'allallynzlwurllllwwilll ' ,. f LIB R A R Y m”,- Michigan Sr are a University . _—-, ha" *— ‘7 This is to certify that the thesis entitled APPLE $R®EFT£3 'Reutreb ”Tu \r‘ACMQNG, presented by Worm“ J. [(13214 has been accepted towards fulfillment of the requirements for 3L1} dggree in Angw-HMJ .- e 'auuz FINES; V: St per any per its-.1" C. 2 «BURNING [£8th X‘EEIMQ: Place in been retun: 2'; remove charge from circulatiuu recards 0W22 ,_,__Jl_ , -_ APPLE PROPERTIES RELATED TO PACKAGING BY Thomas J. Kusza A DISSERTATION Submitted to Michigan State University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Department of Agricultural Engineering 1979 ABSTRACT APPLE PROPERTIES RELATED TO PACKAGING BY Thomas J. Kusza The effects of controlled atmosphere (CA) storage on the mechanical prOperties of Red Delicious, Red Delicious Promaline (spayed at blossom with promaline) and Ruby applies were studied. Compression tests on apples taken from four CA rooms Opened at intervals over a 5% month period showed decreases in the modulus of elasticity of 0.60, 1.02 and 1.14 MPa for Red Delicious, Red Delicious Promaline and Ruby varieties, respectively. Apples kept at room temper- ature, (23°C), for seven days after removal from CA storage had additional decreases of 0.49, 0.45 and 0.71 MPa for Red Delicious, Red Delicious Promaline and Ruby respectively when compared to apples two days out of storage. Strain values decreased over the total storage time 0.017, 0.025 and 0.021 for the Red Delicious, Red Delicious Promaline and Ruby varieties. Seven days of conditioning produced increased strain values when compared to two days of conditioning in 75 percent of the cases for all three varieties. Thomas J. Kusza A damage boundary curve for pairs of apples was developed in the laboratory using a shock machine. Level of fruit bruising and percentage of change in grade were used as damage criteria. A change in velocity of 1.68 m/sec or equivalent free-fall drOp height of 0.145 m produced a grade change from extra fancy to fancy in 10 percent of the apples with a corresponding critical acceleration level of 15 gs. Package cushioning could be selected to provide isolation from critical impact forces. The damage boundary indicates that not more than 15 gs can be transmitted to the apple in order to maintain a 90 percent grade level of extra fancy. Approved: Maj rof sor haw DepartmEnt Chairman To Jo, Matt and Rachel ii ACKNOLWEDGMENTS The author sincerely appreciates the guidance and close cooPeration of his major professor, Dr. Larry J. Segerlind, whose unending patience made this degree a reality. The author would also like to thank Dr. W. Bickert, Dr. H. E. Lockhart and Dr. C. J. Mackson for their time and counseling. iii LIST OF TABLES Chapter fibbub 01wa TABLE OF CONTENTS LIST OF FIGURES. . . . . . . . . . . . INTRODUCTION . . . . . . . . . . REVIEW OF LITERATURE. . . . . . . . CONTROLLED ATMOSPHERE STORAGE AND ITS EFFECTS ON MECHANICAL PROPERTIES. . . . . . Experimental Procedure. . Experimental Determination of Mechani PrOperties . . . . . . . . Discussion of CA Storag Effects on Modulus Values. . . . . . . 3.3.1 Two Days Out of Storage '. 3.3.2 Seven Days Out of Storage. Discussion of CA Storage Effects on Strain Values . . . . . . . 3.4.1 Two Days Out of Storage . 3.4.2 Seven Days Out of Storage. 3.5 Comments . . . . . . . . . DETERMINATION OF APPLE SUSCEPTIBILITY TO BRUISING O O O O O O O O C O O Damage Boundary Theory. . . . . Objective . . . . . . . . . Experimental Procedure. . . . . Discussion of Apple Bruising Levels Conclusions . . . . . . . . iv Page vi vii 12 14 18 21 21 24 27 29 31 4O 40 44 49 Chapter Page 5. PACKAGE DESIGN FOR MINIMIZING APPLE BRUISING . 53 5.1 Package Forms . . . . . . . . . 54 5.2 Package Design Criteria. . . . . . 55 6. SUMMARY . . . . . . . . . . . . . 61 7. CONCLUSIONS . . . . . . . . . . . . 63 8. RECOMMENDATIONS FOR FURTHER STUDY. . . . . 6S BIBLIOGRAPHY . . . . . . . . . . . . . . 67 GENERAL REFERENCES . . . . . . . . . . . . 