Enemamme PARAMETERS RELATED TO THE HARDNESSOFCARROIS ' Dissertation for the Degree of Ph. D; MECHEGAN STATE UNWERSITY BASSAM AHMED SNOBAR 1973 ’ Mme.-...v..~.._ I ,‘n VJ Ir» ~ . a.» ' La A's '. a .2 hitchgfit ’. 1;”: Ulll‘J'CIf This is to certify that the thesis entitled ENGINEERING PARAMETERS RELATED TO THE HARDNESS 0F CARROTS presented by BASSAM AHMED SNOBAR has been accepted towards fulfillment of the requirements for _Eh.D—degree in AgLLaulLura 1 Engineering or rofess Date 11/6/1973 0-7639 LIBRARY BIND R amomn "AG & SUNS' 300K BIND!" 2mg. '— n .- __ ________._-n m—v-a- W‘“*‘v ‘-'-.-v~' 4"}? . . , . .t v t . ._ .. . .:.I!' \ .Autt . , t, .. 9... ..-.;....~ ‘1 .II“. . Fun . .I it, .. .I Luv. .. . . in . . t . SILK... . ii . . .. n I... Lilli . ....v 4‘- . a 5%.“. '0 . ,4 II» hmly- ' a u . {iii .91. 5H .\7 ‘ . . put I-. a A. v. in ... n tr 1.. Et‘ uterulla. It'll» [slit-v. 1.3th 1 1-..: .- _ . al- klfl...flwauu~fl.l¥k. ‘39.»... .. ....1..... .. . (say. . . .. 1 a a.” .llmlIlL _.v.|nt.l.nta..-..|- ABSTRACT ENGINEERING PARAMETERS RELATED TO THE HARDNESS OF CARROI‘S by Bassam Ahmed Snobar Studies were conducted to indentify and evaluate objectively a textural parameter related to the long-term storage of carrots. Mech- anical and rheological properties were used in this evaluation. An equation was derived, using Hertz's Contact Theory, to calculate the modulus of elasticity of a cylindrical sample canpressed in the radial direction. This equation was used to calculate the tangent modulus of a one-inch diameter carrot sample after it had been subjected to a 0.1- inch displacement in the radial direction. Relaxation tests were also conducted to study the relaxation behavior of cylindrical samples as related to the long term storage of carrots. The tangent modulus varied significantly as the moisture content in an outer ring of the carrot decreased. The tangent modulus decreased fran 869 psi to 27 psi as the moisture content decreased fran 86.6 percent to 72.5 percent (wet basis). Similar variations were observed for the coefficients C1 in the relaxation equations 3 .. F(t) = 2 c1 e01t used to fit the relaxation data (generalized Maxwell Model). No sig- nificant pattern was observed for the al. The Texture Profile Analysis procedure was applied to carrot samples using an axial compression load. No significant changes were detected even though the physical appearance of the carrots changed significantly. This fact was accounted fer by the fact that the center core of a carrot is stronger than the outer ring of material and thus biased the testing procedure. Approved aj r Pr 5 I W 8 A m Department Chairman ENGINEERING PARAMETERS RELATED TO THE HARDNESS OF CARROTS by Bassam Ahmed Snobar A DISSERTATION submitted to Michigan State University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Department of Agricultural Engineering 1973 "-5 ACKNOWIEDGEMENTS The author wishes to express his sincere gratitude to Dr. L. J . Segerlind (Agricultural Engineering), whose guidance, and encourage- ment were invaluable. Special sincere gratitude to Professor C. M. Hansen (Agricultural Engineering) for his encouragement and his providing the assistantship. The assistance from Dr. J. S. Frame (Mathematics) in deriving the mathematical equation and serving as guidance committee member is also acknowledged. Equally, appreciations are also extended to Dr. D. R. Heldman (Agricultural Engineering), who also served as guidance comnittee mem- ber for developing the doctoral program and to Dr. G. E. Mase GMetallury, ZMechanics and Material Science) for his assistance in the theoretical development of the thesis. The author wishes to express his gratitude to Dr. B. A. Stout, Chainman of the Agricultural Engineering Department, fer his approving the assistantship. The author dedicates this work to his father, Ahmed M. Snobar, his mother, Mrs. Yussra Nabhaan, and to his family. Their foresight, en- couragement and personal sacrifice inspired him to undertake a career in agricultural engineering. ii II. III. VI. VII. TABLE OF CONTENTS INTRODUCTION AND OBJECTIVES REVIEW OF LITERATURE 2.1 Methods of texture evaluation 2.2 Rheological Models 2.3 Hertz Contact Problem PRELIMINARY STUDIES THEORY 4.1 Derivation of an equation to determine modulus of elasticity of a cylindrical specimen compressed 4.2 Fbppl's equation 4.3 Relaxation test EXPERIMENTAL INVESTIGATION 5.1 Equipment 5.2 Experimental procedure RESULTS AND DISCUSSION 6.1 Accuracy of the derived equation 6.2 Poisson's ratio 6.3 Deformation test 6.4 Relaxation tests CONCLUSIONS AND RECOMMENDATIONS 7.1 Conclusions 7.2 Recommendations APPENDIX REFERENCES iii 16 20 23 28 30 41 42 45 45 49 55 SS 56 58 59 68 69 71 88 Table Table Table Table Table Table Table Table Table LIST OF TABLES Standard hardness scale (Szczesniak et a1. 1963). 8 Procedure for evaluating texture (Brandt et a1. 1963). 10 Numerical values of coefficients for various commodities. 10 Modulus of elasticity for the center core and the outer ring of six fresh carrot samples. 24 Moisture content of fresh carrots and of carrots stored under different conditions and time periods. 24 Hardness parameter measurements using the TPA method of axial deformation. The hardness is measured from force—deformation curves produced upon twice caupressing cylindrical samples of carrots previously stored in per- forated plastic bags at 52°F and 95% Relative Humidity for three weeks then removed fran the bags prior to testing and stored in a roan at 70°F and 6095 Relative Humidity for 24 hours. 27 Summary of calculated values of E for different potato specimen sizes and deformation using: 2 . 2 E1=0.955m,E2=1.91Pz , E3=§ii L2 D where A is cross sectional area. 57 Poisson's ratio, v, measurenents for fresh carrots and for carrots stored in a roan at 70°F and 60% relative humidity for 24 hours. 58 Values of moisture content, modulus of elasticity as calculated from the derived equation, peak force as the selected experimental curves indicated, and the relaxation coefficients and exponential as calculated from the assumed generalized Maxwell Model 60 iv Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure 9. 10. 11. 12. 13. 14. 15. LIST OF FIGURES Correlation between the panel and the texturoneter on the hardness scale (Szczesniak et a1. 1963). Direct trace (heavy line) of force-distance curve obtained for a G. F. Texture Profile on a cylinder of pear tissue in the Instron machine. The test consists of two complete compression-decompression cycles. (Bourne, 1968a) Compression device used for compressing carrots. Part A is attached to the stationary crosshead of the Instron. Part B is attached to the moving cross-head. Space C is where the carrots are placed to be compressed (Howard and Heinz, 1970) . Typical compression force-distance curve obtained for carrots. -(a) Load, with crosshead moving. - (b) Distance proportional to the change in diameter of the carrot compressed under a 2.5 pomds load (Howard and Heinz, 1970) . Kelvin and Maxwell models showing creep and stress relaxation characterisitics (Sharma, 1964). Typical force-deformation curve for TPA parameters test. Cylindrical sample before compression. Cylindrical sample after compression. Semi-ellipsoid pressure distribution Pressure distribution over the surface of contact. Area of contact. One-feurth the area of contact divided into two triangles. Generalized Maxwell model. Graphical representation of equation [18] . Sampler, (A) is corer and (B) is Base. 12 15 15 18 26 32 32 33 33 37 37 44 44 46 Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure Figure 16. 17. 18. 19. 20. 21. 22. 23. 24. 25. 26. 27. 28. 29. 30. 31. Trimmer, (C) is holding jug (D) is two—bladed knife. Die to be used in measuring the Poisson's Ratio, (B) is base, (E) is sample holding die, and (F) is spacer. Corer with 7/8" outside diameter to be used to separate 1/8" thick outer ring from the 1" diameter sample. Aminco unit with chamber to store carrots at given temperature and relative humidity. Instron.Universa1IMachine. Loading for the unrestrained test. Loading for the restrain test. Force-deformation curves for a cylindrical sample of carrots with one-inch in diameter and one-inch long. Sample loading, in the radial direction or parallel to the longitudinal axis. Typical curve for deformation and relaxation tests. Effect of moisture content on the applied radial ferce in deformation test . Mbdulus of elasticity of carrots as calculated by the derived equation. Effect of moisture content on the first coefficient in relaxation test. Effect of moisture content on the second coefficient in relaxation test. Effect omeoisture content on the third coefficient in relaxation test. Experimental and theoretical results for relaxation test at different moisture content. Table (A-9) vi 46 47 47 48 48 50 50 51 52 53 62 63 64 65 66 67 ‘ 6”, L.:’ on I. INTRODUCTION.AND OBJECTIVES The carrot (Daucas carota) is a popular vegetable and is increasing in importance, owing to the fact that its value in the diet is better understood today than in past years. It is rich in carotine, a precursor of vitamin A, and contains appreciable quantities of thiamine and ribo- flavin. The carrot also has a high sugar content. Concern has risen among growers and processors relative to the changes in the texture of carrots particularly during storage. In order to identify these changes, the texture parameters of carrots must be defined and objectively measurable. Sensory, or subjective, analysis has been used to measure the texture of carrots, but this requires a trained taste panel which is not readily available to many investigators. Lord Kelvin (1891) said, "I often say that when you can measure what you are speaking about and express it in numbers you know something about it, but when you cannot measure it, when you cannot express it in numbers, your knowledge is of a meager and unsatisfactory kind, it may be the beginning of knowledge , but you have scarcely, in your thoughts , advanced to the stage of science, whatever the matter may be." There is a very limited mnnber of reports in the literature related to the objective evaluation of the texture of carrots. An objective procedure is needed in order to bring consistency to the investigation of the effects of storage time on the texture characteristics of carrots. 2 The specific objectives of this investigation are: 1. To define the important textural parameters related to the long term storage of carrots. 2. To investigate methods of objectively measuring the textural parameter hardness. 3. To investigate the relationship between mechanical properties and moisture content . II. REVIEW OF LITERATURE 2.1 Methods of texture evaluation Texture is one of the three main attributes of foods that cause pleasure in eating; the other two being flavor, and appearance. There are many definitions for texture. Reidy (1970) reported a dictionary definition of texture as "an identifying quality; the disposition or manner of union of the particles of a body or substance". The Institute of Food Technologists offered another definition for tex- ture of food (Kramer, 1959) as: "The mingled experience deriving from the sensation of the skin in the mouth after ingestion of a food or beverage. It relates to density, viscosity; surface tension and other physical properties of the material being sampled". A possible defini- tion of texture in carrots may be stated as: "Texture of fresh carrots is the feel of hardness or crispness of the tissue in the mouth". The present methods for evaluation of textural characteristics are classified into: 1. Subjective or sensory evaluation. 