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III III III III IIIIII III IIII |I|I IIII IIII II III III III mm A R y ' Michigan State University This is to certify that the thesis entitled DOLOMITIZATION PATTERNS IN THE WALKER OIL FIELD, KENT AND OTTAWA COUNTIES, MICHIGAN presented by Richard J. Hamrick has been accepted towards fulfillment of the requirements for Mo So degree in GeOlogY W Major professor Date 7724/0/00. /77c9 / J 0-7639 W o - as C! JAN 0 9 2005 x" ' DOLOMITIZATION PATTERNS IN THE WALKER OIL FIELD, KENT AND OTTAWA COUNTIES, MICHIGAN By Richard J: Hamrick A THESIS Submitted to Michigan State University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Department of Geology 1978 ABSTRACT DOLOMITIZATION PATTERNS IN THE WALKER OIL FIELD, KENT AND OTTAWA COUNTIES, MICHIGAN By Richard J. Hamrick A study of the Walker Oil Field was undertaken to achieve better understanding about the origin of dolomite in Devonian reservoir rocks and its relationship to struc- tural configuration. Carbonate samples from producing and nonproducing Traverse Limestone wells were analyzed by the powdered x-ray diffraction method to determine dolomite percentages from various depth intervals. It was found that the highest degree of dolomitization from the upper Traverse Limestone occurred at or near the top of the formation. The degree of epigenetic dolomitization shows a general correlation with the structural contour map developed on the top of the Traverse Limestone. The geometry of folds and distribution of dolomite percentages suggest relationship to faulting. Folding, faulting, and solution activity are the major causes for secondary porosity in the Traverse Limestone pay zone(s). Carbonate and evaporite facies of the Traverse Limestone appears to be related to the hypothesized West Michigan Barrier (early diagenetic dolomite). ACKNOWLEDGMENTS The writer wishes to express his sincere thanks to Dr. C. E. Prouty, Chairmanof the Guidance Committee, for his devotion of time and interest in this problem and for his helpful suggestions and constructive criticism in re- viewing this manuscript. Thanks are also extended to Dr. James W. Trow and Dr. John T. Wilband for their helpful advice and review of the thesis text and illustrations. Foremost appreciation must go to my wife Paulette for her love and friendship throughout this time of trials and tribulation. Her patience, understanding, and encour- agement made completion of this work possible. ii TABLE OF CONTENTS LIST OF TABLES . . . . . . . . . . . . . . . . LIST OF FIGURES . . . . . . . . . . . . . . . . INTRODUCTION . . . . . . . . . . . . . . . . . General Statement . . . . . . . . . . . . . Purpose and Scope Previous Work . . . . . . . . . . . . . . . O O O O O O O ‘ C O O O O . STRATIGRAPHIC FRAMEWORK . . . . . . . . . . . . STRUCTURAL FRAMEWORK . . . . . . . . . . . . . THE WAIKER 0 IL FIELD O I O O O O O O O O C O 0 Location and Extent . History of Development Production . . . . . . Lithology . . . . . . . Structure . . . . . . . LIMESTONE AND DOLOMITE ANALYSES . . . . . . . . Experimental Procedures . . . . . . . . . . Source of Samples . . . . . Sample Study . . . . . . . Well Sample Preparation . . X-Ray Diffraction Procedure The Method . . . . . . . . . . . Standardization Sample Preparation Procedure . . . . . . . . . . . . . Calibration Curve . . . . . . . . . . . Data Calculation . . . . . . . . . . . Data Interpretation . . . . . . . . . . . . Vertical Dolomite Variation . . . . . . Lateral Dolomite Variation . . . . . . iii Page vi H \OKRUNH 16 16 18 19 20 25 25 25 27 27 28 29 30 31 32 34 3h 37 Walker Field Dolomitization Models CONCLUSIONS . . . . . . . . . . . . . BIBLIOGRAPHY . . . . . . . . . . . . APPENDICES . . . . . . . . . . . . . Appendix I. Sample Well Descriptions Appendix II. List of Wells Used in Study Appendix III. Dolomite Percent from Traverse Limestone iv Page 47 57 59 65 65 67 83 LIST OF TABLES Table Page 1. Different Components Used for Standardization . . 30 LIST OF FIGURES Figure 10. 11. 12. 13. 14. 150 16. Stratigraphic Succession in Michigan . . Regional Structure Map of Michigan and EnVironS I I I I I I I I I I I I I I I Regional Structure Map of Michigan with Important Linear Structures . . . . . . Major Structural Trends in the Michigan BaSin I I I I I I I I I I I I I I I I I Southwestern Michigan Oil and Gas Fields Location of Walker Oil Field in Michigan Well Location Map . . . . . . . . . . . . Structure Map on the Top of the Traverse Limestone . . . . . . . . . . . . . . . Calibration Curve of Dolomite Percent . . Typical Vertical Dolomitization Patterns in the Traverse Limestone . . . . . . . Average Vertical Dolomitization Patterns in the Traverse Limestone . . . . . . . Dolomite Ratio Map - 0-5 Feet Below the Top of the Traverse Limestone . . . . . Dolomite Ratio Map - 5-10 Feet Below the Top of the Traverse Limestone . . . . . Dolomite Ratio Map - 10-20 Feet Below the Top of the Traverse Limestone . . . . . Dolomite Ratio Map - 20-30 Feet Below the Top of the Traverse Limestone . . . . . West Michigan Barrier Axes . . . . . . . vi Page 10 13 14 15 17 21 23 33 35 36 39 41 43 45 54 INTRODUCTION General Statement Petroleum production has been actively developed in the southwestern portion of the Michigan Basin, a substan- tial amount of which has been developed from the dolomitized Traverse Limestone of Middle Devonian age. Porosity in this dolomitic limestone has developed because of either strati- graphically controlled, early diagenetic dolomitization or epigenetic (post consolidation) dolomite formed by fluids introduced along faults and fractures. Many geologists contend that dolomitic limestone has a tendency to develop along bedding planes, joints, frac- tures, and faults within limestone formations (Landes, 1946; Powell, 1950; Jodry, 1954; Goodrich, 1957; Egleston, 1958; Jackson, 1958; Paris, 1977; Dastanpour, 1977). A number of geologists have demonstrated that wide- spread dolomitic facies have developed along shallow epi- continental shelves and carbonate platform areas (Prouty, 1948; Cohee and Landes, 1958; Adams and Rhodes, 1960; Deffeyes et al., 1965; Illing et al., 1965; Bathurst, 1971). And others have proposed the development of dolomitization related to persistently emergent areas or structural highs 2 (Hanshaw, et al., 1971; Badiozamani, 1973; Land, 1973). Purpose and Scope The Walker Oil Field of Kent and Ottawa Counties, Michigan has been a prolific Traverse Limestone oil reser- voir, producing over 17 million barrels of oil. This field was chosen as the area of study because the region has a well defined structure with accessible well samples. It is the purpose of this study to; (1) establish the occurrence of dolomitization in the Traverse Limestone petroleum producing zone (implies porosity and permeabil— ity), and (2) examine the distribution of dolomite relative to the field structure. Also of importance will be a valid attempt to put forth mechanism(s) which could have produced dolomitization within the Traverse Limestone of the Walker Field. Structural interpretations will be made from maps based on contacts established through microscopic examina- tion of well samples. Dolomite percentages will be deter- mined by comparative quantitative x-ray diffraction analysis of various well samples and will be vertically represented via bar graphs and laterally displayed by dolomite/lime- stone ratio maps representing different depth horizons below the top of the Traverse Limestone. The dolomite percentage bar graphs and maps will be compared with the structural map on the top of the Traverse Limestone to delineate relation- ships. 3 It is the hope and purpose of this writer that the results of this study will provide helpful information re- garding the nature and characteristics of linear-producing fields and aid future oil and gas exploration and produc- tion programs in Michigan. Previous Work There have been a number of studies related to this area of research. Chemical analyses demonstrating CaC03/ MgCa(CO3)2 ratios, following suggestions by Landes (1946) in regard to local dolomitization, was first done in the Mich— igan Basin by Powell (1950) from the Rogers City-Dundee formations. Jodry (1954) utilized the titration method for determining the Mg/Ca ratios of well samples, comparing the data with several producing oil fields in Mecosta County. In the studies of Tinklepaugh (1957), Jackson (1958), and Dastanpour (1977), a definite relationship was observed be— tween the degree of dolomitization and structural form. Young (1955) and Egleston (1958) compared their Mg/Ca ratios with structural maps in Stony Lake and Winfield Fields, res- pectively, but were not impressed with such correlations in their studies. Recent dolomitization studies from semiquantitative analyses in Michigan were made by Newhart (1976) on the Middle Ordovician, Runyon (1976) on the Traverse Group, and Syrjamaki (1977) on the Lower Ordovician. These studies, 4 along with that of Dastanpour (1977), have established the existence of two types of dolomite: stratigraphic (diage- netic) and secondary (epigenetic). A number of studies have been made related to the Traverse Group in Michigan. Isopach maps of the Traverse Group were first published by Newcombe (1933). Later, Cohee (1947) provided a more accurate estimate of Devonian thick- ness along with a structure contour map based on the avail- able well records to 1947 which penetrated the entire Tra- verse Group section. Henry (1949) studied the Traverse Group in the Pent- water Oil Field and believed the Traverse pay to be part of a Devonian reef structure. An investigation of the Traverse Group in the Lansing area was made by Gustafson (1960), who generated structural and isopach maps of this area. Fisher (1969) examined the Traverse Formation, the top unit of the Traverse Group, and developed a structure contour map on the top of the Traverse Formation. Gardener (1974) suggests the Traverse Group represents interfingering of proximal bio- stromal and biohermal shelf carbonates on the west with dis- tal fossiliferous gray muds to the east. STRATIGRAPHIC FRAMEWORK The stratigraphic sequence of rock lithologies im- portant to this study is Middle Devonian age. Rock units representing this geologic time span on the southwestern side of the Michigan Basin are the Traverse Group and the Rogers City and Dundee formations (Figure 1). The Traverse Group with the Bell Shale formation at the base lies conformably on the top of the Rogers City for- mation (Cohee and Underwood, 1945). The Traverse Group is divided into three major units by Cohee (1944): the upper Traverse Formation, the middle Traverse Limestone, and the lower Bell Shale. Fisher (1969) considered the Traverse Formation to be a legitimate stratigraphic formational unit and recom- mended its inclusion as part of the Michigan stratigraphic column. He described the Traverse Formation as a calcar- eous, medium gray shale and shaley limestone which is a transition zone between the Traverse Limestone of Middle Devonian age and the Antrim Shale of probable Upper Devon- ian age. Cohee (1947) described the lithology of the Traverse Group in the Michigan Basin as argillaceous limestone, shales, and some pure limestone in eastern Michigan grading 11s1s1ocm1~rw 1111111.. STRATIGRAPHIC SUCCESSION IN MICHIGAN '1 elnfitg 1. 1 1.1 A; .1A.11111111 .A. A A 11. Chuch D11II 11A. .1. .11 n.114...11m11.4M.1.1.1-. .04 ..A 1Aw.11..1111 GEOLOGIC NAMI') (OMMIHH KIMER‘DGIAN Lad-adv H1. (hpvmm K..k..11 v. A 1 A. .1 5115111111.. UAW 11.1.1 1 Mud-"hm. 1 a... 1.1.1. 1.1,... ERA SYSTEM SERIES STAGE RECENT 2 “1.4.1 PALEOZOIC THROUGH RECENT 2 Wmomm 1Aok(1..1. 211.1%“. ‘ aw . Man m: 5 r Hut ")1 \ O QUATERNARY FLEISTOCENL G‘M'm" C 21.11.” 0 :‘i‘: 1 m 2 ‘ 1.. A.11 m.- “2.11.15: (“2.1/4 Ci' LU .mqmon Immwammn gig) U 111111111111 0111111110 , .,1 P1 '1. ‘\1_, in OUTCROP NOMENCLATURE SUBSURFACE NOMENCLATURE (+ MICHIGAN DiPARTIENT OF NATURAL RESOURCES F“ [1le smumnanmo ROCK STRATIGRAPHIC Rock smmcmpmc mm mm" 11.1.1111 0Q FORMATION IMEMBER GROUP nrniomcusulm nmsmu Pi SERIES GROUP FORMATION MEMBER 11.1.1u111111. 