69 Table 1. LIST OF TABLES Page CA Storage Room Conditions . . . . . . . 10 Coring Comparison-Perpendicular Versus Parallel to Apple Core. . . . . . . . . . . ll Modulus Values . . . . . . . . . . . 13 Analysis of Variance-Modulus Values-Between Groups 0 O O O O O O O O O O O 0 14 Analysis of Variance--Modulus Values Over Time. 0 O O O O O I O O O O O 0 1? Strain Values . . . . . . . . . . . 22 Analysis of Variance--Strain Values-Between Groups . . . . . . . . . . . . . 24 Analysis of Variance-~Strain Values Over Time. 0 O O O O O O O O O O O O 25 Bruise Measurements--Change in Velocity. . . 47 Bruise Measurements--Critical Acceleration. . 48 vi LIST OF FIGURES Figure Page 1. Modulus values versus time (two days out of storage) . . . . . . . . . . . . . 15 2. Distribution of modulus values (MPa) R-D (two days out of storage) . . . . . . . . . 16 3. Modulus values versus time (seven days out of storage) . . . . . . . . . . . . . l9 4. Distribution of modulus values (MPa) R-D (stored for 5% months) . . . . . . . . 20 5. Strain values versus time (two days out of storage) 0 O O O O O O O O O O O O 23 6. Strain values versus time (seven days out of Storage) 0 o o o o o c o o o o o o 26 7. Shock pulse comparison . . . . . . . . . 32 8. Damage boundary for pulses of same peak acceler- ation and same velocity change. . . . . . 34 9. Damage boundary . . . . . . . . . . . 35 10. Determination of critical velocity change. . . 37 11. Determination of critical acceleration level. . 39 12. Experimental half sine shock pulse . . . . . 42 13. Apple package mounted for shock testing . . . 45 14. Damage boundary--10 percent grade change . . . 50 15. Damage boundary--66 and 73 percent bruising . . 51 16. Static stress Pa . . . . . . . . . . . 57 17. Static stress KPa polyurethane ether 2 pcp, 12" drOp height. . . . . . . . . . . 59 vii CHAPTER 1 INTRODUCTION Apples are harvested during the Fall of every year. After picking, the grower can either sell his crop or store his apples and wait for market prices to rise. If he chooses storage, the grower can use a controlled atmosphere (CA) that will slow the apple metabolism and maintain its quality. Temperature, carbon dioxide and oxygen must be metered to limit respiration in CA rooms. The objective is to maintain apple firmness which is a property desired by consumers. The firmness can be qualitatively defined as the modulus of elasticity and quantitatively measured in the laboratory. Since apples are stored in CA rooms for extended periods, it is of importance to determine whether the modulus values for the apples change during storage. Along with being a desirable consumer attribute, flesh firmness dicates a mechanical prOperty of the apple related to bruising as reported by Schoorl and Williams (1973). Nelson and Mohsenin (1968) and Schoorl and Holt (1974) stated that high modulus values were a good indica- tion of the bruise resistance of apples. 1 A study dbne by Schoorl and Holt (1974) indicated that between 20 and 50 percent of the apples reaching the market had some level of bruising. Since bruising is a major problem, it would be invaluable if a grower could know in advance the fragility or bruise resistance of a given batch of apples leaving CA storage. The grower could then take the appropriate action and provide additional protec- tion to the apples. Hammerle and Mohsenin (1966) reported that the volume of bruise increased with an increase in drOp height. If a critical drop height could be established, then the performance curves for cushioning materials, developed for the packaging industry could be applied to the selection of a packaging materials for apples. The body of this text is broken into three major parts: 1. A study of the influence of CA storage on the firmness of apple flesh. 2. To establish the critical velocity change and acceleration levels which produce bruises in apples. 