1.. ‘va {F.Hlsh .u“ a V .afiisrfl. gang... . . .3 . J, . Laiefinnrfi. sl- ' . . I a .sn:;: .0: .Dé .7 T . 7-15.41... . . 3...... Eu: 2 1.1.2.2. .i W 1.7%.”. n at! :I. p 5.1 n m...“ . . 4 i .51.. . . ‘ 4h! Wrm 6.3.3“; A :1. .fl 1. , 1! :NH It." xtetl‘ i 4 In... [1.2.12.1 4:133 tn 9...! 0‘ r!) “#99:; ..... ~ 63.1.2.2. . :61» a}. Qanurliii I'.<’ 0.43- If: .u ‘fAhnfluh... .1. q ‘ . . 10:4! .5... 4 .WF ‘l Isl“. l‘q-trf '4 ill. . . | 165.. hiya-.7! ‘. 1 p‘liryir 441.P:F...O. . . . ‘ ‘ I. .r.. ’ ‘ . [m 2030 LIBRARY Michigan State University This is to certify that the thesis entitled LAND USE / LAND COVER AND WATER QUALITY IN THE MUSKEGON RIVER WATERSHED, MICHIGAN: A M.A. CASE STUDY presented by Ranjeet John has been accepted towards fulfillment of the requirements for the degree in 6&8th / Major rofessor’s Signature 09/06/05 Date MSU is an Affirmative Action/Equal Opportunity Institution PLACE IN RETURN BOX to remove this checkout from your record. TO AVOID FINES return on or before date due. MAY BE RECALLED with earlier due date if requested. DATE DUE DATE DUE DATE DUE WM 31 ion 2/05 czfimmjlfld-pJS LAND USE / LAND COVER AND WATER QUALITY IN THE MUSKEGON RIVER WATERSHED, MICHIGAN: A CASE STUDY BY Ranjeet John A THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of MASTER OF ARTS Department of Geography 2005 ABSTRACT LAND USE / LAND COVER AND WATER QUALITY IN THE MUSKEGON RIVER WATERSHED, MICHIGAN: A CASE STUDY By Ranjeet John Water quality in the Muskegon River Watershed is a function of land use such as agriculture, residential development, industry, and transportation. Ongoing residential development around the lakes as well as nutrient-rich runoff from urban and agricultural landscapes affect water quality. Landsat 7 (ETM+) imagery was used to obtain an LULC map in the MRW through an unsupervised classification. Surface hydrological modeling was performed on a SRTM DEM to delineate first order sub- watersheds, which are more susceptible to non-point pollution as they have no upstream contributing flow. This study compares LULC (2001-2002) in the MRW with water quality indices such as total nitrogen (TN), total phosphorus (T P), specific conductivity, sensitive insect species (EPT taxa) and total invertebrate taxa. Results indicate that there is significant correlation between an increase in proportions of agricultural / urban land use within the watershed and water quality indices such as total phosphorus concentration. In addition, there was a negative correlation between the percentage of urban land use within the sub-watershed and sensitive insect taxa as well as invertebrate populations. TN and TP concentrations were also influenced by distance to urban and agricultural areas respectively. ACKNOWLEDGEMENTS I would like to express my appreciation to members of my research committee for their patience and helpfulness. Special thanks to my graduate advisor, Dr. Jiaguo Qi, who helped me improve my professional abilities by giving me the opportunity to work on different projects including the MRW project. I would like to thank Dr. Joseph Messina and Dr. Ashton Shortridge for reading and editing previous drafts of this thesis. This work would not have been possible without the timely comments and suggestions made by the committee. I would like to thank my colleagues at the Center for Global Change and Earth Observations (CGCEO) and the Department of Geography, Michigan State University for their support. Special thanks to Eraldo Matricardi and Dr. Cuizhen Wang for their patience in answering my questions and for being role models. I would also like to thank Dr. David Lusch for his helpfulness over the past few years. This work was supported by the Muskegon River Watershed Ecological Assessment Project (MRWEAP) and the NASA LULCC grant (NNGOSGD496) at Michigan State University. iii TABLE OF CONTENTS List of Tables ................................................................................................... vii List of Figures ................................................................................................... ix List of Abbreviations ........................................................................................ xii CHAPTER 1 INTRODUCTION - - l3 1 .1 Background ................................ ' ........................................................... 1 3 1.2 Problem statement and objectives ........................................................ 14 1.3 Study area ............................................................................................ 16 1 .4 Hypothesis ............................................................................................ 18 1 .5 Sub-hypothesis ..................................................................................... 18 1.6 Benefits of this research ....................................................................... 18 CHAPTER 2 LITERATURE REVIEW - 20 2.1 Land use and water quality ................................................................... 20 2.1.1 First order watersheds ............................................................................... 25 2.1.2 Land use in the Muskegon River Watershed ......................................... 27 2.2 EPA monitoring programs in the US ..................................................... 31 2.2.1 The Environmental Monitoring and Assessment Program (EMAP)... 31 2.2.2 EPT taxa ...................................................................................................... 32 2.3 Surface hydrological modeling .............................................................. 33 2.3.1 Advantages of SRTM DEMs ..................................................................... 33 2.3.2 Digital terrain modeling and topographic attributes .............................. 34 iv CHAPTER 3 METHODOLOGY 36 3.1 Surface hydrological modeling .............................................................. 36 3.1.1 Acquisition and pre-processing of SRTM derived DEMs ..................... 36 3.1.2 Delineation of Strahler stream order using D-8 flowline derived stream network ......................................................................................................... 37 3.1.3 Delineation of first order watersheds, percent slope and wetness index ............................................................................................................. 40 3.2 Classification of ETM+ imagery using unsupervised method ................ 43 3.2.1 Imagery inventory ....................................................................................... 43 3.2.2 Image pre-processing and unsupervised classification ....................... 46 3.2.3 LULC within MRW ...................................................................................... 56 3.2.4 Mapping of surface water quality indicators ........................................... 57 3.2.5 Proximity to LULC types ............................................................................ 58 3.2.6 Scale issues in relating LULC to water quality ...................................... 58 CHAPTER 4 RESULTS AND DISCUSSION- _- 60 4.1 LULC and water quality in the MRW ..................................................... 60 4.1.1 Specific conductivity and percentage of LULC ...................................... 60 4.1.2 TN concentration and percentage of LULC ........................................... 63 4.1.3 TP concentration and percentage of LULC ............................................ 79 4.1.4 Total invertebrate taxa and percentage of urban land 'use .................. 94 4.1.5 Total EPT taxa and percentage of urban land use ............................... 95 4.1.6 Proximity to urban areas ........................................................................... 97 4.1.7 Proximity to agricultural areas .................................................................. 99 CHAPTER 5 CONCLUSIONS 101 APPENDICES APPENDIX-A: APPENDIX B: BIBLIOGRAPHY FIGURES USED IN THE STUDY DATA USED IN STATISTICAL ANALYSIS vi 106 - 107 116 119 Table 3-1. Table 3-2. Table 3-3. Table 3-4. Table 3-5. Table 3-6. Table 3-7. Table 4-1. Table 4-2. Table 4-3. Table 4-4. Table 4-5. Table 4-6. Table 4-7. Table 4-8. Table 4-9. List of Tables Satellite data ...................................................................................... 44 ETM+ spectral radiance range in w/ (m2.sr.um) ................................. 48 ETM+ solar spectral irradiances ......................................................... 49 ETM+ scenes and their geo-referencing parameters ......................... 50 Accuracy assessment for MRW LULC mosaic ................................... 54 Confusion matrix for MRW LULC mosaic ........................................... 54 LULC within MRW .............................................................................. 56 Correlation between specific conductivity (u siemens) and LULC typtgs) Urban land use in sub-watersheds greater than 1% .......................... 62 Correlation between specific conductivity (p siemens) and urban land use within sub-watershed ................................................................ 62 Correlation between TN concentrations and LULC within sub- watershed ........................................................................................ 63 Correlation between TN concentrations and LULC within first order watershed ........................................................................................ 64 Percentage of LULC (within sub-watersheds) vs. TN concentrations 66 Percentage of LULC (within first order watersheds) vs. TN concentrations ................................................................................. 70 Correlation between TP concentrations and LULC within sub- watersheds ...................................................................................... 79 Correlation between TP concentrations and LULC within first order watersheds ...................................................................................... 80 Table 4-10. Percentage of LULC (within sub-watersheds) vs. TP concentrations ......................................................................................................... 81 Table 4-11. Percentage of LULC (within first order watersheds) vs. TP concentrations ................................................................................. 85 vii Table 4-12. Percentage of urban land use vs. total invertebrate population within sub-watersheds ............................................................................... 94 Table 4-13. Percentage of urban land use correlated with sensitive insect population within sub-watersheds .................................................... 96 Table 4-14. Proximity to urban areas & TN concentrations within MRW ............. 97 Table 4-15. Proximity to urban areas & TP concentrations within MRW ............. 98 Table 4-16. Proximity to urban areas vs. TN concentrations within MRW ........... 99 Table 4-17. Proximity to agricultural areas & TN concentrations within MRW ....99 Table 4-18. Proximity to agricultural areas & TP concentrations within MRW...1OO Table 5-1. Water quality indicators within MRW sub-watersheds ..................... 116 Table 5-2. Water quality indicators within MRW sub-watersheds ..................... 117 Table 5-3. Percentages of LULC types within sub-watersheds ......................... 118 viii Figure 1-1. Figure 2-1. Figure 3-1. Figure 3-2. Figure 3-3. Figure 3-4. Figure 3-5. Figure 3-6. Figure 3-7. Figure 4-1. Figure 4-2. Figure 4-3. Figure 4-4. Figure 4-5. Figure 4-6. Figure 4-7. List of Figures Muskegon River Watershed .............................................................. 17 MRW: ecological classification .......................................................... 28 Flow chart to extract watersheds from DEM ..................................... 39 DEM flow direction artifacts created due to the nature of the D8 flow line algorithm ................................................................................... 41 Muskegon first order watershed coverage obtained using binary mask of Strahler stream network ............................................................... 41 Spatial extent of MRW overlaid with WRS-2 (Landsat) footprint ....... 43 Spatial extent of MRW overlaid with county boundaries and Digital Ortho Quarter Quads (DOQQ’s) ...................................................... 45 Spatial extent of MRW overlaid with county boundaries and pan sharpened lKONOS imagery ........................................................... 46 Flow chart for image processing of DN to surface reflectance .......... 47 Percentage of agricultural land use (within sub-watersheds) vs. TN concentrations ................................................................................. 66 Percentage of agricultural & urban land use (within sub-watersheds) vs. TN concentrations ...................................................................... 68 Percentage of human use index (urban + agriculture + bare soil within sub-watersheds) vs. TN concentrations ........................................... 69 Percentage of agricultural land use (within first order-watersheds) vs. TN concentrations ............................................................................ 71 Percentage of agricultural & urban land use (within first order watersheds) vs. TN concentrations .................................................. 72 Percentage of human use index (urban + agriculture + bare within first order watersheds) vs. TN concentrations .................................. 73 Percentage of forests (within sub-watersheds) vs. TN concentrations ......................................................................................................... 74 ix Figure 4-8. Percentage of forests (within first order watersheds) vs. TN concentrations ................................................................................. 75 Figure 49 TN and TP concentration distribution overlaid on % agricultural land use ................................................................................................... 78 Figure 4-10. Percentage of agricultural land (within sub-watersheds) vs. TP concentrations ................................................................................. 82 Figure 4-11. Percentage of urban & agricultural land (within sub-watersheds) vs. TP concentrations ............................................................................ 