LCA DATA GAPS IN FEEDSTOCKS OF BIOBASED PLASTICS By Alix Andra Grabowski A THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of Packaging – Master of Science 2013 ABSTRACT LCA DATA GAPS IN FEEDSTOCKS OF BIOBASED PLASTICS By Alix Andra Grabowski Bioplastics are a growing field, but with their expansion comes unique environmental issues associated with the cultivation and processing of feedstocks. Availability of appropriate, high quality data is a problem in life cycle assessment (LCA) of biopolymers and other biobased materials that limits the accuracy and usefulness of study results. It is therefore critical that these data gaps be closed. In order to determine what data is needed to close these gaps, this study reviews currently available life cycle inventory data for biobased polymer feedstocks, and assesses the data quality for the selected feedstocks of corn, sugarcane, and soy. Life cycle inventory databases and relevant publications were searched for appropriate data, and the results collected into a summary table. The quality review was conducted using a pedigree matrix type scoring system which was adapted from the ILCD handbook, and an overall quality score for each dataset was calculated based on the matrix scores. A total of 287 datasets were collected during the review for a total of 22 different feedstocks. The majority of these datasets are from Europe and the USA, with the majority of Asia, the Middle East, and Africa having very limited data available. From the quality analysis, it was determined that more datasets that capture regional variations in crop cultivation are needed, as well as more data on land use change. Additionally, for the processing phase of production there is a need for more recent and better documented data. ii ACKNOWLEDGEMENTS My sincerest thanks to Dr. Selke for all her help and her phenomenal patience with my many questions, and Dr. Auras for explaining LCA to me three million times despite the numerous blank stares he received in return. I’d also like to thank the Center for Packaging Innovation and Sustainability for graciously funding the project, Dr. Narayan for serving on my committee, and Dr. Patel for taking the time to call into our meetings despite the time difference. A special thanks to Alison Schuitema, for never complaining when I asked her for help with a tedious job. I couldn’t have done it without you. Thank you also to my family. You supported my decision to go back to school even though I suspect you secretly thought I should just get a real job. Last, but certainly not least, thanks to Brittany Burns and Juliana Arango for all the hours spent writing at coffee shops, tea houses and libraries; for making me laugh harder than I ever have; for listening to me whine about every class, paper, and deadline; and for generally making grad school the best time of my life. I might have been able to do it without you, but it wouldn’t have been nearly as fun. iii TABLE OF CONTENTS LIST OF TABLES........................................................................................................... v LIST OF FIGURES ....................................................................................................... vii 1. INTRODUCTION .................................................................................................... 1 2. LITERATURE REVIEW .......................................................................................... 5 3. METHODS ............................................................................................................ 10 4. RESULTS AND DISCUSSION .............................................................................. 19 Data Availability ........................................................................................................ 19 Quality Analysis ........................................................................................................ 27 Technological Representativeness ....................................................................... 33 Geographical Representativeness ........................................................................ 35 Temporal Representativeness .............................................................................. 37 Completeness ....................................................................................................... 38 Uncertainty ........................................................................................................... 39 Processing Data Quality ........................................................................................... 40 5. CONCLUSIONS ................................................................................................... 45 APPENDICES .............................................................................................................. 46 Appendix A: Ecoinvent Uncertainty Scoring Information ........................................... 47 Appendix B: Completeness Check ........................................................................... 48 Appendix C: Data Quality Ratings ............................................................................ 65 Appendix D: Processing Data Completeness Check ................................................ 84 Appendix E: Processing Data Quality Ratings .......................................................... 98 Appendix F: Data Summary Table .......................................................................... 111 REFERENCES .......................................................................................................... 293 iv LIST OF TABLES Table 1 - List of publications searched………………………………………………………………………..10 Table 2 – Definition of evaluation categories adapted from the ILCD Handbook……….13 Table 3 –Quality Rating Definitions adapted from the ILCD Handbook………………………14 Table 4 –Pedigree Matrix Data Quality Rating Level Definitions adapted from van der Berg et al………………………………………………………………………………………………………16 Table 5 – Quantity and type of data collected…………………………………………………………….19 Table 6 – Data Availability by Country…………………………………………………………………………25 Table 7 –Corn Dataset Names and Identifiers……………………………………………………………..28 Table 8 – Sugarcane dataset names and identifiers…………………………………………………….30 Table 9 – Soy dataset names and identifiers………………………………………………………………..30 Table 10- Ecoinvent Uncertainty Scoring Information…………………………………………………47 Table 11 - Corn Cultivation Completeness Check………………………………………………………..48 Table 12 - Sugarcane Cultivation Completeness Check………………………………………………56 Table 13 - Soy Cultivation Completeness Check………………………………………………………….61 Table 14 - Corn DQR……………………………………………………………………………………………………65 Table 15 - Sugarcane DQR…………………………………………………………………………………………..72 Table 16 - Soy DQR……………………………………………………………………………………………………..78 Table 17 - Corn Processing Completeness Check……………………………………………………….84 Table 18 - Sugarcane Processing Completeness Check………………………………………………89 Table 19 - Soy Processing Completeness Check………………………………………………………….95 Table 20 - Corn Processing DQR…………………………………………………………………………………98 v Table 21 - Sugarcane Processing DQR……………………………………………………………………....102 Table 22 - Soy Processing DQR………………………………………………………………………………….107 Table 23 – Raw Agricultural Data Summary………………………………………………………………111 Table 24 – Raw Agricultural Data Summary Inputs……………………………………………….…..164 Table 25 – Processed Agricultural Data Summary……………………………………………….…….193 Table 26 - Processed Agricultural Data Summary Inputs…………………………………………..215 Table 27 – Wood Data Summary……………………………………………………………………………… 227 Table 28 – Wood Data Summary Inputs………………………………………………………………….…243 Table 29 – Chemical Data Summary…………………………………………………………………………..257 Table 30 – Chemical Data Summary Inputs…………………………………………………………….....278 Table 31 – Polymer Data Summary……………………………………………………………………………290 vi LIST OF FIGURES Figure 1 - Summary of data collected by crop and category. For the interpretation of the references to color in this and all other figures, the reader is referred to the electronic version of this thesis……………..…………………………………………..…..21 Figure 2 - Geographical Distribution of Datasets…………………………………………………….…...24 Figure 3 - Corn Data Quality Ratings and Component Scores by Dataset………………………….....….28 Figure 4 - Sugarcane Data Quality Ratings and Component Scores by Dataset………..….31 Figure 5 - Soy Data Quality Ratings and Component Scores by Dataset………………..…….32 Figure 6 – Corn Processing DQRs and Component Scores by Dataset……….…………..…….41 Figure 7- Sugarcane Processing DQRs and Component Scores by Dataset…………………..42 Figure 8 - Soy Processing DQRs and Component Scores by Dataset………………………….…43 vii 1. INTRODUCTION Recently, the public and government organizations have become increasingly aware of the sustainability challenges faced by the world. Greenhouse gases (GHGs) in particular, and their link to both global warming and the consumption of fossil fuels, have garnered substantial attention. With this increased awareness comes the opportunity for the academic community to positively impact the decisions that are made and the way business is conducted. However, in order to make sound recommendations, reliable and high quality tools are necessary to objectively evaluate situations and assess the best course of action. Life Cycle Assessment (LCA) is an objective method of evaluating the sustainability of a system and assessing its impacts on the environment [1]. Finding a sustainable solution to a problem is never a simple task. Often each option being considered has its own set of advantages and disadvantages which must be weighed and understood. One of the strengths of LCA is its ability to quantify and categorize the individual impacts of a system and facilitate comparison. It is an effective tool for this purpose because of the level of detail and complexity it is able to convey; but like any method it has its limitations. It has been called “a vital and powerful decision support tool, complementing other methods, which are equally necessary to help effectively and efficiently make consumption and production more sustainable” [2]. The quality of information available from an LCA study is largely limited by the quality and completeness of the data on which it is built. Without complete, high quality data, one cannot be confident that the results of an LCA study accurately represent the 1 situation. Therefore, the quality of the data used in a study affects the quality of the recommendations that come out of said study [2]. This problem is exacerbated by the fact that LCA studies often require the inclusion of an expansive amount of information to achieve their goals. For example, if one wants to accurately describe the environmental impacts of a plastic container, it is necessary to have data not only about the material and production process, but also about the machinery being used, the power source being used, and a multitude of other inputs. As Álvarez-Chávez puts it: “Because of the myriad issues to consider, it can be very challenging to determine which plastic materials are safest and healthiest for workers, consumers, and the environment” [3]. Because of the necessity of including such a large scope of information, it is a common practice for LCA practitioners to draw on data from many sources. It may be impossible or impractical to generate primary data for every aspect of the system covered by a study. To solve this problem, previously generated data from literature is often used to fill in the gaps in information. This means that a bank of data to draw from is extremely useful if not outright necessary for most LCA studies; this presents a particular challenge to practitioners when attempting to conduct an LCA on a system that utilizes newer technologies. New technologies are particularly vulnerable to the problem of low quality data. The relatively short time they have been in existence means that there is a significantly smaller body of research from which to pull, and subsequently one is often forced to settle for data that is less than ideal. Such is the case with data for biopolymers. Interest in biopolymers is increasing because of their potential to address the issue of fossil fuel depletion and mitigate 2 greenhouse gas emissions [4]. An article in May 2012 predicted that the demand for polylactic acid (PLA) is expected to increase by 20% per year [5]. Production of biopolymers is expanding in response to this increased demand. However, bio-based plastics bring with them their own set of problems. In a 2012 comparative analysis Álvarez-Chávez et al state “A bio-based plastic is not necessarily a sustainable plastic; this depends on a variety of issues, including the source material, production process, and how the material is managed at the end of its useful life” [3]. In other words, in order to correctly asses a biopolymer’s environmental footprint one must have accurate and representative data about many aspects of the polymer’s life cycle, including the production of that polymer. A particular challenge of LCA studies of biopolymers is understanding the impact of growing the polymer feedstock since, as discussed by Nemecek et al., “Environmental impact data for crops in the literature and the LCA databases are scarce” [6]. This means LCA data for biopolymers must be obtained; but what type of data should be collected? Before more information can be sought out, it is necessary to identify what types of data are most needed. Identifying critical data gaps for LCA of biopolymers will provide a foundation for future research. By indicating what areas are weak in data availability, researchers can identify the types of data that should be focused on when collecting primary data. If researchers are conducting a study on PLA, for example, they may choose to focus their efforts on the collection of water usage data instead of another type such as pesticide use, depending on which area has a more significant data gap, and therefore less surrogate data to pull from. Understanding the quality and completeness of currently available data also has the potential to clarify the 3 strengths and limitations of existing studies that use this data, as it may shed new light on how representative the study is of the system it is trying to model. The first step in the quest to solve data issues in LCA is addressed by van der Voet et al. in a review of the state of LCA for the related field of biofuels: “The way forward to remedy data problems is clear: identify data needs, collect more and better data and make them accessible” [7]. A review of the state of currently available LCA data is the first step to improving the quantity and quality of available data, because without being aware of what is already published it would be impossible to know where future efforts in data acquisition should be focused. The goal of this project is to identify the critical data gaps present in LCA data for biopolymer feedstocks in order to illuminate the next step in the path to a more sustainable bioplastic. 4 2. LITERATURE REVIEW The importance of high quality data for LCA has been well documented. The International Organization for Standardization (ISO) devotes several sections of their guide for conducting an LCA to data quality requirements, and outlines several tools and checks that a practitioner may use to assess the quality of their data [2]. Additionally, several Life Cycle Inventory (LCI) databases have their own methods of evaluating data. In a 2011 article in the International Journal of Life Cycle Assessment, Cooper et al. [8]explore the strengths and weaknesses of the current commonly used methods for assessing data quality. These methods vary in the way they report data quality. Ecoinvent and the ILCD handbook utilize a numerical scoring method where data can be judged to fall anywhere from 1 (very good) to 5 (very bad). In contrast, the LCA Commons database divides data into two categories, A and B, where A is high quality data and B is low quality data. This method was developed as a way to distinguish between data quality without the use of a numeric scoring system, which has been criticized as being difficult to interpret. However, they all address the data quality issues that are defined by ISO. In fact, the article concludes that “The strengths of data quality analysis methods lie in the consideration of the data quality aspects specified by the ISO standards” [8]. ISO names several areas that should be considered when evaluating data quality. Specifically they are: time related coverage, geographical coverage, technological coverage, precision (measure of the variability of the data values), completeness, representativeness, consistency, reproducibility, source of data, and uncertainty of 5 information. Of the items on the list, the first four are better documented and explored in terms of their effect on the outcomes of LCA studies. When one thinks of examples of gaps in LCA data for agricultural products, the first thing that comes to mind is an instance where there is no data for a certain process, or no data for a certain crop. However gaps in data availability also occur between technologies, geographic areas, and as methods or conditions change over time. Even a seemingly simple example where only the region of production is varied can have hidden depths. This is because agricultural methods can vary significantly by region, even for the same crops; and this variation in turn can create large differences in the environmental impacts of these different systems. For example, soybeans may be grown using a traditional till, irrigated system in one region and a no-till, non-irrigated system in another region. In this situation, the fossil fuel and water usage could both potentially be significantly greater for the first system. This is supported by information from Kim and Dale in a 2009 report on the sustainability and competitive position of biobased chemicals. They found that “local variation in GHG emissions of platform chemicals [ethanol and soy biodiesel] are significant due to tillage practices, irrigation, soil types and fuel consumption” [9]. It is therefore necessary for an LCA practitioner to consider and adjust based on the difference between both the geographical and the technological coverage of the dataset they are using in a situation such as this. However, this is more easily said than done. Variation between geographical areas can be complex and difficult to model. One study that tracked water consumption in ethanol production from corn in 81 different watersheds in Minnesota found significant variation in the range of water consumption 6 between watersheds. The study included the use of both irrigation water and process water. The range in the amount of water used to produce 1 L ethanol was found to be 3 – 181 L in a watershed in central Minnesota. Contrastingly, ethanol produced in a watershed in the south of the state had a much smaller range in the amount of water used. Farms and production facilities based in the southern watershed used only 3 - 8 L of water to produce 1 L ethanol from corn [10]. This demonstrates that the issue of geographical correlation is not as simple as one might assume. LCA practitioners are often compelled to use data from a different region than the one under study. Generally, an effort is made to use data from a region with similar geography and practices, but in this case large variation was found within a single region that was utilizing relatively uniform technology. This suggests not only that it is quite difficult to predict a correlation between regions, but also that even data from a slightly different part of the same region may not be an accurate substitute. This issue of hidden complexity is not isolated to a single incident or a single input. There are cases of disagreement among researchers about the amounts of fossil fuels that are used in the production of biopolymer feedstocks. A study by Reijnders and Huijbregts in 2007 concluded that fossil fuels are most often used as a power source in the production of palm oil based biodiesel, and generally represent 75% of the fuels used in this process. This assumption is not consistent with information from Malaysia and Indonesia which asserts that the main source of energy for processing of palm oil is from combustion of palm residues, mainly shells and fibers, and that as little as 2% of process energy comes from fossil fuels [11]. This is just one example of an instance where uncertainty surrounding the technology being used sparked debate about what 7 data should be used to model a system, but it is a significant one. The variation of fossil fuel use in turn affects the greenhouse gas emissions of the system, in this case by as much as 21% [11]. Another example surrounding the uncertainty of greenhouse gas emissions in relation to biomass production springs from the issue of precision. In an article about sampling error in US crop surveys, Cooper et al. presents this example: “consider…a comparison of the life cycles of a conventional fuel and a biofuel in which the conventional fuel has an estimated mean greenhouse gas emission of 47 grams of carbon dioxide equivalent per mega joule (g CO2eq/MJ) and the biofuel of 38 g CO2eq/MJ. Without consideration of variability, the biofuel is found superior to the conventional fuel” [12]. However, the article goes on to explain how the relative standard errors (RSE) of the data these means are based on affect the viability of this assertion. “Thus, without knowledge of the error and sample sizes, the comparison of greenhouse gas emissions can be meaningless” [12]. Although this example is theoretical, the paper presents a strong case for caution when making these comparisons, and illustrates the effect data precision has on study results. Recently, more attention has been focused on the impacts of agriculture that are harder to measure, and therefore for which data are more difficult to obtain. The inclusion of these impacts has the potential to significantly change the results of an LCA study, and they bring with them additional challenges in data quality that researchers must overcome. In a study about the effect of land use change (LUC) on GHG emissions, Piemonte et al. point out the effects LUC has on the environmental impact of a bioplastic: “If, on one hand, the bioplastics can save in terms of fossil resources and GHG 8 emissions, on the other, agricultural biomass production might cause adverse environmental effects such as soil erosion, eutrophication of ground and surface waters, or fragmentation of habitats” [4]. There is generally agreement that these types of impacts are important to understanding the true environmental effects of biopolymers. Emissions from LUC, both direct and indirect, may be especially important in understanding local and regional effects of biomass production, but it is difficult to measure and quantify them, so they are often excluded for practical reasons [13]. The effects of indirect land use change (displacing previous agricultural production to other land) have been estimated to span a large range of values, varying from a small effect (10 kg CO2-eq/GJ ethanol) to one that is several times greater than the life cycle emissions of CO2 for gasoline (340 kg CO2-eq/GJ ethanol) for the same feedstock [13]. The latter is obviously a concern, since one of the main attributes of biopolymers that make them attractive is their ability to mitigate GHG emissions. These data gaps impact the ability of LCA studies to accurately describe a system. As Weiss et al conclude in “A Review of the Environmental Impacts of Biobased Materials,” “The variability in the results of life cycle assessment studies highlights the difficulties in drawing general conclusions” [13]. Certainly, there are many sources of variability and many reasons why LCA results vary. However, it is just as certain that the availability of appropriate data is one of these sources. 9 3. METHODS In order to identify critical data gaps for bio-based plastics, a review of currently available data was conducted. Information was collected from the LCA databases Ecoinvent, GaBi-PE (Ecoinvent data modified by GaBi), USLCI, LCA Food DK, and LCA Commons. The software programs SimaPro and GaBi were used to access all of these databases except LCA Commons, which has not been integrated into the software programs. The websites of LCA Food DK and USLCI were also searched for information. Additionally, publications were searched for relevant data that had not yet been integrated into the databases. Since it is not feasible to search all publications, a selection of publications was chosen based on the likelihood that they would contain relevant information. Table 1 contains the list of publications and timeframes searched. Table 1 - List of publications searched Publication Name Time Frame Journal of Cleaner Production 2013-2005 International Journal of LCA 2012-2000 Bioresource Technology 2012-2005 Biomass and Bioenergy 2012-2005 Environmental Science and Technology Selected Packaging Technology and Science Selected Journal of Industrial Ecology 2012-2008 Sustainability 2012-2005 Science 2012-2008 PNAS 2012-2005 10 All data pertaining to feedstocks that are viable for use in the production of biobased plastics were considered in the search. These data relate to many aspects of bioplastic production, including raw agricultural feedstocks (i.e. corn, soybeans) through processing steps (i.e. sugar or oil), platform chemical production (i.e. ethanol and biodiesel), and polymer production. The relevant data sources were collected into a summary table. The table organizes data sources by category (raw agricultural, processed agricultural, wood, chemical, and polymer), and feedstock material. The table also captures other information about the data that would be of interest to a practitioner who is considering using one of the datasets, including where the data is available, the details of the study (if applicable), the year(s) of publication, and the region to which the data pertains. The data were also checked against common agricultural inputs and the results catalogued in the summary table. A “1” in the column of the indicated input means that the dataset in that row contains a flow for that input. For example, if a soy data file has a “1” in the column marked “tillage” that means the process of tilling the field and associated inputs are included in that data file. In this way, a preliminary completeness check was conducted on all the data collected in the summary table. Because of the large number of data sources amassed, it was necessary to narrow the focus of the project in order to conduct a deeper analysis of the data. Corn, sugarcane, and soy were the feedstocks selected to be analyzed in more detail. These feedstocks were chosen based on their current use as biopolymer feedstocks. The first step was to conduct a completeness check on the available data for these crops. Information from ISO 14044 and the ILCD handbook was used to inform this process [2, 14]. The completeness check involved searching each data file in detail and noting what 11 inputs were considered and, when possible, how they were accounted for. For the database files, this meant looking through the data directly, at the flow level. For the data contained in journal articles, it involved searching for information within the article and looking up data source information from the references. An effort was made to include all significant input categories for these feedstocks in the check. The input categories that were included in this check are as follows: carbon sequestration, seed production, soil preparation, transport of materials to the farm, fuel used on the field, power for farm activities, machines, machine shelter, sowing, tilling, fertilizer, pesticide, herbicide, lime, crop residue management, irrigation, harvesting, grain drying, direct field emissions, crop storage, land occupation, and land use change. Additionally, several inputs relating to biomass processing were considered in the completeness check. These were considered separately, so some data files underwent two completeness checks. The processing inputs include: loading, transportation of the crop to the refinery, process chemicals, waste treatment, infrastructure, facility land use, processing machinery, process energy, extraction and milling, refining, process water, fermentation, and drying. Not all inputs were relevant to all data sets. For example, a study that only considered GHG emissions would not include water use. It was noted in the completeness check results when an input was specifically excluded from a study because it was not within the study scope. Next, a pedigree matrix scoring system was used to evaluate the data sets for corn, soy, and sugarcane. The data were evaluated on their technological, geographical, and temporal representativeness on a scale from 1-5. When information was available, data uncertainty was also considered in the evaluation. From this evaluation and the completeness evaluation, a Data Quality Rating (DQR) was calculated. Agricultural data 12 was considered separate from processing data. Some datasets therefore have two DQRs, one for agricultural data quality, and one for processing data quality. The evaluation criteria and the formula used to calculate the overall score are were adapted from the ILCD Handbook and van der Berg et al. [14, 15]. Table 2 explains the different categories considered in the evaluation of the data, and Tables 3 and 4 explain the ranking of the quality ratings [14, 15]. It was necessary to consider the quality ranking recommendations of both the ILCD and van der Berg et al. in order to complete a consistent analysis. The ILCD rankings are described in general terms, and do not have category-specific requirements. Therefore, the criteria put forth by van der Berg et al. were used to supplement the ILCD recommendations. Specific category ranking requirements from van der Berg et al. were applied. For example, data that was less than three years older than the study date was given a score of 1 in temporal correlation. It should be noted that the category “Reliability” from van der Berg et al. and the category “Precision/Uncertainty” from the ILCD handbook are equivalent. The ILCD handbook also includes another evaluation category, Methodological Appropriateness and Consistency, which was not used in this evaluation. This category was excluded because it is dependent on the goal and scope of the intended application of the dataset. 13 Table 2 – Definition of evaluation categories adapted from the ILCD Handbook Indicator / Component Definition / Comment Technological Representativeness (TeR) “Degree to which the data set reflects the true population of interest regarding technology, including for included background data sets, if any.” Geographical Representativeness (GR) Time Related Representativeness (TiR) Completeness (C) “Degree to which the data set reflects the true population of interest regarding geography, including for included background data sets, if any.” Comment: i.e. of the given location / site, region, country, market, continent, etc. “Degree to which the data set reflects the true population of interest regarding time/ age of data, including for included background data sets, if any.” Comment: i.e. of the given year (and - if applicable – of intra-annual and intra-daily differences). “Share of (elementary) flows that are quantitatively included in the inventory. Note that for product and waste flows this needs to be judged on a system’s level.” Comment: i.e. degree of coverage of environmental impact i.e. used cut-off criteria. Precision / uncertainty (P) Measure of the variability of the data values for each data expressed (e.g. low variance = high precision). Note that for product and waste flows this needs to be judged on a system level. 