3A1 mm H 'il' “5”." ‘f‘fi ,. Lu' ._‘ i" . . l — ,- a I . l . .-__». {‘9' L" Y , a . {“er ' l I‘m 3 a. 2 It . a u '\ : 21"" -r~:- awry: H|‘\;~.1 , . V x. I .4.(.\ LA: LIBRARY Michigan State University This is to certify that the thesis entitled THE INTERACTION 0F ELECTROMAGNETIC RADIATION WITH A BOUNDED PLASMA presented by Andrew RostysIaw MeInyk has been accepted towards fulfillment of the requirements for Ph. D. degree in Ph2§iCS Date November 13, 1967 0-169 ABSTRACT THE INTERACTION OF ELECTROMAGNETIC RADIATION WITH A BOUNDED.PLASMA by Andrew Rostyslaw Melnyk The interaction between.e1ectromagnetic.waves and a bounded plasma is studied by extending the.Fresnel equa- tions of reflection and transmission to include-plasma waves with irrotational electric fields.. The preperties of the plasma are incorporated in the dispersion rela- tions for propagating waves. These dispersion relations are obtained from a frequency and complex wave vector dependent dielectric tensor §(§,w) calculated from a linearized Boltzmann transport equation. .Results show structure in the absorptance, reflectance, and trans- mittance spectrum of.thin.p1asma slabs (d <.2nc/wp) due to resonance phenomena.at frequencies where kd = nu; (n = l, 3, 5,...). .These results suggest.that the dis- persion relations of metallic plasmas such.as silver films may be optically.measured. THE.INTERACTION OF ELECTROMAGNETIC RADIATION WITH A BOUNDED.PLASMA By Andrew Rostyslaw Melnyk A.THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY .Department of Physics 1967 ACKNOWLEDGEMENTS I wish to thank Professor Michael J. Harrison-for suggesting this research problem, for his advice and his continued encouragement throughout the course of the work. Also I extend my thanks to Professor Truman O. Woodruff, Professor Donald J.Montgomery, Dr. Paul Petersen, and Mr. Don.Slanina for helpful discussions. Finally I am grateful to the National Science Foundation for financial support during the course of this investi- gation. ii TABLE OF CONTENTS ACKNOWLEDGEMENTS LIST OF LIST OF Chapter I. II. III. FIGURES APPENDICES INTRODUCTION . . . . . . . . . . 1. Fundamentals Solid State Plasmas Acoustic Plasma Waves Plasma Waves . 2. Interactions of Plasmas with Electro- magnetic Waves THEORY OF REFLECTION AND TRANSMISSION . . 1. Equations of Transmission and Reflection for a Medium Bounded by a Plane . Snell's Law . . . . . . . . Boundary Conditions Fresnel Equations General Equations . 2. Properties of the General Equations Energy Conservation . 3. Equations of Transmission and Reflection for a Slab . . . . . . . . . DISPERSION RELATIONS FOR A COLLISIONAL PLASMA . . . . . . . . Theoretical Formulation . Calculation of the Distribution Function The Conductivity Tensor . . . . . Evaluation of a and R Dispersion Relat1ons b “NH iii Page ii . viii MMNH I-" O‘ Table of.Contents/cont. Chapter IV. RESULTS . . . 1.. Plasma Slab of Infinite Thickness 2. Plasma Slab of Finite Thickness Numerical Results . . V. DISCUSSION AND CONCLUSION APPENDICES REFERENCES iv Page 57 57 59 59 83 89 95 Figure 4a. 4b. 4c. 5a. 5b. 5c. 6a. 6b. 6c. LIST OF FIGURES Wave ko~incident-on some lossy medium excites a wave .15.: 131 + 1E2. 0 o o o o o o 0 Reflection and refraction of s and.p polarized waves at a boundary. . . . . . . . . Reflection and.transmission by a conducting slab of thickness d. Transmittance versus frequency for p-polar- ized radiation incident at an angle of 30 degrees on plasma slabs of thicknesses d/A = 0.0305, 0.0915, 0.1545,.where 1 .is the P vacuum.wave1ength at the plasma frequency, Ap = ch/w . ‘The plasma 13 described by a Fermi veloBity VF = 1.4x10 cm/sec and a col- lision frequency corresponding to wpr = 100 Reflectance versus frequency for 30 degree incidence . . . . . . . . . . . . Absorptance versus frequency for 30 degree incidence . . . . . . . . . . . Transmittance versus frequency for 60 degree incidence and various thicknesses . . . . Reflectance versus frequency for 60 degree incidence and various thicknesses . . . Absorptance versus frequency for 60 degree incidence and various thicknesses . . . Transmittance versus frequency for 80 degree incidence for various thicknesses . Reflectance versus frequency for 80 degree incidence for various thicknesses Absorptance versus frequency for 80.degree incidence for various thicknesses Page 14 17 28 62 63 64 65 66 67 68 69 70 List of Figures/cont. Figure 7a. 7b. 7c. 8a. 8b. 8c. 9a. 9b. 9c. Transmittance versus frequency for slab thickness d = 0.03051 at various angles of incidence . . .p . . . . . Reflectance versus frequency for slab thickness d = 0.03051p at various angles of incidence . . . Absorptance versus.frequency for slab thickness d = 0.03051 .at various angles of incidence . . .p . . . Transmittance versus frequency for slab thickness d = 0.09151 at various angles of incidence . . .p . . . . . . Reflectance versus frequency for slab thickness d = 0.09151 at various angles of incidence . . .p . . . . . . Absorptance versus frequency for slab thickness d = 0.09151 at various angles of incidence . . .p . . . . Comparison of the transmittance versus fre- quency calculated using the Fresnel equations (11.41), dashed curve, and the genera1.equa- tions, solid curve, for a thickness d = 0.03051 and for 60 degree angle of incidence . . . . . . . . . . Comparison of the reflectance.versus.fre- quency calculated using the Fresnel equations (11.41), dashed.curve, and the general equa- .tions, solid.curve, for