2. Objective or instrumental measurements. Subjective estimations of the textural quality of foods have been per- formed since mankind began eating food and they continue to this day. This method of evaluation depends on human senses. Due to the fact that hunan senses are subject to the influence of various factors which lead to error, scientists began the search for objective or instrumental methods of texture measurements. 4 Scott Blair (1958) classified objective methods of texture measurement under the headings: fundamentz-Il, empirical and imitative. Szczesniak (1966) further defined Scott Blair's classification system as follows: fundamental methods measure the rheological properties, such as elastic modulus and viscosity, and relate the nature of the pro- duct to two basic rheological prototypes; a dashpot for a Newtonian liquid and a metal spring for a Hookean solid. The springs represent elastic moduli. The dashpots represent viscosities. Empirical tests measure characteristics related to textural quality using penetration force test, resistance to compression force test, and shearing force test. Imitative tests are performed under conditions simulating those to which the material is subjected in practice. Bourne (1966a) classified the methods for objectively measuring the textural properties of food under the headings: force-measuring, distance-measuring, time-measuring, energy-measuring, ratio-measuring, multiple measuring, and multiple-variable instruments. The first simple instruments used to objectively assess food tex- ture came with the advent of scientific research into food quality. An examination of the literature of food texture measurement shows that these simple mechanical devices generally compressed, sheared or punc- tured the food in some way. Experimental methods for measuring food texture date back at least to 1905, when Hankoczy in Hungary designed an apparatus for measuring the strength of gluten and in 1907 Lehmann described two instruments for testing the tenderness of meat. Morris (1917) constructed a simple de- vice for measuring the resistance of fruits to penetration. In 1925, Magness and Taylor developed the Magness-Taylor fruit pressure tester. This instrument which is still widely used, consists of a plunger with 5 either a S/l6-inch or 7/16-inch diameter tip attached to a calibrated spring. The round tip is pressed into the fruit to a depth of 5/16-inch, and the penetrating force is read on the scale. The skin is removed from some fruits before the measurement is made. Kramer et a1. (1951) and Decker et a1. (1957) developed the shear press which is one of the popular instruments for measuring textural qualities of both fresh and processed fruits and vegetables. Kattan (1957) described an instrument for measuring firmness of tomatoes based upon compression of the fruit by a concentric chain which encircled the fruit. Drake (1962) described an apparatus for automatic recording of mech- anical resonance curves for test specimens of foodstuffs with the approx- imate size of 6x12x50 mm. The simple evaluation procedure described gave infbrmation on the modulus of elasticity (divided by the density) and the degree of dampening. Schomer et a1. (1963) developed an instrument called the "mechanical thumb" which operates on a principle similar to the Magness-Taylor tester. However, their test is nondestructive in that the fruit can.be evaluated with the skin intact, and the depth of indentation (0.05 inch) causes no significant damage to the carmodity. Parker et a1. (1966) developed a simple, portable, inexpensive micrometer type device for evaluating cherry firmness. Bourne (1965) evaluated the perfbrmance of pressure testers by making punch tests on apples with pressure tips mounted in a universal testing machine. His study showed that the yield point is reached when the pressure tip begins to penetrate the fruit tissue. With the present realization of the importance of texture in con- sumer acceptance, an.increasing amount of attention is being paid to 6 correlating experimental measurements with sensory methods of texture evaluation. Friedman et a1. (1963) studies the correlation between instrumental values using texturometer and subjective evaluation by a trained texture profile panel. This study was applied to measurement of the mechanical textural parameters: hardness, cohesiveness, viscosity, elasticity, adhesiveness, brittleness, chewiness, and gumminess. This study gave good correlation between objectively determined values and f“‘“‘ subjective evaluation. ~ Szczesniak et a1. (1963) developed a standard rating scale for mech- anical parameters of texture and correlation between the Objective and the sensory methods of texture evaluation. Standard rating scales of hardness, brittleness, chewiness, gumminess, viscosity, and adhesiveness were established for quantitative evaluation of food texture. Hard- ness is judged organoleptically as the ferce required to penetrate a substance with molar teeth. The evaluation was restricted to solids and some semisolids because human perception of hardness is limited to samples that can be confined between the teeth. In their study, Szczesniak et a1. avoided fresh fruits and vegetables whose texture varies greatly with variety, degree of maturity, and other factors, and items that required cooking, baking, etc. Table 1 shows the nine points which were selected to represent the scale of hardness. Correlation was very good between taste panel and objective evaluation on the hardness scale (Fig. l). NUmerous methods of objectively measuring texture of agricultural products have been developed, adapted, or studied by many scientists. Szczesniak et a1. (1963) developed 3 Texture Profile Analysis (TPA) technique by which textural parameters were derived from ferce vs. dis- tance curves plotted on the General Food Texturometer. The (TPA) parameters are: hardness, brittleness, chewiness, gumminess, viscosity, cohesiveness, elasticity, and adhesiveness. Brandt et al. (1963) developed a texture profile method that uses the A.D. Little flavor profile method as a model. They defined tex- tural profile as the organoleptic analysis of the texture complex of a food in terms of its mechanical, geometrical, fat, and moisture characteristics, the degree of each present, and the order in which they 'r‘“ appear from first bite through complete mastication. The procedure they _I followed to evaluate texture was mechanical, and geometrical evaluation. The mechanical parameters were evaluated with standard rating scales developed by (Szczesniak et a1. , 1963). The geometrical characteristics of texture were related to the size, shape, and arrangement of particles within a food. Table 2 shows the procedure used in evaluating the different textural characteristics with respect to their appearance. Destructive and nondestructive techniques were developed to measure the texture of foods. Mohsenin et a1. (1965) have suggested a "non- destructive" technique for evaluating firmness of apples based upon the appearance of a "yield point" within the fruit. Bourne (1966b) designed a study to separate and measure the com- pression components (proportional to area) and the shear components (proportional to perimeter) of a simple puncture test. His puncture test measured the force required to push different types of punches into a food product. The test is characterized by: a) using a force-measuring instrument; b) penetration of the punch into the food; and c) a penetra- tion distance usually held constant. Bourne used two sets of punches (one with a constant area and a variable perimeter, and the other with a constant perimeter and a variable area) to measure the compression and shear components in representative foods. The puncture force was Tab_1_e_ll_Standard_hardness_sca_.16 szczesniak et a1 . 1963) . Panel Brand or Sample rating Product type Manufacturer size Temp. 1 Cream cheese Philadelphia Kraft Foods V." 45-SS°F 2 Egg white hardtooked ..... V." tip room 5 min 3 Frankfurters large, uncooked, Mogen David V;" SO—65'F skinless Kosher Meat Products Corp. 4 Cheese yellow, American, Kraft Foods V_»" SO—65°F pasteurized process 5 Olives exquisite giant Cresca Co. 1 olive 50—6$°F size, stuffed 6 Peanuts cocktail type in Planters Peanuts 1 nut room vacuum tin 7 Carrots uncooked, fresh ...... %" room 8 Peanut brittle candy part Kraft Foods room 9 Rock candy ..... Dryden 8; Palmer ...... room 300 ‘— HARDNESS SCALE m L'. z 3' K 200 - u .— u 2 o a: 3 .— X m .— IOO — l l l l l l l O o 2 4 6 SENSORY RATING Fig. 1. Correlation between the panel and the texturometer on the hardness scale (Szczesniak et a1. 1963). f"" 9 expressed by the equation F = KS P + KC A + C, where Ks’ Kc’ and C are constants, P is the perimeter of the punch, and A is the area of the punch. KS represents the shear coefficient and KC the compression coefficient of the food being tested. Bourne tested the validity of the equation postulated above and found that the experimental data obtained fitted the equation. Table 3 gives the numerical values of the coeffi- cients KC, K s’ and C as measured by Bourne for various food commodities. bi Bourne stated that K c and Ks can be a measure of the texture quality .- of foods. Although Bourne did not specify the direction of applying the compression force on the specimen, the work of Howard and Heinz (1970) DIE nw‘ =31n‘h'h.’ "' . - ' i l . vb seems to indicate that the force was perpendicular to the longitudinal axis. Bourne was one of the first people to use the Instron Testing Machine for measuring the properties of food products. In one of his studies (Bourne 1967a) , he used this machine to study the deformation rate of food under constant force. This test was used to determine the softness of the food as means of measuring food quality. Bourne and Mondy (1967b) measured the deformation of: 1) standard cylinders of potato tissue and 2) whole potatoes under a metal punch, using a constant force, as an indication of the fir-mess of whole potatoes. They found that measuring deformation under a punch is pre- ferred over measuring the deformation of a cylinder because a) it can be performed more quickly and easily; b) it is not destructive; c) the correlation with sensory evaluation is slightly improved. Both methods of measuring deformation was found to be a useful objective index of potato firmness. Bourne (1967c) described a model system which closely represents the deformation of a food as it is squeezed in the hand. The model 10 Table 2. Prgcedure_for evaluating texture (Brandt et a1. 