14 Table 3 –Quality Rating Definitions adapted from the ILCD Handbook Quality Level Quality Rating Very Good 1 Good 2 Fair 3 Poor 4 Very Poor 5 Not Applicable 0 Definition “Meets the criterion to a very high degree, having no relevant need for improvement. This is to be judged in view of the criterion’s contribution to the data set’s potential overall environmental Impact and in comparison to a hypothetical ideal data quality.” “Meets the criterion to a high degree, having little yet significant need for improvement. This is to be judged in view of the criterion’s contribution to the data set’s potential overall environmental Impact and in comparison to a hypothetical ideal data quality.” “Meets the criterion to still sufficient degree, having the need for improvement. This is to be judged in view of the criterion’s contribution to the data set’s potential overall environmental Impact and in comparison to a hypothetical ideal data quality.” “Does not meet the criterion to a sufficient degree, having the need for relevant improvement. This is to be judged in view of the criterion’s contribution to the data set’s potential overall environmental Impact and in comparison to a hypothetical ideal data quality.” “Does not at all meet the criterion, having the need for very substantial improvement. This is to be judged in view of the criterion’s contribution to the data set’s potential overall environmental Impact and in comparison to a hypothetical ideal data quality.” Criteria could not be applied 15 Table 4 –Pedigree Matrix Data Quality Rating Level Definitions adapted from van der Berg et al. 1 2 3 4 5 Verified data based on measureme nts Verified data partly based on assumptions or non-verified data based on measurements Non-verified data partly based on assumptions Qualified Estimate (e.g. by industrial expert) Non-qualified estimate Representativene ss unknown or incomplete data from a smaller number of sites and/or from shorter periods Representative data from a smaller number of sites but for adequate periods Representativ e data from adequate number of sites but from shorter periods Representativ e data but from a smaller number of sites and shorter periods or incomplete data from an adequate number of sites and periods Less than three years difference to year of study Less than six years difference Less than 10 years difference Less than 15 years difference Age of data unknown or more than 15 years difference Data from area with similar production conditions Data from area with slightly similar production conditions Data from unknown area or area with very different production conditions Data from processes and materials under study but from different technology Data on related processes or materials but same technology Data on related processes or materials but different technology Geographical Correlation Representati ve data from a sufficient sample of sites over an adequate period to even out normal fluctuations Data from area under study Technological Correlation Temporal Correlation Completeness Reliability Indicator Score Data from enterprises, processes, and materials under study Average data from larger area in which the area under study is included Data for processes and materials under study but from different enterprises 16 Data was examined in the greatest detail possible when scoring each category since most datasets have multiple sources of information that can be of varying quality. These differences are accounted for by scoring each source of data and then resolving their respective scores into a single category score. Background process data were weighted less heavily when resolving scores, as were data that are not sensitive to a specific category. For example, using a US electricity mix for sugar production in Brazil is a significant difference because Brazilian sugarcane processing is generally powered by the burning of bagasse, a sugarcane co-product. This substitution therefore represents a significant technological difference. However, if US diesel tractor emissions were substituted for Brazilian diesel tractor emissions, the difference is not as significant since the technology is nearly identical. Additionally, half scores were given to categories when deemed appropriate. For example, a dataset published in 2010 for which half of the relevant data was from 2009 (less than 3 years difference) and half was from 2005 (less than six years difference) would be given an overall score of 1.5 in the category of temporal correlation. In order to ensure transparency, each score is reported with its individual justification. Equation 1 was used to calculate the DQR for each dataset [14]. Note that the lowest criteria score is weighted in the formula by five-fold. This is done because the weakest quality indicator significantly weakens the overall quality of the dataset being evaluated [14]. The Precision (P) quality indicator was only included in the calculation of the DQR for Ecoinvent data. This was necessary due to the lack of information about precision for most datasets. When evaluating the precision of the Ecoinvent data, the Ecoinvent uncertainty scoring criteria were used to interpret the uncertainty scores for 17 each flow [16]. Then, a single uncertainty score was chosen for the file based on this interpretation. An explanation of these criteria can be found in Appendix A. A dataset with DQR less than or equal to 1.6 is considered high quality, while a dataset with a DQR between 1.6 and 3 is considered to be of basic quality. Any dataset with a DQR between 3 and 4 is considered to be an estimate [14]. Equation 1 – Data Quality Rating Formula and Definitions from the ILCD Handbook DQR = TeR_+_GR_+_TiR_+_C_+_P_+_M_+_(Xw*4) i+4 DQR: Data Quality Rating of the LCI data set TeR, GR, TiR, C, P, M: see table 2 Xw: weakest quality level obtained (i.e. highest numeric value) among the data quality indicators i: number of applicable data quality indicators 18 4. RESULTS AND DISCUSSION Data Availability The summary table containing the details of all the collected datasets can be seen in Appendix F. Table 5 describes the type and number of entries it contains. Table 5 – Quantity and type of data collected Feedstock: Wood Agricultural Residues Corn Wheat Canola / Rapeseed Soy Other Sugarcane Palm Potato Barley Sugarbeet Switchgrass Rye Algae Cassava Dedicated Energy Tree Oat Rice Sorghum Blood meal Waste Oils Total Raw Processed Chemical Agricultural Agricultural Feedstocks Total Feedstocks Feedstocks (Ethanol/Biodiesel) Polymers 60 0 54 6 0 42 22 21 21 8 20 15 4 0 6 6 1 0 4 0 20 18 17 13 11 11 9 6 9 5 4 3 12 9 2 3 0 8 9 2 4 4 0 0 5 5 4 5 8 2 0 1 3 0 3 0 3 3 11 4 3 1 0 3 2 1 1 3 0 1 0 1 0 0 0 0 0 0 0 0 3 3 3 3 2 2 287 0 3 3 2 0 2 0 0 0 1 2 114 1 0 0 0 0 0 1 0 7 110 19 1 0 0 56 A total of 287 datasets were collected. It should be noted that in the case where one study contained multiple data sets each was counted individually. For example, one study compared US corn, UK sugar beet, and Australian sugarcane as producers of sugar for fermentation [17]. This study contained datasets for the cultivation of each of these crops, so three datasets were counted (one for sugarcane, one for corn, and one for sugar beet). Likewise, a study with both cultivation data and processing data for corn would contribute two datasets to the above count, one in the raw agricultural feedstock category and one in the processed agricultural feedstock category. Of the 287 datasets found, 110 are for raw agricultural feedstocks, 114 are for processing of agricultural feedstocks, and 56 are for production of platform chemicals (mainly ethanol and biodiesel). Only seven datasets were found for the complete production of biopolymers. Figure 1 illustrates the number of datasets found for each crop. Each bar is a stacked total which represents the composition of the datasets for each crop by category. Wood and agricultural residues are excluded for reasons of convenience. 20 Figure 1: Summary of data collected by crop and category. For the interpretation of the references to color in this and all other figures, the reader is referred to the electronic version of this thesis. Data Summary by Crop Raw Agricultural Feedstocks Processed Agricultural Feedstocks Chemical Feedstocks (Ethanol / Biodiesel) Polymers Waste Oils Bloodmeal Sorghum Rice Oat Dedicated Energy Tree Cassava Algae Rye Switchgrass Sugarbeet Barley Potato Palm Sugarcane Other Soy Canola / Rapeseed Wheat Corn 0 5 10 15 20 25 The feedstock with the largest amount of datasets is wood, with a total of 60. However, this is largely because the same base data is available in multiple iterations. For example, data for board trimmings, sawdust, and woodchips in the US Pacific Northwest are all available and build off of the same base data. Therefore the high total is somewhat misleading. Agricultural Residue is the feedstock with the second highest 21 amount of datasets collected at 42. This category includes things like corn stover, sugarcane bagasse, and wheat straw. This number is almost exclusively made up of Ecoinvent files. Ecoinvent has separated the data associated with the co-products of crop production into separate files, which means that for each crop Ecoinvent has data available, it also has data for the associated agricultural residue. Here, all of these residues are collected into a single category, which is why they are so numerous. The crop with next largest amount of available data is corn (22), which is closely followed by wheat (21), rapeseed (20), and soy (18). Rapeseed and canola are grouped together because canola is a specific type of rapeseed suitable for human consumption [18]. The category “other” is mostly composed of data for ethanol from mixed feedstocks, which is available from Ecoinvent, and generic data for unspecified biomass. Sugarcane (13) has slightly less data available in relation to the other commodity crops commonly used to produce biopolymers. It should also be noted that no applicable datasets could be found for chitosan, despite the fact that a search was specifically conducted for this material. It should also be noted that over half (4 of 7) of the polymer datasets are based on corn. The table and figure show that 8 datasets are available for raw corn. However, the 131 datasets available for corn from the US database LCA Commons are represented by a single entry in the summary table. This was done for reasons of practicality, since datasets in LCA Commons are state specific for a single harvest year. The short data collection time period is a quality issue, but 18 of the 131 data sets are aggregated over multiple years. These aggregated datasets are still state specific; LCA Commons does not have a file meant to represent averages for the entire USA. LCA Commons datasets 22 are also included for soy (137), oats (12), rice (6), and wheat (155). They are represented in the table as described above. Geographically, the data is skewed to Europe and North America with about 60% of the datasets (175 of 287) from one of the two regions (105 for Europe and 70 for North America). Additionally, about half of the European data (58 of 106) is for Switzerland. This is likely related to the fact that the Ecoinvent project is based in Switzerland. Likewise, nearly all of the North America data is for the USA. Only one of the 70 datasets for North America is explicitly for another country, a study about biodiesel production in Costa Rica. There are a number of USLCI datasets whose region is described in general as “North America” but these files are more reflective of the USA than of North American averages, being mainly built off of US data and modeling technology typical of the US. Figure 2 describes the regional breakdown of the data, while Table 6 gives a detailed breakdown of data availability by country. 23 Figure 2 – Geographical Distribution of Datasets Geographic Distribution of Datasets Raw Agricultural Data Platform Chemical Data 70 Processed Agricultural Data Polymer Data 64 60 50 38 40 30 20 10 19 18 16 15 9 4 1 13 8 1 7 3 5 1 0 Europe North America Asia and Middle East 24 South America 1 5 1 0 Oceania 0 0 0 0 Africa Table 6 – Data Availability by Country Raw Agricultural Data Count Switzerland 39 USA 29 North America 9 UK 7 Denmark 7 Processed Agricultural Data USA Malaysia 7 4 4 4 3 3 3 3 2 2 1 4 4 3 3 3 2 2 2 Australia Iran 1 Indonesia 1 New Zealand Taiwan Thailand Unspecified China Sweden Argentina Australia Costa Rica Denmark Count 12 7 Switzerland Australia Brazil North America Europe General Germany UK China Denmark Argentina China Germany Unspecified France India Brazil Europe Spain Average: USA and Europe Argentina Chemical Data Switzerland Brazil North America USA Europe 1 Philippines Thailand Polymer 1 Data 1 USA 2 France 1 India 1 Brazil 1 Europe New 1 Zealand 1 Count 10 7 7 7 5 4 4 3 2 1 1 1 1 Count 4 1 1 1 As illustrated by Figure 2, the most obvious geographical data gap is that zero datasets were found that represent anywhere on the continent of Africa. Additionally, the category “Asia and the Middle East” covers a very large amount of area in theory, but in reality the datasets are focused on Southeast Asia and China. Only one dataset, potato production in Iran, breaks this pattern. The data designated Oceania is composed of one dataset for New Zealand with the remainder representing Australia. The South American data consists of entries from Brazil and Argentina, and is mostly for 25 sugarcane and soybeans. In general, the geographical concentration of the datasets is in line with the demand for LCA data in each region. It makes sense that Europe and the USA, which both have strong policies in place that promote biofuels and LCI database projects, have more data available. Furthermore, the pattern of data concentration is consistent with areas that produce large amounts of commodities that are commonly used to produce biofuels and biopolymers. A notable exclusion is that neither Canada nor Russia is represented in the datasets. The two largest countries in the world, Canada and Russia are both also major producers of grains that are commonly used to produce biodiesel and ethanol. Canada is the largest producer of canola, and Russia was the second largest producer of wheat in 2005 [19, 20]. The largest producer of wheat in 2005, India, is also under-represented in data availability [20]. There are four datasets for India but none of them are for wheat. Three are for agricultural residues suitable for cellulosic ethanol production (jute and kenaf stalks), and the fourth is for jatropha (an oilseed crop that can be grown on degraded land) [21]. 26 Quality Analysis A data quality evaluation was undertaken for cultivation of corn, soy, and sugarcane. The full results of this evaluation with score justifications can be seen in Appendix C. The processing data for these crops was evaluated separately, and results of this evaluation can be found in Appendix E. Full results of the completeness check for agricultural data are listed in Appendix B, and Appendix D contains the completeness check results for the processed agricultural data. It should be noted that some studies listed in the summary table for these crops were excluded from this evaluation. This was done if it was discovered during the completeness check that the data was taken from another source already under evaluation. For example, a sugarcane study that was built off the Ecoinvent file “sugarcane, at farm” would be excluded because that dataset was already included. Figure 2 illustrates the composition of the corn DQRs by breaking them down into their constituent categories of completeness, uncertainty, and technological, geographical, and temporal representativeness. Figures 4 and 5 illustrate the same thing, but for sugarcane and soy, respectively. Tables 7, 8 and 9 match the identifiers in the figures with the corresponding dataset names for each feedstock. 27 Table 7 –Corn Dataset Names and Identifiers Corn Dataset Name: Identifier Annual Report: Life Cycle Assessment to Improve the Sustainability and Competitive Position of Biobased Chemicals: A Local Approach A Grain maize organic, at farm (Ecoinvent) B Silage maize organic, at farm (Ecoinvent) C Corn grain, at harvest in (year), at farm 85-91% moisture (state) (LCA Commons) D Regional variations in GHG emissions of bio-based products in the United States - Corn based ethanol and soybean oil E Corn, at farm (Ecoinvent) F Grain maize IP, at farm (Ecoinvent) G Silage maize IP, at farm (Ecoinvent) H Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment I Life cycle assessment of various cropping systems utilized for producing biofuels: Bioethanol and Biodiesel J Improvements in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of Corn-Ethanol K LCA of cropping systems with different external input levels for energetic purposes L Corn, whole plant, at field (USLCI) M Corn, production average, US, 2022 (USLCI) N 28 Figure 3 – Corn Data Quality Ratings and Component Scores by Dataset 0 1 2 3 4 Technological Rep A 1.4 Geographical Rep B 1.6 Time Rep C 1.6 Completeness D 1.6 Uncertainty 1.6 Data Quality Index E F 1.7 G 1.7 H 1.7 I 1.9 J 1.9 K 2.0 L 2.5 M 2.5 N 2.6 Average 1.9 29 Table 8 – Sugarcane dataset names and identifiers Sugarcane Dataset Name: Identifier Life Cycle Assessment of fuel ethanol from sugarcane in Brazil A comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation O Carbon footprint of sugar produced from sugarcane in eastern Thailand R Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry S Sugarcane, at farm/BR (Ecoinvent) T Life cycle assessment of Australian sugar cane production with a focus on sugarcane growing A decision support tool for modifications in crop cultivation method based on LCA: a case study on GHG emissions reduction in Taiwanese sugarcane cultivation Life Cycle Assessment of Sugarcane Ethanol and Palm Oil Biodiesel Joint Production P Q V V W Table 9 – Soy dataset names and identifiers Soy Dataset Name: Soy beans organic, at farm/CH (Ecoinvent) Soy beans IP, at farm/CH (Ecoinvent) Soybeans; at harvest in (year); at farm; 85-92% moisture (state) (LCA Commons) Life cycle assessment of soybean based biodiesel production in Argentina Soybeans, at farm/US (Ecoinvent) Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Soybean grains, at field (1998-2000)/kg/US (USLCI) Soybeans, at farm/BR (Ecoinvent) Identifier X Y Z AA BB CC DD EE Soybean grains, at field/kg/US (USLCI) FF Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans Soy bean, from farm (LCA Food DK) GG HH 30 Figure 4 - Sugarcane Data Quality Ratings and Component Scores by Dataset Technological Rep Geographical Rep Time Rep Completeness 0 1 Uncertainty 2 Data Quality Index 4 5 3 O 1.8 P 2.1 Q 2.1 R 2.1 S 2.4 T 2.5 V 2.4 V 3.6 W 3.7 Average 2.5 31 Figure 5 - Soy Data Quality Ratings and Component Scores by Dataset Technological Rep Time Rep Completeness 0 Geographical Rep Uncertainty Data Quality Index 1 2 3 4 5 X 1.6 Y 1.7 Z 1.6 AA 1.8 BB 2.3 CC 2.3 DD 2.4 EE 2.5 FF 2.5 GG 2.8 HH 4.5 Average 2.4 32 Overall, the DQRs for the corn datasets ranged from 1.4 to 2.6, with five of the datasets ranked in the high quality range and the remaining eight datasets in the basic quality range. The sugarcane datasets ranged from 1.8 to 3.7, with seven of the datasets in the basic quality range and the remaining two classified as estimates. Sugarcane has no datasets with a DQR in the high quality range. These less desirable DQRs for sugarcane are mainly a result of poorer scores in the category of temporal representativeness. The soy datasets have the largest range of DQRs, from 1.6 to 4.5. Two of the datasets are classified as high quality, with the majority (eight) in the basic quality range. The dataset “Soy bean, from farm”, available from the LCA Food DK database, was the lowest scoring of all the datasets assessed with a DQR of 4.5. This rating is outside the range defined by the ILCD handbook for the lowest quality level of estimate (3.0 to 4.0). In the DQR table for soy, it has been given the designation “low quality estimate”. The low DQR is a product of receiving the undesirable score of 5 in the categories of both completeness and temporal representativeness. The temporal score was given because the age of the data is unknown, and the completeness score reflects the fact that very few flows are present in the dataset and major omissions were found in both the inputs and the emissions. Technological Representativeness The datasets for all three feedstocks consistently scored the best in the technological representativeness category. This means that data from a different process than the one under study rarely had to be used as a substitute to fill a data gap. A technology aspect of corn and soybean cultivation that warrants attention is tilling practices. The method of tilling can have a large effect on the environmental impacts of 33 a system as it affects the use of fossil fuels and soil degradation, among other issues [22]. Conventional till, reduced / conservation till, and no-till are the basic methods used in corn and soy cultivation. In reduced and conservation till, the amount of tilling is decreased in relation to the conventional method, and a different type of plough is usually employed, while no-till uses a different planting technology to eliminate the need to till altogether [22]. A 2010 USDA report estimates that 28.8% of corn in the US was grown using conventional till practices in 2005 compared to 47.5% grown with reduced or conservation tillage, and 23.5% which used no-till technology [23]. Ecoinvent uses a weighted average of conventional and conservation till practices for both corn and soy in their files. Of the 13 datasets evaluated for corn, seven (including Ecoinvent) reflected average tilling practices at the national level. Two represent state level averages, and one was varied by county. One dataset is explicitly for no-till technology. There is no corn dataset specifically representing conservation or reduced tillage practices, despite the fact that this is the most common tillage practice in the US. A higher percentage of soy was produced using no-till in 2005 than corn (45.3%), while 43.2% used reduced or conservation till technology and the remaining 11.6% was conventional till. Unlike corn, a dataset modeling conservation till is available for soy. However the majority of the soy files (seven of eleven) use a weighted average of conventional and conservation till similar to that used by Ecoinvent. This weighted average data is not ideal for an LCA study that seeks to model a specific cultivation system because it does not accurately model any one tillage method. Additionally, the state averages vary significantly from the national averages. Texas, for example, produced 68.4% of corn in 2005 using conventional till while Nebraska used 34 conventional till for just 5.7% of its corn production. Therefore, depending on what state is under study, the national average could either over- or under-estimate the amount of inputs and emissions associated with tilling by a wide margin. Sugarcane has other technological issues worth noting, particularly relating to the method of harvesting. Sometimes sugarcane is burned before harvest, and sometimes it is harvested green. This difference has an effect on emissions to air, and also on the amount of process water used during milling [24]. This is because the burned sugarcane becomes sticky from the release of juices during burning and therefore generally has a large amount of debris mixed in with the harvested cane. As a result, a more vigorous washing process is required during processing. The sugarcane datasets vary in the percentage of cane that is burned before harvest. The Australian datasets reflect the national average of around 40% burned and 60% green at time of harvest, while a Brazilian dataset has the opposite ratio of 60% burned and 40% green harvest [24, 25]. Additionally, there is a significant difference between manual and mechanical harvest. The Ecoinvent file that models sugarcane production in Brazil assumes that 80% of the harvesting is done manually. In contrast, Australia uses dominantly mechanical harvesting, which is reflected in the Australian datasets. Harvesting sugarcane is the part of cultivation that contributes most significantly to global warming [26]. Therefore, data that accurately represents the method used to harvest sugarcane is important for accuracy of the final results of an LCA. Geographical Representativeness In the category of geographic representativeness the corn datasets scored fairly well. All but one dataset either represents the area under study or is from a larger area 35 that includes the study area. The exception is a dataset based on a single site field study conducted in central Italy. The publication associated with this data was intended to model corn production in the “Mediterranean region”, so the dataset was classified as from a smaller area within the Mediterranean and therefore was scored at a value of 3 [27]. Four of the corn datasets are based on US average values. This is problematic because the US is quite large, and therefore subject to regional variations not only in weather and conditions, but also in technology. For example, the USDA reports that about 14% of corn grown in 2002 in the US was irrigated [28]. However, this 14% is not evenly scattered over the entire growing region, but concentrated in certain areas. Nebraska, for example, has an irrigation rate of 60.6%, much higher than the national average [29]. A dataset based on national averages would therefore likely underestimate the amount of water used if the system under study was in Nebraska. More geographically specific data has the potential to solve this problem, and some of it is available. Three datasets model corn cultivation at the county level. Of the three, one is only for water in Minnesota and one is specifically for Scott County, Iowa. These two datasets will therefore be of limited use to practitioners because of their geographic and technological restraints. The third dataset, titled “Annual Report: Life Cycle Assessment to Improve the Sustainability and Competitive Position of Biobased Chemicals: A Local Approach”, by Kim and Dale is far more versatile in scope [9]. It includes detailed data for several counties across corn growing states, and also has the highest DQR (1.4) of all the datasets evaluated. This level of geographic detail is unique to corn cultivation. State level data is the most geographically specific level of information available for all other crops in this report. Only the LCA Commons data is 36 available by state for soy cultivation. The rest of the soy datasets reflect national averages. This type of regional variation is not unique to the USA. Four of the sugarcane datasets represent Brazilian production, with two specifically for the state of Sao Paulo. Three datasets are for Queensland, Australia. This region accounts for 98% of sugarcane production in Australia, so the lack of data from other areas is not a particularly important gap [24]. However, there is significant variation in the growing conditions and intensity of inputs within this region. One study by Renouf et al. includes datasets for the two areas of Queensland with the most disparate growing conditions [24]. As illustrated by the discussion above, geographical and technological differences are often strongly related, with quality issues bridging both categories. These types of quality issues call into the question the usefulness of datasets based on national averages when there is significant variation within regions. Temporal Representativeness Of the three crops evaluated, sugarcane scored the worst in the category of temporal representativeness with five of the nine sets receiving a rating of 3 or above. Two soy datasets have a score of 5 in this category; one is based on primary data of an unknown age, and the other uses a significant amount of data from 1979. Even the Ecoinvent dataset for sugarcane relies on older data than the Ecoinvent files for corn and soy, using data for agronomic inputs from 1988. This is uncharacteristic of the Ecoinvent database, which collected most of their data between the late 1990s and the mid-2000s. 37 Crop yield data is particularly sensitive to age because of advances in yields over recent years. A yield increase basically has the effect of diluting the environmental impacts of a cropping system by spreading them over more outputs. For this reason, the results of LCA studies involving crops tend to be quite sensitive to yield changes [30]. Therefore, when new data is collected, a high priority should be given to the collection of updated crop yields. Completeness Land use change, and specifically indirect land use change, is the largest problem in the category of completeness. Four of the corn datasets do not include any type of land use change data, and only two of the datasets explicitly include indirect land use change. It should be noted that the database files (Ecoinvent, USLCI, and LCA Commons) do not distinguish between the types of LUC at the flow level. Therefore, all that was able to be determined about these files is that they include some land use change data, but it was not possible to distinguish between direct LUC and indirect LUC for these datasets. This data gap is even more pronounced for sugarcane. Five of the ten datasets evaluated do not account for land use change, and three of those five also do not include land occupation. The Taiwanese sugarcane dataset does not include land use change despite the fact that the article itself states that sugarcane production is expected to expand in the region and that fallow land will likely be converted for cultivation [30]. Additionally, three of the studies that do include LUC also state that their information on this input is not complete. One of the Australian studies that includes land use change presents the data with the qualifier that the methods used to 38 evaluate both LUC and water impacts have significant limitations [31]. Another study echoes this sentiment when it states that the LUC emissions are uncertain due to lack of uniform methods [32]. The Ecoinvent file also follows this pattern as there is a high degree of uncertainty associated with the land use change flows. The soy datasets also deal inconsistently with this impact, although it is less pronounced than in the sugarcane data. Four of the eleven soy files do not include indirect LUC, and two of these also exclude direct land use change. The significance of this omission varies depending on the system under study. If the study is for an established growing system that is not expanding, than it would not be highly important information to include. However, for most of these crops, production is expanding in response to increased demand for bio-products. This is especially true in South America, where sugarcane production has expanded in Brazil at an average rate of approximately 85,000 hectares per year since 1990 and soy production in Argentina has gone from less than a million hectares to 13 million since 1970 [33, 34]. Uncertainty As stated in the Methods section, an uncertainty evaluation was only done for the Ecoinvent data. In general, these datasets had low uncertainty since data is mostly based on verified measurements. The exception is that all transport distances in the Ecoinvent datasets are estimates. The Ecoinvent sugarcane datasets also has a greater degree of uncertainty than the soy or corn Ecoinvent datasets because the sugarcane file’s energy and carbon dioxide data is partly based on qualified estimates. 39 Additionally, an uncertainty score was given to one USLCI file: “Corn, production average, US, 2022”. It was possible to score this dataset because it is a qualified estimate for corn production in the future, and therefore was given the standard uncertainty score of 4 for qualified estimates. As discussed above, many studies that included data for LUC expressed concerns of uncertainty along with that data. It was not possible to give an overall uncertainty score to these datasets, however, because these concerns were generally expressed only in qualitative terms and uncertainty information was not available for the other inputs in the datasets. Processing Data Quality Figures 6, 7 and 8 illustrate the results of the processing Data Quality Ratings for corn, soy, and sugarcane. Overall, the processing datasets for each crop scored worse than the cultivation datasets. The corn processing datasets have DQRs ranging from 1.6 to 4.1, with only one dataset in the high quality range. The sugarcane datasets range from 1.9 to 3.6, with three datasets in the basic quality range and four that are considered estimates. The soy processing data had the tightest range with datasets scored between 2.3 and 3.1. All but one of the seven soy datasets are in the basic quality range, with a single dataset qualifying as an estimate. 40 Figure 6 – Corn Processing DQRs and Component Scores by Dataset Technological Rep Geographical Rep Time Rep Completeness Uncertainty Data Quality Rating 0 Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment 1 2 3 4 5 1.6 Ethanol, 95% in H2O, from corn, at distillery/US (Ecoinvent) 2.4 Ethanol, denatured, corn dry mil (USLCI) 2.6 Regional variations in GHG emissions of biobased products in the United States - Corn based ethanol and soybean oil 2.7 Maize starch, at plant/DE (Ecoinvent) 3.0 corn grain, at conversion plant, 2022 (USLCI) 3.5 Corn, in distillery (GaBi PE) 4.1 Average 2.8 41 6 Figure 7- Sugarcane Processing DQRs and Component Scores by Dataset Technological Rep Geographical Rep Time Rep Completeness Uncertainty Data Quality Rating 0 1 Life Cycle Assessment of fuel ethanol from sugar cane in Brazil 2 3 4 1.9 Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry 2.0 Life cycle assessment of australian sugar cane production with a focus on sugarcane processing 2.4 A comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil 3.1 Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR (Ecoinvent) 3.1 sugarcane, in sugar refinery (GaBi PE) 3.2 Life Cycle Assessment of Sugarcane Ethanol and Palm Oil Biodiesel Joint Production 3.6 Average 2.7 42 5 6 Figure 8 - Soy Processing DQRs and Component Scores by Dataset Technological Rep Geographical Rep Time Rep Completeness Uncertainty Data Quality Rating 0 1 Life cycle assessment of soybean based biodiesel production in Argentina 2 3 4 5 2.3 Soybean oil, at oil mill/US (Ecoinvent) 2.3 Soy oil, refined, at plant/kg/RNA (USLCI) 2.3 Soybean oil, crude, degummed, at plant (USLCI) 2.4 Soy biodiesel, production, at plant (USLCI) 2.4 Soybean oil, at oil mill/BR (Ecoinvent) 2.5 Soya oil, at plant/kg/RER (Ecoinvent) 3.1 Average 2.5 The processing data for all three crops scored the worst overall in the category of temporal representativeness. Part of the reason for this is that at least a portion of many of the datasets are from industry statistics and unpublished data. Some of these sources are extremely old and some are of unknown age. One study, “A Comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil”, uses data from 1981 but verified that it was still relatively accurate with laboratory experiments. 43 In general, the documentation of data sources was poorer for the processing datasets than for the cultivation datasets, which is likely because of the use of industry data for which it is often difficult to obtain details. This issue resulted in a diminished ability to accurately assess these datasets. The Ecoinvent datasets also follow this pattern, with high uncertainty relative to the Ecoinvent cultivation files. The combination of these differences results in the processing data having less desirable DQRs as a whole than the cultivation datasets. 44 5. CONCLUSIONS Significant data gaps exist in the availability of life cycle inventory data for biobased polymers. These gaps occur geographically, technologically, and temporally. In addition, gaps exist for certain inputs, like land use change, independent of those qualifying factors. National averages are unlikely to adequately represent either technology used to cultivate a crop in any specific region or the growing conditions in that region. There is therefore a need for more regionally explicit data that accurately models the technology and conditions of a specific system under study. Land use change is often not accounted for in otherwise relatively complete datasets, which is a significant quality issue because it can have a large influence on the overall impacts of a system. More data for land use change is needed, and standardized methods for collecting and incorporating such data into LCA studies are also necessary. Newer and better documented processing data is needed for biopolymer feedstocks, and newer data for the cultivation of feedstocks, especially crop yields, would also be beneficial. Finally, the currently available data is skewed heavily to Europe and the USA, leaving a significant portion of the globe with very few datasets available. In conclusion, understanding the impacts caused by the production of bioplastics is the first step on the path to a more sustainable bioplastic, and in order to accurately evaluate these impacts the data gaps described above must be resolved. 