a thickness d = 0.03051 and for 60 degree angle of incidence . . . . . . . . .Comparison of the.absorptance versus fre- quency calculated using the Fresnel equations (11.41), dashed.curve,.and the general equa- tions, solid curve,.for a thickness d = 0.03051 and for 60 degree angle of incidence P . vi Page 71 72 73 74 75 76 77 78 79 List of Figures/cont. Figure 10a. 10b. 10c. 11. Comparison of the transmittance versus fre- quency calculated using the Fresnel equations (11.41), dashed curve, and the general equa- tions, solid curve, for.a.thickness d = 0.0915 and for 60 degree angle.ofincidence Comparison of the reflectance versus fre- quency calculated using the Fresnel equations (11.41), dashed curve, and.the general equa- tions, solid.curve, for a thickness d = 0.0915 and for 60 degree angle.of.incidence .Comparison of the absorptance versus.fre- quency calculated using the Fresnel equations (11.41), dashed curve, and the general equa- tions, solid curve, for a thickness d = 0.0915 and for 60 degree angle of incidence . Coordinate system defining direction of tensor components . . . vii Page 80 81 82 90 LIST OF APPENDICES Appendix Page A. EVALUATION OF 3 AND V . . . .. . . . . 89 viii I. INTRODUCTION 1. Fundamentals Plasma physics came into existence in 1929 when Tonks and Langmuir1 presented their now famous theory of plasma oscillations in an ionized gas to explain certain anomalies in arc discharges.2 Idealizing the ionized gas as elec- trons imbedded in a uniform positive background, they found that a small displacement of a slab of these electrons from their equilibrium position produces, by Coulomb interac- tions, a restoring force which to first order is pr0por- tional to the displacement. Thus the electrons oscil- late in simple harmonic motion with a.characteristic frequency mp; (.02 = 41TN€2 p m , (1.1) where N is the density, e the charge, and m the mass of the electrons.* Noting the similarity between these os- cillations and the oscillations of a jelly plasma, Tonks * If the material in the positive background is polar- izable, e.g. the lattice ions in a solid state plasma, th . _ 41rNe2 . e relat1on becomes mp - _ETfi—" where so 15 the dielectric constant. and Langmuir christened them ”plasma oscillations" and named the nearly neutral part of the ionized gas a "plasma.” Today a plasma is defined as: "the portion of-a mater- ial body which is much larger than the shielding length which in turn is larger than the interparticle distance of the charged particles moving through the body." The shielding length 1D is the distance in which the Coulomb field of a test charge will be screened out by the charged particles. For particles with a Maxwellian energy distribution, A2 .__ KT = KT/m 4TrNe2 2 OJp (1.2) and is called the Debye length;3 and for particles with a Fermi-Dirac distribution, V2 1;; = F (1.3) 5002 P and is called the Fermi-Thomas length. In Eqs. 1.2 and 1.3, K is the Boltzmann constant, T is the temperature, and VP is the Fermi velocity. Solid State Plasmas. Until 1951, only gaseous plasmas, consisting of electrons and ions were known and studied. Besides laboratory plasmas, these included naturally occurring gaseous plasmas such as stellar atmOSpheres, interstellar gas clouds, the ionosphere, etc.. But the 1948 experiments of Ruthemann and Lang,4 in which they observed that kev electrons upon passing through thin metallic foils lost energy in discrete steps characteris- tic of the metal, led to the discovery.of the solid state plasma. By treating the metal as a plasma of electrons in a positive lattice, Bohm and.PinesS explained the discrete energy losses as the result of exciting quantized plasma oscillations, calledplasmOns,6 each quantum possessing energy equal to hop. While alike in their essential features, solid state and gaseous plasmas are dissimilar in one important respect: stability.. Gas plasmas, because they are pro- duced by violent means such as spark discharges, are far from therma1.equilibrium, are.not easily contained, and as a consequence of one or more of the many insta- bilities tend to break up. .Thus the central problems in gaseous plasma research are containment and control of all the instabilities.. The solid state plasma, however, is absolutely stable and contained by the neutralizing lat- tice. The problem is no longer how to produce and con- tain the plasma, but given the plasma, what to do with it; i.e., how to throw it out of equilibrium and produce instabilities. Acoustic plasma waves.. In addition to the high.frequency electron-plasma oscillations, Tonks and Langmuir showed that a two component plasma, containing two types of mobile charge carriers or particles, has a low.frequency mode of oscillation. In such a two component plasma, the high frequency oscillation results from.the two charge 'species oscillating out of phase with the frequency w2 = w2 + w2 , (1.4) where wp- and w + are the plasma frequencies.of each P species, e.g., electrons and ions. .If there are more than two species,e.g. different ions or electrons with dif- ferent effective masses, Eq. 1.4 is extended to include the plasma frequency of each species. Because in a gas- eous plasma the ions are much heavier than the electrons; i.e. wp_ >> wp+’ their motion can be neglected and the plasma frequency is just the electroneplasma frequency, but in general the high.frequency oscillation of a.mu1ti- component plasma is given by a generalization of 1.4. The lower frequency