83 Figure 4-12. Percentage of human use index within sub-watersheds vs. TP concentrations ................................................................................. 84 Figure 4-13. Percentage of agriculture (within first order -watersheds) vs. TP concentrations ................................................................................. 86 Figure 4-14. Percentage of urban & agriculture (within first order-watersheds) vs. TP concentrations ............................................................................ 87 Figure 4-15. Percentage of human use index (urban + agriculture + bare within first order watersheds) vs. TP concentrations .................................. 88 Figure 4—16. Percentage of forests vs. TP concentrations within sub-watersheds ......................................................................................................... 89 Figure 4-17. Percentage of forests vs. TP concentrations within sub-watersheds ......................................................................................................... 90 Figure 4-18. TN and TP concentrations overlaid on % human use index ........... 92 Figure 5-1. Imagery from WRS Path 21 Row 30 Landsat 7 (ETM+) ................. 107 Figure 5-2. Imagery from WRS Path 22 Row 30 Landsat 7 (ETM+) ................. 108 Figure 5-3. MRW-LULC map derived through unsupervised classification ...... 109 Figure 5-4. MRW—LULC map derived through unsupervised classification and smoothed with 3x3 majority filter .................................................... 110 Figure 5—5. SRTM derived Digital Elevation Model (DEM) ................................ 111 Figure 5-6. SRTM derived DEM overlaid with Strahler stream order ................ 112 Figure 5-7. Wetness index derived from SRTM DEM overlaid with MRW wetlands coverage ........................................................................................ 1 13 Figure 5-8. Urban development around Lake Houghton (2001) ........................ 114 Figure 5-9. Urban development around Lake Higgins (2001) ........................... 115 Images in this thesis are presented in color. xi List of Abbreviations AOI CAFO CGCEO DEM DN DOQQ DTED EPA EPT ETM+ H.U.lndex ISA ISODATA IWI LULC MDNR MIRIS MMU MRW ' MRWEAP NAWQA NRCS NPS SRTM TOA TN TP TRFIC UTM WGS WI Area Of Interest Confined Animal Feeding Operation Center for Global Change and Earth Observation Digital Elevation model Digital Number Digital Ortho Quarter Quads Digital Elevation Terrain Data Environmental Protection Agency Ephemeroptera, Plecoptera & Trichoptera, Enhanced Thematic Mapper Human Use Index lmpervious Surface Area Iterative Self-Organizing Data Analysis Technique Index of Watershed Indicators Land Use / Land Cover Michigan Department of Natural Resources Michigan Resource lnforrnation System Minimum Mapping Unit Muskegon River Watershed Muskegon River Watershed Ecological Assessment Program National Water Quality Assessment project National Resource Conservation Service Non-Point Source Pollution Shuttle Radar Topography Mission Top Of the Atmosphere Total Nitrogen Total Phosphorus Tropical Rainforest Information Center Universal Transverse Mercator World Geodetic System Wetness Index xii CHAPTER 1 INTRODUCTION 1.1 Background Human induced changes in the Muskegon River Watershed (MRW) in north-central Michigan have had an adverse effect on the quality of water in its lakes and streams. Water quality in the MRW is a function of the different land uses such as agriculture, residential development, industry, and transportation. Residential development around the lakes as well as the construction of roads and parking lots affect water quality. Water quality also be affected because of algal blooms and high sediment loads carried by runoff from urban and agricultural landscapes. The lakes and wetlands of the MRW have important recreational and economic uses, but some are in danger of hyper-eutrophication, a phenomenon caused by excessive nutrients in the runoff from urban and agricultural landscapes. Eutrophication is characterized by water-bodies being dominated by the same set of nuisance species that can tolerate the eutrophic conditions and leads to the subsequent reduction in the diversity of species (Carpenter et al., 1995). The increase in stream runoff is due to the cumulative impact of urban growth along the eastern shores of Lake Michigan (Pijanowski et al., 2002). This urban growth encompasses urban, sub-urban and near shore residential development, an d has increased in 2002. 13 1.2 Problem statement and objectives There is an increase in urban development within the watershed, Which affects water quality due to increase in surface runoff. The increase in impervious surface area due to urban development leads to a subsequent increase in water temperature in streams fed by surface runoff, which modify the stream hydrology through incision. Stream incision is defined as “the rate of incision in detachment- limited systems and by definition, determined by the stream's ability to erode the bed, usually by a combination of abrasion and plucking” (Whipple et al., 2000). Water quality is degraded in certain sub-watersheds by inputs of nutrients such as nitrogen and phosphorus from towns and agricultural areas in the form of non-point source pollution (NPS). Confined animal feeding operations (CAFO’s) act as a point source for phosphorus input. Excessive sedimentation, another reason for deterioration of water quality, is attributed to stream bank erosion, roads, and farm practices like drainage. To obtain a firm understanding of the spatial and temporal nature of water quality, an ecological assessment of the watershed using remote sensing and GIS is necessary, as it is cost effective. The ecological assessment is carried out at the sub-watershed level rather than a basin wide study. This allows a cross comparison of the sub-watersheds in terms of their vulnerability to deterioration in water quality. 14 Ecological assessments are necessary in the protection, maintenance and restoration of ecological systems (US EPA, 1996). Land use indicators such as percentage of urban I built up and agriculture combined with topographic attributes such as elevation and slope help identify the anthropogenic activities that generate stress in the ecosystem under study. The objectives of the research are: 1) The mapping of urban built up areas and agricultural land use at the sub- watershed level as well as areas susceptible to non-point source pollution. 2) Statistical analysis to correlate percentage of land use with water quality indicators This research seeks to correlate land use / land cover (LULC) in the sub- watersheds with water quality indicators. In addition, an inventory of the LULC types was carried out in areas that were susceptible to non-point sources of pollution such as first order watersheds. The percentage of urban and agricultural land use within the sub-watersheds as well as the first order watersheds were regressed against various water quality indices such as total nitrogen, total phosphorus, conductivity as well as biological indicators such as sensitive insect populations (EPT taxa) and total invertebrate taxa to build predictive models. 15 1.3 Study area The Muskegon River is 219 miles long from its start at Houghton and Higgins lakes down to its mouth at Muskegon Lake, and eventually, Lake Michigan. The watershed is located between latitude 43° to 44°30’N and longitude 84°30’ to 86°W (Figure 1-1). The MRW covers an area of almost 7000 square km and includes 94 tributaries, 183 stream segments and 95 dams (O'Neal, 1997). The watershed is within the counties of Wexford, Missaukee, Roscommon, Kalkaska, Crawford, Lake, Osceola, Clare, Newaygo, Mecosta, Montcalm and Muskegon. The primary tributaries of the Muskegon river include the West Branch of the Muskegon River, the Clam River, the Middle Branch River, the Hershey River, the Little Muskegon River, Bigelow Creek, Brooks Creek, and Cedar Creek (O'Neal, 1997). Some of the important cities in the watershed are Big Rapids, Newaygo and Muskegon. l6 Muskegon River Watershed Figure 1-1. Muskegon River Watershed. 17 1.4 Hypothesis The purpose of this research is to test whether there is a correlation between water quality and percentage of LULC within the MRW. The specific hypothesis is that LULC affects water quality within the MRW. 1.5 Sub-hypothesis 1) LULC within the MRW can be accurately mapped through an un- supervised classification of Landsat-7 (ETM+) imagery and aggregated to the sub- watershed level. 2. Water quality within the MRW, measured through a set of water quality indicators and aggregated to the sub-watershed level, can be correlated with the percentage of LULC. 1.6 Benefits of this research This study, based on correlations between specific LULC types and water quality would not only assess the ecological integrity but also identify the sub- catchments within the MRW with greater proportions of urban and agricultural land use and thus help in better management of watershed. Once identified, the relationships between the various land uses and water quality indicators can be applied to other watersheds in the State of Michigan as well. This study of land— water interactions within the MRW is especially important at a time when urban 18 sprawl threatens the ecological integrity of Michigan’s water and natural resources. 19 CHAPTER 2 LITERATURE REVIEW 2.1 Land use and water quality Anthropogenic activities on land can have a detrimental effect on riparian bodies such as rivers and streams. The National Water Quality Assessment Program (NAWQA) was initiated by the USGS in 1991 to understand how human activities and natural processes affect water quality in this nation (USGS, 1999). This study came about partly due to the growing public concerns about the quality of the nation’s water resources. The passing of the Clean Water Act in 1977, whose purpose was “to restore and maintain the chemical, physical, and biological integrity of the waters of the United States” led to a strong campaign by the public and private sectors to limit contaminants from point sources from entering streams (USGS, 1999). NAWQA findings indicate that streams in watersheds and basins with significant agricultural and urban development have higher levels of nutrients and pesticides, which contribute to higher growth of algal growth. The increase in impervious surfaces like paved lots and urban pavements increased surface runoff (USGS, 1999). Also, the NAWQA studies showed that streams in basins with steep slope and clayey soils were vulnerable to contamination due to stream runoff. In the continental United States, urban streams had the highest concentrations of pesticides such as chlordane and dieldrin (USGS, 1999). It was also found that concentrations of phosphorus were higher in urban areas than in rural areas and this in part due to the effluent from wastewater plants (USGS, 1999). The runoff from urban areas have elevated levels of phosphorus and nitrogen and caused the eutrophication in lakes, streams and reservoirs. Cities are important contributors to 20 non-point pollution and homeowners with lawns apply just as much fertilizer and pesticides per unit area as farmers would on their farms. Studies conducted in the upper Midwest suggest that lawn care, through the application of nutrients rich in nitrogen and phosphonrs contributes to nutrient rich mnoff and that nutrient concentrations are more than those originating from impervious surface areas like roofs and paved surfaces like streets and driveways (Bannennan et al., 1993; Waschbusch et al., 2000; Steuer et al., 1997). The sources of water pollution typically fall into two categories, 1) point source pollution and 2) non-point source pollution. Point source pollution originates from discrete locations that are spatially explicit and some examples are sewage treatment plants, industrial effluents and land disposal sites. Non-point sources of pollution originate from various diffuse sources that occur over a larger and broader geographical area. Some examples of non-point source of pollution include agricultural runoff, storm water, urban runoff and atmospheric deposition. Because of its diffuse nature, non-point source pollution cannot be isolated in a spatially explicit manner (USGS, 1999). Agriculture is the most important source of non-point source pollution according to the US EPA (2000). Agricultural practices like the spraying of pesticides and herbicides, irrigation, planting and harvesting, and confined animal feedlots all contribute to NPS pollution. Another significant form of agricultural NPS pollution seems to be siltation (Rabeni & Smale, 1995). The nutrients most often considered in 21 land-water interaction studies are nitrogen and phosphoms (Turner et al., 2001). Nitrogen concentrations in rivers are sensitive to land use patterns, the riparian zone structure and river flow (Cirrno and McDonnell, 1997). Accumulation of excess phosphorus in rivers and streams has been recognized as the cause for eutrophication (Carpenter et al., 1998). Similarly, concerns about nitrogen inputs into aquatic ecosystems have been raised (Mueller and Helsel, 1996; Vitousek and Howarth, 1991). Farmers apply nutrients such as nitrogen and phosphorus to their farm plots, but not all of it is absorbed by the plants. The nutrients in the soil are leached through runoff and find their way into lakes and streams where they cause eutrophiwtion. Recent advances in technologies such as GIS and remote sensing have seen various studies conducted to assess agricultural NPS pollution at different geographical scales that include catchment, watershed, basin and landscape level assessments (Richards et al., 1993; Allan et al., 1997; Johnson & Gage, 1997; Harding et al., 1999; Lammert and Allan, 1999). Regression analysis has been used to determine relationships between land use patterns and nitrogen l phosphorus concentrations (Osborne and Wiley, 1988). The land use patterns in the Salt River Basin, Illinois, were mapped from aerial photos and results indicated that urban land use and its distance to the stream was the most important variable in predicting nutrient concentrations in stream water (Osborne and Wiley, 1988). A study in the Minneapolis—St. Paul Metropolitan region demonstrated that lakes within watersheds dominated by forests and intact wetlands tended to be less eutrophic and have lower levels of 22 chlorides and lead (Detenbeck et al., 1993). On the other hand, lakes within agricultural watersheds were more likely to be eutrophic. There