45 APPENDICES 46 Appendix A: Ecoinvent Uncertainty Scoring Information Table 10- Ecoinvent Uncertainty Scoring Information Indicator Score 1 2 Reliability Verified data based Verified data partly on measurements based on assumption or nonverified data based on measurements Completeness Data from all Data from >50% of relevant sites over relevant sites over adequate period to adequate period even out normal fluctuations Temporal Less than 3 years Less than 6 years Correlation difference to difference to reference year reference year (2000) (2000) Geographical Data from area Average data from Correlation under study larger area in which the area under study is included Further Data from Technological enterprises, Correlation processes and materials under study (i.e. identical technology) Sample Size >100 >20 3 Non-verified data partly based on qualified estimates Data from only some relevant sites (<50%) or >50% of sites but from shorter periods Less than 10 years difference to reference year (2000) Data from smaller area than are under study, or from similar area Data on related processes or material but same technology, or from processes and materials under study but different technology >10 47 4 Qualified estimate (e.g. by industrial expert; data derived from theoretical information Representative data from only one relevant site or some sites but for shorter periods Less than 15 years difference to reference year (2000) 5 Non-qualified estimate Data on related processes or markets but different technology, or data on laboratory scale processes and same technology Data on related processes or materials but on laboratory scale of different technology >=3 unknown Representativeness unknown or data from a small number of sites and shorter periods Age of data unknown or greater than 15 years different from reference year (2000) Data from unknown or distinctly different area Appendix B: Completeness Check Includes Data Country Data Source Ecoinvent 1 kg corn grain functional unit (water content 14%, carbon content .375 kg/kg fresh mass, biomass energy content 15.9 MJ/kg fresh mass, Yield 9315 kg/ha). Emissions of N2O and NH3 to air are calculated with emission factors from NREL 2006. Emission of nitrate to water is calculated with a nitrogen loss factor of 32% includes cultivation of corn in the USA including use of diesel, machines, fertilizers, and pesticides Modeled for USA modeled with data from literature USLCI Harvested acres represent 91% of the planted acres. The impacts of producing 1kg seed are assumed to be equal to producing 1 kg grain. Only consumptive use of water taken into account. This model uses "conservational" or "reduced" tillage. Seed production, tillage, fertilizer and pesticide application, crop residue management, irrigation and harvesting. Carbon sequestration is credited. Diesel use in industrial equipment included along with electricity and quicklime. Transportation of fertilizers to the farm (400km) by train. USA Corn, whole plant, at field/kg/US (Corn, at field/kg/US) Details Data Years Corn, at farm/US S Corn, at farm/US U Data Availability Time of publications Name 1998-2000 Table 11 - Corn Cultivation Completeness Check Primary 48 49 Swiss lowlands Ecoinvent Includes the processes of soil cultivation, sowing, , fertilization, harvest and drying 1 kg grain maize IP at form of the grains. Machine with moisture content of infrastructure and shed for 14%. Fresh matter yield/ ha machine sheltering is included. 9279kg. Average production Inputs of fertilizers, pesticides in Swiss lowlands with and seeds as well as their integrated production. 1996transports to the regional 2003 data collection processing center (10km), and direct emissions on the field. Land occupation (non-irrigated) is included. Statistics, pilot network, fertilizing recommenda tions, and expert knowledge Swiss lowlands Grain maize organic, at farm/CH S Crain maize organic, at farm/CH U Ecoinvent 1996-2003 Grain maize IP, at farm/CH S Grain maize IP, at farm/CH U Includes the processes of soil cultivation, sowing, weed control, fertilization, pest and 1 kg grain maize IP at form pathogen control, harvest and with moisture content of drying of the grains. Machine 14%. Fresh matter yield/ ha infrastructure and shed for 9279kg. Average production machine sheltering is included. in Swiss lowlands with Inputs of fertilizers, pesticides integrated production. 1996and seeds as well as their 2003 data collection. This transports to the regional model is non-irrigated. processing center (10km), and direct emissions on the field. Land occupation (non-irrigated) is included. 1996-2003 Table 11 (cont’d) Statistics, pilot network, fertilizing recommenda tions, and expert knowledge LCA Commons LCA Commons has very specific datasets for each of the states listed for multiple years. Not all states have data for all years. fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use. 50 Swiss Lowlands 1 kg silage maize IP, at farm. Moisture content 72% USA: various states Corn grain, at harvest in (year), at farm 8591% moisture (state) Ecoinvent 1996-2003 Silage maize IP, at farm/CH S Silage maize IP, at farm/CH U Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. Direct emissions on the field are also included. 1995-2001, 2005 Table 11 (cont’d) Statistics, pilot network, fertilizing recommenda tions, and expert knowledge Ecoinvent 1 kg silage maize organic, at farm. Moisture content 72%. 51 Swiss Lowlands Silage maize organic, at farm/CH S Silage maize organic, at farm/CH U Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm (1km) are considered. Direct emissions on the field are also included. Carbon sequestration accounted for. 1996-2003 Table 11 (cont’d) Statistics, pilot network, fertilizing recommenda tions, and expert knowledge Life cycle assessment of various cropping systems utilized for producing biofuels: Bioethanol and Biodiesel Biomass and Bioenergy 2005 Functional unit 1 Ha arable land used to produce biomass. Corn monoculture with ground cover, corn monoculture with no stover removal and no ground cover, and corn / soybean rotation are modeled. No till agriculture is assumed for all scenarios. Wet milling used to convert corn to ethanol. System expansion method is used to deal with coproducts. agronomic inputs, fuel used in machines, harvesting, wet milling, conversion of stover into ethanol, soybean milling, electricity, fertilizers 52 USA (Scott County Iowa for corn data) Table 11 (cont’d) Soil carbon and nitrogen estimated by DAYCENT model. National Agricultural Statistics Service (agronomic inputs). Climate and soil data from crop site (primary) 53 Italy International Journal of LCA Sept 2009 Corn ethanol represents dry Direct land use change is milling process, and Soybean included. It is measured and oil was made using the the change in soil carbon crushing process. GHG only organic material. Includes reported category. Data is at impacts associated with the the county level, 40 counties biomass, bio-refining, upstream in the US corn belt were processes. chosen. Tilling, fertilizer, weed control, pest control, seed production, transport of inputs to farm, planting, irrigation, harvest. Fuel used in cultivation, machine manufacture and maintenance, direct field emissions, Primary data / field study. Literature data used for machine production and transportatio n of inputs (Bentrup et al 2004, Audsley et al 1997) USA Regional variations in GHG emissions of bio-based products in the United States Corn based ethanol and soybean oil Journal of Biomass and Bioenergy, July 2012 LCA to evaluate environmental impacts of sunflower and maize, both in rotation with wheat. Reports GWP, eutrophication, and acidification. Three scenarios were studied: Low input, medium input, and high input. 2009 LCA of cropping systems with different external input levels for energetic purposes 17-year period, beginning in 1985 Table 11 (cont’d) Corn cultivation data is from (Kim and Dale 2009) water consumption during corn cultivation and ethanol production 54 USA (Midwest) International Journal of LCA Jan 2012 Ecological impacts of corn based ethanol - water consumption in 81 spacially explicit Minnesota watersheds. Water data taken from Minnesota department of natural resources and water appropriations permit program. Fertilizer, fuels, agrochemicals, transport, milling (crushing), electricity, process chemicals Primary / observation and field study. USA (Minnesota) Measuring ecological impact of water consumptio n by bioethanol using life cycle impact assessment Unpublished LCA of soy biodiesel and corn ethanol. System expansion method used to allocate co-product impacts. Both wet and dry milling of corn is modeled. Local biorefinery data is utilized for each area of study. Data is broken down by county across multiple states. 2004-2011 (data sources) Life Cycle Assessment to Improve the Sustainabilit y and Competitive Position of Biobased Chemicals: A Local Approach 2009 (reported) Table 11 (cont’d) Minnesota department of natural resources, USDA, Patzek (2006), Mishra and Yeh (2011), Nebraska Energy Office Renewable Fuels Association Journal of Industrial Ecology, February 2009 Researchers created their own Biofuel Energy Systems Simulator (BESS) software to compare different types of corn-ethanol systems in a "seed-to-fuel life cycle. Energy and GHG reported. Four component submodels for crop production, ethanol biorefinery, cattle feedlot, and anaerobic digestion. Energy for grain drying and irrigation (but not water). energy used for feedstock production and harvesting, including fossil fuels for field operations and electricity for grain drying and irrigation. 55 USA Improveme nts in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of CornEthanol 2009 (Published) Table 11 (cont’d) Crop yields: USDA-NASS, production energy: USDA-ERS (2001). Progressive, high yield cropping scenario: Verma et al (2005). A decision support tool for modifications in crop cultivation method based on LCA: a case study on GHG emissions reduction in Taiwanese sugarcane cultivation Data Country Life cycle assessment of Australian sugar cane production with a focus on sugarcane growing Data Years diesel, machines, fertilizers, and pesticides Time of publicati ons (various) Scenarios modeled for average (all of Queensland) and regional (Wet Tropics and Burkedin) growing. Nitrogen loss from runoff could not be modeled. Diesel, water for irrigation, seed cane, fertilizer, lime, pesticide, transport of farm inputs, production of "capital goods" i.e. farm equipment. 2002 (agricult ural data)2010 (study publishe d) GHG data for the cultivation of Taiwanese sugarcane. System modeled as 1 year new planting, 1 year ratoon, and 1 year fallow. Soil preparation, growing, harvesting, transport, diesel, direct field emissions, fertilizer, pesticide, herbicide, power generation. Carbon sequestration by sugarcane is taken into account. Details Ecoinvent Cultivation of sugar cane with 20% mechanical harvest and 80% manual harvest Internation al Journal of Life Cycle Assessmen t Nov 2010 Internation al Journal of LCA November 2009 56 1979 (oldest data) 2009 (publish ed) Data Source Australia Sugarcane, at farm/BR S Sugarcane, at farm/BR U Includes Data Availability Agriculture inputs: Millford and Pfeffer 2002, industry statistics Taiwan Name Brazil Table 12 - Sugarcane Cultivation Completeness Check Agriculture and Food Agency (2006), Taiwan Sugar Corporation (1979), Water Resources Agency (2003-2005), Interview (2007), Chinese Fertilizer Association (2005) Carbon footprint of sugar produced from sugarcane in eastern Thailand Biomass and Bioenergy Vol 32 (2008) Journal of cleaner production vol 19 Fertilizer, lime, pesticide, water for irrigation, harvesting, milling, bagasse combustion (for sugarcane only), electricity, transport, machinery, fuel use, clarification. Reports estimated GHG emissions from CO2, CH4, and N2O. Tilling, irrigation, herbicide and pesticide application, diesel, fertilizer, biomass burning, transport, energy use and waste water treatment. 57 2008 2011 USA, UK, and Australia an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation Functional unit is 1 kg of glucose or fructose for fermentation. The three things that were found to have the greatest effect on environmental performance were: commodities displaced by coproducts, agricultural yields, and nitrogen use efficiency. Each crop was assumed to have the same N, P and K fertilizer profile. This study assumes that all crops were produced in monoculture. Field Survey: Fuel use in farm equipment, fertilizer and pesticide use, water use, emissions. Industry statistics: Cane yields Thailand Table 12 (cont’d) Fossil fuel use, sugarcane biomass data, and fertilizer data are from: Field survey, questionnaire and interview. Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry Internation al Journal of LCA May 2009 Functional Unit is 10,000 Km covered by car of a specific size engine, but data is broken into phases. Soil preparation, cane plantation, chemical application, harvesting, fuel ethanol process, and energy co-generation 20032009 Sao Paulo, Brazil Life Cycle Assessment of fuel ethanol from sugar cane in Brazil Journal of cleaner production Vol 39 System based, consequential approach. A range of scenarios involving different uses for coproducts was explored. Land use change, milling and production, fermentation, additional cane growing (for scenarios 3 and 4). Publishe d 2012 Australia Table 12 (cont’d) 58 Water, energy, and emission data from SimaPro (2003) Other: Primary data from sugarcane farms and industries. Energy flows and balances: Hobson P. (unpublished data). Sugar cane growing: Ranouf et al (2010). Fuel use: APACE (1998), Environment Australia (2002). A comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil Journal of Industrial Ecology, June 2012 Details LCA studies of sugarcane-based LDPE produced in Brazil and used/disposed of in Europe, Consequential and attributional LCAs conducted in parallel. Impact categories: GWP, acidification, eutrophication, photochemical ozone creation, primary energy consumption. Fertilizer production, cane cultivation including LUC, ethanol production, ethylene production, LDPE production. Transport, use phase, and disposal also included. Only CO2 was considered in GWP and only from fossil fuel origin. Biogenic CO2 release was not accounted for, and neither was sequestration during cane growing. Functional unit is 1 kg PE. 59 20042006 (Literatu re publishe d) Brazil, Europe Table 12 (cont’d) Brazilian data for every step through ethanol production. Sugar cane cultivation data from: Macedo et al (2004), Cheesman (2005), and Smeets et al (2006). Literature sources used to estimate LUC. Life Cycle Assessment of Sugarcane Ethanol and Palm Oil Biodiesel Joint Production Journal of Biomass and Bioenergy, September 2012 Three LCA studies were carried out in parallel: one for the traditional sugarcane ethanol system, another for a palm oil biodiesel system, and one for the joint production system of sugarcane ethanol and palm biodiesel. Seeds, production and use of agricultural inputs, cropping practices, harvesting and transportation, manufacture and maintenance of machineries and agricultural implements, co-products disposal and transportation, manufacture and use of chemicals inputs, manufacture and maintenance of equipment and industrial construction, and coproducts energy generation. Land occupation and transformation. 60 Sao Paulo, Brazil Table 12 (cont’d) Primary / field survey and questionnaires Soy bean, from farm Soy beans IP, at farm/CH S - Soy beans IP at farm/CH U Includes "Carbon Sequestration should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product" (USLCI). Data Years Data Country Details Data source USDA, EPA, Sheehan J (1998), USGS (1999), National Agriculture Statistics, Pesticide Action Network Diesel used on field, electricity and natural gas for farm activities, fertilizer, lime, land occupation, tilling, transport, water for irrigation, pesticide, herbicide 19902011 LCA Food DK Land occupation arable, fertilizer, fuel for farm machines, lubricant oil for machines 2002 (Data file created) Argentina Soybean grains, at field Data Availability Ecoinvent Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and housing. Inputs for fertilizers, pesticides and seed as well as their transports to the regional processing center (10km) are considered, direct emissions on the field also included. 19962003 Swiss lowlands Name USA Table 13 - Soy Cultivation Completeness Check USLCI 1 kg of soy beans IP, at farm with a moisture content of 11% 61 Soybeans, at farm/BR S Soybeans, at farm/BR U USLCI 1 planted acre for 1 year Seed production, carbon sequestration, tillage, fertilizer and pesticide application, crop residue management, irrigation and harvesting. Only consumptive use of water taken into account. Quicklime and transportation of inputs to the farm is included. Ecoinvent 1 kg soybeans modeled with data from literature, some data extrapolated from Europe (production of fertilizers and pesticides), and Switzerland (machine use). Transports modeled for standard distances. Use of diesel, machines, fertilizers, and pesticides. Carbon sequestration, land transformation and occupation, tilling, sowing, harvesting, seed input, and transport of inputs to the farm. 62 19962004 19982000 USA Soybean grains, at field/kg/US Ecoinvent System Processes / Ecoinvent Unit Processes Time of literatur e publicati ons (various) Brazil Soy beans organic, at farm/CH S - Soy beans organic, at farm/CH U Soil cultivation, sowing, fertilization, harvest and grain drying. Machine infrastructure and housing. Inputs for fertilizers, 1 kg soy beans organic, at farm pesticides and seed as well as with moisture content of 11% their transports to the regional processing center (10km) are considered, direct emissions on the field also included. Swiss lowlands Table 13 (cont’d) USDA, EPA, Sheehan J (1998), USGS for NOAA (1999), National Agriculture Statistics, Pesticide Action Network Soybeans, at farm/US S Soybeans, at farm/US U fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use, seeding 19962000, 2002, 2006 USA: various states Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO LCA Commons LCA Commons has specific data for each state listed for various years. Not all states are available for all years. Journal of Cleaner Production 2009 Data for Jatropha, soy, palm oil, rape seed oil, and used cooking oil for production of biodiesel. Reports carbon footprint and GHG savings (except for Jatropha). Includes GHG from direct and indirect land use change. GHG and carbon footprint only. Land use changes included in this calculation. 2009 (Publish ed) Import to UK Soybeans; at harvest in (year); at farm; 85-92% moisture (state) 1 kg soybeans with moisture content of 11%. Modeled with data from literature, some data extrapolated from Europe (production of fertilizers and pesticides), and Switzerland (machine use). Transports modeled for standard distances. Use of diesel, machines, fertilizers, and pesticides. Carbon sequestration, LUC and use, tilling, sowing, harvesting, seed input, and transport of inputs to the farm. Carbon sequestration, land transformation (place holder for ongoing process), land occupation, lime, sowing, tilling, harvesting, and herbicide. Seed inputs also included. Time of literatur e publicati ons (various) USA, with some data from Europe and Switzerland Table 13 (cont’d) Ecoinvent 63 NGO and Policy sources Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans Journal of Cleaner Production 2009 GHG emissions only. System models soybeans grown for 25 years on land from cleared rainforest or savannah with no tilling. 64 20012005 Argentina Life cycle assessment of soybean based biodiesel production in Argentina Primary data was obtained for the crop portion of the data only. Economic allocation was used for co-products. Different Only CO2, CH4, and N2O types of soy (first and second were considered in the global class, conservation till and no warming calculation. Land International till) were used, and weighted use change except for direct Journal of by their production volumes. de-forestation is excluded. LCA March Second class soy uses the Storage and drying is 2009 residual fertilizers in the soil excluded. Agriculture, from the wheat that is extraction and refining, transcultivated in rotation with it, esterification included. while first class soy is produced in monoculture and has fertilizers applied. 2009 Brazil, Europe Table 13 (cont’d) Field survey and primary data from Donato et al 2005 used for agriculture data. Ecoinvent data used for all else. Appendix C: Data Quality Ratings Data Country Technological Rep USA (Midwest) Cultivation practices varied by county. State level input statistics used when county level unavailable. Current tillage practices represented. 1.5 Switzerland Data Years 2008-2009 1996-2003 Data Availability Unpublished Ecoinvent Annual Report: Life Cycle Grain maize organic Assessment to Improve the at farm/CH S – Sustainability and Competitive Grain maize organic Position of Biobased Chemicals: A at farm/CH U Local Approach Name Table 14 - Corn DQR Represents Organic cultivation in Switzerland 1 Geographical Rep Time Rep Completeness Data available on a county basis, accounts for variation between locations Corn data averaged from 20002006 (continuous) System expansion model used, direct land use change included but not indirect. 1 1 1.5 Data is from Switzerland. Data collected from 19962003 High level of completeness. 1 2 1 65 Uncertainty Data Quality Rating High 1.4 Low uncertainty Transport distances are estimates. 1.5 High 1.6 Switzerland USA Switzerland 1996-2003 Time of publications 1996-2003 Ecoinvent Ecoinvent Ecoinvent Grain maize IP, at farm /CH S - Grain maize IP, at farm/CH U Corn, at farm/US S – Corn, at farm/US U Silage maize organic, at farm/CH S - Silage maize organic, at farm/CH U Table 14 (cont’d) Represents Organic cultivation in Switzerland Data is from Switzerland. Data collected from 19962003 High level of completeness. 1 Data is for the typical cultivation system used in the USA. Tillage practice not stated, but appears to represent conventional tillage practices. 1 1 2 1 Data for the USA. Regional differences are not accounted for. Data from 2004-2006. Ecoinvent's reference year is 2000. High level of completeness. 1.5 2 1 Represents cultivation system used in Switzerland during the reference period. Data is from Switzerland with general European data Data collected from 19962003 High level of completeness 66 Low uncertainty Transport distances are estimates. 1.5 Most data has low uncertainty. Carbon dioxide and energy from biomass are estimates as well as transport distances. 1.5 Low uncertainty. Transport distances estimates some agronomic inputs have moderate uncertainty. High 1.6 Basic 1.7 Basic Table 14 (cont’d) Switzerland USA various states 1996-2003 1995-2001, 2005 Ecoinvent 1.5 2 1 Represents cultivation system used in Switzerland during the reference period. Data is from Switzerland with general European data Data collected from 19962003 High level of completeness. 1 LCA Commons Corn grain, at harvest in (year), at farm 85-91% moisture (state) Silage maize IP, at farm /CH S - Silage maize IP, at farm/CH U 1 1.5 2 1 1.5 1.7 Relatively complete. Land transformation is accounted for (including the change caused by rotational cropping). However, cutoff values are applied to many inputs. 2 LCA Commons uses a scoring system of A (good) and B (less good). Uncertainty varies by state and year. High Data for the system under study (USA) broken down by state. Data available at state level. Available as averages of multiple years or as data from individual years. 1 1 1 67 1.5 Low uncertainty for most flows. Transport distances are estimates. 1.7 Basic 1.6 USA (by county) USA (Minnesota) 2009 Cultivation practices varied by county are weighted for state level inputs. Data available on a county basis, accounts for variation between locations 1 2004-2011 (data sources) International Journal of LCA International Journal of LCA Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment Regional variations in GHG emissions of bio-based products in the United States - Corn based ethanol and soybean oil Table 14 (cont’d) 1 Represents current corn irrigation practices in region under study. Irrigation requirements for individual farms taken from water permit office, very specific geographic information used. 1 1 68 Data from 2000-2008 2 Data from 2004-2011 with disparate sources. The data from 2004 is USDA corn yield and production data at county level. 2.5 GHG emission study only. Direct land use change is included. System expansion is used to deal with allocation issues High 1 1.6 Water only, meets study scope Basic 1 1.9 USA (Scott County Iowa = corn data) USA 2005 (study published) 2009 (study published) Biomass and Bioenergy Industrial Ecology Improvements in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of Corn-Ethanol Life cycle assessment of various cropping systems utilized for producing biofuels: Bioethanol and Biodiesel Table 14 (cont’d) Soil and temperature data is based Three scenarios on one country are modeled, all (Scott country, with no-till Iowa). This is agriculture. The within the US, EPA estimates but may not be 2/3 of corn in representative the US uses of averages. conservation This is balanced tilling, but not by use of necessarily no national till statistics for agronomic inputs. 1.5 2 Standard and Weighted "progressive" averages used scenarios for input rates. modeled. EPA Midwest estimates accounts for change in the 88% of corn technology production in used from 2005. The 2005-2009 "progressive" (conservation model is based tillage increase on a single field from 40% to study in 70%) Nebraska 69 Most data is from 20002005 with some fertilizer data from 1994 (urea production) and 1998. System expansion model used, but land use change not included. Basic 2 2 1.9 Data from 2001-2005, study published in 2009 Does not include direct or indirect land use change Basic Table 14 (cont’d) Italy 1985-2002 Biomass and Bioenergy 2 Primary data Primary data from field from Tuscany, study central Italy. conducted The Primary 1985-2002. data is from a Other data smaller region from 1997 than the and 2004. abstract sites Spread of 19 as the area of year the study primary data (Mediterranean has region). continuity. 3 2 2 2.0 Land use change not accounted for Basic 2 2.5 Data is for US cultivation. Averaged conservation and conventional tillage practices. Irrigated system Data based on US averages, regional variations not captured. Significant data sources from 19952003. Several dummy processes used to model agrochemicals. Land use change not accounted for. Basic 1 1.5 3 2.5 2.5 Three scenarios (low, traditional, and high input is modeled). S2 represents the standard practice in the area, and conditions are well documented USA Data Sources from 1995-2003 1 USLCI Corn, whole plant, at field/kg/US (Corn, at field/kg/US) LCA of cropping systems with different external input levels for energetic purposes 2 2 70 USA Estimates 2022 USLCI Corn, production average, US, 2022 Table 14 (cont’d) Estimates of production for 2022 Data based on US averages, regional variations not captured. Calculated estimates for 2022 High level of completeness including land transformation. 1 1.5 1 1 71 From qualified estimates derived from theoretical information. 4 Basic 2.6 Data Country Brazil Brazil Data Years 2003-2009 2004-2006 (Literature published) Data Availability International Journal of LCA May 2009 Journal of Industrial Ecology, June 2012 A comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil Life Cycle Assessment of fuel ethanol from sugarcane in Brazil Name Table 15 - Sugarcane DQR Technological Rep Geographical Rep Time Rep Cane is grown in 6 year cycles. 20% replaced every year. Study reflects Data specific to the high NE Sao Paulo intensity of Brazil inputs typically used in Brazil. Cane is mostly burned before harvest. 1 1 Both mechanical and manual harvest are modeled. Details of cultivation process modeled are vague. Brazilian data used for cane cultivation, but from various literature sources. Detailed account of geographic information unavailable. 72 Completeness Primary data collected from 2001-2008. N, P, and K fertilizer input data from 2000 and 2003. Land occupation and land use change are not accounted for. Study uses a cut-off of 0.05% for inputs. 2 Data sources range from 2004-2009. Various literature sources used. 2 Both attributional and consequential methods are used. System expansion is used to deal with coproducts for the consequential method. Uncertainty Data Quality Rating Basic 1.8 Land use change emissions are uncertain due to lack of uniform methods. Basic Table 15 (cont’d) Australia Thailand 2008 2011 Journal of cleaner production vol 19 Carbon footprint of sugar produced from sugarcane in eastern Thailand an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation Biomass and Bioenergy Vol 32 (2008) 1.5 Monoculture with conventional practices assumed. New planting every 4-6 years. Typical technology for region. 2 Data for Queensland, which has a large variation in climate conditions. Min and max values are provided for inputs, but variation is represented to a limited extent. 1.5 1 Sugarcane Data is from harvested the study area green and (Eastern burned. Thailand). Manual harvest Cropping Sugarcane practices were cultivation in found to vary Thailand is an significantly established within this process. Farms area, which is in operation for reflected in the 20 years or data. longer. 73 2.5 Data for yields (2003) and harvesting energy (2002) are the most significant due to the sensitivity of results to these two items. Other data ranges from 19962007. 2.5 Survey cropping averages from 2003-2007. Soil conditions data is from 1993. 1 Land occupation and land use change not accounted for. Some data partly based on estimates. Displacement method used to deal with coproducts. 2 Land occupation and transport of inputs to farm not accounted for. Land use change excluded since this study was conducted on established farms. GHG estimates from CO2, N2O, and CH4. 2.1 Min and max input values calculated. Variation due to regional differences accounts for most of this. Study does not capture all variation. Basic 2.1 N fertilizer rate varied by a factor of 18, and the yield varied by a factor of 3. Basic Table 15 (cont’d) Australia Published 2012 Journal of cleaner production Vol 39 Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry 1 1.5 2 Data used from Data from Both standard Queensland Renouf et al cropping (98% 2010 is rated system and Australian at 3. Other "eco-efficient" production), data cropping but does not introduced in system capture this study is modeled. Input variation in the consistent with levels for both region as this timeframe clearly defined. averages are (2004-2009). used. 1 1.5 3 74 2.5 Based on data from Renouf et al 2010, but includes land use change and a progressive cropping scenario. However, the methods used to evaluate water and land use have significant limitations. 1.5 2.1 Basic 2.4 Brazil Australia Time of literature publications (various) 2002 (agricultural data)-2010 (study published) Ecoinvent International Journal of Life Cycle Assessment Nov 2010 Life cycle assessment of Australian sugar cane production with a focus on sugarcane growing Sugarcane, at farm/BR S Sugarcane, at farm/BR U Table 15 (cont’d) Harvesting is assumed to be 20% mechanical and 80% manual. Not indicated if cane is harvested green or burned. Tillage practice not identified. 2 60% irrigated, 39% burned before harvest. Methods modeled are varied by region, based on field survey. 5-6 year cropping cycles modeled, some with fallow periods Data for land use and change from 1996. Data for Data modeled some from literature. agronomic Most data inputs from specific to 1988, and Brazil, but US harvesting and electricity fram activities used. data is from 1996. All other data within 3 years of reference year. 2 3 Average scenario modeled for Queensland (98% Eight year gap Australian between production), agricultural scenarios also data and study modeled for publication. areas within Queensland to capture variability. 75 Most flows are complete. Land occupation and transformation as well as energy from biomass and CO2 have uncertain completeness. Most inputs have very low uncertainty, but CO2 and energy from biomass are qualified estimates (score of 4 on pedigree matrix) Basic 1.5 2 2.5 N loss from runoff not accounted for. Scope of the study does not include land use change. Monte Carlo analysis revealed "significant variation" Basic Table 15 (cont’d) Taiwan 1979 (oldest data) - 2009 (published) International Journal of LCA November 2009 A decision support tool for modifications in crop cultivation method based on LCA: a case study on GHG emissions reduction in Taiwanese sugarcane cultivation 1 1 3 2 3 year cropping cycle assumed (plantingratoon-fallow). Varying levels of inputs modeled to compare effect on yield and GHG emissions. Most data specific to Taiwan. Some Chinese data used for fertilizer production impacts. A significant amount of data is used from 1979 from the Taiwanese Sugar Corporation. Including agricultural inputs and machinery. Land use change is not included despite the fact that sugarcane production is expected to increase in Taiwan and fallow land will likely be converted. 1 1 5 2 76 2.4 Sensitive to sugarcane yield Data Estimate 3.6 Brazil Journal of Biomass and Bioenergy, September 2012 Life Cycle Assessment of Sugarcane Ethanol and Palm Oil Biodiesel Joint Production Table 15 (cont’d) Sugarcane data from Sao Paulo, Brazil. Data sources Palm data from from 1995a different 2008, study region. This published may affect the Based on 2012. Main accuracy of the regional data data sources predictions in that reflects are primary the "joint actual practices data / surveys. production" in that region. No information model. Only 3 about the refineries dates of the surveyed. surveys is Effects of using available. different types of land are discussed. 1 2 5 77 All major components are accounted for. However, detailed info about the agricultural inputs used is not available and the transport of inputs to the farm is not accounted for. Data Estimate 1.5 3.7 Data Country Data from Switzerland. Data from19962003 High level of completeness. 1 2 1 Switzerland Data Years 1996-2003 1996-2003 Ecoinvent Ecoinvent Name Soy beans IP, at farm/CH S - Soy beans IP at farm/CH U Represents organic cultivation in Switzerland during the data years 1 Soy beans organic, at farm/CH S - Soy beans organic, at farm/CH U Technological Rep Switzerland Data Availability Table 16 - Soy DQR Geographical Rep Time Rep Represents cultivation method typical in region during data period. Data from Switzerland and Europe Data from 1996-2003 1 1.5 2 78 Completeness Uncertainty Low level of uncertainty for most flows. Transport distances are estimates. 