1963) EQELUErEEin-d on firsT‘ 131$)" \ Geometrical any, depending upon product structure Marlicatory _ A__(_perceived during chewing) _-_._-_-__/_ Mechanical / . . . hardness Viscosuy brittleness / Mechanical / l \ gumminess chewiness adhesiveness \ Geometrical any, depending upon product structure Residual (changes made during mastication) rate of breakdown type of breakdown moisture absorption 1 mouthcoating Table 3. Numerical values of coefficients for various commodities (Bourne 1966b) Compression Shear coeffi- coefficient K. cient Ks Constant C Commodity (Kg/cm”) (Kg/cm) (Kg) Expanded polystyrene 4.86 0.34 —0.23 High-density polystyrene 13.14 2.20 —2.75 Polyurethane 3.57 0.29 -0.47 Apples (raw, Limbertwig variety) 7.52 0.16 0.03 Apples (raw, Fr. von Berl variety) 6.43 0.07 0.40 Banana (ripe, yellow) 0.43 0.06 —0.06 Creme filled wafers 1.06 0.14 0.64 Carrot (uncooked core tissue) 28.0 -0.03 2.18 Wiener (cold) 1.69 0.004 0.15 Potato (Irish, uncooked) 10.79 0.52 0.60 Rutabaga (uncooked) 29.58 0.86 —0.15 Sweet potato (uncooked) 19.8 0.90 0.35 1% agar gel 0.15 0.005 --0.01 2% agar gel 0.63 0.029 -0.02 3% agar gel 1.21 0.16 —0.33 11 consists of a set of true springs of differing heights and with differing Hooke's constants arranged in parallel. No dashpots were needed in this simple model. The model was restricted to represent the physical response of the food to a single compression. He described a graphical method for measuring the number, size, and Hooke's constants of the springs in the model. The spring model showed that with some foods at least, small compression forces measured differences in softness better than large forces. Bourne (1968a) described a method to determine TPA parameters from force-distance curves produced upon twice compressing a specimen to a fixed deformation on the Instron machine. The curve produced for deriving the TPA parameters for pear parenchyma tissue from Instron force vs. distance is shown in Fig. 2. Brittleness, hardness and elasticity parameters are shown on the curve. Other TPA parameters can be calculated as follows: . A Cohesrveness = 2 AT Gtmminess = Hardness x Cohesiveness Chewiness Gumminess x Elasticity where A1 is the area under the first curve and A2 is the area under the second curve. Ourecky and Bourne (1968) measured the texture of strawberry with an Instron machine. In this test, skin toughness and flesh firmness were determined by obtaining a puncture-force curve on the Instron. Many of the curves consisted of two or three distinct peaks. The first peak was defined as the mecture—force required to penetrate the skin. The second or middle peak was interpreted as the resistance of the flesh 12 FORCE Kg A POW." ' ' W ‘7'" 5") 7i: 0 ‘M W 7.5 DISTANCE mm — Fig. 2. Direct trace (heavy line) of force-distance curve obtained for a G. F. Texture Profile on a cylinder of pear tissue in the Instron machine. The test consists of two complete compressioi-decompression cycles . (Bourne, 1968a) 13 or cortex and vascula cylinder to the penetrating probe. The third peak was defined as the maximum force required to penetrate the fruit. Fruits with a uniform flesh and core area gave no second peak. Bourne and Meyer (1968b) reported studies on an extrusion type of texture-measuring test cell as an attempt to measure the texture of fresh peas. The extrusion cell was mounted on the Instron. The studies included the effect of plunger speed, effect of annulus width, and effect of sample size on the extrusion force. The force required fer this ex- trusion was measured.using green peas as a test material. From.their studies they found that this type of cell showed promise as a routine testing instrument in commercial use because of its simplicity in construction and operation, and.comparative low cost. Bourne (1969) determined the possible relationship between deform- ability, which is related to Young's modulus of elasticity, and the puncture test, which is related to the bioyield point. He measured the deformability and bioyield of eleven different apple varieties. The deformability was measured as the distance the whole apple deformed under a 5/16-inch diameter Magness-Taylor punch between 0.5 kg and 2.5 kg ferce using a universal testing machine. The bioyield point was measured using the same 5/16-inch diameter Magness-Taylor punch in the universal testing machine and measuring the force necessary to reach the bio- yield point (Bourne, 1965). The resulting data showed that there is no apparent correlation between firmness as measured by deformability with the firmness as measured by the bioyield point. Both.measurements are considered to be an index of apple firmness. , Finney (1969) gave a brief description of methods for measuring the texture of meats, dairy products, bakery foods, fresh fruits and vege- tables, and.processed commodities. He also gave new techniques fer ob- 14 jective evaluation of texture of foods. These techniques were based upon analyses of sound, light transmission, and vibration phenomena. Howard and Heinz (1970) stated that there were no reports in the literature on the correlation between objective methods and sensory analysis for determining the texture of carrots. These investigators studied the texture of carrots measuring the compression and shear strength of individual carrots with the Instron Universal Testing Machine. Based upon the values reported for uncooked carrots (Bourne, 1966b) as Kc = 28.0 kg/cmz, KS = -0.03 kg/cm, and C = 2.18 kg, they predicted that the compression measurements would be a better indication of texture than shear measurements. A compression device was used with the Instron to deform a carrot in the radial direction (Fig. 3). A typical compression force—distance move is illustrated in Fig. 4. The compression test was performed on carrots that were purchased locally and stored in plastic bags at 0 - 2°C. The carrots were removed from the bags prior to testing and stored on trays in a conditioning room at 21°C and 65 percent relative humidity for one to twenty- four hours. Carrots were evaluated manually for compressibility and flexibility by five well-trained judges, using a nine-point scale. Compressibility was determined by pressing the middle portion of the carrot with the fingers and evaluating the resis- tance. Flexibility was determined by gently bending the carrot at the middle with both hands. The results showed that compressibility measurements were highly correlated with sensory hardness as judged by the taste panel. Shear measurements had a low correlation with the sensory evaluation. Breene et al. (1972) determined the TPA parameters of cucumbers using Bourne's (1968a) method of force vs. distance curves. A sliced 15 / «PART A X; y.“ DlAMETER e—PART B \ S Fig. 3. Compression device used for compressing carrots. Part A is attached to the stationary crosshead of the Instron. Part B is attached to the moving cross- head. Space C is where the carrots are placed to be compressed (Howard and Heinz, 1970). zs - l 2.0 . i h I (D I ‘2’ l 8 "5 r- l 9.3 0“ I . a 3 l0 .. r -J : I I 05 _ l E b . 1.x. 0 l 2 TIME (MIN) Fig. 4. Typical compression force-distance curve obtained for carrots. -(a) Load, with crosshead moving. -(b) Distance proportional to the change in diameter of the carrot compressed under a 2.5 pounds load Howard and Heinz, 1970). ( 16 specimen of one- inch diameter and one-centimeter long was used for the test. The specimen was placed on the load cell of the Instron machine, and subjected to an axial load. The results of this test indicated variability in texture from one end of a cucumber to the other. 2.2 Rheological Models Rheology is defined as "a science devoted to the study of defor- mation and flow", Mohsenin (1970). Therefore, when the action of forces result in deformation and flow in the material, the mechanical properties will be referred to as rheological pr0perties. The rheological behavior of a material is expressed in terms of the three parameters; force, deformation, and time. Examples of rheological properties are time- dependent stress and strain behavior, creep, stress relaxation, and viscosity. The rheological behavior of linear viscoelastic materials can be explained and interpreted by use of mechanical models consisting of springs and dashpots. Based on experimental evidence, agricultural products are viscoelastic. From the very limited data available in this area, it appears, however, that the viscoelastic behavior is non— linear. Since solutions of non-linear problems are very difficult to obtain, the general procedure has been to make simplifying assumptions and apply the theories of linear viscoelasticity in an attempt to explain the rheological behavior of agricultural products. The two basic mechanical elements used in mechanical models are a spring which obeys Hooke's law and a dashpot with the pr0perties of a Newtonian liquid. The two elementary combinations of these elements, known as the Kelvin Model and Maxwell Model, are used as the rheological models. Maxwell's model is usually used to represent stress relaxation under constant strain. Kelvin's model is usually used to represent 17 creep under constant stress. The two models, the stress relaxation and the creep are illustrated in Fig. 5. Viscoelastic behavior of agricultural products has been studied by many investigators. Barkas (1953) found that the resistance of organic materials to deformation is mainly dependent on the moisture held by molecular forces with the capillary water having little effect. Zoerb (1958) studied small core samples of wheat kernels and found the response to be more non-linear approaching an elastic-plastic be- havior with strain hardening tendencies . Stewart (1964) fomd that an inter-relationship existed between the wheat kernels moisture coitent and their viscoelastic properties. Reidy (1970) in an attempt to find relationships between engineering and texture parameters of pre-cooked freeze-dried beef, developed two models: a) a four-element linear viscoelastic model of Kelvin and Maxwell bodies in series (Model 1); and b) an empirical constitutive equation (Model 2) which contained a probably non-linear term. He con- cluded that: a) Model I successfully predicted relaxation functions of the freeze-dried product; b) Model 2 predicted responses to relaxation, creep, and cyclic tests. This model predicted the texture indices of hardness and Chewiness; c) water activity had an influence on the stress-strain behavior of pre-cooked freeze-dried beef. Resistance to deformation decreased at higher moisture contents; and d) relaxation stresses decreased with increased water activity. Herum et a1. (1973) studied the viscoelastic behavior of soybeans due to temperature and moisture content. They determined the time- dependent uni-axial moduli of intact soybeans by relaxation tests in parallel plate compression. Four temperatures and four levels of 18 Strain e E m Time, t Strain vs. time relationship corresponding to step function stress history. Stress o Time, t Stress vs. time relationship corresponding to step function strain history. Fig. 5. Kelvin and Maxwell models showing creep and stress relaxation characteristics (Sharma, 1964) 19 moisture content were used in the tests in an effort to determine if the techniques of time- temperature and time-moisture shift factors could be applied to describe a relaxation modulus for intact soybeans. Their goal was to identify the individual and joint contributions of temp- erature and moisture content upon the overall response. They concluded that soybeans may be described as thermo-rheologically and hydro- rheologically simple. Bashford (1973a) studied creep and relaxation of meat related to tenderness. In his study Bashford found that rheological parameters obtained from creep and relaxation investigations correlated to taste panel evaluation. He concluded that these parameters are potentially good indicators of meat tenderness. Chen et a1. (1971) deve10ped a computer program to determine the coefficient C i and exponential “i in the general relaxation equation: -a.t’ n F(t) = 2 Ci e 1 i=1 for the generalized Maxwell relaxation model, where 3/2 - . - 1/2 1 3/2 a KEi étl e 0‘1“1 T ) I de 0 II and “i = 51/"1 Bashford et al. (1973b) developed a computer program to calculate the elastic and viscous parameters for the generalized Maxwell and Kelvin models. Maxwell's model is used as a relaxation model. They used the general form of relaxation equation F(t) =3 C i Eat/Ti to determine 1=1 the coefficient C1 and eXponential t/Ti. 20 2.3 Hertz Contact Problem Hertz (1896) proposed a solution fer contact stresses in two elastic isotropic bodies, such as the case of two spheres of the same material touching each other. In his problem, Hertz attempted to find answers to such questions as the shape of the contact surface, the normal pressure distribution on the surface of contact, the magnitude of the maximum pressure, and the approach of the centers of the bodies. In developing his theory, Hertz made some fundamental assumptions. These assumptions, given by Kosma and Cunningham (1962) are the following: 1. The material of the contacting bodies is homogeneous. 