mode results from the two.charge species oscillating in phase, and for the electron-ion plasma is _ w;+(k1D_)2 l + (k1D_)2 (1.5) where k is the wave vector, k = 2n/1, and.1D_ is the screening length for the electrons. Because-the.mode 1.5 exists only for wavelengths larger than the.screening length, i.e. for (k1D) 1, N being the particle density, macroscopic electric forces suppress density fluc- tuations over distances greater than AD, hence the col- lision term is replaced by a.macroscopic em force field due to the correlated effect of many particles. Because 8 first used this fluid-like treatment of a plasma, Vlasov the resulting collisionless Boltzmann equation usually bears his name. The macrosc0pic treatment begins with.the hydrody- namic equations of.motion,.which presents a problem since they can be an infinite set of coupled equations. For the sake of illustration only the equations of motion in the low temperature.approximation (LTA) will be.considered. Let N be the particle density, E.the force.on the par- ticles of mass m, g = Ny_the net-particle current, and a the pressure tensor resulting from.the particle motion. Then the hydrodynamic equation of motion of the particles is <5 —1 -lV. fig- aEN m g . (111.2) In the LTA some assumption must be made about the pres- sure tensor, for example p = va2 (111.3) The above equations along with.the continuity equation '3? N + Vt.) = 0. (111.4) and Maxwell's equations determine the system of charged particles. To show how the microsc0pic and macroscopic treat- ments are related, we start with the following moment integrals N(£,t) = Jf(£,v,t)d3v a F 3 9131.0 =J1f(1.x.t)d v, (111.5) £(£,t) = mvvf(£,v,t)d3v. Obviously N, g, and glare respectively the mean particle density, current, and pressure. Note that 111.3 is just the trace of the expression for a, 111.5. If we now take the velocity integral of the Boltzmann equation 111.1, 38 we arrive at the continuity Eq. 111.4. Similarly multi- plying the Boltzmann equations by the velocity v and integrating we arrive at the hydrodynamic Eq. 111.2. In performing the integrals we have assumed that the particle number and momentum.or-current are each conserved under collisions so that the collision terms vanish. We have also assumed that f is well behaved in velocity space and its surface integrals vanish. Higher moment equations are formed by integrating.the Boltzmann equation with additional velocity factors; e.g. the next moment equation gives the equation of motion of the pressure tensor 3 in terms of the heat flow tensor 3, etc.. .Each higher moment recovers more information about the system that is completely contained in f.. This infinite set of.coup1ed equations must be truncated and.some approximation given to the last term. Because the macroscopic approach.excludes certain detailed information such as the effect of collisions due to other mechanisms, e.g. scattering by lattice, we will use the microscopic approach. 2. .Calculation of the Distribution Function Let us consider a homogeneous, isotropic, and un- bounded gas of charged particles,.whose net-charge is zero. This gas.may contain different species of charged particles; each species being characterized by a set of parameters including mass, charge, temperature, Fermi 39 energy, etc.. 1n.addition to any external.force fields, E in 111.1 contains the interaction between all the charged particles, while the.collision term contains all other scattering mechanisms such as impurities, phonons, etc.. Suppose the system is disturbed from equilibrium such that the force field is harmonic in space and time, i.e. propor- tional to exp(ik-r - iwt). Or, to put it in another equally valid way, since any disturbance in an unbounded steady state system can be Fourier decomposed into har- monic components, we choose one. Then the differential operators in space and time.become algebraic: §?.= -iw , (Z.= 15 . (111.6) With no static external electric or magnetic.fields the force field is §,= -e(§ + %.g x g) (111.7) Although the following calculations will be made for electrons, the results are quite general and can.be applied to any "free".charged.particles by changing.the para- meters.. 111.7 may be rewritten in terms of the B field only, )1‘.E (111.8) 40 by the use of Maxwellls equation - - .1 Q. vrxg- Gag, (111.9) where l in 111.8 represents the unit identity.tensor. We will treat the collision term by the relaxation time ansatz of t I -Y[f(£’1’t) - f3(£919t)] 9 (111.10) coll. where y is the collision frequency, f is the distribution function before scattering, and f5 is the distribution function after scattering, i.e. the local equilibrium function. The total distribution function for the.e1ec- trons is 3N0 r2m 3’2 [ [EF'EU'I fo = -—————' —— l + exp _FT_ . (111.11) 811er [hz] where No is the average density, a the energy per particle, 5F the Fermi energy, and RT the thermal energy. Because the Fermi energy is.a function of density, at T = 0 being 0 _ h .2 an .61: - '2? (311 N) , . (111.12) and because the density.varies in space and time, N(_r_,t) = N0 + Nlexp(ik°r - iwt) (111.13) 41 the local equilibrium distribution also varies. Assuming the density variations are small compared with the equili- brium value (No >> N1), we can make a linear expansion of fS about £0, f = £0 + [is-3'] [gfi-F] N1(£,t). (111.14) From now on quantities subscripted with.l.are small com- pared to the equilibrium value (subscript O) and their spaceetime dependence is exp(ik-r - iwt), which.will not be written explicitly. Before proceeding any further something.must be said about the temperature of the electrons.and their equil- ibrium distribution. In general 111.11.is-difficult to handle except in the limit.of very low.or very high temp- eratures. But.because.the.Fermi.energy of electrons at room temperature is so much greaterthan the thermal energy, 111.11 may be approximated to be at-a temperature of absolute zero. On the other hand,charged carriers in a semiconductor or gas plasma have high temperatures and 111.11 may be approximated by the Boltzmann-distribution. Because we are interested in a low temperature solid state plasma we shall use the zero temperature approxi- mation. Thus 111.14 may be rewritten as 0 . 