. .iaaslkmna... .a‘mmhm, : .. Nb. It. fififitmn .c Kira—4%.. j .5: nu. qufiflnuflwfl. I“: 1.5.5. . 3.3-. J .911. . . at. . ‘ . 1.17;”: ."a' 'lSITJ’s‘h an annaithflo ‘ . ‘ .- , ,1 “Li. Hflv‘.tit(:. .I Ann. I. :14.) c}... 51...! ‘ x. r .I 2:90.53 ...§vl...,.:.r!:.,u.x 3!. . . .342. :1... This is to certify that the thesis entitled Characterization of Aquifer Heterogeneity and Tracer Test Simulations by Incorporating Geologic Information in the Form of Outcrop Analog and Well Core at a Distal and Medial Outwash Aquifer in Schoolcraft, Michigan presented by Susanne Evelyn Biteman has been accepted towards fulfillment of the requirements for ' a Master 5 degree In Geology 18 Major professor Date August 22, 2002 0-7639 MS U i: an Affirmative Action/Equal Opportunity Institution LIBRARY Michigan State University PLACE IN RETURN BOX to remove this checkout from your record. TO AVOID FINES return on or before date due. MAY BE RECALLED with earlier due date if requested. DATE DUE DATE DUE DATE DUE OCT 0 1 2006 W i ii at n U “ V V v " 6/01 chlRC/Datoouopes-ms CHARACTERIZATION OF AQUIFER HETEROGENEITY AND TRACER TEST SIIVIULATIONS BY INCORPORATING GEOLOGIC INFORMATION IN THE FORM OF OUTCROP ANALOG AND WELL CORE AT A DISTAL AND MEDIAL OUTWASH AQUIFER IN SCHOOLCRAFT, MICHIGAN By Susanne Evelyn Biteman A THESIS Submitted to Michigan State University In partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Department of Geological Sciences 2002 r y ‘N ZL' l‘. MU. J, Li it. -f' iii 3» ABSTRACT CHARATERIZATION OF AQUIFER HETEROGENEITY AND TRACER TEST SIMULATIONS BY INCORPORATIN G GEOLOGIC INFORMATION IN THE FORM OF OUTCROP ANALOG AND WELL CORE AT DISTAL AND MEDIAL OUTWASH AQUIFER IN SCHOOLCRAFT, MICHIGAN by Susanne Evelyn Biteman The integration of geostatistics and geologic data in the form of outcrop analogs and well core produced detailed models of aquifer heterogeneity using two methods, zonal kriging and transition probability geostatistics (Carle and Fogg, 1996). This study was conducted at the Schoolcrafl Plume A site, located in Kalamazoo County, Michigan. Sediments at this site were deposited as outwash medial and distal to the Kalamazoo Moraine. Using core data from the site and outcrop analog data from nearby sand and gravel pits, the aquifer was separated into major sedimentologic units to preserve abrupt changes in hydraulic conductivity and to better honor the assumption of stationarity. For the first geostatistical method, zonal kriging was used to estimate hydraulic conductivity distribution. After geostatistic estimation all the zones were combined to produce a complete aquifer realization. A non-zonal krige was also generated using the same conditioning data but without the geologically based zones. Both the zonal krige and the non-zonal krige hydraulic conductivity values were used as inputs for three dimensional ground water flow models and transport simulations. The zonal krige more accurately simulates the migration of an injected tracer pulse. (m (I 3' ACKNOWLEDGEMENTS I extend my thanks to my advisor Dr. Gary Weissmann who has helped me over the past two years by providing stimulating discussion which have lead me to have a greater knowledge and understanding of the many aspects of hydrogeology. His insightful reviews of this manuscript were greatly appreciated. Committee members Dr. David Hyndman and Dr. Grahame Larson provided much knowledge and experience ~ throughout the different stages of this project. M.S. Phanikumar’s help with the groundwater modeling and transport simulations was irreplaceable. I thank Michelle Vit for her help conducting the field work portion of this study. This research was funded in part by Michigan Department of Environmental Quality (Contract # Y403 86) and in part by Michigan State University through Dr. Gary Weissmann’s set up fund. I would thank my parents and my brother who have supported me throughout my educational endeavors. I would also like to thank my friends who have experienced graduate school with me, most of all Jennifer Wade, who has been a wonderful friend to me. I am especially grateful to my husband, Adam for his absolute love and support. iii TABLE OF CONTENTS LIST OF TABLES ................................................................................ vii LIST OF FIGURES ................................................................................ x I. INDRODUCTION AND SCOPE OF WORK ............................................. 1 INTRODUCTION ........................................................................... 1 PURPOSE OF THE STUDY .............................................................. 3 THESIS OUTLINE .......................................................................... 5 II. PREVIOUS WORK ............................................................................. 7 GEOLOGY .................................................................................. 7 Regional Bedrock Geology ....................................................... 7 Glacial History of Southwestern Michigan ..................................... 9 General Stratigraphy and Sedimentology of Glaciofluvial Deposit ....... 12 HYDROGEOLOGY ....................................................................... 20 Regional Hydrogeology ......................................................... 20 History of Contamination at Plume A ......................................... 23 Bioremediation of Plume A ..................................................... 24 III. INTEGRATION OF SEDIMENTOLOGIC AND HYDROGEOLOGIC PROPERTIES FOR INPROVED TRANSPORT SIMULATIONS: DETAILED CHARACTERIZATION OF A GLACIAL OUTWASH AQUIFER AT THE SCHOOLCRAFI‘ BIOREMEDIATION SITE, MICHIGAN ............................ 25 INTRODUCTION ........................................................................ 26 SITE DESCRIPTION ..................................................................... 28 CORE DESCRIPTIONS .................................................................. 32 iv Methods ............................................................................ 32 Core facies interpretation .............................................. 34 Schoolcrafi Stratigraphic Evaluation ........................................... 37 OUTCROP ANALOG .................................................................... 41 GEOSTATISTICS ........................................................................ 42 GROUNDWATER MODELING AND TRACER TEST SIMULATIONS ...... 44 RESULTS AND DISCUSSION ......................................................... 49 CONCLUSTIONS ........................................................................ 5 1 IV. TRANSITION PROBABILITY GROSTATISTICS ................................. 52 INTRODUCTION ........................................................................ 52 STRATIFICATION OF ZONES ....................................................... 54 Explanation of Hydrofacies from Categories ................................. 54 Top Zone .................................................................. 56 Bottom Zone ............................................................. 61 MARKOV CHAIN MODELS ........................................................... 64 Top Zone Markov Chain Models ............................................... 64 Bottom Zone Markov Chain Models .......................................... 69 CONDITIONAL SEQUENTIAL INDICATOR SMULATION .................. 77 COMBINING THE ZONES ............................................................. 77 CONCLUSIONS .......................................................................... 81 V. CONCLUSIONS .............................................................................. 82 DEPOSTIONAL EVIRONMENT OF THE AQUIFER BELOW SCHOOLCRAFT ........................................................................... 82 AQUIFER CHARACTERIZATIONS .................................................. 83 Kriging Method ................................................................... 84 Transition Probability Method ................................................. 84 APPENDIX A. STRATIGRAPHY OF THE SCHOOLCRAFT PLUME A SITE ..86 CORE DATA .............................................................................. 86 INTERPRETATIONS OF DEPOSITIONAL ENVIRONMENT OF THE AQUIFER BENEATH SCHOOLCRAFT ............................................. 86 APPENDIX B. OUTCROP ANALOGS .................................................... 123 REFERENCES ................................................................................... 134 vi TABLE 3.1 TABLE 3.2 TABLE 3.3 TABLE 3.4 TABLE 4.1 TABLE 4.2 TABLE 4.3 TABLE 4.4 TABLE 4.5 TABLE 4.6 LIST OF TABLES Anisotropy values for vertical K and horizontal K, determined by comparing repacked to non-repacked core .................................... 35 Vertical K (cm/s) of facies vs. sorting from well P18 ........................ 35 Horizontal K (cm/s) statistics for the four stratigraphic zones and the non- zonal model ........................................................................ 4O Variogram parameters for zonal krige and non—zonal krige. A11 variograms fit using exponential model ........................................ 45 Mean grain size (GS) in Phi unit, corresponding Wentworth size class (Boggs, 2001), mean standard deviation (SD), sorting based on standard deviation (Boggs, 2001), and number of data points in each zone for the transition probability (T .P.) zones and the four zonal kriging zones. Zone one is the same for the transition probability and zonal krige zones ......... 55 Proportions of hydrofacies in the top and bottom zone ...................... 55 Hydrofacies and corresponding assigned category for the top zone with high K value, low K value, average K value, and number of points ....... 57 Hydrofacies and corresponding assigned category for the bottom zone with high K value, low K value, average K value, and number of points ................................................................................ 57 Embedded transition probability matrices for the top zone. These matrices are read as transition probabilities from the row hydrofacies to the column hydrofacies. (hydrofacies labels: PMS, poorly sorted medium sand; PCS, poorly sorted coarse sand; MWFS, moderately to well sorted fine sand; PF S, poorly sorted fine sand; VFS, very fine sand. Other labels: L, mean length. Bold numbers indicate background category with computed values listed in the table.) ................................................................. 66 Embedded transition probability matrices for the bottom zone. These matrices are read as transition probabilities from the row hydrofacies to the column hydrofacies. (hydrofacies labels: PGVCS, pebbles, gravel and very coarse sand; WMS, well sorted medium sand; PCS, poorly sorted coarse sand; PMS, poorly sorted medium sand; MWFS, moderately to well sorted fine sand. Other labels: L, mean length. Bold numbers vii TABLE 4.7 TABLE A.l TABLE A.2 TABLE A.3 TABLE A.4 TABLE A.5 TABLE A.6 TABLE A.7 TABLE A.8 TABLE B.l indicate background category with computed values listed in the table). ........................................................................................ 73 W.r.t independent transition frequencies matrices for the bottom zone. These matrices are read as independent transition probabilities from the row hydrofacies to the column hydrofacies. (hydrofacies labels: PGVCS, pebbles, gravel and very coarse sand; WMS, well sorted medium sand; PCS, poorly sorted coarse sand; PMS, poorly sorted medium sand; MWFS, moderately to well sorted fine sand. Other labels: L, mean length. Bold numbers indicate background category with computed values listed in the table.) ........................................................................ 75 Key for the core descriptions .................................................... 92 Well D2. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)) .............................................................. 116 Well D4. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)) .............................................................. 117 Well D6. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001 )) .............................................................. 1 18 Well D8. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)) .............................................................. 119 Well D10. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain .size (Boggs, 2001)) ....................................... 120 Well D12. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)) ........................................ 121 Well D14. X, Y, and Z location, Log K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)) ........................................ 122 Key for photomosaics ........................................................... 123 viii TABLE B.2 Description of outcrop analog shown in Figure B.5. Bed number, mean grain size, grain size range, sorting, facies, and apparent trends are given ............................................................................... 129 TABLE 33 Description of outcrop analog shown in Figure 85. Bed number, mean grain size, grain size range, sorting, facies, and apparent trends are given ............................................................................... 13 1 TABLE B.4 Description of outcrop analog shown in Figure B.5. Bed number, mean grain size, grain size range, sorting, facies, and apparent trends are given ............................................................................... 133 ix FIGURE 2.1 FIGURE 2.2 FIGURE 2.3 FIGURE 2.4 FIGURE 2.5 FIGURE 2.6 FIGURE 2.7 FIGURE 2.8 FIGURE 3.1 FIGURE 3.2 FIGURE 3.3 LIST OF FIGURES Bedrock map of the Lower Peninsula of Michigan. Kalamazoo County is outlined in black. Modified from Milstein, 1987. Image is presented in color .................................................................................. 8 Location of Moraines in southwestern Michigan. Notice the interlobate boundary marking the extent of both the Saginaw and Lake Michigan lobes. Kalamazoo County is marked by a bold outline. Modified from Monaghan et al., 1986 ............................................................ 10 Till sheets underlying moraines in southwestern Michigan. Modified from Monaghan et al.,1986 ............................................................ 11 Figure 2.4. Study areas of Steinmann (1994) and Baresse (1991). Boundary of Prarie Rhonde Fan as described by Steinmann, maked by Steinmann’s study area. Modified from Baresse, 1991 and Steinmann, 1994 .................................................................................. 13 Principal bar types and where they form in a stream. Modified from Miall, 1977 .......................................................................... 16 Vertical facies models of Scott-type, Donjeck-type and Bijou Creek type. Modified from Miall, 1977; 1996 ................................................ 17 Block diagrams showing the braided stream patterns associated with Scott-type streams (A), Donjeck-type streams (B), and Platte type Streams (C). Modified from Miall, 1985 ................................................. 18 Study area of Lipinski (2002) regional model. Lipinski’s smaller scale transport model is outlined by the bold rectangle near Schoolcraft. Modified from Lipinski, 2002 ................................................... 22 Kalamazoo County Surficial Geology, location of Kalamazoo Moraine and outcrop site used for this study. Modified from Monaghan and Larson, (1982) ...................................................................... 29 Schoolcraft Plume A site. Location of biocurtian is marked by arrow. Modified from Mayotte (1991) ................................................... 31 Location of delivery wells (D) and monitoring wells (MW) at the Plume A Schoolcrafi site ..................................................................... 33 Fl FIGL' FIGL’P FIGURE 3.4 FIGURE 3.5 FIGURE 3.6 FIGURE 3.7 FIGURE 3.8 FIGURE 3.9 FIGURE 4.1 FIGURE 4.2 FIGURE 4.3 FIGURE 4.4 FIGURE 4.5 Core description of P18 showing zonal boundaries (marked by arrows) and measured vertical K .......................................................... 38 Cross-section of log K data points used for interpolation. Figure 3.5a is transect through the delivery wells, Figure 3.5b is a transect through the down gradient wells (Figure 3.3 for location). Zonal boundaries picked at 16 m bgs, 20 m bgs, and 21 m bgs. Scalebar is in log K (cm/s) ............... 39 A portion of the outcrop analog showing the stratigraphic character of the outwash material with a shovel for scale. Image is presented in color. . ..43 Zonal (top) and non-zonal (bottom) kriged results. Arrows mark boundaries of zones in zonal krige. Note that abrupt changes in K are preserved in zonal krige approach. Scalebar is in log K (cm/s) ............ 46 Discretization of grid in plan view, delivery well gallery is located near the center of the grid, marked by light colored squares where discretization is the finest ......................................................................... 48 Measured tracer test from site (x) with simulated zonal krige (black line) and simulated non-zonal krige (gray line) ..................................... 50 Top zone of Schoolcraft site, 1-5 are categories of hydrofacies, corresponds to Table 4.3. Top diamond is high K value, bottom diamond is low K value and middle diamond is mean K value. Cross-section of categories in top zone. Category 1, poorly sorted medium sand (PMS); category 2, poorly sorted coarse sand (PCS); category 3, moderately to well sorted fine sand (MWFS); category 4, poorly sorted fine sand (PF S); category 5, very fine sand (VF S). X axis is depth (m). Image is presented in color .......................................... 60 Bottom zone of Schoolcrafi site, 1-5 categories of hydrofacies, corresponds to Table 4.4. Top diamond is high K value, bottom diamond is low K value and middle diamond is mean K value ........................ 62 Matrix of vertical (z)-direction transition probabilities showing core data as measurements (open circles) and the Markov chain model (solid line) from the core measurements. The diagonal elements represent auto- transition probabilities within each category, and the off diagonal elements represent transition probabilities between categories ........................ 63 Matrix of perpendicular to flow (y)-direction transition probabilities showing core data as measurements (open circles) and the Markov chain model (solid line) from the core measurements. The diagonal elements xi represent auto-transition probabilities within each category, and the off diagonal elements represent transition probabilities between categories..68 FIGURE 4.6 Cross-section of category in bottom zone. Category 1, pebbles, granules and very coarse sand (PGVCS); category 2, poorly sorted medium sand (PMS); category 3 poorly sorted coarse sand (PCS); category 4, poorly sorted medium sand (PMS); category 5, moderately and moderately to well sorted fine sand (MWFS). Image is presented in color ................ 70 FIGURE 4.7 Outcrop analog with 0.25 m grid overlay. Image is presented in color. . .71 FIGURE 4.8 Matrix of vertical (z)—direction transition probabilities showing core data as measurements (open circles) and the Markov chain model (solid line) from the core measurements. The diagonal elements represent auto- transition probabilities within each category, and the off diagonal elements represent transition probabilities between categories ........................ 72 FIGURE 4.9 Matrix of perpendicular to flow (y)-direction transition probabilities showing core data as measurements (open circles) and the Markov chain model (solid line) from the core measurements. The diagonal elements represent auto-transition probabilities within each category, and the off diagonal elements represent transition probabilities between categories..76 FIGURE 4.10 A realization of the Schoolcrafi plume A site based on transition probability/ Markov chain geostatistics in two zones. This image is presented in color .................................................................. 79 FIGURE 4.11 A realization of the Schoolcrafi plume A site based on transition probability/ Markov chain geostatistics in two zones. This image is presented in color .................................................................. 80 FIGURE A.1 Location of delivery wells (D), monitoring wells (MW), peizometers (P) and other wells at the Schoolcraft plume A site. FIGURE A.2a Core descriptions of well P18. Vertical K measurements shown in second column .............................................................................. 93 FIGURE A.2b Core descriptions of well P18. Vertical K measurements shown in second column .............................................................................. 