective stresses. It appears that once equilibrium has been established between the sludge structure, temperature, and stress, the different temperatures have no additional effect on the amount of consolidation. The coefficient of permeability computed on the basis of equation (6. 1) using observed values of cv, a and e are summarized in Table v, 5. 7 and plotted in Figure 6. 24. Larger k values at warmer temperatures and lower pressures appear to be primarily due to the lower water vis- cosity. Equilibrium void ratios will change with temperature. The 76 influence of temperature on the permeability becomes almost negligible at a pressure equal to 10 kg/cmz. Primary compression ratios for consolidation tests on sludge H-3 run at 6°C and 38 0C are summarized in Table 5. 7 and plotted in Figure 6. 25. The decrease in r with increase in temperature is fairly signifi- cant with over 40 percent secondary consolidation at 38 0C. Values for the coefficient of secondary compression, plotted in Figure 6. 26, show an increase with increase in temperature. Leonards and Girault (1961) stated that secondary compression cannot be attributed to viscous drag (or other mechanisms) associated with the orientation of polar molecules in the vicinity of clay particles, although the rate of secondary compression is influenced by this factor. Campanella and Mitchell (1968) explained the influence of increased temperature on secondary compression in terms of the strength of the soil structure. An increase in temperature causes a decrease in the shearing strength of individual interparticle contacts. This decrease in interparticle bond strength may be considered to result from the increase in thermal energy which acts in conjunction with the shear force at interparticle contacts to increase the probability of bond slippage or failure. As a consequence there is a partial collapse of the soil structure, and a decrease in void ratio until a sufficient number of additional bonds are formed to enable the soil to carry the stress at the higher temperature. This explanation may also be applicable to pulp and papermill sludges. It may be reasonable to conclude, within limits, that a larger temperature increase will induce higher secondary com- pre 8 sion rates. 77 004000 0000000004 40004 o>$ 00 N44 0040540 000 00000000 00 4005400004 0:000> 00400404400000 00 00040400000 0000\0v4 a .0050000n4 04 04 . 0 N N 0 .4 0 .0 4 .0 «i 4 a _ J A q 4 4 4 S q . 4 q 7 . q 4 x a \ m x Y 0 0 n a x 1 x 9 m. B D D B \ L a O .H ul- duIQI I! g I. “000000 0400000 0.00 .00 L N-m 00030 .00 00:00.0 o Sod m 9 H. m. 9 W 0.. N8 0 o O U S m- m W mood m D A‘ m. . 2 25.0 'utm/ 78 1‘5 . Sludge H-2 43. 