114.111.111.111...” 1.1.1.1 .11 1.11 .11111me'm'“ m DOMINANI WHOIOGV 111 Ma xubimlnu N0 5: All “mow manna tum-.4 A11A1A. “A," 14 .111... 1. 11.11.111.41 1A. .1 x 1.. :3‘ p... O U) INFORMAL TERMS I 11111111DA1.111 .11..A 1,111.11 .1111 1A1111111111 1.11.11 111u111,1.11.111-11111 CONEMAUGH " QM kw h“ “AL. .1101 .11: 1.11115 11 11.1111 .14 111111.1111111. 1,1 .11111111 111 1111 11111 11I... O‘\ I UOISSSOOH . STKATIORAPHIC ROSITIQN lNIJRM-‘xl ”RM: PAY} pony/111; 3.11.... 1.. 9.1.1 1.11141111A.1 .11 5.911111». 1111 ,7, 11.1... 1.....11AA . MERAMECIAN (11111411 RAPID; 1 , w 11 10A,. 1w M :3 ~11.qu rm M1J11an 1 c... g s; .1 1.... 0,1 M..1111.111 s1 _:..1 1 0.1 i‘" (1.1.11.1111 51 111.1... O (A1aA.11.~1 51 I I A. _ ‘— 0.. 1113111, 1.11.»... A... 11.11.11 1.1.1119... 1A up11.1 1.1-1 D1 . [IIwvaI' SI M111. M1- J! _o11a 1,... 111111111 311 me s1 . 1. 11..1.111A.,A,1 _01IA 13A. Squww Bl!) lx hAn- N1 _— 01' A En IAJ 0‘2 51: :3 Hum-1 w" “I \ 11m.» 1.A11.1.11 1AA 011 1. 12.1 I \1,1.-1 1.1. ,1... __011 A (1.1 T111vr-1u-(11011p1r 111...... C11. 11 011; A“ Aipl-na 11 Dundee 11 011:. 6.1 TRAVERSE Dundee I~ 7 Uppr' 9.11101 1111.11 1111 11 — A... 111 1A. 0113 c». 111111.11- 111. °“ ‘ ““ I 1:". AZ 1: 11A1..A_11. 01150.1 1) r AAAAAmg 11. 1.11 11.. t 11011 RIVER ULSTERIAN p.111 5.111111 1 , 010111 E 111111 . 11 911 U1v1=11m (1| A I 1:114..- 1 1111.4 1A1 Cmbonnr . 5.1 1A. 11.11 1.11111.” , - 51.11.011.11. 1 1111A 1. —011 1 5.. ans: 151mb: ISLANDS Unpr‘ 9.111 111 A. A...” 1 11 1 11 141.111.11.111 Sent) _ _ I ,1.,A.1.1. \ ° “ CAYUGAN I .111. x a. . v11. .1111 (11111.1 511 (A11. .A.1. p.111 1.1 141.11.11.11 5.11.. 1.1.1 AAA... r1en11111(.1u11p Q11 A z... 1 11..1 51.4 wa mm 1.11 11.1 0.11 r... I .. v1.1» 11-. 01.1.1115 DoI 011 NIAGARAN EXPLANATION MANTSTIQUT lmwnmvc BURNT awn . 1.41 (111.11 111.». 51 1A.", ALEXANDRIAN (1111111110 9‘ 'I‘ “mam. A1wIm-1A11 "I 1:11.11: 11.11 3.11111Ag1m 1m CINCINNATI/AN 121011.1wa 11.11. 11.111 111-91 511 A... "1.11.1 "“ .. 111mm. 11.1.1.1. 1131141014 1“” MONAWXMN (mam 1.111.111 BLACK RIVER am 1.1111111. WI CANADIAN ”wan DU (111: W MEN AAA... 1:: Tvemwxiuu 1111 ST CRDIXAN LAKE SUPERIOR SUPERIOR (Mm Mummy 1... (WA... 1,111.... 1A.11 lacobiwlle s. G|OAOCIL 1mm COWILAVIONS 11.1 o 11...». (.111... AA 0.111....» 11.1.11 w Jazuberla S1 1. 1114 1.1114141. 541..» (AA-"d D 111. 1... >441.» 11.1qu 0.11... 11». em: 1“ 1:.“ .,. .1. 1 1....... . 1A....1...1..A .1... MA 1...... 5.1.11. 1......1 AA. 1 .41 A1... .AsA.A1A1...,A»A MA..11.A..A111..1. 1 w.11.1.1..,1.1,.1 1 4 m. m. CHART 1 1964 mm 111-11.. 1111 7 to the west into calcareous shales with the limestone becom- ing more pure until the whole group becomes relatively pure limestones in western Michigan with some dolomite and dolo- mitic and argillaceous limestone. Jodry (1957) recognized a lagoonal dolomitic facies in Western Michigan and open sea facies east of a line at about the position of the Walker Field today. The ”barrier" bringing about this facies change was believed to reflect a high in the Precambrian basement. Runyon (1976) recognized a similar facies distri- bution in his semiquantitative study of the dolomite and limestone of the Traverse Group. More will be said in this regard later. The lower Bell Shale formation of the Traverse Group thins and disappears in much of the western and southwestern portions of Michigan, so that the middle Traverse Limestones rest directly on top of the Rogers City-Dundee limestones. When present in the subsurface, the Bell Shale is typically a soft, fossiliferous, gray shale (Jodry, 1957). Cohee and Underwood (1945) stated that the Rogers City and Dundee formations in the central part of the Michi- gan Basin were composed of dolomite and limestone, whereas in the far westcentral and southwestern area it is predomin- antly dolomite. They also went on to state that although easily recognizable on the eastern side of the Michigan Basin, the Rogers City and Dundee formations in the west- central and western side of the Basin are relatively indis- tinquishable in subsurface due to similar lithology. 8 The Traverse Limestone, for purposes of this study, is that interval between the top of the Bell Shale (if pre- sent) and the base of the Traverse Formation. STRUCTURAL FRAMEWORK The Michigan Basin is a roughly circular and symme- trical structural and sedimentary basin in the Central In- terior platform of the United States. It encompasses the Southern Peninsula and the eastern part of the Northern Pen- insula of Michigan, Eastern Wisconsin, the northeast corner of Illinois, Northern Indiana, Northwest Ohio and portions of Ontario bordering Lake Huron, Lake St. Clair, and the western end of Lake Erie (Cohee and Landes, 1958). Border- ing the Basin is the Algonquin Arch to the east (Ontario), the Findlay Arch to the southeast (NW Ohio), the Kankakee Arch to the southwest (N. Indiana), the Wisconsin Arch to the west (C. Wisconsin) and the Canadian Shield to the north and northeast (Figure 2). A number of theories have been postulated concerning the origin of the Michigan Basin. Pirtle (1932) thought the Basin probably originated in Precambrian time. He believed the Wisconsin and Kankakee Arches were the cores of Precam— brian mountains that stretched from central Wisconsin to NW Indiana and that principle folds that now exist in later sedimentary rocks were controlled by trends of folding or lines of structural weakness that existed in basement rocks. Folding by compression was most intense in Mississippian 10 CANADA / LAKE SuPERIOR ‘ UPPER WISCONSIN DOME ‘ ' 1 C 3 | g \ mscousm \ 3 <1 2 q MICHIGAN ; U own a: a? a ' <9“ 3. 2 J V _. |LLINOIS Figure 2 Regional Structure Map of Michigan and Environs 11 time. Newcombe (1933) also believed that the inherent structure of the Michigan Basin was of Keweenawan (Precam- brian) origin. He maintains that the present anticlinal trend (NW-SE) in the Basin was the result of reactions of zones of weakness developed in the basement during late Pre- cambrian disturbances to the northeast. Lockett (19A?) be- lieved downwarping of the Basin was caused by differential sedimentary loading, causing block faulting in the basement complex. He states that the parallel pattern of structural trends in the Basin conform along basic lines of weakness in the basement rock. Cohee and Landes (1958) claim that the incipient folding (NW-SE) occurred intermittently in the Paleozoic, with the main diastrophic activity during the Lower Mississippian—pre-Pennsylvanian emergence. Green (1957) stated that the Michigan and immediately surrounding basins sank while the present bordering structures remained stable, with the age of the Michigan Basin being Niagran. Utilizing both geophysical and geological data, Hinze and Merritt (1969) believe that a major rift zone (Mid-Michigan Gravity and Magnetic High) had a dominant role in the devel- opment of the Basin. The Basin may have originated from isostatic sinking in response to the added mass of Keweena- wan mafic rocks in the basement complex. Subsequent defor- mation within the Basin has been associated with movements along lines of basement weakness, apparently related to the rift zone. Prouty (1970) concludes that the basic structural 12 patterns of the Basin, including basement lineations and bordering structures, was inherited from the Upper Precam- brian. Structures within the Michigan Basin (Howell Anti- cline, Lucas-Monroe Monocline, Albion-Scipio trend, etc.) are generally thought to be fault controlled with the fault- ing developing along lines of weakness in the Precambrian basement rocks, Figure 3 (Ells, 1969; Fisher, 1969; Harding, 1974). Prouty (1976) believes that lineaments gleaned from LANDSAT imagery are faults which fit a wrenching deformation model and that the folded structures of the Michigan Basin are generally related to the faults of this wrench system (Figure A). From these lineaments, Prouty has demonstrated that many of the oil and gas fields of Michigan produce where fractures intersect (Figure 5). He indicates that it is in these cross-structures that dolomitization is apt to be most marked. Runyon (1976) states that the coincidence of the suggested faults in Ottawa and Kent Counties and Allegan County in crossing present day major structural trends and tending to fall on isolated oil fields, such as the giant Walker Field, suggest that these might also be cross-structures occurring after Traverse deposition and related to the origin of the major structural trends (Fig- ures h and 5). 13 #_ / L AKE \ ‘ summon ‘ CANADA UPPER WISCONSIN DOME WISCONSIN now "03$! ILLmous k mow“ omo 04 K41“? ¢ .0 0 am .0 a “PO, §v $5 tIEIEJIZZZZZJIIIIII \ I,::q;::apnuc::§:l-:n mg”. Figure 3 Regional Structure Map of Michigan with Important Linear Structures § (000.009 “VG-IA. ‘0 nun run a... '. 3‘ \ . ill 0—. 5 5X0“; . ‘ ,uu‘o'u n'v', “nu Q \L. 3.: ‘ ' Figure 4. Major Structural Trends in the Michigan Basin (compiled by C. E. Prouty, 1971) 15 Figure 5. Southwestern Michigan Oil and Gas Fields THE WALKER OIL FIELD Location and Extent The Walker Field is located in the western portion of the present greater Grand Rapids, Michigan area. It in- cludes sections 19, 20, and 27-35 of Walker Towship (T7N- R12W), Kent County; sections 2-9 of Wyoming Township (T6N- R12W), Kent County; Sections 13-15, 22-28, and 33-36 of Tallmadge Township (T7N-R13W), Ottawa County; and sections 1, 2, and 12 of Georgetown Township (T6N-R13W), Ottawa County (Figure 6). The Walker Field extends in a northwest-southeas- terly direction for a length of nearly eight miles, and is approximately four miles in width at its widest point. History of Development The way to the discovery and development of the Walker Field was pointed when the Salem Field in Allegan County showed a northeast trend in the direction of Grand Rapids. The area which ultimately became the field (Figure 5) was approximately at the intersection of the two trends determined by extending the main axes of the Salem and Mus- kegon Fields (Newcombe, 1939). The Grand River takes a broad southward meander around the area in which doming was 16 1 7 B 9 99 F S ‘ 1 4 I (an 4- ‘ lit? 1.. L [3‘0 - e V IcIIi'qvo-n. ‘1)..4. ' 1:21 .eatsouu .M_u--'_ c Ann‘od I ‘33- MJ 1 _T- $ -- __..__T__T.J... —‘- . — —' .1 6 I I: ' . , '- B I "I‘I-ir-I-L-Hi. “*"I' “II" . 8 . "I yam!!! Io Hammond‘s. "u I” ‘Amruu I 'w' ' 1 ‘L -. 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I I Q ' *5 __I 1 4" - )—1 —u— —u—-——---1)-— —0—- --u-- ’ ' 1 I , l J A-TQT— 11.4.1 .9 A --i 34;] \\_//’_\\r ' ‘1 "‘" _ ' I.- /IUNH; c1334“ aoutu ! Cilia” - agiujTo ”1‘2": ,4.” . LAKE (RI! 1 I l 1 I . I L! j 4:- _.I. _|_‘. VAL“ L. I a. 11.1.I_I_L‘_ 3' 1__11, . C I? '0“. @ Figure 6. Location of Walker Oil Field in Michigan 18 thought to exist, and shallow bedrock of the Michigan for- mation quarried and mined near Grandville suggested compara- tively strong off-structure dip and reversal. The shallow bedrock was thought to be under a region of abnormal dip because this condition had been characteristic of several Michigan producing structures (Newcombe, 1939). A structure contour map, based on data from 35 water wells and core holes and the subsurface topography of three gypsum mines, was developed on the Marshall sandstone to delineate the structure. The discovery well in the Walker Field was loca- ted in an area encircled by the highest closing Marshall contour. The Walker Oil Field came into being with the dis- covery of oil on September 24. 