8f 2 8F = I- 4— ——I—- I 42 and 111.1.becomes 6 , -_ e -, 11$ 12- , _ E f + XVf " fil- E1 [1.11—- + (l-T)L] Vf - -Y[f'fs](111.16) If we assume 111.16 has a solution linear in harmonic quantities. (111.17) 1+: A [’1 I< fl V H H') o + H"; H (D N 'U A He I7? IN I He 8 ff v we find 0 = éfo 1112.1. ._ _2_ E: 5f. yN. f1 e[XE_]VTTETTE:i 3 0[6€ ]y-iw+ikov (111.18) 3. The Conductiviterensor The conductivity tensor may be best described as the linear response function of a system relating the com- ponents of an electric field to the components of a cur- rent density produced-by this field. The.most general linear relation possible-between.two.vector-quantities that vary in space and time is £(r,t) = Idar'det'g(r,t,r',t')°§(r',t'), (111.19) i.e. the current density g at the position 3 and time t depends on the electric field B at all points in space and all times through some tensorial relation g. But for 43 a homogeneous causally related system Q is a function of relative position and time only,and its Fourier eXpansion is (111.20) Since we are interested in fields with harmonic space time dependence, §1(r',t') = §(k,w)exp(ik°r' - iwt') (111.21) 111.19 may be reduced to 1113.0 = g1l<_.w)°§1(1.t) (III-22) by the use of the orthogonality property of the exponen- tial function. The current density gand the distribution function f are related by the moment equation __ 3 i —.§qijd Vixifi, (111.23) where qi is the charge and vi.is the velocity of the ith species of charged particles. The current for the elec- trons whose distribution function we have.just.calcu- lated is 44 J (£:t) = -6Jd3vxf1(1.t) (111.24) Only f1 contributes to the current since f0 is.symmetric in v. Because fl is a function of E1 and N1, 111.24 has two parts: The conductivity current which is proportional to E1; and the diffusion current, which is due to the variation of the local equilibrium density and.is pro- portional to N1. g1(£,t) = g'(k,w)°§1 — ew§(k,w)N1 (111.25) where g'(k,w) = e2[d3v[-%§£];TI%:¥ETV (111.26) 3 = [davé 3;. %[-§:o]y-iw%i£'l (111.27) To reduce 111.25 to the form 111.22 we define the tensor 3 as 3(149) = 3(§.w)£ . (111.28) so that the equation of continuity 1°11 + ewN1 = 0 (111.29) 45 may be rewritten as 3’11 = -ewBN1- (111.30) Substituting 111.30 into 111.25, the generalized conduc- tivity tensor becomes 1 5115.4) = [,1 .- gcmm)’ 9315.4). (111.31) where 5-1 represents the inverse of tensor A. Note, if more than one charged species is present 3 and 2' are ' replaced by £31 and 121. Evaluation of g' and 3. .At absolute zero.the Fermi-Dirac distribution function 111.11 becomes a step function in energy or velocity which permits us to reduce velocity integrations to solid angle integrations by the.identity Jd3vG(X)['%§£] = Z;i§£; JdQG(vF), (111.32) P Since 111.32 is a good approximation for.temperatures less than the Fermi temperature we apply it to our metal- lic plasma and obtain 2 w _ 3 1 2' --z% IE'VTTB l . (111.33) VF 1 46 The integrals I'-] = I 11.31“ (111.35) 1+1a-§ and - - “d9 y_ - (151:1: , (111.36) where r is a unit radial vector in spherical coordinates and I” III 1: < (111.37) are evaluated in Appendix A. So far in this chapter, k_has been a general vector, but now we will choose our coordinate system byrequiring the real part of k, i.e. the direction of phase propaga- tion, to be in the positive 2 direction. Since, as was demonstrated in Chapter 11, for inhomogeneous waves the imaginary part of R has a different direction, we choose the x direction so that the most general k lies in the x-z plane. In other words k_and a possess only x and 2 components. In this coordinate system we find.(Appendix A) for A homogeneous waves with a = azg, IIQ where 3w Ot - 8n y-iw 3w2 2 n y-iw and R has only the z-z where a represents the and for the homogeneous-wave is just a Defining ofi as 47 Gt 0 0 = 0 0t 0 0 O oi 2 -£— [1+3 arctan a - l] a2 a 1_ 1 _ arctan a 2 a in component = 1_. 1 _ arctan a 1w a 9 scalar magnitude of a; 20 111.38 takes the simple form (111. (III (III (III (III (III 38) .39) .40) .41) .42) .43) 48 0t 0 0 g = 0 0t 0 (111.44) 0 0 02 The tensor 3 for the inhomogeneous case, as evaluated in Appendix A, may be put in the following form: I7? [w R = [1 - EIE£§E_E] (111.45) - 0 1“) 8 Similarly, the non-zero components of g' may be written as k 2 X 1 xx 0t + E-E on 0 II (111.46) where 02' and 0t are given by 111.39 and 111.40 and 2 3 “p 1 3+a ' = ' - = —I- _ '- ou o£ 0t 86 V715 a2 [3 a arctan a] (111.47) After some simple but tedious algebra, 111.45 and 111.46 may be combined to give the components of g Oyy - 0t k2 (111.48) = x 022 02 cp, k 0 = o = kxkz 0 x2 zx E55 0 ’ where 0t and 02 are given by 111.39 and 111.43 and cp = ou' + Rog (111.49) so that 02 = OH + ot (111.50) 4. Dispersion Relations A dispersion relation, in the sense that we employ the term, gives the wave vector k, which in general may be complex, as a function of the frequency m, which we assume to be real. Because of our sign convention, a positive imaginary part of k corresponds to a wave growing in space, while a negative value corresponds to a wave attenuating in space. 