3. The relation of mechanical properties to bruise resistance and how the damage boundary procedure can be used to design a package to provide protec- tion and maintain apple quality will be presented. CHAPTER 2 REVIEW OF LITERATURE The firmness of apple flesh is largely dependent upon apple maturity as reported by Schoorl and Williams (1973). The apple reaches a peak modulus value and then looses its firmness as the metabolic process continues. Nelson and Mohsenin (1968) did study the effect of 4.4°C for thirteen days and 32.2°C for one day on mechanical properties. They reported that the high temperature accel- erated the metabolic process, decreasing the modulus value and increasing the level of bruising. Their conclusions stated that apples with a high elastic modulus would ensure a high resistance to bruising under dynamic loading. No literature was found which discussed the effect of storage time in CA rooms on mechanical properties of apples. The bruising of an apple begins with a softening of the tissue resulting from the breakdown of cellwalls and consequent loss of tugor; with this is associated the release of polyphenols which are oxidized to melanin-like compounds with consequent unsightly discoloration. Assessment of bruising has commonly been by a rating system based largely on diameter of the bruise O'Louglin (1964) or by volume Mohsenin (1970). Numerous techniques have been developed to produce dynamic impacts resulting in bruising. Hammerle and Mohsenin (1966) used a vertical drop-testing apparatus to measure the effectiveness of cushioning materials in miti- gating impact forces resulting in bruising. They reported a fragility factor which is dependent upon the cushioning materials, impacting specimen and the loading rate. Nelson and Mohsenin (1968) used a pendulum impacting apparatus with a steel impacting surface to study bruising of apples stored at two different temperatures. They found inconsistencies with previous work and hypothesized that the time in storage affected the mechanical properties of the apple. Bittner et al. (1967) used the pendulum impacting apparatus to evaluate cushioning materials and their energy absorbing characteristics. Hanna and Mohsenin (1972) impacted apples in a polystyrene tray using a free-fall technique reported by the American Society of Testing and Materials (D 775-61). The investigations reported above all used single apple contact and contacting surfaces that were either steel plates or cushioning materials. Peleg (1972) reports that nearly 80 percent of the apples packaged are put in poly bags resulting in extensive apple to apple contact. Hanna and Mohsenin (1972) report that apples packed in polyethylene bags showed a 30 percent bruise level with bruises less than 1.27 cm in diameter. This indicates that three or four pound poly bags provide little protection. Schoorl and Williams (1972) studied the effect of drop height on apple bruising in trays and pattern packed cases. They found a marked difference in package protective ability in favor of the tray carton. They also noted that the quantity of bruising could be greatly affected by the equipment used for shock testing. Differences in impacting surface along with the flatness of the drOp can change the level of bruising. Horsfield (1972) used a theoretical approach developed from Hertz's contact theory to predict the level of damage from two impacting bodies. By considering the modulus of elasticity, surface radii, impact energy and shear strength the level of damage could be predicted. Unfortunately the measurement of the above quantities under dynamic conditions, to avoid errors due to viscoelastic properties, is very expensive and time consuming. It also provides only for single apple impacts and not multiple contacts that exist in case quantities. Segerlind and Fabbro (1978) studied the failure criteria for apple flesh. They concluded that apple flesh fails when a normal strain rather than a maximum shear stress exceeds a critical value. Their experiments also discounted the possibility that apple flesh fails when a normal stress exceeds a critical value. MTS Systems (1971) in conjunction with Michigan State University developed a methodology