1938, by MacCallum and Herr's L. M. Story No. 1 located in section 32 of Walker Township (T7N-R12W), Kent County. Field development started slowly until Spring, 1939, when larger producing wells were brought in approximately one-half mile east of the discovery well. Then a drilling boom began which took on major proportions by June, 1939. Because of this frenzied activity, the Walker Field was known as the "field of the year" in Mich- igan in 1939. Production The Walker Field produces from the Traverse Lime— stone at approximately 1,140-1,205 feet depth below sea level. The limestone section in which porosity has 19 developed is 30-50 feet thick, but the actual pay section is much less than this. It may total 3-12 feet in thickness. In 1940, the Walker Field was the most active field in the state with 170 producing wells completed. With dril- ling based on a ten acre spacing pattern, production in the field reached its peak in January, 19h0, with 566,665 bar- rels of oil and steadily declined to 162,940 barrels of oil in December, 1940 (Grant, 19fi1). At the end of that year, recovery had been approximately 1,500 barrels of oil per acre. The Walker Field is still an active field with 342 Traverse Limestone wells producing. As of the end of 1976, 784 Traverse wells had been drilled in the Walker Field, covering and area of 8,560 acres (Mich. Geol. Survey, 1977). Total production in 1976 was 112,081 barrels of oil, and the cumulative oil production for the field through 1976 was 17,042,228 barrels of oil (Mich. Geol. Survey, 1977). Lithology The lower twenty feet of the Traverse Formation in the Walker Field is typically a light gray to gray, shaley, slightly pyritic, fine crystalline limestone. In numerous wells throughout the field's extent and at various depth horizons in the lower twenty feet of the Traverse Formation are thin units of gypsum. These evaporite units are massive‘ and earthy to fibrous, with some random speckling of insol- uble residue materials. 20 The Traverse Limestone interval from the Walker Field, as examined under the binocular microscope (Appendix I), ranges from limestone to dolomite, with dolomitic lime- stone and calcic dolomite most prevalent. Color is gray to buff to tan brown. This fine to medium crystalline carbon— ate rock has associated beds of gypsum, which are typically white to buff color, massive-earthy, randomly speckled with very fine grain insoluble residues, and often slightly pyritic. In the majority of well sample suites examined, a 5-6 feet thick bed of gypsum occurs approximately 10-15 feet below the top of the Traverse Limestone interval. This evaporite unit is usually overlain by fine to medium crys- talline dolomitic limestone or calcic dolomite. More well data from the area of study is necessary to attempt success- fully the generation of cross-sections through the field depicting possible facies relationships between dolomites, limestones, and evaporites. Structure Structural interpretation of the Walker Field was based upon a cuttings study from 133 wells and selected driller's logs. Well locations are shown in Figure 7 and well locations and depths are recorded in Appendix II. A general structural contour map of the field on the top of the Traverse Limestone is shown in Figure 8. This map reveals a large regional anticlinal structure with a 2T RT3W [12W OTTAWA CO. KENT CO. T 7 N S>FXMS H‘s—v. £FXMS H‘s—v. £x—\\;\. ,1 1 l g . I e” e e O 91 /e I / :5 e \ K ~1'55//.—\~ . . V >K I // ’ ’4‘ o ‘716‘,\ / < a a" \ e v," \\_/-/ / / / 2‘ x . $ 5:290 \\\_"// // , 1’ \ / \ / W\ \ \\\ l// . O C O I, 9 \ h‘ 10 11 12 1 a s 9 11 6 9 10 , \\ I; \\ \\ \\ / N o \‘b” \\ \ \ \ ’/ \ \ N \ o a \ \ \ R I3 W OTTAWA CO. KENT CO. R I2 W 24 smaller doubly-plunging anticlinal structure to the south— west and trending parallel to it. A small synclinal struc- ture separates these two anticlinal structures. The major axes of these larger structural trends is in a northwest- southeast direction. This structural alignment is in agree- ment with the general structural trends of the Traverse Group in the southwestern portion of the Michigan Basin as described by Runyon (1976). Cross-structure trends within the Traverse Limestone appear to be oriented in a general southwest-northeast di- rection. These trends are especially discernable on the northeast flank of the field where drag folding is observed between the -1150 to -1175 feet contour intervals. Also, a number of structural highs are oriented in a northeast- southwest direction. In a summary of structural trends within the Basin, Prouty (1970) states that there is promin- ent NW-SE and NE-SW folding with evident lateral faults (Figure #). The geometry of the Traverse Limestone struc— ture highly suggests fault-related folding in the Walker Field. 0n the basis of LANDSAT imagery studies, Prouty (1976) has concluded that lineaments gleaned from these studies are shear faults, that most basin folds are fault related, that the principal faulting and folding was in pre- Marshall-Mississippian time, and that the causative shearing stresses are related to structural activity in the east (Appalachian Orogeny). LIMESTONE AND DOLOMITE ANALYSES Experimental Procedures Source of Samples In subsurface geological research, the best type of sample materials for analysis are well core samples, because of known depth and lack of contamination. Rotary drill sam- ples usually are unsatisfactory to work with because of dif- ficultly in locating sample depth (due to down-hole contami- nation), whereas cable tool samples are comparatively pure and are satisfactory for depth location (Krumbein and $1058, 1963). The well samples utilized in this study were from cable tool sample suites from the Walker Oil Field which, among other samples, the Gulf Refining Company donated to the Department of Geology, Michigan State University. Sample Study Because of the lack of electric and mechanical logs from the Walker Oil Field, the top of the Traverse Limestone was picked from cuttings from 133 cable tool sample suites and selected driller's logs. The sample suites represent both producing and nonproducing wells and display a good geographical spacing throughout the field. 25 26 To check the validity of certain driller's logs for their designation of the top of the Traverse Limestone, the writer contacted two drillers who heavily participated in the field's development (John Mackey of Marne, Michigan and Orville Palmer of Allegan, Michigan). It was established that the Traverse Limestone top is an important drilling marker throughout much of the Michigan Basin and this parti- cular top is very distinctive and is an easy call to make. Two-thirds of the sample suites examined microscopically were from wells drilled by one or the other of these two drillers. Comparison of the Traverse Limestone tops as picked by these drillers and my own interpretation varied no more than two feet in each well, with one exception. The Traverse Limestone interval lies between the top of the Bell Shale and the base of the Traverse Formation. The top of this limestone interval was placed at the 90-100 percent level of carbonate concentration, as suggested by Runyon in his study of the Traverse Group of Michigan (1976). All well cuttings were examined under an Olympus Binocular Microscope under a 10X combination of lenses, with a maximum magnification of up to 40X. A fluorescent lamp was used as the light source. For identifying and differentiating car- bonates, a mixture of 7 parts water to 1 part concentrated hydrochloric acid was utilized. Differentiation of carbon- ate samples followed the procedure discussed by Low (1951). 27 Well Sample Preparation The well samples to be used for x-ray diffraction analyses were throughly washed with distilled water and dried. Samples representing each five foot interval below the top of the Traverse Limestone were selected and weighed to approximately 2.0 grams. Most of the well sample suites used penetrated only up to 30 feet into the Traverse Lime- stone upon reaching the pay zone. X-Ray Diffraction Procedure Conventional chemical methods utilized in the deter- mination of limestone and dolomite percentages in particular rock specimens usually are very tedious and time consuming. The x-ray diffraction method is a newer technique that of- fers speed without sacrificing the accuracy and precision found in wet chemical procedures (Kutsykovich, 1971; Gunatilaka and Till, 1971). In the x-ray method, which is based on the crystal phases of dolomite and calcite, the ratio of calcite-to-dolomite is determined independently of other Mg, Ca, and other carbonate-bearing materials (Tennant and Berger, 1956). The x-ray diffraction technique is being applied by workers in various areas of geological research (Tennant and Berger, 1956; Weber, 1967; Otalora and Hess, 1969; Gunatilaka and Till, 1971; Badiozamani, 1973; Folk and Land, 1975; Supko, 1977). 28 The Method The determination of the relative quantities of a multicomponent mixture by x-ray diffraction is based on the relationship between the absorptive properties of minerals and their peak intensities (Jenkins and DeVries, 1968). The method utilized in this study consists of the measurement of the relative peak intensities of the stron- gest powder x-ray diffraction line for calcite and for dolo- mite in a series of mixtures of known proportions. A cali- bration curve is then constructed from these standards of known quantities or proportions, and samples of unknown com- position are then compared with the calcite/dolomite stand- ardization curve (Tennant and Berger, 1956). This procedure is primarily reliable for the determination of a quantita- tive ratio for the minerals present in a rock specimen. When an accurate and precise quantitative measurement of a single mineral is required, a spiking system (use of an in- ternal standard) becomes necessary (Gunatilaka and Till, 1971). Diffraction peak intensities are influenced by grain size, sample packing, and mineral orientation (Jenkins and DeVries, 1968). To minimize peak intensity variability, all samples x-rayed (calibration standard samples and well sam- ples) were crushed and placed in a tungsten carbide grinding vial and ground for approximately ten minutes in a Spex 8000 Ball Mill Grinder to achieve grain size uniformity. All powdered samples were packed tightly with consistency into 29 specially crafted sample holders of Bakelite. Sample sur- faces were then smoothed off and covered with a thin Mylar strip. Standardization Sample Preparation In this study, previously prepared dolomite calibra- tion standards were used. These standards were prepared by M. Dastanpour for a recently completed investigation (1977). The following two paragraphs and Table 1 are a summation describing the procedure Dastanpour followed in preparing the calibration standards. The dolomite and calcium carbonate used in preparing the calibration standards were purchased specimens of analy- tical quality. The dolomite grains were soaked in 5 percent hydrochloric acid for several hours to dissolve any fine calcite crystals that might have grown between the dolomite crystals. The dolomite grains were then throughly washed with distilled water and dried. Different proportions of dolomite and calcite were weighed to an accuracy of one tenth of one milligram. Each component was then completely mixed with another weighed component to produce the desired dolomite mixture. Table 1 illustrates the different mixtures which were prepared for use as calibration standards. 30 Table 1. Different Components Used for Standardization. Grams Grams Weiggiogiigent Mass dolomite Mass calcite 15 0.3000 1.7000 25 0.5000 1.5000 30 0.6000 1.h000 50 1.0000 1.0000 60 1.2000 0.8000 75 1.5000 0.5000 90 1.8000 0.2000 100 2.0000 0.0000 Procedure Once packed into sample holders, the powdered car- bonate samples were placed into the x-ray diffraction gonio- meter and irradiated using Iron Km radiation with Manganese filtration at 50 kilovolts and 10 milliamperes. A General Electric X-Ray Diffraction Goniometer (Model XRD-6) was util- ized for the irradiation of the carbonate samples. The x-ray diffraction peaks were recorded by a strip-chart re- corder (type HF, DC millivolt) with an event marker pen and multispeed chart-drive unit. A range of 200 counts per sec- ond and a time constant of 1 were used with a scan rate of 0.50 Ze/minute and a chart speed of 75 inches per hour. All scans of 029 were made using a 1°, 0.1o slit system. 