94 FIGURE A.2c Core descriptions of well P18. Vertical K measurements shown in second column .............................................................................. 95 FIGURE A.2d Core descriptions of well P18. Vertical K measurements shown in second column .............................................................................. 96 xii FIGURE A.2c Core descriptions of well P18. Vertical K measurements shown in second column .............................................................................. 97 FIGURE A.3a Core descriptions of well P6 ..................................................... 98 FIGURE A.3b Core descriptions of well P6 ..................................................... 99 FIGURE A.4a Core descriptions of well P7 ................................................... 100 FIGURE A.4b Core descriptions of well P7 ................................................... 101 FIGURE A.5a Core descriptions of well P8 ................................................... 102 FIGURE A.5b Core descriptions of well P8 ................................................... 103 FIGURE A.50 Core descriptions of well P8 ................................................... 104 FIGURE A.5d Core descriptions of well P8 ................................................... 105 FIGURE A.5e Core descriptions of well P8 ................................................... 106 FIGURE A.5f Core descriptions of well P8 ................................................... 107 FIGURE A.6a Core descriptions of well P9 ................................................... 108 FIGURE A.6b Core descriptions of well P9 ................................................... 109 FIGURE A.7a Core descriptions of well P11 .................................................. 110 FIGURE A.7b Core descriptions of well P11 .................................................. 111 FIGURE A.8a Core descriptions of well P12 .................................................. 112 FIGURE A.8b Core descriptions of well P12 .................................................. 113 FIGURE A.8c Core descriptions of well P12 .................................................. 114 FIGURE A.8d Core descriptions of well P12 .................................................. 115 FIGURE 3.1 Photomosaic of outcrop analog at Azon pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. Shovel for scale. Image is presented in color ............................... 124 xiii FIGURE 82 FIGURE 3.3 FIGURE B.4 FIGURE 3.5 FIGURE B.6 FIGURE B.7 Photomosaic of outcrop analog at Azon pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. Shovel for scale. Image is presented in color ............................... 125 Photomosaic of outcrop analog at Azon pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. All measurements are in centimeters and are shown by pink arrows. Image is presented in color ..................................................... 126 Photomosaic of outcrop analog at Stadler sand and gravel pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. Height of outcrop is approximately 12 meters. Image is presented in color ............................................................. 127 Photomosaic of outcrop analog at Stadler sand and gravel pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. Measurements are in centimeters and are shown by pink arrows. Bed numbers correspond to descriptions given in Table B.2. Image is presented in color .................................................... 128 Photomosaic of outcrop analog at Stadler sand and gravel pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. Measurements are in centimeters and are shown by pink arrows. Bed numbers correspond to descriptions given in Table B.3. Image is presented in color .................................................... 130 Photomosaic of outcrop analog at Stadler sand and gravel pit. Yellow lines represent bounding surfaces. Thinner lines represent lower order bounding surfaces. Measurements are in centimeters and are shown by pink arrows. Bed numbers correspond to descriptions given in Table B.4. Image is presented in color .................................................... 132 xiv Chapter One Introduction and Scope of Work Introduction Inaccurate characterizations of aquifer heterogeneity commonly result in simulations of groundwater flow and contaminant transport that are inadequate to fully understand the migration of contaminant plumes. The need to more accurately simulate the migration of fluids has led to better heterogeneity characterization approaches in aquifers through incorporation of more geologic information. Koltermann and Gorelick (1996) stated that in order to accurately model and predict containment transport, we must be able to predict the spatial variability of hydraulic properties. Many studies e. g Borden (Sudicky, 1986); Cape Cod (Hess et al., 1991); Twin Lake (Moltyaner and Killey, 1998; MADE site (Adams and Gelhar, 1992; Boggs er al., 1992; Renfeldt et al., 1992) have shown that the resolution of acquired data necessary for predicting solute transport cannot be achieved by standard subsurface investigation techniques such as pumping tests, flow meter measurements or core analysis. Klingbeil et al. (1999) stated that aquifer stress tests by pumping yield parameters at a scale much larger than the typical length of structures in a heterogeneous aquifer. When characterizing an aquifer, focus should be placed on fine scale geologic properties rather than on larger scale hydraulic responses of the wells to accurately predict fluid flow and solute transport (Klingbeil et al., 1999). Weissmann and Fogg (1999) used the geology and stratigraphy as a framework for geostatical realizations in order to preserve stationarity. Most geologic information comes from boreholes. Core from boreholes can be described for geologic features, or core can be described using standard engineering geology techniques. Geophysical logs may also be used in boreholes to test resistivity, conductivity, porosity, density and other parameters. Although measurements that come from a borehole may yield enough detailed information to characterize heterogeneity in the vertical direction, the spacing between boreholes is generally too great to yield sufficient information on the heterogeneity in the horizontal direction. One approach to increasing lateral geologic information is studying an outcrop composed of similar stratigraphy and similar lithologies as the aquifer of interest. This outcrop may be viewed as an analog to the aquifer (“outcrop analog”). Miall, (1985), used outcrop analogs to interpret facies architecture in fluvial settings, however using them as a characterization tool of the subsurface to create a geologic based characterization of an aquifer or reservoir is a relatively new idea. Many recent researchers have used outcrop analogs as an aid to subsurface characterization of aquifers and reservoirs (Davis et al., 1993; Davis et al., 1997; Robinson and McCabe, 1997 ; Anderson et al., 1999; Bersezio et al., 1999; Klingbeil et al., 1999; and Hornung and Aigner, 1999). Anderson et a1. (1999) quantified the spatial distribution of hydrofacies in braided stream deposits using two approaches 1) a small scale outcrop analog and 2) a large scale model of a medial braided stream deposit. In both approaches, three-dimensional images showing interconnectedness of high K units were used as inputs to a groundwater flow model and flow paths were analyzed by following the transport of particles. They found that particles that were uniformly distributed at the up gradient end of the model were clustered along preferential flow paths during transport, showing that connection among high permeability facies is a critical factor in hydrogeological investigations involving solute transport. Bersezio et al. (1999) found strong anisotropic behavior in two-dimensional groundwater models based on an outcrop analog exposure in a delta environment, which was attributed to the layering of sedimentologic units. Davis et al. (1993) suggested that architectural elements may provide a role in evaluating aquifer heterogeneity at the scale of meters. Davis et al. (1997) used three different meter scale outcrops to demonstrate that fluvial bounding surfaces provide a good geological basis for conceptualizing and modeling heterogeneity in alluvial deposits. Klingbeil et al. (1999) defined 5 hydrofacies from 23 lithofacies at an outcrop analog composed primarily of gravel. These hydrofacies were to be used in subsequent hydrogeological analysis. Homung and Aigner (1999) characterized an aquifer using fluvial architectural elements (Miall, 1985, 1996) on a large alluvial plain outcrop analog. Nine architectural elements were recognized in their study, and information collected in this study provided a database for subsequent fluid flow simulations. Robinson and McCabe (1997) measured geometries of sand and shale bodies in a braided fluvial environment, generated a three-dimensional stratigraphic model of the reservoir, and simulated flow through the model. They found that flood deposits affected flow in the simulation by having sufficient thickness and lateral extent to compartmentalize reservoir flow units and increase vertical flow tortuosity. Purpose of the study The purpose of this study was to apply stratigraphic methods of aquifer characterization of Weissmann and Fogg (1999) to a smaller scale in a glacial outwash setting. This method uses stratigraphic breaks identified in core to define zones of similar deposits and model heterogeneity within the stratigraphic framework. This is important because it provides a framework to better honor the stationary assumption. The mean and standard deviation of the zones is more spatially consistent within the zones than in the entire aquifer. This method also better preserves abrupt changes in K that would commonly be smoothed with traditional geostatistics. This method was implemented at the Schoolcraft Plume A site, located in the village of Schoolcrafl southwest of Kalamazoo in Kalamazoo County, Michigan. The Schoolcrafi Plume A site is located in a 27 m thick sand and gravel aquifer that overlies a regional till layer that acts as an aquitard, with a water table at 4.5 m below ground surface. Seven contaminant plumes (A-G) have been identified in the Schoolcrafi area. The focus of this project is a transect across the down gradient end of plume A, at the site of the Schoolcraft bioaugrnentation project (Hyndman et al. , 2000; Dybas et al., 2002). Plume A is roughly 1.2 km long and 90 m wide, and extends from 8 to 26.5 m below ground surface (Hyndman et al., 2000). This study site was selected for this project for the following reasons: 1) much closely spaced core data is available, 2) hydrologic and injected tracer test measurements exist for the site, 3) it is a site of ongoing groundwater investigation, and 4) detailed characterization approaches are needed to improve previous groundwater flow models and transport simulations. The main approach used to characterize aquifer heterogeneity at the Schoolcraft site was zonal kriging, which is a method where the aquifer parameters are kriged within zones of similar geology. The mean and standard deviation of K is more spatially consistent within each zone, thereby better honoring the stationarity assumption. To test the effects of zonal kriging, a non-zonal krige distribution of K was estimated using the same conditioning data but without dividing the data into stratigraphically based zones. Transition probability geostatistics was used as another method to characterize the heterogeneity. Both the zonal krige and the transition probability geostatistics methods were used within a stratigraphic framework provided by core descriptions, with lateral correlation lengths supplemented by measured data from outcrop analogs. Stratigraphic breaks in core identifying major bounding surfaces were used to define stratigraphic zones used in zonal kriging. To test the hypothesis that a better aquifer characterization would lead to a better tracer test comparison, both the zonal and non-zonal kriged aquifer characterizations were used as inputs to groundwater flow models and tracer test simulations. A closer match of the simulated tracer to the measured tracer breakthrough fiom field tracer tests indicates a positive test of the hypothesis. Running tracer simulations through the transition probability geostatistics results was beyond the scope of this thesis. Thesis outline This document is divided into four main sections with subsequent appendices: I The first section, covered by chapter two, describes the bedrock and glacial geology of the study region. A brief review is given of previous hydrological studies in Kalamazoo County, specifically in the Schoolcrafi Aquifer, and the history of contamination and bioremediation of Plume A. I The second section, covered by chapter three, presents an approach to incorporate geostatistical estimation into a stratigraphic framework utilizing zonal kriging to better represent aquifer characterization. Using a hi gh- resolution three-dimensional flow model and transport simulation, simulation of an injected tracer pulse was improved. This chapter forms a manuscript that has been submitted for publication (Biteman, et al. submitted). The third section, covered by chapter four, applies a transition probability / Markov chain approach in a stratigraphic framework to simulate the distribution of K. The stratigraphy provides a framework in which the K distribution can be simulated while better honoring the stationarity assumption. The fourth section, covered by chapter five, reviews the overall conclusions of the work conducted for this thesis. Subsequent appendices are attached and list core descriptions, outcrop analog photomosaics and descriptions, and data tables that were used / collected in this study. Chapter 2 Previous Work Geology Regional Bedrock Geology Kalamazoo County overlies the southwestern rim of the Michigan basin. The Michigan Basin is nearly 5 km deep with a radius of approximately 250 km (Howell and van der Pluijm, 1990). The Michigan Basin reveals a number of subsidence reactivations and cessations (Sleep and $1033, 1978). Howell and van der Pluijm (1999) cite evidence to support their theory that episodes of different types of subsidence occurred from the Cambrian to Pennsylvanian to form the Michigan Basin. The Mississippian Marshall Formation subcrops in the most northeastern comer of Kalamazoo County and the Mississippian Coldwater Shale Formation subcrops over the remainder of Kalamazoo County (figure 2.1) (Forstat and Sorensen, 1982). In the early Mississippian, the Coldwater Shale was deposited as a fine grained mud in an off shore environment and at the close of the early Mississippian, a reduction of the seas caused much of southern Michigan to become a beach environment (Dorr and Eschman, 1970). The Marshall Formation was deposited at this time and is composed of the Marshall Sandstone and Napoleon Sandstone. The Coldwater Shale is blue-gray in color and contains small amounts of limestone, dolomite, siltstone and sandstone (Martin, 1957). The bedrock which subcrops under Schoolcraft consists of a limestone facies of the Coldwater Shale. The surface of the limestone slopes gently towards the northwest (Mayotte, 1991 ). ..28 c. 8.88... m. 8%. NS. 5.92.5. 59. 858.2 .xomfi :. 85.50 m. 2560 83.5.3. €3.55. .0 385:9". 826.. on. .0 one xoofiom .FN 659". 9.9.0 3.3m I 9.90 9.6.2 wmmm I games". 28.2 c6990 I 5.89:0“. ocmE m.om I c.0065 85.8.2 I ocofiocmw m.cm>.>m I 9.2.0 82m .650 I ocofioE... mousse U 6.2m :3. I 9.90 6299... I aficw E...E< I 295 ..toBflm I 6.95 2058 I ...w 2058 new mm mobm I 99% 23:5 I 2.2m 5.96.00 I 8.885“. ..m52m2 I 5:950“. 595.... a 6:288... togmm I cozmctou 393mm I coszBH. 52$ 9.96 ! moon com. I 232.com $25.. .0 .6280 sootuom Glacial History of Southwestern Michigan With the exception of recent alluvial deposits, the sediments that overlie bedrock in Kalamazoo County were deposited in the last glacial episode, the late Wisconsinan, as the Laurentide Ice Sheet retreated. Researchers believe that both the Saginaw and Michigan Lobes of the Laurentide Ice Sheet contributed to surfical deposits in Kalamazoo County (Monahan and Larson, 1982; Monahan et al., 1986; Monahan and Larson, 1986; F inkbeiner, 1994). Finkbeiner (1994) stated that the county is located within a reentrant between the Lake Michigan Lobe and the Saginaw Lobe. Figure 2.2 shows the location of moraines in southwest Michigan and the extent of both the Saginaw and Lake Michigan Lobes. The prominent features of the Kalamazoo Moraine are the main reason that so many authors believe a significant retreat and readvance occurred before its formation (F inkbeiner, 1994). The presence of lacustrine sediments between the Ganges and Saugatuck Tills implies that a significant retreat of the Lake Michigan Lobe occurred between the formation of the Tekonsha Moraine and the Sturgis-Kalamazoo Morainic System (Monaghan et al., 1986). Monaghan et al. (1986) showed contrasting mineralogy of clays within different till units and concluded that the Saugatuck, Ganges and Glenn Shores tills are unlikely to represent till facies of the same advance. An east-west cross- section through southwestern Michigan summarizes the correlations of Moraine and underlying till unit as proposed by Monaghan et al. (1986) (Figure 2.3). Outwash deposited as meltwater from the glacier compose approximately two thirds of the surfical deposits in Kalamazoo County. Studies by Straw (1991) and Steinman (1994) presented descriptions of the outwash fans in Kalamazoo County. The \‘l \\ \‘8M 1 4//l\-.\ \ChM I I ‘ I -. \ \ \ , ; +41 — County border ‘3‘ ,’ I ./ — Moraines a g“ $ ,1 I _/ —--- Intenobate boundary 0 ‘ I / 4 0 ¢/ / ' I b N g 1' 210 \+ +9 / o m' 15 as a!“ “7?" Lake Michigan Lobe Moraines Saginaw Lobe Moraines LBM- Lake Boarder Moraine LaM- Lansing Moraine lVM- Inner Valpraiso Moraine ChM- Charlotte Moraine OVM- Outer Valpraiso Moraine KM- Kalamazoo Moraine IKM- Inner Kalamazoo Moraine TkM- Tekonska Moraine OKM- Outer Kalamazoo Moraine StM- Sturgis Moraine TkM- Tekonsha Moraine Figure 2.2. Location of Moraines in southwestern Michigan. Notice the interlobate boundary marking the extent of both the Saginaw and Lake Michigan lobes. Kalamazoo County is marked by a bold outline. Modified from Monaghan et al., 1986. 10 Figure 2.3. Till sheets underlying moraines in southwestern Michigan. Modified from Monaghan et al., 1986. 11 city of Schoolcraft lies within the Prairie Rhonde Fan, described by Steinman (1994). The Prairie Rhone Fan was deposited when meltwater and outwash broke through a narrow breach in the Kalamazoo Moraine near Paw Paw Lake and deposited the material from braided streams throughout Prairie Rhonde and Schoolcrafi Townships Steinman (1994) (Figure 2.4). General Stratigraphy and Sedimentology of Glaciofluvial Deposits Streams that are fed from glacial meltwater carry enormous quantities of detrital sediment, most of which is deposited in broad alluvial plains called sandar or sandurs (Icelandic: “sand plains”, singular sandur) (Smith, 1985). Two different kinds of sandur were recognized by Kingstrom (1962) — valley sandar and plain sandur. Valley sandur occur within well defined valley walls, are usually formed by one main channel and are commonly associated with individual cirque or valley glaciers. In North America, valley sandur are called valley trains. Plain sandar are broad and unconfined when compared to valley sandar; they are formed by the coalescence of many braided streams that deposit sediment to form extensive alluvial plains. They are usually associated with large ice sheets and are common features of the Pleistocene landscape of North America (Smith, 1985). Plain sandur are commonly called outwash plains. Krigstrom (1962) recognized three rather distinct zones of sandar related to distance from the ice margin, 1) proximal, 2) intermediate and 3) distal. Meltwater flow in the proximal zone is confined to only a few main channels that are relatively deep and narrow. Incision of proximal channels into alluvium is common and is likely a result of slope adjustment to a normal hydraulic and sediment-load regimen. The intermediate 12 odi"""'—. c‘.’ ..... 's g N e ‘. U \ ‘\ \ e \y ‘. . \ ‘. o u I \ ‘\ D \ \ n ‘ e : \ \ , | ‘s .‘ .0 “Q\ ! ‘5 \ I ‘~ 3 ’\ \ ~.‘\ \ , \ “x‘ \' \ a: \ s‘~~. \ \ \“ \ ‘4“ I \ i ‘3‘ \ ‘x I ' ‘ l 11}, J 1 \ ‘. \ Schoolcraft ‘y Kalamazoo County E“ St. Joesph County i Stream/river/wetland/lake ------ Boundary of Baresse's study area ----------------- Boundary of Steimann’s study area Figure 2.4. Study areas of Steinmann (1994) and Baresse (1991). Boundary of Prarie Rhonde Fan as described by Steinmann, maked by Steinmann’s study area. Modified from Baresse, 1991 and Steinmann, 1994. 