1.5 Data Quality Index High 1.6 High level of completeness. Low level of uncertainty for most flows. Transport distances are estimates. Basic 1 1.5 1.7 USA LCA Commons Soybeans; at harvest in (year); at farm; 85-92% moisture (state) Table 16 (cont’d) Represents system under study. Variation is accounted for. Argentina Published 2009 International Journal of LCA March 2009 Life cycle assessment of soybean based biodiesel production in Argentina 1 Represents cultivation practices typical of the region weighted by production volume. Data available as Data for the USA average broken down by over state. Variation several captured. years or for individual years. 1 1 Relatively complete. Land transformation is accounted for (including the change caused by rotational cropping). However, cutoff values are applied to many inputs. 2 Differences Majority of Most major between regions data is contributors are weighted from 2005 accounted for, based on through but only direct productions 2007. Some deforestation is volume, but background measured for further data from land use refinement is early 2000s change. called for. used. 79 LCA Commons uses a scoring system of A (good) and B (less good). Uncertainty varies by state and year. High 1.6 Basic Table 16 (cont’d) USA Literature sources 20042006 Ecoinvent Soybeans, at farm/US S Soybeans, at farm/US U 1 Represents system under study. Soy data is for South America Published 2009 Journal of Cleaner Production 2009 Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO 1 Details of the agricultural system modeled are vague, but monoculture with high amount of agro chemicals is assumed. Data from multiple sources used. 2.5 1.5 2 Some data from the US, but many inputs adapted from Swiss and European data. 3 Data from various regions in South America used (Brazil, Argentina, and Bolivia) but variation between regions not distinguished. Unclear what types of data were used from each region. 2.5 80 2 1.8 Co2 and energy from biomass are calculated estimates. Transport distances also estimates. 1.5 Literature sources published 2004-2006 High level of completeness 2 1 Soy data from 20032009. Multiple sources used. GHG only, matches study scope. Direct Land use change is accounted for based on different conversion scenarios. Indirect land use change not accounted for. Basic 2 1.5 2.3 Basic 2.3 Soybean grains, at field (1998-2000)/kg/US Table 16 (cont’d) USA Brazil 1998-2000 Modeled from literature USLCI Ecoinvent Based on US averages, regional differences not accounted for. Significant data sources from 19952003. 1 Soybeans, at farm/BR S - Soybeans, at farm/BR U Based on US averages. Weighted conventional and conservation tillage. 1.5 1.5 Represents cultivation Some data system under specific to Brazil, study, but but agronomic unclear if inputs adapted conventional from Swiss and or European data. conservation tillage is used. 1.5 3 Literature sources published 2001-2006 2 81 Several dummy flows used to model agrochemicals. Farm processes (harvesting, tilling etc) not called out in flows. 3 Basic 2.4 CO2 and energy from High level of biomass are completeness calculated including land estimates. transformation Transport from forest and distances shrub land. also However, estimates. application of Significant Lime is not uncertainty accounted for. in agronomic inputs. 1.5 3 Basic 2.5 Table 16 (cont’d) USA Brazil 1997-2010 Submitted 2007 USLCI Journal of Cleaner Production 2009 Soybean grains, at field/kg/US Based on US averages, regional differences not accounted for. 1997-2010 from various sources. 1 Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans Based on US averages. Weighted conventional and conservation tillage. 1.5 3 Different scenarios (no till and conventional till) modeled. Data mostly based on averages. Economic allocation used but based on prices from Europe. Some data from Europe and the US adapted for Brazil. Regional variations not accounted for. 2.5 2.5 Dummy processes are used for several chemicals and land use change is not accounted for. 2.5 Basic 2.5 Basic 3 82 Data from 1998 2008 from disparate sources. Carbon and GHG only, matches scope of study. However, many estimates used. Study assumes land will be abandoned after 10 or 25 years. 2 2.8 Argentina Unknown LCA Food DK Soy bean, from farm Table 16 (cont’d) Cultivation of soy but unspecified technology Arable land data is from Argentina, other data generic. Unknown 3 3 5 83 Very few flows present. Types of fertilizer unspecified. Emissions incomplete. 5 Low Quality Estimate 4.5 Appendix D: Processing Data Completeness Check Data Availability Details Includes Data Years Data Country Data Source USLCI This process transports corn grain to the conversion plant. It does so using transportation modal allocation from the USDA Ethanol Backgrounder (2007), assuming this current allocation will apply in 2022. Distances for each mode are from a combination of references; still missing a good distance estimate for barge, but since the share of barge transportation is ~2%, the final result will not be sensitive to this parameter. Infrastructure impacts are included in this process by calling the Ecoinvent "transport" processes. The production of corn grain feedstock utilized in this transport process allocates inputs to the stover and grain based on the amount of ethanol that can be produced from each co-product. 2022 USA Unknown corn grain, at conversion plant, 2022 Name Table 17 - Corn Processing Completeness Check 84 This process is the production steps required to obtain maize starch from corn. The corn input refers to Grain Maize IP. Allocation was done on an economic basis. Moisture content is 14% by weight. The only emission included in this process is heat. No other emissions to the environment are accounted for. Mechanical separating steps, swelling in process water, milling of the swelled corns, desiccation and drying of the extracted starch. Processing of water was included as well as infrastructure use. 1998 Germany Detailed literature study processing data for corn grain, at conversion plant 2022 Corn dried and stored, milling, gluten drying, waste disposal, fermentation, electricity, and process water. Infrastructure not included. 2000-2010 North America McAloon 2000, Hsu 2010, Mueller 2007 Ecoinvent System Processes / Ecoinvent Unit Processes USLCI Ethanol, denatured, corn dry mil Maize starch, at plant/DE S - Maize starch, at plant/DE U Table 17 (cont’d) 85 USA transport of corn grains to the distillery, processing to hydrated ethanol. System boundary is at the distillery and dehydration is not included. USA 86 Project Alcosuisse, industrial data, literature. Tramsport Ecoinvent, modified by GaBi distances estimates. Unknown GaBi PE Ecoinvent Unit Process 1 kg hydrated ethanol 95% ( dry basis, i.e. 1.05 kg hydrated ethanol wet basis). Dry milling technology. Economic allocation 97.6% to ethanol. CO2 emissions are allocated based on carbon balance. Infrastructure, transport to facility, waste treatment, process chemicals, process energy, water. 1990-2006 Corn, in distillery Production of 1 kg hydrated ethanol 95% dry basis (1.05kg wet basis). Also delivers co-product "DDGS, from corn, at distillery". Economic allocation w/ factor of 97.6% to ethanol. Allocation according to carbon balance for CO2 emissions. Does not specify which Ecoinvent file data is taken from. Ethanol, 95% in H2O, from corn, at distillery/US S Ethanol, 95% in H2O, from corn, at distillery/US U Table 17 (cont’d) 87 Literature and industry sources from 19912009. Background data from Ecoinvent and Ecobilan. Dry milling process: grinding, cooking, fermentation, distillation and DDGS recovery. Chemicals used are caustic lime, soda, sulfuric acid, and urea. USA Corn ethanol represents dry milling process, and Soybean oil was made using the crushing process. GHG only reported category. Data is at the county level, 40 counties in the US corn belt were chosen. System expansion is used to deal with allocation. DDGS displaces corn, soy meal, and nitrogen in urea. 1991-2009 International Journal of LCA Sept 2009 Regional variations in GHG emissions of biobased products in the United States - Corn based ethanol and soybean oil Table 17 (cont’d) International Journal of LCA Jan 2012 Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment Ecological impacts of corn based ethanol - water consumption in 81 spatially explicit Minnesota watersheds. Water data taken from Minnesota department of natural resources and water appropriations permit program. Water consumption during corn cultivation and ethanol production. Represents dry milling process. 88 Minnesota department of natural resources water permit appropriation program, USDA (2004, 2010), Patzek (2006), Mishra and Yeh (2011), Nebraska Energy Office (2011), Renewable Fuels Association (2008). USA (Minnesota) 2006-2011 (data sources) Table 17 (cont’d) Includes Data Years Data Country The multi-output process "sugarcane, in sugar refinery" delivers the coproducts: Sugar, ethanol 95% in H2O, sugarcane molasses, bagasse, electricity, and vinasse. Economic allocation with 80-85% to sugar and 1011% to ethanol. Allocation according to carbon balance for CO2. Sugar Cane used is from "sugar cane , at farm" BR Process energy (from burning of residues, coal, and wood), process water (tap), waste disposal (modeled with CH municipal disposal, ash disposal both landfill and incineration), ethanol fermentation plant, limestone, transport (unspecified), wastewater treatment, process chemicals, and sugar refining. Land use / transformation not included. 2011 (entered into database) Brazil 89 Data Source Data Availability Details Gabi-PE sugarcane, in sugar refinery Name Table 18 - Sugarcane Processing Completeness Check Time of publications Brazil Functional Unit is 10,000 Km covered by car of a specific size engine, but data is broken into phases. Waste water from the ethanol process is used to irrigate the fields, transported there by trucks. Cane Washing, juice extraction, refining, fermentation, and distillation of ethanol. Electricity cogeneration by steam. 90 2003-2008 Sao Paulo, Brazil Water, energy, and emission data from Publications. Also "some data are SimaPro (2003) Other: derived from other or unknown Primary data from plant or have been estimated". sugarcane farms and industries (2001-2008) Ecoinvent Allocation based on economic criteria. Fermentation of sugar cane including materials, energy uses, infrastructure, and emissions. Lubricating oil for machines included. International Journal of LCA May 2009 Ethanol, 95% in H20, from sugar Life Cycle Assessment cane, at fermentation plant/BR S of fuel ethanol from Ethanol, 95% in H20, from sugar sugar cane in Brazil cane, at fermentation plant/BR U Table 18 (cont’d) 91 Energy flows and balances: Hobson P. (unpublished data). Sugar cane growing: Ranouf et al (2010). Fuel use: APACE (1998), Environment Australia (2002). Background Data: Life Cycle Strategies (2009). Fermentation: Aden et al (2002). PLA production: Vink et al (2003). Australia System based consequential approach. A base case and 5 scenarios are represented. In the base case, the mill produces sugar and molasses (used as animal feed). Scenario 1: Cane crushing, juice extraction excess electricity from and purification, bagasse is exported to the concentration and grid. Scenario 2: ethanol is crystallization (if applicable). made from molasses. Fermentation including Scenario 3: ethanol is made chemical inputs, and PLA from bagasse. Scenario 4: production included. ethanol is made from cane juice with increased sugarcane production. Scenario 5: PLA is made from cane juice with increased sugarcane production. Published 2012 Journal of cleaner production Vol 39 Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry Table 18 (cont’d) 92 Brazilian data for every step through ethanol production. Ethanol yield data from: Macedo et al (2004). PE production based on process simulation and literature (Kochet et al. 1981 and Barrocas and Lacerda 2007). Data from NTM 2009, Bargigli et al. 2004, cottro et al 2003, and Tillman et al. 1992 also used. Cultivation of cane, cane washing, crushing, juice extraction, PH adjustment, fermentation and distillation included in ethanol production. Ethylene production: heating, dehydration by aluminum catalyst, and purification to PE grade ethylene. LDPE production: polymerization at 130-330 C and 81-276 mpa. Brazil, Europe Details LCA studies of sugarcane-based LDPE produced in Brazil and used/disposed of in Europe, and fossil-based LDPE produced, used, and disposed of in Europe. Consequential and attributional LCAs conducted in parallel. No major differences found between the two methods for "key" impacts. Impact categories: GWP, acidification, eutrophication, photochemical ozone creation, primary energy consumption. Only CO2 was considered in GWP and only from fossil fuel origin. Biogenic CO2 release was not accounted for, and neither was sequestration during cane growing. Functional unit is 1 kg PE. 1981- 2009 (Literature published) Journal of Industrial Ecology, June 2012 A comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil Table 18 (cont’d) 93 Primary / field survey and questionaires. Data for ethanol production collected from three biorefineries. Manufacture and use of chemicals inputs, manufacture and maintenance of equipments and industrial construction, and co-products energy generation. Sao Paulo, Brazil Three LCA studies were carried out in parallel: one for the traditional sugarcane ethanol system, another for a palm oil biodiesel system, and one for the joint production system of sugarcane ethanol and palm biodiesel. GHG and Energy only. 2012 (published) Journal of Biomass and Bioenergy, September 2012 Life Cycle Assessment of Sugarcane Ethanol and Palm Oil Biodiesel Joint Production Table 18 (cont’d) 94 "Industry consultation" in association with Sugar Research and Innovation at Queensland University of Technology (unpublished data). Australian LCI database (2007), and Ecoinvent (2009). process energy from bagasse, dunder (used on fields), process chemicals, flocculent, lubricant for machinery, displaced products for system expansion; sorghum, electricity, LP steam, potassium chloride. Cane crushing, juice purification, juice concentration, crystallization, and fermentation. Fossil fuels for start-up of boilers are not included. Australia Three scenarios are modeled. 1) sugar mill produces only sugar an molasses. Power is generated from bagasse combustion with no cogeneration. 2) sugar mill produces sugar and molasses with cogeneration from bagasse. Excess power is exported to the grid. 3) Sugar mill uses co-generation and produces ethanol from molasses. Economic, mass, and system expansion methods of allocation are all modeled. Water evaporated from cane juice is used for processing. Study published 2011. Data sources 2007, 2009. International Journal of Life Cycles Assessment 2011 Life cycle assessment of Australian sugar cane production with a focus on sugarcane processing Table 18 (cont’d) 95 Data source Data from a US study, cross Reusser 1994, Cederberg 1998, checked with literature von Daniken et al. 1995. Some sources, industrial data. values provided by European Energy data from national manufacturing companies. statistics. Data Country Soy data refers to "Soybeans, at farm/BR U" Europe Transport to process facility, process energy (electricity and natural gas), organic chemicals for processing. Conditioning of the beans, but not drying, is included. Infrastructure and land use. Transport to mill, processing into oil and meal. Process chemicals are accounted for as well as process energy. Brazil (adapted from US data) Ecoinvent Soy data file refers to "Soy bean IP, at farm/CH". This process refers to their further processing. Process energy is provided by natural gas. Processing is done in Europe with beans that are assumed to be imported. Data Years Includes 1998-2005 Data Availability Details Ecoinvent Soybean oil, at oil mill/BRS – Soybean oil, at oil mill/BR U Soya oil, at plant/kg/RER S Soya oil, at plant/kg/RER U Name Table 19 - Soy Processing Completeness Check USLCI Processing of Soy into Soy oil. "Refers to Soybean grains, at field" Energy, process chemicals, water, transportation to processing facility, and dummy process for waste disposal. 2010 USA Omni Tech 2010, NOPA Soy data file refers to "soybeans, at farm/US" Allocation based on carbon balance. Solvent extraction modeled, typical for USA. Includes carbon sequestration, soybean inputs, transport to the oil mill, infrastructure of the oil mill, process water (tap), process energy, and process chemicals. 2006 (data file created) USA US study and literature sources, energy data from national statistics 96 USA Soy input refers to "Soy, degummed, at plant". This process adds process water, process energy (natural gas and electricity), and transport to processing facility. It also includes sodium hydroxide (process chemical) and disposal of liquid wastes. Late 2000s USLCI Further processing of "Dummy Soybean oil, crude, degummed, at plant/kg/RNA". No impacts are associated with this dummy file. Energy data is from the late 2000s and all other data is theoretical. Carbon sequestration should be accounted for by the practitioner based on the oil use. Ecoinvent Soybean oil, at oil Soybean oil, mill/US S crude, Soybean oil, at oil degummed, at mill/US U plant Soy oil, refined, at plant/kg/RNA Table 19 (cont’d) 97 Jungluuth et al 2007, IDIED 2004. Only CO2, CH4, and N2O were considered in the global warming calculation. Land use change except for direct deforestation is excluded. Storage and drying is excluded. Agriculture, extraction and refining, trans-esterification included. Argentina Primary data was obtained for the crop portion of the data only. Economic allocation was used for coproducts. Oil extraction and trans-esterification data adapted from Jungluth et al 2007 and IDIED 2004. Solvent extraction is modeled. Allocation factors, yields, natural gas, electricity consumption and mix, and transport distances are specific to Argentina. North America Materials, process energy, water, transport, 2001-2005 USLCI "CARBON SEQUESTRATION should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product"(USLCI). International Journal of LCA March 2009 Life cycle assessment of soybean based biodiesel production in Argentina Soy biodiesel, production, at plant Table 19 (cont’d) Appendix E: Processing Data Quality Ratings Data Country Data Years 1998 (volume) 2007 (data file created) Germany Data Availability Ecoinvent Maize starch, at plant/DE S - Maize starch, at plant/DE U Name Table 20 - Corn Processing DQR Time Rep Completeness Uncertainty Data Quality Rating Represents technology under study Refers to typical conditions in Germany Most data of unknown age. Production volume taken from 1998. Water, power, transport and infrastructure accounted for. The only emission is heat. No process chemicals accounted for. Low uncertainty for most flows. Transport distances are estimates. Estimate 1 1 4 3 2 3.0 Technological Geographical Rep Rep 98 Ethanol, 95% in H2O, from corn, at distillery/US S - Ethanol, 95% in H2O, from corn, at distillery/US U Table 20 (cont’d) USA North America Data from 1990 -2006 Data from 2000-2010 USLCI Ecoinvent 1 Ethanol, denatured , corn dry mil Represents technology under study Data for USA adapted mainly from Europe (similar conditions). US electricity used. 2.5 3 1.5 File claim corn dry milling, but input flows refer to wet milling inputs. Data for North America, bur no regional variations accounted for. Data from 20002010 from literature sources. Data file was established in 2011. Energy input data is from 2007. Good level of completeness but infrastructure and land use not accounted for. Basic 3 1.5 2.5 2 2.6 Data from 1990Facility land 2006, data file use and created in 2006. transformation However, data not accounted reflects current for. Otherwise processing complete. technology. 99 Low uncertainty for most flows. Transport distances are estimates. Basic 2 2.4 North America corn grain, at conversion plant, 2022 Table 20 (cont’d) Barge transport distance is Transport only, uncertain, meets study but this is scope less than 2% of the total transport distance. USA 2005 1991-2009 USLCI International Journal of LCA Sept 2009 Data for area under study Data is from 2005, this file is an estimate for 2022 1 Regional variations in GHG emissions of bio-based products in the United States – Corn based ethanol and soybean oil Data is for technology under study 1 5 1 3.5 Data is for technology under study Site specific data not available, industry averages used. Oldest foreground data from 1998 and oldest background data from 1991. Chemical data from 2000. Industry process statistics from a range of 10 years. GHG only, meet study scope. Inputs have good completeness. Basic 1 2 3.5 1 2.7 100 Estimate USA (Minnesota) 2006-2011 International Journal of LCA Jan 2012 Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment Table 20 (cont’d) Data is for technology under study Facility specific data from Minnesota DNR water permits. Data is from 2006-2011. Study published in 2012 Water only, matches study scope. High 1 1 2 1 1.6 101 Data Country Australia Data Years 2011 (published) Data Availability International Journal of Life Cycles Assessment 2011 Life cycle assessment of Australian sugar cane production with a focus on sugarcane processing Name Table 21 - Sugarcane Processing DQR Technological Rep Geographical Rep Time Rep Completeness Three scenarios, representative of the area, are modeled. Data is for Queensland, Australia. This accounts for 98% of Australian production. Unpublished data is of unknown date. Most other data from 20042009, but oldest background data is from 1989. Good level of completeness, but infrastructure and land occupation / transformation not included. System expansion model includes displaced products. Basic 1 1 3 2 2.4 102 Uncertainty Data Quality Rating Time of publications Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR S Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR U Table 21 (cont’d) Good level of completeness, but facility land use / transformation not accounted for. Most flows have moderate uncertainty. Some data is estimated. Estimate 3.5 3.1 Brazil Ecoinvent Journal of Biomass and Bioenergy, September 2012 Data is for Brazil, but several inputs are adopted from Europe. 1 Life Cycle Assessment of Sugarcane Ethanol and Palm Oil Biodiesel Joint Production Data is for the technology under study. Data from 1998 - 2004. Data entered in 2010. Some data is based on estimations. 2 4 1.5 Data is for Sao Paulo, Brazil. Local survey taken. Data sources from 19952008, study published 2012. Main data sources are primary data / surveys. No information about the dates of the surveys is available. GHG and Energy Balance only, matches study scope. Transport between the farm and processing facility is not accounted for. Data is for the technology under study. 103 Estimate Table 21 (cont’d) Brazil 1981- 2009 Journal of Industrial Ecology 2012 A comparative Life Cycle Assessment of PE Based on Sugar Cane and Crude Oil 1 1 5 1.5 High degree of completeness, but facility land Data is mostly Oldest source use not for technology from 1981, but Most data for accounted for. under study, but verified with Brazil, but some Biogenic CO2 is polymerization experimentation data taken from also not data adapted for accuracy. All Swedish considered in from similar other sources producer either uptake data. from 1992 Borealis. or emission Experimentally (emissions data) because verified. to 2009. disposal by incineration is assumed. 1.5 1.5 4 104 1.5 3.6 Polymerizati on data taken from Borealis had to be allocated because it was for the production Estimate of both HDPE and LDPE. The division was based on energy consumptio n. 3.1 Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry Table 21 (cont’d) Australia Brazil 2002-2010 2001-2008 Journal of cleaner production Vol 39 International Journal of LCA May 2009 Completeness meets study scope. This is a consequential LCA, so only marginal impacts are accounted for compared to the base case. Waste treatment is not sufficiently documented. 1 Life Cycle Assessment of fuel ethanol from sugar cane in Brazil Data is for technology under study. Data for Queensland. Region represents 98% of sugarcane production for Australia, and there is little regional difference in processing. Study first submitted in 2010. Data ranges from 2002-2010, but milling, bagasse combustion, and ethanol fermentation from sucrose are all data from 2010. 1 2.5 1.5 2.0 Data represents technology under study. Data for Sao Paulo, Brazil (primary). Background data from SimaPro (generic) Continuous data from 20012008. Background data from SimaPro 2003. Study published 2009. Good level of completeness, but land use and infrastructure not accounted for. Basic 1 2 2 2 1.9 105 The displaced products assumed for the system expansion approach may not be appropriate for all uses of this data. Basic GaBi sugarcane, in sugar refinery Table 21 (cont’d) Represents technology under study. Some data adapted from europe. Unknown data used to modify file. Data from "sugarcane, at farm/BR" gets a time rating of 3 (see sugarcane DQR table). Unknown data used to modify file. Good degree of completeness, but land occupation and transformation not accounted for. Estimate 1 3 4 1.5 3.2 106 Data Country Argentina Data Years 2004-2007 Data Availability International Journal of LCA March 2009 Life cycle assessment of soybean based biodiesel production in Argentina Name Table 22 - Soy Processing DQR Technological Rep Represents the processing system under study. Solvent extraction technology is modeled. 1 Geographical Rep Data from USA and Europe adapted to Argentina. Yields, allocation factors, natural gas, electricity consumption, electricity mix and transport distances are specific to Argentina. 2.5 107 Uncertainty Data Quality Rating Time Rep Completeness Data used from 2004 and 2007. Study published 2009. Crop storage and drying are excluded due to lack of data. Facility land use and transformation are not accounted for. Basic 2 2.5 2.3 Table 22 (cont’d) Europe Brazil 1994, 1998, 1995 1998-2005 Literature sources Ecoinvent Ecoinvent Soya oil, at plant/kg/RER S – Soya oil, at plant/kg/RER U 2 Soybean oil, at oil mill/BR S Soybean oil, at oil mill/BR U Generally represents European processing facilities, but some data from European manufacturing companies whose representativeness of the whole market is unknown. Data from Europe and Switzerland used to model Europe. Main data sources are from 1994, 1998, and 1995. Data entered in 2004. Land use is claimed to be represented in the documentation, but no flows are present for this input. Process water is also not included. Moderate to high uncertainty is present for all flows. Basic 2 2 2 4 3.1 Data for soy oil extraction process. Data adapted to Brazil from US study (similar production conditions). Data sources from 19982005 (literature) Data entered in 2006. Facility land use not accounted for, otherwise complete. Low to moderate uncertainty for most flows. Transport distances are estimates. Basic 1 3 3 1.5 2 2.5 108 Soy oil, refined, at plant/kg/RNA Table 22 (cont’d) North America North America Unknown 2010, unknown USLCI USLCI Data for North America 1 Soybean oil, crude, degummed, at plant Data for soy oil refining Energy data from "late 2000s", all other data theoretical. 1 3 Data for soy oil extraction process. Data for North America Data from Omni Tech 2010, data from NOPA date unknown. NOPA data is for water and processing chemicals 1 1 3 109 only oil refining inputs, matches study scope. Infrastructure and facility land use not accounted for. 1.5 Soy oil extraction only, meet study scope, but Infrastructure not accounted for, facility land use not accounted for, and waste treatment is dummy process. 2 Basic 2.3 Basic 2.4 1998-2005 Literature sources Soybean oil, at oil mill/US S Soybean oil, at oil mill/US U Table 22 (cont’d) USA North America 2010, 1998, 2001 Ecoinvent USLCI Data for the USA. 1 Soy biodiesel, production , at plant Data represents process under study. Solvent extraction modeled. Data sources from 19982005 (literature) Data endted in 2006. 1 3 Data represents process under study. Data for North America Data from 2010, 1998, and 2001. File created 2011. 1 1 3 110 Facility land use not accounted for, otherwise complete. 1.5 Process chemicals are dummy processes, infrastructure and facility land use not accounted for, waste treatment not included. 2.5 Low to moderate uncertainty for most flows. Transport distances are estimates. Basic 2 2.3 Basic 2.4 Appendix F: Data Summary Table Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and 1kg barley grains grain drying. Machine extensive, at farm infrastructure and a shed for respective barley straw machine sheltering is included. 1996extensive, at farm, both w/ Inputs of fertilizers, pesticides, 2003 15% moisture content. and seed as well as their 89.9% economic allocation transports to the regional to grains. processing center (10km) are considered. Direct emissions on the field also included. 111 Data Country Includes Swiss Lowlands 10% Details Data Years Allocation* Data Availability Ecoinvent Barley straw extensive, at farm/CH S – Barley straw extensive, at farm/CH U Name Table 23 – Raw Agricultural Data Summary 9% Swiss Lowlands 10% 1kg barley grains IP, at farm respective barley straw IP, at farm, both w/ 15% moisture content. 89.9% economic allocation to grains. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. 1996Inputs of fertilizers, pesticides, 2003 and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field also included. 1kg barley grains organic, at farm respective barley straw organic, at farm, both w/ 15% moisture content. 91.3% economic allocation to grains. Soil cultivation, sowing, weed control, fertilization, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. 1996Inputs of fertilizers, pesticides, 2003 and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field also included. Swiss Lowlands Ecoinvent Ecoinvent Barley straw organic, at farm/CH S Barley straw organic, at farm/CH U Barley straw IP, at farm/CH S – Barley straw IP, a t farm/CH U Table 23 (cont’d) 112 Corn, Whole Plant, at Field 0% 1 planted acre for 1 year. Harvested acres are 84% of the planted acres. The impacts of producing 1 kg of seed are considered = to producing 1 kg lint. Only consumptive use of water taken into account. Seed production, tillage, fertillizer and pesticide application, crop residue management, Irrigation, Harvesting 113 USA 0% Seed production, tillage, fertilizer and pesticide application, crop residue management, Irrigation, Harvesting 19982000 USA USLCI USLCI Cotton straw, at field/kg/US Corn stover, at field/kg/US Table 23 (cont’d) 100 % Production of Jute delivers the coproducts jute fibers, irrigated system, at farm and jute stalks, from fiber production, irrigated system at farm. Allocation based on economical and mass criteria. Manual cultivation of Jute from conventional production standards. Cultivation, pesticides, mineral fertilizer, harvest, loading for transport and extraction of fibers after retting process. India 100 % Production of jute delivers the coproducts jute fibers, refined system, at farm and jute stalks, from fiber production, refined system at farm. Allocation based on economical and mass criteria. Manual cultivation of Jute from conventional production standards. Cultivation, pesticides, mineral fertilizer, harvest, loading for transport and extraction of fibers after retting process. India Ecoinvent Ecoinvent Jute stalks, from fibre production, refined system, at farm/IN S Jute stalks, from fibre production, refined system, at farm/IN U Jute stalks, from fibre production, integrated system, at farm/IN S - Jute stalks, from fibre production, integrated system, at farm/IN U Table 23 (cont’d) 114 Manual cultivation of Kenaf from conventional production standards. Cultivation, pesticides, mineral fertilizer, harvest, loading for transport and extraction of fibers after retting process. 0% Potato, whole plant, at field. 1 planted acre for 1 year seed production, tillage, fertilizer, pesticide, crop residue management, irrigation, harvesting 19982000 USA 1 planted acre for 1 year, harvested acres are 97% of planted acres. Only comsumptive use of water taken into account. seed production, tillage, fertilizer, pesticide, crop residue management, irrigation, harvesting. All impacts are allocated to the rape seed, and none to the residues. 19982000 0% 115 India 100 % Production of kenaf delivers the co-products "kenaf fibres" and "kenaf stalks." Allocation was based on economical and mass criteria. US and European averages Ecoinvent USLCI USLCI Rapeseed residues, at field/kg/US Potato leaves, at field/kg/US Kenaf stalks, from fibre production, at farm/IN S Kenaf stalks, from fibre production, at farm/IN U Table 23 (cont’d) Seed production, tillage, fertilizer and pesticide application, crop residue management, irrigation and harvesting. Only consumptive use of water taken into account. 10% Cultivation of Rye delivers the coproducts rye grains and baled rye straw. 1 ha cultivated w/ rye. Allocation based on economic criteria. 9.7% to straw. Emissions of N2O and NH3 to air and the emissions of nitrate to water are calculated w/ standard factors from Nemecek et at. 2004. materials, energy uses, infrastructure and emissions. 116 19982000 USA 0% Farming of rice on 1 plant acre for 1 year. Harvested acres are 99% of planted acres. Impacts of producing 1 kg seed are assumed to be equal to producing 1 kg grain. Only consumptive use of water is taken into account. Europe USLCI Ecoinvent Rye straw conventional, at farm/RER S - Rye straw conventional, at farm/RER U Rice straw, at field/kg/US Table 23 (cont’d) 10% 19962003 Swiss Lowlands 10% Production of 1 kg rye straw extensive, at farm. Economic allocation 90.3% to grains (see report for exceptions). soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field included. Production of 1 kg rye straw IP, at farm. Economic allocation 90.3% to grains (see report for exceptions). Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field included. 19962003 Swiss Lowlands Ecoinvent Ecoinvent Rye straw IP, at farm/CH S – Rye straw IP, at farm/CH U Rye straw extensive, at farm/CH S – Rye straw extensive, at farm/CH U Table 23 (cont’d) 117 100 % Production mix for integrated straw for Switzerland 118 Swiss Lowlands 19982000 USA USLCI 0% 1 planted acre for 1 year, harvested acres are 98% of planted acres. Only consumptive use of water taken into account. Seed production, tillage, fertilizer and pesticide application, crop residue management, irrigation and harvesting. Only consumptive use of water taken into account. 