was also a positive correlation between the percentage of urban land use and phosphorus in the Minneapolis area (Detenbeck et al., 1993). In another study, LULC within 62 catchments in the Saginaw River, Michigan was related to stream water chemistry (Johnson et al., 1997). The results of the study demonstrated that the land use / land cover had a strong influence on water quality but the predictive power of specific water quality indicators varied by season (Johnson et al., 1997). The spatial distribution and proportion of different land use I land cover types has been found to directly affect water quality (Hunsaker & Levine, 1995). Forested riparian zones had better water quality than deforested riparian zones with similar agricultural land use (Hunsaker & Levine, 1995). Soranno (1996) found significant relationships between land use and concentrations of phosphorus in the Lake Mendota watershed, Wisconsin. A GIS based predictive model was built where the phosphorus export coefficient varied by land use type. The study also measured the contribution of phosphorus to a lake as a function of distance. In addition, the results emphasized the importance of riparian vegetation in reducing forest runoff (Soranno et al., 1996). Horton (1933) suggested that rainfall within a watershed either infiltrates the soil or is transported overland to streams as storm flow. Overland flow or sheet flow occurs when the precipitation intensity exceeds the soil infiltration capacity. However, hortonian overland flow, which is widely accepted as the case 23 for degraded watersheds that are predominately agricultural, does not seem to hold for forested watersheds where abundant canopy cover prevents erosion and facilitates infiltration. Urbanization is a significant land use today as it is associated with population, the economy and the conversion of other LULC types. The proliferation of impervious surface areas (ISA), in areas that are heavily vegetated reduces carbon sequestration (Milesi et al., 2003). In addition, the increase in impervious surface areas results in the alteration of sensible and latent heat fluxes leading to the formation of urban heat islands (Changnon, 1992). Urban development plays an important role in influencing the rate of runoff and erosion (Goudie, 1990). Urban growth undergoes several stages (Kibler, 1982). In the early stage of urban development, the logging of trees and vegetation may result in the decrease of evapotranspiration, interception and increase siltation as well as total suspended solids. The latter stages of growth include an increase in the construction of houses, streets and storm drains which in turn leads to a decrease in infiltration, increase in storm flows and a lower ground water table. As the number of residential and commercial buildings increase, there is a subsequent increase in paved surfaces liked roads and parking lots which in turn decrease the time of concentration which is the amount of time required for water to move from the most distant part of the watershed or catchment to the outlet and is a function of the percentage of impervious area and slope. The increase in impervious surfaces will result in higher peak 24 discharges after rainfall events because of a decrease in infiltration and result in an increase in surface and storm water runoff (Booth, 1991). The effects of an increase in ISA are found when 10% of the watershed is covered with impervious surfaces, leading to the alteration of stream channels; rising water temperatures; a reduction in the diversity of aquatic insects and fish; and the degradation of wetlands and riparian zones (Beach, 2002). The response of rivers in terms of discharge due to increase in sediment loading due to changes in land use patterns such as deforestation has been documented (Ligon et al., 1995). 2.1.1 First order watersheds First order streams are the uppermost, stream channels that do not have any upstream reaches and have perennial or intermittent flow (Gomi et al., 2002). First order watersheds make up a large portion (60-70%) of the catchment area (Siddle et al., 2000; Meyer and Wallace, 2001). The first order watersheds are important sources of nutrients organic matter and sediments for the higher order streams and their catchments (Gomi et al., 2002). The movement of organic matter and invertebrate species from the first order to higher order watersheds supports the fish population downstream (Wipfli and Gregorvich, 2002). In addition, leaf litter and large woody debris alter and control the stream morphology and provide habitats like riffles and pools for invertebrates and fish fry (Zimmerman and Church, 2001). Invertebrate species found in the first order streams serve as food for aquatic biota (erfli, 1997). The large woody debris also dams the stream channels and alters the channel reaches such as 25 cascades and step pools (Halwas and Church, 2002). The riparian forest canopy in the first order streams attenuates incoming solar radiation and so controls the water temperature as well as the amount of light (Gomi et al., 2002). Headwater systems that include hill slopes and first order watersheds control stream flow generation (Tsukamoto et al., 1982) and water chemistry in the stream (Likens et al., 1977). These headwater systems contain four topographic units (Hack and Goodlett, 1960) which are 1) hill slopes, 2) zero- order basins, 3) ephemeral channels emerging from the zero order basins called transitional channels, and 4) first order streams. The hillslopes do not have channelized flow. The zero order basins could be defined as an unchannelized hollow with converging contour lines (T sukamoto et al., 1982). Temporary channels or transitionary channels may connect the zero order basin and first order streams (T sukamoto et al., 1982). These ephemeral channels do not support the complete life cycles of macro invertebrate biota. Storm flow generation within the river basin Is more rapid in first order watersheds owing to the small storage capacity. There is also a greater variation in peak flow discharge as compared to higher order watersheds (Gomi et al., 2002). The increase in impervious surface area due to urban development in the first order watersheds could increase the peak flow discharge and so are especially vulnerable to NPS pollution from urban landscapes (Gomi et al., 2002). In spite of the significant role of first order watersheds within the larger basin or catchment, 26 their processes have been extensively modified by land use (Meyer and Wallace, 2001) 2.1.2 Land use in the Muskegon River Watershed The Muskegon River Watershed (MRW) can be broadly classified into three major ecological zones: 1) the outwash bowl, 2) the morainal valleys, and 3) the freshwater estuary (Figure 2-1). The headwaters of the Muskegon river originate in an outwash plain formed by deposits of stratified debris from glacial meltwater streams. The morainal valley which constitutes the mid-river section was created by deposits of unsorted debris (gravel, sand and boulders) left behind by retreating glaciers. The freshwater estuary or the mouth of the Muskegon river is a drowned river valley created due to coastal subsidence or through inundation by glacial melt water (Christopherson, 1995). 27 Figure 2-1. MRW: ecological classification The history of land use within the MRW is relevant to the study as it is important to consider the past consequences of significant alterations to the watershed system. Human settlements in the MRW expanded as population increased drastically between 1810 to 1840 (O'Neal, 1997). This was largely influenced by intensive logging operations for copper and white pine. The logging caused extensive damage to the existing aquatic habitat. The water quality in the MRW was also affected by anthropogenic activities that increased in the early 1900's and reached a peak in the 1950’s and 1960’s. Nutrient and sediment pollution was common as well as extensive wetland reclamation in the vicinity of Muskegon lake (O'Neal, 1997). 28 Agricultural and urban land uses cause the greatest impact on water quality (Mueller and Helsel, 1996). Agricultural land use predominated in the MRW in 1997, and accounted for 33.4% of the total area with urban areas taking up 0.6% of the watershed (O'Neal, 1997). Agricultural lands in Michigan also contribute to poor water quality through erosion of sediments into streams (O'Neal, 1997). It is estimated that the soil erosion from crop and pasture lands might be 14 to 21 times higher than erosion rates on forest land. Roads also contribute to erosion of sediments through an increase in runoff over paved surfaces (Alexander et al., 1995) The Muskegon river basin lies within two major land resource area classifications of the National Resource Conservation Service (NRCS). These are the northern lower Michigan sandy drift and the southern lower Michigan drift plain (O'Neal, 1997). Soil erosion in the form of annual sheet and rill erosion is 0.84 tons/acre for crops-pasture land and 0.04 tons/acre for forests in the northern lower Michigan sandy drift and 2.09 tons/acre for crops-pasture land and 0.15 tons/acre for forests (O'Neal, 1997). To help prevent the soil erosion, the NRCS has considered drainage, and forage improvements. The draining of land by deepening of existing streams destroys and eliminates many aquatic habitats. The removal of trees and other riparian vegetation leads to a degradation of canopy cover over the streams and leads to increased water temperatures (O'Neal, 1997). 29 Dams were constructed on Muskegon river at Big Rapids during 1866 and Newaygo in 1900 and dismantled in 1966 and 1969, respectively. Four major dams still remain on the Muskegon river and they include Reedsburg dam, Rogers dam, Hardy dam and Croton dam. Of these, Reedsburg dam is a wildlife flooding and the rest are hydroelectric dams (O’Neal, 1997). The dams pose serious environmental problems to the river as the natural flow regime of the river is altered and also change their physical, chemical and biological characteristics (Poff et al., 1997; Poff and Hart, 2002). The dams cause fish mortalities as they get caught in the hydroelectric turbines. Of the fish mortalities, as much as 70% are game fish (O’Neal, 1997). The dams also prevent the movement of aquatic insect larva, which serve as food for the various fish species. Changes in water quality and rising temperatures have been attributed to the major hydroelectric dams, namely, Croton, Hardy and Rogers’s dams. The current pattern of land use in Michigan indicates an increase in urban/built up area and a subsequent decrease in agricultural and pastureland. In 1952, the land use under agriculture in Michigan was approximately 72, 843 km2 (Veatch, 1953). The area under agriculture decreased to 50,000km2 and 49, 446 km2 in 1987 (Natural Resources Inventory, 1987). The farmland loss can be attributed to urban sprawl or as in some cases in the MRW, re-growth of vegetation. Though the population growth is less than the national average (6.9% as compared to 13.1%), there has been significant population shifts within Michigan’s 30 borders. The general trend is that people seem to move from urban areas to the suburbs and rural areas (Machemer et al., 1999). The increase in urban development seems to outstrip the population growth and is characteristic of urban sprawl. The increase could be attributed to the low cost of land in niral areas as compared to the cities. The increasing urbanization is alarming as Michigan’s natural resources account for a large percentage (29%) of Michigan’s economy (Machemer et al., 1999). The primary effect of urban development in the suburbs is fragmentation of forests from large contiguous tracts to small patches. 2.2 EPA monitoring programs in the US 2.2.1 The Environmental Monitoring and Assessment Program (EMAP) The Environmental Monitoring and Assessment Program (EMAP) is a research program undertaken by the Environmental Protection Agency (EPA) to monitor and assess the status and trends of the ecological resources of the United States (Paulsen et al, 1991; US EPA, 1997). The EPA published a report titled “Ecological assessment of the mid-atlantic region, a landscape atlas”. The atlas described ecological conditions across the mid-Atlantic region of the United States that included the states of Delaware, the District of Columbia, Maryland, Pennsylvania, Virginia, and West Virginia. The report was based on information derived from satellite imagery as well as other sources of geo-spatial information. In October 1997, the EPA released another report, which was its first index of watershed indicators (US EPA, 1997) that shared many similarities with the EMAP mid-Atlantic landscape atlas. The primary difference between the two reports is that 31 the index of watershed indicators primarily deals with water quality issues but the mid-Atlantic landscape atlas documents the impact of land use / land cover on water quality. This study uses some of the methods mentioned in both reports to address the possible effects of land use / land cover on water quality. 2.2.2 EPT taxa Environmental monitoring groups across the United States have adopted EPT (Ephemeroptera, Plecoptera, Trichoptera) taxa richness as a useful measure of stream water quality. The EPT taxa that include mayflies, caddis flies and stone flies evolved in streams with high levels of oxygen and in fast flowing waters. Any reduction in flow, depleted oxygen supply or increase in temperature results in a decrease in population. The widespread use of EPT taxa as a stressor indicator might be owing to its ease of use and effective tracking of water quality as well its habitat specific impact (Wallace et al., 1996). The use of EPT taxa is a follow—on to the historic use of benthic macro-invertebrates to evaluate water quality that dates back to early studies in the Illinois River (Richardson, 1928). Macro-invertebrate taxa were increasingly used to monitor water quality from the 1950’s onwards and studies from the mid-century period began to cite EPT taxa as intolerant (Gaufin and Tarzwell, 1952). 