13 zone is characterized by networks of wide, shallow distinct channels that shift frequently. Abandoned channels are prominent during normal discharge. In the distal zone, channels become shallower and poorly defined. At periods of high discharge, flow may merge into a single sheet. The streams responsible for sandur are typically braided (Benn and Evans 1998). Braided streams are characterized by high width to depth ratios, steep slopes, abundant bedload, cohesionless banks, fluctuating discharge and generally low sinuosities (Benn and Evans, 1998; Miall, 1977). At least nine variables interact to determine the nature of the resulting braided stream channel: 1) discharge amount, 2) discharge variability, 3) sediment load, 4) grain size of sediment load, 5) width, 6) depth, 7) velocity, 8) slope and 9) bed roughness (Leopold and Wohnan 1957). Braiding is developed by sorting action as a stream leaves behind particle sizes that it is unable to transport. Deposition of the coarser bed load causes mid-channel bars to form (Boggs, 1987). Repeated bar formation and channel branching generate a braided network of bars and channels over the stream bed (Leopold and Wohnan 1957). There are three main bar types found in braided stream systems 1) longitudinal, comprising crudely bedded gravel sheets, 2) transverse to linguoid, consisting of sand or gravel and formed by downstream avalanche-face progradation and 3) point or side bars, formed by bedform coalescence and chute and swale development in areas of low energy (Miall, 1977). Longitudinal bars are mid-channel bars that form when the coarsest part of the stream load is deposited as stream flow wanes (Boggs, 1987). They are diamond shaped in plan view with the long axis in the parallel to flow direction. They are bounded on either side by active channels and may therefore have partially eroded margins. Bars 14 formed in gravel are most common, although some sand bars show similar morphology (Miall, 1977). The internal structure in longitudinal bars is weak horizontal bedding commonly with imbrication (Miall, 1996). Common in sandy streams transverse and linguiod bars are also called 2-D and 3-D dunes, respectively. 2-D dunes are formed under lower flow velocities than 3-D dunes for any grain size (Ashley, 1990). The internal structure in 2-D dunes is characterized by planar tabular cross-bedding while the internal structure of 3-D dunes is characterized by trough cross-bedding (Ashley, 1990). Point and side bars are genetically the same as lateral bars, they form in areas of low energy, such as the inside of a meander (Miall, 1977). Although point bars are usually thought to occur in meandering streams, they may also occur in braided streams (Miall, 1977). The internal structure in lateral, point and side bars is complex, and may include planar-tabular cross-bedding, trough cross-bedding, ripple cross-lamination, coarse- grained lag deposits, and fine-grained drape and fill deposits (Miall, 1977). Figure 2.5 shows the location and geometries of bars within braided streams. Miall (1977) proposed four vertical models that can develop under varying conditions of bedload and discharge, these are 1) Scott-type, 2) Donjeck-type, 3) Platte type and 4) Bijou Creek-type (Figure 2.6 and 2.7). The Scott-type is characteristic of proximal, gravelly rivers and consists of mainly longitudinal bars gravels with sand lenses formed by infill of channels and scours during low water (Miall, 1977). The Donj eck-type, characteristic of medial streams, may be dominated by either sand or gravel, and consists of fining upward cycles of variable scale. Longitudinal-bar deposits, linguoid-bar deposits, channel-floor dune deposits, bar-top and overbank deposits all may be important (Miall, 1977). The Platte-type model, representative of distal streams, is 15 0 50M 0 500M o 1000" i | L_.___..J L.___l Bartypes Lo longitudinal bars D longitudinal with diaginal flow R eroded bar remnant Li linguoid M modified linguiod P point S side Figure 2.5. Principal bar types and where they form in a stream. Modified from Miall, 1977. Scott-type Donjeck-type Platte-type Bijou Creek-type . .. :43?» . f, raga ' fir "- ' l 0 c. 9 I'- was! raw, 1’?! 2'1 ‘ r "3) I Figure 2.6. Vertical facies models of Scott-type, Donjeck—type, Platte-type and Bijou Creek-type. Modified from Miall, 1977; 1996. Figure 2.7. Block diagrams showing the braided stream patterns associated with Scott- type streams (A), Donjeck-type streams (B), and Platte type Streams (C). Modified from Miall, 1985. 18 characterized by linguoid and transverse bars that generate largely cross-bedded, sandy deposits (Miall, 1977). There is no well developed cyclicity, although some fining upward sequences may be identified (Boggs, 1987). Bijou Creek-type deposits consist of horizontally laminated sand and a lesser amount of sand showing planar cross-bedding and ripple cross-lamination (Miall, 197 7). Deposits are formed during flash flood, and each flood event is represented by a fining upward sequence (Miall, 1977). There is no absolute indicator that can be used to estimate proximity to source in braided stream environments (Miall, 1977). However, grain size is one of the best parameters that shows downstream variation. Thus, grain size is useful in measuring proximity (Miall, 1977). Mean and maximum grain size tend to decrease down stream at a rate that varies depending on stream power (Miall, 1977). Smith (1985) stated that grain size tends to decrease down-sandar in an approximately exponential way, but, the rate of diminution varies significantly between sandar. Smith (1985) suggested that this is probably a reflection of different aggradation rates. The coarsest gravel in the system is moved infrequently and only for short distances, during high energy flows, whereas finer grained material can be transported progressively farther during any time or flow event. If a stream is degrading, little or no downstream fining occurs because sediments that enter the system must leave it (Smith, 1985). If a stream is aggrading, the coarse sediments will be buried before they are transported far. Thus the faster they are buried (i.e. the higher the rate of aggradation), the shorter their final distance can be, resulting in a downstream-fining gradient proportional to the aggradation rate (Norman, 1985). 19 Hydrogeology Regional Hydrogeology Groundwater studies have been conducted within the Kalamazoo outwash plain by Barrese (1991), Steinmann (1994), with subsequent results presented by Kehew et al. (1996), Hyndman et al. (2000) and Lipinski (2002). Barrese (1991) divided the Schoolcraft Aquifer, into two flow systems based on geochemical results. A northern flow system located north of the Spring Creek-Government Marsh and a southern flow system located south of the Spring Creek-Government Marsh (figure 2.4). Barrese (1991) defined the Schoolcraft aquifer as ranging in saturated thickness fi'om 230 feet to 200 feet, the base of the aquifer is defined as the top of the Coldwater Shale. He stated that the aquifer is composed of sand, gravel and diarnicton. Three aquifer stress tests by pumping conducted near the village of Schoolcraft yielded calculated hydraulic conductivity (K) values ranging fi'om 3.6 x10'2 cm/s to 5.2 x 10'2 cm/s (Barrese, 1991). Maps of groundwater elevation near the village of Schoolcraft show groundwater flowing generally southeast. Steinmann (1994) used newly installed monitoring wells, county well logs, gamma ray logs, head measurements, flow nets, slug tests, and aquifer stress tests by pumping to characterize the geologic and hydrologic conditions of the aquifer below Schoolcraft. Steinmann’s study area was similar to Barrese’s (1991) (figure 2.4). Steinmann (1994) used tritium data and flow nets to support the conclusion of two separate ground water flow systems, where horizontal flow dominates the region with the exception of limited recharge and discharge areas. K values were calculated from three aquifer stress tests by pumping conducted near the village of Schoolcraft. Calculated K 20 values are 3.8 x 10'2 cm/s, 3.9 x 10'2 curls and 5.0 x 10'2 cnr/s based on estimated saturated thicknesses of 152.5 feet, 168 feet, and 130 feet respectively. Steinmann (1994) stated that the regional gradient ranges from 0.0022 to 0.0012, depending on location within the Prairie Rhonde fan. Groundwater flow direction is down fan or southeast. Kehew et al. (1996) published much of Barrese (1991) and Steinmann (1994) results, focusing on the area within the Prairie Rhonde fan. Hyndman et al. (2000) studied a small area within the Schoolcraft Aquifer where they developed a bioremediation system that degrades carbon tetrachloride, discussed in more depth below. Small scale groundwater and transport models were developed to predict the migration of tracer. This aquifer is composed of 27 meters of glaciofluvial sediment overlying a regional clay layer with a water table at approximately 4.5 m below ground surface (bgs). 220 core segments fiom 7 wells were analyzed for K. The average K value was approximately 2.7 x 10'2 cm/s and a log (K) variance of 0.12, highest K values are at the base of the aquifer. The gradient is 0.0011 and flow is to the southeast. Lipinski (2002) built a regional scale model with boundaries based primarily on surface water bodies in the vicinity of Schoolcraft, Michigan (figure 2.8). In this model, Lipinski (2002) used regional geological studies to build a three layer model 60 to 90 m thick. Two layers representing outwash were separated by a third layer that represented a discontinuous till. K values used in this model were taken from previous studies. Lipinski (2002) also constructed a smaller scale groundwater model and reactive transport simulation around plume G based on head results from the regional model (figure 2.8). This model was approximately 27 meters thick and represented the upper unit of outwash. A clay layer at the base of the aquifer marks the bottom of the model. 21 ‘J ‘I—QJ . t/ Schoolcraft '! ; i /\d C l U}: " /\/ Roads N Rivers/Streams Moraine , "x I Drain % Wetland lllllllllllllllll Lake 0 4 5.25555 km Figure 2.8. Study area of Lipinski (2002) regional model. Lipinski’s smaller scale transport model is outlined by the bold rectangle near Schoolcraft. Modified from Lipinski, 2002. 22 The gradient of the water table is approximately 0.0012 near Schoolcraft and flow is to the southeast. History of Contamination at Plume A A history of the contamination source at plume A, located in Schoolcraft, Michigan, is given by Mayotte (1991) and is briefly described here. In 1986, significant concentrations of carbon tetrachloride and trichloroethene were detected in ground water quality samples obtained from residential wells just outside the village of Schoolcraft. Water quality data reveled that the contamination most likely originated at the Countyka Incorporated facility (Mayotte, 1991). The data also indicate that chloroform and 1,1,1-trichloroethane are minor constituents of the pltune. At the date of Mayotte’s report, the plume was known to extend 1128 m down gradient of the Countrymark property and was present throughout most of the saturated thickness of the aquifer. Mayotte (1991) reported that evidence obtained by the Michigan Department of Natural Resources indicates that carbon tetrachloride was used as a fire retardant, as a transport agent for carbon disulfide, and as an insecticide applied to grain silos on the Countrymark property. It is believed that carbon tetrachloride and other solvents were stored in bulk in above ground storage tanks located near the silos. Throughout the history of the facility, contaminants leaked from the silos and/or storage tanks and infiltrated the vadose zone and the ground water (Mayotte, 1991). 23 Bioremediation of Plume A Bioremediation studies at Plume A focused on the design and implementation of a delivery well system for bioaugrnentation (Hyndman et al., 2000; Dybas et al., 2002). Bioaugrnentation is a process that involves the addition of microbes and the necessary nutrients to sustain them in an aquifer. The researchers designed a system where water was allowed to flow passively through a treatment zone, or biocurtain, where injected bacteria attach to the sediments degrade carbon tetrachloride. A row of delivery wells spaced one-meter apart and screened across the vertical extent of contamination were installed. Ground water is periodically extracted from alternating delivery wells, amended with the chemicals needed to support bioremediation, and then the amended water is injected into adjacent wells. An intermittent feeding schedule maintains adequate biomass to efficiently remove contaminants without significant reduction to aquifer conductivity. This biocurtain has proven to be 97% effective (Hyndman, et al., 2000). To better understand the heterogeneity at the Schoolcraft plume A site, core from 11 wells were collected and either sieved, measured for K value on a constant head perrnearneter, described for sedimentologic features, or a combination of these. A firll scale field tracer test was conducted in November 1997, using Flourescein and Bromide as relatively conservative tracers to verify to the researchers that their selected pumping strategy would provide roughly the expected extraction well concentrations and to evaluate the fate of fluid pumped through the delivery well gallery (Hyndman et al., 2000). 24 Chapter 3 Integration of Sedimentologic and Hydrologic Properties for Improved Transport Simulations: Detailed Characterization of a Glacial Outwash Aquifer at the Schoolcraft Bioremediation Site, Michigan (Note: This chapter forms a manuscript that has been submitted to SEPM for publication and was authored by BI T EMAN, S.E., H YNDMAN, D. W., PHANIKUMAR, MS, and WEISSMAMV, G.S., Dept. of Geological Sciences, Michigan State University, East Lansing, MI, 48824) Abstract: Traditional geostatistical approaches for estimating hydraulic conductivity values fail to reflect sharp contrasts that occur at boundaries between different stratigraphic units, thus limiting the accuracy of contaminant transport models. We present a novel approach to incorporate geostatistical simulation into a stratigraphic framework to better represent aquifer heterogeneity. The approach was developed and tested at the Schoolcraft Bioremediation Site in Southwestern Michigan, where detailed aquifer property estimates were needed to accurately simulate multicomponent reactive transport and to design an effective bioremediation strategy. The sediments at the site were deposited as outwash medial and distal to the Kalamazoo Moraine, and consist of primarily fine to medium sands with interbedded gravels and silts. A series of l8-meter long continuous cores were collected in the vicinity of the 210 square meter biocurtain injection zone. These cores were assessed for sedimentologic character, grain size distribution, porosity, and hydraulic conductivity values. Sedirnentologic character and correlation lengths from outcrop analogs in the same outwash unit supplemented the 25 site’s core data. Based on the core data, the aquifer was separated into major sedimentologic units to preserve abrupt natural changes in conductivity, and the conductivity values were then geostatistically interpolated within each stratigraphic unit to better preserve stationarity. The stratigraphically-based conductivity and porosity estimates were used as inputs to a high-resolution three-dimensional flow and transport model of the region. The model with stratigraphic interpolation provided improved transport predictions for an injected tracer pulse. Introduction In recent years, the need to more accurately predict contaminant migration has focused efforts to develop novel aquifer characterization approaches, such as those that incorporate geological information. In the Northeastern and upper Midwestern United States, many aquifers for domestic and agricultural uses are composed of unconsolidated Quaternary glacial sediments. These aquifers have a high risk of point and non-point source contamination due to their generally unconfined nature. Glacial deposits typically have moderate to high levels of heterogeneity, which often complicates transport predictions within these environments. Contaminants follow subsurface preferential flow paths, such as paleo-river channels, flowing faster and in slightly different directions than the regional groundwater flow. Without an understanding of the depositional setting and the geometries of heterogeneities, an accurate characterization of the aquifer is unlikely. Since the distribution of sedimentologic heterogeneities is directly related to the distribution of hydraulic conductivity (K) and other aquifer properties, stratigraphic complexities should be incorporated into heterogeneity models. This concept has lead to 26 sedimentologic research for estimating the heterogeneity of hydrologic properties (e.g., Webb and Anderson, 1996; Carle et al., 1997; Davis et al., 1997). Traditional geostatistical methods that interpolate between hydrologic property estimates without considering stratigraphy commonly misrepresent a site’s geology by not honoring the stationarity assumption and smoothing the data rather than preserving abrupt conductivity changes (Weissmann and Fogg, 1999). The need to improve simulation of fluid and solute migration has led to characterization approaches in aquifers and petroleum reservoirs that incorporate more geologic information. Eschard et al. (1998) and Weissmann and Fogg (1999) used the geology and stratigraphy as a framework for geostatistical realizations in order to better preserve stationarity. While outcrop analogs have been used to interpret facies architecture (Miall, 1985), there is a renewed interest in such subsurface characterization tools to estimate aquifer hydrologic properties (Davis et al., 1997; Anderson et al., 1999; Bersezio et al., 1999; Homung and Aiger, 1999; Klingbeil et al., 1999). Facies distributions can be measured on outcrop analogs and can be applied to anisotropic variograms, as has been applied at a small scale by Davis et al. (1997) to interpret bounding surfaces. In this paper, we present a method to better characterize aquifer heterogeneity through separate geostatistical interpolation within zones of similar sedimentologic character. Within each zone, geologic information distinct to that zone was used to estimate the lateral correlation lengths. Each hydrostratigraphic zone was then kriged separately to estimate that zone’s K field. The different zonal conductivity estimates were then merged to create a single K field. By dividing the data into geologically based 27 zones of similar sedimentologic character, where the mean and standard deviation of K are distinct from other zones, stationarity is much more likely to be honored. Additionally, K values are estimated (kriged) separately by zone, thereby preserving the natural abrupt changes in K across bounding surfaces. Core from the site yielded stratigraphic and sedimentologic data that was used to identify zones. In addition, core material was used to measure horizontal and vertical K values using constant head permeameters, with dense vertical information but relatively sparse horizontal information. To supplement the common lack of information to accurately estimate the horizontal correlation parameters, measurements from outcrop analogs were used to evaluate K distributions, facies distributions, and width to thickness ratios. Our results show that the transport simulations based on the stratigraphically-based model more closely match measured tracer concentrations at the site. Site Description The Schoolcraft site is composed of glaciofluvial sands and gravels that were deposited as water drained away from a retreating ice margin. The ice margin later stagnated long enough for sediments to accumulate and form the Kalamazoo Moraine. The moraine, located west of Kalamazoo, was deposited in the last glacial episode (late Wisconsinan), and trends northeast-southwest (Figure 1). The glaciofluvial sediments are coarsest near the glacier where braided rivers had the highest energy as they flowed southeastward away from the ice margin. The energy of the rivers decreased with distance from the ice margin. Thus the further the glacier retreated, the finer the sediments that were deposited at any location. Subsurface sediments at the Schoolcraft 28 Kalamazoo County Surfical Geology 1:] Kalamazoo River Climax-Scott Kalamazoo Moraine . Schoolcraft Figure 3.1. Kalamazoo County Surficial Geology, location of Kalamazoo Moraine and outcrop site used for this study. Modified from Monaghan and Larson, (1982). 