8% Swiss Lowlands 19962003 Ecoinvent Production of 1 kg rye straw organic, at farm. Economic allocation 91.9% to grains (see report for exceptions). soil cultivation, sowing, weed control, fertilization, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field included. Ecoinvent Straw IP, at farm/CH S - Soybean residues, at Straw IP, at farm/CH U field/kg/US Rye straw orgainic, at farm/ CH S - Rye straw orgainic, at farm/CH U Table 23 (cont’d) Ecoinvent LCA Food DK 100 % Denmark Straw organic, at farm/CH S 100 % Straw, from farm Production mix for organic straw for Switzerland 119 Swiss Lowlands Table 23 (cont’d) Cultivation of straw on a straw area. 100 % 1 ha cultivated with sweet sorghum. Emissions of N2O and NH3 to air are calculated with standard mineral fertilizers from Nemecek et al. Emission of nitrate to water calculated with nitrogen loss factor of 32%. Allocation based on economic criteria. 120 included steps are harvest and loading for transport Swiss Lowlands 100 % China Ecoinvent Ecoinvent Sweet sorghum stem, at farm/CN U - Sweet sorghum stem, at farm/CH S Straw, from straw areas, at field/CH S – Straw, from straw areas, at field/CH U Table 23 (cont’d) 8% 19962003 Swiss Lowlands 8% 1kg wheat grains extensive, at farm respectively wheat straw extensive, at farm. Both with a moisture content of 15%. 92.5% allocated to grain. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and housing included. Inputs of fertilizers, pesticides and seed as well as grain transports to the regional processing center (10km) are considered. The direct emissions on the field are also included. 1kg wheat grains IP, at farm respectively wheat straw IP, at farm. Both with a moisture content of 15%. 92.5% allocated to grain Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and housing included. Inputs of fertilizers, pesticides and seed as well as grain transports to the regional processing center (10km) are considered. The direct emissions on the field are also included. 19962003 Swiss Lowlands Ecoinvent Ecoinvent Wheat straw IP, at farm/CH S – Wheat straw IP, at farm CH U Wheat straw extensive, at farm/CH S - Wheat straw extensive, at farm/CH U Table 23 (cont’d) 121 7% 1kg wheat grains IP, at farm respectively wheat straw IP, at farm. Both with a moisture content of 15%. 93.1% allocated to grain. 122 Soil cultivation, sowing , weed control, harvest and grain drying. Machine infrastructure and housing included. Inputs seed as well as grain transports to the regional processing center (10km) are considered. The direct emissions on the field are also included. 19962003 Swiss Lowlands Ecoinvent Wheat straw organic, at farm/CH S - Wheat straw organic, at farm/CH U Table 23 (cont’d) North America USLCI USLCI 12% Wheat production based on US average yields and practices extrapolated from historic data to 2022. Includes all crop production processes from field preparation to crop maturity. Infrastructure, maintenance, and construction of facilities and equipment is included. Harvest and storage is not included. Grain and components are assumed to be at field-dry conditions of 15% moisture. Multiple output process has been reviewed by Dr. Dwayne Westfall, Dept. Soil and Crop Sciences, Colorado State University. Date of review Sept 10 - 30 2008. Data from NASS where available. Projections based on historic data. Extrapolation of historic data to 2022 estimates. Mass based between straw and grain. 1 metric ton of wheat straw, dried to 12% moisture North America Spring wheat straw, production, average, US, 2022 15% spring wheat straw, ground and stored, 2022 Table 23 (cont’d) 123 spring wheat straw, carted, 2022 USLCI winter wheat straw, ground and stored USLCI Crop Production - Wheat Farming North America 12% Crop Production - Wheat Farming North America Table 23 (cont’d) 124 15% Wheat production based on US average yields and practices extrapolated from historic data to 2022. Includes all crop production processes from field preparation to crop maturity. Infrastructure, maintenance, and construction of facilities and equipment is included. Harvest and storage is not included. Grain and components are assumed to be at field-dry conditions of 15% moisture. Multiple output process has been reviewed by Dr. Dwayne Westfall, Dept Soil and Crop Sciences, Colorado State University. Date of review Sept 10 - 30 2008. Data from NASS where available. Projections based on historic data. Extrapolation of historic data to 2022 estimates. Mass based between straw and grain. Biomass Production: 12/08 Incremental Allocation 125 2022 North America USLCI Winter wheat straw, production, average, US, 2022 Table 23 (cont’d) USLCI 1 planted acre for 1 year. Harvested acres are 85% of the planted acres. The impacts of producing 1 kg of seed are considered = to producing 1 kg grain. Only consumptive use of water taken into account. Seed production, tillage, fertilizer and pesticide application, crop residue management, Irrigation, Harvesting 19982000` USA 1 kg barley grains conventional, at farm. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and machine shelter included. Inputs of fertilizers, pesticides, and seed and their transports to the farm are considered. The direct emissions on the field are also included. System boundary at farm gate. 20002004 Barrios, France North America USLCI Crop Production - Wheat Farming Ecoinvent Barley grains conventional, Barrios, at farm/ FR S – Barley grains conventional, Barrios, at farm/ FR U Wheat straw, at field/kg/US Winter wheat straw, carted Table 23 (cont’d) 0% 100 % 126 100 % 1 kg barley grains conventional, at farm. 20002004 Castilla-y-Leon, Spain 100 % Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and machine shelter included. Inputs of fertilizers, pesticides, and seed and their transports to the farm are considered. The direct emissions on the field are also included. System boundary at farm gate. 1 kg barley grains conventional, at farm. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and machine shelter included. Inputs of fertilizers, pesticides, and seed and their transports to the farm are considered. The direct emissions on the field are also included. System boundary at farm gate. 20002004 Saxony-Anhalt, Germany Ecoinvent Ecoinvent Barley grains conventional, Saxony-Anhalt, at farm/ DE S - Barley grains conventional, Saxony-Anhalt, at farm/ DE U Barley grains conventional, Castilla-y-Leon, at farm/ES S Barley grains conventional, Castilla-y-Leon, at farm/ES U Table 23 (cont’d) 127 91% 19962003 Swiss Lowlands 90% 1 kg barley grains extensive and barley straw extensive. Economic allocation factor of 89.9% to grains. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and machine shelter included. Inputs of fertilizers, pesticides, and seed and their transports to the regional processing center (10 km) are considered. The direct emissions on the field are also included. System boundary at farm gate. 1 kg barley grains organic and barley straw organic. Economic allocation factor of 91.3% to grains. Soil cultivation, sowing, weed control, fertilization, harvest and drying of the grains. Machine infrastructure and machine shelter included. Inputs of fertilizers, seed and their transports to the regional processing center (10 km) are considered. The direct emissions on the field are also included. System boundary at farm gate. 19962003 Swiss Lowlands Ecoinvent Ecoinvent Barley grains organic, at farm/CH S – Barley grains organic, at farm/CH U Barley grains extensive, at farm/CH S Barley grains extensive, at farm/CH Table 23 (cont’d) 128 Seed, harvesting, grain drying, sowing, fertilization, tilling, weed control, transport, pesticide control. 90% 1 kg barley grains extensive and barley straw extensive. Economic allocation with 89.9% to grains. Seed, harvesting, grain drying, sowing, fertilization, tilling, weed control, transport, pesticide control. 90% 1 kg barley grains IP and barley straw IP. Economic allocation with 89.9% to grains. Seed, harvesting, grain drying, sowing, fertilization, tilling, weed control, transport, pesticide control. Swiss Swiss Lowlands Lowlands Swiss Lowlands 90% 1 kg barley grains IP and barley straw IP. Economic allocation with 89.9% to grains. 91% 1 kg barley grains organic and barley straw organic. Economic allocation factor of 91.3% to grains. Seed, harvesting, grain drying, sowing, fertilization, tilling, weed control, transport. Swiss Lowlands GaBi-PE GaBi-PE GaBi-PE GaBi-PE barley organic barley IP barley extensive barley grains IP, at farm Table 23 (cont’d) 129 USA (Northern Planes) Ecoinvent 1 kg corn grain fictional unit (water content 14%, carbon content .375 kg/kg fresh mass, biomass energy content 15.9 MJ/kg fresh mass, Yield 9315 kg/ha) includes cultivation of corn in the USA including use of diesel, machines, fertilizers, and pesticides Modeled for USA 100 % Harvested acres represent 91% of the planted acres. The impacts of producing 1kg seed are assumed to be equal to producing 1 kg grain. Only consumptive use of water taken into account. 130 USA International Journal of LCA January 2012 Carbon footprint of oilseed crops grown in semi-arid great plains CO2 equivalents from agricultural activities (fertilizer, pesticides, herbicides, diesel for machines etc.). USLCI corn, whole plant, at field Corn, at farm/US S – Corn, at farm/US U Carbon footprint of canola and mustard as a function of the rate of N Fertilizer Table 23 (cont’d) 100 % Corn on 1 planted acre for 1 year (yield 3421 kg) USA 100 % Includes seed production tillage fertilizer and pesticide application, crop residue management, irrigation and harvesting 1 kg grain maize IP at form with moisture content of 14%. Fresh matter yield/ ha 9279kg. Average production in Swiss lowlands with integrated production. 1996-2003 data collection Includes the processes of soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and shed for machine sheltering is included. Inputs of fertilizers, pesticides and seeds as well as their transports to the regional processing center (10km), and direct emissions on the field. Swiss lowlands USLCI Ecoinvent Grain maize IP, at farm/CH S – Grain maize IP, at farm/CH U Corn, at field/kg/US Table 23 (cont’d) 131 100 % 1 kg silage maize IP, at farm. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. Direct emissions on the field are also included. 132 Swiss Lowlands 100 % 1 kg grain maize IP at form with moisture content of 14%. Fresh matter yield/ ha 9279kg. Average production in Swiss lowlands with integrated production. 1996-2003 data collection Includes the processes of soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and shed for machine sheltering is included. Inputs of fertilizers, pesticides and seeds as well as their transports to the regional processing center (10km), and direct emissions on the field. 19962003 Swiss Lowlands Ecoinvent Ecoinvent Silage maize IP, at farm/CH S – Silage maize IP, at farm/CH U Grain maize organic, at farm/CH S – Crain maize organic, at farm/CH U Table 23 (cont’d) LCA Commons has very specific datasets for each of the states listed for multiple years. Not all states have data for all years. 19952001, 2005 USA: Various States 100 % Fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use. 1 kg silage maize organic, at farm. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm (1km) are considered. Direct emissions on the field are also included. 19962003 Swiss Lowlands LCA Commons Ecoinvent Silage maize organic, at farm/CH S - Silage maize organic, at farm/CH U Corn grain, at harvest in (year), at farm 85-91% moisture (state) Table 23 (cont’d) 133 LCA Food DK GHG and carbon footprint only. Land use changes included in this calculation. 100 % 134 Swiss Lowlands Ecoinvent Journal of Cleaner Production 2009 Oat, organic, from farm Data for Jatropha, soy, palm oil, rape seed oil, and used cooking oil for production of biodiesel. Reports carbon footprint and GHG savings (except for Jatropha). Includes GHG from direct and indirect land use change. 100 % Transport processes required to collect biowaste from households and deliver to treatment plant. Credit is given for extraction of CO2 from atmosphere. Transport as part of municipal waste collection scheme. Distance 15km for municipal waste and 17km from collection point to treatment center. 40% dry matter, 70% organic matter 2009 UK Biowaste, at collection point/CH S - Biowaste, at collection point/CH U Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Table 23 (cont’d) 2005 USA: Various States 100 % Fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use. 2009 Denmark LCA Commons LCA Food DK Journal of Cleaner Production 2009 LCA Commons has very specific datasets for each of the states listed for 2005. UK Oats, at harvest in 2005, at farm 86-92% moisture (state) Oat, conventional, from farm Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Table 23 (cont’d) Produced on farm type 21 Data for Jatropha, soy, palm oil, rape seed oil, and used cooking oil for production of biodiesel. Reports carbon footprint and GHG savings (except for Jatropha). Includes GHG from direct and indirect land use change. 135 GHG and carbon footprint only. Land use changes included in this calculation. 19982000 Soil cultivation, sowing, weed control, fertilization, pest and pathogen control and harvest. Machine infrastructure and shed for machine sheltering included. Inputs of fertilizers, pesticides and seed as well as their transports to the farm (1km). Direct field emissions included. 19962003 Harvested acres are 97% of planted acres. Impacts of 1kg seed are assumed to equal those of 1 kg potatoes. Only consumptive use of water taken into account. 100 % 1 kg potatoes IP, at farm with moisture content of 78% 136 USA seed production, tillage, fertilizer, pesticide, crop residue management, irrigation, harvesting North America Potato, whole plant, at field. 1 planted acre for 1 year Swiss lowlands USLCI 100 % USLCI Ecoinvent Potatoes IP, at farm/CH S – Potatoes IP, at farm/CH U potato, whole plant, at field Potato, at field/kg/US Table 23 (cont’d) 100 % 1 kg of potatoes organic, at farm with moisture content of 78% 19962003 Swiss lowlands 100 % Soil cultivation, sowing, weed control, fertilization, pest and pathogen control and harvest. Machine infrastructure and shed for machine sheltering included. Inputs of fertilizers, pesticides and seed as well as their transports to the farm (1km). Direct field emissions included. 1 kg potatoes, at farm with moisture content of 78%. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, irrigation and harvest. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. The direct emissions on the field are included and the system boundary is the farm gate. 20012006 USA Ecoinvent Ecoinvent Potatoes, at farm/US S – Potatoes, at farm/US U Potatoes organic, at farm/CH U – Potatoes organic, at farm/CH S Table 23 (cont’d) 137 100 % Machinery, human labor, diesel, biocide, fertilizer, water for irrigation, seed. 2012 Weighted average of the marginal production at 28 farm types Soil cultivation, sowing, fertilizing, plant protection, harvesting, making silage and transport of crops. Pesticides and machine and building construction and maintenance also not included. 138 England / Wales 2010 Iran Crop storage, cooling and drying prior to sale. System boundary is the farm gate. Energy, pesticides, herbicides, and fertilizer, land occupation, and irrigation water included Denmark International Journal of Life Cycle Assessment September 2010 Journal of Cleaner Production Vol 33 LCA Food DK Production of potatoes in Iran, scenarios based on farm size. Energy and GHG reported. Potatoes, from farm Environmental burdens of producing bread wheat, oilseed rape, and potatoes in England and wales using simulation and system modeling Fictional unit is 1 ton marketable fresh weight. What is marketable as food < what can be used for ethanol production. Long term approach to soil nutrients. Energy consumption and CO2 emission analysis of potato production based on different farm size levels in Iran Table 23 (cont’d) 100 % Cultivation of rape in Germany modeled with data from literature Use of diesel, machines, fertilizers, and pesticides 1996, 2001, 2006 Germany 100 % 1 kg rape seed conventional, Barrios, at farm (10% moisture content) soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and a shed for machine sheltering. System boundary is at farm gate. Seed inputs and material transport 20002004 Barrios, France Ecoinvent Ecoinvent Rape seed conventional, Barrios, at farm/FR S – Rape seed conventional, Barrios, at farm/FR U Rape seed conventional, at farm/DE S – Rape seed conventional, at farm /DE U Table 23 (cont’d) 139 100 % 1 kg rape seed conventional, Saxony-Anhalt, at farm (9% moisture content). 20002004 Saxony-Anhalt, Germany 100 % Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and a shed for machine sheltering. System boundary is at farm gate. Seed inputs and material transport 1 kg rape seed extensive, at farm (6% moisture content) Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure, shed for machine sheltering, inputs for seeds, transport of materials to regional processing center (10km). Direct emissions on the field. 19962003 Swiss lowlands Ecoinvent Ecoinvent Rape seed extensive, at farm/CH S - Rape seed extensive, at farm/CH U Rape seed conventional, SaxonyAnhalt, at farm/DE S - Rape seed conventional, Saxony-Anhalt, at farm/DE U Table 23 (cont’d) 140 1 kg rape seed, at farm with 6% moisture content. Yield is given as fresh matter, 12% moisture content. Water for irrigation is pumped form 48 m depth w/ electric pumps. Soil cultivation, sowing, weed control, fertilization, pesticides and pathogen control, harvest. Machine infrastructure and sheltering, inputs of fertilizers, pesticides and seed as well as their transports to the farm, direct emissions on the field. 20012006 1 kg rape seed, organic, at farm with 6% moisture. Fresh matter yield at 6% moisture given. soil cultivation, fertilization, harvest, drying and transport to farm 141 Swiss lowlands 19962003 USA 100 % 1 kg rape seed IP, at farm with moisture content of 6%. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and drying of the grains. Machine infrastructure and sheltering, inputs of fertilizers, pesticides and seed as well as their transports to the regional processing center (10km), direct emissions on the field. Swiss lowlands Ecoinvent 100 % Ecoinvent Ecoinvent Rape seed, at farm/US S – Rape seed, at farm/US U 100 % Rape seed, organic, at field/CH S - Rape seed, organic, at field/CH U Rape seed IP, at farm/CH S Rape seed IP, at farm/CH U Table 23 (cont’d) 1 planted acre for 1 year, harvested acres are 97% of planted acres. Only consumptive use of water taken into account. seed production, tillage, fertilizer, pesticide, crop residue management, irrigation, harvesting 19982000 USA and European average practices USLCI International Journal of Life Cycle Assessment 100 % Functional unit is 1 ton marketable fresh weight. What is marketable as food < what can be used for ethanol production. Long term approach to soil nutrients. Crop storage, cooling and drying prior to sale. System boundary is the farm gate. Energy, pesticides, herbicides, and fertilizer, land occupation, and irrigation water included 2010 England / Wales Rapeseed, at field/kg/US Environmental burdens of producing bread wheat, oilseed rape, and potatoes in England and wales using simulation and system modeling Table 23 (cont’d) 142 USLCI LCA Commons 100 % seed production, tillage, fertilizer, pesticide, crop residue management, irrigation, harvesting 19982000 LCA Commons has specific data for each state listed for 2006. Fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use. 2006 143 North America UK 2009 USA Rice grain, at field/kg/US Harvested acres are 99% of planted acres. Impacts of 1kg seed are assumed to equal those of 1 kg grain. Only consumptive use of water taken into account. GHG and carbon footprint only. Land use changes included in this calculation. USA: Various States Journal of Cleaner Production 2009 USLCI 1 planted acre for 1 year, harvested acres are 97% of planted acres. Only consumptive use of water taken into account. rapeseed, whole plant, at field Data for Jatropha, soy, palm oil, rape seed oil, and used cooking oil for production of biodiesel. Reports carbon footprint and GHG savings (except for Jatropha). Includes GHG from direct and indirect land use change. Rice; at harvest in 2006 at farm 63-90% moisture (state) Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Table 23 (cont’d) 1 kg rice at farm. Yield given at 21% moisture 90% 1 ha cultivated with sweet rye. Emissions of N2O and NH3 to air are calculated with standard mineral fertilizers from Nemecek et al. Emission of nitrate to water calculated with the method described in Nemecek et al. Allocation based on economic criteria 90.3% grains, 9.7% straw. 144 20012006 USA 100 % Soil cultivation, sowing, weed control, pest and pathogen control, irrigation and harvest. Machine infrastructure and shelter included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. The direct emissions on the field are also included. System boundary is at the farm gate. Cultivation of rye in Europe including materials, energy uses, infrastructure, and emissions. Time of literat ure public ations (vario us) Europe Ecoinvent Ecoinvent Rye grains conventional, at farm/RER S – Rye grains conventional, at farm/RER U Rice, at farm/US S – Rice, at farm/US U Table 23 (cont’d) 90% 19962003 Swiss Lowlands 90% 1 kg rye grains extensive. Economic allocation with factor of 90.3% to grains. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and shed for machine sheltering included, as well as the inputs for fertilizers, pesticides and seed. Grain transports to the regional processing center (10km) are considered. Direct emissions on the field are also included. 1 kg rye grains IP. Economic allocation with factor of 90.3% to grains. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and shed for machine sheltering included, as well as the inputs for fertilizers, pesticides and seed. Grain transports to the regional processing center (10km) are considered. Direct emissions on the field are also included. 19962003 Swiss Lowlands Ecoinvent Ecoinvent Rye grains IP, at farm/CH S Rye grains IP, at farm/CH U Rye grains extensive, a t farm/CH S Rye grains extensive, at farm/CH U Table 23 (cont’d) 145 100 % 1 ha cultivated with sweet sorghum. Emissions of N2O and NH3 to air are calculated with standard mineral fertilizers from Nemecek et al. Emission of nitrate to water calculated with nitrogen loss factor of 32%. Allocation based on economic criteria. Diesel, machines, fertilizers and pesticides 146 19962003 Swiss Lowlands 92% 1 kg rye grains organic. Economic allocation with factor of 91.9% to grains. Soil cultivation, sowing, weed control, fertilization, harvest and grain drying. Machine infrastructure and shed for machine sheltering included, as well as the inputs for fertilizers, and seed. Grain transports to the regional processing center (10km) are considered. Direct emissions on the field are also included. China Ecoinvent Ecoinvent Sweet sorghum grains, at farm/CN S – Sweet sorghum grains, at farm/CN U Rye grains organic, at farm/CH S - Rye grains organic, at farm/CH U Table 23 (cont’d) China USA USLCI LCA Food DK Diesel, machines, fertilizers and pesticides Argentina Ecoinvent Soybean grains, at field “Carbon Sequestration should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product. For example, a soy-based resin may retain the sequestered carbon indefinitely, while a soybased biodiesel releases the sequestered carbon at use phase” (USLCI). sweet sorghum 1 ha cultivated with sweet sorghum. Emissions of N2O and NH3 to air are calculated with standard mineral fertilizers from Nemecek et al. Emission of nitrate to water calculated with nitrogen loss factor of 32%. Allocation based on economic criteria. Soy bean, from farm Table 23 (cont’d) 100 % 147 100 % 1 kg of soy beans IP, at farm with a moisture content of 11% 19962003 Swiss lowlands 100 % Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and housing. Inputs for fertilizers, pesticides and seed as well as their transports to the regional processing center (10km) are considered, direct emissions on the field also included. 1 kg soy beans organic, at farm with moisture content of 11% Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and housing. Inputs for fertilizers, pesticides and seed as well as their transports to the regional processing center (10km) are considered, direct emissions on the field also included. 19962004 Swiss lowlands Ecoinvent Ecoinvent Soy beans organic, at farm/CH S – Soy beans organic, at farm/CH U Soy beans IP, at farm/CH S – Soy beans IP at farm/CH U Table 23 (cont’d) 148 19982000 Brazil 100 % 1 planted acre for 1 year 100 % 1 kg soybeans with moisture content of 11%. Modeled with data from literature, some data extrapolated from Europe (production of fertilizers and pesticides), and Switzerland (machine use). Transports modeled for standard distances. Use of diesel, machines, fertilizers, and pesticides Time of literat ure public ations (vario us) LCA Commons has specific data for each state listed for various years. Not all states are available for all years. fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use, seeding 19962000, 2002, 2006 149 USA Seed production, tillage, fertilizer and pesticide application, crop residue management, irrigation and harvesting. Only consumptive use of water taken into account. USA: Various States Ecoinvent LCA Commons USLCI Soybeans, at farm/BR S Soybeans, at farm/BR U Soybeans; at harvest in (year); at farm; 85-92% moisture (state) Soybeans, at field/kg/US Table 23 (cont’d) LCA Food DK Weighted averages of the marginal production at 28 farm types 150 UK Sugar beet, from farm 100 % 2009 Use of diesel, machines, fertilizers, and pesticides Time of literat ure public ations (vario us) USA, with some data from Europe and Switzerland Ecoinvent 100 % 1 kg soybeans with moisture content of 11%. Modeled with data from literature, some data extrapolated from Europe (production of fertilizers and pesticides), and Switzerland (machine use). Transports modeled for standard distances. GHG and carbon footprint only. Land use changes included in this calculation. Denmark Journal of Cleaner Production 2009 Data for Jatropha, soy, palm oil, rape seed oil, and used cooking oil for production of biodiesel. Reports carbon footprint and GHG savings (except for Jatropha). Includes GHG from direct and indirect land use change. Soybeans, at farm /US S – Soybeans, at farm /US U Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Table 23 (cont’d) 100 % 1 kg sugar beets IP, at farm with a moisture content of 77% Cultivation of sugar cane with 20% mechanical harvest and 80% manual harvest 151 19962003 Swiss lowlands 100 % Soil cultivation, sowing, weed control, fertilization, pest and pathogen control and harvest. Machine infrastructure and housing included. Inputs of fertilizers, pesticides and seed as well as their transports to the farm (1km) are considered. Direct emissions on the field also included. diesel, machines, fertilizers, and pesticides Time of literat ure public ations (vario us) Brazil Ecoinvent Ecoinvent Sugarcane, at farm/BR S – Sugarcane, at farm/BR U Sugar beets IP, at farm/CH S – Sugar beets IP, at farm/CH U Table 23 (cont’d) International Journal of Life Cycle Assessment Nov 2010 International Journal of LCA November 2009 GHG data for the cultivation of Taiwanese sugarcane 152 Soil preparation, growing, harvesting, transport 2009 Taiwan Australia Life cycle assessment of Australian sugar cane production with a focus on sugarcane growing A decision support tool for modifications in crop cultivation method based on LCA: a case study on GHG emissions reduction in Taiwanese sugarcane cultivation Table 23 (cont’d) Production and energetic utilization of wood from short rotation coppice - a life cycle assessment International Journal of Life Cycle Assessment July 2010 Environmental assessment of black locust based ethanol as potential International Journal of Life Cycle Assessment June 2011 Table 23 (cont’d) This study is broken into parts: 1 production of wood (poplar chips). This is the only part applicable to this study as step 2 is the combustion of the biofuel in a medium sized car. This study assumes carbon neutrality. 153 Soil preparation, harvest, drying, and transport. FU = 1 oven dried ton. Description mass of Switchgrass at 34% moisture with 20% harvest loss. 154 This process Includes all crop production processes from field preparation to harvest and baling. Assuming a 10year stand. Transport and storage of bales is not included. 2022 USA USLCI USLCI US switchgrass production (1hectare) for 2022. Based on projections from Sokhansanj et al. 2009 and MacLaughlin and Kszos 2005. The mean switchgrass yield in the US in 2008 was estimated to be 11.3 Mg per ha, this includes both upland and lowland varieties. The projected 2022 yield was determined by the following (2022 yield = (2008 yield)*(1+.02)^14, where the 2008 yield = 11.2 Mg per hectare, 0.02 is the 2% annual yield improvement, and 14 is the number of years. The annual rate of yield increase is estimated to be 2%. USA Switchgrass, production, US, 2022 Switchgrass, harvested, wet Table 23 (cont’d) 1 kg wheat grains conventional, Barrios w/ moisture content 14.5% 20002004 Seeding, fertilizer, herbicide (different amounts and types for year 1 than for years 2-20). Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. Direct emissions on the field included, system boundary at farm gate. 2022 North America 100 % Seed, planting Barrios, France USLCI International Journal of Life Cycle Assessment Ecoinvent Planting, switchgrass, 2022 Functional unit of study is power to the wheels of a car, but separate LCA data of Switchgrass production is included. This is a 20 year crop cycle where year 1 is separated out because it has significantly different inputs. Wheat grains conventional, barrios, at farm/FR S – Wheat grains conventional, barrios, at farm/FR U Includes only seed and planting Life cycle assessment of switchgrass derived ethanol as transport fuel Table 23 (cont’d) 155 100 % 1 kg wheat grains conventional, Castilla-y-Leon w/ moisture content 15% 20002004 Castilla-y-Leon, Spain 100 % soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering are included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. Direct emissions on the field included, system boundary at farm gate. 1 kg wheat grains conventional, Saxony-Anhalt w/ moisture content 14.5% Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the farm are considered. Direct emissions on the field included, system boundary at farm gate. 20002004 Saxony-Anhalt, Germany Ecoinvent Ecoinvent Wheat grains conventional, Saxony-Anhalt, at farm/ DE S -Wheat grains conventional, Saxony-Anhalt, at farm/DE U Wheat grains conventional, Castilla-y-Leon, at farm/ES S – Wheat grains conventional, Castilla-y-Leon, at farm/ES U Table 23 (cont’d) 156 93% 1 kg wheat grains extensive, at farm respectively wheat straw extensive, at farm both with moisture content of 15%. 92.5% allocated to grain, remainder to straw. 157 19962003 Swiss lowlands 93% 1 kg wheat grains extensive, at farm respectively wheat straw extensive, at farm both with moisture content of 15%. 92.5% allocated to grain, remainder to straw. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field included, system boundary at farm gate. Swiss Lowlands Ecoinvent GaBi-PE wheat extensive Wheat grains extensive, at farm/CH S Wheat grain extensive, at farm/CH U Table 23 (cont’d) 93% 1 kg wheat grains IP, at farm respectively wheat straw IP, at farm both with moisture content of 15%. 92.5% allocated to grains, remainder to straw. 158 19962003 Swiss lowlands 93% 1 kg wheat grains IP, at farm respectively wheat straw IP, at farm both with moisture content of 15%. 92.5% allocated to grains, remainder to straw. Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, harvest and grain drying. Machine infrastructure and a shed for machine sheltering are included. Inputs of fertilizers, pesticides, and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field included, system boundary at farm gate. Swiss Lowlands Ecoinvent Ecoinvent wheat IP Wheat grains IP, at farm/CH S – Wheat grains IP, at farm/CH U Table 23 (cont’d) 93% 1 kg wheat grains organic, at farm respectively wheat straw organic, at farm both with moisture content of 15%. 93.1% allocated to grains, remainder to straw. 159 19962003 Swiss lowlands 93% 1 kg wheat grains organic, at farm respectively wheat straw organic, at farm both with moisture content of 15%. 93.1% allocated to grains, remainder to straw. Soil cultivation, sowing, weed control, fertilization, harvest and grain drying. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides, and seed as well as their transports to the regional processing center (10km) are considered. Direct emissions on the field included. Swiss Lowlands Ecoinvent GaBi-PE wheat organic Wheat grains organic, at farm/CH S – Wheat grains organic, at farm/CH U Table 23 (cont’d) 1 kg wheat grains, at farm w/ moisture content 15% 100 % 1 planted acre for 1 year. Harvested acres are 85% of the planted acres. The impacts of producing 1 kg of seed are considered = to producing 1 kg grain. Only consumptive use of water taken into account. Seed production, tillage, fertilizer and pesticide application, crop residue management, irrigation, harvesting 160 20012006 USA 100 % Soil cultivation, sowing, weed control, fertilization, pest and pathogen control, irrigation and harvest. Machine infrastructure and a shed for machine sheltering is included. Inputs of fertilizers, pesticides and seed as well as their transports to the farm are considered. The direct emissions on the field are included, system boundary at farm gate. 19982000 USA Ecoinvent USLCI Wheat grains, at field/kg/US Wheat grains, at farm/ US S - Wheat grains, at farm/US U Table 23 (cont’d) LCA Commons USA LCA Food DK 100 % Denmark USLCI Wheat conventional, from farm 1 planted acre for 1 year. Harvested acres are 85% of the planted acres. The impacts of producing 1 kg of seed are considered = to producing 1 kg grain. Only consumptive use of water taken into account. LCA Commons has specific data for each state listed for various years. Not all states are available for all years. 