32 2.3 Surface hydrological modeling Topography is an important factor in determining the stream flow in forested uplands (Wolock and Price, 1994). It also defines the movement of water within a catchment area due to gravity, the spatial distribution of soil moisture (Burt and Butcher, 1985) and the water chemistry of the stream flow (Wolock et al., 1990). Surface hydrology is defined as “the spatial and temporal storage and redistribution of rainfall as it falls on or enters into the soil“ (Engman, 1997). The prediction of spatial patterns and the rate of surface runoff require a hydrologic model and a categorization of the land surface (Zhang and Montgomery, 1994). Digital elevation model (DEM) data are arrays of regularty spaced elevation values referenced horizontally either to a Universal Transverse Mercator (UTM) projection or to a geographic coordinate system (USGS, 2000). Digital elevation models are being used in hydrological modeling studies (Bruneau et al., 1995) and for a variety of engineering as well as planning applications (Zhang and Montgomery, 1994). 2.3.1 Advantages of SRTM DEMs The Shuttle Radar Topography Mission (SRTM) derived DEM, currently the highest resolution global DEM, was sampled at 1 are second or 30m (Rabus et al., 2002). Until now, high resolution DEMs were obtained mostly from optical stereo data acquired from aerial photographs or satellite imagery. The DEMs obtained from these were not homogeneous due to the quality of image contrast. 33 Also, the presence of clouds or the lack of sunlight in stereo-pairs resulted in image artifacts (Rabus et al., 2002). The SRTM data set, on the other hand was obtained by a single technique, i.e., interferometic Synthetic Aperture Radar (lnSAR) sampling in 11 days by the Space Shuttle Endeavour (Rabus et al., 2002). The absolute vertical accuracy is +/- 16 m and the absolute horizontal (90% circular error) accuracy is 20m (Sun et al., 2003). The SRTM global data set was obtained from the post processing of the C band radar interferometry which introduces an error in the vertical accuracy as the C band radar return effectively samples the height at the top of the canopy and unlike radar bands with longer wavelengths (P and L bands), does not reach the ground beneath. A validation of SRTM DEM’s vertical accuracy using the Shuttle Laser Altimeter (SLA-02) showed that areas with sparse vegetative cover had absolute vertical accuracy that exceeded the mission specifications of 16m. Surface slope comparisons between the SRTM and Digital Elevation Terrain Data (DTED) DEM showed that slope derived from the SRTM DEM was superior to the slope derived from the DTED Level 1 (3 arc sec) DEM (Sun et al., 2003). 2.3.2 Digital terrain modeling and topographic attributes Topographic attributes include primary attributes like elevation and slope as well as secondary attributes that are derived from combinations of primary data. The primary attributes like slope, catchment area, and specific catchment area are significant because they influence overland flow velocity and runoff rates, mnoff volume, and steady state runoff rate respectively (Moore et al., 1991). The catchment 34 area is a measure of the surface runoff of the landscape and it combines the effect of upslope contributing area as well as the local convergent and divergent flows within (Moore et al., 1991). Secondary or compound data describe the spatial distribution and variability of specific processes that occur within a landscape such as wetness index (soil water content) or stream power (Moore et al., 1991). Wetness index is a second order derivative of slope and relates to the spatial distribution of soil saturation zones (Moore et al., 1991). Stream power is the erosive power of stream flow (Moore et al., 1991). The stream power index can be used to identify places where soil conservation practices that reduce the erosive power of the stream can be implemented (Moore et al., 1991). Depending on the scale of regional planning, the fundamental units for water resource conservation are the basin, watershed or sub-watershed (Moore et al., 1991). The traditional mapping and delineation of watershed and sub watershed boundaries was centered on the stream network and therefore considered a conservative representation (Mark, 1983). The past decade has seen the rapid development in the field of hydrological modeling through the use of DEMs. The ARC GRID module uses an algorithm (O’Callaghan and Mark, 1984; Jenson and Domingue, 1988) that determines the flow direction of each element in 3x3 matrix to one of its eight neighbors in the direction of steepest descent (Moore et al., 1991). 35 CHAPTER 3 METHODOLOGY 3.1 Surface hydrological modeling 3.1.1 Acquisition and pro-processing of SRTM derived DEMs SRTM derived 30m DEMs were used to model surface flow in the MRW. These DEMs were downloaded from the USGS seamless web server (http://seamless.usgsgovl) and merged to obtain coverage for the entire watershed. The grids were downloaded as floating point and in order to conserve disk space were converted to 16 bit unsigned integer by the use of the GRID command, INT (ESRI, 1994). Errors in DEMs some times manifest in the form of “sinks” or “pits”. These production artifacts are regions that have lesser elevation than the area around it. These sinks were identified with the SINK command in ARC GRID. The output grid was found to contain nodata cells caused during acquisition / production of the SRTM data. Cells that do not have a valid value assigned are termed as nodata cells (ESRI, 1994). The nodata cells were subsequently filled with a FOCAL MEAN command. After, the nodata cells were removed the individual grids (six in number) were projected UTM, Zone 16, datum & spheroid WGS 84. The SINK command (ESRI, 1994) was run again on the merged grid, as there might still be legitimate sinks of natural origin rather than artifacts due to the nature of radar backscatter. After the sinks had been identified, the FILL command, based on the algorithm developed by Jenson and Domingue (1988) was used to fill the artificial production artifacts. 36 3.1.2 Delineation of Strahler stream order using D-8 flowline derived stream network In DEM analysis for hydrologic application, it is often assumed that all flow from a cell is directed towards one and only oneiof its neighbors and this assumption is referred to as the “deterministic eight-neighbors” or D-8 model (Fairfield and Leymarie, 1991). The D-8 flow-line algorithm is a standard algorithm that is used by the Environmental Systems Research Institute (ESRI) software to derive flow direction from a surface. The algorithm uses an input DEM to depict the direction of flow from each cell within a 3x3 window. There are eight valid directions or eight adjacent cells into which the flow can travel (ESRI, 1994). The flow direction determines the direction of flow from every cell or element in the grid and is determined by finding the direction of steepest flow (ESRI, 1994). The flow accumulation function computes accumulated flow as the weight of all the cells flowing into each down-slope cell in the output grid (ESRI, 1994). Cells with high flow accumulation have concentrated flow and are used to determine the stream network. A threshold value can be applied to the flow accumulation product to obtain the stream network within a watershed (Jenson and Domingue, 1988). The surface hydrology commands such as flow direction & flow accumulation were an on the MRW grid (Fig 3-1). To obtain the stream network, a threshold value was derived by adding the mean of the flow accumulation grid to the standard deviation and re-classed such that, all values greater than the mean + 1 standard 37 deviation would be 1 othenrvise 0. This process was repeated iteratively until the raster stream network derived from the SRTM DEM matched vector stream networks in two different datasets namely Michigan Resource lnfonnation System (MIRIS) as well as Digital Line Graphs (planimetric information obtained from various USGS maps). The threshold number, 3326, was found to be near the mean of the flow accumulation distribution. The threshold number was then multiplied by 0.003x 0.003 to obtain the area required to generate a first order stream (2.99 sq km) within the Muskegon river watershed. The STREAMORDER command (Strahler) was run on the output grid. In the Strahler stream order, order increases when streams of the same order intersect (Strahler, 1957). Therefore, the intersections of two first order streams will give rise to a second order stream and intersection of two second order streams would give rise to a third order stream. However, the intersections of two different orders will not result in increase in order. This method is the most commonly used model for stream networks (ESRI, 1994). The stream order grids were then converted to are coverages using the STREAMLINE command. The WATERSHED command, which uses the streamline arc coverages as well as the flow direction grid as input was used to generate the sub-watersheds. These watersheds differ slightly from the MIRIS watershed as the stream order was derived from various sources (digitizing of existing maps or from aerial photos). 38 Merge DEM Flow direction FILL sinks Flow accumulation Thresholded flow Stream order Streamline coverage I Watersheds Figure 3-1. Flow chart to extract watersheds from DEM 39 3.1.3 Delineation of first order watersheds, percent slope and wetness index In order to delineate the first order watersheds, a binary mask was applied on the Strahler stream order grid. The higher order streams were masked out leaving only the first order streams. The STREAMLINE command in ARC GRID was used on the first order stream grid along with the flow direction force grid to obtain an Arc- coverage of the first order streams. The WATERSHED command in ARC GRID was then run using the first order streams coverage and flow direction force grid. The first order watershed grid thus obtained was converted to a vector layer. The D-8 flow line algorithm models flow direction at 45° angles and so the conversion of the raster watershed layer to a vector layer results in the formation of a number of spindle shaped polygon artifacts at the pour points (Figure 3-2). To correct for this anomaly, the first order watershed arc coverage was edited using the are tools module in the ARC INFO software. The post processing of the first order watershed was time consuming, but absolutely necessary to delineate the first order watersheds within the sub—watersheds (Figure 3-3). 40 Figure 3-2. DEM flow direction artifacts created due to the nature of the D8 flow line algorithm l 0 20 40 80 Kilometers Figure 3-3. Muskegon first order watershed coverage obtained using binary mask of Strahler stream network 41 In addition to first order watersheds, percent slope and wetness index (W.l) were also obtained from the SRTM derived DEM. Slope identifies the maximum rate of change between each cell and its neighbors (ESRI, 1994). Percent slope was obtained using the SLOPE command using the percent rise option instead of degree slope and Is useful in identifying areas of steep slope, which might be vulnerable to erosion. The wetness index or topographic index is the log of the ratio of the catchment area and the percent slope (Wolock and Price, 1994). The wetness index helps in identification and delineation of wetlands (Moore et al., 1991). The equation for wetness index is WI = In (a/tanb) or Wl = In (a / (rise / run) + 0.0001) (3—1) where a = flow accumulation b = slope and tan b = slope percentage x 0.01 Implementing the wetness index for raster processing requires some adjustment. Wolock and Price (1994) suggest that flow accumulation or upslope contributing cells might be scaled by contour length, and in this case the cell side (Wolock and Price, 1994). The cell side was the resolution of an ETM+ pixel, i.e. 30m. In GRID, the wetness index was obtained using the following command Wl = LN ((FA + 1) * cell side) / (slope (percent rise) * 0.01 + 0.0001) 42 The wetness index was used to aid in the image classification of the ETM+ imagery by overlaying the wetness index grid over the classified image. 3.2 Classification of ETM+ imagery using unsupervised method 3.2.1 Imagery inventory Four ETM+ (Landsat-7) images in the World Reference System (WRS-2) Path 21, Rows 29 & 30 and Path 22, Rows 29 & 30 were obtained from 2001 and 2002 (Table 3-1). The imagery was obtained from the TRFIC archive at the Center for Global Change and Earth Observations (CGCEO) at Michigan State University. Pith 021 Row 029 Path on Rowlnli Path 021 row03ll Figure 3-4. Spatial extent of MRW overlaid with WRS-2 (Landsat) footprint 43 Landsat 7 Date ETM+ Path/row 22/29 9/7/2002 ETM+ Path/row 22/30 7/2/2001 ETM+ Path/row 21/29 6/25/2001 ETM+ Path/row 21/30 7/14/2002 Table 3-1. Satellite data The spatial extent of the MRW is such that it covers portions of four Landsat scenes (Figure 3-4). The portions of the ET M+ imagery mentioned above were then clipped using the subset option in ERDAS IMAGINE. The spatial database thus obtained includes subsets from 2001/2002 (ETM+) which would facilitate an inventory of the land use / land cover within the forty sub watersheds through the process of image classification. In addition, two lKONOS-scenes from 2002 (September & October) were obtained over the MRW at Houghton Lake and over the Big Rapids-Haymarsh area to provide ground truth for accuracy assessment of the image classification process (Figure 3-6). The 4m multi-spectral data was pan-sharpened using the 1m panchromatic band. Digital Ortho-Quarter Quads (DOQQ’s) were downloaded from the Michigan Department of Natural Resource’s (MDNR), Spatial Data Library. The DOQQ’s were then mosaicked and reprojected to UTM Zone 16 to be used as ground truth reference (Figure 3-5). 44 K‘UUGHA WORD m... I -=-_:——_—— IGIorneters 0 10 20 40 60 80 Figure 3-5. Spatial extent of MRW overlaid with county boundaries and Digital Ortho Quarter Quads (DOQQ’s) 45 _ _ lfilometers 0 1O 20 40 60 80 Figure 3-6. Spatial extent of MRW overlaid with county boundaries and pan sharpened lKONOS imagery 3.2.2 Image pre-processing and unsupervised classification The Landsat data record is extremely important to earth sciences as it marks over three decades of earth observation. Its advantages include a high spatial resolution, medium temporal resolution, and an extensive swath (Teillet et al., 2001). However, in order to benefit from this impressive dataset, it is absolutely essential to process the digital numbers collected by the sensor by radiometric calibration to an absolute scale, in physical units (Teillet et al., 2001). Image pre—processing and radiometric correction was carried using ERDAS IMAGINE version 8.6 (Fig 3-7). 