for testing the resistance of electronic components to impacts. The pro- cedure centered around using shock machines that eliminate testing problems due to frictional platen drag and flatness of drops. The procedure, called damage boundary, is re- ported in the American Society of Testing and Materials designation, D 3332-77. Damage boundary testing develops drop height and acceleration threshold levels above which damage does occur. O'Brien (1964) defined drop height thresholds for various types of fruit. Schoorl and Williams (1972) found that a 5.08 cm drOp height produces bruises on apples in full cases. Peleg (1972) evaluated two different package types and used a 2 percent grade change from extra fancy to fancy as defined by the United States Department of Agriculture for his threshold. He reported a 3.81 cm drop height threshold and a 7 g acceleration threshold for grade changes. Kipp (1971) developed a damage boundary for Golden Delicious apples in case quantities using a damage criteria of slight to serious damage. A critical acceleration level of 40 gs was reported. CHAPTER 3 CONTROLLED ATMOSPHERE STORAGE AND ITS EFFECTS ON MECHANICAL PROPERTIES The mechanical prOperties of the apple dictate its ability to survive dynamic inputs or free-fall drops. It was reported earlier that as the modulus of elasticity (E) decreases the subsequent susceptability to bruising in- creases. Also, the failure strain (e), maximum deformation prior to tissue rupture, was reported to be independent of maturity level in the apple. Since the maturity level of the apple has an over- whelming effect on the bruising and subsequent quality, the ability of CA storage to retard or stop the metabolic pro— cess in apple flesh is of major concern. An apple with a low modulus of elasticity will present problems in handling to the grower, distributor and the retailer, by requiring special precautions to minimize bruising and resulting loss of quality. The study of the effects of CA storage on the mech- anical prOperties of modulus of elasticity and failure strain are presented separately. Discussion of the data follows each section. 3.1 Experimental Procedure The apples used in this research were purchased from Lynd's Fruit Farm in Pataskala, Ohio. The apples were picked randomly from bins after they had been hand harvested. The apples were put in full telesc0ping corrugated boxes for either CA storage or transportation to the laboratory in Dayton, Ohio for testing. Three groups of apples, Red Delicious (R-D), Red Delicious-Promaline (R-D-Promaline), and Ruby were studied. R-D-Promaline were R-D apples that were sprayed at blossom with the chemical Promaline manufactured by Abbott Labora- tories, Chicago, Illinois. The purpose of the spray is to alter the apples' growing characteristics and produce a shape similar to a Washington State Fancy Red Delicious. This would produce a better apple appearance and command a higher price. Fifty apples from each group were measured for length and maximum diameter and the length diameter ratio was calculated. The R-D-Promaline group approached 1.00 while the R-D and Ruby groups were 0.87 and 0.84, reSpectively. The mean ratios proved different at the a = 0.01 signifi- cance level using a two-tailed z-test for two means. The standard deviations for the R-D-Promaline, R-D and Ruby were 0.08, 0.05 and 0.05, respectively. It can be concluded that the Promaline spray does produce an elongated apple but there is much more variation in apple size as evidenced by the standard deviations. This variation could prove costly to the grower by yielding a higher percentage of cider grade apples. A larger sample size and an accompanying consumer appraisal of the new apple should be performed. Two boxes of each apples variety with a total of six were placed in each of four CA rooms. Table 1 contains room conditions and the dates of closing and opening. Tem- perature, carbon dioxide and oxygen measurements were taken at the door of each storage room at intervals of three to six days by the grower. 