161 fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use, seeding 19961998, 2000, 2004, 2009 USA: Various States wheat, at field 100 % Winter wheat; at harvest in (year); at farm; 86-90% moisture (state) Table 23 (cont’d) USA: Various States LCA Commons LCA Food DK 19961998, 2000, 2004, 2009 fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use, seeding 19961998, 2000, 2004, 2009 California, North Dakota, Montana LCA Commons Durum wheat; at harvest in (year); at farm; 88-89% moisture (state) LCA Commons has specific data for each state listed for various years. Not all states are available for all years. fertilizer, water, land use and conversion, transportation, tilling, harvest, pesticide and herbicide use, seeding Denmark Spring wheat; exclu. Durum; at harvest in (year); at farm; 86-90% moisture (state) LCA Commons has specific data for each state listed for various years. Not all states are available for all years. Wheat, organic, from farm Table 23 (cont’d) 100 % 162 The impact of local crops consumption on the water resources in Beijing Journal of Cleaner Production Vol 21 Reports water consumption only for the following crops: Wheat, maize, sweet potato, soybean, groundnut, watermelon, open vegetables, covered vegetables. Water is divided into the sub categories of blue, green and gray. 163 Crop storage, cooling and drying prior to sale. System boundary is the farm gate. Energy, pesticides, herbicides, and fertilizer, land occupation, and irrigation water included 2010 England / Wales International Journal of Life Cycle Assessment September 2010 Functional unit is 1 ton marketable fresh weight. What is marketable as food < what can be used for ethanol production. Long term approach to soil nutrients. Rainfall, irrigation, nitrogen application, planted area. 2011 China Environmental burdens of producing bread wheat, oilseed rape, and potatoes in England and Wales using simulation and system modeling Table 23 (cont’d) GHG, eutrophication, and land occupation reported. Different fertilizer and yield scenarios are reported. Direct N and P emissions *Allocation is based on economic values unless otherwise noted. 164 Denmark International Journal of Life Cycle Assessment June 2008 System delimitation in agricultural consequential LCA: outline of methodology and illustrative case study of wheat in Denmark Table 23 (cont’d) Weed Control Pesticide Crop Residue F G H I J K 1 1 1 1 1 1 1 1 1 1 1 1 1 1 165 N O 1 1 1 1 1 1 Land Transformation M Land Occupation L Crop Storage Direct Field Emissions Fertilizer E Grain Drying Tillage D Harvesting Sowing C Irrigation Machine Shelter 1 Farm Machine Transport 1 Diesel used on field Seed Production B Barley straw extensive, at farm/CH S - Barley straw extensive, at farm /CH U Name A Barley straw IP, at farm/CH S – Barley straw IP, at farm/CH U Table 24 – Raw Agricultural Data Summary Inputs P Q R 1 1 1 1 1 1 D E F G H I Barley straw organic, at farm/CH S – Barley straw organic, at farm/CH U 1 1 1 1 1 1 1 Corn stover, at field/kg/US 1 1 1 1 1 1 1 1 Cotton straw, at field/kg/US Table 24 (cont’d) A 1 1 1 1 1 1 1 1 B 1 C 166 J L M N O 1 K 1 1 P Q R 1 1 Kenaf stalks, Jute stalks, from fibre from fibre production, production, refined system, at farm/IN S - Kenaf at farm/IN S – stalks, Jute stalks, from fibre from fibre production, production, refined system, at farm/IN U at farm/IN U Jute stalks, from fibre production, integrated system, at farm/IN S - Jute stalks, from fibre production, integrated system, at farm/IN U Table 24 (cont’d) A B C D E F G H 1 1 1 1 1 1 1 167 I J Q R 1 1 1 1 1 1 1 1 1 1 1 K L M N O P Rye straw conventional, at farm/RER S – Rye straw conventional, at farm/RER U H Potato leaves, at field/ kg/US 1 1 1 Rice straw, at field/kg/US A G Rapeseed residues, at field/kg/US Table 24 (cont’d) 1 B C D E F J K L M 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 168 I N O P Q 1 R 1 D E F G H I J Rye straw extensive, at farm/CH S – Rye straw extensive, at farm/CH U 1 1 1 1 1 1 1 1 Rye straw IP, at farm/CH S - Rye straw IP, at farm/CH U 1 1 1 1 1 1 1 1 Rye straw organic, at farm/CH S – Rye straw organic, at farm/CH U 1 1 1 1 1 1 1 1 Soybean residues, at field/ kg/US Table 24 (cont’d) A 1 1 1 B C 169 M N O 1 1 1 1 1 1 1 K 1 L 1 1 Q R 1 1 1 1 1 1 1 1 1 1 1 P 1 Straw, From farm R 1 1 Straw organic, at farm /CH S Straw, from Straw areas, at field/CH S - Straw, from straw areas, at field/CH U A Q Straw IP, at farm/ CH S – Straw IP, at farm /CH U Sweet sorghum stem, at farm/CN U - Sweet sorghum Stem at at farm/CH S Table 24 (cont’d) 1 1 1 1 1 1 B C D E F G H 170 I J K L M 1 N O P spring Spring wheat wheat straw, straw, ground and production, stored, average, US, 2022 2022 Wheat straw organic, at farm/CH S – Wheat straw organic, at farm/CH U Wheat Wheat straw straw IP, extensive, farm/CH S – at farm/CH S – Wheat Wheat straw straw IP, extensive, at farm CH U at farm/CH U Table 24 (cont’d) A B 1 1 1 D E F G H I J 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C 1 171 M N O 1 1 1 1 1 1 K L Q R 1 1 1 1 1 1 1 1 1 1 1 P 1 1 Wheat straw, at field /kg/US spring wheat straw, carted, 2022 1 winter wheat straw, ground and stored 1 Winter wheat straw, production, average, US, 2022 1 Winter wheat straw, carted Table 24 (cont’d) A 1 B C D E F G 1 H 1 172 I J 1 K 1 L 1 M 1 N O P Q 1 1 R D E F G H I J Barley grains conventional, Barrios, at farm/ FR S – Barley grains conventional, Barrios, at farm/ FR U 1 1 1 1 1 1 1 1 Barley grains conventional, Castilla-y-Leon, at farm/ES S Barley grains conventional, Castilla-y-Leon, at farm/ES U Barley grains Barley grains conventional, extensive, at farm Saxony-Anhalt, /CH S at farm/ DE S - Barley grains Barley grains extensive, at farm conventional, /CH Saxony-Anhalt, at farm/ DE U Table 24 (cont’d) A 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 B C M N O 1 1 1 1 1 1 1 1 1 1 1 1 173 K L Q R 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 P Carbon footprint Barley grains of canola and Barley organic, at mustard as a barley Barley Barley grains farm/CH S function of organic IP extensive IP, Barley grains the rate of N at farm organic, at Fertilizer farm/CH U Table 24 (cont’d) A B 1 1 1 D E F G H I 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C 1 M N O 1 1 1 1 1 1 1 1 1 1 1 1 1 1 174 J 1 L Q R 1 1 1 1 1 1 1 1 1 1 1 1 1 1 K 1 1 1 P Corn, at field /kg/US 1 Grain maize IP, at farm/CH S Grain maize IP, at farm/CH U 1 1 1 1 1 1 1 1 1 1 1 1 1 Grain maize organic, at farm/CH S Crain maize organic, at farm/CH U corn, whole plant, at field Corn, at farm/US S Corn, at farm/US U Table 24 (cont’d) A C D 1 B 1 E F G 1 1 1 1 1 1 1 1 1 1 1 1 1 1 H 175 I 1 1 J 1 K 1 1 M N O 1 1 P Q R 1 L 1 1 1 Biowaste, at collection point/CH S Biowaste, at collection point/CH U Silage maize organic, at farm/CH S Silage maize organic, at farm/CH U Corn grain, at harvest in Silage maize IP, (year), at farm at farm/CH S 85-91% Silage maize IP, moisture at farm/CH U (state) Table 24 (cont’d) A B 1 1 1 1 C D E F 1 1 1 1 1 1 1 G 1 H J 1 1 1 1 176 M N O 1 1 1 1 1 1 1 1 1 1 K L 1 1 R 1 1 1 P Q 1 1 1 1 I 1 Oat, Oats, at harvest in Oat, conventional, 2005, at farm 86organic, from farm 92% moisture (state) from farm Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Table 24 (cont’d) A B 1 C D E F G 1 H 1 177 I 1 J 1 K L 1 M 1 1 N O 1 P Q R 1 1 1 1 Potatoes IP, at farm/CH S - Potatoes IP, at farm/CH U 1 1 1 1 1 1 1 1 1 1 1 1 1 Potatoes organic, at farm/CH U Potatoes organic, at farm/CH S potato, whole plant, at field Potato, at field /kg/US Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Table 24 (cont’d) A B C D E F 1 G 1 H 178 I 1 J 1 K 1 L 1 M 1 N O 1 1 P Q R 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Energy consumption and CO2 emission Potatoes, analysis of potato from farm production based on different farm size levels in Iran Environmental burdens of producing bread wheat, oilseed rape, and potatoes in England and wales using simulation and system modeling Potatoes, at farm/US S Potatoes, at farm/US U Table 24 (cont’d) A B 1 1 1 C 1 1 D E F G H I J 1 1 1 1 1 1 1 1 1 1 1 1 179 L M 1 1 1 1 1 1 1 1 1 1 K 1 N 1 O P 1 1 1 Q R 1 1 Rape seed conventional, Barrios, at farm/FR S – Rapeseed conventional, Barrios, at farm/FR U 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Rape seed conventional, Saxony-Anhalt, at farm/DE S Rape seed conventional, Saxony-Anhalt, at farm/DE U 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Rape seed extensive, at farm/CH S – Rape seed extensive, at farm/CH U Rape seed conventional, at farm/DE S - Rape seed conventional, at farm /DE U Table 24 (cont’d) A C D 1 B 1 E F G H 180 I 1 J K L M O 1 P Q R 1 N 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Environmental burdens of producing bread Rapeseed, wheat, oilseed organic, at Rapeseed, rape, and field/CH S – at field potatoes in Rape seed, /kg/US England and organic, at wales using field/CH U simulation and system modeling Rapeseed, at farm/ Rape seed IP, at US S farm/CH S - Rape Rapeseed, seed IP, at farm/CH at farm U /US U Table 24 (cont’d) A B 1 1 1 D E F G H I J 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C 1 1 1 181 1 M N O 1 1 1 1 1 1 1 K 1 L 1 1 1 1 1 1 1 Q R 1 1 1 1 1 1 1 1 P 1 1 Rice, at farm/ US S – Rice, at farm/ US U Rice; at harvest in 2006 at farm 63-90% moisture (state) Rice grain, at field/kg/US Substitutable biodiesel feedstocks rapeseed, for the UK: a review whole plant, of sustainability at field issues with reference to the UK RTFO Table 24 (cont’d) A 1 B 1 1 C 1 D 1 1 1 1 F 1 1 1 1 E G H 182 I J 1 1 1 1 1 1 1 1 K 1 L 1 1 M 1 N O 1 P Q R 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Rye grains extensive, at farm/CH S Rye grains extensive, at farm/CH U 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Rye grains IP, at farm/CH S – Rye grains IP, at farm/CH U 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Rye grains organic, at farm/CH S – Rye grains organic, at farm/CH U Rye grains conventional, at farm/RER S - Rye grains conventional, at farm/RER U Table 24 (cont’d) A B C D F G H 183 I J K L M N O 1 P Q R 1 E 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Soy beans IP, at farm/CH S - Soy beans IP at farm/CH U Sweet sorghum grains, at farm /CN S - Sweet sorghum grains, at farm/CN U 1 1 1 1 1 sweet sorghum D 1 Soybean grains, at field C 1 Soy bean, from farm Table 24 (cont’d) A 1 B 1 1 1 E 1 F 1 G 1 H 1 184 I 1 1 Q R 1 1 1 1 J 1 1 1 K L M 1 N 1 O 1 P 1 1 1 Soybeans; at harvest in (year); at farm; 8 5-92% moisture (state) Soybeans, at farm/BR S Soybeans, at farm/BR U Soy beans Soybeans, organic, at at field/ farm/CH S - Soy kg/US beans organic, at farm/CH U Table 24 (cont’d) A B C D E F G H I J 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 185 1 1 K 1 1 M N O 1 L 1 1 1 1 P Q R 1 1 1 1 1 1 1 Sugar beet, from farm 1 Soybeans, at farm/US S Soybeans, at farm/US U Sugar beets IP, at farm /CH S - Sugar beets IP, at farm/CH U Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO Sugarcane, at farm /BR S Sugarcane, at farm /BR U Table 24 (cont’d) A 1 1 1 1 1 1 1 1 1 B C D E 1 F G H 1 1 1 1 1 1 186 I 1 1 J 1 K L 1 1 1 N/ A 1 N O 1 1 1 P Q R 1 1 1 M 1 1 1 1 1 Production and energetic utilization of wood from short rotation coppice – a life cycle assessment A B C D Life cycle assessment of Australian sugar cane production with a focus on sugarcane growing 1 1 1 1 A decision support tool for modifications in crop cultivation method based on LCA: a case study on GHG emissions reduction in Taiwanese sugarcane cultivation Table 24 (cont’d) 1 1 1 E F G H 1 1 1 1 1 1 187 I 1 L M 1 J 1 1 1 N/ A 1 K N O 1 P Q 1 R Life cycle assessment of Planting, Switchgrass, switchgrass switchgrass, harvested, derived 2022 wet ethanol as transport fuel Switchgrass, production, US, 2022 Environmental assessment of black locust based ethanol as potential Table 24 (cont’d) A 1 1 C D E F G 1 B 1 H 1 188 I 1 J 1 1 K L M N O P Q 1 1 1 R D E F G H I J Wheat grains conventional, barrios, at farm/FR S – Wheat grains conventional, barrios, at farm/FR U 1 1 1 1 1 1 1 Wheat grains conventional, Castilla-y-Leon, at farm/ES S -Wheat grains conventional, Castilla-y-Leon, at farm/ES U 1 1 1 1 1 1 Wheat grains conventional, SaxonyAnhalt, at farm/DE S Wheat grains conventional, SaxonyAnhalt, at farm/DE U 1 1 1 1 1 Wheat grains extensive, at farm/CH S – Wheat grain extensive, at farm/CH U Table 24 (cont’d) A 1 1 1 1 1 B 1 C M N O 1 1 1 1 1 1 1 1 1 1 1 1 189 K L Q R 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 P wheat organic Wheat grains organic, at farm/CH S – Wheat grains organic, at farm/CH U wheat IP Wheat grains IP, at farm/CH S Wheat grains IP, at farm/CH U wheat extensive Table 24 (cont’d) A 1 1 1 D 1 1 E 1 1 F 1 1 G 1 1 H 1 1 190 1 1 J 1 1 K L M 1 1 N 1 1 O 1 1 P 1 1 1 1 1 1 1 I R 1 1 C Q 1 B 1 Winter wheat; at harvest in (year); at farm; 86-90% moisture (state) Wheat wheat, conventional, at from farm field A B Wheat grains, at farm/US S Wheat grains, at farm/US U 1 1 Wheat grains, at field /kg/US Table 24 (cont’d) 1 1 1 D E F G H I J 1 1 1 1 1 1 1 1 C 1 1 1 1 191 1 1 1 K 1 L M 1 1 1 1 1 N O 1 P Q R 1 1 1 1 1 1 Environmental burdens of producing bread wheat, oilseed rape, and potatoes in England and Wales using simulation and system modeling Wheat, organic, From farm A B Spring wheat; exclu. Durum; at harvest in (year); at farm; 86-90% moisture (state) 1 Durum wheat; at harvest in (year); at farm; 88-89% moisture (state) Table 24 (cont’d) 1 F G H I J 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 C 1 D E 192 K L 1 Q R 1 1 1 1 M 1 1 1 N 1 O P 1 1 System delimitation The impact of in agricultural local crops consequential LCA: consumption outline of methodology on the water and illustrative case resources study of wheat in in Beijing Denmark Table 24 (cont’d) A B C D E F G H 193 I J K L M N O P Q 1 1 R Data Country Inventory refers to the production of 1 kg sugar, respectively 1 kg ethanol (95%w/w dry basis, i.e. 1.05kg hydrated ethanol 95% wet basis). 1 kg excess bagasse, I kWh electricity and 1 kg vinasse. transport of sugarcane to the sugar refinery and the processing of the sugarcane to sugar, ethanol, bagasse, excess electricity and vinasse from ethanol production. System boundary is at the sugar refinery. Treatment of waste effluents is not included. Packaging is not included. China Brazil Data Years Allocation* Includes 2004-2005 Ecoinvent bagasse, from sweet sorghum, at distillery 100.0% Bagasse, from Sugarcane, at Sugar refinery/BR/ S Bagasse, from Sugarcane, at Sugar refinery/BR/ U Details Ecoinvent Name Data Availability Table 25 – Processed Agricultural Data Summary 194 195 USA Bailing, transport USA Further processing of corn stover production average 2022 2022 USLCI corn stover, carted Infrastructure impacts are included in this process by calling the Ecoinvent "transport" processes. The production of corn stover feedstock utilized in this transport process assigns inputs to corn stover based on activities and inputs that are required for the growth and harvest and preprocessing of corn stover and none of the activities or inputs that would normally be used to produce, harvest and preprocess corn grain (so-called "incremental allocation").(USLCI). 2022 corn stover, at conversion plant, 2022 "This process transports corn stover to the conversion plant. It does so using transportation modal allocation from the USDA Ethanol Backgrounder (2007), assuming those current allocations are applicable to stover and for year 2022. Distances for each mode are from a combination of references; still missing a good distance estimate for barge, but since the share of barge transportation is ~2%, the final result will not be sensititive to this parameter."(USLCI). USLCI Table 25 (cont’d) 196 USA "Corn stover based on US average corn yeilds and practices extrapolated from historic data to "These processes include 2022. Grain and components are additional harvesting energy for assumed to be at field-dry single pass harvest, additional conditions of 15.5% moisture. The nutrients, and hay substitition for stover process has been seperated loss of potential over-winter cattle from corn to allow for incremental feed."(USLCI). allocation. Only processes directly attributed to stover collection are counted."(USLCI). Direct emissions Sox, machinery, storage, loading, drying (electricity), grinding USA Corn stover, production, average, US, 2022 USLCI corn stover, ground and stored "Taken from Sheehan, Corn Stover Ethanol LCA. (Directly from TEAM). The corn steep liquor production involves the steeping of harvested corn for a period of from 24 to 48 hours in a light sulfurous acid solution. All of the production burdens from corn are assumed to be allocated to the production of the SOx." (USLCI). USLCI Table 25 (cont’d) 1995-2006 Malaysia 1 kg rape meal, economic allocation of 25.7% to meal. CO2 emissions allocation based on carbon balance. Transport of rape seeds to the mill, and the processing of the seeds to rape oil and rape meal. Cold press oil extraction technique. System boundary at oil mill. 1998-2006 Switzerland 197 Switzerland 1.4% 1 kg palm kernel meal, from palm fruit bunches. 1.4% allocated to meal. CO2 emissions allocated based on carbon balance. extraction of palm kernel meal, energy supply from extracted solids, and treatment of specific wastwater effluents are taken into account. System boundary is at the oil mill. (Sterilization, stripping, digestion, oil extraction, screening, settling and refining). 1998-2005 Transport of sugar beets to the sugar refinery, and the processing of sugar beets to sugar, molasses and pulps. System boundary is at the sugar refinery. Treatment of waste effluents is included. Packaging of sugar is not included. 3.8% 1 kg sugar, 1 kg molasses andd 1 kg of pulps. Economic allocation with allocation factor for common stages of 91.7% to sugar, 4.5% to molasses, and 3.8% to pulps. Allocation is done according to carbon balance for CO2 emissions. 25.7% Rape meal, at oil mill/CH S - Rape meal, at oil mill/CH U Ecoinvent Palm kernel meal, at oil mill/MY S Palm kernel meal, at oil mill/MY U Ecoinvent Pulps, from sugar beet, at sugar refinery/CH S Pulps, from sugar beet, at sugar refinery/CH U Ecoinvent Table 25 (cont’d) Brazil Fuctional unit is 1 kg of soybean meal produced in argentina and delivered to the netherlands. Global warming, ozone depletion acidification, eurtrophication and photochemical oxidation reported. Two scenarios reported for allocation: economic and mass. fertilizer, diesel, electric, transport, credit for avoided products Argentina / Netherlands 198 Europe 1 kg soybean meal (incl. hulls). Economic allocation of 59.3% to meal. CO2 allocated based on carbon balance. Transport of soybean to the mill, processing of soybeans into meal and oil by the solvent method (pre-cracking, de-hulling, oil extraction, meal processing and oil purification). 1996-2003 Transport of rape seeds to the mill, and the processing of the seeds to rape oil and rape meal. Cold press oil extraction technique. System boundary at oil mill. 1998-2005 25.7% 59.3% 1 kg rape meal, economic allocation of 25.7% to meal. CO2 emissions allocation based on carbon balance. 2008 LCA of soybean meal Ecoinvent Soybean meal, at oil mill/BR S Soybean meal, at oil mill/BR U Ecoinvent Rape meal, at oil mill/RER S - Rape meal, at oil mill/RER U Ecoinvent Table 25 (cont’d) 199 North America transport of soybean to the mill, processing of soybeans into meal and oil by the solvent method (pre-cracking, dehulling, oil extraction, meal processing and oil purification). USA 1 kg soybean meal (incl. hulls). Economic allocation of 65.5% to meal. CO2 allocated based on carbon balance. 2022 USLCI 65.5% Soybean meal, at oil mill/US S Soybean meal, at oil mill/US U Ecoinvent wheat straw, at conversion plant, 2022 "This process transports wheat straw to the conversion plant. It does so using transportation modal allocation from the USDA Ethanol Backgrounder (2007), assuming the current corn grain allocations described in the report are applicable to wheat straw and to year 2022. Distances for each mode are from a combination of references; still missing a good distance estimate for barge, but since the share of barge transportation is ~2%, the final result will not be sensitive to this parameter." (USLCI). 1998-2005 Table 25 (cont’d) Collection of waste vegetable oil and deliver to the treatment Treated vegetable oil consists of plant, treatment for impurities 93.7% triglycerides and 6.7% fatty and water removal, conditioning acid methyl ester. Process refers and storage of the oil. Treatment to the acid-catalyzed esterification of effluents is taken into account. of free fatty acids and includes Includes gross calorific value of water removal, glycerin washing the biomass and the carbon and methanol recovery. dioxide credit. System boundary is at the oil refining facility. 200 Germany, India, Malaysia Crop production, oil extraction, combustion. 2011 Cradle to grave study. Includes from the production of the vegetable oil to its combustion. Process contribution for each stage is available. Reports: fossil fuels, GWP, acidification, and eutrophication. Data for Rape, palm oil, and Jatropha China Vegetable oil, from cooking oil, at plant/CH S Vegetable oil, from cooking oil, at plant/CH U Ecoinvent Life cycle assessment of hydrotreated vegetable oil from rape, palm oil, and Jatropha Journal of cleaner production vol 19 Iss 2-3 Table 25 (cont’d) France includes transport from slaughterhouse to rendering plant and further processing of slaughterhouse wastes to tallow. Energy demand for operation a rending plant (electricity and natural gas, use of tap water, output of waste water and building infrastructure) is included. Upstream processes not included as tallow material is considered as waste. Switzerland 100.00% Tallow, at plant/CH S - Tallow, at plant/CH U Ecoinvent Vegetable oil, from cooking oil, at plant/FR S Vegetable oil, from cooking oil, at plant/FR U Treated vegetable oil consists of Collection of waste vegetable oil 93.7% triglycerides and 6.7% fatty and deliver to the treatment acid methyl ester. Process refers plant, treatment for impurities to the acid-catalyzed esterification and water removal, conditioning of free fatty acids and includes and storage of the oil. Treatment water removal, glycerin washing of effluents is taken into account. and methanol recovery. Includes gross calorific value of C57H102O6. Data is mostly from the biomass and the carbon one US literature sources and dioxide credit. System boundary is adapted to FR. at the oil refining facility. Ecoinvent Table 25 (cont’d) 1 kg tallow at rending plant. Since the processes of making tallow and meat and bone meal are very similar, this process may also be used to approximate the production of meat and bone meal. 201 Philippines North America Malaysia North America 202 1995-2006 100.0% Palm kernel oil, processed, at plant/RNA USLCI Palm Kernel Oil, at oil mill/MY S - Palm Kernel Oil, at oil mill/MY U Ecoinvent Crude palm kernel oil, at plant/RNA 100.0% 17.3% Palm kernel oil, processed, at plant. Physical refining using steam distillation in high temperature vacuum. Ecoinvent Production of 1 kg palm kernel oil. 17.3% allocated to palm kernel oil. CO2 emissions based on carbon balance Extracting of palm kernel oil from palm fruit bunches, energy supply from extracted solids, treatment of specific wastewater effluents are included. System boundary is at the oil mill. Crude coconut oil, at plant/PH S Crude coconut oil, at plant/PH U USLCI Data based on the ECOSOL study of the European surfactant industry. Allocation based on mass of outputs. Material and energy input, production of waste and emissions for the steps from the harvested coconuts to the crude coconut oil (Halving, extraction of water, meat removal and shell production, drying and oil extraction). Water consumption and infrastructure are estimated. 100.0% Table 25 (cont’d) Table 25 (cont’d) cultivation, oil milling, refining 203 Malaysia Consequential LCA that used system expansion to avoid allocation. Rapeseed data is for Denmark, Palm oil data is from Malaysia and Indonesia Denmark, Malaysia, Indonesia Production of 1 kg palm l oil. 81.3% allocated to palm oil. CO2 emissions based on carbon balance Extracting of palm oil from palm fruit bunches, energy supply from extracted solids, treatment of specific wastewater effluents are included. System boundary is at the oil mill. Malaysia Waste, harvesting, transport, incineration of waste wood. 1995-2006 Comparative LCA of rapeseed oil and palm oil 81.3% Ecoinvent USLCI Palm oil, at oil mill/MY S - Palm oil, at oil mill/MY U International Journal of LCA February 2010 Palm kernels, at plant "Bunch ash, crude palm oil, and shells used in road construction have been treated as coproducts, for which credit has been given on a mass basis. Mass imbalance is due to unavailability of the weight of empty fruit bunches sent to incineration" (USLCI). 1996-2003 Distribution of 1 kg rape oil in Switzerland Transport of rape oil from the oil mill to the end user, including operation of storage tanks and equipment. Emissions from evaporation and treatment of effluents. 204 Switzerland Transport of seeds to mill, processing of seeds to rape oil and rape meal. The oil extraction refers to the solvent extraction method. System boundary at oil mill. Europe 1998-2006 74.3% 1 kg rape oil. Allocation is economic with 74.3% to rape oil. CO2 is allocated based on carbon balance. Switzerland 74.3% 1 kg rape oil. Allocation is economic with 74.3% to rape oil. CO2 is allocated based on carbon balance. Transport of seeds to mill, processing of seeds to rape oil and rape meal. The oil extraction refers to the cold-press extraction method. System boundary at oil mill. 100.0% Rape oil, at regional storage/CH S Rape oil, at regional storage/CH U Ecoinvent Rape oil, at oil mill/RER S - Rape oil, at oil mill/RER U Ecoinvent Rape oil, at oil mill/CH S - Rape oil, at oil mill/CH U Ecoinvent Table 25 (cont’d) 1 kg soybean oil, system boundary at oil mill. Economic allocation of 40.7% to oil. CO2 allocated based on carbon balance. Transport of soybeans to the mill, processing in to soybean oil. Solvent extraction process (Precracking of beans, de-hulling, oil extraction, meal processing and oil purification). Brazil "Energy data: late 2000s, other data: theoretical. CARBON SEQUESTRATION should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product" (USLCI). Waste disposal, process energy, transport, materials USA 205 Europe 28.0% Manufacturing process starting with dry beans. 28% allocation to Soya Oil. The inventory includes the conditioning (but not drying) of the beans before extraction. The production of soya scrap is also included as well as the consumption of auxiliaries, energy, infrastructure and land use, generation of emissions to land and water. Generation and transportation of solid waste is not included. 40.7% Soy oil, refined, at plant Ecoinvent Soybean oil, at oil mill/BR S - Soybean oil, at oil mill/BR U USLCI Soya oil, at plant/RER S - Soya oil, at plant/RER U Ecoinvent Table 25 (cont’d) 206 2011 Cultivation of seedlings, cultivation of palms, land use, milling, refining, Trans esterification, and utilization of diesel in engines of vehicles USA Transport of soybeans to the mill, processing in to soybean oil. Solvent extraction process (Precracking of beans, de-hulling, oil extraction, meal processing and oil purification). Primary data collected from 12 palm nurseries, 102 plantations, 12 mills and 11 refineries. North America Ecoinvent Determination of GHG contributions by subsystems in the oil palm supply chain using the LCA approach Materials, transportation, water, waste disposal, natural gas, electricity Malaysia Soybean oil, at oil mill/US S - Soybean oil, at oil mill/US U 1 kg soybean oil, system boundary at oil mill. Economic allocation of 34.5% to oil. CO2 allocated based on carbon balance. Soybean oil, crude, degummed, at plant 34.5% USLCI "CARBON SEQUESTRATION should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product. For example, a soy-based resin may retain the sequestered carbon indefinitely, while a soy-based biodiesel releases the sequestered carbon at use phase." (USLCI). International Journal of Life Cycle Assessment August 2011 Table 25 (cont’d) 207 New Zealand Credit for removed CO2 Switzerland Process is only a credit entry accounting for the extraction of CO2 from the atmosphere. 4.9% lactose, 0.5% lipids 2011 Farming processes: raising cattle, fuel and electric for farm activities, nitrogen and phosphate fertilizer for cattle feed. Meat Processing: slaughtering, blood collection, removing of offal, cutting of meat, rendering, steam coagulation, drying blood, milling into blood meal. Other processes included in Part 2 of the paper. 100.00% Whey, at dairy/CH S - Whey, at dairy/CH U International Journal of Life Cycle Assessment - Bier et all. An eco-profile of thermoplastic protein derived from blood meal LCA data for making NTP (Novatein Thermoplastic Protein) from blood meal. Only nonrenewable energy and GHG emissions are reported. NTP has applications similar to LLDPE. New Zealand has higher than average wind energy use, other locations would have more nonrenewable energy reported. Ecoinvent Table 25 (cont’d) 2022 USA Functional unit is 1 kg of glucose or fructose for fermentation. The three things that were found to have the greatest effect on environmental performance were: commodities displaced by bio-products, agricultural yields, and nitrogen use efficiency. USA, UK, and Australia USLCI an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation This process transports corn grain to the conversion plant. It does so using transportation modal Infrastructure impacts are allocation from the USDA Ethanol included in this process by calling Backgrounder (2007), assuming the Ecoinvent "transport" this current allocation will apply processes. The production of corn in 2022. Distances for each mode grain feedstock utilized in this are from a combination of transport process allocates inputs references; still missing a good to the stover and grain based on distance estimate for barge, but the amount of ethanol that can since the share of barge be produced from each cotransportation is ~2%, the final product result will not be sensitive to this parameter. 2008 corn grain, at conversion plant, 2022 Biomass and Bioenergy Vol 32 (2008) Table 25 (cont’d) 208 Fertilizer, lime, pesticide, water for irrigation, harvesting, milling, bagasse combustion (for sugarcane only), electricity, transport, machinery, fuel use, clarification. Germany Transport of sugar beets to the sugar refinery, and the processing of sugar beets to sugar, molasses and pulps. System boundary is at the sugar refinery. Treatment of waste effluents is included. Packaging of sugar is not included. Denmark 100.0% 4.5% Molasses, from sugar beet, at sugar refinery/CH S - Molasses, from sugar beet, at sugar refinery/CH U USA Washing of potatoes, chopping, separation of potato fruit water, second washing, refining, starch drying. Process water included, infrastructure use considered. Switzerland 100.0% Germany Ventilated storage, transport, loading, conveyor belt 2022 USLCI Potato starch / potato flour Ecoinvent Potato starch, at plant/DE S - Potato starch, at plant/DE U Ecoinvent Maize starch, at plant/DE S - Maize starch, at plant/DE U Further processing of corn grain for 2022 LCA Food DK corn grain, harvested and stored Ecoinvent Table 25 (cont’d) 1 kg sugar, 1 kg molasses and 1 kg of pulps. Economic allocation with allocation factor for common stages of 91.7% to sugar, 4.5% to molasses, and 3.8% to pulps. Allocation is done according to carbon balance for CO2 emissions. 209 USA, UK, and Australia Thailand Reports estimated GHG emissions from CO2, CH4, and N2O. Tilling, irrigation, herbicide and pesticide application, diesel, fertilizer, biomass burning, transport, energy use and waste water treatment. Brazil Journal of cleaner production vol 19 Sugarcane as a Carbon Source: The Brazilian Case Fertilizer, lime, pesticide, water for irrigation, harvesting, milling, bagasse combustion (for sugarcane only), electricity, transport, machinery, fuel use, clarification. 2008 Biomass and Bioenergy Vol 32 (2008) Carbon footprint of sugar produced from sugarcane in eastern Thailand Functional unit is 1 kg of glucose or fructose for fermentation. The three things that were found to have the greatest effect on environmental performance were: commodities displaced by bio-products, agricultural yields, and nitrogen use efficiency. 2011 an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation Journal of Biomass and Bioenergy Table 25 (cont’d) 210 Life cycle assessment of Australian sugar cane with a focus on cane processing International Journal of Lice Cycle Assessment Sept 2010 The multi-output process "sugarcane, in sugar refinery" delivers the co-products: Sugar, ethanol 95% in H2O, sugarcane molasses, bagasse, electricity, and vinasse. Economic allocation with 80-85% to sugar and 10-11% to ethanol. Allocation according to carbon balance for CO2. Australia sugarcane, in sugar refinery GaBi PE Table 25 (cont’d) 211 switchgrass, carted, 2022 Crop Production - unspecified 212 Fertilizer, lime, pesticide, water for irrigation, harvesting, milling, bagasse combustion (for sugarcane only), electricity, transport, machinery, fuel use, clarification. USA, UK, and Australia Biomass and Bioenergy Vol 32 (2008) Functional unit is 1 kg of glucose or fructose for fermentation. The three things that were found to have the greatest effect on environmental performance were: commodities displaced by bio-products, agricultural yields, and nitrogen use efficiency. 2008 an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation USLCI Table 25 (cont’d) 213 USA USA USLCI Infrastructure impacts are included in this process by calling the Ecoinvent "transport" processes. 2022 Switchgrass, ground and stored, 2022 This process transports switchgrass to the conversion plant using transportation modal allocation from the USDA Ethanol Background (2007), assuming these current corn grain allocations are applicable to switchgrass and to year 2022. Distances are from a combination of references; still missing a good distance estimate for barge, but since the share of barge transportation is ~2%, the final result will not be sensitive to this parameter. 2022 Switchgrass, at conversion plant, 2022 USLCI Table 25 (cont’d) 2011 General Algae harvesting, harvesting of Chitin and processing into Chitosan, Al and Fe extraction and processing, machine manufacturing and operation, treatment of wastewater and solid waste. All energy and materials inputs are included, but cultivation of algae is not. General This was a lab scale study and only energy consumption was reported, includes cleaning of the filters. Study compares filters with different pore sizes. This article includes LCA data for the harvesting and processing of algae. It uses the TRACI model of impacts. *Allocation based on economic value unless noted otherwise 214 General Algae cultivation, harvesting, dewatering, lipid extraction, conversion into bio-diesel, byproduct management. 