2. The loads applied are static. 3. HOoke's law holds. 4. Contacting stresses vanish at the Opposite ends of the body (semi-infinite body). 5. The radii of curvature of the contacting solid are very large when.compared with the radius of surface of contact. 6. The surfaces of the contacting bodies are sufficiently smooth so that tangential forces are eliminated. The first known application of the Hertz solution for contact stresses in agricultural products was reported by Shpolyanskaya (1952), who applied it to evaluate modulus of elasticity of wheat kernels. Morrow and Mohsenin (1966) have applied the results of Hertz's work to calculate the relaxation modulus and creep compliance of apples. Fridley et a1. (1968) obtained experimental force-deformation curves for peaches and pears and compared them to the theoretical curves as calculated using the Hertz equation fer plate against sphere. 21 Horsfield et a1. (1970) applied theory of elasticity to the design of fruit harvesting and handling equipment for minimum bruising. They extended Hertz's contact theory, given by Timoshenko and Goodier (1951), for the colliding of two spheres, to determine internal shear stresses generated under impact considering effects of the modulus of elasticity and radius of both the fruit and the impact surface. They discussed experimental techniques for measurement of modulus of elasticity under impact loading. They concluded that the modulus of elasticity and surface radius of both surfaces, in addition to the impact energy and flesh strength, permit meaningful prediction of bruising and serve as good criteria fOr design of machines to reduce bruising. iMohsenin (1970) reported several applications of Hertz's contact theory on agricultural products. He reported the formulas to calculate the modulus of elasticity for a convex body of an agricultural material being tested under a steel flat plate or under a spherical indenter. Hoki (1973) studied the mechanical strength and.damage analysis of navy beans. In his study, Hoki used Hertz's contact theory given by'Thmoshenko and Goodier (1951) to determine the radius of the contact surface and the approach of two spheres when compressed together. He concluded that: a) using the contact theory to predict mechanical damage of navy beans showed promise; and b) it is appropriate to apply the contact theory to predict bean deformation under static loading for beans with low moisture content. The solution of the viscoelastic counterpart of the Hertz problem in elasticity can be deduced from the elastic solution (Lee and Radok, 1960). Foppl (1922) derived an equation to determine modulus of elasticity of a cylindrical specimen compressed in the direction parallel to the 22 longitudinal axis. His assumption of the contact surface pressure differs from that used by Hertz. Fbppl used a parabolic distribution while Hertz used the semi-ellipsoid distribution. III. PRELIMINARY STUDIES me to the fact that a very limited amount of information was available on the texture evaluation of carrots, preliminary studies were conducted. The Texture Profile Analysis (TPA) parameters , modulus of elasticity of the two distinct areas of cross-sectional samples of carrots and Poisson's ratio were measured. The effect of storage time on these parameters was also investigated. In looking at a cross-section of a cylindrical sample taken from a carrot, one can identify two areas, a center core, dark in color, and outer ring, light in color. In a cylindrical sample of one-inch in diameter, the center core is approximately one-half—inch in diameter. Preliminary measurements of the modulus of elasticity for the center core and the outer ring were made using axial loading of cylindrical samples. The results showed that the modulus of elasticity, EC for the center core is approximately twice the modulus of elasticity, Eo for the outer ring (Table 4). Moisture content of the whole sample was measured for fresh carrots and for carrots stored in the Aminco chamber at 70°F and 50 percent relative humidity. Also, the moisture contents of the center core and the outer ring of samples, stored at 120°F and 50 percent relative humidity for 14 hours, were measured (Table 5) . The results of the moisture content measurements showed no significant changes in the mois- ture content when measuring for the whole sample or the center core. But the moisture content changed significantly in the outer ring of the sample. 23 24 Table 4. JModulus of elasticity for the center core and the outer ring of six fresh carrot samples. Sample No. E0 EC psi psi 1 796 1475 2 847 1000 3 847 1750 4 593 1250 5 847 2000 6 847 1375 Ave. 796 1475 Table 5. IMOisture content of fresh carrots and of carrots stored under different conditions and.time periods. M.C. % of center core and outer ring of Sample M.C. % of M.C. % of carrots carrots stored at No. fresh carrots stored at 70°F 120°F and 50% R.H. and 50% R.H. for for 14 hours 24 hours center outer core ring 1 88.7 85.6 84.0 80.2 2 86.3 84.3 84.8 72.3 3 85.7 83.7 84.8 72.3 4 87.3 84.1 85.2 75.6 5 88.5 83.5 85.5 79.5 6 88.9 85.0 85.5 79.5 7 88.8 83.2 84.8 79.1 8 87.9 84.0 84.4 76.2 9 86.3 84.6 83.6 78.1 10 87.5 84.5 84.6 82.4 Ave. 87.6 84.5 84.7 77.5 25 A Texture Profile Analysis (TPA) parameters were determined by the method described by Bourne (1968a) from.force-defbrmation curves produced.upon twice compressing each sample 0.1-inch on the Instron Testing Machine . Cylindrical samples of one-inch in diameter and 3/4-inch long, were compressed axially. Typical "first bit" and second bit" curves were as shown in Fig. 6. The TPA parameters tested were: 1. Hardness 2. Cohesiveness 3. Gumminess 4. Brittleness .Although there was a noticeable change in the appearance of the carrots after seven hours of storage, the data showed no significant change in the values of the measured parameters, especially the hard- ness parameter. Hardness data fer samples of fresh carrots and carrots stored at a temperature of 70°F and 60 percent relative humidity for 24 hours are given in Table 6. It was concluded that axial loading of the cylindrical samples was not usefu1 in detecting the change in the texture parameters such as hardness. The nonsignificant results in determining the TPA para- meters is believed to be due to the difference in the values of modulus of elasticity of the center core and the outer ring of samples. It.may also be due to the nonsignificant 10Sses of moisture from the inside core compared to the outer ring. In defonming the samples axially, the center core dominates the reaction to the applied ferce at a given defbrmation, because it is stiffer and contains higher moisture than the outer ring, leaving the outer ring to fellow the behavior of the Force, lbs. 26 Hardness i // A1 Fig. 6. Defbrmation, inches Typical ferce-defOrmation curve for TPA parameters test. 27 Table 6. Hardness parameter measurements using the TPA.method of axial defermation. The hardness is measured from force-deformation curves produced upon twice compressing cylindrical samples of carrots previously stored in per- forated plastic bags at 32°F and 95% Relative Homidity fer three weeks then removed from the bags prior to testing and stored in a room at 70°F and 60% Relative Humidity for 24 hours Hardness, lbs. obtained at different storage times at Sample room conditions of 70°F and 60% Relative Humidity No. 0 ‘ 4 7 16 21 24 hours hours hours hours hours hours 1 40 38 37 30 33 23 2 35 38 36 34 34 20 3 40 36 37 32 31 21 4 38 39 38 35 30 26 5 35 39 35 33 32 20 center core under the applied load. The outer ring from the previous experiment, appears to be controlling the decrease in the moisture con- tent. It receives the first action when the carrots are bit or physi- cally tested for consumer acceptance of fresh products. This conclusion suggested that the samples be loaded in the radial (parallel to the longitudinal axis) direction between two flat steel plates and that the moisture content be measured in the outer portion of the cylindrical samples. IV. THEORY Mechanical properties have been defined as "those properties having to do with the behavior of the material under applied force". Mechanical prOperties are widely used to study engineering materials or non-biological products. As of late, they have also been used to characterize agricultural products. The modulus of elasticity is one of the properties which is of considerable interest. The Hertz contact problem has been one approach to determining the elastic modulus in agricultural products. Hertz's problem of contact stress, was originally developed to calcu- late the stresses resulting fron the contact of common engineering materials. One result of the theory is an equation giving the modulus of elasticity, E, for a convex body compressed under a flat steel plate. This equation is E = 0.338 k3/2 F (1 - v2) (_1_ + l )1/2 [1] (13/2 R R’ where o = Total deformation of the body, in. F = Compression force, lbs. k = Constant taken from a table (A-l) R = Minimum radii of curvature, in. R’= Maximum radii of curvature, in. The total deformation of the body along the axis of load at the point of contact is giver by 28 29 /3 Q ll 1 331W K2 ($112)] [21 where The value of k depends on the principal curvatures of the bodies at the point of contact and the angle 45 between the normal planes con- taining the principal curvatures. This value can be obtained from Table A-1 by first calculating cos T, for general case of two bodies, 1 and 2 pressed together, from 1 1 2 1 1 1 1 1 1 1 2 cos T = [ (1:1 Rf) "' (Ti-2 fi, ) + Zffil Rf) (1:2 R5 ) C05 24’] l l l l (R1+R1+R2+R’) [3] where R1 and Rf are minimum and maximum radii of curvature for body one, and R2 and R5 for body two. The preceeding equations are valid when the specimen is a sphere. When the specimen is a cylindrical (i.e. R1 = co) cos T becomes one and the value of k is not defined. To determine the elastic modulus for a cylindrical specimen com- pressed in the radial direction between two flat plates, an equation has to be derived based upon Hertz's contact theory. 