31 Each calibration standard sample and each well sam- ple was scanned twice (sample was rotated 1800 in goniometer holder before second scan) and the average intensity for both calcite and dolomite was determined. The following x-ray diffraction data was utilized in the x—ray procedure (Berry, 1974; Fang and Bloss, 1974). The interplanar spacing (d) corresponds to 029 for various wavelengths where 026<90°: Dolomite Calcite MgCa(C03)2 Caco3 O 0 d spacing 2.88 A 3.03 A °2e 39.14° 37.13° File No. 11-78 5-586 Fiche No. 1-38-D10 1-18-E4 Calibration Curve The meaning of the percentage of dolomite, as used in this study, is the percent of the total carbonate, dolo— mite (MgCa(C03)2) plus calcite (CaCOB), which is present as dolomite in a rock specimen. Also, the dolomite described in this study is considered an ideal dolomite. The ideal mineral dolomite is described by Goldsmith and Graf (1958) as a rhombohedral carbonate containing equal molar propor- tions of calcium carbonate and magnesium carbonate. A calibration curve was constructed by plotting the dolomite/(dolomite+calcite) x 100 intensity ratio as measur- ed versus the weight percent dolomite in the mixture 32 (Figure 9). Points plotted on the calibration curve were obtained by preparing three samples of each weight percent dolomite concentration and scanning each one twice (sample rotation of 180°). Each point on the curve represents the average result of six separate intensity peaks for each dolomite standard concentration. Data Calculation The correlation coefficient between the peak inten- sities and the mass of dolomite percents from the calibra- tion standard samples is 0.996 (r = 0.996). This value in- dicates that there is a high correlation or "good fit" be- tween these two sets of variables. The calibration curve (Figure 9) demonstrates that the calculated peak intensity value,-Efia%235 x 100, represents the dolomite percent con- centrated in that sample. Expressed in another way: Dolomite_ Dolomite mass x 100 ,_ Dolomite_peak x 100 percent ‘(Dolomite + Calcite) mass-(53lomite + Calcite) peak Each of the 315 powdered samples from 58 wells in the study area were scanned twice and the average intensity peaks for calcite and dolomite were determined. The dolomite percent- age of each well sample was calculated using the following expression: Dolomite average peak x 100 Dolomite percent = (Dolomite + Calcite) average peak 33 100- 90- 80- 70" 60‘ x 100 50' hD hD + hC 40‘ 30- 20- 10" o T T f 1 01020504osow7b§o§i160 % DOLOMITE O Height of Dolomite Peak at 2.88 A 0 Height of Dolomite Peak at 3.03 A hD hC Figure 9. Calibration Curve of Dolomite Percent 34 Data Interpretation The Traverse Limestone in the area of study was divided into intervals of 0-5, 5-10, 10-20, 20-30, and 30- 40 feet below the top of the Traverse Limestone in each well that was x-rayed. Some wells do not have the lower depth intervals because these wells had reached the pay zone. Dolomite percentage for each of these depth intervals was calculated from the result of the x-ray diffraction analysis (Appendix III). Vertical and lateral variation of dolomite percent is discussed below. Vertical Dolomite Variation Dolomite percent values were plotted against their depth below the top of the Traverse Limestone. Typical vertical dolomitization patterns within the upper Traverse Limestone in the area of study is shown in Figure 10. Two of the wells show the highest dolomite ratios in the 0—5 feet interval, and the other two wells show the highest ra- tios in the 5-10 feet interval. All these wells display a distinct decrease in dolomite percentage downward from high- er dolomite percentages at or near the top of the Traverse Limestone. Bar graphs were constructed depicting the field average of dolomite percent values versus depth interval and the average percent values versus depth interval from the northwest portion and the southeast portion of the field's main structural trend (Figure 11). The bar graphs of the Depth Below the Top of Traverse Limestone 35 % DOLOMITE 0 1p 20 3‘0 49 so op 79 so 99 190 5-10 10-20 20-30 Well No. 7 % DOLOMITE 0 1p 29 39 49 so 69 79 8p 99 190 __2:§__ 5-«> ] 10-20 20-30 30-40 Well No. 89 % DOLOMITE % DOLOMITE o '3) 29 39 .10 o ‘ua 29 39 10 0-5 0-5 5-10 5-10 10-20 10-20 20-30 20-30 Well No. 121 Well No. 319 Figure 10 Typical Vertical Dolomitization Patterns in the Traverse Limestone Depth Below the Top of Traverse Limestone 36 % DOLOMITE o 53 1o 15 20 25 30 3.5 _°"_5_. 5-10 10-20 20-30 30-40 Average values for NW structure (Tallmadge Township) % DOLOMITE o§1o1520253035 A J I l L .1 0-5 5-10 A 10-20 20-30 30-40 Average values for SE structure (Walker and Wyoming Townships) % DOLOMITE 0 § ‘NJ 15 20 23 39 35 0-5 5-10 . 10-20 20-30 30-40 Average values for Walker Field Figure 11 Average Vertical Dolomitization Patterns in the Traverse Limestone 37 field average and that of the NW portion of the structural trend show the highest dolomite percent values in the 5-10 feet depth interval. The SE portion of the main structural trend shows the highest dolomite percent value in the 0-5 feet depth interval. As demonstrated in the bar graphs of individual wells, the bar graphs illustrating average dolo- mite percent values show a decrease in dolomite percent downward from higher dolomite percent values at or near the top of the Traverse Limestone. Lateral Dolomite Variation The dolomite analyses provided data for dolomite ratio maps, which indicate the relative degree of dolomiti- zation to the Traverse Limestone structure. Dolomite per- cent values were plotted on the base map of the area for each of the top four depth intervals (0-5 feet, 5-10 feet, 10-20 feet, and 20-30 feet) and lines of equal dolomite per- cent (isodolic) were constructed. A similar map of the 30- 40 feet depth interval was not constructed because of the small lateral variation demonstrated in this section. The dolomitization patterns of each isodolic map (Figures 12, 13, 14, and 15) roughly correlate with the structural alignment of the area. With each of the iso- dolic maps, high dolomitization values coincide closely with a structural high located in the most westerly portion of the field. In the north-northwesterly portion of the field structure, the highest dolomitization values do not 38 Figure 12 Dolomite Ratio Map 0-5 Feet Below the Top of the Traverse Limestone OTTAWA CO. KENT CO. I I2W WALKER OIL FIELD Kent In Ottawa Counties, Michigan Dolomite Ratio Map: 0-5 Feet Below 13 1. " to the Top of the Traverse Limestone leopleth Interval = 5% Dolomite Producing Well: . Dry Hole: . 0 miles I m— _| GEORGETOWN TWP. TALLMADGE TWP. R I3W OTTAWA CO. KENT CO. . R I2 W q 'dMl ONIWOAM 'clMl IBXIVM —¢ 40 Figure 13 Dolomite Ratio Map 5-10 Feet Below the Top of the Traverse Limestone We- «.0 W-v‘w‘.—_H —--‘-O~"-—.——-.-—c R I3 W OTTAWA CO. KENT CO. R I2 W WALKER OIL FIELD Kent & Ottawa Counties, Michigan Dolomite Ratio Map? 5-I0 Feet Below 13 1., 16 the Top of the Traverse Limestone Isopleth Interval = 5% Dolomite Producing Well: . Dry Hole: 0 0 miles I m __l__L__.__._______ 2V4 ‘ ‘4‘— 21 22 23 \ \ \ \I: \ \\ ll 23 \\ 27 26 ’l l. \ \33 o \ \\\ 3. \\ \ \ \ T33 34 l 35 __...2o/'i‘ I . ’0 .2. \ GEORGETOWN TWP. TALLMADGE TWP. .. . ,3... ”A...“ A.) .m, ZV-I l I fio §e so/ a l—/ fie . g. !e 5 5' / I // / ‘t L/‘// ,v fie 20" \ i0 R I3 W OTTAWA CO. KENT CO. - R I2 W 'dMI. ONIWOAM 'dMl liXIVM 20" 42 Figure 14 Dolomite Ratio Map 10-20 Feet Below the Top of the Traverse Limestone ZV-t GEORGETOMIN TWP. TALLMADGE TWP. 20-! R I3 W OTTAWA CO. KENT CO. R I2 W 3’ \ WALKER OIL FIELD Kent & Ottawa Counties, Michigan Dolomite Ratio Map: IO-20 Feet Below re 15 ‘1 u the Top of the Traverse Limestone lsopleth Interval = 5% Dolomite Producing Well: . Dry Hole: 0 0 miles I -:-:—:— 21 22 20 21 22 23 \ \ \. *° . \ .. "’ \ \ \ 22 21 \0 29 \ 21 26 I .e ,, ,, \ :/ °/\ \ . / , / /.:r1o .:. / .:. .3. / \0 ‘U \ \ 2 \_/ ‘0, \ \g/ ,o .:. / // )3: I“ \\ 33 34 35 36 31 32 ° 34 35 .3. 2:. .3. \ .:. 2 2. 3. ‘°/\ 5' 4 . 3 2 1 o 5 4 3 53' 1 / if .— ~ — — ~ __—20/ ’z. e .I. /_/15 // / 9 1o 11 12 1 e 9 1o 11 . I” R I3W OTTAWA CO. KENT CO. R I2 W ZV-e 'dMl ONIWOAM 'dMl IJXIVM 20-! 44 Figure 15 Dolomite Ratio Map 20-30 Feet Below the Top of the Traverse Limestone OTTAWA CO. KENT CO. 2‘4" GEORGETOWN TWP. TALLMADGE TWP. .4 I W R I2W a / 3’79, / I WALKER OIL FIELD / /I ‘0 §// I Kent In Ottawa Counties, Michigan / /"’°~g// ,5 I Dolomite Ratio Map: 20-30 Feet Below 16 / 2° \ the Top of the Traverse Limestone 1s / 13 I 10 11 1o 3 \ I lsopleth Interval = 5% Dolomite I Producing Well: 0 Dry Hole: 0 I 0 miles I \ I \ I \ \\ / 3 \ \\ 21 22 24 \ 21 22 23 \ \\ \\ \ \ 1' 7 \ /\___,_/ \ \\ \ N .'. I\ \ \\ \ \ \ \ e 21 24 25 \ 29 23 \ 21 26 / \ 2'" \ ‘ -A / \ a O .6 ° /” . \ ”\ I , /... .3. ‘\ 225 ‘3 \ \ / g \ 1o ____— /. \ /’ ,2, \ // \ s 33 34 as 34 32 33 34 \ 35 .2 2:4 ‘0 x 5- . \\ S .2. .1. \ g ___________________________________________ 4:1 m______.______5_ K _____ ' \U ’4 \ 5 .2. 3. .3 \ o - E m z 4 3 2 1 5 4 3 .2. 2 ,0 3:9 ' \ I \ l I T 9 1o . 11 12 I e 9 1o 11 5 I N I .3. l I. R I3W OTTAWA CO. KENT CO. R I2 W 46 correlate with the structural high, but increase in value downdip off structure. Isodolic maps representing the top three depth in- tervals (Figures 12, 13, and 14) display a number of NE-SW trends, which in some instances, closely correlate with cross-structures observed in the structure contour map. The isodolic maps of the 0-5 and 5-10 feet intervals display a N-S trend of certain isodolic contour intervals in the NW portion of the field. 0f the four isodolic maps constructed depicting lat- eral dolomite variation in the upper Traverse Limestone, the isodolic map representing the 0-5 feet depth interval below the top of the Traverse Limestone most closely correlates with the field's diverse structure. Where the degree of dolomitization increases along the structural trend and the apices of folds, the inference can be made that channelways along which dolomitization oc- curred are related in some way to the axes (and origin) of these folds. This implies faulting and fracturing. Where dolomitization patterns do not correlate with the structural trends or folding, the dolomitization patterns might be identifying the traces of faults and fractures not expressed by folding. 47 Walker Field Dolomitization.Models Dolomite percent in the upper portion of the Tra- verse Limestone throughout the Walker Field displays a wide variation over a short distance, both vertically and later- ally. Much of this limestone interval is composed of very fine to finely crystalline dolomitic limestone and calcic dolomite with associated evaporite units (gypsum). In only 7 of the 315 well samples x-rayed were the dolomite percent values over 70 percent. This dolomite was typically fine to medium crystalline. In the majority of well samples x-ray- ed, dolomitization values ranging from 10 percent up to 70 percent within limestone and gypsum units indicates the presence of dolomite, even though dolomite itself was not observed under the binocular microscope. Criteria exist which point to two separate dolomiti- zation processes which developed at different times within the upper Traverse Limestone of the Walker Field. One dolo- mitization process is an early diagenetic dolomitization, where Mg replacement of Ca occurs before cementation of the calcite matrix, probably penecontemporaneous with sediment deposition. The second dolomitization process is post-dia- genetic in nature where a secondary, clearly epigenetic dolomite replaces calcite after cementation of the original calcite matrix. Certain conditions are necessary for dolomitization to occur (Wilson, 1975): (1) a sufficiently porous and 48 permeable calcareous sediment to act as host for the Mg re- placement; (2) a fluid of the correct chemical composition to react, capable of dissolving CaC03 releasing Mg; (3) a long-enduring supply fo Mg; and (4) a hydrodynamic head to force great volumes of water through the sediment. Secondary, post diagenetic dolomite is believed to exist in a number of wells in the Walker Field based on crystalline dolomite, high x-ray dolomite percent values, and a general correlation between dolomite