3.2 Experimental Determination of Mechanical PrOperties Apples brought into the laboratory were conditioned at 23°C (73°F) for either two or seven days. The 23°C tem- perature was used because there were no cold storage faci- lities available in the laboratory, and this was the average temperature in the room. The longer conditioning period was used to simulate warehousing conditions at either the wholesaler or retailer level. Using a round piece of brass tubing with a diameter of 1.68 cm, samples were cut so that only apple flesh and not core was pulled. Once removed from the apple body, the sample was cut to a length of 1.905 cm by shearing both ends 10 Table l.--CA Storage Room Conditions. Room Date Date Average Average Average No. Closing Opening Temperature(C°) C02(%) 02(%) 1 10-24-78 1-22-79 3.4* 1.4 4.0 2 11-1-78 2-13-79 2.2 1.3 5.5 3 11-1-78 3-9-79 2.5 1.6 5.5 4 11-1-78 3-28-79 3.3 1.7 5.7 *Malfunction of the refrigeration equipment allowed the temperature to rise to 6.7°C on occasion. of the sample simultaneously to provide parallel planes for loading. The cylindrical apple sample was then placed in an Instron Materials Tester, model 1130, using a 4.9 kN Tension/ Compression load cell. The crosshead speed was 10 cm per minute and the chart paper speed was one meter per minute. Due to size and shape variations of the apple, the cylindrical cut was made either parallel or perpendicular to the apple core. In order to be sure that there was little or no variation in mechanical properties between planes, two samples of fifty apples from each group were randomly selected. Cylindrical specimens were all cut parallel to the apple core for one sample and perpendicular to the core for the other sample. Average modulus of elasticity and strain failure values for each sample were used to test the following null hypothesis: H : E-Perpendicular O H : E-Perpendicular O The alternative hypothesis were: H : E-Perpendicular O H : E-Perpendicular O 11 Table 2 contains the Z-test E-Parallel E-Parallel E-Parallel E-Parallel statistics. These values were compared to the Z-values of 2.326 at an a = 0.01 and only the strain failure sample for the Ruby group rejected the null hypothesis. Table 2.—-Coring Comparison-Perpendicular Versus Parallel to Apple Core. Group Z-Test Z-Value(a=0.01) Decision Red Delicious Strain Value 1.955 2.326 Accept Modulus Value 1.588 2.326 Accept Red Delicious Promaline Strain Value 1.183 2.326 Accept Modulus Value 1.808 2.326 Accept Ruby Strain Value 2.710 2.326 Reject Modulus Value 0.246 2.326 Accept 12 From the statistical analysis in Table 2 it was concluded that there was little variation in mechanical prOperties of the apples relative to the orientation of the specimen. Therefore, cyclindrical specimens were taken from the apple either perpendicular or parallel to the stem-caylax axis with little concern for biasing the results. Modulus of elasticity values were calculated using the slope from the initial loading to the point of primary rupture. This represented the linear portion of the curve and elastic range of the sample and resulted in a secant modulus. The strain at failure was calculated using the displacement of the primary rupture point. 3.3 Discussion of CA Storage Effects on Modulus Values Table 3 contains the modulus of elasticity values for the three apple groups over the time period studied. Schoorl and Williams (1973) reported no variety differences in mechanical properties as they relate to bruising. They investigated Delicious and Jonathan varieties purchased from a commercial packing house. The study did not mention the date when the tests were conducted, storage conditions at the packing house nor the storage conditions in the laboratory. These factors all contribute to the maturity level and subsequent bruise resistance of the apple. The sample size consisted of only two cases of each variety and since their unit of evaluation was a full case this provided little comparison. 13 ommum>m 30mm cw moaflfimm cm I « coaumn>ma cumeamum I .o.m mm.o mm.