30 4.1 Derivation of an equation to determine modulus of elasticity of a cylindrical specimen compressed radially. Timoshenko and Goodier (1951) expressed the deformation at the surface of contact of two bodies as a = (K1 + K2 )1; q d" + BY2 + (1x? [4] r In which B and C are constants depending on the magnitudes of the prin- cipal curvatures of the surfaces in contact and on the angle between the planes of principal curvatures of the two surfaces. If R1 and Rf denote the principal radii of curvature at the point of contact of one of the bodies, R2 and R5 those of the other body and v the angle between the normal planes containing the curvatures l/Rl, and l/RQ, then the con- stants B and C are determined from the equations _ 1 1 1 1 B + C - 2 ( R1+ Rf + R2 + R5) _ 1 l 1 2 1 l 2 1 l 1 1 1/2 C - B - 2 [(RI Rf) + (R2 - R5) + 2(R1 - Rf)(R2 — R§)COS 2?] where total deformation of the cylinder (in.) 52 ll q = pressure at any point of load distribution (psi) dA = element area on the area of contact (in?) r’= the distance from the center of the area of contact to the element area dA (in.) 2 Kl_1-v1 11E 2 _ 1 ‘ V2 75 N I 11E 31 v = Poisson's Ratio E = Modulus of Elasticity (psi) In the case of contact of a cylinder with a plane surface, Figs. 7 and 8, B and C become B+c=._1._ 2R1 C-B=_1_ 2R1 whichmeansthatB=0andC=_1__. 2R1 Taking X to be equal to one-half the width of the contact area, b, at maximum deformation, equation [4] becomes 2 a=(x1+1<2)rrfli‘5+9_ 5 r’ 2R [] The problem now is to find a distribution of pressure to satisfy equation [5]. Hertz showed that this requirement is satisfied by assuming that the intensity of pressure q over the surface of contact is represented by the ordinates of a semi-ellipsoid constructed on the surface of con- tact as shown in Figs. 9 and 10. q=§gv’52-xz [6] The maximum pressure qo is clearly along the center line of the surface of contact. The magnitude of the maximum pressure is obtained by summing forces in the y direction, yielding P = 2 rL/2 b _ b 'L/2 f0 QdA - 2L [0 de [7] 13.4.3513 12’de L b 32 Pl Fig. 7. Cylindrical sample before compression > T ‘\ H? 1 0/2 T Fig. 8. Cylindrical sample after compression 33 ‘ ioi ; a . . ..l! flillijl .n——-—b————ai 1......x Fig. 9. Semi-ellipsoid pressure distrilartion 2 Fig. 10. Pressure distribution over the surface of contact 34 p’ = qob" and qo = 2P’ [8] 2 m: where P is total load and P’ is load per inch of length. Timoshenko and Goodier give the expression P’ (K1 + K2) Rle - b =f 19] R1 + R2 for the case of contact of two cylinders with parallel axes. R1 and R2 are the radii of the two cylinders- When a cylinder contacts a flat surface, R2 becomes 00 and b becomes b = f4P’ (K1 + KZTRI If the cylinder is a biological material with small modulus of elasticity E1, and the flat plate is made from steel, E2 = 30 x 106 psi, then K2 + 0 and b reduces to b = W [10] where R is the cylinder radius. Equation [5] now becomes 2 a=KfffEfi+L [11] r’ 2R Utilizing equation [11] and the assumption of semi-elliptic pressure distribution for the case where the cylinder is loaded with a flat steel plate, (Fig. 11), an equation for the elastic modulus, E, of the material can be derived as outlined below. Starting with [11] and substituting [6] gives 2 a-L =4“?ng 19./”W -x dxdy 2R br’ 35 where the integral is over one-fourth of the contact area. Two changes are now in order if evaluation of the integral is to be simpli- fied. The first is a change in variables by letting This change produces 2 1 r-Trt——7—2 a-9_=4qu fo /_b____i_)_§. deXdY 2R b 0 ° br or 2 o-P_=4qubf:1f;v’l-X1dXdY 2R r where 11:1; 2b The second involves dividing the contact area (Fig. 11) into two triangles ‘with e and o defined as shown in Figure 12, and then chaning the equation into the Polor Coordinates. This transformation yields -1 2 _, Z T 1 (a _ E.) = IEan M fiece //l r cos 6 r dr d6 4Kq b 2R r -1 tan l/M Msec¢ f f O O + “/1 - rYSinze r dr de 1' or 2 4K b (C! ' 13—) = II + 12. qo 2R 36 Considering the individual components 11 and 12 gives -1 - - _ Z. Z 11 = If)“ M 13°C 6 /i_29_5_9dr d6 1' ° 0 c050 t ’111 m d‘ I an _ sec 0 d0 O 4 3. =31. iogem+/T+—M“27 - 4 j 11.. and -1 2.2 12:15:81) l/Mflglseco /1-r51n¢rdrd¢ r -1 = fie-n W 113“” W (N (21¢, Y = r sine sine -1 tan l/M 651,14 y + %Y J l - Y2]l:I tam csce d4 0 = f -1 1 _ w = % [San ”’1 [sin 1 (M tamp) + M tan¢ / 1 — MYtanZ¢]csc¢d¢ sin v ’ Substituting sin v = M tamp, sine = /M2 + sinzv d¢=Mcosvdv M2 + sinzv yields MA—w- — u. Fig. 11. Area of contact Y I L I -1 M 'Zb. 9 tan M 1 r’ 9, l- a o " ' 1 K Fig. 12. One-feurth the area of contact divided into two triangles 38 12 = l fH/z (v + sin v cos V) COt v dv 2 ° / .2 2 1 + (Sin v) /?M since M>2,(sinv)/M<—1-, wecanexpand .7 - (1 + srn v) 1/2 M? by the binomial theorem as sin v -1/2 1 srn v 1 . 3 sin“ v (1+ 2 ) ‘ [1 "‘ 2 +2— 1" 1+ ..... ] .M .M M Then 12 may be written as 0 2 . I2 = l-fn/Z (v cot v + coszv) (1 — l_srn V + l—' 3_srn“v.. ) dv 2 o 2 M2 2 4 'M“ Integration by parts gives I“2 v cot v dv = - fn/2 log sin v dv = E.log 2 O 0 e 2 e and fg/2 v cot v sin2n v dv = fg/2 v sinzn'1 v cos v dv . 2n _ v srn v n/2 l H/2 . 2n ‘[—_2—n—] *23'. 51" “1" 0 II =— [1 - 1’3'50000 2n " 1)] 4n 20406000211 39 From that 12 becomes II 1 1 1 1 1 11 12=rlfloge2*2‘)'2(z'r*z 2111—12“ 1 3 1 1 1,3 1 1 3 1 zrfr‘r 7 1+2 4 63m“ 1 3,5(1_1 1.3.5+1,1,3,5)_1] 246662462468M5 12=£[1ogez+%- 3 + 21 -__£9_5___] 4 16 M2 256 M” 6144 M6 12=I-1-[loge2+%-- 3 (l— 7 + 98 ] 4 16 M2 16 M2 384 M" Since — _ 2 m“1 X+X ..... 7 98 . . 1 (l - + ) 15 approxmately -———-7——— 16 M2 394 M“ 1 +——- . 16 M7- and 12 becomes 11 l 3 l 12‘111082+7‘ ) e 16 M2 1 + 7 16 M2 3 II 1 4-[10ge2+_2- 40 Then 1 _ b2 _m r—————Z— 1 3 '——-—4qub (a 712') -E[10ge 04+ 1+M) +10g92+7-————16M2+ 7 _II 1 3 -__[log 2(M+/I+MZ)+7- ——————— 4 ° 16M2+7 But 2P’ qo TIE -/T—’Ifii -b2 b” P »K‘1p—m = L M rs Therefore 2 b a-Q-fi=Hqub[loge(M+/TrMZ)+-%—- 3 16M2+7 b2 1 3 = [log 2(‘M+/-l_+—W)+—-———— .2?- e 2 1m2+7 2 a=%§[logeZ(M+/T_+—M7)+%-__3__ . 16M2+7 Letting W = TI; = 2M yields the following equation 01R 1 3_ 3 175‘sz [1°gem+'4+w)+7 4w2+7] “21 41 Table A-2 was prepared from equation [12] for values of W at different values of 9;. Once W is know, E can be calculated as follows _ L ___ L W ‘ b" ___“ (4P’KR L2 K __7—4P’W R 1 - v2 = L2 1113 4 P’WZR _ 2 e 2 E=4(1 v)PWR [13] mL2 4.2 Fbppl's Equation An equation which gives the modulus of elasticity for a cylinder compressed by a flat plate was found after [13] had been derived. This equatior was developed by Fbppl (1922). There is a major difference in the assumptions used by Fbppl when compared to the work done by Hertz. Fbppl used the second power of the semi-elliptic function for the pressure distirbution. His equation for q was q = 32 (b2 - x2) [14] b2 which resulted in the following relationships 1 -v2 TIE 2R o = 4P’ ( ) (1/3 + loge —b) [15] - Im- 42 =8 (I-vZ) P’ 22 RD E [16] where Z = R/b and values are given in Table (A-3). 4.3 Relaxation test Stress relaxation experiments have been conducted on several agri- cultural products. In this rheological test, the specimen is suddenly q brought to a given deformation (strain), and the stress required to 1 hold the deformation constant is measured as a function of time. Since the deformation of the product under load is held constant, it is usually 'F‘fi .- a x .- ‘Hu_m; assumed that the loaded area of contact remains constant during the relaxation test and the recorded force- time is representative of the stress-time curve. The generalized Maxwell model can be used to represent force or stress relaxation. A generalized Maxwell model is composed of n Maxwell elements with a spring in parallel with the nth element as illustrated in Fig. 13. When the model is subjected to a constant strain so at time = 0, the stress can be represented by 0 (t) = so (Eli—2"1t + E2é°2?..+ Ené°nt) [17] where on = En/nn, E is stiffness or modulus of the spring, m is viscosity coefficient of the liquid in the dashpot. Then the equation representing the portion of the curve where t > t1, (Fig. 14) can be written as 1 . éalt’ [18] "Mb ('3 F(t) = i 43 where C1 = to E1 a3/2 K 1:1 é°1(t1 " ‘)1:2 dr II (N \ N E O t, t'tl a = rate of deformation in./min. Factor K is being a function of the geometric parameters of the specimen. The approximate values of C1 and a1 can be determined by the num- erical methods which used a computer program developed by Chen (1971). 44 4%m 1 El En n1 ___] m2 LP] mg] I [___] on F Fig. 13. Generalized Maxwell model / / I I n / - , _ _ . I %K 113/2 2 Bi [1:1 e “131 T) :1/2 dr]e “It / i=1 8 u. \ .3: 1 \.\ 8 *\_ 12 0 t1 Time, t Fig. 14. Graphical representation of equation [18] ’ 45 V. EXPERIMENTAL INVESTIGATION 5 . 1 Equipment To obtain one-inch diameter samples, one-inch long, a corer (A), two inches long, was constructed with an internal diameter of one- inch and mounted on a base (B), (Fig. 15). A holding jug (C), one-inch long with internal diameter of one inch, and two-bladed lmife (D), (Fig. 16) , were used to trim the samples to a proper length of one inch for the (1+4..- radial and Poisson's ratio tests. To measure the restrained modulus needed to determine Poisson's ratio, v, a cylindrical die (E) with a one-inch inside diameter mounted on a base (B) with spacer (F) of outside diameter to exactly fit inside die (E), (Fig. 17), were used. Another corer (C), (Fig. 18) , with an outside diameter of 7/8-inch was used to separate a l/8-inch thick outside ring from the one-inch diameter sample. This ring was removed after the radial test, for the purpose of measuring the sample moisture content. An Aminco-Air unit was used to maintain a constant temperature and relative humidity in the chamber where the carrots were stored, (Fig. 19). An Instron Universal Testing Machine, table model TM, 200 kilograms capacity, with standard crosshead speeds of 0.2 to 50 in/min. was used to load the samples, (Fig. 20). (B) Fig. 15. Sampler, (A) is Corer and (B) is Base. Fig. 16. Trimmer, (C) is holding jug (D) is two-bladed knife. 47 (E) (B) Fig. 17. Die to be used in measuring the Poisson's Ratio, (B) is base, (E) is sample holding die, and (F) is spacer. Fig. 18. Corer with 7/8" outside diameter to be used to separate 1/8" thick outer ring from the 1" diameter sample. 48 Fig. 19. Aminco unit with chamber to store carrots at given temperature and relative humidity. Fig. 20. Instron Universal Machine. 