46 Raw DN I Radiance l Radiometric Correction Reflectance (TOA) MODTRAN 4 Reflectance (Surface) I Rectified Geometric Image Correction Figure 3-7. Flow chart for image processing of DN to surface reflectance The raw digital numbers are first converted into physical units of radiance (L1,) using wlibration coefficients (Table 3-2) in a given spectral band L), = [(LMAX - LMIN)]/255] x DN + LMIN (3-2) Where LMAX = spectral radiance scaled to DNmax in WI (m2.sr.pm) LMIN = spectral radiance scaled to DNmin in w/ (m2.sr.pm) DN = Digital Numbers 47 BAND ETM+ in w/(m2.er.rm) LMAX LMIN 1 191.6 -6.2 2 196.5 -6.4 3 152.9 -5.0 4 241.1 -5.1 5 31.06 -1.0 7 10.80 -0.35 Table 3-2. ETM+ spectral radiance range in w/ (m2.sr.pm) When there is a need to compare imagery from different sensors, it is advantageous to use reflectance values instead of using radiance. The cosine effect of different sun angles can be removed and the differences due to variability in exo-atmospheric radiances between spectral bands can also be accounted for. Unitless planetary reflectance was obtained by the following equafion __ n-L, OdZ Esun,1 0 cos 9, where pp = Unitless planetary reflectance L). = Spectral radiance at the sensor’s aperture 93= Solar zenith d = Earth-sun distance in astronomical units Esun 1 = Mean solar exo-atmospheric irradiances from table below 48 (3-3) Band ETM+ Solar Spectral Irradiances Units: in w/(m2.sr.pm) 1970.00 1843.00 1555.00 1047.00 227.00 80.53 \ICfl-thA Table 3-3. ETM+ solar spectral irradiances The ETM+ radiance values were radiometrically corrected to at-sensor reflectance using the calibration parameters in the metadata and then to surface reflectance after correcting for distorting atmospheric effects. Haze in the upper atmosphere often causes satellite imagery to look faded due to Rayleigh scattering and ozone absorption. The top of the atmosphere (T OA) reflectance was then converted into surface reflectance by using the coefficients of slope and intercept, which in turn were obtained by running the MODTRAN 4 program. Geodetic accuracy or the geographic navigation accuracy for a particular pixel is absolutely essential especially in the case of change detection studies. The ETM+ level 1G imagery products are systematically corrected, i.e., registration is performed without ground control (Goward et al., 2001). After systematic correction, ETM+ imagery has a geodetic error of less than 250m with 1 standard deviation (Masek et al., 2001). The ETM+ images were geometrically corrected to ensure proper alignment and scale and were rectified to the Universal Transverse Mercator (UTM) projection (Zone 16) and WGS 84 datum using a first order polynomial and nearest neighbor resampling. To correct for 49 horizontal displacement and inaccuracy, GPS co-ordinates recorded at the road intersections within the watershed were used as ground control Points (GCPs) to serve as a reference in the process of geometric correction to geo-reference the imagery. The accuracy was within one pixel (Table 3-4). L-7 Path IROW X Residual Y Residual RMS Error 22130 (ETM+) 0.0678 0.0510 0.0849 21/30 (ETM+) 0.0676 0.2258 0.2357 21129 (ETM+) 0.1882 0.3466 03944 22129 (ETM+) 0.2024 0.2024 0.2862 Table 3-4. ETM+ scenes and their gee-referencing parameters An unsupervised classification was carried out on the ETM+ scenes through the use of the Iterative Self-Organizing Data Analysis Technique (ISODATA) algorithm. The ISODATA clustering method uses minimum spectral distance to iteratively classify pixels until the spectral distance patterns emerge in the form of clusters (T ou and Gonzalez, 1974). To perform ISODATA classification, the user needs to specify the maximum number of clusters thought necessary , the number of iterations to be run and the convergence threshold, which defines the maximum percentage of pixels that are allowed to remain unchanged between iterations. The ISODATA algorithm was run on the ETM+ scenes after specifying 100 clusters, 80 iterations, and a convergence threshold of 0.98. The National Land Cover Database (NLCD 92) thematic map was created by an unsupervised classification using 100 clusters and so the same number of clusters was used in the generation of a classified product for this research (Vogelmann et al., 1998). 50 The classification was performed after geo-referencing so that the resultant thematic map would be more accurate (ERDAS, 2004). Each image reached the convergence threshold before the maximum level of iterations. Visual interpretation helped in identification of eight distinct LULC classes from the Michigan Land Cover/ Use Classification System (2000), namely 1) deciduous, 2) coniferous, 3) grass, 4) water, 5) wetland, 6) bare soil, 7) urban, and 8) agriculture. These classes were then recoded to an Anderson’s level I classification (Anderson, 1976) with seven classes, 1) urban, 2) agriculture, 3) grass, 4) forest, 5) water, 6) wetland and 7) bare soil. The seven classes were defined as follows: 1) Urban: Developed areas that were characterized by 30 % or more area under constructed material (Asphalt & concrete). 2) Agriculture: Areas characterized by croplands, which include row crops (corn & soybean), small grain (wheat & barley) as well as pasture/hay. 3) Grass and shrublands: These include areas that have 25% or more area covered by grasses and shrubs 4) Forest: Areas that had 20% or more covered by broadleaved forest as well as coniferous forests. 5) Water: Areas under open water 51 6) Wetlands: Areas where the soil or substrate is periodically saturated with or covered with water (Cowardin et al., 1979). These areas are characterized by both forested and non-forested wetlands. 7) Bare: Area covered by bare rock, silt, sand or clay with little or no vegetation. The accuracy assessment of the ETM+ derived LULC maps through image classification required the comparison of the classified imagery with reference or ground truth data (Congalton, 1988). The high- resolution (1m) pan- sharpened lKONOS images and DOQQ’s were used as ground truth images and as a photo-interpretation key in the accuracy assessment process. The accuracy assessment utility in ERDAS IMAGINE 8.6 was used to generate 300 random points with 40 or more points per class using stratified random sampling. Congalton (1991) suggests that a minimum of 40-50 samples be collected for each land cover in the error matrix to adequately sample the dataset to be evaluated. Random sampling was used in an earlier assessment but was replaced by a stratified random sampling scheme as the former tends to under sample small but important classes such as urban areas in watersheds. It is for this reason that stratified random sampling was chosen where a minimum number of sample points (40-50) were collected for each class type (Congalton, 1 988). 52 The randomly sampled co-ordinates were imported into Arcview 3.2 as a tab delimited file and saved as a point shapefile. This shapefile was overlaid over the high-resolution reference images, namely the 2002 lKONOS images and the Michigan DNR DOQQ’s (1998). The reference targets were identified using visual interpretation and entered in the reference column of the accuracy assessment utility. The relationship between the classified map product and the reference images are summarized in an error matrix (Table 3-4). The overall classification accuracy or the percentage of correctly classified pixels of the LULC product was 83.33% and was obtained by dividing the sum of the (correctly classified) pixels in the major diagonal by the total number of samples (Table 3-5). The producers accuracy (which is a measure of the reliability of the map) was derived by the total number of correct pixels for a land cover type divided by the total number of pixels of that land cover type derived from reference data, in other words, the column total. The users accuracy (a measure of the adequacy for each category) was derived by dividing the total number of correct pixels for a land cover type divided by the total number of pixels that were accurately classified in that land cover class. The Kappa (Km) statistic, a measure of percent accuracy within an overall measurement of classifier accuracy (Congalton, 1991), was 0.8054. The Kappa statistic is a better measure of accuracy than an overall assessment as it considers inter class agreement (Fitzgerald and Lees, 1994). 53 where r is the number of rows in the matrix, N is the total number of observations, xii is the number of observations in row i and column i, x». and x+,- K hat — r r NZ xii - 20514 x x+i _ i=l i=1 r 2 N _ Z t-critical at a = 0.05). The t critical value = 1.695 at a = 0.05 (95% probability) and df = 34. Ho: Null hypothesis: there is no correlation between specific conductivity and the percentage of land use H1: Alternative hypothesis: there is a correlation between specific conductivity and the percentage of land use The null hypothesis was rejected as the tvalues for the different land use / land cover types (table 4-1) were greater than t critical value = 1.695. The correlation between urban, agricultural LULC types as well as the percentage of combined land use and specific conductivity, which ranged between 0.60 and 0.72 was statistically significant at the 95 % confidence level. This could be attributed to the percentage of urban land use greater than 1% in some of the watersheds (Table 4-2). 61 Sub-watershed City/T own 1 Higgins lake/l -127 3 Houghton/l -127 12 Cadillac 14 Lake city 23 Reed city/Evart 24 Big rapids/US 31 25 Big rapids/US 31 31 Howard city 35 Newaygo (Brooks & Hess lakes) 36 Freemont 38 Muskegon wastewater ponds 39 Muskegm city 40 Muskegon ciy Table 4-2. Urban land use in sub-watersheds greater than 1% L Model summary Parameter estimates I Equation I R Square F df1 df2 Sig. Constant b1 |Linear | .205 8.789 1 34 .006 329.099 11.040| Table 4-3. Correlation between specific conductivity (u siemens) and urban land use within sub-watershed A simple linear regression characterized a positive linear association between the percentage of urban land use (independent variable) and specific conductivity, the dependent variable (Table 4-3). The model explained 20 % of the dependent variable (specific conductivity) at a = 0.05. 62 4.1.2 TN concentration and percentage of LULC Total nitrogen concentrations (measured in parts per billion) within the sub-watershed were assumed to be positively correlated (using Spearrnan’s rank correlation) with the percentages of urban land use, agricultural land, combined percentage of urban and agricultural land as well as percentage of human use index (combined percentages of urban, agricultural and bare land). It was also assumed that the percentage of forest cover and TN concentrations were negatively correlated. TN vs. LULC Correlation tvalue tcritical, a = 0.05 TN vs. urban 0.189 1.1386 1.695 TN vs. agriculture 0.4 2.5819 1.695 TN vs. urban + agriculture 0.454 3.0144 1.695 TN vs. human use index 0.464 3.0988 1.695 TN vs. forest -0.47 -3.1501 -1.695 Table 4-4. Correlation between TN concentrations and LULC within sub- watershed 63 TN vs. LULC Correlation tvalue tcritical, a = 0.05 TN vs. urban 0.169 1.014 1.695 TN vs. agriculture 0.364 2.2833 1.695 TN vs. urban + agriculture 0.351 3.0228 1.695 TN vs. human use index 0.360 2.9811 1.695 TN vs. forest -0.437 -3.4339 -1.695 Table 4-5. Correlation between TN concentrations and LULC within first order watershed In addition, TN concentrations within the first order watersheds were assumed to be positively correlated with the percentages of urban and agricultural LULC types as well as their combined percentages. It was also assumed that the TN concentrations were negatively correlated with the percentage of forests within the first order watersheds. As hypothesis, it was assumed that TN concentrations increase as the percentage of anthropogenically modified land within the sub watershed and first- watersheds increases. The null hypothesis was that there is no correlation between the two variables (t st—critical at a = 0.05). As alternative hypothesis, it was assumed that there is a positive correlation between TN concentrations and the percentage of land use (t > t-critical at a = 0.05). The t critical value = 1.695 at a = 0.05 (95% probability) and df = 34. 64 Ho null hypothesis: there is no correlation between TN concentrations and the percentage of land use H1 alternative hypothesis: there is a correlation between between TN concentrations and the percentage of land use The null hypothesis was rejected as the tvalues for the different land use / land cover types (table 4-4) were greater than t critical value = 1.695. However, the correlation between the percentage of urban land (within the sub-watershed as well the first order watershed) and increasing TN concentrations were not statistically significant at the 95 % confidence level. Logarithmic regression was undertaken to explain the relationship and variance in a regression model between the percentage of LULC (dependent variable) and TN concentrations (dependent variable). A non-linear regression was considered, as a linear least square regression did not explain any variance. A logarithmic model was fitted to TN concentrations and the percentage of urban use within the sub-watersheds which yielded an R2 = 0.003 (Table 4-6). The model could only explain 0.03% of the dependent variable (TN concentrations) and was also not statistically significant at the 95 % confidence level. F critical value = 4.13 at a = 0.003 (95 % probability) and df = 35 F statistic = 0.091, therefore 0.091 < 4.13 or F < F critical 65 Independent Logarithmic Model for total nitrogen Parameter estimates (dependent) °/o LU R Square F df1 df2 Sig. Constant b1 urban .003 .091 1 34 .764 25.006 6.740 _agriculture .024 0.847 1 34 .364 1351.463 253.085 urb. +39. .017 0.584 1 34 0.584 916.198 358.346 H.U. Index .016 0.538 1 34 .468 944.906 345.990 forest .024 0.851 1 34 .363 6527.997 1264.905 Table 46 Percentage of LULC (within sub-watersheds) vs. TN concentrations Percentage of ag vs. TN (sub—watershed) 14000.0 "I 12000.0 .4 10000.0 - 8000.0 - 6000.0 - 4000.0 - 2000.0 — 0.0- O I 0.00 I 10.00 I 20.00 I 30.00 I 40.00 Percentage agriculture 50.00 60.00 Figure 4-1. Percentage of agricultural land use (within sub-watersheds) vs. TN 66 concentrations Then, a logarithmic model fitted to TN concentrations and the percentage of agricultural land use within the sub-watersheds, yielded an R2 = 0.024 (Figure 4.1). The model explained only 2.4 % of the dependent variable (total nitrogen) and was not statistically significant at a = 0.05 (Table 4-6). F critical value = 4.13 at a = 0.05 (95 % probability) and df = 35 F statistic = 0.847, therefore 0.847 < 4.13 or F statistic < F critical When the percentages of urban and agricultural land use (Figure 4-2) were summed and regressed with the TN concentrations in the sub watersheds, the model explained 1.7 % of the dependent variable (total nitrogen) and was not statistically significant (Table 46). F critical value = 4.13 at a = 0.05 (95 % probability) and df = 35 F statistic = 0.584, therefore 0.584 < 4.13 or F statistic < F critical 67 Percentage of urban 8: ag vs. TN 14000.0 4 o 12000.0 .