~ mm.o mm.H mm.o mm.m h mhImIv mm.o vm.~ ow.o ov.m mm.o mm.m m mnIHMIm ¢N.o mm.m om.o mh.H Hm.o mH.N b mhImHIm Hm.o mm.m mm.o mm.m m~.o on.m m mthHIm mm.o He.m om.o Ho.~ m~.o m¢.~ h mhINNIN mm.o mo.m mv.o H>.m mm.o eo.m m mnImHIm Hm.o hm.m vm.o om.H om.o No.~ h mhININ em.o nm.m om.o vo.m om.o mm.m m mbImNIH I I om.o mv.m I I N mhIhmIoa mm.o mm.m I I I I m mnImNIoa I I I I vv.o mv.m m mnImHIoa Amazs.a.m Amazc.m Ammzs.o.m Ammzc.m imazv.a.m Amaze.m emconpsacoo mama mama mo .02 wnsm ocflameoum msoflowaoo pom mzoflowaoo pom anonw .mmsam> madneozun.m manna 14 Using a one-way classification for statistical analysis Table 4 indicates a significant difference in modulus values at the a = 0.01 level between the groups. The Ruby apples have modulus values 14 percent larger than the other groups and were initially firmer. Table 4.--Analysis of Variance-Modulus Values-Between Groups. Source of Degrees of Sum of Mean Variation Freedom Squares Square F Varieties 2 10.09 5.04 36.00 Error 144 20.48 0.14 Total 146 30.57 3.3.1 Two Days Out of Storage Figure l is a plot of the modulus values for the apple samples two days after removal from CA storage. The apples were held at 23°C for the two days. The modulus value of each variety decreased relative to the October values. Figure 2 is the distribution of modulus values for the R-D variety. There is a decrease in the March group, stored for 5% months, compared to the October group. Corre- lation coefficients of -0.79, -0.93 and -0.78 were calcu- lated for the Ruby, R-D and R-D-Promaline groups, respec- tively. The lowest correlation of r = -0.78 indicates that at least 61 percent of the variation in modulus of elasti- city is explained by the time in storage. Table 5 is an analysis of variance of the modulus values within each Modulus Values (MPa) 15 Ruby 0 R-D O 4.00—1 R-D Promaline C] C) C) C) 3.50 .. C) E! 3 00 —— C) C) (D C) C) 2.50.... [3 0 El 2 00 "‘ D C] 1.50 —— 1.0 _ ° 1 I 1 l I l 1 OCT NOV DEC JAN FEB MAR APRIL Time (Months) Figure l. Modulus values versus time (two days out of storage). Class Frequency (Percent) 16 OCT 24 (No Storage) MAR 28__ _ A (5% Mo. Storage) 50—4 I I“ ' I I I ' I 40.4 I \ ’ I ’ I ’ I I 30.— I ’ I ’ I I I 20-— I \ \ ’ I / I 10-— I \ / \ ’ \ I, \\ —\l‘ (I I I I ’F I I 0-1 1.2 1.16 2.l0 2.'4 2.8 3.2 3.6 4.0 4.4 4. Figure 2. Distribution of modulus values (MPa) R-D (two days out of storage). 8 17 Table 5.--Analysis of Variance--Modulus Values Over Time. Degrees of Sum of Mean Source of Variation Freedom Squares Square F Groups Red Delicious 4 14.90 3.72 23.25 Red Delicious Promaline 4 57.44 14.36 102.57 Ruby 4 56.14 14.04 117.00 9.2.225. Red Delicious 243 37.74 0.16 Red Delicious Promaline 245 33.90 0.14 Ruby 243 28.92 0.12 1211. Red Delicious 247 52.64 Red Delicious Promaline 249 91.34 Ruby 247 83.06 18 group. The data show that there is significant differences at the a = 0.01 level between apples stored in CA rooms. Modulus values of apples tested in October versus those tested at the end of March, showed significant de- creases with time. Eighteen, 30 and 29 percent decrease in modulus of elasticity values were recorded for R-D, R-D- Promaline and Ruby apples, respectively over the 5% month period. The Promaline spray decreased the average modulus of elasticity 0.52 MPa when compared to R-D without the spray. It appears that R-D apple sprayed with Promaline should not be stored since their firmness decreases signi- ficantly with time. This actually defeats the purpose of the Promaline to provide an improved apple in appearance to be sold later in the year. The appearance of the R-D— Promaline was more cylindrical with straight sides as opposed to a traditional R-D. Also, the variation in size was much greater with a large number being less than 5.0 cm in dia- meter. 