values and the field's structure. This secondary replacement dolomite is probably brought about by ground water percolation through existing fractures in brittle carbonate rocks. Ground wa- ter in this zone percolating along joints, fractures, seams, and other post-consolidation channelways could selectively dissolve the relatively soluble calcite and precipitate dolomite. In their study of dolomitization by ground water, Hanshaw, et al. (1971) state that the Mg/Ca ratio in aquifer water has low magnitude, where the water is undersaturated with respect to both calcite and dolomite. With time and length of travel path in the system, the water increases systematically in Mg/Ca ratio, then dolomite crystals will form. Because of the limited amount of magnesium available from the solution of magnesium calcite and dolomite in the zone of active fluid circulation, they maintain that only localized dolomitization can occur. The source of these dolomitizing fluids necessary to 49 produce secondary, post diagenetic dolomite could be of artesian origin from outcrops off of the Wisconsin Arch (Figure 2). The high magnesium concentration in the ground- water develops by its movement along the bedding planes of Lower Ordovician (i.e. Pairie du Chien Group) and Upper Cam- brian dolomitic formations and may have migrated upwards through fault and fracture systems, dolomitizing the Tra- verse Limestone, among other susceptible formations. Hydrocarbon production in stratigraphic sections of the Middle Ordovician and the Middle Devonian are primarily located in the south and southwest areas of Michigan (Fig- ure 5). Newhart (1976) and earlier workers have postulated for Ordovician fields, and Runyon (1976) for Traverse fields, that magnesium-rich waters ascended fracture systems and were dammed by an impervious seal above, the Utica Shale in the former and the shale-rich Traverse Formation and/or the Antrim Shale in the latter. The fact that the percent dolo- mite in the Traverse Limestone of the Walker Field has a relatively higher at or near the top of the limestone inter- val beneath the limy shale of the Traverse Formation (Fig- ures 10 and 11), indicates these shaley beds might have act- ed as dams to the upward percolating water. Another possible explanation for the vertical dolo- mitization patterns observed in the upper portion of the Traverse Limestone could be an environmental buildup that allowed increasing dolomitization of the carbonate sediments to occur. The slow development of a shallow lagoonal or 50 sabkha environment, for example, could be reflected in the vertical dolomitization patterns, which demonstrate an in- crease from low dolomite percent values in the lower depth intervals within the Traverse Limestone to significantly higher dolomite percent values at or near the top of the Traverse Limestone. These higher dolomitization values at or near the top of the Traverse Limestone might indicate the presence of a carbonate depositional environment that was more susceptible to early diagenetic dolomite replacement than earlier environmental conditions represented by dolo- mite percent values of the lower depth intervals within the Traverse Limestone. A high amount of dolomite along the west side of Michigan in the Traverse Group has been noted by Gardener (1974). Others, such as Hake and Maebius (1938) indicate that various counties on the west side of Michigan contain a higher amount of dolomite than usual. Regional dolomitiza- tion of carbonate facies in western Michigan is suggested in the studies by Syrjamaki, 1977, Lower Ordovician; Newhart, 1976, Middle Ordovician: and Runyon, 1976, Middle Devonian. Some interesting parallels can be drawn between their res— pective studies. Stratigraphic sections from each of these studies demonstrate the same high regional dolomite trend in a north-south orientation, along western Michigan, indica- ting a possible close relationship to the Wisconsin Arch during Ordovician and possibly Devonian time. As regional dolomite content may indicate a shallow, near—shore 51 environment (Prouty, 1946), the presence of a high amount of dolomite in this north-south trend in western Michigan sug- gests the possibility that the Wisconsin Arch might have been high and broad enough to cause shallowing of the Tra- verse seas along it. Much of the upper Traverse Limestone interval of the Walker Field is composed of crystalline dolomitized lime- stones and calcic dolomites with associated evaporites (gyp- sum). The occurrence of crystalline dolomitized carbonate rock, the general lack of correlation between dolomite val- ues of these carbonate rocks and the field structure, the the significant presence of evaporites in this stratigraphic interval, and the regional dolomite trends through the area of study tend to support the idea of early diagenetic dolo— mitization of some of the Traverse carbonate sediments. Some of the dolomitization patterns observed from isodolic maps of the field could possibly be related to an early diagenetic dolomitization process, probably penecon- temporaneous with sedimentation. Adams and Rhodes (1960), Deffeyes, et al. (1965), and Illing, et al. (1965) have provided a dolomitization theory to explain early diagenetic replacement based on the development of Mg-rich brines through evaporation. These authors have proposed that dense saline brines, whose Mg/Ca ratios have been raised by the loss of Ca through evapora- tive precipitation of gypsum and anhydrite in tidal flats, ponds, and supratidal areas (sabkhas), have migrated 52 regularly down through lime sediment, dolomitizing it (evap- orative reflux). Folk and Land (1975) state that an important way to precipitate dolomite is to dilute sea water or sabkha-evap- oritic water with fresh water. Dilution allows the Mg/Ca ratio to remain very high, but slows the crystallization rate and reduces the concentration of competing ions. There are two ideal sites where such a mixing mechanism can take place. One site is floodable sabkhas or inundatable shallow lagoons where the salinity undergoes rapid fluctuation be- tween hypersaline and nearly fresh water conditions. Anoth- er important site is the subsurface zone where sea water or evaporitic waters come into contact with a wedge or lens of meteoric water and salinity reduction occurs. In both of the above cases Mg is supplied by saline waters, but pre- cipitation is permitted only by dilution with fresh water. Studies by Land (1973), Badiozamani (1973), and Land, et al. (1975) indicate that the freshwater phreatic (water table) zone, in places where some slight mixing with sea water occurs, may be an important zone of dolomitization. The Dorag dolomitization model (Ordovician of Wis- consin) of Badiozamani (1973) illustrates the concept that saturation with respect to dolomite increases continuously with increasing sea water added to phreatic water. He cal- culated that in brackish water ”in the range of 5—30% sea water, the solution is undersaturated with respect to cal- cite and many times supersaturated with respect to 53 dolomite." His proposed model necessitates a continuous supply of Mg derived from sea water and mixing with meteoric water during constant fluctuations of sea level. During emergence, the interface where the phreatic lens of fresh water impinges on underlying marine or saline connate water would be a dolomitizing zone; this front could pass through a considerable thickness of sediment as sea level drops. The same conditions would occur during marine transgression. In support of the idea of regional dolomitization of Traverse Group sediments in western Michigan, several wri- ters have noted the existence of a structural barrier in the western Michigan area. In postulating the barrier's exis- tence during Traverse Group time, Jodry (1957) cites as evi- dence the presence of Traverse structural contour highs, high dolomite and evaporite content to the west of it, reef development abreast of it (Paris Oil Field), and a litho- facies change from a lagoonal environment on the west side of the barrier to an open sea environment east of the bar- rier. As additional evidence to delineate this barrier, Jodry utilized a regional gravity map of Michigan by Logue (Tulsa Geological Society Digest, volume 18, 1950). The map shows the major regional gravity anamoly in Michigan to lie along the axis of the postulated West Michigan "Barrier" (Figure 16). Jodry further states that by projecting the barrier from areas of better control, it appears to pass directly through the Walker-Wyoming Park fields. Gardener (1974), in his Middle Devonian study of the Michigan Basin, 54 I—ISAOIIID—V‘Ij _.,- flit—I" 7 CI_ . "sfuqsslpu L!!! 37 (ill. CAIADA ‘T.JOI!’N III-OI 9 I '2 II."- I:::==:== Gardener's Barrier Axis = -— -— —— Jodry’s Barrier Axis = -—-—-—— Runyon's Barrier Axis = Figure 16. West Michigan Barrier Axes 55 indicates a linear biohermal and biostromal development along this West Michigan Barrier (Figure 16). Runyon (1976) suggests that the lack of clastics on the west side of Mich- igan during Traverse time indicates that the barrier was probably a physical barrier with respect to currents (Fig- ure 16). Gardener (1974), on a common association of dolomite below anhydrite beds, suggests that the Deffeyes et al. evaporative reflux model could explain the diagenetic ori- gin of these sediments in the lagoonal area. Runyon (1976) believes a evaporative-seepage reflux dolomitization model helps to explain the relationship of the barrier to the limestone, dolomite, and evaporite trends observed in the western part of the Basin during Traverse time. The Walker Field could possibly be a part of this hypothetical barrier-backwater lagoonal system. The re- stricted nature of the waters west of this hypothetical bar- rier could have developed a highly saline environment favor- able for the occurrence of early diagenetic dolomitization. High salinity levels would be enhanced during periods of slight regression, where the water level in the lagoonal area would be lowered and possibly favor the deposition of evaporites. Periodic flushing of these marine saline waters with fresh water (i.e. tropical rainfall) would lower sali- nity but maintain a high Mg/Ca ratio that would be conducive to dolomitization of carbonate sediments. The restricted nature of this lagoonal area could have been augmented by 56 the presence of the Wisconsin Arch to the west (Figure 2). Due to the absence of core samples from the upper Traverse Limestone of the Walker Oil Field, there was no direct petrographic evidence available with which to postu— late which dolomitization process (early diagenetic or epi- genetic) was primarily responsible for the development of porosity and permeability in the Traverse Limestone pay zone(s). Petrographic analysis of the total carbonate rock fabric is necessary to successfully attempt the determina— tion of the timing of dolomite replacement and its timing relative to other diagenetic events that could have occur- red, such as anhydrite replacement, silicification, and calcite cementation(s). Utilizing evidence compiled during this study, it appears that early diagenetic dolomitization occurred pene- contemporaneously with the deposition of the Traverse Lime- stone. Secondary, post-diagenetic dolomitization of por- tions of the Traverse Limestone could possibly have occurred contemporaneously with or after Basin faulting during post- Osagean-Mississippian time caused by shearing stresses from the east. CONCLUSIONS From the analytical data obtained from the Middle Devonian be drawn: (1) (2) (3) (4) (5) Traverse Limestone rocks, certain conclusions can The highest values of dolomite percent were found at or near the top of the Traverse Limestone. There is a general correlation between the dolomi- tization patterns and the structural configuration of the Traverse Limestone interval in the Walker Field. A few high dolomite percentage value locations occur outside of the fold closure area of the Walker Field and therefore are likely located on faults or fractures where epigenetic dolomitization has occurred. Widespread, crystalline dolomitic limestone is associated with significant amounts of gypsum. This type of dolomite is probably the result of early diagenetic dolomitization and is likely pene- contemporaneous with sedimentation. Folding, fracturing, and solution activity are the major causes for the secondary porosity in the pay zone(s) of the Traverse Limestone of the Walker 57 I.. .. Let- IL .rl.