2012 Preferential technological and lice cycle environmental performance of chitosan flocculation for harvesting of the green algae Neochloris oleoabundans All stages of production are considered separately and multiple methods are included for each process. 2012 Harvesting microalgal biomass using submerged microfiltration membranes Biosource Technology 2012 Combinational Life Cycle Assessment to inform Process Design of Industrial Production of Algal Biodiesel Bioresource Technology Environmental Science volume 111 May and Technology 2011 2012 Table 25 (cont’d) Land Use Material Transport Waste Treatment Infrastructure Machines Process Energy De-Hulling Digestion Stripping Extraction Screening Refining Water Drying Direct Emissions Harvesting A Name Loading Table 26 - Processed Agricultural Data Summary Inputs B C D E F G H I J K L M N O P Q R Bagasse, from Sugarcane, at Sugar refinery/BR/ S Bagasse, from Sugarcane, at Sugar refinery/BR/ U 1 1 bagasse, from sweet sorghum, at distillery corn stover, at conversion plant, 2022 corn stover, carted 1 1 1 1 1 215 Table 26 (cont’d) A corn stover, ground and stored Corn stover, production, average, US, 2022 Pulps, from sugar beet, at sugar refinery/CH S - Pulps, from sugar beet, at sugar refinery/CH U Palm kernel meal, at oil mill/MY S - Palm kernel meal, at oil mill/MY U B C D E F 1 1 1 H 1 1 G 1 I J K L M N 1 1 1 1 1 216 1 1 1 1 1 P Q 1 1 O 1 R Table 26 (cont’d) A B C D E F G H I J K L Rape meal, at oil mill/CH S - Rape meal, at oil mill/CH U 1 1 1 1 1 Soybean meal, at oil mill/BR S - Soybean meal, at oil mill/BR U 1 N 1 Rape meal, at oil mill/RER S - Rape meal, at oil mill/RER U M LCA of soybean meal 1 1 1 1 1 1 wheat straw, at conversion plant, 2022 Soybean meal, at oil mill/US S - Soybean meal, at oil mill/US U 1 1 217 1 O P Q R Table 26 (cont’d) A Life cycle assessment of hydrotreated vegetable oil from rape, palm oil, and Jatropha B C D E F G 1 H I J K L M N O P 1 Vegetable oil, from cooking oil, at plant/CH S - Vegetable oil, from cooking oil, at plant/CH U 1 1 1 1 Vegetable oil, from cooking oil, at plant/FR S - Vegetable oil, from cooking oil, at plant/FR U 1 1 1 1 Tallow, at plant/CH S Tallow, at plant/CH U 1 1 1 1 218 1 Q R Table 26 (cont’d) A Crude coconut oil, at plant/PH S - Crude coconut oil, at plant/PH U B C D F 1 1 E G 1 H I J K L N O P 1 1 M Q R 1 Crude palm kernel oil, at plant/RNA Palm Kernel Oil, at oil mill/MY S - Palm Kernel Oil, at oil mill/MY U 1 1 1 Palm kernel oil, processed, at plant/RNA Palm kernels, at plant Palm oil, at oil mill/MY S - Palm oil, at oil mill/MY U 1 1 1 1 1 1 219 1 Table 26 (cont’d) A B C D E F G H I J K L M N O P Q Comparative LCA of rapeseed oil and palm oil Rape oil, at oil mill/CH S - Rape oil, at oil mill/CH U 1 1 1 Rape oil, at oil mill/RER S - Rape oil, at oil mill/RER U 1 1 1 Rape oil, at regional storage/CH S - Rape oil, at regional storage/CH U 1 Soya oil, at plant/RER S - Soya oil, at plant/RER U 1 Soybean oil, at oil mill/BR S - Soybean oil, at oil mill/BR U 1 1 1 1 1 1 220 1 1 1 1 1 R Table 26 (cont’d) A B C D E Soy oil, refined, at plant 1 1 1 1 Soybean oil, crude, degummed, at plant 1 1 1 1 Soybean oil, at oil mill/US S - Soybean oil, at oil mill/US U 1 1 1 H 1 An eco-profile of thermoplastic protein derived from blood meal G 1 Determination of GHG contributions by subsystems in the oil palm supply chain using the LCA approach F 1 I J K L M N 221 P Q R 1 1 1 1 1 1 O 1 1 1 Table 26 (cont’d) A B C D an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation 1 corn grain, harvested and stored 1 E F G H 1 1 1 1 1 1 I J K L M N O 1 1 P Q R Whey, at dairy/CH S Whey, at dairy/CH U corn grain, at conversion plant, 2022 Maize starch, at plant/DE S - Maize starch, at plant/DE U 222 1 1 Table 26 (cont’d) A B C D E F G H I J K L M N O 1 1 P Q R Potato starch, at plant/DE S - Potato starch, at plant/DE U Potato starch / potato flour Molasses, from sugar beet, at sugar refinery/CH S Molasses, from sugar beet, at sugar refinery/CH U an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation 1 1 1 1 1 1 1 223 1 1 Table 26 (cont’d) A Carbon footprint of sugar produced from sugarcane in eastern Thailand B C D E 1 1 F G 1 H I J K L M N O Sugarcane as a Carbon Source: The Brazilian Case sugarcane, in sugar refinery 1 Life cycle assessment of Australian sugar cane with a focus on cane processing 224 1 Q R 1 1 P 1 Table 26 (cont’d) A B D 1 an environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugar for Fermentation C E 1 F G H 1 I J 1 K L 1 M N O 1 P 1 Q R 1 switchgrass, carted, 2022 Switchgrass, at conversion plant, 2022 Switchgrass, ground and stored, 2022 Combinational Life Cycle Assessment to inform Process Design of Industrial Production of Algal Biodiesel 1 1 1 1 225 1 1 1 Table 26 (cont’d) A B C D E F G H 1 1 I J K L M N O P Q R Harvesting microalgal biomass using submerged microfiltration membranes Preferential technological and lice cycle environmental performance of chitosan flocculation for harvesting of the green algae Neochloris Oleoabundans 1 1 226 1 1 Transportation for the collection as well as the further transportation to the next paper production site. Nothing else included. Switzerland Collected waste paper has a biogenic C content of 40.4 % (Average 2004) Transportation for the collection as well as the further transportation to the next paper production site. Nothing else included. Europe Data Country Collected waste paper has a biogenic C content of 40.4 % (Average 2004) 227 Data Years Allocation* Ecoinvent Waste paper, mixed, from public collection, for further treatment/RER S Waste paper, mixed, from public collection, for further treatment/RER U Includes 100.0% Data Availability Waste paper, mixed, from public collection, for further treatment/CH S Waste paper, mixed, from public collection, for further treatment/CH U Details 100.0% Name Ecoinvent Table 27 – Wood Data Summary Switzerland Europe USA 228 US Inland West 100.0% 100.0% USLCI Bark, softwood, average, state or private moist cold forest, at forest road, INW Collected waste paper Includes sorting of collected paper (energy and materials), treatment of extracted wastes, and transportation to the next paper production site. Nothing else included. 1989-1996 Forest residue, processed and loaded, at landing system Collected waste paper Includes sorting of collected paper (energy and materials), treatment of extracted wastes, and transportation to the next paper production site. Nothing else included. USLCI Waste paper, sorted, for further treatment/RER S Waste paper, sorted, for further treatment/RER U Ecoinvent Waste paper, sorted, for further treatment/CH S Waste paper, sorted, for further treatment/CH U Ecoinvent Table 27 (cont’d) 3.3% Germany / Central Europe 100.0% Bark mulch, at oriented strand board production, US SE/kg/US transports from forest, sawing, and debarking at sawmill Germany / Central Europe Ecoinvent Volume refers to the wood not including the bark. Allocation is based on economic value. US South East 100.0% Bark chips, softwood, u=140%, at plant/RER S Bark chips, softwood, u=140%, at plant/RER U Bark chips, softwood, u=140%, at forest road/RER S - Bark chips, softwood, u=140%, at forest road/RER U Ecoinvent Tractor driven debarking delivers the two coproducts "round wood, softwood, debarked, u=70% at forest road" and "bark chips, softwood, u=140%, at forest road". Allocation based on the overall proceeds of the process. Data for Germany used for central Europe. USLCI Table 27 (cont’d) 229 US South East Debarking of logs, sawing and sorting of green lumber US Pacific North West US South East Log debarking at plant yielding wood and bark, bark used to fire boiler. 230 US Pacific North West 13.0% 5.6% USLCI Log debarking at plant yielding wood and bark, bark used to fire boiler. 6.3% Bark, at rough green lumber sawmill, softwood, US PNW/kg/US Debarking of logs, sawing and sorting of green lumber 7.7% Bark, at plywood plant, US SE/kg/US USLCI Bark, at plywood plant, US PNW/kg/US USLCI Bark, at sawmill, US SE/kg/US USLCI Table 27 (cont’d) Co-products of laminated veneer lumber production, unspecified, US PNW/kg/US 4.4% Allocation based on mass or volume USLCI Co-products of glue laminated beam production, at plant, unspecified, US SE/kg/US 231 Sweden and Finland US Pacific North West US South East US Pacific North West 100.0% Allocation based on mass or volume Final manufacture of 1000cuft of LVL from plywood and dry veneer (and coproducts) 18.3% Final manufacture of 1000cuft of Glulam beams from dry and rough green lumber (and coproducts) Allocation based on mass or volume 17.6% Final manufacture of 1000cuft of Glulam beams from dry and rough green lumber (and coproducts) Co-products of glue laminated beam production, at plant, unspecified, US PNW/kg/US USLCI Allocation based on economic criteria. Debarking and further production of sawn timber, wood chips and sawdust. Transport of wood from forest road to sawmill is included. USLCI Chips, Scandinavian softwood (plantdebarked, u=70%, at plant/NORDEL S Chips, Scandinavian softwood (plantdebarked, u=70%, at plant/NORDEL U Ecoinvent Table 27 (cont’d) Trim and saw process, at plywood plant. Allocation based on mass or volume. Trim and saw process, at plywood plant. Allocation based on mass or volume. 232 US Pacific North West US South East US South East US South East Gate to gate system analysis. Allocation based on mass or volume Final manufacture of 1000cuft of LVL from plywood and dry veneer (and coproducts) US South East 8.7% 0.7% 1.4% USLCI Gate to gate system analysis. Allocation based on mass or volume 11.6% Hogfuel, from trimsaw, plywood plant, US SE/kg/US Allocation based on mass or volume 4.4% Hogfuel, from trim and saw at plywood plant, US PNW/kg/US USLCI Fines, at oriented strand board production, US SE/kg/US USLCI Dust and scrap, at oriented strand board production, US SE/kg/US USLCI Co-products of laminated veneer lumber production, unspecified, US SE/kg/US USLCI Table 27 (cont’d) US South East Rotary peeling of logs to produce green veneer. Allocation performed using mass or volume. US Pacific North West Rotary peeling of logs to produce green veneer. Allocation performed using mass or volume. US South East US Pacific North West 9.0% 5.2% USLCI Final trim and saw to length of plywood. Allocation based on mass or volume. 5.3% Peeler core, from green veneer production at plywood plant, US SE/kg/US Final trim and saw to length of plywood. Allocation based on mass or volume. 7.5% Peeler core, from green veneer production at plywood plant, US PNW/kg/US USLCI Panel trim, from trim and saw at plywood plant, US SE/kg/US USLCI Panel trim, from trim and saw at plywood plant, US PNW/kg/US USLCI Table 27 (cont’d) 233 Allocation based on mass or volume. Planed green lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. Allocation based on mass or volume. Rough green lumber processing, at sawmill. Debarking of logs, sawing and sorting of green lumber. 234 US Pacific North West US South East Allocation based on mass or volume. Planed dried lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. US Pacific North West 13.1% 7.0% 7.0% USLCI Allocation based on mass or volume Planed dried lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. US Pacific North West Pulp chips, at rough green lumber production, US PNW/kg/US 26.8% Planer shavings, from green lumber, at planer mill, US PNW/kg/US USLCI Planer shavings, from dried lumber, at planer mill, US PNW/kg/US USLCI Planer shavings, at planer mill, US SE/kg/US USLCI Table 27 (cont’d) Allocation based on mass or volume. Pulp chips, from green veneer production at plywood plant, US PNW/kg/US Allocation based on mass or volume. 235 US Pacific North West US South East US Pacific North West US Pacific North West 31.5% 6.0% Rotary peeling of logs to produce green veneer. 6.0% Planed green lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. Pulp chips, from green lumber, at planer mill, US PNW/kg/US 23.8% Allocation based on mass or volume. Planed dried lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. USLCI Allocation based on mass or volume. Rough green lumber processing, at sawmill. Debarking of logs, sawing and sorting of green lumber. USLCI Pulp chips, from dried lumber, at planer mill, US PNW/kg/US USLCI Pulp chips, at sawmill, US SE/kg/US USLCI Table 27 (cont’d) Allocation based on mass or volume. Planed dried lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. US South East US South East Allocation based on mass or volume. Final manufacture of 100 linear feet of generic Ijoists from LVL and OSB inputs Allocation based on mass or volume. Rough green lumber processing, at sawmill. Debarking of logs, sawing and sorting of green lumber. Allocation based on mass or volume. Rough green lumber processing, at sawmill. Debarking of logs, sawing and sorting of green lumber. 236 US South East Rotary peeling of logs to produce green veneer. US Pacific NorthWest 56.1% 7.0% 1.9% 8.6% USLCI Allocation based on mass or volume. US South East Sawdust, at sawmill, US SE/kg/US 5.9% Sawdust, at rough green lumber production, us PNW/kg/US USLCI Sawdust, at planer mill,US SE/kg/US USLCI Sawdust from I-Joist processing, at plant, US SE/kg/US USLCI Pulp chips, from green veneer production at plywood plant, US SE/kg/US USLCI Table 27 (cont’d) Planed dried lumber processing, at planer mill. Transfer, de-sticking of KD lumber, planing, sorting and stacking. 1.0% Processing of 1000 board feet of surfaced, green softwood lumber. Allocation based on mass or volume. Planed green lumber processing, at planer mill. Transfer, planing, sorting and stacking. US Pacific North West Allocation based on mass or volume. Final manufacture of 100 linear feet of generic Ijoists from LVL and OSB inputs US Pacific North West 237 US Pacific North West 1.0% Processing of 1000 board feet of surfaced, kiln dried softwood lumber. Allocation based on mass or volume. 10.2% Sawdust, from IJoist processing, at plant, US PNW/kg/US USLCI Sawdust, from green lumber, at planer mill, US PNW/kg/US USLCI Sawdust, from dried lumber, at planer mill, US PNW/kg/US USLCI Table 27 (cont’d) 0.8% US Pacific North West US South East Economic allocation Debarking and further production of sawn timber, wood chips and sawdust. Transport of wood from forest road to sawmill is included. Sweden and Finland 100% economic allocation Final trim and saw to length of plywood USLCI Allocation based on mass or volume. Sawdust, from trim and saw, plywood plant, US SE/kg/US USLCI Final trim and saw to length of plywood Sawdust, from trim and saw at plywood plant, US PNW/kg/US Ecoinvent Allocation based on mass or volume. 0.4% Table 27 (cont’d) Sawdust, Scandinavian softwood (plantdebarked), u=70%, at plant/NORDEL S Sawdust, Scandinavian softwood (plantdebarked), u=70%, at plant/NORDEL U 238 28% hard wood, 72% soft wood bulked volume. Density 239-169 kg/m3 dry mass. Transport of waste urban and demolition wood to the chopping facility (50km), infrastructure, chopping of the wood into chips in sawmill, consumption of water and the disposal of effluents and wastes from sorting. Includes carbon dioxide credit. No specific treatment of the wood is considered. Austria and Switzerland / Central Europe Bulked volume dried matter content 239 kg/m3. Chopping of residual hardwood with a stationary chopper in the sawmill. No transports for the inputs are assumed. Austria / Central Europe 100.0% 100.0% Wood chips, hardwood, from industry, u=40%, at plant/RER S - Wood chips, hardwood, from industry, u=40%, at plant/RER U Ecoinvent Waste wood chips, mixed, from industry, u=40%, at plant/CH S - Waste wood chips, mixed, from industry, u=40%, at plant/CH U Ecoinvent Table 27 (cont’d) 239 100.0% Austria / Central Europe Average mix 72% softwood and 28% hardwood (Swiss average). Chopping residual wood with stationary chopper in the sawmill. No transports are included. Austria and Switzerland / Central Europe Ecoinvent Wood chips, mixed, from industry, u=40%, at plant/RER S - Wood chips, mixed, from industry, u=40%, at plant/RER U Bulked volume dried matter content 239 kg/m3. Chopping of residual hardwood with a mobile chopping in the forest. Also includes the driving of the mobile chopper to and within the forest. 100.0% Wood chips, hardwood, u=80%, at forest/RER S Wood chips, hardwood, u=80%, at forest/RER U Ecoinvent Table 27 (cont’d) 240 100.0% Austria and Switzerland / Central Europe Bulked volume dried matter content 169 kg/m3. Chopping residual softwood with stationary chopper in the sawmill. No transports are included. Austria / Central Europe Ecoinvent Wood chips, softwood, from industry, u=40%, at plant/RER S - Wood chips, softwood, from industry, u=40%, at plant/RER U Average mix 72% softwood and 28% hardwood (Swiss average). Chopping of residual wood with a mobile chopper in the forest. Also includes the driving of the mobile chopper to and within the forest. 100.0% Wood chips, mixed, u=120%, at forest/RER S Wood chips, mixed, u=120%, at forest/RER U Ecoinvent Table 27 (cont’d) 241 *Allocation is mass based unless indicated otherwise. 242 Italy 2012 (published) Chopping of residual softwood with a mobile chopper in the forest. Also includes the driving of the mobile chopper to and within the forest. Austria / Central Europe Bulked volume dried matter content 169 kg/m3. USA (Maine) Weed control, tree felling, skidding, seedling production, site preparation and plantation, harvesting and woodchip processing, transport to facility, soil scarification, bucking, de-limbing. The use of ethanol derived from black locust was found to have the lowest impact in most categories. Global warming potential over 100 years reduced 97%, Acidification potential reduced 42%, Eutrophication potential reduced 41%, Fossil fuels use reduced 76%. 100.0% Wood chips, softwood, u=140%, at forest/RER S Wood chips, softwood, u=140%, at forest/RER U Journal of cleaner Production Vol 19 Iss 8 Comparative life cycle assessment of ethanol production from fast-growing wood crops (black locust, eucalyptus and poplar) Functional unit is 4 cubic meters of hardwood chips. Cradle to gate study. Ecoinvent Attributional life cycle assessment of wood chips for bioethanol production Journal of Biomass and Bioenergy April 2012 Table 27 (cont’d) Waste paper, mixed, from public collection, for further treatment/CH S Waste paper, mixed, from public collection, for further treatment/CH U Transport of Equipment Debarking Sawing Planting Sorting Stacking Handling Drying Rotary Peeling Facility Infrastructure Water Consumption Energy Materials Waste Treatment A Name Transport to Process Facility Table 28 – Wood Data Summary Inputs B C D E F G H I J K L M N O 1 243 Table 28 (cont’d) A M N O Waste paper, sorted, for further treatment/CH S Waste paper, sorted, for further treatment/CH U 1 1 1 Waste paper, sorted, for further treatment/RER S Waste paper, sorted, for further treatment/RER U 1 1 1 Waste paper, mixed, from public collection, for further treatment/RER S Waste paper, mixed, from public collection, for further treatment/RER U B C D E F G H I J K L 1 244 Table 28 (cont’d) A B C D E F G H Forest residue, processed and loaded, at landing system Bark, softwood, average, state or private moist cold forest, at forest road, INW Bark chips, softwood, u=140%, at forest road/RER S - Bark chips, softwood, u=140%, at forest road/RER U Bark chips, softwood, u=140%, at plant/RER S Bark chips, softwood, u=140%, at plant/RER U 1 1 1 1 1 245 I J K L M N O Table 28 (cont’d) A B C D E F Bark, at sawmill, US SE/kg/US 1 1 1 Bark, at plywood plant, US PNW/kg/US 1 Bark, at plywood plant, US SE/kg/US 1 Bark, at rough green lumber sawmill, softwood, US PNW/kg/US 1 1 1 Bark mulch, at oriented strand board production, US SE/kg/US 246 G H I J K L M N O Table 28 (cont’d) A Chips, Scandinavian softwood (plantdebarked, u=70%, at plant/NORDEL S Chips, Scandinavian softwood (plantdebarked, u=70%, at plant/NORDEL U 1 B C D 1 E F 1 Co-products of glue laminated beam production, at plant, unspecified, US PNW/kg/US Co-products of glue laminated beam production, at plant, unspecified, US SE/kg/US Co-products of laminated veneer lumber production, unspecified, US PNW/kg/US 247 G H I J K L M N O Table 28 (cont’d) A B C D E F Co-products of laminated veneer lumber production, unspecified, US SE/kg/US Dust and scrap, at oriented strand board production, US SE/kg/US Fines, at oriented strand board production, US SE/kg/US Hogfuel, from trim and saw at plywood plant, US PNW/kg/US 1 Hogfuel, from trimsaw, plywood plant, US SE/kg/US 1 248 G H I J K L M N O Table 28 (cont’d) A B C D Panel trim, from trim and saw at plywood plant, US PNW/kg/US F G H I J 1 Panel trim, from trim and saw at plywood plant, US SE/kg/US E 1 Peeler core, from green veneer production at plywood plant, US PNW/kg/US 1 Peeler core, from green veneer production at plywood plant, US SE/kg/US 1 Planer shavings, at planer mill, US SE/kg/US 1 1 249 1 1 K L M N O Table 28 (cont’d) A B C D E F G H Planer shavings, from dried lumber, at planer mill, US PNW/kg/US 1 1 1 1 Planer shavings, from green lumber, at planer mill, US PNW/kg/US 1 1 1 1 1 1 Pulp chips, at rough green lumber production, US PNW/kg/US 1 1 1 Pulp chips, at sawmill, US SE/kg/US 1 1 1 Pulp chips, from dried lumber, at planer mill, US PNW/kg/US 1 1 250 I J K L M N O Table 28 (cont’d) A B C D F G H 1 Pulp chips, from green lumber, at planer mill, US PNW/kg/US E 1 1 I J 1 Pulp chips, from green veneer production at plywood plant, US PNW/kg/US 1 Pulp chips, from green veneer production at plywood plant, US SE/kg/US 1 Sawdust from I-Joist processing, at plant, US SE/kg/US Sawdust, at planer mill, US SE/kg/US 1 1 1 251 K L M N O Table 28 (cont’d) A B C D E F Sawdust, at rough green lumber production, us PNW/kg/US 1 1 1 Sawdust, at sawmill, US SE/kg/US 1 1 G H 1 1 Sawdust, from dried lumber, at planer mill, US PNW/kg/US 1 1 1 Sawdust, from green lumber, at planer mill, US PNW/kg/US 1 1 1 Sawdust, from IJoist processing, at plant, US PNW/kg/US 252 I J K L M N O Table 28 (cont’d) A B C D Sawdust, from trim and saw at plywood plant, US PNW/kg/US F 1 Sawdust, from trim and saw, plywood plant, US SE/kg/US E 1 Sawdust, Scandinavian softwood (plantdebarked), u=70%, at plant/NORDEL S Sawdust, Scandinavian softwood (plantdebarked), u=70%, at plant/NORDEL U 1 1 1 253 G H I J K L M N O Table 28 (cont’d) A Waste wood chips, mixed, from industry, u=40%, at plant/CH S - Waste wood chips, mixed, from industry, u=40%, at plant/CH U B 1 D E F 1 1 1 254 G H I J K L 1 1 Wood chips, hardwood, from industry, u=40%, at plant/RER S - Wood chips, hardwood, from industry, u=40%, at plant/RER U Wood chips, hardwood, u=80%, at forest/RER S Wood chips, hardwood, u=80%, at forest/RER U C 1 M N O 1 Table 28 (cont’d) A B Wood chips, mixed, from industry, u=40%, at plant/RER S - Wood chips, mixed, from industry, u=40%, at plant/RER U Wood chips, mixed, u=120%, at forest/RER S Wood chips, mixed, u=120%, at forest/RER U Wood chips, softwood, from industry, u=40%, at plant/RER S - Wood chips, softwood, from industry, u=40%, at plant/RER U C D E F 1 1 1 1 255 G H I J K L M N O Table 28 (cont’d) A Attributional life cycle assessment of wood chips for bioethanol production B D E 1 1 C F 1 1 Comparative life cycle assessment of ethanol production from fast-growing wood crops (black locust, eucalyptus and poplar) Wood chips, softwood, u=140%, at forest/RER S Wood chips, softwood, u=140%, at forest/RER U 1 G 1 256 H I J K L M N 1 O ethanol, denatured, mixed feedstocks, at conversion facility, 2022 Ethanol, denatured, switchgrass, biochemical USLCI Blend of corn, corn stover, forest residues, switchgrass and wheat straw ethanol Materials Materials, waste disposal, electricity, diesel, water 257 North America North America North America Data Country Materials, waste disposal, electricity, diesel, water North America Ethanol, denatured, wheat straw, biochemical North America USLCI Materials, waste disposal, electricity, diesel, water Includes Data Years Ethanol, denatured, corn stover, biochemical Details 2022 USLCI Materials, waste disposal, electricity, diesel, water Allocation* Data Availability Ethanol, denatured, forest residues, thermochemical USLCI Name USLCI Table 29 – Chemical Data Summary 258 USA 1 kg hydrated ethanol 95% (dry basis, i.e. 1.05 kg hydrated ethanol wet Transport of corn grains to the basis). Dry milling distillery, processing to hydrated technology. Economic ethanol. System boundary is at allocation 97.6% to the distillery and dehydration is ethanol. CO2 emissions are not included. allocated based on carbon balance. Unspecified Production of 1 kg hydrated ethanol 95% dry basis (1.05kg wet basis). Also delivers co-product "DDGS, from corn, at distillery". Economic allocation w/ factor of 97.6% to ethanol. Allocation according to carbon balance for CO2 emissions. 1990-2006 97.6% USLCI Corn dried and stored, milling, gluten drying, waste disposal, fermentation, electricity 97.6% Ethanol, 95% in H2O, from corn, at distillery/US S Ethanol, 95% in H2O, from corn, at distillery/US U GaBi PE Corn, in distillery Ecoinvent Ethanol, denatured, corn dry mill North America Table 29 (cont’d) Multi-output process "grass, to fermentation" delivers the co-products Ethanol 95%, fibers from grass, and proteins from grass. Economic allocation. Data from a Swiss pilot plant. Fermentation of grass including materials, energy uses, infrastructure, and emissions. Time of publications Switzerland 1 kg hydrated ethanol 95% ( dry basis, i.e. 1.05 kg hydrated ethanol wet Transport of potatoes to the basis). Dry milling distillery, processing to hydrated technology. Economic ethanol. System boundary at the allocation 95.6% to distillery gate, dehydration not ethanol. CO2 emissions are included. allocated based on carbon balance. 2002-2005 Switzerland 95.6% Ethanol, 95% in H2O, from potatoes, at distillery/CH S Ethanol, 95% in H2O, from potatoes, at distillery/CH U Ecoinvent Ethanol, 95% in H2O, from grass, at fermentation plant/CH S - Ethanol, 95% in H2O, from grass, at fermentation plant/CH U Ecoinvent Table 29 (cont’d) 259 97.7% 1 kg hydrated ethanol 95% (dry basis, i.e. 1.05 kg hydrated ethanol wet Transport of grains to the basis). Dry milling distillery, processing to hydrated technology. Economic ethanol. System boundary at the allocation 97.7% to distillery gate, dehydration not ethanol. CO2 emissions are included. allocated based on carbon balance. 2002-2006 Europe 94.5% 1 kg hydrated ethanol 95% (dry basis, i.e. 1.05 kg hydrated ethanol wet Transport of molasses to the basis). Dry milling distillery, processing to hydrated technology. Economic ethanol. System boundary at the allocation 97.7% to distillery gate, dehydration not ethanol. CO2 emissions are included. allocated based on carbon balance. 1998-2005 Switzerland Ethanol, 95% in H2O, from sugar beet molasses, at distillery/RER S Ethanol, 95% in H2O, from sugar beet molasses, at distillery/RER U Ecoinvent Ethanol, 95% in H2O, from rye, at distillery/RER S Ethanol, 95% in H2O, from rye, at distillery/RER U Ecoinvent Table 29 (cont’d) 260 Allocation based on economic criteria. Fermentation of sugar beets including materials, energy uses, infrastructure, and emissions. Time of publications Modeled for Switzerland with data from Finland Allocation based on economic criteria. Fermentation of sugar cane including materials, energy uses, infrastructure, and emissions. Time of publications Brazil Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR S - Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR U Ecoinvent Ethanol, 95% in H2O, from sugar beets, at fermentation plant/CH S - Ethanol, 95% in H2O, from sugar beets, at fermentation plant/CH U Ecoinvent Table 29 (cont’d) 261 10-11% 1 kg hydrated ethanol 95% ( dry basis, i.e. 1.05 kg hydrated ethanol wet basis). Dry milling technology. Economic allocation 97.7% to ethanol. CO2 emissions are allocated based on carbon balance. Transport of sugarcane to the sugar refinery and the processing to ethanol. System boundary is at the sugar refinery. Treatment of waste effluents is not included (most waste water used on nearby fields). 1994-2006 Brazil 91.0% 1 kg hydrated ethanol 95% (dry basis, i.e. 1.05 kg hydrated ethanol wet basis). Dry milling technology. Economic allocation 97.7% to ethanol. CO2 emissions are allocated based on carbon balance. Transport of sorghum to the distillery and the processing to ethanol. System boundary is at the sugar refinery. Treatment of waste effluents is not included (most waste water used on nearby fields). 1992-2005 China Ethanol, 95% in H20, from sweet sorghum, at sugar refinery/CN S Ethanol, 95% in H20, from sweet sorghum, at sugar refinery/CN U Ecoinvent Ethanol, 95% in H20, from sugarcane molasses, at sugar refinery/BR S Ethanol, 95% in H20, from sugarcane molasses, at sugar refinery/BR U Ecoinvent Table 29 (cont’d) 262 1 kg hydrated ethanol 95% (dry basis, i.e. 1.05 kg hydrated ethanol wet Transport of wood to the basis). Dilute acid predistillery and the processing to hydrolysis and ethanol. System boundary is at simultaneous the sugar refinery. Dehydration saccharification and cois not included. Process heat and fermentation. Economic power supply is generated by allocation 97.7% to unconverted solids. ethanol. CO2 emissions are allocated based on carbon balance. 263 Switzerland Switzerland Fermentation of whey including materials, energy uses, infrastructure, and emissions. 1999-2006 Allocation based on economic criteria. 99.7% Ethanol, 95% in H20, from wood, at sugar refinery/CH S Ethanol, 95% in H20, from wood, at sugar refinery/CH U Ecoinvent Ethanol, 95% in H20, from whey, at sugar refinery/CH S Ethanol, 95% in H20, from whey, at sugar refinery/CH U Ecoinvent Table 29 (cont’d) 264 Sweden Brazil Dewatering of ethanol 95%, including ethanol mix. Switzerland Dewatering of ethanol 95% Modeled with ethanol production from sugar beets, whey and grass. 1999 Dewatering of ethanol 95% 2007 99.7% Ethanol, 99.7% in H2O, from biomass, at distillation/CH S Ethanol, 99.7% in H2O, from biomass, at distillation/CH U Ecoinvent Ethanol, 99.7% in H2O, from biomass, at distillation/BR S Ethanol, 99.7% in H2O, from biomass, at distillation/BR U 1 kg hydrated ethanol 95% (dry basis, i.e. 1.05 kg hydrated ethanol wet Transport of wood to the basis). Dilute acid predistillery and the processing to hydrolysis and ethanol. System boundary is at simultaneous the sugar refinery. Dehydration saccharification and cois not included. Process heat and fermentation. Economic power supply is generated by allocation 97.7% to unconverted solids. ethanol. CO2 emissions are allocated based on carbon balance. Ecoinvent Ethanol, 95% in H20, from wood, at sugar refinery/SE S Ethanol, 95% in H20, from wood, at sugar refinery/SE U Ecoinvent Table 29 (cont’d) Dehydration of hydrated ethanol (95%). Treatment of waste also included. 2002-2006 Europe 1 kg corn-based ethanol. Molecular sieve technology used for dehydration. Dehydration of hydrated ethanol (95%). Treatment of waste also included. USA 265 China 1 kg rye-based ethanol. Molecular sieve technology used for dehydration. 1992-2005 Dehydration of hydrated ethanol (95%). Treatment of waste also included. 1990-2006 Ethanol, 99.7% in H2O, from biomass, at distillation/US S Ethanol, 99.7% in H2O, from biomass, at distillation/US U Ecoinvent Ethanol, 99.7% in H2O, from biomass, at distillation/RER S Ethanol, 99.7% in H2O, from biomass, at distillation/RER U 1 kg Sorghum-based ethanol. Molecular sieve technology used for dehydration. Ecoinvent Ethanol, 99.7% in H2O, from biomass, at distillation/CN S Ethanol, 99.7% in H2O, from biomass, at distillation/CN U Ecoinvent Table 29 (cont’d) Bioethanol and coproducts from switchgrass. Land use change, harvesting, transport to refinery, drying and palletizing, biorefinery functions. Also includes cultivation, seeding, fertilizer, herbicides, lime and direct emissions. 266 USA (Minnesota) Life cycle assessment of a biorefinery concept producing bioethanol, bioenergy, and chemicals from switchgrass USA (Oregon) water consumption during corn production Unspecified Ecological impacts of corn based ethanol - water consumption in 81 spatially explicit Minnesota watersheds. 2011 Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment 2010 International Journal of LCA 2011 Ethanol from Tall Fescue grass straw by various methods: dilute acid, dilute alkali, hot water, steam explosion. Grass seed production, straw collection and transportation, electricity and process energy. Conversion to ethanol: Biomass Preparation, pretreatment, conditioning (or hydrolysis), fermentation, distillation, waste water treatment, energy recovery from biogas. International Journal of LCA Jan 2012 Life cycle assessment of energy and GHG emissions during ethanol production from grass straws using various pretreatment processes International Journal of LCA Jan 2010 Table 29 (cont’d) Brazil Corn ethanol represents dry milling process, and Soybean oil was made using the crushing process. GHG only reported category. Data is at the county level, 40 counties in the US corn belt were chosen. Direct land use change is included. It is measured and the change in soil carbon organic material. Includes impacts associated with the biomass, bio-refining, upstream processes. 267 USA Soil preparation, cane plantation, chemical application, harvesting, fuel ethanol process, and energy co-generation 2009 Functional Unit is 10,000 Km covered by car of a specific size engine, but data is broken into phases. USA Regional variations in GHG emissions of bio-based products in the United States - Corn based ethanol and soybean oil Agriculture: Seeding, energy, minerals, pesticides, fertilizers, inorganics and water (land use excluded). Cellulosic stage: pretreatment, hydrolyze fermentation, distillation, dehydration and evaporation. 2009 Life Cycle Assessment of fuel ethanol from sugar cane in Brazil Different allocation methods are used to assess sensitivity of result to allocation method. GHG, acidification, eutrophication, photochemical oxidation, ecotoxicity, abiotic depletion and ozone layer depletion are reported. 