3.3.2 Seven Days Out of Storage Figure 3 is a plot of modulus values for apples held for seven days at 23°C after removal from storage. There is an additional decrease in the modulus values when com- pared with the modulus values for apples out of storage for two days, as illustrated by Figure 4. The correlation coefficients of -0.88, -0.76 and —0.01 were calculated for the Ruby, R-D, and R-D-Promaline groups, respectively. Modulus Values (MPa) 19 Ruby v 4.00— R'” O R-D-Promaline Cl C) v 3.00- V v C) v C) 2.50-— C] 2.00- Cl C] 1.50.. 1.00- o l I l l l ML 1 OCT NOV DEC JAN FEB R APRIL Time (Months) Figure 3. Modulus values versus time (seven days out of storage.) Class Frequency (Percent) 50.. 40-— 30""I 20'- 10- Figure ‘\ °"‘“I I!) I I I Iz‘I 3.6 4. 4. 20 Seven days out of storage .1 Two days I out of storage I\ I\ I\ I l\ / \ 1.2 1.6 2.0 2.4 2.8 3.2 0 Distribution of modulus values (MPa) R-D (stored for 58 months). 4. I 4 21 When comparing paired two and seven day values from the same storage room there are decreases ranging from 0.18 to 1.25 MPa with an average decrease of 0.55 MPa. This demon- strates the importance of keeping apples at low temperatures in order to maintain apple firmness and consumer appeal. Comparing R-D versus R-D-Promaline, there is an average decrease of 0.45 MPa between groups from the same CA room. Again, the modulus of elasticity appears to be adversely affected by the promaline spray which reduces flesh firmness and subsequent consumer satisfaction. 3.4 Discussion of CA Storage Effects on Strain Values Table 6 contains the failure strain values for the three groups over the time period tested. Using a one-way classification for statistical analysis the strain values between groups proved to be significantly different at the a = 0.01 level as indicated in Table 7. 3.4.1 Two Days Out of Storage Figure 5 is a plot of strain values for the three groups of apples over the time interval studied. All three groups show a decrease in the strain needed to rupture the flesh when stored over a 5% month period. Correlation coefficients of -0.97, -0.81 and -0.93 were calculated for the Ruby, R-D and R-D-Promaline groups, respectively. The lowest correlation coefficient of r = -0.81 indicates that at least 66 percent of the variation in strain values can be attributed to storage time. 22 ommuo>¢ comm ca moamfimm om I a GOflUMflKrOQ UHOUCMHW l oQom 0H0.0 50H.0 MH0.0 000.0 HN0.0 NOH.0 h 0hIm Iv NHo.o moa.o HHO.o 000.0 mHo.o moa.o N mbIHMIm 000.0 50H.0 MH0.0 000.0 MH0.0 50H.0 h 0bI0HIm NHo.o moa.o NHO.o mmo.o HHo.o Hoa.o N mthHIm HH0.0 HHH.0 0H0.0 m0a.0 MH0.0 mHH.0 h 0hINNIN 0H0.0 00H.0 0H0.0 000.0 0H0.0 500.0 N 0bI0HIN 0H0.0 00H.0 NH0.0 000.0 0H0.0 HNH.0 h 0bIN IN NH0.0 MNH.0 0H0.0 000.0 HH0.0 VHH.0 N 0hI0NIH I I MH0.0 VHH.0 I I N mhthIOH 0H0.0 0NH.0 I I I I N mblmNIOH I I I I m~o.o mmH.o N mhImHIoH .Q.m m .D.m «m .Q.m «W >ndm ocfiHmsoum msoflowaoo pom moofloflaoo pom cocofluwpcoo mama mama mo uoz .mmsam> ewmuumII.o manna Strain 23 Ruby C] __ R-D A '130 R-D-Promaline C) C) U D .120.— r‘ b .110" D D CI A .100-- b A O O .090-— C) {D .OBO-H . 070 ‘4 0 1 I F I I I OCT NOV DEC JAN FEB MAR APRIL Time (Months) Figure 5. Strain values versus time (two days out of storage). 24 Table 7.--Ana1ysis of Variance--Strain Values-Between Groups. Source of Degrees of Sum of Mean Variation Freedom Squares Square F Varieties 2 0.0036 0.0018 6.00 Error 144 0.0487 0.0003 Total 146 0.0523 Table 8 is an analysis of variance of strain values within each group. The null hypothesis is rejected at the o = 0.01 significance level. Comparison of initial strain readings in October with those at the end of March, indicate the failure strain decreases 0.017, 0.025 and 0.021 for R-D, R-D-Promaline and Ruby groups, respectively. The R-D-Promaline apples were 0.011 units of strain below R-D apples from the same CA room. This indicates less force is required to produce rupture of apple tissue. 3.4.2 Seven Days Out of Storage Figure 6 is a plot of strain values for apples con- ditioned at 23°C for seven days after removal from storage. The strain values decrease with time but do appear to level off. Correlation coefficients of -0.31, -0.47 and -0.81 were calculated for the R-D, Ruby and R-D-Promaline groups, respectively. 25 Table 8.