‘ l! (6) (7) (8) 58 Field. Dolomite percentage determinations can be helpful in detecting fault traces in folded structures in the Traverse Limestone that may otherwise go unde- tected. There appears to be a good correlation between faults and folds in the Traverse Limestone of the Walker Oil Field, and the relationship is probably a "cause and effect" relationship. The carbonate and evaporitic facies of the upper Traverse Limestone in the Walker Field appear to be related in some way to the hypothesized West Michigan Barrier. BIBLIOGRAPHY BIBLIOGRAPHY Adams, J. E., and Rhodes, M. L., 1960, Dolomitization by Seepage Refluxion: Am. Assoc. Petroleum Geologists Bull., v. 44, pp. 1912-1940. Badiozamani, K., 1973, The Dorag Dolomitization Model — Ap- plication to the Middle Ordovician of Wisconsin: Jour. of Sed. Petrology, v. 43, pp. 965-984. Bathurst, R. G. C. (ed.), 1971, Carbonate Sediments and Their Diagenesis: Developments in Sedimentology, v. 12, Elsevier, Amsterdam, 620 p. Berry, L. G. (ed.), 1974, Selected Powder Diffraction Data for Minerals: Joint Committee on Powder Diffraction Standards, lst Edition, 833 p. Cohee, G. V., 1944, Thickness and Character of the Traverse Group and Dundee Formation in Southwestern Michigan: U. S. Geol. Survey Oil and Gas Inv. Prelim. Chart 4. , 1947, Lithology and Thickness of the Traverse Group in the Michigan Basin: U. S. Geol. Survey Oil and Gas Inv. Prelim. Chart 28. , and Landes, K. K., 1958, Oil in the Michigan Basin: in Habitat of Oil: Am. Assoc. Petroleum Geologists Symposium. pp- 473-493- , and Underwood, L. B., 1945, Lithology and Thick- ness of the Dundee Formation and the Rogers City Limestone in the Michigan Basin: U. S. Geol. Survey Oil and Gas Inv. Prelim. Map 38. Dastanpour, M., 1977, An Investigation of the Carbonate Rocks in the Reynolds Oil Field, Montcalm County, Michigan: Unpublished Master's Thesis, Michi- gan State University. Deffeyes, K. S., Lucia, F. J., and Weyl, P. K., 1965, Dolo- mitization of Recent and Plio-Pleistocene Sediments by Marine Evaporite Waters on Bonaire, Netherlands Antilles: Soc. of Econ. Paleontologists and Miner- alogists, Spec. Publ. No. 13, pp. 71-88. 59 60 Egleston, D. C., 1958, Relationship of the Magnesium/Calcium Ratio to the Structure of the Reynolds and Winfield Oil Fields, Montcalm County, Michigan: Unpublished Master's Thesis, Michigan State University. Ells, G. D., 1969, Architecture of the Michigan Basin: Mich. Basin Geol. Soc. Ann. Field Excursion, pp. 0-88. Fang, J. H., and Bloss, F. D., 1966, X-Ray Diffraction Tables: Southern Illinois University Press, unnum- bered pages. Fisher, J. C., 1969, The Distribution and Character of the Traverse Formation of Michigan: Unpublished Mas- ter's Thesis, Michigan State University. Fisher, J. H., 1969, Early Paleozoic History of the Michi- gan Basin: Mich. Basin Geol. Soc. Ann. Field Excur- Slon, pp. 89-95- Folk, R. L., and Land, L. s., 1975, Mg/Ca Ratio and Salin- ity: Two Controls over Crystallization of Dolomite: gm.6Assoc. Petroleum Geologists Bull., v. 59, pp. 0' 8e Gardener, W. C., 1974, Middle Devonian Stratigraphy and De- positional Environment in the Michigan Basin: Mich. Basin Geol. Soc. Spec. Papers, No. 1, pp. 43-48. Goldsmith, R. E., and Graf, D. L., 1958, Structural and Com- positional Variations in some Natural Dolomites: Jour. Geology, v. 66, pp. 678-693. Goodrich, R. E., 1957, Geology of the Reynolds Oil Field in Montcalm and Mecosta Counties, Michigan: Unpub- lished Master's Thesis, Michigan State University. Grant, R. P., 1940, Oil and Gas in Michigan in 1940: Am. Assoc. Petroleum Geologists Bull., v. 24, pp. 974- 993- Green, D. A., 1957, Trenton Structure in Ohio, Indiana, and Northern Illinois: Am. Assoc. Petroleum Geologists Bulle, Ve “1g ppe 627-642e Gunatilaka, H. A., and Till, R., 1971, A Precise and Accu- rate Method for the Quantitaitve Determination of Carbonate Minerals by X-Ray Diffraction Using a Spiking Technique: Mineralogical Magazine, v. 38, pp. 481-487. 61 Gustafson, W., 1960, Structure and Stratigraphy of the Tra- verse Group in the Lansing Area of Michigan: Unpub- lished Master's Thesis, Michigan State University. Hake, B. F., and Maebius, J. B., 1938, Lithology of the Tra- verse Group of Central Michi an: Mich. Acad. Of Sci. Papers, v. 23, pp. 447- 61. Hanshaw, B. B., Back, W., and Dieke, R. C., 1971, A Geochem- ical Hypothesis for Dolomitization by Groundwater: Econ. Geol., v. 66, pp. 710-724. Harding, T. P., 1974, Petroleum Traps Associated with Wrench Faults: Am. Assoc. Petroleum Geologists Bull., v. 58, pp. 1290-1304. Henry, W. W., 1949, An Investigation of Subsurface Reef Con- ditions in the Traverse Group of Michigan: Unpub- lished Master's Thesis, Michigan State University. Hinze, W. J., and Merritt, D. W., 1969, Basement Rocks of the Southern Peninsula of Michigan: Mich. Basin Geol. Soc. Ann. Field Excursion, pp. 28-59. Illing, L. V., Wells, A. J., and Taylor, J. C. M., 1965, Penecontemporaneous Dolomite in the Persian Gulf: Soc. of Econ. Paleontologists and Mineralogists, Spec. Publ. No. 13, pp. 89-111. Jackson, R. P., 1958, Dolomitization and Structural Rela- tions of the Deep River, North Adams, and Piconning Oil Fields, Michigan: Unpublished Master's Thesis, Michigan State University. Jenkins, R., and DeVries, J. L., 1968, Practical X-Ray Spec- trometry: Springer-Verlag, New York, pp. 105-120. Jodry, R. L., 1954, A Rapid Method for Determining the Mag- nesium/Calcium Ratio of Well Samples and Its Use as an Aid in Predicting Porosity in Calcareous Forma- tions: Unpublished Master's Thesis, Michigan State University. , 1957, Reflection of Possible Deep Structures by Traverse Group Facies Changes in Western Michigan: Am. Assoc. Petroleum Geologists Bull., v. 41, pp. 2677-2694. Krumbein, W. C., and Sloss, L. L., 1963, Stratigraphy and Sedimentation: Freeman and Co., San Francisco, 2nd Edition, pp. 71-74. 62 Kutsykovich, M. B., 1971, Roentgen-Diffractometric Method of Determination of Carbonates, Quartz, and Other Min- erals in Sediments: Lithology and Mineral Resources, v. 6, pp. 513-514. Land, L. S., 1973, Contemporaneous Dolomitization of Middle Pleistocene Reefs by Meteoric Water, North Jamaica: Bull. of Marine Science, v. 23, pp. 64-92. , Salem, M. R. I., and Morrow, D. W., 1975, Paleo- hydrology of Ancient Dolomites: Geochemical Evi- dence: Am. Assoc. Petroleum Geologists Bull., v. 59, pp. 1602-1625. Landes, K. K., 1946, Porosity Through Dolomitization: Am. Asgoc. Petroleum Geologists Bull., v. 30, pp. 305- 31 . Lockett, J. R., 1947, Development of Structures in Basin Areas of Northeastern United States: Am. Assoc. Petroleum Geologists Bull., v. 31, pp. 429-446. Low, J. W., 1951, Examination of Well Cuttings: Colorado School of Mines Quarterly, v. 46, no. 4, pp. 9-20. Michigan Geological Survey, 1977, Michigan's Oil and Gas Field's, 1976: Mich. Geol. Survey, Ann. Stat. Sum- mary No. 26. , 1964, Stratigraphic Succession in Michigan: Mich. Geol. Survey, Chart 1. Newcombe, R. B., 1933, Oil and Gas Fields of Michigan: Mich. Geol. Survey, Publ. 38, G. Ser. 32. , 1939, Developments in Michigan during 1939: Am. Assoc. Petroleum Geologists Bull., v. 24, pp. 974- 993- Newhart, R. B., 1976, Carbonate Facies of the Middle Ordo- vician of the Michigan Basin: Unpublished Master's Thesis, Michigan State University. Otalora, C., and Hess, H. H., 1969, Modal Analysis of Igne- ous Rocks by X-Ray Diffraction Methods with Example from St. Paul's Rock and an Olivine Nodule: Am. Jour. of Science, v. 267, pp. 822-840. Paris, R. M., 1977, Developmental History of the Howell Anticline: Unpublished Master's Thesis, Michigan State University. 63 Pirtle, G. W., 1932, Michigan Structural Basin and Its Rela- tionship to Surrounding Areas: Am. Assoc. Petroleum Geologists Bull., v. 145-152. Powell, L. W., 1950, Calcium Carbonate/Magnesium Ratios in the Rogers City and Dundee Formations of the Pincon- ning Field: Unpublished Master' s Thesis,-Miehigan— State-University. Now. of M10. 1...». Prouty, C. E., 1946, Lower Middle Ordovician of Southwest Virginia and Northeast Tennessee: Am. Assoc. 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Syrjamaki, R., 1977, Stratigraphy of the Prairie du Chien Group of the Michigan Basin: Unpublished Master's Thesis, Michigan State University. Tennant, C. B., and Berger, R. W., 1956, X-Ray Determina- tion of Dolomite-Calcite Ratio of a Carbonate Rock: Am. Mineralogist, v. 42, pp. 23-29. Tinklepaugh, B. M., 1957, A Chemical, Statistical, and Structural Analysis of Secondary Dolomitization in the Rogers City-Dundee Formation of Central Michi- gan Basin: Unpublished Ph.D. Thesis, Michigan State University. 64 Weber, J. N., 1967, Factors Affecting the Carbon and Oxygen Isotopic Composition of Marine Carbonate Sediments, Part 1 - Bermuda: Am. Jour. of Sci., v. 265, pp. 586-608. Wilson, J. L., 1975, Carbonate Facies in Geologic History: Springer-Verlag, New York, pp. 310-318. Young, R. T., 1955, Relationship of the Magnesium/Calcium Ratio as Related to Structure in the Stony Lake Field, Michigan: Unpublished Master's Thesis, Michigan State University. APPENDICES APPENDIX I SAMPLE WELL DESCRIPTIONS APPENDIX I SAMPLE WELL DESCRIPTIONS Well Name: R. Terpstra No. 1 Location: NW-NE-NE Sec. 15, T7N-R13W Permit No. 8418 Elevation: 665 feet above sea level Traverse Formation fib, pyr I52); tr sh, bl gn: tr bent. 1850-55 LS, shy. 1t gy-gy. Vf Xllt £08 (95%); gypt gy brn, fib (5%): tr pyr. 1855-62 Ls, shy, gy, vf xll, sl pyr. 1862-67 Ls, dol, gy, vf-f xll, fos (85%): gyp, wh-brn, rthy-fib, tr cht, wh-lt gy, porcel: tr pyr. Top of Traverse Limestone 1867-70 Dol, calc, buff-gy, f-m xll (85%); gyp, wh, rthy-mas, spec: tr pyr; tr cht, wh, porcel. 1870-77 Dol, calc, buff-tan brn, f-m xll (60%); gyp, wh-buff, mot, rthy-fib: tr sh, gy. 1877-82 Dol, , f-m xll (90%); gyp, wh, rthy-mas, spec TIO%): tr cht, wh, porcel. 1882-86 Dol, gy-tan brn, f-m xll (50%): gyp, wh, rthy-mas (50%). 