29 site are composed of gravels at the base of the aquifer, fining upward to medium and fine sands with some interbedded very fine silty sands. This is the typical fining outward and upward succession present in glacial outwash systems, as described by Miall (1977). The Schoolcraft Plume A study site is located within an unconfined aquifer composed of a 27.5 m thick sequence of glaciofluvial sediments that lie directly over a regional clay-rich till that acts as an aquitard in Schoolcraft, Michigan. Plume A is the location of a carbon tetrachloride (CT) bioaugrnentation experiment, where microbes and substrate were injected to degrade aqueous and sorbed phase contaminants (Figure 2) (Hyndman et al., 2000; Dybas et al., 2002). The contaminant plume is about 1.2 km long and 90 m wide, extending from roughly 8 to 26.5 m below ground surface (bgs), with CT concentrations from 5 to 150 parts per billion (ppb). The water table at this site lies at roughly 4.5 m bgs. The Schoolcraft site was chosen for this study because a large existing database is available that includes core descriptions, K measurements from many wells, and many measured concentration histories collected during tracer tests. The bioaugrnentation system at this site was designed as a series of closely spaced recirculation wells for delivery of microbes and nutrients. The spacing and flow rates were chosen by minimizing the total design and operation cost using a flow and transport model coupled to an optimization routine (Hyndman, et al. 2000). A portion of the contaminant plume flows passively into the treatment zone or “biocurtain,” where microbes degrade the CT. Groundwater is periodically extracted from alternating delivery wells, amended with the chemicals needed to support bioremediation, and then injected into adjacent wells. An intermittent feeding schedule maintains adequate biomass to efficiently remove contaminants without significantly reducing the aquifer 30 Location of biocurtain the q“. WL '“Vfi'IWI' F‘Jrr —. L-w’te___-_ m Mt‘r ' , nil l" l :- ,fi- 0 1 000 r l r SCALE IN FEET 1" =1000' Figure 3.2. Schoolcraft Plume A site. Location of biocurtian is marked by arrow. Modified from Mayotte (1991). 31 conductivity. This biocurtain has proven to be greater than 97 % effective at removing aqueous phase contaminants (Hyndman, et al., 2000), and effective at removing sorbed phase CT in the biocurtain region over greater than 4 years of operation (Dybas et al., 2002) Core Descriptions Methods We evaluated core from seven of the 15 delivery wells in the biocurtain (D2, D4, D6, D8, D10, D12 and D14), spaced 2m apart in a transect perpendicular to flow, and from wells P6, P7 P8, and P18, located approximately 2-3 m downgradient of the biocurtain (see Figure 3). These cores were collected in 1.5 m sections using the Waterloo continuous core sampler that advances a core barrel ahead of an auger string. A vacuum sealed core liner minimized sediment loss. Sediment from each core except well P18 was sieved for grain size distribution, repacked to its original volume, flushed with carbon dioxide, and tested for K values on a constant head perrneameter. For this study we assumed that these repacked K values were representative of local horizontal K. Core segments from P18 were cut into 15.2 cm sections, flushed with carbon dioxide, saturated with water from below over a 4-8 hour period, and then tested for vertical hydraulic conductivity values using a constant head permeameter. Each core segment was weighed while saturated, photographed and described for sedimentologic characteristics, dried and reweighed to estimate porosity, then sieved for the grain size distribution. Additionally, core from wells P6, P7, P8, and P18 were described for geologic properties including grain size, sorting and stratigraphic bedding character and grain size trends. Vertical K values were measured from P18. To obtain horizontal K, vertical K to 32 ground water “Erection N ms . ' 014 D13 I MW11 , e 012 . I . . 011 ' o1o ' [)9 I MW13 . P18 ' . e 08 0 P8 ' . I . , D7 MW1o. . - 0 06 0 P7 D5 I MW12 . p5 . e D4 ' . . 03 I . O o 0 D2 01 I . ' “1m IKdata O K and strat data e monitoring well 0 ootherwells -:| 0m 2m Figure 3.3. Location of delivery wells (D) and monitoring wells (MW) at the Plume A Schoolcraft site. 33 horizontal K anisotropy factors were applied to the vertical K values. The average K anisotropy factor of each zone was calculated as the ratio of the average vertical K values from undisturbed vertical core samples (well P18) to average horizontal K (assumed equivalent to the repacked K from D2 to D14 samples). The values were 0.72, 0.81, 0.73, 0.75, for zones 1 to 4 respectively, the average across all the zones was 0.74 (Table 3.1). Corefacies interpretation Six facies were interpreted from the core: 1) massively bedded to finely laminated very fine sand, 2) massively bedded medium to coarse sand, 3) massively bedded fine sand, 4) cross-stratified fine sand, 5) cross-stratified medium to coarse sand and 6) cross- stratified gravel. The massively bedded to finely laminated very fine sand facies is moderately well sorted with a high abundance (16%) of silt and clay. Grain sizes for this facies ranged from medium sand to clay. Vertical K was only measured on one sample from this facies due to lack of available material, with a measured value of 1.45 x10"3 cm/s (Table 3.2). The massively bedded medium to coarse sand facies is well, moderately-well or poorly sorted. Vertical K values range from 1.14x10'2 to 1.82x10'2 crn/s in the poorly sorted samples. Vertical K was only measured on one well sorted sample and one moderately to well sorted sample; the values were 1.38 x10'2 cm/s and 2.40x10'2 cm/s The massively bedded fine sand facies is well to moderately-well sorted, with coarse sand to silt grain sizes. Vertical K values in the well sorted sand range fi'om 8.62 x10’3 to 1.61x10'2 cm/s, while vertical K values in the moderately to well sorted fine sand respectively (Table 3.2). Grain size for this facies ranged from pebbles to very fine 34 vertical to horizontal zone four 1.25 zone three 1.27 zone two 1.19 zone one 1.28 average 1.26 Table 3.1. Anisotropy values for vertical K and horizontal K, determined by comparing repacked to non-repacked core. O>Tl I11 Table 3.2. Vertical K (cm/s) of facies vs. sorting from well P18. SORTI NG well "Highly moderately poorly very poorly low 1.14E-02 lMassl I"? 'y everege 1385-02 2405-02 1575-02 medium and high 1.825-02 coarse sand no. or maples 1 1 3 low 8.62503 4.35503 363::ny average 1.23502 1.01502 fine sand high 1.61502 1.62502 no. of samples 5 1 1 low Exam average 1455-03 very fine sand Nah no. 01 san'oles 1 low 2.625-02 Cross stratified avenge 1.785-02 3.85E-02 3.50503 medium and high 5.085-02 coarse sand no. or We: 1 2 1 low 2.84503 3.28503 1.50503 Cross stratified average 6.67503 4.46503 7.20503 3.62503 fine sand nigh 1.25502 5.00503 5.36503 no. 0! samples 7 3 1 4 low Cross stratified average 2.40E-02 gravel high no. 01 sanples 1 35 sands. range from 4.35x10'3 to 1.62x10'2 cm/s. Generally, the better sorted the massively bedded fine sand, the greater the K value (Table 3.2). The cross—stratifiedfine sand facies is well to poorly sorted, and vertical K values generally increased with better sorting (Table 3.2). Grain sizes for this facies ranged from pebbles to silt. Vertical K values of the well sorted fine sand ranged from 2.84x10'3 to 1.25x10’2 cm/s. Vertical K values of the moderately well sorted fine sand ranged from 3.28x10'3 to 5.00x10'3 cm/s. The moderately sorted sand had a vertical K value of 7.20x10'3 cm/s and the poorly sorted fine sand had a vertical K value of 3.50x10 ’3 cm/s. Cross-stratified medium to coarse sand facies is moderately, poorly or very poorly sorted. Grain size for this facies ranged from pebbles to very fine sand. Moderately sorted medium to coarse sand had a vertical K value of 1.78x10'2 cm/s. Cross-stratified medium to coarse sand with poor sorting had vertical K values of 2.62x10’2 and 5.08x10'2 crn/s. The very poorly sorted medium to coarse sand had a vertical K value of 3.50x10'3 m/s (Table 3.2). The cross-stratified gravel facies is very poorly sorted with a vertical K value of 2.40x 10'2 cm/s (Table 3.2). Grain size for this facies ranged from pebbles to very fine sand. The massively bedded to finely laminated veryfine sand facies was interpreted as abandoned channel fill, commonly found in distal outwash facies (Donj eck and Platte type, as described by Miall, 1977). All other massively bedded sand facies were interpreted as having been deposited during high discharge when flow becomes less channelized and forms a large sheet. It is also possible that the stratification is too subtle to be identified at the core scale, or core collection disturbed the subtle cross- 36 stratification. All cross-stratified facies were interpreted as channel bar deposits in a braided stream environment. In all facies, a larger grain sizes indicate either greater stream energy and/or a more proximal location of the glacier. Schoolcraft Stratigraphic Evaluation Three stratigraphic breaks were identified in the cores, which provided a framework of four zones for K interpolation (Figure 3.4). Stratigraphic breaks were identified in cores as one or more of the following: 1) an erosional surface, 2) abrupt changes in mean grain size and 3) abrupt changes in sedimentary structures. Additionally, the same four zones were apparent in the measured K distribution: zone 1 — a high K zone at the base of the section (Kmmge= 5.44 x 10'2 cm/s), zone 2 - a small low K unit (14.,ng 1.56 x 10'2 cm/s), zone 3 — a medium high K unit (lemme: 3.2 x 10'2 cm/s) and zone 4 — a medium low K unit (Kevmge: 1.38 x 10'2 cm/s) at the top of the section (Figure 5). Table 3.3 lists the statistics of K values for each zone. Zone 1 (21-27.4 m bgs) is located at the base of the aquifer and is generally composed of the cross-stratified gravel, cross-stratified coarse sand and cross-stratified medium to coarse sand facies. Zone 2 (21-20 m bgs) is composed of massively bedded fine sand facies and finely laminated very fine sand facies. The very fine sand facies comprises a low K area that was identified within this zone in three delivery wells (D8, D10 and D12) and in three down-gradient wells (PS, P7 and P18). Zone 3 (16-20 m bgs) is composed of massively bedded fine sand facies and the massively bedded medium to coarse sand facies. Zone 4 (16-8 m bgs) consists of the cross-stratifiedfine sand facies with cross-stratified medium to coarse sand facies at the erosional base of the zone. Pilot 37 Grain Sizel K cmlsec Grain Size K cmlsec 3 NN 13 30.10101 5 3 Ehaaggi a 5 Elwfi'fi macaw-new: (DC/JQN'v-‘éo'v' ii . S 14‘13 ‘ :3 3: 0 ml Sm o 15"” - '5 ° 0 g N 17- , ° g o Sm ° :4 22 - ° last core ‘5. a , e D - a / 184 “ Figure 3.4. Core description of P1 8 showing zonal boundaries (marked by arrows) and measured vertical K. 38 A 8— - 4- DZ D4 D6 D10 D12 D14 1 10* 12* a U 3. m 5;; a “51' 3 G33?) m E” E5952). 3 ”Or-3:1?) O“ 16 18* .lir @ J 20 C -=O J 9 22 * 21.. .7- 1n- ‘5' 24* 21 23 25 27 29 31 33 35 1o~ 12» 14- 18 *1 a 18* 11% 11 P7 20 ‘ Edam ' 3 NW!- ” 3 5. 22- 8 24* 26* L L 1 28 1 1 1 41 41 .5 42 42.5 43 43.5 44 Figure 3.5a and 3.5b. Cross-section of log K data points used for interpolation. Figure 3.53 is a transect through the delivery wells, Figure 3.5b is a transect through the down gradient wells (Figure 3.3 for location). Zonal boundaries picked at 16 m bgs, 20 m bgs and 21 m bgs, identifying 4 zones. Scalebar is in log K (cm/s). 39 mean median standard deviation no. of data points Table 3.3. Horizontal K (cm/s) statistics for the the four stratigraphic zones and the non- zonal model. zone 1 zone 2 zone 3 zone 4 all zones 5.44 E-02 1 .56E-02 3.20E-02 1 .38E-02 3.07E-02 5285-02 1.74E-02 3.125—02 1.27E-02 2.59E-02 2905-02 1 .1 1 E-02 9.40E-03 5.40E-03 2.43E-02 106 25 82 133 346 4O studies indicated that sediments above 8 m b gs did not have CT contamination, and were, therefore, not included in this study. Outcrop Analog Cores at this site provided an excellent sampling of vertical distributions for K analysis, but lateral data was limited even with the closely spaced cores from this site. To supplement the limited lateral core data, outcrop analogs were used to evaluate lateral variability of hydraulic conductivity at the site and to aid in the interpretation of bounding surface geometries. The excavation of sand and gravel pits in the Kalamazoo moraine outwash deposits exposed unconsolidated outcrops that could be analyzed for facies distribution, channel size, bed thickness, and lateral bed variability. Outcrop analogs to the Schoolcraft Plume A site (Figure 3.1) were selected based on: 1) location within the same outwash complex, 2) comparable distance from the Kalamazoo Moraine, 3) grain size, 4) bed thickness and 5) sedimentary structures. Using these criteria, the analog sites and the Schoolcraft site appear to have been deposited under a similar energy conditions in the same type of environment. Once the analog sites were chosen, beds and lithofacies were identified, measured and then drawn and labeled on photo mosaics (Appendix B). Samples for horizontal K and grain size distributions were collected by inserting 15.2 cm long brass sleeves in lateral and vertical rows within chosen facies of the outcrop. These samples were tested for hydraulic and sedimentologic properties using similar methods as core from well P18. Width to thickness ratios of facies units for this study were estimated using the sand and gravel pit measurements that compared most closely to the grain size, bed thickness and bedding 41 structures of the core (Figure 3.6). The sand and gravel pit that was most similar to sediments at the Schoolcraft site is composed of cross-stratified gravel facies, cross- stratified medium to coarse sand facies and some cross-stratifiedfine sand facies. Width to thickness ratios were estimated for bed sets from the outcrop analog to be an average of 7.7: 1. This ratio corresponds well to published data by Robinson and McCabe (1997), who reported trough cross bed sets have an average width to thickness ratio of 8.5:1 to 10.4: 1. It was not possible to measure the bed lengths, since the outcrop is two dimensional and bed lengths at the site are longer than the scale of the outcrop. No published data were available on the bed width, depth and length ratios, likely for the reason stated above. Geostatistics We use the stratigraphic zones identified at the Schoolcraft site as geologic regions for geostatistical interpolation. For each zone, experimental variograms were developed to estimate the correlation lengths in the vertical, parallel to paleoflow, and perpendicular to paleoflow directions. Variogram parameters were estimated using horizontal log K values measured from core samples. Log K data were used instead of K in this and other geostatistical analysis because hydraulic conductivity values for this site are more log-normally distributed than normally distributed (Hoeksema and Kitanidis, 1985). The parameters for the vertical correlation length were estimated to fit the experimental variogram. Because horizontal data are sparse, the horizontal, perpendicular to flow correlation length structures were determined using the 7.7:] width to thickness ratio measured from outcrop analog. The horizontal, parallel to flow 42 Figure 3.6. A portion of the outcrop analog showing the stratigraphic character of the outwash material with a shovel for scale. Image is presented in color. 43 correlation length structures were extended as far as Groundwater Modeling System (GMS3.1, BYU, 2000) would allow, approximately 18 m. Yet, we believe this is shorter than the true parallel-to-flow correlation length based on the outcrop analogs and the nature of these fluvial deposits. Table 3.4 summarizes the sill, nugget, parallel to flow range, perpendicular to flow range, and vertical range for each stratigraphic unit. Using the estimated variogram models and conditioning data, we generated a three-dimensional K field for each hydrostrati graphic zone using ordinary kriging. The four zones were then merged to create a final K field surrounding the biocurtain area. This zonal kriged field preserved abrupt K changes, especially noticeable at approximately 20-21 m depth in zone 2 (Figure 3.5). In addition to the zonal kriged results, a K field was estimated by kriging without the zonal boundaries to evaluate the influence of the additional geologic information. For this model, the variogram range was set at 18.0 (to be consistent with the zonal kriging). The nugget, sill, and range in all three orthogonal directions were fit to the experimental variograms based on the core data (Table 3.4). In a visual comparison, the zonal kriged field had significantly more horizontal bedding-like features than the traditional kriged field, which had smoother features with less horizontal continuity. Additionally, the low K area, (20—21 m bgs), interpreted as an abandoned channel fill, is much larger and diffuse in the non-zonal kriged case than suggested by the core data (Figure 3.5). Groundwater Modeling and Tracer Test Simulation We used the three-dimensional groundwater flow model MODFLOW-96 (McDonald and Harbaugh, 1988; Harbaugh and McDonald, 1996) to compute the flow Range nu et Sill parallel to flow perpendicular to flow vertical non-zonal model 0.011 I 0.065 I 18.0 T 6.84 i 2.700 ] zonal model zone 1 0.012 0.026 18.3 2.61 0.353 zone 2 0.027 0.21 17.7 4.09 0.531 zone 3 0.0017 0.020 18.0 8.33 1.081 zone 4 0.0053 0.024 18.4 12.51 1.619 Table 3.4. Variogram parameters for zonational krige and non-zonational krige. All variograms fit using exponential model. 45 / Non-zonal Kriged Results Figure 3.7. Zonal (top) and non-zonal (bottom) kriged results. Arrows mark boundaries of zones in zonal krige. Note that abrupt changes in K are preserved in zonal krige approach. Scalebar is in log K (cm/s). 46 and heads for the region. Constant head boundaries were used in the flow direction to provide a gradient of 0.0011 based on regional head measurements (Figure 3.2). The model domain is a rectangular region 101.5 m wide (Y) by 57.2 m long (X) by 27.4 m in depth (Z). We discretized this region using a computational grid with 136 (Y) x 86 (X) x 44 (Z) cells (Figure 3.8). The delivery well gallery is located at the center of the computational domain such that fine cells (20 cm x 20 cm) approximately equal to the size of the well boreholes surround the delivery wells. Cell size increased in a geometric progression away from the well gallery. The resolution in the vertical direction varies and is discretized most finely around the low conductivity zone located at approximately 20-21 m bgs (Table 5). During the tracer test, a conservative tracer (bromide) was injected into the seven even-numbered wells and extracted from the eight odd-numbered wells for the first five hours. During the next hour the same pumping rate was used in a flow reversal phase where tracer was extracted fiom the even wells and injected into the odd wells. We used the reactive transport code RT3D (Clement and Jones, 1998; Clemet, 1997) to simulate three-dimensional tracer transport through the site. Since the injected bromide concentration changed during the tracer test, we divided the five-hour interval in the transport model into three stress periods with different concentrations, 18, 14, and 17 ppm respectively. The one hour flow reversal phase was simulated with a single stress period where injected concentrations were 23.5 ppm. The last stress period in this simulation represents a 20-day natural gradient period with no pumping. The differences in hydraulic conductivity across the vertical extent of the aquifer, cause proportional differences in the flux through different layers of the well bore. To represent this 47 Figure 3.8. Discretization of grid in plan view, delivery well gallery is located near the center of the grid, marked by light colored squares, where dicretization is the finest. layers thickness of layer (m) Table 3.5. Vertical discretization of layers. 48 behavior, we used a conductivity-weighted average to compute the fluxes for the injection and extraction wells. Results and Discussion The tracer test comparison shows that the addition of geologic data can significantly improve simulations in some localities while in others the zonal and non-zonal simulated tracers are very similar (Figure 9). In most cases, the hydrostratigraphic interpretation improves the match between simulated and observed tracer concentrations. The most significant improvement was at 19.8 m depth, especially at wells MW10 and MW 13. The massively bedded to finely laminated very fine sand facies, interpreted as an abandoned channel fill, is present at this depth over about half of the simulation area. The core descriptions and K data place this channel fill through delivery wells 8, 10, and 12. MW 13 and MW10 are located downgradient from delivery wells 10 and 8 respectively (figure 3). MW10 and MW13 are the most affected by the addition of geologic data because this is where the low K channel fill is located. At the same depth with no evidence for the low K abandoned channel fill, tracer simulations MW11 and MW12 respond similarly for both types of kriging. No core was recovered from well D2 at this depth, however, the measured tracer breakthrough at MW9 is very similar to the measured data from MW13, suggesting another possible abandoned channel fill at this location. At most other depths, the comparison between tracer tests simulated in the zonal and traditional kriging simulations are very similar. Slight improvements are made in MW10, and MW13 at depth 22.9 m, and MW10 and MW11 at depth 16.8 m, and MW11 49 10-7 13.7 1P 7 b r _ Zonal 0.5er 1‘ 1' "MN 1 ’ ‘r a 0.5' " ’ W10 “-4 ii a a or 4 3 ‘ 2 1 r 1- a C10. 