49 5.2 Experimental procedure The modulus of elasticity is to be calculated using the equation derived in the previous section. Poisson's ratio and the deformation force are variables in the equation and therefore must be measured. The relaxation test is to be performed in order to study the relaxation behavior under constant strain. Hughes and Segerlind's (1972) method of measuring the Poisson's r— ratio was used. TWO similar cylindrical samples of one-inch in diameter :3 and one- inch long were removed from the individual carrot (length-wise) using the corer (A) and the base (B), the holding jug (C), and the two-bladed knife (D). g One sample was axially compressed in the Instron Machine, (Fig. 21) for the unrestrained test. The other sample was placed in the die (E) as shown in Fig. 22 and then compressed. The two force-deformation curves were obtained (Fig. 23) and used to determine Poisson's ratio. Carrots grown in the State of Arizona and purchased through the Michigan State University food stores were stored in the Aminco unit chamber at 85°F and 50 percent Relative Humidity for one to 72 hours. Samples of whole carrots were drawn from the Aminco unit chamber and cylindrical samples of one- inch diameter and one-inch long were prepared as described above. The cylindrical samples were placed in the Instron Machine and compressed radially, parallel to the longitudinal axis, (Fig. 24), using a crosshead speed of 5 in. /min and a maximum deformation of 0.1 inches at chart speed of 50 in. /min. A force-displacement curve similar to the one in Fig. 25 was obtained. The experiment was conducted using fresh carrot samples and samples drawn from the Aminco lchamber at time intervals of 4, 6, and 8 hours over a period of 72 hours. Moisture 50 "U Fig. 21. loading for the unrestrained test. mar (F) / / I a I 7 ,I r ' I, // W . '1‘ I I - . '1’ .1 . / ' . ' ‘ x/ ’1 . . . .' I I ,' / I / / // .l,. 'e (B) 37/ .-/ / / . - y _I . / .’ I . ' .‘i I" ’ fiample ,/ ./ ,/.. I v f :7 [I / e(B) 80 70 60 50 40 30 20 10 51 / Restrained - f/ 51 = 4.75 R - §_%.= 0'2 = 0.041 s1 4.75 R= (1+v) (l-Zv) : (1 ' V) b- j! I v = 0.495 r- Unrestrained P /SZ = 0'2 1 L 1 L 1 0 0.02 0.04 0.06 0.08 0.01 Deformation, inches Fig. 23. Force-deformation curves for a cylindrical sample of carrots with one-inch in diameter and one-inch long. 52 Fig. 24. Sample loading, in the radial direction or parallel to the longitudinal axis. 53 Force , lbs . Deformation, inches or time, sec. Fig. 25. Typical curve for defamation and relaxation tests. 54 content was determined by removing a 1/8-inch thick outside ring cut from the cylindrical samples and dried in an oven at 70°C for 20 hours. Two sets of data were obtained, 138 samples in Set #1 (Table A-4) and 70 samples in Set #2 (Table A-5) . The moisture content of the l/8-inch thick outer ring was determined for each sample. The samples were divided according to the peak compression force into 11 groups and the average force and moisture content of the outer ring of each group were obtained (Set #1, Table A-6; Set #2, Table A-7). By grouping the data according to force, it was possible to select force-deformation curves with a peak force equal to the group average force and then use the selected curves to obtain the relation between deformation force, modulus of elasticity and moisture content. The relaxation behavior was studied by maintaining a constant defamation (strain) of 0.1-inch on the sample for 30 seconds. A crosshead speed of 5 in./min and chart speed of 50 in. /min were used. Welve points on each curve were used to determine the coefficients and exponential of the generalized Maxwell model. VI. RESULTS AND DISCUSSION 6 .1 Accuracy of the derived equation The equation derived for determining the modulus of elasticity was verified experimentally. The method of examining was a comparison between the modulus of elasticity values for a homogeneous and isotro- pic agricultural product as measured by applying an axial load and a radial load on separate cylindrical specimens. Homogeneous and isotro- pic materials should have the same modulus of elasticity value in both axial and radial directions. The potato was used for the speci- mens since it represents a homogeneous and an isotropic agricultural product. Specimens with variois combinations of 0.5-inch and 1.0-inch diameters and lengths were prepared and subjected to a deformation in the axial or radial direction, of 0.025 inches, 0.05 inches or 0.1 inch. The Instron Testing Machine was used to defonm the cylin- drical samples. A cross-head speed of S in/min and a chart speed of 50 in/min were used. TWO specimens from the same location of the potato were prepared. The modulus of elasticity was calculated using the axial equation, the derived equation, and F6ppl's existing equation. Assuming Poisson's Ratio, v, for potatoes to be 0.5, the derived equation [13] and FOppl's existing equation [16] become: - 2 Derived: E1 =4(1 0-25) 13’sz ___. 0.955 P’W R H L2 L2 [19] 55 56 = 8(1 - 0.25) P.22 = 1.91 P’22 IID D Poppl's: E2 [20] The axial loading equation to detenmine the modulus of elasticity is: E3: >l'11 QIL‘" [21] A summary of the calculated values of B for different specimen sizes and defonmations is presented in Table 7. The averaged values of B were 415 psi, 496 psi, and 419 psi as calculated by the derived equation, FOppl's equation and the standard axial equation respectively. The mean, variance, and standard deviation were calculated (Table .A-8) and an F statistical test was used to determine whether the popula- tion variances are equal or not. The null hypothesis of = oi was tested at the 0.05 level. The results showed that there is insufficient evi- dence to indicate a difference in the population variances. The conclusion. , 2 2 . . 15 that of = 02 = 03 15 not reJected. 6.2 Poisson's ratio The Poisson's ratio for fresh carrots was found to be approximately 0.5, The value fer carrots stored in a room temperature of 70°F and relative humidity of 60 percent for a time period of 24 hours was found to be essentially the same, 0.50. Twenty-one samples of carrots were studied in each case. The average values were 0.492 for fresh carrots and 0.496 fer stored carrots (Table 8). The derived equation [13] reduces to [19] for carrots since Poisson's ratio is 0.5. 57 9}. .- ..'I‘P' mfie woe mHe name emm «em Nme AH.m Ne.m omo.o mNo.o m.m N.m m.o m.o mNo.o Ram ewe was NH.m oe.o~ omo.o mNeoo.o m.e w.~ o.H m.o mNo.o omm ONm mam mm.h em.o mmc.o omo.o m.e m.mH m.o o.H mmo.o mam emm ome we.“ mm.mH mmo.o m~ao.o 0.4 m.m o.H o.H mNo.o «me hoe mNe em.m om.e CH.o omo.o o.HH m.m m.o m.o mo.o wee com oem em.m mm.ma oa.o mNHo.o R.HH 0.4 o.H m.o mo.o mew mew Nam afi.m w~.e mo.o o~.o ~.HH 4.0m m.o o.H mo.o mow see man 5H.m Ne.m mo.o mNo.o H.m w.mH o.H o.H mo.o «me new man em.m om.~ H.o om. m.HN H.me m.o o.H H.o flee Hfie mam em.m em.o H.o mo.o m.mH n.4m o.H o.H H.o emu uma awe N 2 n\5 .wu. :a\na DH seen seen such mm mm Hm as a m A a a a a. a N4 .83 35308 880 3 < when: w. m. a mm .MNIM 34 u «m .Immzlum 3.3 u 5. “momma nomads—poms Ea menwm 553on 3309 30.8.33 pom m mo 833 woumgoamo mo bfiefim .N. 038. Table 8. Poisson's ratio, v, measurements for fresh carrots and for carrots stored in a room at 70°F and 60% relative humidity for 24 hours. Sample No. KOWVO‘UTbQNNF-I' 58 Fresh carrots 0.493 0.493 0.495 0.492 0.494 0.493 0.494 0.492 0.493 0.489 0.493 0.488 0.483 0.494 0.494 0.485 0.490 0.490 0.486 0.497 0.495 0.492 24 hours stored carrots .496 .497 .496 .497 .498 .496 .497 .498 .494 .494 .498 .495 .495 .498 .497 .497 .497 .495 .495 .493 .496 OOCOOOOOOOOOOOOOOOOOO 0.496 The relationship between the peak force needed to deform.the sample 0.1 inch in the radial direction and the moisture content in the outer ring (percent wet basis) was plotted from the results summarized in Table 9. .A best fit-curve was drawn using a statistical sub-routine (Fig. 26). A second degree polynomial curve was found to be the best fit of the plotted data. This curve showed a significant relationship between the peak force and the moisture content. content decreased, the force needed to deform the sample, also decreased. 6 . 3 Deformation Test As the moisture 59 A correlation coefficient of 0.937 was obtained for the curve. The modulus of elasticity, 13, was calculated using the derived equation, [19] , and the results are plotted as related to the moisture content (Fig. 27) . The second degree polynomial curve indicated that there is a significant relationship between the modulus of elas- ticity and the moisture content. As the moisture content decreased, the modulus of elasticity decreased. The correlation coefficient was 0.937. The modulus of elasticity at 85 percent moisture content was 725 psi which is almost ten times greater than the value of 70 psi at 76 percent moisture content. The sharpest drop in the modulus of elasticity occurs during the first five percent drop of the moisture content below that of fresh carrots. After this, the rate of decreases changes less rapidly. The decrease in the modulus of elasticity is believed to be a measure of the hardness parameter of carrots . As the carrots lose moisture from the outer surface of the sample, it becomes less rigid causing the defamation force to drop. The results of the defamation indicate that a slight drop in the moisture content of the outer ring creates a sharp drop in the hard- ness of carrots. Earlier results had shown no difference in the hardness of carrots as related to storage time when the measurements were in the axial direction of cylindrical samples. 6.4 Relaxation tests The computer program by Chen (1971) was used to calculate the coefficients C1 and the expanentials 011 using a three element (i=3) generalized Maxwell model [18] . 60 wwoo.o H5m.o 5o.m vw.o 5N.o mN.o v.H 5N m.N5 owoo.o 5mm.o mo.m mo.H mm.o mm.o w.N em H.m5 omoo.o m5v.o mw.m ow.m oo.H mm.o w.m NHH 5.55 O5oc.o mo¢.o Hm.m wm.m m¢.H NM.H m.w voa m.m5 5moo.o mwm.o om.m H5.w 50.H No.N m.NH HVN w.m5 mvoo.o mmv.o mw.m om.HH OH.N om.N v.0H 5Hm m.Hm mmoo.o 05m.o mo.N wv.wH mm.N Nm.N o.v~ «ow N.Nw mmoo.o mom.o mN.m mo.H~ MH.m mm.N m.5N 5mm o.mw m~oo.o mov.o O5.m wo.5N Nv.m ON.M o.¢m 5mo m.mm wmoo.o m5v.o em.¢ mm.w~ H5.m em.m v.mm ewe 5.vw omoo.o va.o mw.m 5H.mm 55.v ow.¢ o.m¢ mow 0.0m me we :0 mo mu 6 mMH «Emma: .56.: #0on H3582 woufiehanom 8:53.... 05 Sum wanna—guano mp 335595 98 mucofioflmooo 533309 05 EB .Eumogfi maize Hausafiyaoxa vapoofiom any we auuom Moon .8333 35.8w 05 Scam Engage mm 3339...? we magmas .3380 0.53on me wonder .m 3an 61 The coefficients C1, C2, C3 and the exponentials a1,'a2, a3, were determined by taking points from the force-time curve. Table 9 shows the values of C1 and 01 at various moisture contents. Three relationships between C1, C2, and C3 and the moisture content 'were plotted and the second degree polynomial curves were the best fit for the plotted data. These relationships are shown in Figures 28, 29 and 30 for C1, C2, and C3, respectively. Each curve shows a signifi- cant relationship between C1, C2, and.C3 and the moisture content with correlation coefficients of 0.963, 0.965, and 0.927, respectively. The relaxation coefficients C1, C2, or C3 decreased as the moisture con- i a a" i '0 51 A ". ‘ tent decreased. The relaxation coefficients C1, C2, and C3 and the expanentials al, a2, and a3 were used to calculate the farce-time experimental curves (Table A-9). The experimental and calculated curves of the generalized Maxwell model, with three elements, are shown in Fig. 31, at sample moisture contents of 86.6 percent, 83.3 percent, 79.8 percent, and 77.7 percent. The calculated relaxation curves are identical with the experimental curves, indicating that the force relaxation curve of a carrot could be represented by equation [18]. Table 9 shows that there is no significant relationship between the exponential ml and the moisture content since the data fluctuated with no behavior pattern. 