50 The dispersion relation is derived by requiring the fields of the wave to satisfy Maxwell's equations -11 -léEl VXEI“CJ3_ C 1'. (111.51) _ _l 5&1 ‘7X E1 - c 8? Assuming g and B are related by 111.22, we solve for g ((C/leg-Ll. - (C/w)21<_ 5 - ;(l<_.w)]°§1 = 0 (111.52) where 4fli 3 (111.53) is the dielectric tensor. For a non-trivial solution to 111.52 we demand that the secular equation ||(C/w)2£f§l - (c/w)2£ 5 - gll = 0 (111.54) be satisfied, which gives us the desired dispersion rela- tions. Using the conductivity tensor we have just calcu- lated and 111.53 we may write down the components of the dielectric tensor for an inhomogeneous wave: k2 _ x EXX _ at + k2 EU Syy = at (111.55) Exz Ezx k2 9 k2 e = e - x e , 22 2. kg 11 where n wz. 1+a? = _ . 123 3 J - at 1 Z w(w+iy;) 23? aj arctan aj 1 (111.56) J n 8;) 3 arctan aJ Z me+1y.) a7? 1 - a. 2 =1-1 3 J .441 (11157) 2 n y. arctan a. ' 1 + ii —l 1 - J ] . w a. J J cu = 62 - st . (111.58) At this point we have generalized our results to an n- component plasma and that is the reason for the summa- tion in above expressions. For homogeneous waves, i.e. for kx = 0, the secular equation yields three solutions; two degenerate diSper- sion relations 52 (c/w)2_lgt°kt = et(§t,w) (111.59) associated with electric fields polarized in the x and y direction; i.e. transverse waves, and the dispersion re- lation €£(££,w) = 0 (111.60) associated with the electric field in the z-direction; i.e. a longitudinal wave. These results are well known, but it should be pointed out that usually no distinction is made between the longitudinal dielectric function a, and the transverse dielectric function at. For inhomogeneous waves, however, we would expect the dispersion relation for y polarized waves to be 111.59, but the x and z polarized waves to be mixed. Indeed the y-polarized solution factors out and we are left with [(6/6)2k§ - EXX][(c/6)Zk; - 622] (111.61) -[(c/w)2kxkz + exz][(c/w)2kzkx + 62x] = 0. But-the above equation may be simplified with 111.58 into [(C/w)2k2 - at] a, = o , (111.62) 53 which shows the remaining two waves to be independent with "transverse" and."longitudinal" like dispersion relations. But they are not transverse and longitudinally polarized waves as in the homogeneous case. To see how the fields are related to the wave vectors let us solve 111.52 explicitly for the fields: II CD [(C/w)2k: - ExxJEx - [Cc/w)2kxkz + EszEz (111.63) ll 0 [(c/w)2kzkx + an Ex - [(6/6)21> VF, the absolute value of a is always less than 1 for the em wave. .Thus we may approximate at by expanding 111.56 as a power series in a. Since arctan a = Z (-l) fHTT_ (111.66) we find (-1)n332n 2 w - = - 1 I et 1 E w1w+iyi 1 + % (2n+3)(2n+1) (111°67) Or to zero and first order in a2 we have 55 6t = 1 ‘ WEE-{7T (111.68) wz k-hv2 .- _ l Z;__§;. St - 1 EXPO-TEE? 1 + 5 . (111.69) (Wiv)2 For the sake of simplicity we wrote 111.68 and 111.69 for a one component plasma, but the results may be easily generalized to a multi—component plasma. Solving 111.69 explicitly for kt,we have (02 . 1 _ [EEtJ‘ = “(9+1Y5 , . (111.70) w + 1 VF 2mm ‘ 1 '5' 2;" TLM 3 Since (VF/C)2 is about 10.5 or less, Eq. 111.70 indicates that the commonly used expression 111.68, for ET , is good for frequencies w/wp > 10-2. We next examine the behavior of the irrotational polarization wave in a one component plasma. For fre- quencies near mp, |a| < 1 provided y < w, and $2, expanded to first order in a2, is '2 2 2 .w [1 + 3 kLVF 2] = 1 - 919*115 kivng (“+1Y5 . (111.71) - -1 . 1 1w 3iw+1yi‘ Note, that to zero order in a2, a, and e are equal, but I: because this approximation neglects all except the infinite wavelength dispersion of the irrotational, for our problem we cannot equate 82’ 56 with €t° For a collisionless plasma (y = 0), the dispersion relation becomes [slur (0 As for the em wave, k2 w w P 2 2 a2.) ML] 4] (111.72) VF w P is primarily imaginary for and vanishes near mp The pri- mary difference is that k2 is greater than kt by approx- imately %— or inversely the em wavelengths are always larger F than the irrotational wavelength by the factor %—. This F fact, we shall later see, has important consequences. IV. RESULTS 1. Plasma Slab of Infinite Thickness Taking the dispersion relations calculated in the last chapter,we shall evaluate the expressions for transmission and reflection of em waves by a plasma. Since the size of the effect due to the irrotationa1.p1asma wave depends on the ratios of y to a and B (Eqs. 11.16 and 11.24) we shall consider.approximate.values of these quantities and determine if the.effect is measurable. Neglecting the collision frequency in 111.68 and 111.72 we find /cos2 6 - x:2 (1V.1) ID ll Y = /3/5 sin2 e[:§], x2 x - l where x = w/wp, e is the angle.of incidence, and the first medium is chosen to be vacuum, so so = 1. Since the fraction of the energy flowing into the irrotational xvave (Eq. 11.29) has a maximum when 8 = [Sgt] vanishes, ‘ n the largest effect of the irrotational wave should occur 1mhen the em wave is refracted into a surface wave along 57 58 the interface. This condition is achieved in IV.1 when cos 6 = x‘1 = (mp/w), (1v.2) so that a = Sin2 6 cos 6 , (1v.3) - /3/5 (VF/C) sin 6 cos3 9. .4 I Since there is no transmitted em wave.the condition for all the energy of the incident.wave to go into the long- itudinal plasma wave.is a = y,or tan a sec 6 /3/5 (VF/C) (IV.4) w/wp sec 6 For typical solid state plasmas with a Fermi velocity of about 108cm/sec,this critical angle is only a few min- utes, i.e. almost norma1.incidence, and.the.frequency exceeds the plasma.frequency by.a few tenths of a per- cent. But.because the usual Brewster angle, corres- ponding to a = B, is also a few minutes near the plasma frequency, the dip in the reflection due to the longi- tudinal plasma wave would be.indistinguishable from the 59 dip due to the usual Brewster condition. 