0.15» .. . W11 11 1" I a n o W ‘ .. 1 V v v 4} 0.5' 1r 1i MW12 1i 0 0.5: 1’ MW13 0* W‘s—q 10 ° d ’ O O Time (Days) Figure 3.9. Measured tracer test from site (x) with simulated zonal krige (black line) and simulated non-zonal krige (gray line). 50 at 13.7 m and 10.7 m, where the breakthrough occurs a bit earlier in the zonal kriging tracer simulation. There are a few instances where the two kriging approaches provide similar transport results and a few sites where the traditional kriging breakthrough better matches the measured tracer concentrations. The nonzonal krige transport simulation better matches the measured tracer at MW12 at 17.8 m depth. This is because the nonzonal krige interpolated a higher K value than the zonal krige interpolated at 17.8 m depth. Conclusions The addition of stratigraphically significant boundaries into geostatistical interpolation methods helps preserve abrupt changes in K as they occur in the sedimentologic record, thus better honoring the stationarity assumption implicit in the kriging method. The zonal kriging approach requires an understanding of the depositional environment, which can be accomplished by visual analysis of the core material to evaluate stratigraphic units. In locations where core data do not provide enough information, outcrop analogs were used to provide approximate correlation lengths for different facies type. Kriging K values using the stratigraphic fi'amework identified by the core yields a more realistic aquifer characterization that better matches the true geology of a site. The zonal model of K improved the tracer simulations, most evident where the heterogeneity is the highest or in regions where there is a contrast in K of an order of magnitude or more. 51 Chapter 4 Transition Probability Geostatistics Introduction Transition Probability Geostatistics is an indicator geostatistical method that can be used to estimate the spatial distribution of facies based on geologic information input by the modeler. This is done by first categorizing the data set into three to five geologically distinct facies or hydrofacies. Second, a three-dimentional Markov chain model is fit or developed for the data. Third, this model is used in sequential indicator simulation to simulate the three dimensional facies distributions. Important geological attributes such as 1) volume fraction (proportions), 2) mean lengths (e. g. thickness and lateral extent) and 3) juxtapositional tendencies (how one category tends to locate in space relative to another) are considered in this approach (Carle et al., 1998). Markov chains offer a stochastic model for categorical variables that incorporate all of these geological attributes (Carle and Fogg, 1998). The Markov chain is a model used to mathematically describe the transition probabilities seen in geologic medium. The probability of one facies transitioning directly to another is used to help define the Markov chain model. After the Markov chain models are developed in three principle directions (vertical parallel to flow and perpendicular to flow), conditional simulation followed by simulated annealing was run. Conditional simulation is a process that creates multiple, equally probable spatial distributions of random variables or “realizations” that honor hard data conditioning points at specified locations (Carle et al., 1998). This is a much different method of estimating distribution of K than kriging, 52 which will only produce one distrubution of K (Deutsch and J ounel, 1992). Simulated images do not exhibit the characteristic smoothing effect of kriging (Deutsch and J ounel, 1992). Therefore, simulated images better preserve abrupt changes in K. Existing variogram based methods do not provide 1) consideration for asymmetric juxtaposition relationships such as fining upward tendencies; 2) a framework for incorporating geologic interpretation of proportions, lengths, and juxtaposition tendencies into models of spatial variability; or 3) consideration for locally variable anisotropy directions (Carle et al. 1998). Incorporating geologic interpretation of proportions, lengths, and juxtaposition tendencies into models of spatial variability, as well as consideration for asymmetric juxtaposition relationships are very important to creating an accurate geologic model at the Schoolcraft site. By enforcing juxtaposition relationships, proportions, and lengths, based on geologic data from the site, geologically plausible simulations of the distribution of facies will are produced even where the data are sparse. Although the transition probability geostatistical approach produces geologically _ plausible distributions of heterogeneity, this is only accurate where stationarity can be assumed, or where the mean and standard deviation do not vary spatially (Weissmann and F ogg, 1999). The Schoolcraft site as a whole is not stationary, as described previously in chapter 3. For the transition probability/ Markov chain based simulations, the Schoolcraft site was divided into 2 zones, to better honor stationarity --a coarse grained bottom zone (medial deposits) and a finer grained upper zone (distal deposits). The upper and bottom zones were simulated separately and later combined to create a full aquifer characterization. 53 Stratigraphic Zones Two zones were identified at the Schoolcraft Plume A site —a gravely zone at the bottom of the aquifer (22-27 m bgs) that represents intermediate (Donj eck-type) outwash deposits and —a sandy zone at the top of the aquifer (8-22 m bgs) that represents distal (Platte-type) outwash deposits (see Appendix A). The bottom zone was the same as zone 1 used in the zonal kriging (see chapter 3). The top zone was a compilation of zones 2-4 used in the kriging chapter (3). These upper zones were combined since similar hydrofacies are present. The mean and standard deviation of grain size are significantly different between the two zones (Table 4.1). To show that mean grain size and standard deviation do not depend on location in the top zone of the transition probability geostatistics simulations, the data were divided into the same three zones as the kriging zones from chapter 3 and assessed for mean grain size and standard deviation. Division of the region into two stratigraphic zones for transition probability modeling appears justified since mean and standard deviation are approximately the same for kriging zones 2-4 (Table 4.2). Additionally, the bottom zone consists of predominately medium (46.6%) and coarse sand (23.6%) while the top zone consists of predominately fine sand (74.2%). Explanation of Hydrofacies from Categories Within each zone, five distinct hydrofacies were identified by comparing grain size, sorting and K. Mean grain size and standard deviation of grain size were measured from sections of sieved cores (P18, D2, D4, D6, D8, D10, D12 and D14). Core P18 was also described for sedimentologic properties (Appendix A, Figure A.2). Many 54 T. P. zones mean GS mean GS mean SD mean sorting no. data points 1 0.11 very coarse sand 1.73 poorly 29 2 2.29 upper fine sand 0.77 moderately 84 Kriging zones 1 0.11 very coarse sand 1.73 poorly 29 2 2.28 upper fine sand 0.62 moderately well 5 3 2.08 upper fine sand 0.78 moderately 36 4 2.48 fine sand 0.79 moderately 42 Table 4.1. Mean grain size (GS) in Phi unit, corresponding Wentworth size class (Boggs, 2001), mean standard deviation (SD), sorting based on standard deviation (Boggs, 2001), and number of data points in each zone for the two transition probability (T. P.) zones and the four zonal kriging zones. Zone one is the same for the transition probability and zonal krige zones. Ifldrofacies of the Top Zone Proportions Poorly sorted medium sand (PMS) 0.065 Poorly sorted coarse sand (PCS) 0.032 Moderately to well sorted fine sand (MW FS) 0.742 Poorly sorted fine sand (PFS) 0.130 Very fine sand (VFS) 0.032 Hydrofacies of the Bottom Zone Proportions Pebbles, gravel and very coarse sand (PGVCS) 0.135 Moderately well to well sorted medium sand (W MS) 0.115 Poorly sorted coarse sand (PCS) 0.236 Poorly sorted medium sand (PMS) 0.466 Moderately to well sorted fine sand (MWFS) 0.048 Table 4.2. Proportions of hydrofacies in the top and bottom zone. 55 things were considered when choosing categories, including: 1) relationship between grain size and sorting, 2) the interpreted process under which each grain size / sorting combination was deposited and 3) the distribution of K for each grain size / sorting combination. Generally, a relationship exists where, for any grain size, the better a sand is sorted the higher the K value, assuming a normal distribution of grain size (Beard and Weyl, 1973). Measured data indicate from the Schoolcraft site indicate that this assumption is true, even though the sands and gravels from the Schoolcraft site lack normal distribution (Table 4.3 and Table 4.4). Thus, it is believed that this is still reasonable to assume this relationship exists for sands and gravels at the Schoolcraft site. Top Zone For the top zone, the five identified categories are: l) moderately to poorly sorted medium sand (PMS), 2) poorly to very poorly sorted coarse sand with pebbles (PCS), 3) well to moderately sorted fine sand (M WFS), 4) poorly sorted fine sand (PFS) and 5) moderately to poorly sorted very fine sand ( VF S). Mean K decreases fiom category one to category five. Mean, high and low K values are given in Table 4.3, and plotted in Figure 4.1. PMS (category 1) is the hydrofacies with highest K in the top zone, and is poorly to moderately sorted. In core, this hydrofacies displayed either faint cross-stratified bedding or massive bedding and grain shape is rounded to subrounded. The sediment color is light olive brown (Munsell 2.5Y 5/4) when wet and pale yellow (Munsell 2.5Y 7/3) when dry. This hydrofacies tends to occur as lenses within the MWF S hydrofacies and is interpreted to have been deposited on channel bars. 56 Category Hydro facies 1 01-wa TOP ZONE no. of averafi K high K low K points oorly sorted medium sand (PMS) 0.025 0.04 0.005 16 Poorly sorted coarse sand (PCS) 0.019 0.044 0.004 4 oderately to well sorted fine sand (MWFS) 0.013 0.029 0.007 51 oorly sorted fine sand (PFS) 0.010 0.032 0.002 6 ery fine sand (VFS) 0.008 0.012 0.002 7 Table 4.3. Hydrofacies and corresponding assigned category for top zone with high K value, low K value, average K value, and number of points. BOTTOM ZONE no. of Category Hydro facies avenge K hiLhK low K points 1 ebbles, gravel and very coarse sand (PGVCS) 0.057 0.103 0.024 11 2 oderately well to well sorted medium sand (WMS) 0.043 0.066 0.018 4 3 oorly sorted coarse sand (PCS) 0.041 0.062 0.018 7 4 oorly sorted medium sand (PMS) 0.032 0.046 0.017 5 5 oderately to well sorted fine sand (MWFS) 0.017 0.019 0.016 3 Table 4.4. Hydrofacies and corresponding assigned category for bottom zone with high K value, low K value, average K value, and number of points. 57 00500«-—~r—~—1+——’T’*T*-j~+jl I . ’ . a E 004001 _ - f - - __-1___-._W ”.5, l l E 00300 '—- — --—# ----- “w“? “55—4- 1 '4 00200I i . i i J l 5 i i fir 1» l 1 g x 0.0100 —-—-4— 1’ 1i "“1 i 1 . ‘ l , 0.0000 ,_ d4 1 21 ‘ o 1 2 3 4 5 6 l Category Figure 4.1. Top zone of Schoolcraft site, 1-5 are categories of hydrofacies, corresponds to Table 4.3. Top diamond is high K value, bottom diamond is low K value and middle diamond is mean K value. 58 The PCS hydrofacies (category 2) is poorly to very poorly sorted and contains both pebbly coarse sand and coarse sand without pebbles. These two lithologies were combined because they both display similar K values and represent the coarsest grained sediments in the upper zone. The pebbly sand is matrix supported with rounded pebbles and subrounded grains. The matrix consists of coarse and medium sand. The color is olive brown (Munsell 2.5Y 4/4) when wet, and pale yellow (Munsell 2.5Y 7/3) when dry. The samples of coarse sand without pebbles could not be described for sedimentologic features since only sieve data exists for these samples. This hydrofacies is interpreted to have been deposited on channel bars. The M WF S (category 3) is the most abundant hydrofacies in the top zone (Table 4.2). The moderately to well sorted sand appears to have thicker and more continuous beds than any of the other hydrofacies in this zone (Figure 4.2). In core, MWF S displays massive bedding from the base of the zone to about 16 m bgs, above which it becomes cross-stratified (see Appendix A Figure A2). The color of the sand is generally olive brown (Munsell 2.5Y 4/4) when wet and pale yellow (Munsell 2.5Y 7/3) when dry, and the grain shape is generally subrounded. This hydrofacies is interpreted to have been deposited on channel bars. The PF S (category 4) has a lower K than the moderately to well sorted fine sand due to its poorer sorting. It is generally cross-stratified with either coarser grains along cross-stratified beds or with seemingly randomly placed pebbles composed of sand cemented with calcium carbonate. This hydrofacies appears to be thinner and laterally discontinuous when compared to M WFS. This hydrofacies is interpreted to have been deposited on channel bars. 59 Cross-section of top zone 8' D4 06 D10 D12 5 DZ . . . 101 ‘ P18 01.4 l -4.5 e O ' ' e .2. D8 __ . . ., O . ' D . 14. . . . 35 O 16* . . ‘ . 3 e I .1. 18— 7 1 2.5 e . . . e . 5 9 20— . . ' . . 2 22* O . . 1.5 24 L i 4 r 1 1 1 d1 22 24 26 23 30 32 34 36 Y direction (m) Figure 4.2. Cross-section of categories in top zone. Category 1, poorly sorted medium sand (PMS); category 2, poorly sorted coarse sand (PCS); category 3, moderately to well sorted fine sand (MWFS); category 4, poorly sorted fine sand (PFS); category 5, very fine sand (VFS). X axis is depth (m). Image is presented in color. 60 The VF S (category 5) is the lowest K hydrofacies and it is this facies that forms the “low K zone”, discussed in earlier chapters. In core, the very fine sand is finely laminated, had a high amount of silt and clay (16%), and was well to moderately sorted. The sediment color is olive brown (Munsell 2.5Y 4/4) when wet and pale yellow (Munsell 2.5Y 7/3) when dry. This hydrofacies was interpreted as abandoned channel fill, commonly found in medial and distal outwash facies (Donjeck and Platte type, as described by Miall, 1977 ). Abandoned channel fills are common in medial and distal outwash facies during flooding where what is commonly referred to as overbank fines infill abandoned channels (Miall 1985; Benn and Evans 1998.) Bottom Zone For the bottom zone, the five identified categories are: 1) pebbles, granules, and very coarse sand (PG V CS), 2) moderately well to well sorted medium sand (WS), 3) poorly to very poorly sorted coarse sand (PCS), 4) poorly to very poorly sorted medium sand (PMS) and 5) moderately and moderately to well sorted fine sand (MWF S). Mean K decreases from category one to category five. Mean, high and low K values are given in Table 4.4, and plotted in Figure 4.3. The PG VCS (category 1) is the hydrofacies with the highest K in the bottom zone (Figure 4.3, Table 4.4) and is composed of three different mean grain sizes pebbles, gravels and very coarse sand, all of which are poorly or very poorly sorted. These different sub-categories were grouped together because within each there was a high abundance of the other two grain sizes (e. g. the very coarse sand had pebbles and 61 Bottom Zone i 0.1000 1 , T—H I -—-»| , - -j 7,; 0.0800 I ,- + i I 3 0.0600 --- f” A“ -- ; 1 x 0.0400 —-——~ "—1 -__,_ 0.0200 -.——_ 4 __ I 4 4 0.0000 1 -- l i , -—- —T i I ‘. i o 1 2 3 4 5 6 l l 0.1200 ll -——- _ Figure 4.3. Bottom zone of Schoolcraft site, 1-5 categories of hydrofacies, corresponds to Table 4.4. Top diamond is high K value, bottom diamond is low K value and middle diamond is mean K value. 62 granules present) and all three subcategories had similar K values. In core, the pebbles and granules are rounded and grain supported and display cross-stratified bedding with the coarsest grains tending to occur along cross-stratified beds. The samples of very coarse sand were not described for sedimentologic features since only sieve data exists for these samples. This hydrofacies is present along the base of the aquifer and is interpreted to represent channel lag deposits. The WMS (category 2) is well to moderately well sorted, has rounded grains, and displays cross-stratified bedding. Coarser grains exist along bedding planes. The sediment color is olive brown when wet and light olive brown to pale yellow when dry. This hydrofacies is interpreted to have been deposited on channel bars. The PCS (category 3) is poorly to very poorly sorted. The coarse sand is cross- stratified with subrounded to rounded grains. Coarser grains exist along bedding planes. Grain size ranges from silt to granules. The coarse sand is light olive brown (Munsell 2.5Y 5/4) when wet and pale yellow (Munsell 2.5Y 7/3) when dry. This hydrofacies is interpreted to have been deposited on channel bars. This hydrofacies is very similar to the PCS hydrofacies in the upper zone and consequently has the same name. The PMS (category 4) is distinct from category 2 because of differences in average K (Table 4), and sorting. Grain size ranges from silt to granule within this facies. There is a fining upward relationship from PMS (category 4) to WMSM (category 2). In core, the PMS hydrofacies is cross-stratified and displays coarser grains along bedding planes. This hydrofacies is interpreted to have been deposited on channel bars. This hydrofacies is very similar to the PMS hydrofacies in the upper zone and consequently has the same name. 63 The M WF S (Category 5) is the lowest K hydrofacies in the bottom zone. This hydrofacies is distributed in very small proportions in the bottom zone. Because of the finer grain size than the rest of the bottom zone, this hydrofacies is interpreted to have been deposited on channel bars under a lower energy than the rest of the sediments in the bottom zone. This hydrofacies is very similar to the MWF S hydrofacies in the upper zone and consequently has the same name. Markov Chain Models Top Zone Markov Chain Models The vertical (z)-direction transition probability values for the top zone were measured from core based on a 0.25 m-spacing. Proportions of categories were estimated from the core data (Figure 4.2). In this zone, the MWFS hydrofacies has the highest proportions (74.2%) and seems to fill in around all the other categories. Thus MWF S was used as the background category (Table 4.2). Unfortunately, the data are very sparse and the addition of more data would have significantly improved the measured and modeled Markov chain models. Moreover, an outcrop analog that closely matched the distribution of grain size and beds to this upper zone was not found, so a Markov chain model could not be developed fi'om analog data. Using the available data, however, a Markov chain model was fit to the measured data (Figure 4.4). The vertical embedded transition probabilities and the mean lengths of the Top zone are given in Table 4.5. Because the M WFS hydrofacies is the background category, the vertical (z)-direction embedded transition probabilities are the highest where M WF S occurs. The highest embedded 64 PFS MWFS PCS PMS VFS Transition Probabili Top Zone PCS MWFS PFS Vertical Transition Probability VFS f I l A L A v 0.5 0.0 4 r3' . D o I-aa (m) Measured Modeled Figure 4.4. Matrix of vertical (z)-direction transition probabilities showing core data as measurements (open circles) and the Markov chain model (solid line) from the core measurements. The diagonal elements represent auto-transition probabities within a category, and the off diagonal elements represent transition probabilites between categories. 65 PMS PCS MWFS PFS VFS PMS PCS MWFS PFS VFS_ PMS? PCS MWFS PFS VF S Table 4.5. Embedded transition probability matrices for the top zone. These matrices are read as transition probabilities fiom the row hydrofacies to the column hydrofacies. (hydrofacies labels: PMS, poorly sorted medium sand; PCS, poorly sorted coarse sand; MWFS, moderately to well sorted fine sand; PFS, poorly sorted fine sand; VFS, very fine sand. Other labels: L, mean length. Bold numbers indicate background category with PMS L=.750 0.100 0.208 0.001 0.050 PMS L=30.0 0.100 0.178 0.001 0.050 PMS L=3.00 0.100 0.182 0.001 0.050 Vertical (z)-direction PCS MWFS PFS 0.100 0.889 0.010 L=.400 0.898 0.001 0.203 L=2.089 0.363 0.001 0.997 L=1 .000 0.001 0.948 0.001 Parallel to flow (x)-direction PCS MWFS PFS 0.100 0.799 0.100 L=10.0 0.898 0.001 0.303 L=74.74 0.414 0.001 0.997 L=30.0 0.001 0.948 0.001 Perpendicular to flow (y)-direction PCS MWFS PFS 0.200 0.699 0.100 L=1.0 0.898 0.001 0.288 L=7.64 0.424 0.001 0.997 L=3.0 0.001 0.948 0.001 computed values listed in the table.) 