6% Organic content 0 U >45 0) l O _A A "g — -C‘r V v— 0— c. .9 U) (D 0 3 o 5 g ' I U E L L L J J 0 0.25 0.50 0.75 1.0 1.25 Load increment ratio, Ap/p Figure 6. 2. Compression index versus load increment ratio for sludge H-2. 80 0° 1*- ‘7 ‘ 21:10 O .3 __ P n: 70 )- . c: G + .2 0 m U) 2 0. 60 F E O U i? Q 090 5 5° 5 \g_ AP-zo.zs 04 0 We 40 l I 1 1 L1 L11 0 L A A I 11111 __i 0.1 0.2 0.4 1.0 2 10 Pressure, p kg/cm Figure 6. 4. Primary compression ratio versus logarithm of pressure for sludge H-Z at two load increment ratios. 79 6. 0F a Sludge H-Z A . 43. 6% Organic content 5. 0 . 4. 0 P o o A 3 A \ J : l O E p u a? 3. 0L 0 x 0. 75 .34 0 >1 u 2. 0 .. A 2‘3 0. 50 .o ‘3 8 ° . u a A ‘3 l. 0 r- 0 . in} c: .2 o A L o a O r. 0 o o 8 0.0 J 14;;1L1] 1,1 lejlio J 0. 2 0. 5 l. 0 Z 5 10 20 Pressure, p kg/cmz Figure 6. 3. Coefficient of permeability versus logarithm of pressure for sludge H-Z with different load increment ratios. .~-m omega .8“ spammed mo EzfiummoH msmum> ousmmoum fies you nommnouafluoo .Cdvaouom mo 3333000 .m 6 0.3me ~80\mx a .0usuuoum 80 on o“ v N acouaoo ufiaamuo ebo .mv Ni $33 9 .H fiqJ I a q q 1 ~.o 6 16° .0 land Jmné lend mm .o flit/21113 'd/OQ ‘axnssszd nun/noissazdwoo Arepuooas }o zuspggeog 81 r Test nc. A-Z Sludge H-2 48 0 Organic content 43. 6% 3 44 >‘ 4- .0 2S . A-lZ A-S “ ‘ -11 '- E L A o 8 4o _ " Sludge H-3 .3 Organic content 22‘ 40. 4% ‘ -16 o - A a) '3 A-l I: 36 __ ‘K 1 . 1 l l l l . 0. 7 0. 8 O. 9 l. 0 Compre s sion index, C c Figure 6. 6. Initial solids content versus compression index for sludges H-2 and H-3. > o c? 10 ,. Initial .2. solids content «3 Test no. "a 3 Q 36. 0% m 0 A_l 3 5 C ' 5 o 0 ‘3'} L a 48.5% a 2 a . A-S D. O .5 + a gm. 0 41. 5% A l A '3 S A—Z I: . ‘3 N 0 l 1 1 1 1 J— 8 0.5 1. o z 8 12 Pressure, p kg/cm Figure 6. 7. Coefficient of consolidation versus logarithm of pressure for Sludge H-Z with three initial solid contents. 82 3. 0 " Sludge H-2 43. 6% Organic content a 2. 5 P no i Initial solids NE content 36. 0% u * 2. O .3 I 55 5 .o -; l. 5 _ m o H o. E 0 U o “-0 f3 1' 0 ~ 41. 5% A c .3 .2 m 8 U 0. 5 ’ 48. 5% A 0 a E A C (1 c/A/O 0, 3:1, A’O 1 1 1 J 1.0 1.5 2.0 2.5 3.0 3. Void ratio, e Figure 6. 8. Coefficient of compressibility versus void ratio for Sludge H-Z. with three initial solid contents. 83 ' 8 ermeability, k, x 10' N o T )2. L» O T 0 Initial solids content 36. 0% 8C b cm 1—1 O Coefficient of J 0. l 0. 2 0. 4 l. 0 2 4 2 10 20 Pressure, p kg/cm Figure 6. 9. Coefficient of permeability versus logarithm of pressure for Sludge H-Z with three initial solid contents. 80 F o s g: 36. 0% solids 3 o 2 7° "' 48.5% solids I3 .2 El 3 1:1 0 a. E 60 1- O U >~ In. E H a. 50 _ l - 1 J J l 4 1 _L J l m 0.1 0.2 go.4 1.0 2 3 10 Pressure, p kg/cm Figure 6. 