2.. Plasma Slabs of Finite.Thickness Although the experimental conditions for observing irrotational.polarization.waves in the.ref1ection spec- trum of.a very thick plasma slab appear difficult to rea- lize, they may be.met for thin slabs. Since the problem lies with the fact.that.at the frequency and.ang1e at which the polarization.wave.has a.measurable.effect, the reflec- tion changes drastically.because.the plasma becomes trans- parent.to em waves, let us.consider-p1asma.slabs or films thin enough to be transparent.to.these em.waves. In other words,-we can-exploit the fact that the wavelengths of the em waves.in.plasmas exceed the wavelengths of the polarization waves.by.the.factor.c/VF, by choosing plasma slabs thin compared to the wavelength of the em-wave; .ReCngt)d << n, but.thick compared to the wavelength of the polarization.wave; Re(n-k1)d >.n. Such a slab would be almost entirely-transparent.to em waves per- mitting the effects of the.irrotational waves to be observable. Numerical Results.. Defining the transmittance, T, and reflectance, R, in the usual way; as the fraction of energy transmitted and reflected.by.the.entire slab: g . s, T "' Egg, R no , (IV.5) 60 we calculate them by taking the absolute value squared of the expressions 11.38: = mm |2 T 0 WI2 IMI2 (IV.6) Nt’ Nr’ and M are_given.by 11.39, and-for a plasma slab bounded by.a vacuum on both-sides they simplify to: 2 II t 4a[(1 - ¢§)¢,v + (1 - ¢§)¢t8] Z I r - (1 - 0.02)2AD . (0t - ¢,)ZCB (1v 7) I: n (1 '-' ¢t¢3la) [D2 ' A2¢t¢pl ' l - (0t - 0,)[02¢t - C20,] These expressions have been computed numerically for fre- quencies between 0.6 mp and 1.5 wp in steps of 0.005 mp, for three slab thicknesses, and four angles of incidence. The values of slab thickness chosen were d/Ap . 0.0305, 0.0915, and 0.1525, where AP is the wave- length of an em wave in vacuum at the plasma.frequency and is defined by A = ———-. (IV.8) P Angles of incidence of 10, 30, 60, and 80.degrees were 61 used in the computation. The exact, collision dependent, dispersion relations (Eqs. 111.56 through 111.60) were solved numerically for a one component plasma described by a.Fermi.velocity VF = 1.4 x 108cm/sec. and a constant collision frequency equal to lO'ZwPprr= 100). The results were plotted directly by the.computer,.along with the-absorptance A, defined as .A=1-R-T, . (1v.9) and are presented in Figs. 4 through 10. TRANSMITTANCE Fig. l. 0. 0. 0. 0 4a. 0 9 .8 7 6 .5 .4 .0 0. 62 ~ [VF = 1.4x108cm/sec wpt = 100 ,_ e=10° AP = ch/w d1 = 0.03051 1 d2 = 0.09151p d3 = 0.15251 P 1.0 1.1 1.2 1.3 1.4 1000 (/p) Transmittance versus frequency for p-polarized radiation incident at an angle of 30 degrees on plasma slabs of thicknesses d/A = 0.0305, 0.0915, 0.1545, where 1 is the vacuum Bavelength at the plasma frequency, A = ch/ . The plasma is described by a Form? velocigg VF = 1.4x108 cm/sec and a collision frequency corresponding to pr=100. 6 0.7 0.8 0.9 Fig. REFLECTANCE 0 4b. 0 63 dence and various thicknesses. .9 - 8 r Infinite (j/thickness _ d1 I L I 1 __ 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1. 0000 (/p) Reflectance versus frequency for 30 degree inci- 4 ABSORPTANCE 64 1.0 0.9 r 0.8 - 0.7 r 0.6 . 0.5 _ 0.4 _ 0.3 , .1, d2 0.2 k \ T d3 0'1 / k \x 0.0 1, i 1;; 1 , , V§~A~--.. 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 (w/wp) 4c. Absorptance versus frequency for 30 degree inci- dence, and various thicknesses. Fig. TRANSMITTANCE O .5 5a. 0 O‘ O 01 0.3 0.1 0.0 65 0. 6 d3 0 .9 d1 1.0 (w/wp) 1 1.1 1. 2 ‘ 1. 3 l. Transmittance versus frequency for 60 degree inci— dence and various thicknesses. Fig. REFLECTANCE 5b. 66 ° 0 1 J n L A l a 0.6 0.7 0.8 0.9 1.0 1.1 1.2 ‘ 1.3 (w/wp) Reflectance versus frequency for 60 degree inci- dence and various thicknesses. .4 Fig. ABSORPTANCE 5c. 67 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1. (w/wp) Absorptance versus frequency for 60 degree inci- dence and various thicknesses. Fig. TRANSMITTANCE 6a. 68 d2 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 l. (w/wp) Transmittance versus frequency for 80 degree inci- dence and various thicknesses. 4 69 1.0 d3 0.9 d2 0.8 ‘ 0.7 - ‘11 0.6 - [L] L) 2 F5 L20 5 - LL} A LL. LL] “0.4 _ 0.3 g 0.2 _ 0.1 _ 0‘0 4 l l I l n 4* 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 (w/wp) Fig. 6b. Reflectance versus frequency for 60 degree inci- dence and various thicknesses. ABSORPTANCE Fig. 6c. 70 r. P d1 2 d3 1 I __*-..——M“§w 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1. 1000 (/p) Absorptance versus frequency for 80 degree inci- dence and various thicknesses. Fig. TRANSMITTANCE 7a. 71 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 (w/wp) Transmittance versus frequency for slab thickness d = 0.03051p at various angles of incidence. 