62 .pmou 539E820 S... Show 3:32 “condom on» no pfiueou 8339: we gamma .3. .mE w .3: page 05 me 9538 33302 no 00p 0.1m amp 0.0m opp one aim own 0.05. a _ i _ n a _ o _ a i _ _ o _ o _ 1 4 L L 4 l a 1 i _ . . . _ _ . _ _ _ _ . _ _ OO'T mfg W'OT '3'08 L °sq1 ‘QDJOd 5'2 5. .‘OE E'EE 63 L3 .eoflumsco eo>fihoe one 5: uaumfisuHmu mm mpohhmo mo 5uwuwpmmfio mo measeez. .5N .mwm w .mewa Hausa can we peoueou ouspmflaz .mm 0.4m m.on o.pn m.ma o.ma m.mn o.mx- O .1 [I] U) L art 1 l ‘43: 5nI“PQN J are l '39-. l l _l 1 '24. . 11?: '63:. 3111/ 5‘11 misuseta JO '6TB l l '61}; 64 .umou oofimxwfiah 5 poofiuwmmooo umhfl m5 :0 “59:8 8:3on mo uoammm . mm .mfim » .wfih house 05 mo 95550 830.82 .03 04mm 0.3m 0.3m O.Nm 0.0m O.m5. 0.0.5: 0.35.. O.N5| 0.05.- CO'O 0'“. 0’78 CQ'T 00 E I 111919155800 ":3 65 .pmou 83883." 5 uoafiuflmmoou vacuum 05 no 28280 8339: we 903mm .3 .mwm w .wfiu .830 05 mo 23:00 055302 .00 ohm 0.1m 0mm. 0.0m 01mm 00a 0.15. can con _ Li _ A i _ _ _ _ a _ _ _ _ o _ _ o o _ 17 i a a 1 do '1 L \.. 1 0? 09' (1‘1 03' ’f ' 0- 0 Z 111953133902) ‘ 32) 66 .ummp cofiumxgma 5 ucmwummmou v.35 on» :0 33:8 8339: we uuommm .om .mwm * .3? House 05 mo ucounoo 33302 0.03 0mm ohm 0.1m 9mm 0.0m own OJP Gib 0ND 0.9. r _ _ _ _ _ a a _ _ _ 1 . _ . _ . _ _ _ _ [1| I J I 1 i \ i .. \ L \ ' \\ IL \ 4 .l. \m. I; I. \\ IL ‘\ 0 \ J \ - K 1 n \.. I . LT ('1 0'0“ S 11131393903 ‘89 67 45 - ll —— Experimental \‘ ------ Calculated 40 A\ 35 '— \~\~§=§\ ll ‘3‘:::~::.-.___ 7.» 86.696 M.C. h. m:-- ‘ a 30 7-\ ,fian‘aaflr“; .--.- _ 83.396 M.C. 25 *- -—--—-_--~m 1 20 .— 4 I 15 _ 10 _--__________________ 79.8% M.C. am 77.7% M.C. ‘- Wis c. -'- do- u d”--- -‘O-‘-----'-~“W'* O ‘ l l 1 g l __l_ O 5 10 15 20 25 30 Time, Sec. Fig. 31. Experimental and theoretical results for relaxation test at different moisture content. Table (A-9) VII; CONCLUSIONS.AND RECOMMENDATIONS 7.1 Conclusions The conclusions derived from this study are as follows: 1. Measuring the change in TPA parameters, using an axial load on F———qg a sample of carrot, gave no significant results between hard- ness as a textural parameter and moisture content of the outer ring. F There are two distinct areas in a cross section of a cylindri- E~ j cal sample, a center core and an outer ring. The center core 6 has a.modulus of elasticity twice that of the outer ring when measured in the axial direction of a cylindrical sample. The moisture content after a period of storing is not unifbrnn throughout the cylindrical sample. It increases as the center core is approached. The Poisson's Ratio of a carrot is approximately 0.5 and is independent of moisture content. An equation for calculating the modulus of elasticity, E, of a cylindrical sample compressed in the radial direction.was de- rived as E = fl£l_;_231.p’w2R nL2 Comparison between the derived equation and Poppl's equation for- calculating the modulus of elasticity of a radially compressed. sample gave no significant variation in the modulus values, indicating that the assumption relative to the pressure 68 10. 11. 12. 13. 69 distribtution may not be a critical factor. The hardness of texture parameter was found to be an important parameter as related to moisture content. As the moisture con- tent decreased, the hardness, as measured to be the force to deform cylindrical sample compressed radially, decreased. The force-time relaxation curve can be predicted by using three elements of the generalized Maxwell Model, i.e. F (t) = cléalt + czéazt + c3é°‘3t The coefficients C1, C2, and C3 of the relaxation equation showed a significant variation when plotted against moisture content. The exponential coefficients (:1, a2, (13 showed no significant variation when plotted against moisture content. As the moisture content in the outer ring decreases, the cal- culated modulus of elasticity decreases. The modulus of elas- ticity is an indication of stiffness. Moisture content is the critical factor in carrot texture as indicated by the hardness parameter. The hardness parameter should be measured as the peak force applied to deform cylindrical sample radially. 7 . 2 Recomnendat ions Further study should be made to determine the (TPA) parameters from force-deformation curves produced by twice compressing a cylindrical sample in the radial direction. 7“: I P“. I“. E‘ v ,— " :.' La, _ 70 A study is recommended on measuring the modulus of elasticity of carrots stored under different temperatures and relative humidity to find the range of the modulus of elasticity value as related to the consumer acceptance of the product. This range could be used as a scale to measure carrot freshness objectively. The K value (Chen, 1972) in the relaxation equation should be determined so the modulus of elasticity can be cal- culated from the relaxation test and compared to the value calculated ”___“. from the derived equation. The study of the moisture content distribution from the center to the outer surface of a cross-section cylindrical sample of carrot is also J .— reconmended . s w..— APPENDIX 71 72 Table A-1. values of m, n, and k corresponding to Cos T (After Kosma and Cunningham, 1962). Cos T m n k Cos T m n k 0 1.000 1.000 1.3514 0.760 2.111 0.571 1.111 0.020 1.013 0.987 1.3512 0.780 2.195 0.558 1.091 0.040 1.027 0.974 1.3507 0.800 2.292 0.545 1.070 0.060 1.041 0.961 1.3502 0.820 2.401 0.530 1.047 0.080 1.056 0.948 1.3494 0.835 2.494 0.518 1.027 0.100 1.070 0.936 1.3484 0.845 2.564 0.511 1.013 0.120 1.085 0.924 1.3469 0,855 2.638 0.502 0.998 0.140 1.101 0.912 1.3453 0.865 2.722 0.494 0.983 0.160 1.117 0.901 1.343 0.875 2.813 0.485 0.966 0.180 1.133 0.889 1.341 0.885 2.915 0.476 0.948 0.200 1.150 0.878 1.339 0.895 3.029 0.466 0.929 0.220 1.167 0.866 1.336 0.905 3.160 0.455 0.908 0.240 1.185 0.855 1.334 0.912 3.262 0.448 0.892 0.260 1.203 0.844 1.330 0.916 3.326 0.443 0.882 0.280 1.222 0.833 1.327 0.920 3.395 0.438 0.872 0.300 1.242 0.822 1.323 0.924 3.468 0.433 0.862 0.320 1.262 0.812 1.319 0.928 3.547 0.428 0.851 0.340 1.283 0.801 1.315 0.932 3.631 0.423 0.839 0.360 1.305 0.790 1.310 0.936 3.723 0.418 0.828 0.380 1.327 0.780 1.305 0.940 3.825 0.412 0.815 0.400 1.351 0.769 1.300 0.944 3.935 0.406 0.801 0.420 1.375 0.759 1.294 0.948 4.053 0.399 0.787 0.440 1.401 0.748 1.288 0.952 4.187 0.393 0.772 0.460 1.428 0.738 1.281 0.956 4.339 0.386 0.756 0.480 1.456 0.728 1.274 0.960 4.509 0.378 0.739 0.500 1.484 0.717 1.267 0.964 4.700 0.370 0.719 0.520 1.515 0.707 1.259 0.968 4.94 0.361 0.699 0.540 1.548 0.696 1.251 0.972 5.20 0.351 0.676 0.560 1.583 0.685 1.242 0.976 5.52 0.341 0.650 0.580 1.620 0.675 1.232 0.980 5.94 0.328 0.621 0.600 1.660 0.664 1.222 0.984 6.47 0.314 0.586 0.620 1.702 0.653 1.211 0.988 7.25 0.298 0.545 0.640 1.748 0.642 1.200 0.991 8.10 0.281 0.504 0.660 1.796 0.631 1.187 0.993 8.90 0.268 0.472 0.680 1.848 0.619 1.174 *0.995 10.14 0.251 0.432 0.700 1.905 0.608 1.160 *0.997 12.26 0.228 0.376 0.720 1.966 0.596 1.145 *0.999 18.49 0.185 0.278 0.740 2.035 0.584 1.129 *These intervals cannot be interpolated. 73 Table A-2. values of W at different values of %§-of the equation: 01R OR OR W F W :7 W 1.7 2.00 .36801 4.20 .10322 6.40 .04950 2.05 .35289 4.25 .10113 6.45 .04883 2.10 .33873 4.30 .09910 6.50 .04817 2.15 .32546 4.35 .09713 6.55 .04753 2.20 .31298 4.40 .09522 6.60 .04689 2.25 .30124 4.45 .09337 6.65 .04628 2.30 .29018 4.50 .09158 6.70 .04567 2.35 .27975 4.55 .08984 6.75 .04508 2.40 .26990 4.60 .08815 6.80 .04450 2.45 .26058 4.65 .08651 6.85 .04393 2.50 .25175 4.70 .08491 6.90 .04337 2.55 .24339 4.75 .08337 6.95 .04282 2.60 .23546 4.80 .08186 7.00 .04228 2.65 .22792 4.85 .08040 7.05 .04175 2.70 .22076 4.90 .07897 7.10 .04124 2.75 .21394 4.95 .07759 7.15 .04073 2.80 .20745 5.00 .07624 7.20 .04023 2.85 .20126 5.05 .07493 7.25 .03975 2.90 .19536 5.10 .07365 7.30 .03927 2.95 .18972 5.15 .07241 7.35 .03880 3.00 .18434 5.20 .07120 7.40 .03834 3.05 .17919 5.25 .07002 7.45 .03788 3.10 .17426 5.30 .06887 7.50 .03744 3.15 .16954 5.35 .06775 7.55 .03700 3.20 .16501 5.40 .06666 7.60 .03657 3.25 .16068 5.45 .06560 7.65 .03615 3.30 .15651 5.50 .06456 7.70 .03574 3.35 .15252 5.55 .06354 7.75 .03533 3.40 .14868 5.60 .06255 7.80 .03493 3.45 .14499 5.65 .06159 7.85 .03454 3.50 .14144 5.70 .06065 7.90 .03416 3.55 .13803 5.75 .05973 7.95 .03378 3.60 .13474 5.80 .05883 8.00 .03340 3.65 .13157 5.85 .05795 8.05 .03304 3.70 .12852 5.90 .05709 8.10 .03268 3.75 .12558 5.95 .05625 8.15 .03233 3.80 .12274 6.00 .05544 8.20 .03198 3.85 .12000 6.05 .05463 8.25 .03164 3.90 .11735 6.10 .05385 8.30 .03130 3.95 .11479 6.15 .05309 8.35 .03097 4.00 .11232 6.20 .05234 8.40 .03064 4.05 .10994 6.25 .05160 8.45 .03032 4.10 .10762 6.30 .05089 8.50 .03001 4.15 .10539 6.35 .05019 8.55 .02970 74 Table A-2 continued. m? “7924703692592592603715937159372615049383837272728383949 8776554322100988776554332210099887765544332211009988776 11111111111111000000000000000099999999999999999998888888 11111111111111111111111111111100000000000000000000000000 00000000000000000000000000000000000000000000000000000000 o ooooooooooooooooooooooooooooo 50505050505050505050505050505050505050505050505050505050 23344556677889900112233445566778899001122334455667788990 coo-eo-oooooooooo00000000000000.00.00.00...0000.00.00.00 444444444444444555555555555555.35555666666666666666666667 11111111111111111111111111111111111111111111111111111111 63963074197421976432109988777778889001234678013578035792 65321087643210876543219876543210987765432109987654432100 7777776666666655S555554444444444333333333332222222222222 11111111111111111111111111111111111111111111111111111111 0000000000000000000000000000000000000000000000000000000 .0000...OOOOOOOOOOOOOOOOOOOOOO 0 0.0.0.0.... 0000...... 50505050505050505050505050505050505050505050505050505050 ‘5566778899001122334455667788990011223344556677889900112 Ooooooooooooooooooooooono...cocoooooooooooooooooooo.0000 11111111111222222222222222222223333333333333333333344444 11111111111111111.111111111111111111111111111111111111111 999 07 :681 938384073 08 64210999990123579247037159377273940 307752 963185308531864197531864209753197642197642196832098 99888777766665555444433333222221111100000099999988888877 22222222222222222222222222222222222222222211111111111111 00000000000000000000000000000000000000000000000000000000 00......OOOOOOOOOOOOOOOCOOOOOOOOCOOIOOOOOOOOOOOOOO0.0... 05050505050505050505050505050505050505050505050500505050 66778899001122334455667788990011223344556677889901122334 .0...I...OOOOOOOOOOOOOOOOOOOOOO0.0.0.0...I...0.0.0.0.... 88888888999999999999999999990000000000000000000011111111 1111111111111111111111111111 Table A-2 continued. 