— 10000.0 -I 8000.0 -' 0 6000.0 '- 0 4000.0 - o 0 2000.0 - 8 o O 63> o o $9 0° 0.0-I I I I I I T I 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage urban + agriculture Figure 4-2. Percentage of agricultural & urban land use (within sub-watersheds) vs. TN concentrations 68 Percent of human use index vs. TN 14000.0 4 O 12000.0 _ 10000.0 - 8000.0 - 0 6000.0 - 4000.0 - O O 8 £06) 90 O 00 2000.0 — O O 0.0- (9 I I I I I I l 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage of human use index Figure 4-3. Percentage of human use index (urban + agriculture + bare soil within sub-watersheds) vs. TN concentrations The percentage of human use index, i.e., the combined percentages of urban, agricultural and bare-soil, was regressed with TN concentration (Figure 4- 3). However, the model did not significantly explain 1.6 % of the dependent variable, total nitrogen (Table 4-6). F critical value = 4.13 at c = 0.05 (95 % probability) and df = 35 F statistic = 0.538, therefore 0.538 < 4.13 or F statistic < F critical 69 Logarithmic regression was also undertaken to explain the relationship and variance in a regression model between the percentages of land use (independent variable) and TN concentrations (dependent variable) aggregated to the first order watershed level. The percentages of land use types include the percentages of urban land use, agricultural land, the combined percentage of urban and agricultural land as well as the percentage of human use index (combined percentages of urban, agricultural and bare land). Independent Logarithmic model for total nitrogen Parameter estimates (degendent) % LU-first R square F df1 df2 Sig. Constant b1 urban .000 .000 1 35 .990 1895.525 9.586 igriculture .175 7.223 1 34 .011 11.760 8.444 urban + ag. .071 2.675 1 35 .111 -380.810 790.953 h.u. index .071 2.666 1 35 .111 431.927 803.948 Forest .049 1.791 1 35 .189 8007.71 -1645.04 Table 4-7. Percentage of LULC (within first order watersheds) vs. TN concentrations A logarithmic model (Table 4-7) fitted to TN concentrations and the percentage of urban land use within the first order-watersheds yielded an R2 = 0.000. The model could not explain any variance in the dependent variable (TN concentration) and was not statistically significant at the 95 % confidence level. F critical value = 4.13 at a = 0.003 (95 % probability) and df = 35 F statistic = 0.000, therefore 0.000 < 4.13 or F < F critical 70 Percentage agriculture within first order watershed vs. TP 140.0— 120.0— 100.0— 80.0# 60.0—1 40.0— 20.0— l l I l 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage agriculture Figure 4-4. Percentage of agricultural land use (within first order-watersheds) vs. TN concentrations F critical value = 4.13 at a = 0.05 (95 % probability) and df = 35 F statistic = 7.223, therefore 7.223 > 4.13 or F statistic > F critical Another logarithmic model fitted to TN concentrations and the percentage of agricultural land use within the first order-watersheds yielded an R2 of 0.175 (Figure 4-4). The model explained 17% of the dependent variable, TN concentration, but was not statistically significant at the 95 % confidence level (Table 4-7). 71 The combined percentages of urban and agricultural land use (Figure 4-5) in the first order watersheds were regressed against the TN concentrations and explained 7.1 % of the dependent variable, TN concentration, but was not statistically significant at the 95 % confidence level (Table 4-7). F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 2.675, therefore 2.675 > 4.12 or F statistic > F critical Percentage of urban + ag (first order watersheds) vs. TN 140000.. 0 12000.0— 10000.0— 8000.0—i 0 6000.0- 4000.0— 20000.. O CI) 0 0C5D 0 .0 l l l l T 1 n 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage of urban & agriculture Figure 4-5. Percentage of agricultural & urban land use (within first order watersheds) vs. TN concentrations 72 Percentage of human use index ( first order watershed) vs. TN 14000.0— 0 12000.0— 10000.04 8000.0— 0 6000.0— 4000.0— 2000.0- O O 06300 co 00 0.0— O l l l I I T r 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage human use index Figure 4-6. Percentage of human use index (urban + agriculture + bare within first order watersheds) vs. TN concentrations The combined percentages of urban and agricultural land uses as well as bare soil were regressed with TN concentrations within the first order watersheds (Figure 4-6). The logarithmic model explained 7.1 % of the dependent variable, total nitrogen, but was not statistically significant at the 95 % confidence level (Table 4-7). F critical value = 4.13 at a = 0.05 (95 % probability) and df = 35 F statistic = 2.666, therefore 2.666 < 4.13 or F statistic < F critical 73 The TN concentrations could be influenced by land use types such as urban, agricultural and bare soil. However, this is to be expected as the three LU LC types are all created and modified by humans. Therefore, we would expect to find an inverse or negative correlation between natural cover such as forests and nitrogen concentrations to prove that nutrient loading in the MRW is a function of land use. A logarithmic model (Figure 4-7) in which the percentage of forest cover was regressed with TN concentrations within the sub-watersheds resulted in R2 = 0.024, explaining 2.4 % of the dependent variable (TN concentration), but was not statistically significant at a = 0.05 (Table 4-6). Percentage of forests vs. TN (sub-watershed) 14000.0 - o 12000.0 - 10000.0 - 8000.0 -‘ O 6000.0 ‘ 4000.0 q 0 2000.0 - 0 C6 0 C9 00 8000) O@ O 0.0~ I T I I 0.00 20.00 40.00 60.00 80.00 Percentage of forest Figure 4-7. Percentage of forests (within sub-watersheds) vs. TN concentrations 74 F critical value = 4.13 at a = 0.05 (95 % probability) and df = 35 F statistic = 0.851, therefore, 0.851< 4.13 or F statistic < F critical Percentage of forest cover vs.TN 14000.0. 0 12000.0-— 10000.0— 8000.0-9 6000.0— 40000.4 2000.0— l l T l l 0.00 20.00 40.00 60.00 80.00 100.00 Percentage of forest Figure 4-8. Percentage of forests (within first order watersheds) vs. TN concentrations Another logarithmic model (Figure 4-8) in which the percentage of forest cover was regressed with TN concentrations within the first order watersheds resulted in R2 = 0.049 explaining 4.9 % of the dependent variable, TN concentration, but was not statistically significant at c = 0.05 (Table 4-7). 75 critical value = 4.13 at c = 0.05 (95 % probability) and df = 35 F statistic = 0.851, therefore, 0.851< 4.13 or F statistic < F critical The proportion of urban land use within a watershed gives us an indication of urban development. However, a more accurate picture of the effects of anthropogenic modification can be realized through the use of a human use index. The human use index combines the proportion of land use types such as urban, agriculture and bare soil. The index allows us to identify areas that have been converted from their natural state (O’Neil et al., 1988) instead of considering individual LULC categories. The logarithmic regressions between total nitrogen distributions and percentages of LULC indicate an initial increase in TN concentrations with an increase in the percentages of agricultural and urban land use and then remain unchanged regardless of any increase in LULC percentages. Denitrification, sedimentation and uptake by aquatic biotic communities would account for some of the variability in the regression model (Hill, 1981; Burns 1998). In addition to the above, nutrient transport within a watershed is a function of stream discharge and travel time. Travel time is a measure of stream length divided by stream velocity. Stream velocity itself is directly proportional to stream discharge. As stream discharge drops, velocity also drops resulting to an increase in travel times from the source to the stream system. As a result, a lesser volume of water entering the watershed system would mean a greater loss 76 of nutrients such as nitrogen and phosphorus. Total nitrogen distribution, depicted by graded symbols across the watershed was overlaid on a GIS layer depicting the percentage of agricultural land using ESRI Arc Map. The resultant map shows a strong spatial correlation between increasing total nitrogen concentrations and the percentage of agricultural land use (Figure 4-9). It is interesting to note that the upper Midwest has the highest application rates of fertilizer (greater than 7 tons per square mile) when compared to the rest of the Nation (USGS circular, 1999). 77 Total Nitrogen 19.9 - 734.0 734.1 - 1221.3 1221.4 - 2080.0 2080.1 - 4850.0 4850.1 - 13902.2 Percent Agriculture " ‘ 0.10-0.88 0.89-2.41 " 2.42.455 :' ‘,' 4.86-8.05 [:3 8.081397 in 13.98- 18.54 a 18.55- 22.52 - 22.53 -27.52 - 27.53 -35.90 - 35.91 -51.46 I Total phosphorus - 0.00- 7.10 e 7.11 - 20.70 0 20.71 - 39.60 . 39.61 - 74.10 0 74.11 - 129.60 Figure 4-9. TN and TP concentration distribution overlaid on % agricultural land use 78 4.1.3 TP concentration and percentage of LULC Total phosphorus concentrations (measured in parts per billion) within the sub-watershed were assumed to be positively correlated (using Spearman’s rank correlation) with the percentages of urban land use, agricultural land, the combined percentage of urban and agricultural land, as well as the percentage of human use index (combined percentages of urban, agricultural and bare land). It was also assumed that TP concentrations were negatively correlated with forest cover. TP vs. LULC Correlation tvalue tcritical, a = 0.05 TP vs. urban 0.384 2.425 1.695 TP vs. agriculture 0.564 3.982 1.695 TP vs. urban + agriculture 0.651 5.000 1.695 TP vs. urban + ag + bare 0.658 5.095 1.695 TP vs. forest -0.496 -3.330 -1.695 Table 4-8. Correlation between TP concentrations and LULC within sub- watersheds In addition, TP concentrations within the first order watersheds were assumed to be positively correlated with percentages of urban and agricultural LULC types as well as their combined percentages. It was also assumed that the TP concentrations were negatively correlated with the percentage of forests in the first order watersheds. 79 TP vs. LULC Correlation tvalue tcritical, d = 0.05 TP vs. urban 0.295 1.8002 1.695 TP vs. ag 0.568 4.0241 1.695 TP vs. urban + agriculture 0.640 4.8567 1.695 TP vs. urban + ag + bare 0.629 4.7178 1.695 TP vs. forest -0.499 -3.3575 -1.695 Table 4-9. Correlation between TP concentrations and LULC within first order watersheds As hypothesis, it was assumed that TP concentrations increase when the percentage of anthropogenically modified land within the sub-watersheds and the first order watersheds increases. The null hypothesis was that there is no correlation between the two variables (t s t-critical a - 0.05). As alternative hypothesis, it was assumed that there is a positive correlation between total invertebrate taxa and percentage of urban land use (t > t-critical at a = 0.05). The t critical value was 1.695 at a = 0.05 (95% probability) and df = 34. Ho Null hypothesis: there is no correlation between TP concentrations and percentage of land use H1 Alternative hypothesis: there is a correlation between TP concentrations and percentage of land use The null hypothesis was rejected as the tvalues for the different cases (Table 4- 8) were greater than the t critical value = 1.695. 80 Logarithmic regression analysis was also undertaken to explain the variance in a regression model between percentage of LULC (dependent variable) and TP concentration in the sub-watershed as well as within the first order watersheds. A non-linear regression was considered, as a linear least square regression did not explain any variance in the independent variable. A logarithmic model (Table 4—10) fitted to TP concentrations and the percentage of urban land use within the sub- watersheds which yielded an R2 = 0.020. The model explained 2.0% of the dependent variable, TP concentrations and was not statistically significant at a = 0.05. F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 0.701 therefore 0.701 < 4.12 or F statistic < F critical Independent Logarithmic model for total phosphorus Parameter estimates (dependent) % LU-sub R Square F df1 df2 Sig. Constant b1 urban .020 0.701 1 34 .408 25.006 6.740 agriculture .187 7.836 1 34 .000 10.884 9.1 63 urb.+ag. .307 15.053 1 34 .000 -20.436 ’ 18.713 h.u. index .309 15.206 1 34 .000 -21.401 18.948 forest .404 23.012 1 34 .000 238.851 -56.44 Table 4-10. Percentage of LULC (within sub-watersheds) vs. TP concentrations A logarithmic model (Figure 4-10) fitted to TP concentrations and the percentage of agricultural land use within the sub-watersheds yielded an R2 = 0.187 and significantly explained 18.7 % of the dependent variable, TP concentrations (Table 4-10). 81 F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 7.836 Therefore 7.836 4.12 or F statistic > F critical Percentage agriculture within sub-watershed 140.00— 120.00.... 100.00- 80.00 - 60.00 -l 40.00 - 20.00 -1 000-4 l l l l l l 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage agriculture Figure 4-10. Percentage of agricultural land (within sub-watersheds) vs. TP concentrations 82 Percent of urban + agriculture vs. TP (sub-watershed) 140.00 — 120.00 - 100.00 0 80.00 A 60.00 A 40.00 J 20.00 a 0.00— l 1 l 1 i l 1 0.00 10.00 20.00 30.00 40.00 50.00 60.00 percent urban + agriculture Figure 4-11. Percentage of urban & agricultural land (within sub-watersheds) vs. TP concentrations A logarithmic model (Figure 4-11) fitted to TP concentrations and the combined percentages of urban and agricultural land use raised the R2 to 0.307, significantly explaining 30.7 % of the dependent variable, TP concentrations (Table 4-10). F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 15.053 therefore 15.053 > 4.12 or F statistic > F cn'tical 83 Percentage of human use index vs. TP 140.00— 120.00.. 