1. 4 72 800 600 30° REFLECTANCB <3 U'l 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 (w/wp) Fig. 7b. Reflectance versus frequency for slab thickness d = 0.0305).p at various angles of inCidence. 73 1.0 0.9 F 0.8 * 0.7 ' - 0.6 - m D Z 5 9,05- 0!. O U) m “ 0.4 . 30° 0 3 . 10° 600 0.2 _ 80° 0.1_ \ j ‘ J / 0.0 JL - _ A 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 w (w/ p) Fig. 7c. Absorptance versus frequency for slab thickness d = 0.03051? at various angles of incidence. Fig. TRANSMITTANCE 8a. .91 100 74 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1.4 (w/wp) Transmittance versus frequency for slab thickness d = 0.0915).p at various angles of incidence. Fig. REFLECTANCE 8b. 0. Reflectance versus frequency for slab thicknesses d 75 800 60° 6 0.09151 P .8 0.9 1.0 1.1 1.211. (w/wp) at various angles of incidence. .4 76 1.0 0.9 ' 0.8 ’ 0.7 t m 006 b L1 2 :5 n. 0 5 . g; 10° a: 5% 0.4 . 0.3 L 0.2 b 0.1 _ 0.0 0.6 0.7 0.8 0-9 1.0 1.1, 1.2 1.3 1. (w/wp) 8c. Absorptance versus frequency for slab thickness d = 0.0915).p at various angles of incidence. Fig. TRANSMITTANCE 9a. 0 1. 77 0 .5 s \ l .3, ’ l ‘ l L l J l 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 (w/wp) Comparison of the transmittance versus frequency calculated using the Fresnel equations (11.41), dashed curve, and the general equations, solid curve, for a thickness d = 0.0305).p and for 60 degree angle of incidence. .4 REFLECTANCE 78 1.0 0.9 ’ 000 ,. I l J J 0.6 0.7 0.3 0.9 1.0 1.1 1.2 1.3 00 (mp) 9b. Comparison of the reflectance versus frequency calculated using the Fresnel equations (11.41), dashed curve, and the general equations, solid curve, for thickness d 0.0305).p and for 60 degree angle of incidence. Fig. ABSORPTANCE 9c. 79 0.6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 (w/wp) Comparison of the absorptance versus frequency calculated using the Fresnel equations (11.41), dashed curve, and the general equations, solid curve, for thickness d = 0.0305).p and for 60 degree angle of incidence. Fig. TRANSMITTANCE 10a. 80 .6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 1 (w/wp) Comparison of the transmittance versus frequency calculated using the Fresnel equations (11.41), dashed curve, and the general equations, solid curve, for thickness d = 0.09151p and for 60 degree angle of incidence. .4 Fig. REFLECTANCE 10b. 81 I J L L 1 1 I .6 0.7 0.8 0.9 1.0 1.1 1.2 1.3 (w/wp) Comparison of the reflectance versus frequency calculated using the Fresnel equations (11.41), dashed curve and the general equations, solid curve, for thickness d = 0.0915).p and for 60 degree incidence. 1. Fig. 1.0 0.9 0.8 O O‘ ABSORPTANCE O L. O 4:. 10¢. 82 (w/wp) Comparison of the absorptance versus frequency calculated using the Fresnel equation (11.41), dashed curve, and the general equations, solid d = 0.0915).p and for 60 curve, for thickness degree incidence. 1.0 1.1 1.2 1.3 1. 4 V. DISCUSSION AND.CONCLUSION The maxima and.minima structure.in.the.reflectance, transmittance, and.absorptance.spectra appearing in Figs. 4 through 10 arises from spatial resonances of long- itudinal plasma waves.of.finite wavelength propagating in a slab.of.finite.thickness., The source and the condition for the.occurrence of this structure become apparent if we approximate the.equations of.ref1ection.and transmis- sion IV.7 under the.condition that the wavelength of the em wave.is larger than the slab.thickness.. Then 0t = exp (in-ktd) is nearly unity, and Nr 2 [AD - BC|(1 - 0,)2 = ‘4YBC1.' ¢£)2 Nt 2 408(1 - 4,2) (Vol) M = (D. - 42¢, - 32 -.C¢,](1 - ¢,) 4e[a(1 + 0,).+ ycl - ¢,))(1 - ¢,) Neglecting damping, so that the.waves.are homogeneous and a and y (Eqs.-11.16 and 11.24) are real, we find R and T 83 84 (Eqs. 1V.6): R=liL1 ' C05 ”)1 A (v.2) .T.=.a2(1 + cos p) A where A = 02(1 + cos 0) +.y2(l - cos 0) . (v.3) and 1» =-Re(g‘,l_<_£)d (v.4) Clearly, even if y << d, the reflectance (transmittance) will have relative maxima (minima) whenever w = nn; n = l, 3, 5,... (v.5) i.e., whenever the slab thickness equals.an odd number of half wavelengths.of.the.longitudina1.wave. The resonance condition can be.visua1ized.as.a standing polarization wave, with the volume charge.density developed.in the region of the boundary coupling the.incident.em.wave to the polarization wave. 85 Superimposed in these relative maxima (minima) is one large maximum (minimum) due to the em wave being refracted into a surface.wave. This effect increases with angle of incidence as seen in Figs. 7 and 8. It is interesting.to note that our eXpressions for the reflectance and transmittance V.2, reduce to the corres- 25 ponding equations of McAlister.and.Stern» near the plasma frequency. Near mp,.w becomes small so ¢£ = l + 10 k (v.6) c = 1 +'i[ 8] 2nd ’ w n and the expressions for.R.and T become . i 2 R 7a - 170 .an sin2 0 2 = 1 cos 6(1'6) A (v.7) 2 a 2 T 2d - 1yw - 32 2 - A where _ g . 20d sin2 6 A - 25 1 1 cos e(l-e) (V.8) 86 Eqs. V.7 differ from the corresponding expressions of McAlister and Stern (Eqs. (3) and (4) in their paper) by the factor 1 --e 2 (wp/w)2, which approaches unity near the.plasma frequency. Our results indicate that the wavelength of the longitudinal highfrequency plasma wave in a metallic plasmasuch as an alkaline or noble metal may be meas- ured by an.optical.experiment,.provided the metallic foil is quite.thin.. Silver,.for example, whose conduction elec- trons have a Fermi velocity of 1.4 x 108.cm/sec, has a plasma frequency of 5.8 x 1015.secfl,-corresponding to a plasma wavelength AP of 3280 Angstrom units in thickness. For comparison, the screening length for the silVer plasma, AP = vF/wp,is approximately 50 Angstrom units. Thus the spectrum of the thinnest foi1,-which provides the most resolved resonance peaks, may not be applicable since the wavelengths are approaching the limiting screening length. 