10. Primary compression ratio versus logarithm of pressure for Sludge H-Z with different initial solid contents. ,-/ min N V Coefficient of consolidation, c , in Figure 6. ll. (1 Coefficient of secondary compression, C 0.015 0. 010 0. 005 0. 03 0. OZ 0. 01 Figure 6. l3. 84 p 8 Test no. 3720 p81 back pressure . 13-5 . A 2 M A Decreasing back pressure F No back pressure 1 1 l l 1 j s L J 0.1 0.2 0.4 1.0 2 4 26 8 10 20 Pressure, p kg/cm Coefficient of consolidation versus logarithm of pressure for Sludge H-3 with different back pressures. F’ 6 N b k Test no. [ c; ac pressure A-lZ 4.x - v— .0 Gt El 20 psi back pressure A __ 6 s-——a— B-Z Z A Decreasing back pressure El 4 m'LL1J11L u 1 L 11111Ll. 4 0.1 0.2 0.4 1.0 2 4 6 810 20 Pressure, p kg/cm2 Coefficient of secondary compression versus logarithm of pressure for Sludge H-3 with different back pressures. 85 E] 50 _ o 40 __ o D \ E o co 'o .. 30 j_ A N '5‘ Test Back >1 No. Pressure a O B-5 constant In ‘ g 20 _ B-Z decreasing E A-IZ none 0 o. ‘04 o u a o o D O 1 1 L14111l 1 1 11L1LL" J 0. l 0. 5 l. 0 2. 0 10 20 Pressure, p kg/cm Figure 6. 12. Coefficient of permeability versus logarithm of pressure for Sludge H-3 with and without back pressures. 86 Ana omm on. 3% 3050605 memo." 4mm m 6mm 02660.3 xoan £13 0356 A3 008.26 @059..st 05 us :oflmawmmmv 0udmmoum 0.3a mm0ox0 fidoflouoofi was Haucgnmuomxm A: .o 0.33% n 0358 .085. com com co con cm 3 m . c A m .oL T‘ 1 ‘ Iofiu'1’dd+ q .1 d. -ddd q d I ‘ ‘ “‘1‘ 1d .‘ 1 ‘ 0°" j X m 1 S m 9 9 1 w J a 1 d 3 a B 8 n 1 I 05:30 33053093.“ I M. I no 0?:5 aaofiaogfi. s. 0 0:16 o¢ .m , w . m. , .u I O % x / o~ Na 6 n 03.2 3050.35 v.34 0 «ma omm on. mvN u 3050.35 @004 I won m .vMN n 05500.2» xodm / ~-m .oz :3. .0: omega .0... ................ 87 Am; NNH 3 mo 3080.83 Umofi .mmm or 0u:mm0um xomn .Num 0mvsfim 3v 0035.0 “00509.13 05 94... "83030020 0usmm0um 0.8a .3033 3030.209: van HmuG0EC0mxH ASL .o 0.33M m 0358 .085. on: o~ ogv o.N OZ” and N6 0 - 4 q q q 1. a q 1 A q . . on: 3 n o a 8 a d m 1 0 IA cm a .d J a q a s m o a q 1 3 m aducoemugwxm : w. d 0 3030.393. l:- W I m. d/ m» o L o¢ % O J a 4 ON 4 so .0 u 030.“ 3080.85 @004 Ga 34 3 3 u 30820:. 084 /. «mm 2. n 0.3000um xomm 0’0] r. . Tm .oz :8. .~-m «33m 0 Sludge H-3 1. 00 F st Organic content U 49. 5 % by wt. 0 x“ O. 90 L 0 11 .S G .3 3’, 0. 80 , 0 L. o. E o L) 0.70 . n *e; 1 ' *4 37 38 39 40 41 42 Solid content % by wt. Figure 6. 15a. Extrapolation of compression index to the same solid content. l. 20 _ 0 0 Initial solid Organic Compression ~ 1- 00 * content % content index 23 by wt. by vol. % by wt. extrapolated '3 35.2 22.8+ 67:6 1.15 ‘3 c) 37.6 22.8 49.5 0.99 g 0 80 _ 38. 