100.00— 80.00 - 60.00 — 40.00 — 20.00 — 0.00 — l l l l l l l 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percentage of human use index Figure 4-12. Percentage of human use index within sub-watersheds vs. TP concentrations A logarithmic model (Figure 4-12) in which the combined percentages of urban land use, agricultural land use, and bare soil were regressed with TP concentrations within the sub-watersheds resulted in R2 = 0.309, significantly explaining 30.9 % of the dependent variable, TP concentrations (T able 4-10). F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 15.206. therefore 15.206 > 4.12 or F statistic > F critical 84 Logarithmic regression was also undertaken to explain the relationship and variance in a regression model between the percentages of LULC (dependent variable) and TP concentrations (dependent variable) aggregated to the first order watershed level. The percentages of land use types include the percentages of urban land use, agricultural land, the combined percentages of urban and agricultural land as well as the percentage of human use index (combined percentages of urban, agricultural and bare land). Independent Logarithmic model for total phosphorus Parameter (dependent) estimates % LU-first R Square F df1 df2 Sig. Constant b1 urban .018 .639 1 34 .430 25.593 6.612 agriculture .175 7.223 1 34 .011 1 1.760 8.444 urban+ag. .282 13.32 1 34 .001 -18.886 17.636 human index .284 13.50 1 34 .001 -20.333 18.031 forest .367 19.69 1 34 .000 218.885 -50.37 Table 4-11. Percentage of LULC (within first order watersheds) vs. TP concentrations A logarithmic model (Table 4-11) fitted to TP concentrations and the percentage of urban land use within the first order -watersheds yielded an R2 = 1.8. The model explained 1.8% of the dependent variable (T P concentration) and was not statistically significant at a = 0.05. F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 0.639 therefore 0.639 < 4.12 or F statistic < F critical 85 Percent agriculture within first order watershed vs. TP 140.0— 0 120.0— 0 100.0— 80.0— 0 o 60.0— 0 O O O 40.0— o O O ochbO O 0.0— l l l I l l l 0.00 10.00 20.00 30.00 40.00 50.00 60.00 Percent agriculture Figure 4-13. Percentage of agriculture (within first order -watersheds) vs. TP concentrations A logarithmic model (Figure 4-13) fitted to TP concentrations and the percentage of agricultural land use within the first order-watersheds yielded an R2 = 0.175 and significantly explained 17.5 % of the dependent variable, TP concentrations (Table 4-11). F critical value = 4.12 at a = 0.05 (95 °/o probability) and df = 34 F statistic = 7.223 Therefore 7.223 4.12 or F statistic > F critical 86 Percentage of urban + ag within first order watershed vs. TP 140.04 0 120.04 0 100.0— 80.0— 0 o 60.0— 40.0— 20.0“ 0.0— l l l l l 1 r 0.000 10.000 20.000 30.000 40.000 50.000 60.000 Percent of urban + ag LULC Figure 4-14. Percentage of urban & agriculture (within first order-watersheds) vs. TP concentrations A logarithmic model (Figure 4-14) fitted to TP concentrations and the combined percentages of urban and agricultural land use resulted in an R2 of 0.282, significantly explaining 28.2% of the dependent variable, TP concentrations (Table 4-11). F critical value = 4.12 at a = 0.05 (95 % probability) and df= 34 F statistic = 13.328 therefore 13.328 > 4.12 or F statistic > F critical 87 Percentage of human use index within first order watershed vs. TP 140.0— 0 1200— 0 100.0— 80.0— 0 o 60.0— 40.0— 20.04 0.0— I I I I T I T 0.000 10.000 20.000 30.000 40.000 50.000 60.000 Percentage human use Index Figure 4-15. Percentage of human use index (urban + agriculture + bare within first order watersheds) vs. TP concentrations Another logarithmic model (Figure 4-15) in which the combined percentages of urban, agricultural and bare soil were regressed with TP concentrations within the first order watersheds resulted in R2 = 0.284, significantly explaining 28.4 % of the dependent variable, TP concentrations (Table 4-11). F critical value = 4.12 at a = 0.05 (95 % probability) and df = 34 F statistic = 13.500, therefore 13.500> 4.12 or F statistic > F critical 88 The amount of TP concentrations increased with the percentages of urban & agricultural land use and then remained the same irrespective of any increase when bare soil cover was added. This might be accounted for by mitigation of TP concentrations due to sedimentation, and stream flow. The TP concentrations were positively correlated with the land use types such as urban, agricultural and bare soil. However, this is to be expected as the three LULC types are all created and modified by humans. Therefore, we would expect to find an inverse or negative correlation between natural cover such as forests and phosphorus concentrations to prove that nutrient loading in a watershed is a function of land use. Percentage of Forests vs.TP (sub-watersheds) 140.00— 120.00.. 100.00-l 80.00 -1 60.00 — 40.00 — 20.00 — 0.00— F T l l 0.00 20.00 40.00 60.00 80.00 Percentage of forest Figure 4-16. Percentage of forests vs. TP concentrations within sub-watersheds 89 A logarithmic model (Figure 4-16) in which the percentage of forest cover was regressed with TP concentrations within the sub-watersheds resulted in R2 = 0.404, significantly explaining 40.4% of the dependent variable, TP concentrations (Table 4-11). F critical value = 4.13 at a = 0.05 (95 % probability) and df = 34 F statistic = 23.012, therefore 23.012 > 4.13 or F statistic > F critical Percentage of forest cover within first order watersheds vs. TP 140.0— 0 120.0— 0 100.04 80.0— 0 O 60.0_ 0 O 0 O 40.0— o o 8 o _ o . 20.0 o o 0 9 o QO 0 00—- l I I I I I 0.000 20.000 40.000 60.000 80.000 100.000 Percentage of forest Figure 4-17. Percentage of forests vs. TP concentrations within sub-watersheds Another logarithmic model (Figure 4-17) in which the percentage of forest cover was regressed with TP concentrations within the first order-watersheds resulted in R2 = 0.367, significantly explaining 36.7% of the dependent variable, TP concentrations (Table 4-11). 90 The regression between total phosphorus and forest cover within the sub- watershed as well as the first order watersheds confirmed the negative correlation between the variables. This negative relationship confirms the premise that land use patterns influence TP concentrations within the MRW. The nutrient export within the watershed as downstream of the headwaters is a function of various physical and anthropogenic factors. Factors such as inter-annual changes in precipitation, cropping practices, fertilizer applications relative to rainfall events, local geology, and the density and spatial distribution of impervious surfaces play an important role in influencing total nitrogen and total phosphorus transport (Wickham et al., 2003). Concentrations of nutrients in watersheds with a greater proportion of agricultural areas are higher in spring and summer months owing to higher flow conditions as well as fertilizer application in the peak—growing season. 91 Legend TN 0 19.9-7340 o 7341-12213 . 12214-20800 . 2080.1 - 4850.0 . 4850.1 - 13902.2 Percent Human Use Index T—_ 1.40-3.77 lf 3.78 - 5.39 [1 _ 5.40- 9.62 I: ‘3 963-1505 [1‘5 15.06-18.25 18.26- 22.78 .; 22.79-26.88 - 28.89- 30.73 - 30.74- 42.17 - 42.18-54.88 Total phosphorts - 0.00- 7.10 e 7.11 - 20.70 0 20.71 - 39.60 . 39.61 - 74.10 . 74.11 - 129.60 Figure 4-18. TN and TP concentrations overlaid on % human use index The differences between sub-watershed nutrient concentrations could be explained by different cropping practices such as conservation tillage versus non- conservation tillage (Wickham et al., 2003). A sub-watershed where conservation tillage was practiced would have greater phosphorus concentrations than compared to a forested watershed. On the other hand, a sub-watershed where non-conservation tillage was practiced would have greater phosphorus concentrations than a sub-watershed which practices conservation tillage. As compared to total nitrogen, a smaller proportion of phosphorus is lost to nutrient decay. Total phosphorus originates from livestock manure and agricultural fertilizer and wastewater treatment plants. Even though less phosphorus is leached from agricultural field than nitrogen, there is a higher probability that it will reach concentrations (greater than 0.1 mg/liter) enough to cause eutrophication in streams and lakes through aquatic plant growth (USGS circular, 1999). Total phosphorus distribution depicted by graded symbols across the watershed in ESRI ArcMAP, was overlaid on the percentage of agricultural land use (Figure 4-18). The total phosphorus distribution was also mapped on the total proportion of the landscape modified by human activities, ie, the human use index (urban + agriculture + bare). Again, a strong spatial correlation was seen between the two variables. A visual assessment indicates that total phosphorus 93 concentrations that are downstream of sub-watersheds with greater percentage of agricultural land use have higher values (Figure 4-18). 4.1.4 Total invertebrate taxa and percentage of urban land use Total invertebrate taxa within the sub-watershed were negatively correlated with the percentage of urban land use (Spearman’s rank correlation: - 0.416, a = 0.05). The null hypothesis was that there is no correlation between the two variables (t st-critical at a = 0.05). As alternative hypothesis, it was assumed that there is a negative correlation between total invertebrate taxa and the percentage of urban land use (t > t-critical at a = 0.05). The t critical value = - 1.695 at a = 0.05 (95% probability) and (if = 34. Ho Null hypothesis: there is no correlation between total invertebrate taxa and the percentage of urban land use H1 Alternative hypothesis: there is a correlation between total invertebrate taxa and the percentage of urban land use The null hypothesis was rejected as the t = -2.675 and was greater than —1.695. Total invertebrate taxa & LULC Correlation tvalue tcritical, a = 0.05 Total invertebrate taxa & % urban -0.416 -2.675 -1.695 Table 4-12. Percentage of urban land use vs. total invertebrate population within sub-watersheds 94 Linear regression of the total invertebrate taxa and the percentage of urban land use failed to explain the variance in the data and so a log-transforrn was used on the percentage of urban land use to linearize the model. . 0.5 1 (4-1) ' =1 N* +— 1— +— y1 og[ y N( y) 2] where y = % urban land use The log-transformed model (Bailey and Gatrell, 1995) significantly described 22% of the variance (p < 0.003) between total invertebrate taxa and the percentage of urban land use. The linear regression performed after the log transform showed a negative trend between the diversity of invertebrate taxa and the percentage of urban land use (constant = 5.5661 and slope = -0.022). 4.1.5 Total EPT taxa and percentage of urban land use Total EPT taxa within the sub-watershed were negatively correlated with the percentage of urban land use (Spearman’s rank correlation: -0.381, a = 0.05). The null hypothesis was that there is no correlation between the two variables (t s t- critical, 0 = 0.05). As alternative hypothesis, it was assumed that there is a negative correlation between total EPT and the percentage of urban land use (t > t-cn'tical at a = 0.05). The t critical value = -1.695 at a = 0.05 (95% probability) and df = 34. 95 Ho Null hypothesis: there is no correlation between total EPT taxa and the percentage of urban land use H1 Alternative hypothesis: there is a correlation between total EPT taxa and the percentage of urban land use The null hypothesis was rejected as the t = —2.393 and was greater than t-critical. Sensitive insect taxa & LULC Correlation tvalue tcritical, a = 0.05 EPT taxa & % urban -0.381 -2.393 -1 .695 Table 4-13. Percentage of urban land use correlated with sensitive insect population within sub-watersheds EPT taxa within the sub-watershed were regressed with the percentage of urban use. As in the case of total invertebrate taxa, a linear regression failed to explain the variance in the data and so the percentage of LULC was log- transformed in an attempt to linearize the model. A linear regression of the log- transformed urban land use yielded an R2 = 0.15 (p < 0.011) and shows that there is a slight decrease in EPT taxa with increase in percentage of urban land use (constant = 5.264 and slope = -0.036). This negative correlation can be explained by the fact that the mayflies, caddisflies and stoneflies that make up the EPT taxa evolved in oxygen rich, cool waters. Depleted oxygen levels as well as increasing water temperatures due to 96 increased runoff and short travel times over increasing impervious surfaces might explain the reason in EPT population decline as the percentage of urban land use increases. 4.1.6 Proximity to urban areas A correlation test between total nitrogen concentrations and distance to urban areas found the two variables to be negative correlated (Table 4-14). Total nitrogen concentrations dropped with increasing distance from urban areas. TN concentration & distance to LULC Correlation, a = 0.05 TN concentration & Urban -0.137 Table 4-14. Proximity to urban areas & TN concentrations within MRW The null hypothesis was that there is no correlation between the two variables (t st-critical at a = 0.05). As alternative hypothesis, it was assumed that there is a negative correlation between proximity to urban areas and TN concentrations within the watershed (t > t-critical at a = 0.05). The t critical value = -1.645 at a = 0.05 (95% probability) and df = 217. 