66 VFS 0.001 0.001 0.227 0.001 L=.4OO VFS 0.001 0.001 0.104 0.001 L=31.0 VFS 0.001 0.001 0.106 0.001 L=3.1 transition probability is fi'om PFS to M WFS (0.997). This is likely due to the fact PFS hydrofacies is often found as an erosional base beneath the MWF S hydrofacies and because the proportion of the M WFS hydrofacies. The mean lengths were estimated from the core description and the cross-section of categories in the top zone (Figure 4.2). The parameters used to estimate the perpendicular to flow (y)-direction Markov chain model (Figure 4.5) were estimated from geologic reasoning, juxtaposition relationships and the vertical (z)-direction embedded transition probabilities in an application of Walther’s law (Carle et al., 1998). Walters law states that only those facies that can be found forming side by side in nature can occur in contact with one another in a conformable vertical succession (Miall, 1996). The mean lengths were estimated from the (z)-direction mean lengths. Robinson and McCabe (1997) reported that trough cross bed sets have an average width to depth ratio of 8.5:1 to 10.4:1, depending on unit. A width to thickness ratio of 7.7 :1, measured in an outcrop analog which most closely matched the grain size distribution and vertical thickness of beds in this zone, was applied to the mean lengths in the (z)-direction to estimate (y)-direction mean lengths. Even though this outcrop analog was not a close enough analog to add additional information on juxtapositions, based on the similarity of the width to thickness ratio to published data and the fact that it is the best data available, I applied this width to thickness ratio in this zone. However, there is a high amount of uncertainty in the embedded transition probabilities and the mean lengths due to lack of sufficient continuous data. The parallel to flow (x)-direction Markov chain model were estimated fi'om the perpendicular (y)-direction embedded transition probabilities in an application of 67 PFS MWFS PCS PMS VFS Top Zone Horizontal Transition Probability 4 V 4 4 I 4 0 4 . o J . '1 O -I 0 — .- 1 I 1 0 ° ° 0 ‘ I: 1 I i 1 '- 4 4 1 4 .n . . J l _ fl 4 4 4 4 4 .fl ‘ I I I I o 4 4 4 4 h T.fi~r.:. 4 :Ir.= 4% 4pm I. . . . I I\ . , 3 : i e : o _ - - ° - - '3 O 4 4 m 4 4 I- O O : I 0 j 0 m U, ‘ o ‘ o : 4m1¢m rsT . .4, -e . ..fi. :- - i o 4 4 4 1 P 4 J 4 4 4 ‘. . ‘ ‘. 1 4 4 4 4 o 4 4 4 4 4 4 4M4m Ice fies, .: v... 1.0, ‘ x - 4 4 4 4 4 4 4 4 4 1 4 d 4 J 0-5: 1 1 1 1 4 4 4 4 4 4 4 4 4 4 4 4 4 4 Ono4p-r-III-IIIIU-T-Pvll-Tflsr:| 4W . .Te 1 .e. :3. 4m . . r. 1 .3. cc. 0 2 5 Lag (m) Measured Modeled O O 0 O O O 0 Figure 4.5. Matrix of perpendicular to flow (y)-direction transition probabilities showing core data as measurements (open circles) and the Markov chain model (solid line) from the core measurements. The diagonal elements represent auto-transition probabities within a category, and the off diagonal elements represent transition probabilites between categories. 68 Walther’s law (Carle et al., 1998). The mean lengths were estimated from the (y)- direction mean lengths. The embedded transition probabilities are ahnost the same as the perpendicular to flow (y)-direction embedded transition probabilities (Table 4.5). The mean lengths in the (x)-direction were estimated using the perpendicular to flow mean lengths and multiplying them by 10, an estimate of what the width to length may be off outcrop analogs that were most similar to the characteristics of the top zone. Unfortunately the outcrops were not large enough to measure the length of these units so there is significant uncertainty in the mean lengths in the (x)-direction. Bottom Zone Markov Chain Models Vertical (z)-direction transition probability values for the bottom zone were measured from the data, based on a 0.25 m spacing (Figure 4.6). The core data are sparse, and, for that reason, the Markov chain model fit to these measurements was not very good. In an effort to incorporate more data for model development, a 0.25 m grid was overlain on 3 described outcrop analog which seemed to best fit the facies relationships, proportions, and the thickness of beds in the bottom zone (Figure 4.7). Proportions of categories were estimated based on core data and the outcrop analog (Table 4.2). The additional information on the spatial distribution of facies provided by the outcrop analog helped the Markov chain model, although the addition of more data would further improve the model if the data were available. Figure 4.8 shows the vertical (z)-direction Markov chain model that was fit to the measured data. The embedded transition probabilities and mean lengths used in this model are given in Table 4.6. 69 Cross-section of the bottom zone D10 22 02 “I P18 H 5 e 9 ' 22 5 » DG 45 . . 23» . 3‘ D12 - ‘4 23.5 1’ D14 24 _ . r - 3.5 O 24.5 C 3 O 25 0 . 2.5 O O 255-. O 2 25. S n9 0 e e O 1.5 265 : . . . 27 A A A J A . l 1 22 24 26 28 30 32 34 36 Y direction (m) Figure 4.6. Cross-section of category in bottom zone. Category 1, pebbles, granules and very coarse sand (PGVCS); category 2, poorly sorted medium sand (PMS); category 3 poorly sorted coarse sand (PCS); category 4, poorly sorted medium sand (PMS); category 5, moderately and moderately to well sorted fine sand (MWFS). Image is presented in color. 70 Figure 4.7. Outcrop analog with 0.25 m grid overlay. Image is presented in color. 71 WMS PGVCS Probabili PCS Trans Bottom Zone Vertical Transition Probability 1 1 o 1 4 4 4 ‘ 4 ‘1 0 fl 1 A - -i 0 -1 0 4 o 4 4 4 0 4 0 4 0 O . 4 o 1 ‘ 1 A j °o° o o r V v v I v v V W. 'vY v v v ' 'v'vY W "V . . ° o°° 4 o 4 ° 4 ‘ 0 0 II! -I A % 4 o o 4 4 4 I v m V v V ' l m o o 0 O o o 0000 c o o 2 o O 4 ° - . . , . - M 4m 1 o c . : . 1 00 e: i o .: :4 00° 1 d d 1 '1 4 o 0 o 0 0° 1 » ‘ . O " 0 1m ' :V c l I I: I‘fT Iif , I . .f .. J o 1 0° 4 1 4 . 0 o - ° - 4 1 V o 1 O 0 V 4{ 0 0. T ' T ' v ' T ' ' ' V ' r T ' ' ' ' 2 Lag (m) Measured Modeled 0000000 Figure 4.8. Matrix of vertical (z)-direction transition probabilities showing core data as measurements (open circles) andthe Markov chain model (solid line) from the core and outcrop analog measurements. The diagonal elements represent auto-transition probabities within a category, and the off diagonal elements represent transition probabilites between categories. 72 PGVCS WMS PCS PMS MWFS_ PGVCS WMS PCS PMS MWFS_ PGVCS WMS PCS PMS MWFSL _ Vertical (z)-direction PGVCS WMS PCS PMS MWFS L=.420 0.500 0.240 0.250 0.010 0.050 L=.190 0.250 0.690 0.010 0.010 0.005 L=.200 0.885 0.100 0.162 0.257 0.542 L=.273 0.038 0.010 0.010 0.120 0.860 L=.25 Parallel to flow (x)-direction PGVCS WMS PCS PMS MWFS L=32.0 0.250 0.450 0.290 0.010 s L=15.0 0.250 0.603 0.010 s s L=15.4 0.735 3 0.065 0.248 0.602 L=25.0 0.084 s 3 0.120 0.818 L=25.0 # Perpendicular to flow (y)-direction PGVCS WMS PCS PMS MWFS L=3.20 0.250 0.450 0.290 0.010 s L=1.50 0.250 0.603 0.010 s s L=1 .54 0.735 3 0.065 0.248 0.602 L=2.50 0.084 s 3 0.120 0.818 L=2.50 _ Table 4.6. Embedded transition probability matrices for the bottom zone. These matrices are read as transition probabilities from the row hydrofacies to the column hydrofacies. (hydrofacies labels: PGVCS, pebbles, gravel and very coarse sand; WMS, well sorted medium sand; PCS, poorly sorted coarse sand; PMS, poorly sorted medium sand; MWFS, moderately to well sorted fine sand. Other labels: L, mean length. Bold numbers indicate background category with computed values listed in the table.) 73 Both fining upward and coarsening upward tendencies are present in the bottom zone and preserved in the Markov chain model evident in the W.r.t independent transition frequencies. If the W.r.t values are greater than 1.0 then the transition is more likely to occur and if the W.r.t. values are less than 1.0 than the transition is less likely to occur (Table 4.7). There is a slight fining upward tendency, from PG VCS up to WMS, from PG VCS up to PCS and from PCS up to PMS. However, it is not uncommon to coarsen upward as well. This occurs from PCS up to PG VS, from WMS up to PCS and from MWF S up to PMS. The perpendicular to flow (y)-direction Markov chain model and mean lengths (Figure 4.9) were estimated from the vertical (z)-direction embedded transition probabilities and vertical (z)-direction mean lengths in an application of Walther’s law (Carle et al., 1998). To estimate (y)-direction mean lengths, a 7.721 width to thiclmess ratio, measured in the outcrop analog, was applied to the mean lengths in the (z)- direction. Fining outward tendencies are present in the bottom zone and preserved in the Markov chain model, evident in the W.r.t independent transition fiequencies (Table 4.7). The PG VCS transitions outward to WMS and PCS, WMS transitions outward to PMS, and PMS transitions outward to M WFS. For the (y)-direction Markov chain model symmetry was forced, noted by an s in Table 4.6. The parallel to flow (x)-direction Markov chain model (Figure 4.5) and mean lengths were estimated from the perpendicular to flow (y)-direction embedded transition probabilities and the (y)-direction mean lengths in an application of Walther’s law (Carle et al., 1998). The embedded transition probabilities are the same as for the perpendicular 74 PGVCS WMS PCS PMS MWFS PGVCS WMS PCS PMS MWFs_ PGVCS WMS PCS PMS MWFS_ Table 4.7. W.r.t independent transition fi'equencies matrices for the bottom zone. These matrices are read as independent transition probabilities from the row hydrofacies to the column hydrofacies. (hydrofacies labels: PGVCS, pebbles, gravel and very coarse sand; WMS, well sorted medium sand; PCS, poorly sorted coarse sand; PMS, poorly sorted medium sand; MWFS, moderately to well sorted fine sand. Other labels: L, mean length. Bold numbers indicate background category with computed values listed in the table.) PGVCS L=.420 1.000 0.177 1.288 0.215 PGVCS L=32.0 s 3 0.534 s Perpendicular to flow (y)-directlon PGVCS L=3.20 s 3 0.534 3 Vertical (z)-direction WMS PCS PMS 5.290 1.154 0.373 L=.190 1.146 0.982 0.044 L=.200 1.110 1.030 0.986 L=.273 0.108 0.588 1.310 Parallel to flow (x)-direction WMS PCS PMS 2.019 1.475 0.534 L=15.0 0.770 1.044 s L=15.4 1.028 1.044 1.028 L=25.0 8 0.407 1.561 WMS PCS PMS 2.019 1.475 0.534 L=1.50 0.770 1.044 s L=1 .54 1.028 1.044 1.028 L=2.50 8 0.407 1.561 75 MWFS 0.358 0.341 3.001 0.517 L=.25 MWFS 0.356 0.334 1.561 L=25.0 MW FS 0.356 0.334 8 1.561 L=2.50 PMS PCS WMS PGVCS MWFS Bottom Zone Hortizontal Transition Probability j o 4 4 oo o - 4 o 4 4 ow ‘ O . I . .23: 4W 1 . 4 4 1 1 000 .1 00% a: O u a l0 4 O” 4 . 4 I j T I a «W < o 4 ‘ o d d o q o 4 4 4 . r I r T- «W 4 4 1 4 . o d 4 1 1 Lag (m) Measured Modeled 0000000 Figure 4.9. Matrix of perpendicular to flow (y)-direction transition probabilities showing core data as measurements (open circles) andthe Markov chain model (solid line) from the core and outcrop analog measurements. The diagonal elements represent auto-transition probabities within a category, and the off diagonal elements represent transition probabilites between categories. 76 to flow (y)-direction (Table 4.6). The mean lengths were estimated using the perpendicular to flow mean lengths and multiplying them by 10, an estimate of what the width to length may be based on the outcrop analogs. Unfortunately the outcrops were not large enough to measure the length of these units so there is much uncertainty in the mean lengths in the (x)-direction. For the (x)-direction Markov chain model symmetry was forced, noted by an s in Table 4.6. Conditional Sequential Indicator Simulation Conditional sequential indicator simulation, followed by simulated annealing (Carle et al., 1998), was run on the top and bottom zones separately using the appropriate Markov Chain model for each zone. The cell size for the realization of the Schoolcraft site was 0.2 m in the lateral directions (x and y) and 0.25 m in the vertical direction (2). This small grid spacing was used so that the realizations simulated here could be input into an existing GMS grid with similar dimensions in the future. Information from core were used as hard conditioning data in the simulations. Combining the Zones Once the realizations were complete for the top and bottom zones individually, the results were combined to create a final whole aquifer characterization. There are some categories that occur in both the top and bottom zone. After simulation, these categories were combined to simplify the final product and show similarities between the two zones. Category 5 from the bottom zone (M WF S) was combined with category 3 from the top zone (M WF S) and on the final plot is called moderately-well sorted fine 77 sand. Category 4 from the bottom zone (PMS) and category 1 from the top zone (PMS) were combined and is called poorly sorted medium sand in the final realization. Category 2 from the top zone (PCS) was combined with category 3 from the bottom zone and is called poorly sorted coarse sand in the final realization. The final realizations of the Schoolcrafl site are Figure 4.10 and Figure 4.11. Figure 4.11 is separated into five volurnetrically equal blocks allowing the inside to be more readily viewed. The final geostatistical realization reflects juxtaposition tendencies, proportions and the channel orientation used as inputs to the Markov chain model. Fining upward tendencies are preserved in the top zone where F SP fines upward to MWF S. In the bottom zone, both the fining and coarsening upward tendencies are preserved from PGVCS and PCS up to WMSM and from WMSM up to PCS and from MWFS up to WMSM. Channels are orientated perpendicular to Y axis along the maximum correlation direction. In the top zone, the high proportion of MWFS is preserved and other hydrofacies are distributed in channel like geometries. The most striking channel like geometry is the VFS hydrofacies simulated channel located at about (5, 10, 18) m in Figure 4.10 and Figure 4.11. This is interesting because no conditioning data indicate that a channel is present at this location. Other realizations would likely not simulate a channel at this location. The realization presented here simulated a channel there based on the Markov chain model. By assigning average hydraulic conductivity values (Table 4.3 and Table 4.4) to each hydrofacies, this realization could be used in groundwater flow modeling and contaminant transport simulations. Assigning an average K value to each hydrofacies would preserve abrupt changes in K where other traditional geostatistical tools such as kriging would smooth K values. 78 Schoolcraft Site 2 Vertical (m) N 4 3 8 1 0 x Paralleldiz)“ Pebbles, granules and very coarse sand (PGVCS) 7 Moderately well to well sorted (WMS) 1 Poorly sorted coarse sand (PCS) i Poorly sorted medlum sand (PMS) 1 moderately-well sorted fine sand (MWFS) i Poorly sorted flne sand (PFS) I Very fine sand (VFS) Figure 4.10 A realization of the Schoolcraft plume A site based on transition probability/ Markov chain geostatistics in two zones. This image is presented in color. 79 Schoolcraft Site Pebbles, granules and very coarse sand (PGVCS) Moderately well to well sorted (WMS) fl Poorly sorted coarse sand (PCS) E Poorly sorted medlum sand (PMS) 1 moderately-well sorted fine sand (MWFS) ! Poorly sorted flne sand (PFS) I Very fine sand (VFS) Figure 4.11 A realization of the Schoolcraft plume A site based on transition probability/ Markov chain geostatitics in two zones. This image is presented in color. 80 Conclusions Using the transition probability geostatistics and the Markov chain models, a geologically reasonable aquifer characterization was simulated that better honors the stationarity assumption and better preserves abrupt changes in K. Although this is a very reasonable approach to characterizing heterogeneity in the subsurface, it is unclear how much this realization will improve transport studies at the Schoolcraft Plume A site. This is due primarily to lack of data. More conditioning data would greatly improve the simulated hydrofacies because the final characterization would honor more real data points. A few wells with continuous core data, described for sedimentary features could then be classified into the same hydrofacies used in this study. The continuous data collected would greatly improve the vertical Markov chain fit thereby improving the estimated horizontal models. Selected samples could be tested for K as a quality control measure and to increase the data base where only a few samples were tested previously. At a small scale such as this, it is the fine details that are of concern to produce accurate groundwater models and transport simulations. Without closely spaced detailed continuous core descriptions, only general concepts can be obtained fiom this type of modeling, and at this site accurate detailed aquifer characterizations are the goal. 81 Chapter 5 Conclusions Depositional Environment of the Aquifer Below Schoolcraft Based on grain size data, bedding structures present, location of aquifer and depositional history of Kalamazoo County it was concluded that the base of the aquifer is composed of braided stream deposits located at a position medial (intermediate) the glacier front (Donjeck-type) and the upper portion of the aquifer is composed of braided stream deposits located at a position distal to the glacier front (Platte-type). The grain size of the bottom zone ranges from gravel to medium sand and is primarily gravel to coarse sand. Benn and Evans (1998) stated that a Scott-type stream is composed of greater than 90 percent gravel and a Donj eck-type stream is composed of 10 to 90 percent gravel. Thus, it can be reasoned that a Platte-type stream is composed of less than 10 percent gravel. Benn and Evan’s (1998) grain size based divisions of proximal, medial and distal seem realistic upon comparison to Miall’s (1977) braided stream facies models. The bottom zone is not classified as proximal to the glacier front (Scott-type braided stream) because it is not composed of more than 90 percent gravel and because the aquifer is located to far away from the Kalamazoo Moraine. Proximal (Scott-type) deposits can be found 0.5 miles from the Kalamazoo Moraine (figure 1). The proximal deposits at this gravel pit are composed almost entirely of gravel. Medial deposits are found 2 miles from the Kalamazoo Moraine at a sand and gravel pit where outcrop analogs were constructed to aid in the interpretation of subsurface geology in this study. An outcrop analog that was interpreted to have been deposited distal to the glacier was 82 not found. This is likely due to the high water table at distal locations and the fact that the fine sand is not worth as much as gravel and boulders, so it is not as cost effective to have a sand and gravel pit in most distal locations. The top of the Schoolcraft aquifer is interpreted as being deposited distal to the glacier, and is located approximately 6 miles away from the Kalamazoo Moraine. The fining upward sequence from medial to distal braided stream deposits at the Schoolcraft site indicate that a glacial retreat was recorded in this sediments. Aquifer Characterizations For all of the geostatistical methods used, lack of data was the biggest problem. With more data, better variograrns and Markov chain models could be developed. Increased conditioning data would significantly improve both the zonal krige and the transition probability simulation because the final characterizations would honor more real data points. A few wells with continuous core described for sedimentologic features, sieved to measure grain size distribution and standard deviation, and tested for K value would accomplish this. Another way to increase continuous core data is to do borehole geophysics (e. g., resistivity and conductivity logs) in boreholes where core was not fully recovered. Geophysical logs could then be compared to core descriptions and interpretations could be made to what type of sediment exist where there was no recovery. Closely spaced continuous core is critical to further improvement of the small- scale characterization of this aquifer. When focusing on such a small area, fine details in the heterogeneity must be considered, this can not be achieved without sufficient data. 83 Without close-spaced core data, only general concepts of heterogeneity and facies distribution can be obtained from geostatistical interpolation and simulation methods. At this site, accurate fine scale aquifer characterizations are the goal. Hence, quality close- spaced core data are needed. Kriging Method The addition of geologically based zones significantly improved the aquifer characterization as shown by the comparison of simulated to field tracer tests. Stationarity was better honored in the zonal krige characterization because zones were based on K distribution, such that each zone had less of a range of K than all the zones together did. Abrupt changes in K were preserved, especially around the low K zone, with the addition of stratigraphic zones. By understanding the heterogeneity present in the model and how that relates to the simulated verse field tracer tests, predictions can be made of what the geology is where tracer test data are available but no core was recovered. Transition Probability Method Stratigraphically based zones used in the transition probability simulation better honors the stationary assumption because the zones were delineated by mean grain size. The top and bottom zone have a mean grain size and a standard deviation of grain size that are more spatially consistant within that zone than across the boundary and into the other zone. Transition probability simulations preserve abrupt changes in K by not smoothing the data, and instead simulating a hydrofacies to every cell. Each hydrofacies 84 has a distinct K value that can be put into each cell. This is an advantage over kriging which smoothes data and forces the mean of the geostatistical variable at the edge of the model. As with the other geostatistical methods, lack of quality conditioning data limited the use of transition probability modeling. It is unclear how much this characterization method will improve transport studies at the Schoolcraft site, because not enough data was available to do a thorough characterization. 