75 aR aR 0R W 1'7 W 1.7 W 1:2 17.05 .00865 19.05 .00708—7 21.05 .U039T‘ 17.10 .00860 19.10 .00704 21.10 .00588 17.15 .00856 19.15 .00701 21.15 .00586 17.20 .00851 19.20 .00698 21.20 .00583 17.25 .00847 19.25 .00695 21.25 .00581 17.30 .00842 19.30 .00691 21.30 .00578 17.35 .00838 19.35 .00688 21.35 .00576 17.40 .00834 19.40 .00685 21.40 .00573 17.45 .00829 19.45 .00682 21.45 .00571 17.50 .00825 19.50 .00679 21.50 .00569 17.55 .00821 19.55 .00675 21.55 .00566 17.60 .00817 19.60 .00672 21.60 .00564 17.65 .00812 19.65 .00669 21.65 .00562 17.70 .00808 19.70 .00666 21.70 .00559 17.75 .00804 19.75 .00663 21.75 .00557 17.80 .00800 19.80 .00660 21.80 .00555 17.85 .00796 19.85 .00657 21.85 .00552 17.90 .00792 19.90 .00654 21.90 .00550 17.95 .00788 19.95 .00651 21.95 .00548 18.00 .00784 20.00 .00648 22.00 .00545 18.05 .00780 20.05 .00645 22.05 .00543 18.10 .00776 20.10 .00642 22.10 .00541 18.15 .00772 20.15 .00639 22.15 .00539 18.20 .00769 20.20 .00637 22.20 .00537 18.25 .00765 20.25 .00634 22.25 .00534 18.30 .00761 20.30 .00631 22.30 .00532 18.35 .00757 20.35 .00628 22.35 .00530 18.40 .00754 20.40 .00625 22.40 .00528 18.45 .00750 20.45 .00623 22.45 .00526 18.50 .00746 20.50 .00620 22.50 .00524 18.55 .00743 20.55 .00617 22.55 .00522 18.60 .00739 20.60 .00614 22.60 .00519 18.65 .00735 20.65 .00612 22.65 .00517 18.70 .00732 20.70 .00609 22.70 .00515 18.75 .00728 20.75 .00606 22.75 .00513 18.80 .00725 20.80 .00604 22.80 .00511 18.85 .00721 20.85 .00601 22.85 .00509 18.90 .00718 20.90 .00599 22.90 _.00507 18.95 .00715 20.95 .00596 22.95 .00505 19.00 .00711 21.00 .00593 23.00 .00503 76 in equation 3 D Values of 2 at different values of Table A-3. (loge 22 + %) 1 227 .u—D 00 ED 05 _ 1 EH I.- Iu.u!!illv|b. 988914949642112469372740864333457914826161740853198 05051.6172840628006396296296307418530752075208531964 877665544333221110099988877776665555444433332222111 333333333333333333322222222222222222222222222222222 000000000000000000000000000000000000000000000000000 050505050505050505050505050505050505050505050505050 112233445566778899001122334455667788990011223344556 666666666666666666777777777777777777778888888888888 921796981920176077188176718781754605212483087803841 9.01247049395174297643322233457802479258148259382616 097531086532198754321098765432110987765543321100998 988888877777766666666655555555555444444444444444333 000000000000000000000000000000000000000000000000000 000000000000.O.0.00..OOOOOOOOOOOOOOOOOOOO0000.00.00 505050505050505050505050505050505050505050505050505 566778899001122334455667788990011223344556677889900 333333333444444444444444444445555555555555555555566 45.4227149713889513785302974994209724252361741849943 265978396428243918079558447201495457163101259395310 373099137284209899124703715050506284174185296419753 1864198663109865‘332100988776655‘433322211100009999 544443333333222222222221111111111111111111111110000 on0000000000.coo.00000000000000.0000...000000000000 n505050505050505050505050505050505050505050505050so 001122334455667788990011223344556677889900112233445 111111111111111111112222222222222222222233333333333 77 Table A-3 continued. . 00 GE 05 rEctiuilil 790135680246813681369258148158259 21.11098766503221099876654032210098 222211111111111100000000000000099 1.11111111111111111111111111111100 000000000000000000000000000000000 00000000000000.0000...-oooooooooo 505050505050505050505050505050505 900112233445566778899001122334455 000000000000000000000000000000000 122222222222222222222333333333333 111111111111111111111111111111111 297419753108765432211111112234456 865431098764321098765432109876543 555555544444444433333333332222222 111111111111111111111111111111111 000000000000000000000000000000000 00000000000000.0000...ooooooooooo 050505050505050505050505050505050 334455667788990011223344556677889 0.....0.0.0...’.................. 000000000000001111111111111111111 111111111111111111111111111111111 7.76677891357925825938272738406296 208642087531986431986532097653200. 110000099999888888777777766666665 222227..21111111111111.11111111111111.. 000000000000000000000000000000000 50505050505050505050505050505 5 67788990011223344556677889900 1 00.00.000.00...0.0000000000000000 8888888999999999999999999990000 1111 0 1 78 Table A-4. Set #1, Experimental data of deformation force and moisture content. 1e Force at M.C. % Sample Force at M.C. % $335. 0.1" def. ‘W;B. No. 0.1" def. 'W.B. lbs . lbs . 1 50.4 88.3 47 25.0 83.9 2 49.2 87-5 48 25.0 86.4 3 49.0 87.5 49 25.0 87.2 4 47.5 87.5 50 24.2 83.9 5 47.2 88.0 51 23.8 85.4 6 46.3 88.7 52 23.5 86.2 7 44.5 89.1 53 21.4 84.4 8 44.4 89.1 54 21.0 84.7 9 43.0 88.3 55 21.0 86.2 10 43.0 88.3 56 19.4 85.7 11 42.0 87.0 57 19.0 85.4 12 42.0 86.0 58 17.0 85.7 13 41.5 87.9 59 16.0 84.7 14 41.4 89.9 60 15,7 85.5 15 41.0 85.8 61 15.5 84.2 16 40.7 87.9 62 15.4 83.7 17 40.0 89.4 63 15.0 85.7 18 39.0 86-7 64 14.4 85.2 19 38.3 86.6 65 13,0 84.2 20 38.0 87.7 66 13.0 85.2 21 38.0 87-7 67 12.5 85.5 22 38.0 89.6 68 12.5 85.7 23 38.0 86.6 69 11.6 83.7 24 37.5 86.7 70 11.5 82.3 25 37.0 86.7 71 11.3 85.1 26 37.0 86.6 72 11.0 83.4 27 37.0 87.7 73 10.7 85.5 28 36.0 89.2 74 10.3 82.7 29 36.0 86.0 75 10.0 84.7 30 35.0 87.7 76 10.0 85.1 31 34.4 85.3 77 10.0 84.8 32 34.2 87.2 78 9.5 81.1 33 32.0 87.2 79 9.5 82.7 34 32.0 85.3 80 8.5 81.8 35 32.0 86.6 81 8.2 84.0 36 30.0 85.6 82 8.0 82.5 37 30.0 83.9 83 7.5 85.1 38 28.7 85.6 84 7.5 84.3 39 28.6 86.2 85 7.4 79.3 40 28.0 86.2 86 6.6 82.3 41 27 0 87.2 87 6.7 81.8 42 26 4 86.4 88 6.3 81.0 43 26 0 86.4 89 6.0 84.8 44 25 8 86.2 90 5.9 80.4 45 25 3 84.0 91 5.7 81.1 46 25 0 85.3 92 5.4 81.0 79 Table A-4 continued. Sample Force at M.C.% Sample Force at M.C.% No. 0.1" def. ‘W.B. No. 0.1" def. W;B. lbs. lbs. 93 5.0 81.1 116 2.9 74.5 94 4.5 81.1 117 2.8 76.6 95 4.5 73.9 118 2.8 79.6 96 4.2 82.4 119 2.5 79.6 97 4.0 80.4 120 2.5 72.3 98 4.0 66.7 121 2.5 78.4 99 4.0 75.4 122 2.4 73.4 100 4.0 79.1 123 2.4 74.1 101 4.0 78.9 124 2.3 75.2 102 4.2 76.1 125 2.3 71.0 103 3.8 84.0 126 2.2 77.8 104 3.7 84.8 127 2.0 73.9 105 3.6 81.1 128 1.8 77.4 106 3.7 75.5 129 1.8 69.8 107 3.5 81.0 130 1.8 78.1 108 3.5 79.0 131 1.6 75.2 109 3.5 71.1 132 1.6 64.7 110 3.3 77.9 133 1.5 75.2 111 3.2 72.4 134 1.5 76.9 112 3.1 75.0 135 1.5 73.9 113 3.0 82.4 136 1.5 77.8 114 3.0 75.0 137 1.5 75.7 115 3.0 79.2 138 1.0 73.0 80 Table.A-5. Set #2, Experbnental data of deformation force and moisture content. Sample Force at ‘M.C.% Sample Force at iM.C.% No. 0.1" def. 'W.B. No. 0.1" def. ‘W.B. lbs. lbs. 1 52.0 87.1 36 14.5 79.4 2 47.0 87.9 37 14.0 79.8 3 46.0 86.0 38 13.0 82.5 4 45.0 87.1 39 13.0 80.0 5 45.0 87.6 40 11.5 78.7 6 42.0 85.6 41 11.0 76.2 7 42.0 85.7 42 11.0 81.4 8 40.0 86.1 43 10.0 80.4 9 36.0 84.3 44 9.5 79.8 10 35.0 83.7 45 9.5 81.1 11 35.0 86.2 46 9.0 79.5 12 34.0 83.6 47 9.0 78.1 13 33.0 82.4 48 8.5 78.6 14 32.5 81.9 49 7.0 78.7 15 32.0 85.2 50 6.5 79.5 16 32.0 83.3 51 6.5 79.2 17 28.0 80.7 52 6.5 79.4 18 26.0 85.3 53 6.0 77.0 19 24.0 84.0 54 5.8 79.6 20 23.0 80.2 55 5.6 70.6 21 23.5 81.0 56 5.6 75.3 22 20.0 83.5 57 5.0 79.7 23 19.5 82.1 58 4.5 78.0 24 19.5 84.7 59 4.3 75.4 25 19.0 79.7 60 4.1 79.3 26 18.5 84.6 61 3.7 74.6 27 18.0 82.4 62 3.6 76.6 28 18.0 82.2 63 3.5 75.7 29 17.0 81.0 64 2.8 75.8 30 16.0 80.3 65 2.5 74.0 31 16.0 80.9 66 2.2 74.0 32 16.0 76.8 67 2.1 75.2 33 16.0 81.8 68 1.7 72.9 34 15.5 80.5 69 1.7 70.7 35 15.0 82.5 70 1.4 73.2 IT— 81 Table A-6. Set #1, Average deformation force and moisture content of samples grouped according to force range. Force Range Ave. Force .Ave.iM.C.% lbs. ‘W.B. 50 - to 40 43.4 88.2 39.9 to 35 37.2 87.4 34.9 to 30 33.3 86.5 29.9 to 25 26.6 85.6 24.9 to 20 21.4 84.9 19.9 to 15 16.8 84.4 14.9 to 10 13.7 83.7 9.9 to 7 8.5 82.4 6.9 to 4 4.8 78.6 3.9 to 2 2.9 75.8 1.9 to 0 1.7 74.4 5.1‘1'fl-w" . .— Table A-7. Set #2,.Average deformation ferce and moisture content of samples grouped according to force range. Force Range Ave. Force Ave. M.C.% lbs. ‘W.B. 50 - to 40 45.0 86.6 39.9 to 35 35.3 84.7 34.9 to 30 32.7 83.3 29.9 to 25 27.0 83.0 24.9 to 20 22.6 82.2 19.9 to 15 17.2 81.5 14.9 to 10 12.3 79.8 9.9 to 7 8.8 79.3 6.9 to 4 5.5 77.7 3.9 to 2 2.9 75.1 1.9 to 0 1.5 72.5 82 rue- mom Ham omm o.oa o.ov mam Nwm mmm 5H.m mm.e mo.o oa.o e.HH o.Hm m.o o.H Hem 5mm owe n.HH o.- mmv mom mom N.n c.5H mum mwv mow m.m w.vH m~v ovm mme n.oa 0.0H mmm mmm mom NH.m Nv.m mo.o mmo.o m.o o.m o.H o.H mo.o cam .1. o.Hw mmm mmm mam m.v~ o.om mmv How «am w.wH N.uo ewe nee new wm.m om.~ H.o o~.o N.~N H.wo m.o o.H mom mom wmm c.5H o.m~ omm owm mNm N.n~ N.me omm mvm NNN m.HH m.n~ emu mmv mac wm.m om.o H.o mo.o m.H~ o.mm o.H o.H H.o an an «8 a up 5}: £ 65 8.: .05 S. E N z a m8 a m A a 8 8.8 3.8303 80.8 ma < .w H u mm .Ibll 84 u «m .INHII mmmé 1 am . . A m NNAm MNZXH "mcowumsvo may wofims cofiumsuomoo vow meufim ooswooom coupon unmu0MMflw How m we m03Hm> voomH20Hmu may .m.<.w~cm~ 83 .. 666 664 6.6 .1 66m 654 666 6.4 6.4 566 666 666 4.6 6.5 6N6 666 66~ 66.5 66.66 666.6 6666.6 6.6 6.4 6.6 6.6 666.6 664 664 664 6.66 6.6 644 664 664 6.66 6.6 664 564 664 6.66 6.6 664 N64 664 46.6 66.6 6.6 666.6 6.66 6.6 6.6 6.6 664 464 666 6.66 6.4 644 664 666 4.66 4.4 666 464 N66 6.66 6.6 664 466 666 46.6 66.66 6.6 6666.6 5.66 6.4 6.6 6.6 644 i. I. .1. 6.46 666 656 N66 6.66 6.64 644 666 BN4 56.6 66.4 66.6 66.6 6.66 6.66 6.6 6.6 66.6 666 666 666 N 6. .m. .ww _:6\6H 66 60:6 6066 .6066 mm am am 6 .6 a 6 6 4 .666666660 6-<.6H646 .wouuommu no: m6 66 u m6 n m6 coop .66.6m v 6m 066 6m 00:66 6 6.6 1 66.66 606660 6066 84 mo . I m.mom u N I N 6.666 66.666 46.66 1 6 66 66666 66666 6666 u 66 66.6 a _MMhmnI.u MI." 60 664 664 664 "68: 6.666 m6 666 I. I. I. 6.6 666 666 664 4.6 6.6 664 466 666 6.6 6.4 466 664 666 66.6 64.6 666.6 666.6 6.4 6.6 6.6 6.6 666 666 666 6.6 6.6 644 664 644 6.4 6.6 666 664 666 66.6 64.66 666.6 66666.6 6.4 6.6 6.6 6.6 How omn awe N 0 com H64 mom o.¢ v.HH com 66m hem mw.n cm.o mmc.o omo.o N m m.HH m.o o.H mNo.o 6mm 6mm 6mg 0 o N z 66. 66\66 66 6066 6066 6066 mm mm 66 do \m m A a a 5“: .ooscauaou mn< oHomH 85 .‘il" .1234. po‘rL-r. ‘ -‘1.". Table Ar9. Experimental and calculated points for force-time relaxation curves at different moisture contents. 86.6% M.C. _ 84.7% M.C.' Point 1119, lbs t’ F t lbs t’ Pipefimental Calculated sec rmenta Ca cu ate sec 1 45.0 44.7 0.0 35.4 35.4 0.0 2 42.7 42.7 0.12 35.0 35.4 0.0 3 41.2 41.4 0.24 33.5 33.5 0.15 4 39.8 39.8 0.48 32.6 32.6 0.27 5 39.0 38.9 0.72 31.6 31.6 0.51 6 37.7 37.8 1.32 30.4 30.5 1.11 7 37.0 37.1 1.92 29.9 29.8 1.71 8 36.1 36.1 3.12 29.0 29.0 2.91 9 35.1 35.0 5.52 28.3 28.3 4.71 10 34.5 34.5 7.92 27.8 27.8 7.11 11 34.0 34.2 10.32 27.2 27.3 10.71 12 33.0 33.0 21.12 26.1 26.6 16.71 83.3% M.C. 83.9% M.C. Point F(t), lbs t’ F(t). lbs t’ Experifiental ‘Calculated sec Experimental Calculatéaf sec 1 34.0 33.7 0.0 27.4 27.1 0.0 2 33.0 33.2 0.04 26.2 26.2 0.10 3 32.0 32.0 0.16 25.4 25.4 0.22 4 30.7 30.7 0.40 24.5 24.4 0.46 5 30.0 30.0 0.64 23.7 23.6 0.82 6 29.1 29.1 1.24 23.0 23.0 1.42 7 28.1 28.2 2.44 22.6 22.6 2.02 8 27.6 27.6 3.64 22.1 22.0 3.22 9 27.0 26.9 6.04 21.5 21.6 4.42 10 26.4 26.4 9.64 21.2 21.1 6.82 11 25.8 25.9 15.64 20.5 20.5 11.62 12 25.1 25.1 27.64 19.9 19.9 22.47 86 Table A-9 continued. 82.2% M.C. 81.5% M.C. Point F(t), lbs F(tj} lbs Experimental Calculatedf sec Experimental Calculated sec 1 24.0 23.8 0.0 16.3 16.3 0.0 2 23.1 23.1 0.10 15.5 15.4 0.11 3 22.3 22.4 0.22 14.9 14.8 0.23 4 21.6 21.6 0.46 14.1 14.0 0.47 S 21.0 21.0 0.70 13.7 13.6 0.71 6 20.4 20.4 1.06 13.1 13.0 1.31 7 19.6 19.5 2.26 12.8 12.7 1.91 8 19.0 19.0 3.46 12.4 12.3 3.11 9 18.4 18.4 5.86 12.1 12.0 4.61 10 18.0 18.0 8.26 11.6 11.4 9.41 11 17.7 17.7 11.86 11.0 11.0 17.21 12 17.0 17.0 21.46 10.7 10.6 26.81 79.8% M. C. 79.3% M.C. Point F111; lbs t’ Fit), lbs t’ Experimental calculated sec Experimental Calculatedi sec 1 12.5 12.4 0.0 8.5 8.3 0.0 2 11.5 11.5 0.12 7.9 8.0 0.06 3 11.0 11.0 0.24 7.5 7.5 0.18 4 10.4 10.4 0.48 7.0 7.0 0.42 5 10.0 10.0 0.84 6.5 6.5 0.90 6 9.7 9.7 1.32 6.3 6.3 1.38 7 9.4 9.4 1.92 6.0 6-0 2.22 8 9.0 9.0 3.72 5.8 5.8 3.06 9 8.7 8.7 5.52 5.5 5.5 5.46 10 8.5 8.5 9.12 5.3 5.3 7.86 11 8.3 8.3 13.92 5.1 5.1 12.66 12 8.0 8.0 22.32 4.7 4.7 24.66 87 Table.A-9 continued. 75.1%7M.CC’ 77.7% NLC. 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