7 22. 8 40. 4 0. 91 '3 ' 39.9 22.8 31.3 0.86+ 0 u o. E U 0. 60 l I j 1 J J 40 50 6O 7O 80 Organic content, % by wt. Figure 6. 15b. Organic content versus compression index for Sludge H-3. .Bcounou amnmwuo €28pr fir.» mum 0338 no.“ 9330.3 «0 EniHmon msmuo> coflmgflomnoo mo 330E300 A: .c ouswfih NEo\m& a .ousmmounm 89 0.2 06 o.~ o.” «0.0 N6 .1‘ _ q + _ 4 1 o O m 4" b m M E m . 8 .o w 0 To. a o u 9 :.< m. 1 . I. no 0 w. nu. o .u A... m Am mo 6 mwc a .NN v .3. £19 / 7mm m 6* 311w .m... .I w.- web 19%. u .3» .3 .N. .s - mEHOm acoucoo .oZ 2 4 .o: no Han—m5 omcmmuo amok. u .H. m-$ wmpgm 90 .mnuoucoo owcdmuo E3023 53> T: @338 com ousmmoum mo Ecumumwofi msmuos. ESBmoEuom mo «comoflmooo .: .o 0.3th NEo\mx a .ousmmoum ma 3 04V 0.N o; «0.0 Nd 1| 4 a . l _. . _ . q 1 . Jr 0. 19 l om d a J / a m P o. m7<31< 31< 21¢. l 3. M .0: no u .H x. x m _ 8 1 co m 0.3 m: 3-... V ~.~N ¢.o¢ 31.9 a ~.m~ m .ov E1< o m.- Pfio m~u< 40> 3 .\. a. 1 mpSOm 30300 .02 ow 33¢: 01.8qu “mom. T: 033m 0 m o3 .muconcoo owcmwuo “sought £3. mnm omvgm “Ow oudmmoum mo Ecfiumwofi mdmuo> 03w“ cowmmouQEoo >umemunw .m: .0 0.3th Eo\mx a .oudmmounm 91 S. v N N o A v .o N .o H.o fil fl 4 u a fl - q q q _ q q q q 4 d‘ u d . v o d I O O m. P 2}. O m 1 0.0 m m m o a m 8 AV m. 4 1 w.o I w ‘m. m~u< J 0.3 m .3 2-... .8 $8.. 1 on m .NN o .nw ch< 40> c3 axe om. moSOm 30300 .02 335 oficmwuo noon. Tm omega inZ/min c x10-2 V Coefficient of consolidation, Figure 6.19. 92 O 1. Sludge H-2 43. 6% Organic content Test Initial Admixture No solids 10 0/o _ ‘70 by wt. dry Wf.'_.-__-.. A-Z 48. 5 none 0 - A-3 46. 5 flyash A-4 41. 5 lime A-S 41. 5 none 0 .- 0 .. 0 Test no. 011. A-S A-Z A-3 A-4 1. 0 2 4 10 20 Pressure, p kg/cm Coefficient of consolidation versus logarithm of pressure for Sludge H-Z combined with lime or flyash. 93 80 F 0 7O __ 6O __ 0 Sludge H-2 3 50 __ 43. 6% Organic content U") E Test Initial Admixturc 0 No. solids 10 % 00 9'0 by wt. dry wt. '0 13-2 48. 5 none ._. 40 A-3 46. 5 flyash V- " A-4 41. 5 lime x A-S 41.5 none E5 '3': a) 30 L E 0 <1) :1. ‘5‘ Test no. E A -5 A-Z A-3 A-4 .93 20 _ U E o 8 10 ,.. O 0.3 1 O 2.0 4. 0 10 12 Pressure, p 1 fflEamEuva wo “comowmoou 62m .0 madman Eu w a 6.26m“: N \ x m ma 0; w o w. N o; v.0 Nd ~.o :1I. - u a 4 . :1! s M a 4 q q u _ d . O _ I n d O 4 9 Doc 4 D 1 m 0 n om H m“ a a m o O UONN .m: 4 ov a J m s e 0.. m .m. 1 oo . x. X m . 8 00% 1 om w ougmuomfimfi V o m .95 >3 sew Av 2 unoncoo mUSOm H.335. L sew .ov ucmucoo oflcdwuo OOH 9m mmeflm 97 Sludge 11-3 4]. 2% by wt. initial solids content ‘4 Temperature 9) O. 8 __ 60C {‘3 ._ Q Q. 0 '0' ____0______. c: 0 o '63 U) 3 0. 6 _ g‘ A A 8 38° c A. >. t:- A 9 .§ 0. 5 1.. .— D4