85 Appendix A Stratigraphy of the Schoolcraft Plume A Site Core Data Core was collected at several wells in the Schoolcraft Plume A site. This core was described for visual grain size, measured grain size by use of sieves, and/or tested for K on a constant head permeameter. For this study, all recovered core from well P18 (see Figure A.1 for location) was described in full for sedimentologic features (Table A.l and Figure A.2). Portions of core P18 were sieved and measured for vertical K value. Additionally, segments of core from wells P6, P7 and P8 were described for sedimentologic features (Figures A.3-A.8). Core descriptions of wells P18, P6, P7, and P8 and vertical K measurements of P18 were conducted as part of this study. Previous work by Hoard (2002) assessed the grain size distribution and the horizontal K of portions of seven of the 15 delivery wells in the biocurtain (D2, D4, D6, D8, D10, D12 and D14) and wells P6, P7 and P8, located down-gradient of the biocurtain (Table A.2- A.8) Core was collected from approximately 5 m bgs (below ground surface) to 26.5 m bgs. Previous studies indicated that sediment above 8 m bgs did not show evidence of carbon tetrachloride contamination thus, data were not collected above 5 m bgs. Interpretations of Depositional Environment of the Aquifer Below Schoolcraft Gravel and sand pits located in Kalamazoo County aid in the interpretation of proximal, medial, and distal location from the glacier at the time the sediments that compose the Schoolcraft aquifer were deposited. Benn and Evans (1998) state that proximal (Scott-type) braided stream deposits are composed of greater than 90 percent 86 Z round water “Section 5 D1 . O 0 ' D14 D13 I MW11 , 0 D12 . I . . D11 0 ' D10 ' 09 I MW13 0 P18 ° . 0 DB 0 P8' . I , 9" MW10. ° . - 0 D6 0 P7 05 I MW12 . p6 . 0 D4 ‘ , . 03 I . I Q 0 02 D1 I . ° W9 IKdata 0 K and strat data 0 monitoring well 0 ootherwells -:1 0m 2m Figure A]. Location of delivery wells (D), monitoring wells (MW), piezometers (P) and other wells at the Schoolcraft plume A site. 87 '- .~‘_?i.' gravel and medial (Donj eck-type) braided stream deposits are composed of anywhere between 10 and 90 percent gravel. It can be further reasoned that distal (Platte—type) braided stream deposits are composed of less than 10 percent gravel. Along with mean grain size, bedding structures also helped when classifying the outcrop analogs into proximal, medial and distal locations fiom the glacier. Miall (1977; 1996) stated that proximal braided streams deposits are commonly horizontal gravel . sheets displaying weak imbrication. Trough cross-bedded gravels and planar cross bedded gravels are also prominent (Miall 1977; 1996 and Benn and Evans 1996). Medial deposits can be composed of a variety of facies e. g. massive gravels, trough cross-bedded sands and gravels, planar cross-bedded sands and gravels, ripple cross-laminated sand and sand drapes (Miall 1977; 1996 and Benn and Evans 1996). Distal deposits are composed primarily of trough cross-bedded sands, planar cross-bedded sands and horizontally bedded sands. Minor gravel lenses and overbank fines may be present (Miall 1977; 1996 and Benn and Evans 1996). A gravel pit located approximately 0.5 miles away from the Kalamazoo Moraine on Ravine Road is composed of greater than 90 percent gravel and coarser material with the remaining percent composed of sand. The gravel at this site displays cross-bedding and horizontal bedding with some irnbricated clasts indicating minor channel fills or bedforrns and channel lag deposits. Approximately 2 miles fi'om the Kalamazoo moraine on Ravine Road is the gravel and sand pit interpreted as a medial (Donjeck-type) braided stream deposit. This sand and gravel pit, was a site of outcrop analog study for this project. The entire section studied for the outcrop analog was approximately 10 meters in height and generally fined 88 upward from gravels at the base of the section up to medium sand at the top of the section (Figures B.4- 3.7-Appendix B outcrop analogs). This section had less than 90 percent gravel and greater than 10 percent gravel classifying it as a medial (Donj eck-type) deposit. Gravels were cross-bedded to horizontally bedded and some displayed imbrication suggesting minor channel fills, bedforms, and channel lags as locations of deposition. Coarse and medium sands were mainly trough cross-bedded suggesting deposition on linguoid bars, which are common in Donjeck-type streams (Miall, 197 7). No analogs were found to distal (Platte-type) braided stream deposits in Kalamazoo County, likely for the reason that it is not as cost effective to have a sand and gravel pit in distal environments of deposition. This is most likely due to primarily two factors 1) the cost of gravel is much higher than the cost of sand, so less money will be made by the sale of sand and 2) the further from the Kalamazoo Moraine, the lower the elevation and the higher the water table, making excavation of sands difficult and costly when dewatering the area. The Schoolcraft Aquifer is located approximately 6 miles away from the Kalamazoo Moraine at Paw Paw Lake, which is considered to be the outlet of the river whose sediments compose the Prairie Rhonde Fan and Schoolcraft Aquifer. The bottom of the aquifer (27.5 to 20.5 m bgs) is dominated by gravel fining upward to medium sand, suggesting an intermediate location from the glacier or Donjeck-type braided stream. The medium sands, coarse sands and gravels are cross-stratified with coarser grains deposited along beds. The upper part of the aquifer (20.5 to 5 m bgs) is dominated by medium and fine sand with some very fine sand, silt and gravel. This corresponds well to the Platte type 89 braided stream described by Miall (1977). Further evidence for a Platte type braided stream is the presence of cross-stratified sands, massively bedded sands and silt. The cross-stratified sands may have formed in linguoid and transverse bars. The massively bedded sands may have stratification to fine to see at the core scale, or it may have been deposited during high discharge when all of the channels generally merge to create a sheet flow, as described by Krigstrom (1962). The silt described in the core is thought to have deposited during the last stages of waning flow when deposition of thin silt or mud drapes and channel fills occur in inactive areas (Miall, 1977; 1996 and Benn and Evans 1998) Miall (1977) stated that the Donj eck and Platte types may merge subtly into one another, supporting the degree of difficulty involved in identifying the boundary between medial and distal outwash facies. Although much uncertainty exists when classifying outwash into proximal, intermediate and distal zones, it is believed that the upper portion of the aquifer represents distal outwash (Platte-type) and the bottom portion of the aquifer represent intermediate outwash (Donj eck-type). This conclusion is based on the mean grain size, proportions of grain size, types of bedding, thickness of beds, fining upward cycles and distance from the Kalamazoo Moraine. Below the outwash, lies a light gray clay that was inferred by Mayotte (1991) to be laterally extensive beneath the Schoolcraft, thus marking the base of the aquifer for this study. This is a till unit that occurs beneath the Village of Schoolcraft and acts to retard the downward migration of plumes A-G (Lipinski, 2002). This till is likely the Ganges till reported by Monaghan et al. (1986) to crop out at the Tekonsha moraine and hence underlie sediments between the Tekonsha and Sturgis or Kalamazoo Moraines. 90 The gray till contains small quantities of sand and silt and was reported by Mayotte (1991) to have been encountered in several test borings at depths ranging from 21.3 to 30.5 m below grade. 91 Key for core descriptions Beddirg structure symbols and abbreviations Sm Massively bedded sand \\ g Cross Stratified bedding ‘2'}??3 Faint cross stratified bedding // fl Pebbles or granules along cross stratified bedding Faint laminar bedding Pebbles X-S beddigg cross stratified bedding M bedding massively bedflg Sorti abbreviations -sorted wm-sorted m-sorted well sorted well sorted well to sorted sorted to soned to soned sorted sorted Grain size abbreviations VF sand veg fine sand F sand fine sand M sand medium sand C sand coarse sand F-s-c sand fine sand with high silt and clay content F-m-vf sand fine sand with high medium and very fine sand content F-msand fine sand with high medium sand content F-m-c sand fine sand with high medium and coarse sand content F-m-g sand fine sand with high medium sand aflgranule content F-m-p sand fine sand with high medium sand and pebble content F-m-vf-p sand fine sand with high medium, very fine sand and pebble content M-f sand medium sand high fine sand content M-f-c sand medium sand with high fine and coarse sand content M-c sand medium sand witllgigh coarse sand content M-c-f sand medium sand with high coarse and fine sand content Mg sand medium sand with high granule content C-m sand coarse sand with high medium sand content £_-g sand coarse sand with higflgranule content C-p:g sand coarse sand with higgpebble and granule content Pebbles-c sand pebbles with higgcoarse sand content Other abbreviations "SKA same as above HCL hydrochloric acid Table A1. Key for core descriptions. 92 Well Name: P-18 Location: Plume A,Schoolcraft,Ml Page: _1_ of _§ Date: 1-5-01 thru 1-12-01 Described by: Susanne E. Biteman m Kcm/sec 2N N N m n (D l . I g '0 >-DI.u ' uJ ' Comments = g 984. 3 iii a iii a) "’ mo" ‘7 " ‘° 32% M sand, vp-sorted, subrounded with pebbles composed of limestone and quartzite, color dry 2.5Y 4/4 olive brown, coal <1%. ' ,_ M sand, w-sorted. subrounded to rounded with pebbles composed of quartzite, limestone and clumps of silt color dry 2. SY 6/4 light yellowish brown, coal 1 -2%. sand, m- sort ted, subrounded. pebbles increase downward. *1 M-c sand, w-sorted, subrounded, X-S bedding, coarser grains in X-S beds, coal 1%, abrupt change from above. ~ — Gradual change, granules are limestone and quartzite. ~ Pebbles, composed of quartzite, limestone, and chert vp- sorted, subrounded. ‘ SSA. except pebbles also granite and coal 1-1.5%. " M-c sand, m-sorted, subrounded to rounded, color dry _ 2.5Y 7/4 pale yellow. SAA, except coal present 1%, and subrounded. \'\ M-c sand with pebbles composed of quartzite, granite, limestone and dolomite, subrounded, mp—sorted, color 2.5Y 6/4, no coal. “ Clast supported rounded pebbles composed of granite, limestone, quartzite and schist, largest pebble 25x32 mm. \ “ C sand m-sorted, subrounded. ' C-g sand, mw-sorted, subrounded, clasts SAA , color \ dry 2.5Y 5/2 grayish brown. M-c sand, m-sorted, subrounded, color dry 2.5Y 6/3 . .. light yellowish brown. \ P 1 f; Gravel with pebbles, pvp-sorted, subrounded, color SAA. \ C-p-g sand. m-sorted, rounded to subrounded. i M-c sand, m-sorted. subrounded. ‘Pebbles composed of clay, silt, quartzite, vp-sorted. Gravel with sand and pebbles, m-sorted, subrounded. \\ Pebbles composed of sandstone, granite and quartzite, vp-sorted, rounded. f M-c sand m-sorted, subrounded, color SAA. “ M sand vw-sorted, subrounded, color SAA. Depth (m) a: / / / V \ \ M-g sand, w-sorted, subrounded, X-S bedding, color dry ‘ 2.5 Y 6/3, coal 1-1.5%. M sand vw-sorted, X-S bedding with coal along x-beds, coal 2%, color SAA. “ M sand w-sorted, subrounded, color SAA, coal 1-2%. ‘ SAA, except v. well sorted. \ SAA, except coal 15.-2.5%. ‘ SAA, except color wet 2. SY 5/3 light olive brown, dry 6/3 and coal -2 % ‘ SAA, except coal 0.5- 1.5%. * L M sand vw-to w- ~sorted, iubrounded, M bedded, color dry 2. SY 6/3, coalO i M-c sand, w-sorted, subrounded M bedding, color dry 2. SY 7/3, coal 1 .5.-2 5% \ Figure A.2.a. Core description of well P18. 93 Well Name: P-18 Location: Plume A,Schooleraft,Ml Page: 2 of 5 Date: 1-12-01l 7-19-01 thru 8-12-01 Described by: Susanne E. Biteman Depth (m) K (cm/sec) % “J “I‘ ‘1' ‘1’ "P Comments 3. Lu LU LlJ UJ L” m V. °°. N O. 10. T) N ‘— 4- (D 1— \j / IL 114% M-c sand,w—sorted, subrounded, X—S bedding, color wet 2.5Y ‘ 6/3 light yellowish brown, dry 2.5Y 7/3 pale yellow, coal _\7, _ \ concentrated along beds. “\\w—F sand, vw-sorted, subrounded, X-S bedding, coal \H concentrated along X-S bedding, coal 2-4%, color SAA. ’\\ F‘ 7\_-¥ SAA except color, color wet 5Y 5/2 olive gray, dry 5Y \\\ 6.5/2 light gray to light olive gray. \ SAA except color, color wet 2.5Y 5/4 light olive brown, dry 6/3. / F sand with larger grains, w-sorted, subangular, X-S bedding ,thickness between beds 3-15mm. Color wet 2.5Y 5/4 light olive brown, dry 6/3 light yellowish brown. ,. F sand, vw-sorted, subangular, thin laminations. Color wet 2.5Y 5/4 light olive brown, dry 2.5Y 7/3 light yellowish brown. F sand, vw sorted, subrounded, X-S bedding darker along beds. Color SAA “ F-m-vf sand, vw-sorted, subrounded, X-S bedding (3- 12 mm thick) darker grains and finer grains concentrated along beds. Color SAA \ F-vf-s-sand, w-sorted, subangular, X-S bedding (2—15 mm thick). Color SAA ‘\‘ F sand. vw-sorted, subangular, X-S bedding (2-10 mm thick), darker grains concentrated along beds, color SAA \\ F-m-s sand with pebble size grains at base, w-sorted, subrounded, X-S bedding (0.5-3 mm thick). Pebbles occur alon beds and are composed of calcium carbonate HCL reaction) cementing sand grains together. Color SAA \ F-vf-s-m sand, vw-sorted, subrounded, X-S bedding (0.5-2 mm thick). Color wet SAA \ F-m sand, some cobbles and pebbles wm-sorted, subrounded, X-S beddding 1mm thick 3mm apart, color saa. F sand, w-sorted, subrounded, bedding and color SAA. SAA. alternating dark and light beds \ F sand, w-sorted, subrounded, X-S bedding, 1-4 mm thick, 2-5 mm apart, coal 2-3 %, color saa. \ F sand, w—sorted, subrounded, X-S bedding, 1-3 mm thick, 1-3 mm apart, color saa. \ Color wet 2.5Y 5/2 \ Color wet 2.5Y 5/4. dry 2.5Y 7/3 ~ F-m-vf sand, w-sorted, subrounded. faint X-S bedding, color 2.5Y 5/4, dry 7/3 Figure A.2.b. Core description of well P18. Vertical K measurements shown in second column. 94 Well Name: P-18 Location: Plume A,Schoolcraft,Ml Page: 3 of 5 Date: 7-23-01 thru 8-17-01 Described by: Susanne E. Biteman Comments —l //./:e F m- vf sand w- -,sorted subrounded, color wet 2. SY 5/4, gr)!t light olive brown, dry 7/3 pale yellow, X- S bedding aInt. ~SAA, beds 1-2 mm apart, 2-4 mm thick. _ F-m sand, w-sorted, subrounded, thin X-S bedding (0.5-2 mm thick, 1 to 9 mm apart) color SAA. “SAA \ SAA, except coal 1-2% ~~ F- m- -p sand, p- -sorted, subrounded, X- S bedding 0. 5-1 mm thick, 7mm apartdarker grains and iron oxides are concentrated along beds, pebbles are sandcemented with calcium carbonate (HCL reaction), color SAA F- -m sand w-sorted, subrounded, X-S bedding,1% coal, color S \ F-m-vf sand, w-sorted subrounded, thin X-S bedding (0.5-2 mm thick), color SAA ‘ SAA, except, M bedding ‘ SAA, except, X-S bedding, 4-5 mm thick, 1 mm apart \ SAA, except X-S bedding, 0.5 thick. 2 mm apart SAA, except X-S bedding faint F- -m- -vf sand, w-sorled, subround dd F- m- -vf-p sand, moderately sorted, faint X- S bedding, color SAA \ M- -c- f--sand, w-sorted, subrounded, faint X- S bedding, color wet 2. SY 5/4 light olive brown, dry 6/3l ight yellowish brown, coal fragments % F m-g sand, wm-sorted, subrounded, color wet 2.5Y 5/4, dry 7/3, faint X- S- -bedding. M- sand with some granules wm- -sorted, subrouinded, coal wet 2. SY 5/4, dry 6/3 coal 1 %, X- Sb M-sand, m- sorted, rounded, color wet 2. 5Ye 4/4n o ive \\ brown, dry 7/3, weak X- S bedding \ Pebbles-c sand, vp-sorted. pebbles rounded, sand subrounded, color SAA M-f-c sand, vw-sorted, subrounded, coarser grains along X-S bedding contact at base of X-S bed, F sand beneath contact, color 2.5Y 5/4, dry 7/3. ‘F-m sand, vw-sorted, subrounded, M bedding, color wet 2.5Y 5/4, dry 7/4 pale yellow. \ M sand, w-sorted, subrounded, faint X-S bedding, color wet 2.5Y 4/4, dry 6/4 light yellowish brown, F sand, w-sorted, subrounded, M bedding, color wet, 2.5Y 5/4, dry 7/3 . M c sand, p- -sorted, rosunded, M bedded, color wet, \ 2. 5Y 4/3 (color, dS/4rg M sand, w- -sorte, su rounded, X- S bedding, 1% coal M sand, w-sorted, subrounded, faint X- S bedding, appears v. homogeneous, color wet, 2.5Y 5/4, dry 7 3 M sand, w-sorted, subrounded, M bedding \ SAA, except F-m sand, color wet 2.5Y 5/4, dry 7/3 SAA, except M sand Figure A.2.c. Core description of well P18. Vertical K measurements shown in second column. 95 Well Name: P-18 Location: _P_l_ume A, SchoolcraftI MI Page: 4 of 5 Date: 7-31-01 thru 8-22-01 Described by: Susanne E. Biteman [ K cmlsec I —3 N N 0? '8 ggE u', u‘, m Comments 5 to Q ‘1 “2 N O. a: a) 0,8 1- 4- 0 '- Sm F-m sand, w-sorted, subrounded, appears M bedded, color dry, 2.5Y 7/3 a M-f sand, w-sorted, subrounded, X-S bedding, color wet, 2.5Y5/4 light olive brown, dry 7/4 pale yellow \ F sand, w-sorted, subrounded, color wet 2.5Y 5/4 19.. \ F sand, w-sorted, subrounded, M bedding, color wet, 2.5Y 4/4 olive brown, dry 6/3 light yellowish brown, \ M sand, w-sorted, subrounded, M bedding, color wet, 2.5Y 5/4, dry 7/3 \ SAA, except M—c sand \ SAA, except, M-sand, one cobble 25x25x12 mm , MS-f sand, w-sorted, subrounded, faint X-S bedding, color AA. M-f sand, w-sorted, subrounded, M-bedded or faint X-S bedding, color SAA F-s—c sand, w-sorted, subrounded, coal 1-2 %, color wet 2.5Y 5/4, dry 7/4 pale yellow. * SAA, except fine laminations _ M sand, w-sorted, subrounded, M bedded, color SAA * SAA, except color wet 2.5Y 5/4, dry 7/3 c M-f—c sand, w-sorted, subrounded, M bedded, color wet 2.5Y 5/3 (color), dry 7/3 Depth (m) N _x P M-f-c sand, w-sorted, subrounded, M bedding, color wet, 2.5Y 5/4, dry 7/3 SAA, except rounded grains .. SAA, except subrounded grains — SAA except rounded grains — M-c sand, wm-sorted, rounded, M bedding, color wet, 2.5Y 4/4 (olive brown7), dry 6/3 (color) , x; 3', SAA, except faint X-S bedding Sm Figure A.9.d. Core description of well P18. Vertical K measurements shown in second column. 96 Well Name: P-18 Location: Plume A, Schoolcraft, MI Page: 5 of 5 Date: 7-18-01, 8-2_2l-01 thru 8-24-01 Described by: Susanne E. _Bitemg K cmlsec Comments M-f-c sand, wm-sorted, subrounded, faint X-S bedding at base, top is M bedded M—c sand, w-sorted, subrounded, faint X-S bedding at base, top is M bedded, color wet 2.5Y 5/4 light olive brown, dry 7/3 pale yellow M-c sand, w-sorted, rounded, M bedding, C-m sand, m-sorted, subrounded, X-S bedding (1-1.5 mm apart), color SAA C-m sand, wm-sorted, subrounded-rounded, coarser grains along X-S beds, color SAA M—c sand, w—sorted, subrounded, faint X-S bedding SAA, except M bedding 23 N A F-m sand, w-sorted, rounded, M-bedding, color SAA M-c-f sand, m-sorted, rounded, faint X-S bedding, color wet 2.5Y 4/4 olive brown?), dry 7/3 C-m sand, m-sorted, rounded, coarser grains along X-S bedding, fines upward, bed thickness 5-10 cm C-m sand, ,p-sorted, rounded, faint X-S bedding, color wet 2. SY 64 (color?), dry 5/6 (color), iron oxide present C-m sand, m-sorted, rounded, M-bedded with randomly placed pebbles, color wet 2.5Y 4/4, dry 7/4 (color) SAA, except faint X-S bedding M-c sand, m-sorted, rounded, no bedding preserved, color dry 2.5Y 6/3 M-c sand, p-sorted, rounded, large pebbles along X-S bedding, color wet 2.5Y 4/4, dry 6/3 M-c sand, p-sorted, rounded, faint X-S bedding, color wet 2.5Y 5/4, dry 7/4 Depth (In) M-c sand, m-sorted, rounded, M bedded, color wet 2.5Y 5/4, dry 6/4 SAA, except M-c sand Predominatly pebble sized grains with cobbles and sand, vp-sorted, rounded, X-S bedding thin 0.5-1 cm thick. Cobble (6 cm x 4.5 cm) with pebbles and finer grains, vp-sorted, rounded, no bedding preserved 26 27 Figure A.9.e. Core description of well P18. Vertical K measurements shown in second column. 