65 66 Appendix I - Continued. Well Name: Location: S. Kuiper No. 1 SE-SW-SW Sec. 25, T7N-R13W Permit No. 6617 Elevation: 686 feet above sea level Traverse Formation 1838-52 1852-57 1857-64 1864-72 Ls, shy, gy, vf xll (70%); gyp, gy-brn, mas- fib, sft (30%). Ls, shy, lt -gy, vf xll (80%): gyp, lt gy, mas, sft (20% . Ls, shy, lt gy, vf xll (99%); tr pyr. Ls, shy, lt gy, vf xll (100%). Top of Traverse Limestone 1873-79 1879-85 1885-92 Dol, buff, f-m xll (45%): gyp, dol, m-dk gy, mas. spec (35%): sh. lmy. av (20%). tr pyr- Gyp, wh-gy, spec (80%): ls, coralline, wh- buff, f xll: tr pyr: tr cht, wh: tr qtz: clr, f gr, subang: tr bent, gn gy. Gyp, lmy, wh-buff, mas-fib, spec (95%): sh, gn gy-dk gy (5%): tr ls, coralline, wh. APPENDIX II LIST OF WELLS USED IN STUDY APPENDIX II LIST OF WELLS USED IN STUDY Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County, Tallmadge Township, T7N,5R13W Section 16 1 6801 SE-SE-SE 729 -1996 -1267 Section 15 2 8418 NW-NE-NE 665 -1867 -1202 3 9542 CE/2-SE-NE 677 -1871 -1194 4 9851 NE-SE-SE 683 -1867 -1184 5 7887 SW-SE-SE 667 -1850 -1183 Section 14 6 7699 NE-NE-SW 691 -1877 -1186 7 8287 NW-NW-SE 695 -1875 -1180 8 7695 SE-NW-SW 677 -1861 -1184 9 7318 SW-NE-SW 665 -1848 -1183 10 7825 NE-SE-SW 688 -1863 -1175 11 8424 SW-SE-SW 693 -1870 -1177 12 7768 SE-SE-SW 692 -1865 -1173 13 7995 SE-SW-SE 691 -1861 -1170 Section 13 14 7533 SW-SW-SW 692 -1867 -1175 Section 23 15 8211 NW-NE-NW 695 -1864 -1169 16 7720 NE-NE-NW 691 -1856 -1165 17 7745 NW-NW-NE 694 -1850 -1156 18 7858 NW-NE-NE 684 -1835 -1151 19 7717 SE-NW-NW 695 -1866 -1171 67 68 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County,,Tallmadge Township, T7N, R13W Section 23 20 7605 SW-NE-NW 694 -1858 -1164 21 7637 SE-NE-NW 693 -1855 -1162 22 7681 SW-NW-NE 694 -1846 -1152 23 7578 SE-NW-NE 699 -1854 -1155 24 7263 SW-NE-NE 693 -1856 -1163 25 7378 SE-NE-NE 692 -1854 -1162 26 7600 NE-SW-NW 695 -1853 -1158 27 7570 CN/2-SE-NW 697 -1850 -1153 28 7447 CN/2-SW-NE 695 -1854 -1159 29 7418 NW-SE-NE 694 -1858 -1164 30 7412 NE-SE-SE 699 -1862 -1163 31 7752 CW/2-SE-NW 697 -1853 -1156 32 7411 CE/2-SE-NW 694 -1844 —1150 33 7630 SW-SW-NE 692 -1850 -1158 34 7631 SE—SW-NE 690 -1850 -1160 35 7569 SW-SE-NE 688 -1852 -1164 36 7518 SE-SE-NE 702 -1863 -1161 37 7581 S/2-S/2-SE-NW 695 -1850 -1155 38 7649 NW-NE-SW 688 -1863 -1175 39 7579 NE-NE-SW 694 -1858 -1164 40 7650 NW-NW-SE 694 -1862 -1168 41 7552 NE-NW-SE 691 -1853 -1162 42 7329 NE-NE-SE 709 -1870 -1161 43 8348 SW-NW-SE 693 -1852 -1159 44 7469 SE-NW-SE 691 -1849 -1158 45 7422 SW-NE-SE 697 -1861 -1164 46 7328 SE-NE-SE 711 -1870 -1159 47 8522 NE-SE-SW 689 -1850 -1161 48 7932 NW-SW-SE 693 ~1845 -1153 49 7367 NW-SE-SE 703 -1862 -1159 50 7241 NE-SE-SE 714 -1871 -1157 51 8131 SE-SE-SW 687 -1846 -1159 52 7764 SW-SW-SE 691 -1845 -1154 53 7677 SE-SW-SE 690 -1843 -1153 54 7239 SW-SE-SE 699 -1863 -1164 55 7240 SE-SE-SE 716 -1877 -1161 Section 24 56 7601 SW-NW-NW 714 -1873 -1159 57 7265 SW-NE-NW 746 -1919 -1173 58 7452 NW-SW-NW 719 -1881 -1162 59 7214 NW-SW-NE 752 -1923 -1171 60 7532 SW-SW-NW 717 -1885 -1168 69 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County, Tallmadge Township, T7N, R13W Section 24 61 7291 SE-SW-NW 733 -1901 -1168 62 7051 SW-SE-NW 754 -1913 -1159 63 7285 SW-SW-NE 754 -1918 -1164 64 7215 cw/2 757 -1916 -1159 65 7203 SW-NW-SW 717 -1884 -1167 66 7204 SE-NW-SW 720 -1891 -1171 67 7302 SE-NE-SW 720 -1881 -1161 68 8151 SE-NE-SE 739 -1909 -1170 69 7202 NW-SW-SW 712 -1880 -1168 70 7170 NE-SW-SW 705 -1873 -1168 71 7266 NW-SE-SW 705 -1863 -1158 72 7423 NE-SW-SE 754 -1916 -1162 73 7762 NE-SE-SE 740 -1905 -1165 74 7206 SW-SW-SW 710 -1875 -1165 75 7151 SE-SW-SW 698 -1862 -1164 76 7183 SE-SE-SW 711 -1868 -1157 77 7252 SW-SW-SE 726 -1885 -1159 78 7074 SE-SW-SE 748 -1908 -1160 79 7150 SW-SE-SE 748 -1910 -1162 Section 28 80 22008 SE-NE-NE 718 -1910 -1192 81 22020 CE/2-SW-NE 712 -1901 -1189 82 23963 SE-SE-NW 701 -1904 -1203 83 22202 SW-SW-NE 706 -1901 -1195 84 6317 SW-SE-NE 736 -1910 -1174 85 19562 NE-NW-SE 724 -1904 -1180 86 22829 CW/2-NW-SE 710 -1888 -1178 87 23042 SE-NE-SW 671 -1869 -1198 88 22612 NW-SW-SE 715 -1887 -1172 89 7331 NW-SE-SE 686 -1852 -1166 90 22389 CE/2-SE-SE 673 -1836 -1163 91 24122 SE-SE-SW 641 -1842 -1201 92 7730 SW-SW-SE 688 -1866 -1178 93 8581 SW-SE-SE 673 -1833 -1160 Section 27 94 23028 NE-NW-NW 622 -1806 -1184 95 22947 NE-NE-NW _648 -1832 -1184 96 2187 NE-NW-NE 679 -1860 -1181 97 20161 NE-NE-NE 672 -1846 -1174 98 22105 SW-NW-NW 699 -1887 -1188 70 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County, Tallmadge Township, T7N, R13W Section 27 99 6675 SE-NE-NW 612 -1796 -1184 100 22120 SE-NW-NE 663 -1843 -1180 101 20350 SE-NE-NE 677 -1850 -1173 102 22091 NE-SW-NW 670 -1853 -1183 103 20218 NE-SW-NE 677 -1859 -1182 104 20432 NE-SE-NE 666 -1849 -1183 105 22572 SW-SE-NW 617 -1794 -1177 106 22689 SE-SE-NW 639 -1815 -1176 107 19852 SW-SW—NE 612 -1789 -1177 108 22979 SW-SE-NE 669 -1848 -1179 109 23014 SE-SE-NE 655 -1842 -1187 110 19668 NE-NW-SW 682 -1854 -1172 111 19449 NW-NE-SW 628 -1799 -1171 112 19970 NW-NW-SE 610 -1787 -1177 113 23055 NW-NE-SE 624 -1813 -1189 114 19559 SE-NW-SW 619 -1792 -1173 115 19492 SW-NE-SW 605 -1776 -1171 116 21937 SE-NW-SE 679 -1869 -1190 117 21212 NW-SE-SW 649 -1828 -1179 118 21361 NW-SE-SE 672 -1862 -1190 119 8140 SW-SW-SW 606 -1766 -1160 120 8677 SE-SW-SW 636 -1809 -1173 121 6293 SE-SE-SW 661 -1834 -1173 122 7165 SE-SW-SE 717 -1897 -1180 123 21263 SW-SE-SE 682 -1866 -1184 Section 26 124 20280 NW—NW-NW 676 -1849 -1173 125 8409 NE-NE-NW 685 -1842 -1157 126 7535 CN/2-NW-NE 688 -1847 -1 159 127 7171 NE-NE-NE 699 -1857 -1158 128 7292 CN/2-CN/2-NE 689 -1848 -1 159 129 20489 SE-NW-NW 676 -1846 -1170 130 8629 SE-NE-NW 682 -1840 -1158 131 15831 SW-NW-NE 685 -1845 -1160 132 7262 SW-NE-NE 685 -1841 -1156 133 7172 SE-NE-NE 689 -1845 -1156 134 22262 NW-SE-NW 680 -1860 -1180 135 15532 NE-SE-NE 682 -1850 -1168 136 6998 NE-NW-SW 643 -1845 -1202 137 7175 NE-NE-SE 665 -1870 -1205 138 20567 SE-SE-SW 671 -1872 -1201 71 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County4 Tallmadge TownshipLMTZNJ R13W Section 25 139 7142 NW-NW-NW 702 -1867 -1165 140 7235 NE-NW-NW 701 ~1861 -1160 141 7277 NW-NE-NW 697 -1852 -1155 142 7859 NE-NW-NW 702 -1860 -1158 143 7181 NW-NW-NE 710 -1863 -1153 144 7078 SW-NW-NW 688 -1851 -1163 145 7207 SW-NE-NW 680 -1842 -1162 146 7155 SE-NE-NW 697 -1852 —1155 147 7140 SW-NW-NE 682 -1837 -1155 148 6937 SW-NE-NE 734 -1892 -1158 149 6938 SE-NE-NE 735 ~1890 -1155 150 7143 NW-SW-NW 687 -1862 -1175 151 7236 NE-SW-NW 672 -1846 -1174 152 7276 NW-SE-NW 681 -1845 -1164 153 7085 NE-SE-NW 685 -1848 -1163 154 6979 NE-SW-NE 709 -1858 -1149 155 6861 NW-SE-NE 717 -1869 -1152 156 6860 NE-SE-NE 731 -1876 -1145 157 7397 SW—SW-NW 666 —1850 -1184 158 7237 SE-SW-NW 666 -1844 -1178 159 7121 SW-SE-NW 668 -1840 -1172 160 6895 SE-SE-NW 689 -1848 -1159 161 6981 SW-SW-NE 676 -1833 -1157 162 6845 SE—SW-NE 701 -1851 -1150 163 7157 NW-NE-SW 680 -1855 -1175 164 6741 NE-Nw-SE 692 -1849 -1157 165 6953 CW/2-NE-SE 694 -1845 -1151 166 6106 CE/2-NE-SE 711 -1854 -1193 167 6942 SE—NE-SW 682 -1845 -1163 168 6795 SE-NW-SE 688 -1851 -1163 169 6949 NE-SW—SE 686 -1846 -1160 170 6781 NW-SE-SE 680 -1835 —1155 171 6654 NE-SE-SE 699 -1848 -1149 172 6617 SE-sw-sw 686 -1873 -1187 173 7238 SW-SE-SW 670 -1860 -1190 174 6657 SW-SE-SE 680 -1853 -1173 175 6525 SE-SE-SE 674 -1833 -1159 Section 33 176 22063 NE-NW-NE 681 -1854 -1173 177 8232 NE—NE-NE 657 -1820 -1163 178 8360 SW—NE-NE 656 -1828 -1172 . 179 8340 SE-NE-NE 643 -1806 -1163 72 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County, Tallmadge TownshipJ TZN4 R13W Section_33 180 8342 NE-SE-NE 635 -1810 -1175 181 22989 W/Z-SE-NE 621 -1802 -1181 182 22827 SE-SW-NE 617 -1820 -1203 183 21891 NE-NE-SE 618 -1815 -1197 Sectiong34 184 8209 NW-NW-NW 602 -1764 -1162 185 8313 NE-NW-NW 632 -1800 -1168 186 8139 NW-NE-NW 638 -1806 -1168 187 21187 NE-NW-NE 678 -1848 -1170 188 22102 NE-NE-NE 663 -1849 -1186 189 8189 SW-NW-NW 597 -1763 -1166 190 8201 SE-NW-NW 630 -1793 —1163 191 8071 SW-NE-NW 663 -1825 -1162 192 8391 SE-NE—NW 679 -1846 -1167 193 8458 SW-NW-NE 672 -1844 -1172 194 20864 SW-NE-NE 696 -1876 -1180 195 20780 SE-NE-NE 679 -1870 -1191 196 8273 NW-SW-NW 622 -1789 -1167 197 8093 NE-SW-NW 625 -1785 -1160 198 8002 NW-SE-NW 647 -1807 -1160 199 7854 NE-SE-NW 675 -1840 -1165 200 7694 NW-SW-NE 686 -1857 -1171 201 21238 NE-SW-NE 713 -1888 -1175 202 8338 SW-SW-NW 604 -1772 -1168 203 8374 SE-SW-NW 635 -1795 -1160 204 8339 SW-SE-NW 650 -1817 -1167 205 7933 SW-SW-NE 710 -1888 -1178 206 21375 SE-SW-NE 689 -1871 -1182 207 8481 NE-NW-SW 639 -1811 -1172 208 8676 NW-NE-SW 676 -1852 -1176 209 23515 NE-NW-SE 674 -1860 -1186 210 21814 SW-NE-SW 617 -1796 -1179 211 21569 SW-NW-SE 609 -1793 -1184 212 8425 SE-NE-SE 610 —1806 -1196 Section<35 213 21314 SE-NE-NW 665 -1870 -1205 214 21152 SE-NW-NE 703 -1910 -1207 215 21399 SE-NE-NE 702 -1905 -1203 216 21084 NW-SW-NE 680 -1867 -1187 217 21335 NW-SE-NE 732 -1927 -1195 73 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County; Tallmadge Townshipi T7N, R13W Section¥35 218 14981 SE-SW-NW 719 -1906 -1187 219 13537 SE-SE-NW 675 -1860 -1185 220 22701 SE-SE-NE 728 -1930 -1202 221 14990 NE-NW-SW 710 -1906 -1196 222 14826 NE-NE-SW 704 -1887 -1183 223 15096 NW-NW-SE 715 -1910 -1195 224 6625 NE-SE-SE 726 -1923 —1197 225 16289 SW-NE-SW 624 -1812 -1188 226 19268 SE-NW-SE 645 -1835 -1190 227 19469 SW-NE-SE 612 -1800 -1188 228 15581 NW-SE-SW 592 -1772 -1180 229 15567 NW-SW-SE 596 -1771 -1175 230 18083 NW-SE-SE 590 -1767 -1177 231 17949 NE-SE-SE 608 -1788 -1180 232 15642 SE-SE-SW 592 -1767 -1175 233 16969 SE-SW-SE 598 -1771 -1173 Section‘36 234 20614 NW-NW-NW 702 -1903 —1201 235 6624 NW-NE-NW 672 -1869 —1197 236 6016 NE-NW-NE 674 -1860 -1186 237 7062 NE-NE-NE 679 -1845 -1166 238 21324 SE-NW-NE 682 -1874 -1192 239 21515 SW-NE—NE 683 -1861 -1178 240 21182 SE-NE-NE 682 -1855 -1173 241 6647 NE-SE-NE 680 -1848 -1168 242 21795 SE-SW-NW 734 -1937 -1203 243 23131 SE-SE-NW 714 -1910 -1196 244 21981 NW-NW-SW 719 -1919 -1200 245 22976 NW-NE-SE 681 -1861 -1180 246 18038 SW-NW-SW 723 -1908 -1185 247 21358 NW-SW-SE 703 -1892 -1189 248 21179 NW-SE-SE 689 -1878 -1189 249 22943 NE-SE-SE 685 -1871 -1186 250 22860 C/SE-SW 720 -1896 -1176 251 18468 SW-SW—SW 619 -1789 -1170 252 21248 SE-SW-SE 703 -1886 -1183 253 21092 SE-SE-SE 687 -1869 —1182 74 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Ottawa County, Georgetown TownshipJ T6N._R13W Section 2 254 7959 NE—NW-NW 603 -1777 -1174 255 7871 NW-NE—NW 596 -1771 -1175 256 8018 NE-NE-NW 606 -1772 -1166 257 8329 NW-NW-NE 595 -1761 -1166 258 8683 SW-NW—NW 600 -1794 -1195 259 8400 SW-NE-NW 607 -1774 -1167 260 8164 SE-NE—NW 597 -1763 -1166 261 8465 SE-NW-NE 607 —1776 -1169 262 8617 NW-SE-NW 595 -1774 -1179 Section 1 263 8639 SW-NE-NW 711 -1884 -1173 264 8369 NE-SE—NW 689 -1861 -1172 265 8430 NE-NE-SW 708 -1881 -1173 266 9901 CE/2-SE 677 -1853 -1176 267 8304 NE-SE-SW 695 -1868 -1173 Section 12 268 8542 NE-NE-NW 671 -1848 -1177 269 8447 NW-NW-NE 663 -1839 -1176 Kent Countyi_Walker Township, T7flJ R12W Section 19 270 6282 SW-SW-NW 727 -1903 —1176 271 8419 NW-NW-SW 726 -1899 -1173 272 8535 SE-NW-SW 749 -1914 -1165 273 7930 NW-SW-SW 742 ~1905 -1163 274 7327 SW-SW-SW 737 -1894 -1157 275 7662 SE-SW-SW 742 -1900 -1158 276 6549 SE-SE-SE 727 -1908 -1181 Section 20 277 7268 NW-NE-SW 730 -1920 -1190 278 7565 SE-SW-SW 740 -1915 -1175 279 6841 SE-SE-SW 734 -1906 -1172 280 6894 SW-SE-SE 722 -1895 -1173 75 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County; Walker TownshipJ T7N57R12W Section 30 281 6976 NW-NW-NW 739 —1895 —1156 282 6821 NW-NE-NW 739 -1903 -1164 283 6975 SW-NW-NW 736 -1899 -1163 284 7242 SW-NE-NW 741 -1909 -1168 285 7527 SE-NE-NE 722 -1894 -1172 286 6974 NW-SW-NW 737 -1890 -1153 287 6961 CN/2-SE-NW 736 -1898 -1162 288 6674 NW-SE-NE 730 -1895 -1165 289 7257 NE-SE-NE 735 —1901 -1166 290 6604 CW/2-SE-NW 737 -1892 -1155 291 6522 SW-SW-NW 732 -1874 -1142 292 6825 SE-SW-NW 722 -1873 -1151 293 6808 SE-SE-NW 725 —1883 -1158 294 6664 SE-SW-NE 732 -1890 -1158 295 6514 S/2-S/2-SE-NE 736 —1892 -1156 296 6780 NW-NW-SW 717 -1858 -1141 297 6820 NW-NE-SW 732 -1880 -1148 298 6667 NW-NW-SE 728 -1877 -1149 299 6753 NE-NW-SE 736 -1885 -1149 300 6694 NW-NE-SE 733 -1885 -1152 301 6703 NE-NE-SE 707 -1857 -1150 302 6663 SW-NW-SW 703 -1845 -1142 303 6598 SW-NW-SE 740 -1885 -1145 304 6497 SE-NW-SE 728 -1872 -1144 305 6671 SE-NE-SE 726 -1867 —1141 306 6590 NW-SE-SW 702 -1850 -1148 307 6477 NE-SE-SW 704 -1846 -1142 308 6480 W/Z-SW-SE 729 -1872 -1143 309 6917 SW-SW-SW 676 -1829 -1153 310 6698 SW-SE-SW 693 -1846 -1153 311 6593 SE-SE-SW 704 -1852 -1148 312 6496 SE-SE-SE 738 -1883 -1145 Section 29 313 7061 NW—NE-NW 731 -1899 —1168 314 7058 NE-NE-NW 722 -1888 -1166 315 7025 NE-NW-NE 742 -1910 -1168 316 6923 CW/2-NW—NE 727 -1892 -1165 317 8190 SE-NW-NW 739 -1906 -1167 318 7060 SW-NE-NW 716 -1878 -1162 319 6915 SW-NE-NE 726 -1897 -1171 320 7101 NW-SW-NW 727 -1885 —1158 321 7059 NW-SE-NW 707 —1863 -1156 76 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Walker Township, T7N,_R12W Section 29 322 7023 NE-SW-NE 748 -1913 -1165 323 6888 SW-SW-NW 710 -1865 —1155 324 6930 SE-SW-NW 732 -1880 -1148 325 6765 SW—SE-NW 708 -1855 -1147 326 7021 SE-SE-NW 712 -1864 -1152 327 7264 SW-SW-NE 715 -1868 —1153 328 6967 SE-SW-NE 743 -1905 -1162 329 6834 NW-NW-SW 705 -1853 -1148 330 7127 NE-NE-SW 713 -1865 -1152 331 6929 NW-NW-SE 724 -1882 -1158 332 6735 SW-NW-SW 689 -1833 -1144 333 7091 SE—NW-SW 728 -1874 -1146 334 6914 SW-NE-SW 733 -1881 -1148 335 7146 SW-NW-SE 741 -1896 -1154 336 8116 SW-NE-SE 746 —1904 -1158 337 6746 NW-SW-SW 687 -1835 -1148 338 6833 NW-SE-SW 730 -1878 -1148 339 6851 NE-SW-SE 747 -1898 -1151 340 7219 NE-SE-SE 753 -1905 -1152 341 6759 SE-SW-SW 691 -1839 -1148 342 7182 SW-SE-SW 729 -1876 —1150 343 7336 SE—SE-SW 707 -1856 -1149 344 6600 SE-SW—SE 742 -1891 -1149 345 6843 SE-SE-SE 759 -1909 -1150 Section 28 346 