2009 Allocation issues in LCA methodology: a case study of corn stover based fuel ethanol International International Journal of International Journal of Life Journal of LCA May LCA Sept 2009 Cycle Assessment 2009 2009 Table 29 (cont’d) 2008 Thailand Reports ethanol as E85, but process contribution data is available for cassava production and ethanol conversion. cassava farming: land prep, planting, crop maintenance, harvesting. Chip processing: chipping, dun dying, packing, milling, mixing and liquifying, fermentation, distillation, dehydration 2008 Thailand GHG and particulates reported Fertilizer, fuel, pesticides, drying, extraction, refining 2008 Comparative LCA of two biofuels ethanol from sugar beet and rapeseed methyl ester Sugar cane production: land prep, new planting (once per crop rotation), crop maintenance, harvesting. Sugar milling, fermentation, distillation, dehydration International Journal of Life Cycle Assessment March 2008 Life cycle assessment of fuel ethanol from cassava in Thailand Functional unit is gas equivalent consumed by a new passenger car to travel a specific distance. Sugar factory and ethanol data is primary. International Journal of Life Cycle Assessment May 2008 Life Cycle Assessment of fuel ethanol from cane molasses in Thailand. International Journal for LCA June 2008 Table 29 (cont’d) 268 269 Brazil Both sugarcane and palm tree are crops with high biofuel yields. The joint production of these crops enhances the sustainability of ethanol. For the purpose of this study, three sugarcane mills in Sao Paulo State and one palm oil refinery in Para State were surveyed (Brazil). Results showed that fossil fuel use and greenhouse gas emissions decreased when the joint production system was compared to the traditional sugarcane ethanol production system. As a result, energy efficiency increased.  2012 (publication) Life cycle assessment of sugarcane ethanol and palm oil biodiesel joint production Journal of Industrial Ecology Sept. 2012 Table 29 (cont’d) 270 Australia Ethanol from wheat, sugar beet, and willow. Methyl ester from rape and methane from corn. Thailand Agricultural crop based biofuels resource efficiency and environmental performance including direct land use changes GHG emissions and Direct land use changes. Northern Europe Journal of cleaner production Vol 37 For the purpose of this study, three sugarcane mills in Sao Paulo State and one palm oil refinery in Para State were surveyed (Brazil). 2012 Effect of biogas utilization and plant co-location on life cycle greenhouse gas emissions of cassava ethanol production Cassava farming: Land prep, seed planting, fertilizer, weeding, harvesting. Cassava chip production: weight and measure of harvested roots, chopping and drying, transport to ethanol plant. Fuel production: pre-treatment, liquefying, saccharification. 2011 Journal of cleaner production Vol 39 Land use change, milling and production, fermentation, additional cane growing (for scenarios 3 and 4). Journal of Cleaner Production Vol 19 Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agro-industry 2012 Table 29 (cont’d) 271 USA Dewatering of ethanol 95% from Scandinavian wood China Ethanol from Scandinavian softwood chips Sweden Journal of Cleaner Production Vol 16 (2007) Ethanol, 99.7% in H2O, from wood, at distillation/SE S Ethanol, 99.7% in H2O, from wood, at distillation/SE U 2009 (published) Life cycle inventory and energy analysis of cassava based fuel ethanol in china Results showed that fossil fuel use and greenhouse gas emissions decreased when the joint production system was compared to the traditional sugarcane ethanol production system. As a result, energy efficiency increased. Cassava cultivation and treatment: seed production, field prep and plough, sowing, fertilizer, weed control, harvesting, pilling and slicing, insolation and packing. Conversion from dry chips: Milling, mixing, liquification and saccharification, fermentation, distilling, separation, rectification and dehydration. Denaturing included. Improvements in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of CornEthanol 2007 Journal of Industrial Ecology, Feb. 2009 Energy used for feedstock production and harvesting, including fossil fuels for field operations and electricity for grain drying and irrigation. Ecoinvent Table 29 (cont’d) Conversion of wood chips into synthetic gas. Includes drying and further comminution of wood chips (down to size 30x30x30mm), fluidized bed gasification, treatment of the resulting syngas to remove impurities and contaminants. 1995-2004 Switzerland Composition (%mol) of the resulting gas is 15.5% H2, 39.2% CO, 34.9% CO2, 8.7% CH4, and 1.7 CnHm on a nitrogen and water free basis. Nitrogen content is 50.4%. Density is 1.15 kg/Nm3. Lower heating value of the gas is 5.4 MJ/Nm3. Production of 1 Nm3 syngas. Conversion of wood chips into synthetic gas. Includes drying and further comminution of wood chips (down to size 30x30x30mm), fluidized bed gasification, treatment of the resulting syngas to remove impurities and contaminants. 1995-2004 Switzerland Synthetic gas, from wood, at fluidized bed gasifier/CH S Synthetic gas, from wood, at fluidized bed gasifier/CH U Ecoinvent Synthetic gas, from wood, at fixed bed gasifier/CH S Synthetic gas, from wood, at fixed bed gasifier/CH U Composition (%mol) of the resulting gas is 28.4% H2, 40.6% CO, 23.6% CO2, 5.9% CH4, and 1.5 CnHm on a nitrogen and water free basis. Nitrogen content is 47.6%. Density is 1.15 kg/Nm3. Lower heating value of the gas is 5.4 MJ/Nm3. Production of 1 Nm3 syngas. Ecoinvent Table 29 (cont’d) 272 Materials, process energy, water, transport, 273 Switzerland "CARBON SEQUESTRATION should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product."(USLCI) 1995-2004 Production of synthetic gas from wood chips. 50% fixed gasification, 50% fluidized gasification. North America Soy biodiesel, production, at plant Ecoinvent Synthetic gas, production mix, at plant/CH S Wood gasification in CH is limited to the fixed bed pilot plant experience (Pyroforce, Xylowatt). Average composition (% mol) is 22.0% H2, 39.9% CO, 29.3% CO2, 7.3% CH4, 1.6% CnHm on a nitrogen and water free basis. Nitrogen content is 49.0%. Density is 1.15 kg/Nm3. USLCI Table 29 (cont’d) Denmark Rape seed production, storage, processing, transport, energy requirements, co-products. Costa Rica International Journal of LCA 2012 Life cycle assessment of biodiesel in Costa Rica Specific Denmark case, reports 6 impact categories. 2012 Potential for production and use of rapeseed biodiesel. Based on a comprehensive real-time LCA case study in Denmark with multiple pathways University of Applied Sciences Northwestern Switzerland (FHNW) Table 29 (cont’d) 274 Primary data was obtained for the crop portion of the data only. 2001-2005 Argentina Goal to provide baseline information about algae biodiesel. Data was taken from USLCI and literature sources. Many assumptions / substitutions were made to estimate an LCA for Algae biodiesel. Open pond growth assumed. Soybean processing data used to estimate the conversion of algal lipids into biodiesel, and algae meal was assumed to have the same ethanol yield as wheat straw. Algae growth, harvesting, separation, processing, transportation and distribution included. Partial treatment of wastewater and natural gas requirements also included. Time of publications Unspecified Life Cycle Analysis of Algae Biodiesel International Journal of LCA March 2009 Life cycle assessment of soybean based biodiesel production in Argentina Only CO2, CH4, and N2O were considered in the global warming calculation. Land use change except for direct deforestation is excluded. Storage and drying is excluded. Agriculture, extraction and refining, trans esterification included. Sander and Murthy 2010 – International Journal of LCA Table 29 (cont’d) 275 276 Brazil Compares conventional diesel with biodiesel production from winter rape crop. LCA evaluates the energy balance and the environmental impacts. Thailand Journal of Industrial Ecology July 2012 A life cycle assessment of biodiesel production from winter rape grown in Southern Europe Land use change, palm oil cultivation and harvesting, transport, milling , biodiesel conversion, by product processing, on site waste management, and use of biodiesel in a vehicle included. Southern Europe Food, Fuel and Climate Change: Is palm based biodiesel a sustainable option for Thailand? Uses an indicator called "net feedstock balance" that describes the physical supply of feedstock for the long term. This is a "well to wheels" study, but unit process data is available for land use change scenarios and how they affect GHG emissions. Only 100 year GWP reported. The life cycle assessment of biodiesel from palm oil (“dende”) in the Amazon 2012 Journal of Biomass andBioenergy, Jan. 2012 Palm oil as a promising source of biodiesel in the Amazon Journal of Biomass and Bioenergy May 2012 Table 29 (cont’d) 277 Brazil and Europe 2009 Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans Journal of Cleaner Production 2009 Table 29 (cont’d) Transport Infrastructure Waste Treatment Machines Extraction Process Energy Drying Fermentation Refining Direct Emissions Storage Water Land Use A Name Materials Table 30 – Chemical Data Summary Inputs B C D E F G H I J K L M N Ethanol, denatured, forest residues, thermochemical 1 1 1 1 Ethanol, denatured, corn stover, biochemical 1 1 1 1 Ethanol, denatured, wheat straw, biochemical 1 1 1 1 ethanol, denatured, mixed feedstocks, at conversion facility, 2022 1 Ethanol, denatured, switchgrass, biochemical 1 1 1 1 278 Table 30 (cont’d) A B C D E F G H I J K Ethanol, denatured, corn dry mill Corn, in distillery Ethanol, 95% in H2O, from corn, at distillery/US S Ethanol, 95% in H2O, from corn, at distillery/US U Ethanol, 95% in H2O, from grass, at fermentation plant/CH S - Ethanol, 95% in H2O, from grass, at fermentation plant/CH U Ethanol, 95% in H2O, from potatoes, at distillery/CH S - Ethanol, 95% in H2O, from potatoes, at distillery/CH U 1 1 1 1 1 1 1 279 1 L M N Table 30 (cont’d) A B C D E F G Ethanol, 95% in H2O, from rye, at distillery/RER S Ethanol, 95% in H2O, from rye, at distillery/RER U 1 1 I J K 1 Ethanol, 95% in H2O, from sugar beet molasses, at distillery/RER S - Ethanol, 95% in H2O, from sugar beet molasses, at distillery/RER U H 1 Ethanol, 95% in H2O, from sugar beets, at fermentation plant/CH S Ethanol, 95% in H2O, from sugar beets, at fermentation plant/CH U 1 1 1 280 1 L M N Table 30 (cont’d) A Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR S Ethanol, 95% in H20, from sugar cane, at fermentation plant/BR U B 1 C D E F 1 G 1 Ethanol, 95% in H20, from sugarcane molasses, at sugar refinery/BR S Ethanol, 95% in H20, from sugarcane molasses, at sugar refinery/BR U 1 1 Ethanol, 95% in H20, from sweet sorghum, at sugar refinery/CN S - Ethanol, 95% in H20, from sweet sorghum, at sugar refinery/CN U 1 1 281 H I J K 1 L M N Table 30 (cont’d) A Ethanol, 95% in H20, from whey, at sugar refinery/CH S - Ethanol, 95% in H20, from whey, at sugar refinery/CH U B 1 C D E F 1 G H 1 Ethanol, 95% in H20, from wood, at sugar refinery/CH S - Ethanol, 95% in H20, from wood, at sugar refinery/CH U 1 1 1 Ethanol, 99.7% in H2O, from biomass, at distillation/BR S - Ethanol, 99.7% in H2O, from biomass, at distillation/BR U 1 282 J K 1 1 Ethanol, 95% in H20, from wood, at sugar refinery/SE S - Ethanol, 95% in H20, from wood, at sugar refinery/SE U I L M N Table 30 (cont’d) A B C D E F G H Ethanol, 99.7% in H2O, from biomass, at distillation/CH S - Ethanol, 99.7% in H2O, from biomass, at distillation/CH U 1 Ethanol, 99.7% in H2O, from biomass, at distillation/CN S - Ethanol, 99.7% in H2O, from biomass, at distillation/CN U 1 Ethanol, 99.7% in H2O, from biomass, at distillation/RER S - Ethanol, 99.7% in H2O, from biomass, at distillation/RER U 1 Ethanol, 99.7% in H2O, from biomass, at distillation/US S - Ethanol, 99.7% in H2O, from biomass, at distillation/US U 1 283 I J K L M N Table 30 (cont’d) A B 1 1 Life cycle assessment of a bio-refinery concept producing bioethanol, bioenergy, and chemicals from switchgrass 1 1 Allocation issues in LCA methodology: a case study of corn stover based fuel ethanol 1 Life cycle assessment of energy and GHG emissions during ethanol production from grass straws using various pretreatment processes C D E F 1 G H 1 I J K L M 1 Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment 1 1 284 1 1 1 1 N Table 30 (cont’d) A B C D E F G H I J Life Cycle Assessment of fuel ethanol from sugar cane in Brazil 1 1 Regional variations in GHG emissions of bio-based products in the United States - Corn based ethanol and soybean oil 1 1 1 1 Life Cycle Assessment of fuel ethanol from cane molasses in Thailand. 1 1 1 1 1 Life cycle assessment of fuel ethanol from cassava in Thailand 1 1 1 1 1 1 Comparative LCA of two biofuels - ethanol from sugar beet and rapeseed methyl ester 1 1 1 1 285 K L M N 1 1 1 Table 30 (cont’d) A B C D E F G 1 1 1 1 H I J K L M N Life cycle assessment of sugarcane ethanol and palm oil biodiesel joint production Bioproduction from Australian sugarcane: an environmental investigation of product diversification in an agroindustry 1 Effect of biogas utilization and plant co-location on life cycle greenhouse gas emissions of cassava ethanol production 1 Agricultural crop based biofuels - resource efficiency and environmental performance including direct land use changes 1 2 1 1 1 1 286 Table 30 (cont’d) A B C D E F G H I J 1 1 1 1 K L 1 Improvements in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of Corn-Ethanol Life cycle inventory and energy analysis of cassava based fuel ethanol in china 1 Ethanol, 99.7% in H2O, from wood, at distillation/SE S - Ethanol, 99.7% in H2O, from wood, at distillation/SE U Synthetic gas, from wood, at fixed bed gasifier/CH S Synthetic gas, from wood, at fixed bed gasifier/CH U 1 1 1 287 1 M N Table 30 (cont’d) A B C D E F H 1 Synthetic gas, from wood, at fluidized bed gasifier/CH S - Synthetic gas, from wood, at fluidized bed gasifier/CH U G 1 I J K L M 1 Synthetic gas, production mix, at plant/CH S Soy biodiesel, production, at plant 1 1 Potential for production and use of rapeseed biodiesel. Based on a comprehensive real-time LCA case study in Denmark with multiple pathways 1 1 1 1 1 Life cycle assessment of biodiesel in Costa Rica 288 1 1 N Table 30 (cont’d) A B C D 1 Life Cycle Analysis of Algae Biodiesel 1 1 1 1 G 1 1 1 F 1 Life cycle assessment of soybean based biodiesel production in Argentina E 1 H I J K L M N 1 1 The life cycle assessment of biodiesel from palm oil (“dende”) in the Amazon Food, Fuel and Climate Change: Is palm based biodiesel a sustainable option for Thailand? 1 A life cycle assessment of biodiesel production from winter rape grown in Southern Europe Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans 1 289 1 1 Data Country Includes Production of 1 kg granulate modified starch, highly aggregated background data used. Only highly aggregated data were available, therefore emissions from energy consumption, waste water treatment and raw material inputs have been subtracted resulting in a difference in NMVOC emissions. Production of input material corn starch and fossil components (plasticizers and complexing agents), transports of input materials, energy consumption in the processing and packaging at plant as well as waste treatment. Europe Data Years Details Production of 1 kg PLA, based on data from world's largest PLA plant. The inventories include the LCI data from the report of the producer NatureWorks. Only aggregated data are reported. Only highly aggregated data were available, therefore emissions from energy consumption, waste water treatment and raw material inputs have been subtracted resulting in a difference in NMVOC emissions. Maize production, energy use, transport and waste water treatment. Infrastructure has been added. Wind power used to offset CO2 emissions. USA (Nebraska) Polylactide, granulate, at plant/GLO S Polylactide, granulate, at plant/GLO U Ecoinvent Modified starch, at plant/RER S Modified starch, at plant/RER U Ecoinvent Name Data Availability Table 31 – Polymer Data Summary 290 Heating, agitating, rolling, mixing, extruding, pelletizing, cooling. USA (Nebraska) Thermoplastic processing of NTP derived from bloodmeal into pellets. Materials, waste disposal, process energy, water 291 USA USLCI An ecoprofile of thermoplastic protein derived from blood meal Part 2: thermoplastic processing Materials, waste disposal, electricity, natural gas, water, transport. New Zealand Soy-based resin, at plant " CARBON SEQUESTRATION should be accounted for after the product is built in its LCA model, and should be included depending on the use of end of life fate of that product"(USLCI). Polylactide Biopolymer Resin, at plant 2012 USLCI Data has been peer reviewed by Dr. I. Boustead from Boustead Consulting, UK. Data only represents Ingeo polylactide (PLA) resin production by NatureWorks LLC in Blair Nebraska and cannot be used for PLA production in general. Final review report is attached to the Data Module Report. International Journal of LCA 2012 Table 31(cont’d) Study goal: identify major contributors to the environmental impact of sugar cane-based LDPE and to compare the environmental performance of sugar cane LDPE produced in Brazil and used in Europe with the performance of fossil-based LDPE produced and used in Europe. Land Use Change (LUC) emissions were also accounted for. Land use change, ethanol production, polymerization, and transport of polymer by cargo ship. Data summary table references: [3, 7, 9, 10, 13, 17, 21, 24-27, 29-32, 35-94] 292 USA (shipped to Singapore) Corn production, wet milling, fermentation and recovery, blown film extrusion, ship transport, road transport Brazil This study is for Singapore, but the PHA bags are manufactured in the US and transported vs. the PE bags which are manufactured in Singapore, this difference means there is a long transport step included for the PHA bags but not the PE bags. 2012 (published) A Comparative Life Cycle Assessment Study of PE Based on Sugar Cane and Crude Oil International Journal of LCA March 2010 Environmental impacts of conventional plastic and biobased carrier bags part 1: life cycle production Journal of Industrial Ecology, June 2012 Table 31(cont’d) REFERENCES 293 REFERENCES 1. International Organization for Standardization, Life Cycle Assessment Principles and Framework. 2006. 2. International Organization for Standardization, Life Cycle Assessment Requirements and Guidelines. 2006. 3. Álvarez-Chávez, C.R., et al., Sustainability of bio-based plastics: general comparative analysis and recommendations for improvement. Journal of Cleaner Production, 2012. 23(1): p. 47-56. 4. Piemonte, V. and F. Gironi, Land-use change emissions: How green are the bioplastics? Environmental Progress & Sustainable Energy, 2011. 30(4): p. 685691. 5. Mirasol, F. Potential for bioplastics containers 2012. 6. Nemecek, T., et al., Estimation of the variability in global warming potential of worldwide crop production using a modular extrapolation approach. Journal of Cleaner Production, 2012. 31: p. 106-117. 7. Ester van der Voet, R.J.L., Lin Luo, Life-cycle assessment of biofuels, convergence and divergence. Biofuels, 2010. 1(3): p. 435-449. 8. Cooper, J.S. and E. Kahn, Commentary on issues in data quality analysis in life cycle assessment. The International Journal of Life Cycle Assessment, 2012. 17(4): p. 499-503. 9. Kim, S. and B.E. Dale, Life Cycle Assessment to Improve the Sustainability and Competitive Position of Biobased Chemicals: A Local Approach. 2009, Michigan State University. 10. Chiu, Y.-W., et al., Measuring ecological impact of water consumption by bioethanol using life cycle impact assessment. The International Journal of Life Cycle Assessment, 2011. 17(1): p. 16-24. 11. de Vries, S.C., The bio-fuel debate and fossil energy use in palm oil production: a critique of Reijnders and Huijbregts 2007. Journal of Cleaner Production, 2008. 16(17): p. 1926-1927. 12. Cooper, J.S., E. Kahn, and R. Ebel, Sampling error in US field crop unit process data for life cycle assessment. The International Journal of Life Cycle Assessment, 2012. 18(1): p. 185-192. 294 13. Weiss, M., et al., A Review of the Environmental Impacts of Biobased Materials. Journal of Industrial Ecology, 2012. 16: p. S169-S181. 14. ILCD Handbook: General guide for Life Cycle Assessment - Detailed guidance, E.C.J.R. Center, Editor. 2010. 15. van der Berg, N., et al., Quality Assessment for LCA. Centre of Environmental Science: TNO Environment, Energy and Process Innovation. 16. Ecoinvent, Overview And Methodology 2007, Swiss Center for Life Cycles Inventories. 17. Renouf, M.A., M.K. Wegener, and L.K. Nielsen, An environmental life cycle assessment comparing Australian sugarcane with US corn and UK sugar beet as producers of sugars for fermentation. Biomass and Bioenergy, 2008. 32(12): p. 1144-1155. 18. Barthet, V. Canola. 2012 [cited 2013 April 17]; Available from: http://www.thecanadianencyclopedia.com/articles/canola. 19. Canada, C.C.o. Industry Overview. 2011 [cited 2013 April 14]; Available from: http://www.canolacouncil.org/markets-stats/industry-overview/. 20. Agriculture, U.S.D.o., World Greains by Commodity. 2005. 21. Arvidsson, R., et al., Life cycle assessment of hydrotreated vegetable oil from rape, oil palm and Jatropha. Journal of Cleaner Production, 2011. 19(2-3): p. 129-137. 22. Agency, U.S.E.P. Soil Preparation. Ag 101 2013 [cited 2013 April 17]; Available from: http://www.epa.gov/agriculture/ag101/cropsoil.html. 23. Horowitz, J., R. Ebel, and K. Ueda, "No-Till" Farming is a Growing Practice. 2010, United States Department of Agriculture. 24. Renouf, M.A., M.K. Wegener, and R.J. Pagan, Life cycle assessment of Australian sugarcane production with a focus on sugarcane growing. The International Journal of Life Cycle Assessment, 2010. 15(9): p. 927-937. 25. Souza, S.P., M.T. de Ávila, and S. Pacca, Life cycle assessment of sugarcane ethanol and palm oil biodiesel joint production. Biomass and Bioenergy, 2012. 44: p. 70-79. 26. Roberto Ometto, A., M. Zwicky Hauschild, and W. Nelson Lopes Roma, Lifecycle assessment of fuel ethanol from sugarcane in Brazil. The International Journal of Life Cycle Assessment, 2009. 14(3): p. 236-247. 295 27. Goglio, P., E. Bonari, and M. Mazzoncini, LCA of cropping systems with different external input levels for energetic purposes. Biomass and Bioenergy, 2012. 42: p. 33-42. 28. Service, N.A.S., Irrigated Corn for Grain, Harvested Acres: 2002. 2002, United States Department of Agriculture. 29. Extension, U.N.-L. Irrigation and Water Management for Corn. Irrigation and Water Management resources for Nebraska producers 2012 [cited 2013 April 16]; Available from: http://cropwatch.unl.edu/web/corn/water. 30. Fukushima, Y. and S.-P. Chen, A decision support tool for modifications in crop cultivation method based on life cycle assessment: a case study on greenhouse gas emission reduction in Taiwanese sugarcane cultivation. The International Journal of Life Cycle Assessment, 2009. 14(7): p. 639-655. 31. Renouf, M.A., R.J. Pagan, and M.K. Wegener, Bio-production from Australian sugarcane: an environmental investigation of product diversification in an agroindustry. Journal of Cleaner Production, 2013. 39: p. 87-96. 32. Liptow, C. and A.-M. Tillman, A Comparative Life Cycle Assessment Study of Polyethylene Based on Sugarcane and Crude Oil. Journal of Industrial Ecology, 2012. 16(3): p. 420-435. 33. Martinelli, L.A. and S. Filoso, Expansion of Sugarcane Ethanol Production in Brazil: Environmental and Social Challenges. Ecological Applications, 2008. 18(4): p. 885-898. 34. Grau, H.R., T.M. Aide, and N.I. Gasparri, Global Soybean Semi Arid Argentina Ambio. Ambio, 2005. 34. 35. Alvarado-Morales, M., et al., Life cycle assessment of biofuel production from brown seaweed in Nordic conditions. Bioresour Technol, 2012. 129C: p. 92-99. 36. Bai, Y., L. Luo, and E. Voet, Life cycle assessment of switchgrass-derived ethanol as transport fuel. The International Journal of Life Cycle Assessment, 2010. 15(5): p. 468-477. 37. Beach, E.S., et al., Preferential technological and life cycle environmental performance of chitosan flocculation for harvesting of the green algae Neochloris oleoabundans. Bioresour Technol, 2012. 121: p. 445-9. 38. Bier, J.M., C.J.R. Verbeek, and M.C. Lay, An ecoprofile of thermoplastic protein derived from blood meal Part 2: thermoplastic processing. The International Journal of Life Cycle Assessment, 2011. 17(3): p. 314-324. 296 39. Bier, J.M., C.J.R. Verbeek, and M.C. Lay, An eco-profile of thermoplastic protein derived from blood meal Part 1: allocation issues. The International Journal of Life Cycle Assessment, 2011. 17(2): p. 208-219. 40. Bilad, M.R., et al., Harvesting microalgal biomass using submerged microfiltration membranes. Bioresour Technol, 2012. 111: p. 343-52. 41. Börjesson, P. and L.M. Tufvesson, Agricultural crop-based biofuels – resource efficiency and environmental performance including direct land use changes. Journal of Cleaner Production, 2011. 19(2-3): p. 108-120. 42. Brentner, L.B., M.J. Eckelman, and J.B. Zimmerman, Combinatorial life cycle assessment to inform process design of industrial production of algal biodiesel. Environ Sci Technol, 2011. 45(16): p. 7060-7. 43. Cavalett, O. and E. Ortega, Integrated environmental assessment of biodiesel production from soybean in Brazil. Journal of Cleaner Production, 2010. 18(1): p. 55-70. 44. Cherubini, F. and G. Jungmeier, LCA of a biorefinery concept producing bioethanol, bioenergy, and chemicals from switchgrass. The International Journal of Life Cycle Assessment, 2009. 15(1): p. 53-66. 45. Choo, Y.M., et al., Determination of GHG contributions by subsystems in the oil palm supply chain using the LCA approach. The International Journal of Life Cycle Assessment, 2011. 16(7): p. 669-681. 46. Chua, C.B.H., H.M. Lee, and J.S.C. Low, Life cycle emissions and energy study of biodiesel derived from waste cooking oil and diesel in Singapore. The International Journal of Life Cycle Assessment, 2010. 15(4): p. 417-423. 47. Contreras, A.M., et al., Comparative Life Cycle Assessment of four alternatives for using by-products of cane sugar production. Journal of Cleaner Production, 2009. 17(8): p. 772-779. 48. Dalgaard, R., et al., LCA of soybean meal. The International Journal of Life Cycle Assessment, 2007. 13(3): p. 240-254. 49. de Figueirêdo, M.C.B., et al., Environmental performance evaluation of agroindustrial innovations – part 1: Ambitec-Life Cycle, a methodological approach for considering life cycle thinking. Journal of Cleaner Production, 2010. 18(14): p. 1366-1375. 50. Energy, C.B. Rye cultivation technology 2013; Available from: http://www.coachbioenergy.eu/en/cbe-offers-services/technology-descriptions-andtools/technologies/174-rye-cultivation-technology.html. 297 51. Faist Emmenegger, M., et al., Taking into account water use impacts in the LCA of biofuels: an Argentinean case study. The International Journal of Life Cycle Assessment, 2011. 16(9): p. 869-877. 52. Gan, Y., et al., Carbon footprint of canola and mustard is a function of the rate of N fertilizer. The International Journal of Life Cycle Assessment, 2011. 17(1): p. 58-68. 53. Gnansounou, E., et al., Life cycle assessment of biofuels: energy and greenhouse gas balances. Bioresour Technol, 2009. 100(21): p. 4919-30. 54. González-García, S., et al., Environmental assessment of black locust (Robinia pseudoacacia L.)-based ethanol as potential transport fuel. The International Journal of Life Cycle Assessment, 2011. 16(5): p. 465-477. 55. Halleux, H., et al., Comparative life cycle assessment of two biofuels ethanol from sugar beet and rapeseed methyl ester. The International Journal of Life Cycle Assessment, 2008. 13(3): p. 184-190. 56. Hedal Kløverpris, J., K. Baltzer, and P.H. Nielsen, Life cycle inventory modelling of land use induced by crop consumption. The International Journal of Life Cycle Assessment, 2009. 15(1): p. 90-103. 57. Herrmann, I.T., et al., Potential for optimized production and use of rapeseed biodiesel. Based on a comprehensive real-time LCA case study in Denmark with multiple pathways. The International Journal of Life Cycle Assessment, 2012. 58. Huang, J., et al., The impact of local crops consumption on the water resources in Beijing. Journal of Cleaner Production, 2012. 21(1): p. 45-50. 59. Iglesias, L., et al., A life cycle assessment comparison between centralized and decentralized biodiesel production from raw sunflower oil and waste cooking oils. Journal of Cleaner Production, 2012. 37: p. 162-171. 60. Iriarte, A., J. Rieradevall, and X. Gabarrell, Life cycle assessment of sunflower and rapeseed as energy crops under Chilean conditions. Journal of Cleaner Production, 2010. 18(4): p. 336-345. 61. Jørgensen, A., P. Bikker, and I.T. Herrmann, Assessing the greenhouse gas emissions from poultry fat biodiesel. Journal of Cleaner Production, 2012. 24: p. 85-91. 62. Kendall, A. and B. Chang, Estimating life cycle greenhouse gas emissions from corn–ethanol: a critical review of current U.S. practices. Journal of Cleaner Production, 2009. 17(13): p. 1175-1182. 298 63. Kim, S. and B.E. Dale, Regional variations in greenhouse gas emissions of biobased products in the United States—corn-based ethanol and soybean oil. The International Journal of Life Cycle Assessment, 2009. 14(6): p. 540-546. 64. Kim, S., B.E. Dale, and R. Jenkins, Life cycle assessment of corn grain and corn stover in the United States. The International Journal of Life Cycle Assessment, 2009. 14(2): p. 160-174. 65. Knudsen, M.T., et al., Environmental assessment of organic soybean (Glycine max.) imported from China to Denmark: a case study. Journal of Cleaner Production, 2010. 18(14): p. 1431-1439. 66. Kumar, D. and G.S. Murthy, Life cycle assessment of energy and GHG emissions during ethanol production from grass straws using various pretreatment processes. The International Journal of Life Cycle Assessment, 2012. 17(4): p. 388-401. 67. Leng, R., et al., Life cycle inventory and energy analysis of cassava-based Fuel ethanol in China. Journal of Cleaner Production, 2008. 16(3): p. 374-384. 68. Liska, A.J., et al., Improvements in Life Cycle Energy Efficiency and Greenhouse Gas Emissions of Corn-Ethanol. Journal of Industrial Ecology, 2009. 13(1): p. 5874. 69. Luo, L., et al., Allocation issues in LCA methodology: a case study of corn stoverbased fuel ethanol. The International Journal of Life Cycle Assessment, 2009. 14(6): p. 529-539. 70. Meisterling, K., C. Samaras, and V. Schweizer, Decisions to reduce greenhouse gases from agriculture and product transport: LCA case study of organic and conventional wheat. Journal of Cleaner Production, 2009. 17(2): p. 222-230. 71. Moriizumi, Y., et al., Effect of biogas utilization and plant co-location on life-cycle greenhouse gas emissions of cassava ethanol production. Journal of Cleaner Production, 2012. 37: p. 326-334. 72. Mumtaz, T., et al., Turning waste to wealth-biodegradable plastics polyhydroxyalkanoates from palm oil mill effluent – a Malaysian perspective. Journal of Cleaner Production, 2010. 18(14): p. 1393-1402. 73. Neupane, B., A. Halog, and S. Dhungel, Attributional life cycle assessment of woodchips for bioethanol production. Journal of Cleaner Production, 2011. 19(67): p. 733-741. 74. Nguyen, T.L.T. and S.H. Gheewala, Life cycle assessment of fuel ethanol from cassava in Thailand. The International Journal of Life Cycle Assessment, 2007. 13(2): p. 147-154. 299 75. Nguyen, T.L.T. and S.H. Gheewala, Life cycle assessment of fuel ethanol from cane molasses in Thailand. The International Journal of Life Cycle Assessment, 2008. 13(4): p. 301-311. 76. Nguyen, T.L.T., S.H. Gheewala, and M. Sagisaka, Greenhouse gas savings potential of sugar cane bio-energy systems. Journal of Cleaner Production, 2010. 18(5): p. 412-418. 77. Nie, S.-W., et al., Use of life cycle assessment methodology for determining phytoremediation potentials of maize-based cropping systems in fields with nitrogen fertilizer over-dose. Journal of Cleaner Production, 2010. 18(15): p. 1530-1534. 78. Panichelli, L., A. Dauriat, and E. Gnansounou, Life cycle assessment of soybeanbased biodiesel in Argentina for export. The International Journal of Life Cycle Assessment, 2008. 14(2): p. 144-159. 79. Pereira, C.L.F. and E. Ortega, Sustainability assessment of large-scale ethanol production from sugarcane. Journal of Cleaner Production, 2010. 18(1): p. 77-82. 80. Pishgar-Komleh, S.H., M. Ghahderijani, and P. Sefeedpari, Energy consumption and CO2 emissions analysis of potato production based on different farm size levels in Iran. Journal of Cleaner Production, 2012. 33: p. 183-191. 81. Reijnders, L. and M.A.J. Huijbregts, Biogenic greenhouse gas emissions linked to the life cycles of biodiesel derived from European rapeseed and Brazilian soybeans. Journal of Cleaner Production, 2008. 16(18): p. 1943-1948. 82. Renouf, M.A., R.J. Pagan, and M.K. Wegener, Life cycle assessment of Australian sugarcane products with a focus on cane processing. The International Journal of Life Cycle Assessment, 2010. 16(2): p. 125-137. 83. Roedl, A., Production and energetic utilization of wood from short rotation coppice—a life cycle assessment. The International Journal of Life Cycle Assessment, 2010. 15(6): p. 567-578. 84. Sander, K. and G.S. Murthy, Life cycle analysis of algae biodiesel. The International Journal of Life Cycle Assessment, 2010. 15(7): p. 704-714. 85. Schmidt, J.H., System delimitation in agricultural consequential LCA. The International Journal of Life Cycle Assessment, 2008. 13(4): p. 350-364. 86. Silalertruksa, T. and S.H. Gheewala, Food, Fuel, and Climate Change. Journal of Industrial Ecology, 2012. 16(4): p. 541-551. 87. Stichnothe, H. and F. Schuchardt, Comparison of different treatment options for palm oil production waste on a life cycle basis. The International Journal of Life Cycle Assessment, 2010. 15(9): p. 907-915. 300 88. Tsoutsos, T., et al., Life Cycle Assessment for biodiesel production under Greek climate conditions. Journal of Cleaner Production, 2010. 18(4): p. 328-335. 89. Upham, P., et al., Substitutable biodiesel feedstocks for the UK: a review of sustainability issues with reference to the UK RTFO. Journal of Cleaner Production, 2009. 17: p. S37-S45. 90. von Blottnitz, H. and M.A. Curran, A review of assessments conducted on bioethanol as a transportation fuel from a net energy, greenhouse gas, and environmental life cycle perspective. Journal of Cleaner Production, 2007. 15(7): p. 607-619. 91. Williams, A.G., E. Audsley, and D.L. Sandars, Environmental burdens of producing bread wheat, oilseed rape and potatoes in England and Wales using simulation and system modelling. The International Journal of Life Cycle Assessment, 2010. 15(8): p. 855-868. 92. Yuttitham, M., S.H. Gheewala, and A. Chidthaisong, Carbon footprint of sugar produced from sugarcane in eastern Thailand. Journal of Cleaner Production, 2011. 19(17-18): p. 2119-2127. 93. National Renewable Energy Laboratory., U. S. Life Cycle Inventory Database. 2012. 94. Swiss Ceneter for Life Cycle Inventories., Ecoinvent 301