97 Well Name: E Lomtion: Plume A, Schoolcraft, Ml Page: _1_ of2 Date: 1-3-01 thru 1-4-01 Described by: Susaflie E. Biteman Comments 11 F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 7/3 pale yellow, coal 2-3 %. F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, coal 2-3 "/0. F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 6/3 light yellowish brown, dry 2.5Y 7/3 pale yellow, coal 2-3 %. SAA, except color wet 2.5Y 5/4, dry 2.5Y 7/4 pale yellow. F sand, vw sorted, coal 3-4 %. Core was dry and loosely packed, no bedding was preserved. Depth (m) —L F sand, vw-sorted, subrounded, X—S bedding, color wet 2.5Y 5/4, dry 2.5Y 6/3, coal 2-3 %. 14 SAA SAA Figure A.3.a. Core description of well P6. 98 Well Name: l3 Location: Plume A, Schoolcrgft, Ml Page: _2_ ofg Date: 1-3-01 thru 1-4-01 Described by: Susa_nne E. Biteman Comments 15 F sand, vw-sorted, subrounded, X-S bedding, color dry 2.5Y 7/4 pale yellow. M sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 6/4 light yellowish brown, coal 0.5%. Depth (m) 18 Figure A.3.b. Core description of well P6. 99 Well Name: FIB-7 Location: Plume A, Schoolcraft, Ml Page: _1_ of; Date: 12-29—00 Described by: Susanneig. Bitema_r1 Comments M sand, w-sorted, rounded, M-bedding, color wet 2.5Y 5/3 light olive brown, wet 2.5Y 7/3 pale yellow, coal 3 %. 10 F sand, vw-sorted, subrounded, X-S bedding, color SAA, coal 3 %. F sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 7/4 pale yellow, coal 3 %. 11 F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 6/3 light yellowish brown, coal 2-3 %. E I: F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 4/4 5 olive brown, dry 2.5Y 7/3, coal 2-3 %. o a 12 F sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 coal 2-3 %. Gravel is poorly sorted. M sand, w-sorted, subrounded-rounded, M bedding, color wet 2.5Y 5/4 olive brown, dry 2.5Y 7/3, coal 1 %. 13 F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 4/4, dry 2.5Y 6/4 light yellowish brown, coal 2-3 %. Figure A.4.a. Core description of well P7. 100 Well Name: PlB-7 Location: Plume A, Schoolcraft, Ml Page: 3 of_2_ Date: 12-29-01 thru 1-3-01 Described by: Susanne E. Biteman in u '52 Comments I: > 1° 5 III ‘2 1° (0 to 0:8 - :7 F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 :;—// light olive brown, dry 2.5Y 7/3 pale yellow, coal 2 % coal _/ concentrated along beds. 14 — F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 4/4 % olive brown, dry 2.5Y 6/4 light yellowish brown, coal 2 %, coal § concentrated along beds. .1 - / F sand, vw-sorted, rounded-subrounded, X-S bedding, color SAA Z coal 2-3 %, coal concentrated along beds. 15“ F sand, vw-sorted, subrounded, color wet 5/4, dry 6/3. ' SAA, except grain size is M-sand E 5 —I o. o o 1 6 - _l 1 7- Figure A.4.b. Core description of well P7. 101 Well Name: PlB-8 Location: Plume/L Schoolcraft, Ml Page: _1 of § Date: 12-27-00 thru 12128-00 Described by: Susanne l_E. Biteman Comments Pebbles and cobbles, rounded, composed of sandstone and granite C-sand, poorly sorted, subrounded, color wet 2.5 Y 5/4 light olive brown, dry 2.5Y 6/4 light yellowish brown. F-sand, vw-sorted, subangular to subrounded, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 6/3 light yellowish brown, coal 3-4 %. F-sand, w-sorted, subangular, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 7/4 pale yellow, coal 3 %. F-sand, w-sorted, subrounded to subangular, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 6/3 light yellowish brown, coal 2-3 %. F-sand, w-sorted, subangular to subrounded, X-S bedding, color wet 2.5Y 5/3 light olive brown, dry 2.5Y 7/3 pale yellow, coal 2-3 % coal concentrated along beds. Depth (m) F-sand, w-sorted, subrounded to suban ular, X-S bedding, color wet 2.5Y 5/3 light olive brown, dry 2.5Y 7 3 pale yellow, coal 2-3 % coal concentrated along beds. F-sand, w-sorted, subrounded to subangular, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 7/3, coal 3—4 %, coal concentrated along beds. F-sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, coal 3-4 %. Figure A.5.a. Core description of well P8. 102 Well Name: FIB-8 Location: Date: 12-27-00 thru 12-28—00 Described by: Silt Sand gravel Icobbles 14 W \W/ Depth (m) 16.. 17- Hill! l|\\\l lIH‘I Plume A, Schoolcraft, Ml Page: 3 of § Susgnne E. Biteman Comments F-sand, w-sorted, subrounded, X-S bedding, color dry 2.5Y 7/4 pale yellow. F-sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 7/4, coal 4 %, coal concentrated along beds. F-sand, w-sorted, subrounded, faint X-S bedding, color wet 2.5Y 4/4 olive brown, dry 2.5Y 7/3 pale yellow, coal 4 %. Figure A.5.b. Core description of well P8. 103 Well Name: PlB-8 Location: Plume A, Schoolcra_ft, Ml Page: _3 of Q Date: 12-28-00 thrufl-ZB-OO Described by: Susagne E. Biteman in 1, E’ g Comments 5 5 e P In a) m 8 16 - ‘5‘1 7 .- 5 l a o D :1”; M-sand, w to vw-sorted, subrounded to rounded, X-S bedding, color /< wet 2.5Y 5/3 light olive brown, dry 2.5Y 7/3 pale yellow, coal 1-2 %. Q 18 - Figure A.5.c. Core description of well P8. 104 Well Name: PlB-8 Location: Plume A, Schoolcraft, Ml Page: _4_on Date: 12-28-00 thru 12_-28-00 Described by: Susanne E. Biteman in E 9% Comments E III 91° ‘0 Oi 19 - q 20 - _—-:::: F-m sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 ‘__../< light olive brown, dry 2.5Y 7/3 pale yellow, coal 1-2 %. E \\ E o. o _ o 21 22- M sand, moderately sorted, subrounded to rounded, faint X-S ‘ , bedding, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 7/3, coal 5 5 , : : 1-2 %. Figure A.5.d. Core description of well P8. 105 Well Name: PIE-8 Location: Plume A, SchoolcraflLhfl Page: _5_ of 6 Date: 12-29-00 thru 1;;9-00 Described by: Susanne E. Biteman E 13% Comments 55' III 91° 0) a) m§ 23- 244 E _ .C ‘5. 0 ..a o 25- 26- Figure A.5.a. Core description of well P8. 106 Well Name: PlB-8 Location: Plume A, Schoolcraft, Ml Page: _6_ of § Date: 12-29-00 thru 12-29-00 Described by: Susanne E. Bitemgnfi Silt Sand gravel [cobbles 28- Depth (In) 30— Comments Predominantly pebbles with granules, C sand and M sand, vp-sorted rounded, faint X-S bedding, color wet 2.5Y 4/3 olive brown, dry 2.5Y 7/2 light gray, coal <1%. Pebbles composed of chert, limestone, quartzite, and granite. Figure A.5.f. Core description of well P8. 107 Well Name: PlB-9 Location: Plume A, Schoolcrgfl,Ml Page: _1 of 2 Date: _1_2-19-00 thru 12-21-00 Described by: Susanne g. Bitemgg _— —8 m— :._- E 58 a) a) a8) § 10‘ \\ \ 112% // E ___,. 5 _\ a \____ O a 12 ______._ ::: £4:a Sm 13 // //\ 42:. Comments —— M-c sand, w-sorted, subrounded, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 6/3 light yellowish brown. — M-c sand with a large amount of cobbles and pebbles, m-sorted, subrounded, color wet 2.5Y 4/4 olive brown, dry 2.5Y 5/3 light olive rown. M sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 dry 2.5Y 7/4 pale yellow. F sand, vw-sorted, subrounded, faint X—S bedding color wet 2.5Y 5/4, dry 2.5Y 7/3 pale yellow. SAA F sand, w-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 6/3, coal 1 %. F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, coal 1 %. Pebbles are composed of sand cemented by calcium carbonate (HCL acid reaction). F sand with gravel size clasts composed of sand cemented by calcium carbonate, vp-sorted, subrounded, color wet 2.5Y 4/4, dry 2.5Y 6/4 light yellowish brown. F sand with pebbles, p-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4, dry 2.5Y 6/4, coal 3 %, coal concentrated along beds. Figure A.6.a. Core description of well P9. 108 Well Name: FIB-9 Location: flgme A, Schoolcraft, Ml Page: _2 of_2_ Date: 12-21-00 thru 12-27-00 Described by: Susanne LBitemgg Comments F sand, vw-sorted, subrounded, X-S bedding, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 6/4 light yellowish brown, coal 2-3 %. coal concentrated along beds. 14 F sand, w to vw-sorted, subrounded, X-S bedding, color wet 2.5Y 4/6 dark yellowish brown, dry 2.5Y 6/4, coal 3 %, coal concentrated along beds. F sand, w-sorted, subrounded, faint X-S bedding, color wet 2.5Y 4/4 olive brown, dry 2.5Y 7/4 pale yellow, coal 2-3 %. _s 01 Depth (m) 17 Figure A.6.b. Core description of well P9. 109 Well Name: PlB—11 Location: Plume A, Schoolcraft, MI Page: _1 of g Date: _1_2-15-00 thru ‘lj2-18-00 Described by: Susanne E. Biteman 0) 1, ‘52 Comments c >10 E «I 9‘3 co 0) 008 q M sand, w-sorted, rounded to subrounded, color wet 2.5Y 4/3 olive brown, dry 2.5Y 7/4 pale yellow. —.I 20 a 21- E .. .c a o. o .. O 22— 23- Figure A.7.a. Core description of well P11. 110 Well Name: PlB-11 Location: Plume A, Schoolcraft, Ml Page: 3 ofg Date: 41-15-00 thru 12-18-00 Described by: Susanne E. Biteman in 1, 62 Comments c > 1° 5' III 8 1° (0 (0 0:8 M sand with larger clasts, w-sorted, subrounded, color wet 2.5Y 5/4 - light olive brown, dry 2.5Y 6/3 light yellowish brown. 24 _ 111'], - M-c sand with pebble size clasts, w-sorted, subrounded, faint X-S 312:1? bedding, color wet 2.5Y 4/3 olive brown, dry 2.5Y 6/3. I _— _——_. Depth (m) re 01 n I 26- Figure A.7.b. Core description of well P11. 111 Well Name: PIE-12 Location: Plume A, SchoolcraftI Ml Page: _1_ of_4_ Date: 12-18-00 thru 12-19-00 Described by: Susanne E. Biteman Comments 13 Pm sand, vw-sorted, subrounded to rounded, X-S bedding, color wet 2.5Y 5/4 light olive brown, dry 2.5Y 7/4 pale yellow. 14 Depth (m) 16 Figure A.8.a. Core description of well P12. 112 Well Name: PlB-12 Location: Plume A, Schoolcraft, Ml Page: _2_ of 5 Date: _g—18-00 thru 12-19—00 Described by: Susgnne E. Biteman 1, 0% Comments 5 5 ED 0) (0 0:8 17- 184 E .r: ._ ‘6. 0 o 1911 20" .J Figure A.8.b. Core description of well P12. 113 Well Name: PlB-12 Location: PlumeA,Schoolcraft, Ml Page: ioffl Date: _1_2-18—00thru1g-19-00 Described by: Susanne g. Biteman 7 ll) 1, 9.3 Comments :5 5 9° (D a) 0% 21 1 22 - ..... F-m sand, w-sorted, subrounded to rounded, faint X-S bedding, _ : ff; : color wet 2.5Y 4/3 olive brown, dry 2.5Y 7/3 pale yellow. r~--: E Z : : ~ 2 I ._ a a o a 23— 24 _ Figure A.8.c. Core description of well P12. 114 Well Name: FIB—12 Location: Date: 12-18-00 thru 1&19'00 Described by: 3 E 93 E III 91° to (0 0:8 24 ‘ q 25- Depth (m) N ‘i’ 27" Plume A, SchoolcrafL Ml Page: i of g Susanne E. Biteman Comments Predominantly pebble, grain size ranges from M sand to cobbles, p-sorted, sand is subrounded, pebbles and cobbles are rounded, faint X-S bedding, color wet 2.5Y 4/3 olive brown, dry 2.5Y 6/2 olive gray. Figure A.8.d. Core description of well P12. 115 X Y Z LOG(K) (cmls) K (cmls) mean grain size sortirL 38.7 22.5 2.0 -1.49E+00 3.26E-02 v. fine sand v-poody 38.7 22.5 2.1 -1.18E+00 6.61 E-02 38.7 22.5 2.3 -1.05E+00 8.88E-02 38.7 22.5 2.5 -1.21E+00 6.20E-02 coarse sand poorly 38.7 22.5 2.9 -1.35E+00 4.42E-02 38.7 22.5 3.2 -1.64E+00 2.27E-02 38.7 22.5 3.4 -1.01E+00 9.69E-02 38.7 22.5 3.6 -1.16E+00 6.98E-02 38.7 22.5 3.8 -9.76E-01 1.06E-01 38.7 22.5 4.4 -1.57E+00 2.71 E-02 38.7 22.5 4.9 -1.17E+00 6.75E-02 38.7 22.5 5.1 -1.73E+00 1.86E-02 very fine sand moderately 38.7 22.5 5.3 -1.69E+00 2.04E-02 38.7 22.5 5.6 -1.5SE+00 2.79E-02 38.7 22.5 5.9 -1 .55E+00 2.79E-02 38.7 22.5 7.2 -1 .56E+00 2.75E-02 38.7 22.5 7.4 -1.52E+00 3.02E-02 38.7 22.5 7.8 -1 .42E+00 3.84E-02 38.7 22.5 8.2 -1.44E+00 3.59E-02 38.7 22.5 8.4 -1.41E+00 3.90E-02 med sand moderately 38.7 22.5 8.6 -1 .27E-I-00 5.38E-02 38.7 22.5 9.3 -1.46E+00 3.47E-02 38.7 22.5 9.6 -1.57E+00 2.67E-02 38.7 22.5 9.9 -1.20E+00 6.28E-02 38.7 22.5 10.1 -1.36E+00 4.37E-02 coarse sand v-poorly 38.7 22.5 10.5 -1.53E+00 2.98E-02 38.7 22.5 11.0 -1.43E+00 3.76E-02 38.7 22.5 11.2 -1.41E+00 3.85E-02 38.7 22.5 11.4 -1.35E+00 4.51 E02 38.7 22.5 11.8 -1.90E+00 1.26E-02 38.7 22.5 12.0 -1.84E+00 1.43E—02 fine sand m-well 38.7 22.5 12.3 -1.98E+00 1.04E-02 38.7 22.5 12.9 -1 .90E+00 1.25E-02 38.7 22.5 13.9 -1.94E+00 1 .15E-02 38.7 22.5 14.1 -1.88E+00 1.31 E-02 fine sand well 38.7 22.5 14.4 -1.88E+00 1.31E-02 38.7 22.5 14.7 -1.86E+00 1.38E-02 fine sand well 38.7 22.5 15.5 -1.92E+00 1.20E-02 38.7 22.5 15.9 -2.07E+00 8.60E-03 38.7 22.5 16.4 -1.85E+00 1.41 E-02 38.7 22.5 16.7 -2.05E+00 8.90E-03 38.7 22.5 17.2 -1.97E+00 1.06E-02 v. fine sand well 38.7 22.5 17.6 -1.96E+00 1.09E-02 v. fine sand well 38.7 22.5 18.0 -1 .4ZE+00 3.84E-02 Table A2. Well D2. X, Y and 2 location, Log K value, K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)). 116 X Y Z LOG(K) (cmls) K (cmls) mean ggin size sortirg 38.8 24.4 3.5 -1.14E+00 7.24E-02 38.8 24.4 3.9 -1.37E+00 4.23E-02 38.8 24.4 4.3 -1.52E+00 3.00E-02 38.8 24.4 5.0 -1.34E+00 4.59E-02 38.8 24.4 5.4 -1.73E+00 1.86E-02 38.8 24.4 5.6 -1 .66E+00 2.20E-02 38.8 24.4 7.3 -1.54E+00 2.90E-02 fine sand well 38.8 24.4 8.1 -1.61E+00 2.46E-02 med sand m-well 38.8 24.4 8.5 -1.55E+00 2.83E-02 38.8 24.4 8.9 -1 .72E+00 1 .89E-02 38.8 24.4 10.9 -1.58E+00 2.64E-02 38.8 24.4 11.3 -1.53E+00 2.98E-02 38.8 24.4 11.7 -1.98E+00 1.04E-02 fine sand moderately 38.8 24.4 1 1.9 -1 .88E+00 1.32E-02 38.8 24.4 13.0 -1.90E+00 1.26E-02 38.8 24.4 13.4 -1.99E+00 1.03E-02 38.8 24.4 14.0 -2.09E+00 8.20E-03 fine sand m-well 38.8 24.4 14.4 -1 .80E+00 1.60E-02 38.8 24.4 14.7 -1.80E+00 1.60E-02 38.8 24.4 15.1 -1.88E+00 1.32E-02 38.8 24.4 16.3 -1.97E+00 1.07E-02 v. fine sand well 38.8 24.4 17.0 -2.37E+00 4.30E-03 38.8 24.4 17.4 -1.89E+00 1 .29E-02 38.8 24.4 17.8 -2.13E+00 7.40E-03 v. fine sand well 38.8 24.4 18.0 -1.81E+00 1.56E-02 fine sand moderately Table A3. Well D4. X, Y and 2 location, Log K value, K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)). 117 X Y Z LOG(K) (cm/s) K (cmls) mean grain size sorting 38.8 26.4 0.6 -1 .07E+00 8.59E-02 granules v-poorly 38.8 26.4 1 .0 -1.18E+00 6.62E-02 38.8 26.4 1.3 -1.04E+00 9.02E-02 v. fine sand v-poorly 38.8 26.4 1.5 -1.59E+00 2.55E-02 med sand poorly 38.8 26.4 3.9 -1 .20E+00 6.38E-02 38.8 26.4 4.2 -9.91E-01 1.02E-01 38.8 26.4 4.5 -1.29E+00 5.10E-02 38.8 26.4 4.7 -1.18E+00 6.59E-02 med sand moderately 38.8 26.4 5.0 -1.21E+00 6.19E-02 38.8 26.4 5.4 -1.66E+00 2.17E-02 fine sand moderately 38.8 26.4 5.9 -1.60E+00 2.54E-02 38.8 26.4 7.3 -1 .52E+00 3.03E-02 38.8 26.4 7.7 -1.53E+00 2.93E-02 38.8 26.4 8.1 -1.59E+00 2.59E-02 fine sand moderately 38.8 26.4 8.5 -1.61E+00 2.47E-02 38.8 26.4 9.4 -1.49E+00 3.22E-02 fine sand m-well 38.8 26.4 9.8 -1.55E+00 2.79E-02 med sand moderately 38.8 26.4 10.2 -1.40E+00 3.95E-02 med sand poorly 38.8 26.4 11.0 -1 .52E+00 3.05E-02 38.8 26.4 11.3 -1.50E+00 3.18E-02 38.8 26.4 11.7 -1.63E+00 2.33E-02 38.8 26.4 12.1 -1 .83E+00 1 .48E-02 38.8 26.4 13.0 -1 .89E+00 1.28E-02 38.8 26.4 13.4 -1.84E+00 1.44E-02 38.8 26.4 13.8 -2.14E+00 7.20E-03 38.8 26.4 14.2 -1.91E+00 1.22E-02 38.8 26.4 14.6 -1.81E+00 1.55E-02 38.8 26.4 15.0 -1 .88E+00 1 .33E-02 38.8 26.4 15.8 -2.04E+00 9.10E-03 38.8 26.4 16.2 -1.90E+00 1 255-02 38.8 26.4 16.6 -2.14E+00 7.30E-03 38.8 26.4 17.0 -2.10E+00 7.90E-03 38.8 26.4 17.4 -2.04E+00 9.10E-03 38.8 26.4 17.8 -2.10E+00 8.00E-03 38.8 26.4 18.1 -1.77E+00 1.70E—02 coarse sand v-poorly Table A.4. Well 06. X, Y and 2 location, Log K value, K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)). 118 X Y Z LOGQQ (cm/s flemls) meangrain size sorting 38.8 28.4 1 .0 -1 .46E+00 3.46E-02 38.8 28.4 1.4 -1 .23E+00 5.91 E02 38.8 28.4 1.8 -1.23E+00 5.90E-02 38.8 28.4 2.2 -1.16E+00 6.87E-02 38.8 28.4 2.6 -1.18E+00 6.61E-02 38.8 28.4 3.0 -1 .45E+00 3.55E-02 38.8 28.4 4.1 -1 .63E+00 2.35E-02 38.8 28.4 4.5 -1.45E+00 3.57E-02 38.8 28.4 5.1 -1 .73E+00 1 .85E-02 38.8 28.4 5.7 -1 .41E+00 3.92E-02 38.8 28.4 7.1 -2.96E+00 1.10E-03 38.8 28.4 8.3 -1 .77E+00 1.70E-02 38.8 28.4 8.7 -1.52E+00 3.03E-02 med sand moderately 38.8 28.4 10.2 -1 .83E+00 1 .48E-02 38.8 28.4 10.6 -1.94E+00 1.14E-02 38.8 28.4 11.1 -1.50E+00 3135-02 38.8 28.4 11.6 -1.71E+00 1.96E-02 38.8 28.4 14.6 -1.79E+00 1.61 E02 fine sand well 38.8 28.4 14.9 -2.00E+00 9.90E-03 fine sand m-well 38.8 28.4 15.8 -1 .98E+00 1.04E-02 38.8 28.4 16.2 —2.39E+00 4.04E-03 38.8 28.4 16.6 -1 .49E+00 3.20E-02 Table A5. Well D8. X, Y and 2 location, Log K value, K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)). 119 X Y Z LOG-(K) (cmls) K (cmls) mean grain size sorting___l 38.7 30.4 0.9 -1 .34E+00 4.60E-02 granules v-poorlL 38.7 30.4 1.0 -1.29E+00 5.12E-02 pebble poorly 38.7 30.4 1 .2 -9.87E-01 1 .03E-01 pebble v-poorly 38.7 30.4 3.3 -1.54E+00 2.87E-02 coarse sand v-poorly 38.7 30.4 3.7 -1.18E+00 6.64E-02 38.7 30.4 4.1 -1.18E+00 6.62E-02 38.7 30.4 5.3 -1.34E+00 4.56E-02 med sand poorly 38.7 30.4 5.8 -1.71E+00 1.93E-02 38.7 30.4 6.5 -2.68E+00 2.10E-03 38.7 30.4 6.9 -2.60E+00 2.50E-03 fine sand moderater 38.7 30.4 7.3 -2.20E+00 6.30E-03 38.7 30.4 7.9 -1.59E+00 2.59E-02 38.7 30.4 8.3 -1.55E+00 2.82E-02 med sand m-well 38.7 30.4 8.7 -1.59E+00 2.56E-02 38.7 30.4 9.0 -1 .83E+00 1 .49E-02 38.7 30.4 9.8 -1.55E+00 2.82E-02 fine sand well 38.7 30.4 10.2 -1.51E+00 3.11E-02 med sand poorly 38.7 30.4 11.3 -1.53E+00 2.98E-02 med sand moderately 38.7 30.4 11.7 -1.53E+00 2.96E-02 38.7 30.4 12.1 -1.72E+00 1.89E-02 38.7 30.4 13.4 -2.00E+00 1 .01E-02 fine sand m-well 38.7 30.4 14.2 -1.96E+00 1.10E-02 fine sand m-well 38.7 30.4 14.6 -1.81E+00 1.56E-02 fine sand moderately 38.7 30.4 15.0 -1.89E+00 1.29E-02 fine sand poorly 38.7 30.4 15.9 -2.30E+00 5.00E-03 38.7 30.4 16.2 -1 .99E+00 1 .03E-02 38.7 30.4 16.6 -1.91E+00 1.24E-02 fine sand moderately 38.7 30.4 17.4 -2.17E+00 6.70E-03 38.7 30.4 17.7 -1.95E+00 1.12E-02 38.7 30.4 18.2 -2.07E+00 8.60E-03 med sand poorly Table A6. Well D10. X, Y and 2 location, Log K value, K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)). 120 X Y Z LOG(K) (cmls) K (cmls) mean grain size sorting 38.7 32.4 3.8 -1.55E+00 2.85E-02 med sand poorly 38.7 32.4 4.2 -1.19E+00 6.49E-02 38.7 32.4 5.2 -1.53E+00 2.94E-02 38.7 32.4 5.5 -1.57E+00 2.68E-02 38.7 32.4 5.9 -1.61E+00 2.47E-02 fine sand m-well 38.7 32.4 7.0 -2.82E+00 1.50E-03 very fine sand m-well 38.7 32.4 7.4 -1 .74E+00 1 .84E-02 38.7 32.4 8.3 -1 .41 E+00 3.92E-02 med sand moderately 38.7 32.4 8.8 -2.28E+00 5.20E-03 med sand moderately 38.7 32.4 9.4 —1 .58E+00 2.63E-02 38.7 32.4 9.8 -1.54E+00 2.90E-02 38.7 32.4 10.2 -1.49E+00 3.21 E-02 fine sand poony 38.7 32.4 10.9 -1.52E+00 3.00E-02 38.7 32.4 11.3 -1.48E+00 3.33E-02 fine sand m-well 38.7 32.4 11.7 -1.54E+00 2.86E-02 38.7 32.4 12.8 -1 .85E+00 1 .40E-02 38.7 32.4 13.2 -1 .97E+00 1 .08E-02 38.7 32.4 13.6 -1.94E+00 1.14E-02 fine sand m-well 38.7 32.4 14.0 -2.15E+00 7.00E-03 38.7 32.4 14.4 -1.74E+00 1.82E-02 38.7 32.4 14.8 -1.85E+00 1.41E-02 fine sand poorly 38.7 32.4 15.4 -2.09E+00 8.10E-03 38.7 32.4 15.9 -1.95E+00 1.12E-02 38.7 32.4 16.3 -1.90E+00 1.25E-02 fine sand well 38.7 32.4 16.9 -1.97E+00 1.06E-02 38.7 32.4 17.2 -1.83E+00 1 .48E-02 38.7 32.4 17.6 -1.78E+00 1.67E-02 38.7 32.4 18.0 -1.91E+00 1.23E-02 pebble poorly Table A]. Well D12. X, Y and 2 location, Log K value, K value, mean grain size (determined by sieve analysis), and sorting (determined by standard deviation of grain size (Boggs, 2001)). 121 X Y Z LOG-(K) (cmls) K (cmls) mean grain size sorthg 38.8 34.3 0.5 -1 .47E+00 3.40E-02 pebble v-poorly 38.8 34.3 0.7 -1 .40E+00 3.97E-02 Jebble v-poorly 38.8 34.3 0.9 -1 .04E+00 9.02E-02 granules poorly 38.8 34.3 1.1 -1.57E+00 2.72E-02 granules poorly 38.8 34.3 1.3 -1.37E+00 4.28E-02 med sand poorly 38.8 34.3 1.7 -1.38E+00 4.17E-02 coarse sand poorly 38.8 34.3 2.2 -1.24E+00 5.77E-02 coarse sand poorly 38.8 34.3 2.6 -1.17E+00 6.76E-02 38.8 34.3 3.1 -1.25E+00 5.58E-02 38.8 34.3 3.3 -1.25E+00 5.67E-02 38.8 34.3 3.5 -1.21E+00 6.24E-02 med sand m 38.8 34.3 3.9 -1.15E+00 7.03E-02 38.8 34.3 6.8 -1.64E+00 2.28E-02 38.8 34.3 8.1 -1.58E+00 2.64E-02 fine sand m 38.8 34.3 8.5 -1.43E+00 3.70E-02 med sand moderately 38.8 34.3 9.0 -1.57E+00 2.67E-02 38.8 34.3 9.6 -1.65E+00 2.25E-02 med sand poorly 38.8 34.3 10.0 -1.36E+00 4.34E-02 fine sand m-well 38.8 34.3 10.5 -1.69E+00 2.04E-02 fine sand m-well 38.8 34.3 10.9 -1.68E+00 2.08E-02 38.8 34.3 11.1 -1.71E+00 1.96E-02 38.8 34.3 11.9 -1.94E+00 1 .15E-02 38.8 34.3 13.2 -2.10E+00 7.95E-03 fine sand m-well 38.8 34.3 13.6 -1.90E+00 1.27E-02 38.8 34.3 14.9 -1.92E+00 1.20E-02 veryfine sand moderately 38.8 34.3 15.7 -2.01E+00 9.70E-03 38.8 34.3 16.1 -2.06E+00 8.70E-03 38.8 34.3 16.6 -1.91E+00 1.22E-02 38.8 34.3 17.0 -1.80E+00 1.58E-02 fine sand well 38.8 34.3 17.4 -2.03E+00 9.30E-03 38.8 34.3 17.8 -1.91E+00 1 .24E-02 Table A8. 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Nd 8:08.". 132 8:80.:00-8:_. 88.800 .0 .0. 8 8.8030008... 0:88 8:: 9 E089 8.80.300 88.0000 0:8 88.008789. .:8>.8 8. 88:8: 8N.8 :.8:8 0:8 .80:8.. .850 88.08. 8:...08 .8N.8 :.8:8 :88... 880:5: 08m .58 8.38.". :. 559.8 80.8:8 00.0.20 .0 8:008:08... 6.8 8.08 h 2.00 88:8 8...: 8 08:. 8. 00.8.: :0 82008.- 8.... 8 .8 =83 8.008. - o... .8 =8; 8.08.- m... .8 =8; 88.0000-0:88 08E .8 .8300... 88.0000-0:88 08E .8 .8.8:800E 0:88 9 .8>8: on 0:88 8:...> 88.0000 .8 0:88 8N 88.0000 0:8 88.008.-8:.. .00.. .80.... 88.008. E0058. .8 .98.800E 0:88-... 8N 88:. 08:. . 8. 88.800 8E08 ..0E0.. .806 .8 =83. 0:88 ..5. R 888:8. 88.8 58.8 _ .850 _88.08u.|_ 8:...08 _ 88.8 :.8.8 :88... _080 133 REFERENCES Adams, E. E., and Gelhar, L., 1992, Field study of dispersion in a heterogeneous aquifer, 2. Spatial moments anaylsis: Water Resources Research, v. 28, no. 12, p. 3293- 3307 Anderson, M. P., Aiken, J. S., Webb, E. K., and Mickelson D. 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