6971 SW-NW-NE 743 -1923 -1180 347 7445 SE-SE-NW 750 -1920 —1170 348 16114 NE-NW-SE 733 -1902 -1169 349 7330 NW-NE-SE 731 -1902 -1171 350' 6873 SW-NW-SW 747 -1905 -1158 351 7413 NW-SW-SW 746 -1899 -1153 352 7249 CN/Z-SW-SE 749 -1905 -1156 353 7065 SE-SW-SW 739 -1888 -1149 354 7064 CS/2-SE-SW 754 -1905 -1151 355 8162 CS/2-SW-SE 735 -1892 -1157 Section 27 356 7459 SW-NW-NW 702 -1886 -1184 357 7456 SE-NE-NW 758 -1946 -1188 358 7451 SW-SW-NW 699 -1879 -1180 359 5936 SE-SW-SW 704 -1876 —1172 77 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Walker Townshig,¥T7N, R12W Section_31 360 6523 NE-NW-NW 675 -1828 -1153 361 6459 NE-NE-NW 690 -1838 -1148 362 6506 NW—NW-NE 714 -1860 —1146 363 6488 NE-NW-NE 712 -1857 -1145 364 6476 NW-NE-NE 714 -1860 -1146 365 6850 NE-NE-NE 732 —1881 —1149 366 7243 SW-NW-NW 679 -1838 -1159 367 6589 SE-NE-NW 704 -1857 -1153 368 7588 SW-NE-NE 676 -1830 -1154 369 6995 CN/2-SE-NW 681 -1841 -1160 370 6731 NW-SW-NE 679 -1847 -1168 371 6479 NW-SE-NE 675 -1833 -1158 372 6773 S/2-N/2-SE-NW 685 -1857 -1172 373 6513 SE-SW-NE 701 -1873 -1172 374 6137 NE-NE-SW 675 —1863 -1173 375 8459 NE-NE-SE 720 -1887 -1167 376 6788 NW-SW-SE 695 —1870 -1175 377 7352 SE-SE-SE 672 -1837 -1165 Section532 378 6789 NW-NW-NW 730 -1879 -1149 379 6997 NE-NW-NW 711 -1866 -1155 380 6475 NW-NE-NW 713 -1865 -1152 381 6886 NE-NE-NW 727 -1879 -1152 382 7553 NW-NW-NE 721 -1869 -1148 383 7689 NW-NE-NE 735 -1880 -1145 384 6483 SW-NW—NW 700 —1855 ~1155 385 7160 SE-NE-NW 727 -1876 -1149 386 7159 SW-NE-NE 756 -1898 —1142 387 7033 NE-SE—NW 725 -1873 ~1148 388 7037 SE-SW-SW 663 -1821 -1158 389 6056 SW-SE-NW 680 -1835 -1155 390 6478 SE-SW-NE 690 -1838 -1148 391 7426 NW-NE-SW 700 -1855 -1155 392 7295 NE-NE-SW 706 —1860 -1154 393 7057 NW-NW-SE 715 -1868 -1153 394 7810 NE-NE-SE 703 -1853 -1150 395 7145 SE-NE-SW 669 -1817 -1148 396 7820 SE-NW-SE 659 -1804 -1145 397 7763 SE-NE-SE 626 -1769 -1143 398 5937 NE-SW-SW 644 -1794 -1150 399 5858 NE-SW-SE 653 -1796 -1143 400 7316 SW-SW-SW 716 —1874 ~1158 78 Well Permit Section Ground Traverse Traverse .No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Walker Township, TZN,_312W Section 32 401 5207 SE-SW-SW 702 -1860 -1158 402 5725 SW-SE-SW 658 -1814 -1156 403 5785 SE—SE-SW 647 -1793 -1146 404 6069 SE-SW-SE 619 -1763 -1144 405 5998 SW-SE-SE 607 -1750 -1143 406 6097 SE-SE-SE 610 -1752 -1142 Section 33 407 7020 NW-NW-NW 738 -1886 -1148 408 7141 NE-NW-NW 702 -1850 -1148 409 7807 CN/2-NE-NW 756 -1906 -1150 410 6940 SW-NW-NW 721 -1870 -1149 411 6987 SW-NE-NW 703 —1855 -1152 412 7003 SE-NE-NW 744 -1902 -1158 413 6166 NE-SW-NW 633 -1782 -1149 414 7144 NW-SE-NW 662 -1815 -1153 415 7004 NE-SE-NW 710 -1868 -1158 416 6495 SW-SW-NW 711 -1860 —1149 417 7335 SW-SE-NW 720 -1866 -1146 418 6842 SE-SE—NW 676 -1820 -1144 419 6386 SW-SW-NE 754 -1910 -1156 420 7558 SE-SW-NE 764 -1920 -1156 421 7218 SW-SE-NE 693 -1856 -1163 422 7290 NW-NW-SW 686 -1829 -1143 423 7153 NE-NW-SW 672 -1819 -1147 424 6554 NE-NE-SW 724 -1868 -1144 425 6760 NW-NW-SE 741 -1886 —1145 426 7571 NW-NE-SE 682 —1833 -1151 427 7480 NE-NE—SE 688 -1842 -1154 428 6292 SE-NW-SW 617 -1764 -1147 429 7317 SE-NW-SE 695 -1840 -1145 430 7960 NW-SW-SE 609 -1753 -1144 431 6177 NE-SW-SW 608 -1750 -1142 432 6190 NE-NE-SW 600 -1738 -1138 433 6052 NW-SW-SE 606 -1744 -1138 434 7479 NE-SE-SE 725 -1874 -1149 435 7323 SW-SE-SW 607 -1748 -1141 436 6468 SW-SE-SE 603 -1743 -1140 437 7478 SE-SE—SE 602 -1752 -1150 79 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Walker Township, T7N, R12W Section 34 438 12899 NE-SE-NW 762 -1924 -1162 439 6973 SW-SW—NW 655 -1813 -1158 440 7072 SW-SE-NW 696 -1856 -1160 441 6807 SE-SE-NW 741 -1904 -1163 442 7269 NW-NE-SE 595 -1771 ~1176 443 7658 SW-NW-SW 622 -1775 -1153 444 7404 NW-SW—SW 603 -1755 -1152 445 6939 NW-SE-SW 598 -1753 -1155 446 7659 SE-SW-SW 605 -1757 -1152 Sectionp35 447 7015 NW-SW-NW 597 -1781 -1152 Kent County, Wyoming Township, T6NJ R12W Section 6 448 21386 NE-NW-NW 682 -1866 -1184 449 22479 N/2-NE-NW 667 -1849 -1182 450 6339 NE-NE-NE 697 -1863 -1166 451 21741 SE-NW-NE 662 -1837 -1162 452 6053 SW-NE-NE 663 -1825 -1162 453 7580 SE-SE-NE 697 -1865 -1168 454 13042 NW-SW-NE 662 -1842 -1180 455 19890 NE-SW-NE 658 -1834 -1176 456 13040 SE-SW-NW 672 -1850 -1178 457 12560 NW—NW-SE 661 -1840 -1179 458 13157 SE-NE—SW 669 -1845 -1176 459 12805 SE-NW-SE 712 -1889 -1177 460 21658 SE-NE-SE 700 -1884 -1184 461 9611 CW/Z—SW 672 -1831 -1159 462 13231 NW-SE-SW 666 -1831 -1165 463 21542 CSW/4-SE 715 -1899 -1184 464 21584 SW-SW-SW 659 -1820 -1161 465 21538 SW-SE-SE 729- -1914 -1185 Section_5 466 7035 NW-NW-NW 721 -1880 -1159 467 6033 NW-NE-NW 630 -1782 —1152 468 5433 NE-NE-NW 707 -1861 -1154 469 6062 NW—NW-NE 614 -1765 -1151 470 5880 NW-NE-NE 602 -1748 -1146 80 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Wyoming Township, T6N, R12W Section 5 471 6425 NE-NE—NE 603 -1745 —1142 472 6018 SE-NW-NW 665 -1825 -1160 473 6188 SE-NE-NW 612 -1770 -1158 474 6187 SE-NW-NE 605 -1753 -1148 475 6122 SW-NE-NE 605 -1752 -1147 476 22030 NW-SW-NW 702 -1870 -1168 477 6450 NW-SE-NW 626 -1787 -1161 478 6211 NW-SW-NE 605 -1759 -1154 479 5933 E/2-SE-NW 611 -1768 -1157 480 21876 SE-SW-NW 660 -1830 -1170 481 22357 SW-SW-NE 604 ~1758 -1154 482 6315 SW-SE-NE 614 -1768 -1154 483 6316 SE-SE-NE 617 -1767 -1150 484 21819 NW-NE-SW 622 -1799 -1177 485 8593 NE-NE-SW 603 -1777 -1174 486 7178 NW-NW-SE 600 -1771 -1171 487 5923 NE-NW-SE 618 -1788 -117O 488 13698 cw/2-sw-sw 636 -1820 —1184 489 23988 SE-SW-SE 598 —1780 -1182 490 23192 CS/2-SE-SE 597 —1777 -1180 Section 4 491 6170 NE-NE-NW 599 -1741 -1142 492 6530 NW-NW-NE 598 -1738 -1140 493 6920 NW-NE-NE 597 -1735 -1138 494 7247 NE—NE-NE 595 -1744 -1149 495 6309 SW-NW-NW 608 -1754 -1146 496 6341 SE-NW-NW 608 -1752 -1144 497 6696 - SW-NE-NE 596 -1738 -1142 498 7135 SE-NE-NE 595 -1737 -1142 499 6138 NW-SW-NW 611 -1758 -1147 500 6368 NE-SE-NW 615 -1760 -1145 501 6583 NE-SW-NE 600 -1740 —1140 502 6695 NE-SE—NE 598 -1743 -1145 . 503 6449 SW-SW-NW 623 -1772 -1149 504 6376 SE-SW-NW 620 -1770 -1150 505 6702 SW-SW-NE 597 -1741 -1144 506 6562 SW-SE-NE 593 -1738 -1145 507 6673 NW-NW—SW 625 ~1790 -1165 508 6885 NE-NE-SW 594 -1740 -1146 509 6524 NE-NW-SE 601 -1748 -1147 510 6216 NE-NE-SE 595 -1743 -1148 511 6819 SE-NW-SW 596 -1754 ~1158 81 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Wyoming Township, T6N, R12W Section 4 512 6378 SW-NE-SW 593 -1748 -1155 513 6806 SE—NE—SW 597 -1746 -1149 514 6736 SE-NW-SE 598 -1750 -1152 515 6620 SE-NE-SE 602 -1753 -1151 516 6552 NW—SE-SW 593 -1753 -1160 517 6784 NW-SE-SE 599 -1757 -1158 518 6528 SE-SW-SW 595 -1764 -1169 Section_3 519 7437 NW-NW-NW 595 -1740 -1145 520 7347 SW-NW-NW 594 -1741 -1147 521 6630 SW-NW-NE 598 -1746 -1148 522 7546 SW-NE-NE 605 -1763 -1158 523 6717 NW-SW-NW 595 -1744 -1149 524 6582 NE-SE-NW 594 -1738 -1144 525 7537 NE-SW-NE 598 -1748 -1150 526 6631 SE-SW-NW 603 -1747 -1144 527 6466 SW-SE-NW 598 -1740 -1142 528 7484 SE-SE-NW 599 -1741 -1142 529 7005 SW-SE-NE 607 -1764 -1157 530 6912 NW-NE-SW 594 -1738 -1144 531 7197 NW-NW-SE 606 -1755 -1149 532 6714 SW-NW-SW 595 -1745 -1150 533 5004 SW-NE—SW 607 -1754 -1147 534 6494 SE-NE-SW 603 -1753 -1150 535 7425 SE-NW-SE 619 -1784 -1165 536 6924 NW-SW-SW 602 -1758 -1156 537 8854 NW-SE-SW 613 -1775 -1162 Section 2 538 6536 NE-NW-NE 604 -1786 -1162 539 6670 SW-NW-NW 614 -1780 -1166 540 7087 SE-NW-NW 608 -1784 -1176 541 8261 SW-NW-NE 607 -1788 -1181 Section_Z 542 21425 NW-NW-NW 646 -1821 -1175 543 21237 NE-NE-NW 692 -1869 -1177 544 21407 NE-NW-NE 729 -1912 -1183 545 22502 CNE/4-NE 680 -1867 -1187 546 21781 SE-NW-NW 675 -1863 ~1188 82 Well Permit Section Ground Traverse Traverse No. No. Location Elev. Ls Top Ls Top S.L. Datum Kent County, Wyoming Township, T6N, R12W Section 7 547 22299 CS/2-NE-NW 700 -1879 —1179 548 24170 NW-SW-SW 680 -1875 -1195 549 24870 SE-SW-NW 640 -1840 -1200 550 25364 NE-NE-SW 678 -1876 -1198 551 8675 NW-SW-SW 602 -1885 -1283 Section 8 552 21669 NE-SE-NW 596 -1783 -1187 553 25314 SW-SW-NW 595 -1787 -1192 554 21840 SW-SE-NW 596 -1786 -1190 555 6943 SW-SW-NE 600 -1786 -1186 556 7036 SE-SE-NE 608 -1791 -1183 557 13858 SE-NW-SW 596 -1791 -1195 558 5946 CS/2-NE-SW 601 -1794 -1193 Section_9 559 6653 SW-SE-SE 633 -1810 —1177 Section 11 560 6424 SE-SW-SW 675 -1866 -1191 APPENDIX III DOLOMITE PERCENT FROM TRAVERSE LIMESTONE APPENDIX III DOLOMITE PERCENT FROM TRAVERSE LIMESTONE Well Depth Below Top of Traverse Ls No. well Name ‘ Operator 0-5 5-10 10-20 20-30 30—40 feet feet feet feet feet 2 R. Terpstra No. 1 - 30 70 85 55 X Perry, Gould, & Cross 3 Cross No. 2 - Oil 25 85 92 X X Producers 7 R. Bronkema No. 1 - 68 88 14 12 X Sprenger Brothers 9 A. Lipski No. 1 - Mesel 3O 70 X X X & Spielberg 16 F. T. White No. 3 - 25 34 14 X X Turner Petroleum Corp. 19 R. Bronkema No. 2 - 26 50 16 X X Gulf Refining Company 24 F. Cook No. 1 - George 16 20 6 X X Kernodle 28 F. T. White - Turner 16 12 11 10 X Petroleum Corp. 32 C. Den Boer No. 1 - 10 10 6 X X M. H. Bauman Refining Company 44 A. E. Raup No. 1 - Gulf 20 22 16 5 X Refining Company 46 J. Masterson No. 1 - 14 30 8 X X J. C. Newell, Tr. 47 A. E. Raup No. 3 - 35 14 9 13 X J. C. Newell, Tr. 63 Daverman No. 1 - 28 35 30 14 6 Columbia Oil & Gas Co. 83 84 Well Depth Below Top of Traverse Ls No. well Name ' Operator 0-5 5-10 10-20 20-30 30-40 feet feet feet feet feet 64 J. Zokoe No. 1 - 10 28 7 X X American Drilling Co. 75 McKay No. B-1 - Twin 22 18 15 X X Drilling Company 89 Sutter, et al No. 1 — 50 85 38 26 4 Swanson Consol. Oil Co. 99 R. H. Lauer No. 1 - 20 8 20 10 X Lenoran Petroleum Co. 121 M. Wisniswski No. 1 - 35 20 10 5 X Smith Petroleum Co. 136 W. H. Clarke No. 1 - 32 20 12 X X Smith Petroleum Co. 137 W. & A. Bergman No. 1 - 26 8 5 X X R. W. Atha 144 F. McKay No. 1 - Twin 12 15 9 X X Drilling Company 149 Park No. 4 - Twin 14 8 4 X X Drilling Company 171 F. Sund No. 1 - Turner 16 12 8 5 X Petroleum Corp. 172 S. Kuiper No. 1 - 35 20 11 X X Welsh Oil Company 235 J. Kuiper No. 1 - North 28 12 10 4 X American Drilling & Production Company 267 L. S. Wells No. 1 - 15 X X X X Fisher-McCall Oil & Gas Company 269 Doyle No. 1 — Fisher- 22 12 16 14 X McCall Oil & Gas Co. 277 Lincoln Country Club 16 7 6 6 X No. 1 - Twin Drilling Company 297 Handley & O'Sullivan 26 20 22 8 X No. 4 - Smith Petroleum Company 305 G. Riddering No. 3 - 14 18 8 X X Smith Petroleum Co. 85 Well Depth Below Top of Traverse Ls No. well Name ‘ Operator 0-5 5-10 10-20 20-30 30-40 feet feet feet feet feet 312 G. Riddering No. 1 - 18 14 12 X X Smith Petroleum Co. 319 Synder-McGrath No. 1 - 3O 16 11 8 X Michigan Devonian Petroleum Company 321 Newhouse No. 3 - 16 18 11 X X Fisher-McCall Oil & Gas Company 359 Grand Rapids Plaster Co. 15 18 9 5 X No. 1 - Smith Petroleum Company 372 Smith-Burrows No. 1 - 18 25 19 11 5 Cryden Petroleum Corp. 374 Powers No. 1 - Voorhees 18 20 1O 12 9 Drilling Company 384 G. & C. Engelsma No. 1 - 22 15 12 5 X Smith Petroleum Company 398 Whalen No. 3 - Smith 14 10 13 12 X Petroleum Company 401 Story No. 1 - MacCallum 18 20 10 10 X & Herr 404 Laquae-Fletcher No. 1 - 18 12 10 6 8 Swanson Consol. Oil Co. 406 Zeeff No. 1 - Smith 12 15 5 5 X Petroleum Company 418 Cudahy et al No. 2 - 14 16 10 X X Smith Petroleum Company 428 Van Euwen No. 1 - Smith 26 18 8 8 4 Petroleum Company 433 Renihan No. 2 - Ide & 28 16 11 9 14 Glavin 452 Sagman No. 1 - R. W. 12 10 19 9 4 Atha 468 Orlik No. 1 - Wolverine 14 8 9 13 X Natural Gas Company 478 Van Dyke No. 1 - Swanson 12 16 10 7 X Consolidated Oil Company 489 A. Heald No. 1 - 14 20 14 9 4 R . Wright 86 Depth Below Top of Traverse Ls Well No. Well Name ‘ Operator 0-5 5-10 10-20 20-30 30-40 feet feet feet feet feet 492 Gilbert Estate No. 7 - 11 16 13 8 3 Smith Petroleum Company 496 Johnson No. 6 - 10 12 9 6 3 Wolverine Natural Gas Company 508 W. Gilbert No. 10 - 18 15 14 7 10 Smith Petroleum Company 518 Grand Rapids Trust Co. 16 X X X X N00 1 - H. CO Willialns 529 Grand Rapids Gravel No. 20 24 7 8 4 1 - Twin Drilling Co. 533 Grand Rapids Gravel No. 12 10 9 9 5 1 - Cryden Petroleum Corp. 539 Alabastine Co. No. 1 - 12 8 11 6 4 Hogan Brothers 558 H. A. Chapin No. 1 - 8 12 11 8 10 Charles Harrison 559 Tanglefoot No. 1 - 10 10 10 7 8 R. W. Atha "I1411111111111s