0n the other hand such an.experiment.may provide informa- tion.concerning-the critical cut off wavelength. Another experimental difficulty may be the collision frequency. Although the value pr = 100 is well within.the value opt = 233 obtained from mobility measurements in silver, these measurements were made in large, pure samples and may not apply to evaporated films. A calculation was also made.of the reflectance and transmittance by.the acoustic wave in a.two component 87 plasma. But because the.phase velocity of.the acoustic wave is much smaller than that of thehighfrequency mode no measurable effects.were obtained. Furthermore, the acoustic waves are strongly Landau damped-even without collisions. .Thus.experiments, such as those.of McWhorter 2 to excite acoustic plasma waves by electro- and May,3 magnetic radiation seem very unlikely. .The situation may be improved by applying static electric fields to the plasma.to amplify.the.acoustic wave.3:5 But as a result of the anisotropy produced.by-such a-field.the irro- tationa1-and divergence-free waves.are.no.longer inde- pendent, so that.the.present.theory would no longer be applicable. Using the method-described in Chapter.11, we have also calculated the.case of longitudinal plasma waves incident on a boundary and emitting em waves. This d15 and our equation for the problem was treated by Fiel ratio of the em wave.electric field to the plasma wave electric field agreed with the corresponding equation in Field's paper. This is.not surprising, since Field also describes the real boundary as having a finite transition region of the order of the screening length and he uses the continuity of the normal component of the electric field for a boundary condition. Our results, however, are more general since we consider a dielectric plasma boundary.and inhomogeneous waves,.which are more 88 realistic for a lossy system such as a plasma. In summary, we.have studied the linear.coupling be- tween longitudinal polarization waves.and.transverse elec- tromagnetic waves introduced.by.the.existence of plane boundaries separating.dielectric media or vacuum from conducting media capable of supporting polarization waves. We have investigated this coupling by extending the usual Fresnel equations to include the effects of irrotational fields. Because.the.theory.was developed in terms of. the plasma dispersion.relations a means has-been suggested for studying experimentally.the wavelength.dependence of plasma waves. We have also shown that the dispersion relations for inhomogeneous waves in.the plasma are still separable into electromagnetic-like and polarization waves. Finally, absorptance, reflectance,.and transmit- tance spectra were numerically calculated and the re- sults indicate that the dispersion relations for plasma waves in-thin metallic.films.may be optically measurable. APPENDIX A. EVALUATION OF I AND K In the spherical.coordinate system, Fig. 11, the integrals I = [1"‘1‘Lfla. (A-l) d9? V = [1713—1 U”) become 2n #1 A A .1 = J',d¢J’ . , ‘1‘?” . (11.3) 0 41'1 + lazu + 1ax/l-u2 cos 4 2n f1 A ' " dur X = [\d0J _ 94' (A.4) O -1 1 + 1azu + 1ax/l-u5 cos ¢ For homogeneous waves, ax = 0 and A.3 and A.4 take on a simple form which is easily evaluated: l+a2 T = T = 2" zarctan a - 1 xx yy a 2 a2 2 z (A.5) ‘ 4 arctan a T = n 1 _ z z and arctan a v = L" [1 - 2] (A6) 2 90 Fig. 11. Coordinate system defining direction of tensor components. 91 all other components being zero. To evaluate A.3 and A.4 for the general inhomogeneous wave case we need the value of the integral n _ dx I - J v + w cos x (A'7) The indefinite integral of A.7 has the following values34 2 _ 2 ‘% . W + V COS X 2 2 (v w ) arccos[v + w cos x > w -l v tan (x/Z) v = w -1 -v cot (x/2) v = -w 1 O - w + + -v (w2_v2) 6 1n v cos x w Sln x w2 > v2 v + w cos x Therefore the integral A.7 is defined as long as v2 is unequal to w2 I = -—--. v2 7‘ w2 (A.8) V ‘W From A.8 we find 20 I do = 20 0 v+w cos ¢ /;T:;2 2n ‘ cosodg, = 21. 1 _ v v+w cos 4; w W 0 - _ 20 2 'cos ¢d¢ _ 21 v2 _ J v+w cos ¢ 7 w2 [ v -w V] (A-9) O , Zn . n Sin ¢ cos ¢d¢. = 0 v+w cos ¢ 0 271 2 Sin d - £_ - “FT? 2 0 v+w cos¢ ' W2 [v v w 1 We now extend the integrals A.9 to include complex v and w and state without proof that A.9 exists as long as the absolute value of U does not vanish, where = 1 + a 2 + Ziazu - (ax2 + a 2)u (A.10) X Z The value of the first three integrals of the form +1 1n = undu _i/U_ can be expressed as 2 arctan a 10: a 93 a 1. = -21—-z- [1 “eta“ 3] (A.11) a2 a Zaz-a2 ZaZ-a2(l+a2) 13 = ——£——§— - z X arctan a a“ as where a2 = 373 = a; + a: (A.12) With A.9 and A.11 the desired integrals may now be eval- uated: a2(l+a2) - 2a2 a2 - 2a2 T = 2n 2 x arctan a - z x XX a5 an a a 2 T = T = 20 x z [ - 3+3 arctan a] X; zx a“ a (A.13) 2 T = £1 lié. arctan a - l YY a2 a Zaz-a2 2a2-a2(1+a2) Tzz = 2n ——5——§—-- z x arctan a a“ a5 T T xy yx yz zy and with the condition H-l #- :4 ll H-b :1 that 94 711' 9) a) I. a [1 - a2 laI7‘1 arctan a a arctan a a (A.14) (A.15) 10. 11. 12. 13. 14. 15. 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