97 Ho Null hypothesis: there is no correlation between proximity to urban areas and TN concentrations H1 Alternative hypothesis: there is a correlation between proximity to urban areas and TN concentrations The null hypothesis was rejected as the t = -2.0375 and was greater than t-critical. A correlation test was also carried out between total phosphorus concentrations and distance to urban areas found the two variables to be positively correlated but with a very low correlation co-efficient, which was not statistically significant (at a = 0.05). TP concentration & distance to LULC Correlation, a = 0.05 TP concentration & urban 0.057 Table 4-15. Proximity to urban areas & TP concentrations within MRW The null hypothesis was that there is no correlation between the two variables (t st-critical at a = 0.05). As alternative hypothesis, it was assumed that there is a negative correlation between proximity to urban areas and total phosphorus concentrations within the watershed (t > t-critical at a = 0.05). The t critical value = 1.645 at a = 0.05 (95% probability) and df = 127. Ho Null hypothesis: there is no correlation between proximity to urban areas and TP concentrations 98 H1 Alternative hypothesis: there is a correlation between proximity to urban areas and TP concentrations The alternative hypothesis was rejected as the t = 0.6434 and was less than t- critical. Regression analysis characterized a positive linear association between the dependent variable (total nitrogen concentration) and the independent variable, distance to urban areas resulted in a negative relationship (Table 4—16). However, it was not statistically signifimnt at a = 0.05. I Model summary Parameter estimates I Equation I RSquare F df1 df2 Sig. Constant b1 I I Linear I .008 1.735 1 217 .189 1043.300 -.397 I Table 4-16. Proximity to urban areas vs. TN concentrations within MRW 4.1.7 Proximity to agricultural areas A correlation test carried out between total nitrogen concentrations and distance to agricultural areas found the two variables to be negatively correlated, but with a very low correlation co-efficient, which was not statistically significant at a = 0.05 (Table 4-17). TN concentration & distance to LULC Correlation TN concentration & agriculture -0.0124 Table 4-17. Proximity to agricultural areas & TN concentrations within MRW 99 A correlation test between TP concentrations and distance to agricultural areas found the two variables to be negative correlated (Table 4-18). Total phosphorus concentrations dropped with increasing distance from agricultural areas. TP concentration & distance to LULC Correlation, a = 0.05 TP concentration & agriculture -0.324 Table 4-18. Proximity to agricultural areas & TP concentrations within MRW The null hypothesis was that there is no correlation between the two variables (t st-critical at a = 0.05). As alternative hypothesis, it was assumed that there is a negative correlation between proximity to agricultural areas and TP concentrations within the watershed (t > t-critical at a = 0.05). The t critical value = 1.645 at a = 0.05 (95% probability) and df = 127. Ho Null hypothesis: there is no correlation between proximity to agricultural areas and TP concentrations H1 Alternative hypothesis: there is a correlation between proximity to agricultural areas and TP concentrations The null hypothesis was rejected as t = -3. 8594 and was greater than t—critical. 100 CHAPTER 5 CONCLUSIONS The objective of this research was to obtain an accurate inventory of LULC within the 40 sub—watersheds of the Muskegon River Watershed and correlate the LULC types with water quality indices such as total nitrogen, total phosphorus, specific conductivity, populations of sensitive insect species (EPT taxa) and total invertebrate taxa. The specific hypothesis was that LULC affects water quality within the MRW. The results demonstrate that there is a positive correlation between types of land use (urban, agriculture and bare soil) and water quality indicators. This positive correlation was determined by the spatial scale of study. The two spatial scales considered were the sub-watershed level study and the first order watershed level. In addition, negative correlations were found between forest cover and water quality indicators at the sub-watershed level. This confirms the fact that it is land use within the watershed that affects the water quality and that forest cover within catchments is beneficial. The sub-hypothesis conclusion is that the LULC within the MRW was accurately mapped through an unsupervised classification of ETM+ imagery (Landsat-7) and with an overall classification accuracy of 83%. In addition, water quality indicators measured at 256 sampling locations were aggregated to the sub- watershed level and correlated with LULC types within the 40 sub-watersheds. 101 Statistical relationships were established between water quality measures and percentage of land use I land cover within the watershed. Among the water quality indicators, total phosphorus and total nitrogen distribution as well as biological indiwtors such as EPT taxa and total invertebrate taxa, were influenced by the percentages of agricultural and urban land uses within the sub-watershed. Significant positive correlations were found between total nitrogen concentrations and percentage of urban and agricultural land uses (0.18 and 0.4 respectively). The correlations increased slightly when the combined percentages of urban, agriculture and bare soil were considered. Positive correlations were also found between total phosphorus concentrations and percentage of urban and agricultural land uses (0.38 and 0.65 respectively). These correlations are important as the phosphorus concentrations cause eutrophication in lakes and steams within the watershed. The sources of the nutrients might be from fertilizer application on farms but might also be from confined animal feeding operations (CAFO’s) or wastewater treatment plants. An inverse or negative correlation was found between natural cover such as forests and nitrogen/phosphorus concentrations (0.40 and 0.49 respectively) to prove that nutrient loading in a watershed is a function of land use. The variance in total phosphorus concentrations could be explained more by the percentage of land use within the sub—watersheds as compared to the variance in total nitrogen concentrations. Though the statistical relationships between the 102 dependent variables (water quality indices) and the independent variables (LULC types) were significant at the 95% confidence level, the predictive power of the logarithmic models was very low with R2 ranging from 0.018 to 0.40. The low predictive power of the logarithmic regression models for nitrogen concentrations can be attributed to various physical and anthropogenic factors. For instance, the variability in total nitrogen concentrations could be attributed to denitrifioation, sedimentation and uptake by aquatic biotic communities. The transport of nutrients in a watershed is also influenced by stream velocity and travel time. The variability of the nutrient concentrations within the sub-watersheds could also be governed by factors such as changes in precipitation, cropping practices, fertilizer applications relative to rainfall events, local geology, the density and the spatial distribution of impervious surfaces. Total nitrogen concentrations were influenced more by distance to urban areas as opposed to total phosphorus concentrations, which were influenwd by distance to agricultural areas. Specific conductivity was positively correlated with individual land use types such as urban and agricultural land use or the combined percentages of human modified LULC types with correlations ranging from 0.60 and 0.72. This could be attributed to a greater proportion of urban land use in some of the sub-watersheds. Also, the percentage of forest cover was negatively correlated with specific conductivity. This negative correlation makes a strong case for the influence of urban and agricultural land use on water quality. In addition, sensitive insect populations 103 (EPT taxa) as well as the total invertebrate taxa were negatively correlated with urban land use (0.38 and 0.41 respectively). These correlations were significant at the 95 % confidence level. My research studies the land-water interactions at two spatial scales, i.e., the sub-watershed level and the first order watershed level. It is based in part on Omemik's study (1981) that demonstrated that land use in the distant uplands had as much effect on water quality as land use in the vicinity. in addition, my research considers the proportions of land use within hydrologically distinct units such as sub- watersheds as opposed to the immediate vicinity, which is the case in most ecological studies. These studies suggest that water quality is influenced by the land use within a buffer zone that is approximately 30—100m from the water’s edge. The beautiful natural surrounding and easy access to recreation have resulted in an increase in urban development around the lakes in Michigan. In recent times, land value has gravitated towards residential development rather than agricultural land use. Also, it is important to note that the upper Midwest has the highest application rates of fertilizers on agricultural land when compared to the rest of the nation. Agricultural land use still plays a major role in affecting water quality. This research is important as it documents the correlation between urban and agricultural land use and water quality of Michigan’s second largest watershed. The statistical analysis provides proof that sub-watersheds with a greater proportion of natural cover such as forest cover are beneficial and negatively correlated to nutrient 104 concentrations as compared to sub-catchments with a greater proportion of urban / agricultural land use. Local decision makers could be empowered to act in their own interests and conserve the natural surrounding which in turn would ensure qood water quality. Sub-watersheds that are predominantly urban or agricultural in nature could mitigate their impact on the water quality through the maintenance of riparian buffer strips. In addition to acting as filters and reducing nutrient concentration within lakes and streams, riparian buffers prevent stream bank erosion. Ecologists who believe that landscape patterns influence water quality often prescibe riparian buffers as a conservation measure. Future research that concerns land-water interactions in the MRW might consider correlating landscape metrics (e.g., contagion, dominance) that describe the spatial configuration of the landscape with water quality indicators. 105 1' APPENDICES 106 APPENDIX-A: Figures used in the study Figure 5-1. imagery from WRS Path 21 Row 30 Landsat 7 (ETM+) 107 Figure 5-2. Imagery from WRS Path 22 Row 30 Landsat 7 (ETM+) 108 Figure 5-3. MRW—LULC map derived through unsupervised classification 109 Projection: UTM Zone 16 Datum WGS 84 051) Figure 5-4. MRW—LULC map derived through unsupervised classification and smoothed with 3x3 majority filter 110 Projection: UTM Zone 16 Datum WGS 84 Elevation (in meters) . High : 528 .. _ Low : 177 Figure 5-5. SRTM derived Digital Elevation Model (DEM) 111 Figure 5-6. SRTM derived DEM overlaid with Strahler stream order 112 Figure 5-7. Wetness index derived from SRTM DEM overlaid with MRW wetlands coverage 113 Figure 5-8. Urban development around Lake Houghton (2001) 114 “.4 I. .. 1 .. 42A dtp‘ut NA 9.. a. .. IX. .r n. g- I s. N . I -x ,‘ao- ‘ e v. N. ._ t. a . . a _ .I._ . s. 4. s .7 A M _ .r..l...» . . . .r‘ 3 I; . 4 s... 1.. a... . A a. v0 ’ I . a .. .7. J o .. EN... .2‘ .. ..\. .u r L ... .\w as 5.011. . .. m 1% .pl. :6? .. . . 2 .1 4 .6 . n. .. 10.3.). . a..- .. Car. .4 ._ a _. .... .. 1 ._ .. a .. w . 7. It}-.. t: . , .5 , 6.. . ~ . _ 7)., . {romaifsdfi Left. . .ih.l.r...}..A&1...vi.TlJili If A 2% fluthurqwrivfl L.£.hr..u.«wnfli.t Hi.” / . I . .. .1;1..fi..3n:.u....a . /. . \ . . .1-.. . .. /(\ v r. ~ m _ .. l .. .2 2 0051 Figure 5-9. Urban development around Lake Higgins (2001) 115 APPENDIX B: Data used in statistical analysis Sub-watersheds TN TP 1 270.80 no data 2 1204.20 7.10 3 1460.00 16.17 4 1549.70 12.40 5 1320.00 27.83 6 1006.20 19.80 7 no data no data 8 1 721 .40 48.70 9 1 1 18.78 26.38 10 695.92 1 1 .50 1 1 637.04 1 1 .91 12 1447.30 41 .10 13 1478.90 31.50 14 1200.00 22.30 15 no data no data 16 2060.10 129.60 17 1046.20 1 1 .70 18 848.60 14.00 19 1 193.00 67.20 20 1503.10 27.10 21 890.70 56.20 22 906.60 16.91 23 1325.40 31 .47 24 937.90 32.90 25 13902.20 30.13 26 586.40 13.30 27 2829.40 22.23 28 7811.00 18.00 29 3595.40 57.00 30 4850.00 109.80 31 2483.40 21 .30 32 no data no data 33 641 .30 28.30 34 809.30 15.00 35 1808.70 65.70 36 593.00 14.20 37 1084.40 17.60 38 1070.00 40.95 39 555.60 1 1.60 40 2080.00 49.30 Table 5-1. Water quality indicators within MRW sub-watersheds TN- total nitrogen, TP- total phosphorus (measured in parts per billion) 116 Sub-watersheds Conductivity EPT taxa Tot invert. taxa 1 no data no data no data 2 236.0 16.0 43.0 3 268.5 10.0 34.0 4 224.0 9.0 42.0 5 294.0 23.0 66.0 6 268.8 12.0 36.0 7 no data no data no data 8 292.5 4.0 22.0 9 221.0 11.0 42.0 10 181.0 20.0 50.0 11 324.0 6.0 26.0 12 no data no data no data 13 338.8 13.0 43.0 14 355.9 15.0 39.0 15 no data no data no data 16 398.1 15.0 41.0 17 349.3 17.0 47.0 18 290.8 25.0 58.0 19 359.3 11.0 41.0 20 344.4 15.0 49.0 21 371.6 14.0 42.0 22 521.0 22.0 48.0 23 414.3 13.0 32.0 24 415.7 11.0 37.0 25 455.0 8.0 24.0 26 355.4 17.0 38.0 27 330.0 7.0 33.0 28 519.3 16.0 41.0 29 472.2 14.0 43.0 30 514.0 1.0 9.0 31 525.3 5.0 30.0 32 496.5 6.0 23.0 33 325.0 2.0 26.0 34 287.8 18.0 42.0 35 521 .3 27.0 57.0 36 496.5 6.0 23.0 37 273.5 9.0 34.0 38 444.9 12.0 49.0 39 286.5 6.0 28.0 40 631.0 2.0 16.0 Table 5-2. Water quality indicators within MRW sub-watersheds Conductivity- specific conductivity, EPT taxa- ephemeroptera, plecoptera & trichoptera, tot invert.taxa - total invertebrate taxa 117 sub- urban (log watersheds urban agriculture urban+ agric. bare ag.+urban+bare transformed) 1 4.33% 0.11% 4.44% 0.12% 4.56% 0.808 2 2.62% 0.88% 3.50% 0.28% 3.78% 0.443 3 3.60% 1.18% 4.78% 0.19% 4.97% 0.667 4 1.64% 2.42% 4.06% 0.05% 4.11% 0.156 5 1.49% 8.05% 9.54% 0.09% 9.63% 0.101 6 1.87% 13.98% 15.85% 0.31 % 16.15% 0.231 7 0.80% 0.60% 1 .40% 0.00% 1 .40% —0.183 8 2.12% 24.32% 26.44% 0.45% 26.89% 0.306 9 2.30% 1.04% 3.34% 0.11% 3.45% 0.359 10 2.34% 1.28% 3.62% 0.08% 3.71% 0.370 11 1.71% 3.56% 5.27% 0.10% 5.37% 0.180 12 6.56% 12.55% 19.11% 1.05% 20.16% 1.142 13 2.65% 21 99% 24.64% 0.29% 24.93% 0.452 14 3.67% 15.75% 19.43% 0.23% 19.66% 0.683 15 3.35% 42.68% 46.03% 0.45% 46.47% 0.616 16 2.95% 46.24% 49.18% 0.53% 49.71% 0.525 17 1.85% 16.13% 17.97% 0.29% 18.26% 0.223 18 1.00% 2.00% 3.00% 0.10% 3.10% -0.091 19 2.69% 26.93% 29.62% 0.23% 29.84% 0.461 20 2.40% 1 1.95% 14.35% 0.06% 14.41% 0.387 21 2.86% 34.61% 37.46% 0.13% 37.59% 0.503 22 2.56% 13.32% 15.88% 0.13% 16.01% 0.429 23 3.83% 21.00% 24.83% 0.15% 24.99% 0.715 24 3.45% 35.90% 39.35% 0.15% 39.49% 0.637 25 4.07% 18.55% 22.62% 0.16% 22.78% 0.761 26 2.07% 11.43% 13.50% 0.03% 13.52% 0.291 27 2.50% 22.53% 25.02% 0.27% 25.30% 0.412 28 2.84% 32.07% 34.91% 0.14% 35.05% 0.500 29 3.15% 27.53% 30.68% 0.05% 30.73% 0.572 30 3.25% 51.47% 54.72% 0.17% 54.89% 0.594 31 6.50% 35.37% 41.87% 0.31% 42.17% 1.135 32 5.22% 0.17% 5.39% 0.00% 5.39% 0.955 33 2.57% 4.85% 7.42% 0.01% 7.44% 0.432 34 1.89% 12.18% 14.07% 0.07% 14.13% 0.236 35 3.98% 25.82% 29.80% 0.13% 29.94% 0.744 36 1 .00% 2.00% 3.00% 0.43% 3.43% -0.091 37 3.10% 14.90% 18.00% 0.20% 18.21% 0.561 38 3.98% 20.62% 24.60% 0.25% 24.84% 0.743 39 13.75% 1.02% 14.77% 0.28% 15.06% 1.793 40 26.74% 0.69% 27.42% 2.25% 29.67% 2.416 118 Table 5-3. 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