--Analysis of Variance--Strain Values Over Time. Source of Degrees of Sum of Mean Variation Freedom Squares Square F Groups Red Delicious 4 0.0206 0.0052 26.00 Red Delicious Promaline 4 0.0212 0.0053 53.00 Ruby 4 0.0181 0.0045 22.50 Error Red Delicious 243 0.0605 0.0002 Red Delicious Promaline 245 0.0304 0.0001 Ruby 243 0.0418 0.0002 Total Red Delicious 247 0.0811 Red Delicious Promaline 249 0.0516 .Ruby 247 0.0599 Strain .130 _. .120 _. .110 _. .100 .3 .090 _. .080 -u r OCT Figure 6. .070 26 Ruby 0 R-D EJ R-D-Promaline v I I I I I I NOV DEC JAN FEB MAR APRIL Time (Months) Strain values versus time (seven days out of storage). 27 Comparing paired values of two and seven day con- ditioned apples from identical rooms, 75 percent of the seven day values were larger. 3.5 Comments Controlled atmosphere storage does slow the metabolic process in apples but it does not stop it. The apple firm- ness, related to modulus of elasticity, declines while the apples are in storage and at an accelerated rate when exposed to ambient conditions. It appears that the grower must be careful to match apple quality (firmness) with price. The CA storage pro- cess is designed to delay the release of apples to the market until prices rise, but if consumer dissatisfaction occurs the procedure collapses. The strain values do show a decrease but not markedly. The total decrease is small and there is an increase in the seven day values relative to the two day values. This could be explained by the corresponding water potential of each of the groups. Murase (1979) reported that the water poten- tial level for tomato epidermis alters the critical strain value for failure of vegetative tissue. This relationship may hold true for apple tissue. The decrease in modulus of elasticity and subsequent increase in bruise potential, should specify the level of packaging used to ship from the grower to the market. Judicious selection of packaging materials can negate the 28 weakening of the apple flesh and provide a greater assurance of high quality fruit arriving at the store shelf. CHAPTER 4 DETERMINATION OF APPLE SUSCEPTIBILITY TO BRUISING Apples are often mechanically harvested by tree trunk shaking equipment. Separated from their tree limbs, the apples free-fall into a catching frame, which collects the apples and loads them into large bins. The harvesting procedure often produces impacting of apples into tree limbs causing flesh rupture and subse- quent bruising. Although the problem has been studied, no feasible solutions have been developed. One factor minimi- zing the problem is the apple level of maturity and conse- quent firmness. During this stage of the processing cycle the apple is at a maximum resistance to bruising due to its high modulus of elasticity value. But what about subsequent impacts encountered during shipping and the magnitude of bruising? Chapter 3 showed that CA storage can slow the reduction in modulus values, but it will not st0p it. This dissertation supports previous work indicating that as the apple maturity increases the mechanical strength decreases. But, the question is still to determine the 29 30 magnitude of bruising associated with environmental hazards. If the severity of the hazard is of insufficient magnitude to produce bruising, then the apple will survive distribu- tion with no increase in bruise level. All distribution networks require the transfer of goods from one point to another. Even the grower's own high- way stand requires transfers from the packing house to the roadside facility. This movement and subsequent transfer between acti- vity centers brings about the greatest probability for incurring an impact. The physical handling of cased apples, by either pallet load or individual units, can produce a free-fall onto a variety of surfaces. The surfaces range from black-top and concrete to wooden floors. The free-fall height is dictated by the method of handling and the transfer location. Forty pound boxes of apples can be manually loaded or unloaded onto pallets or directly onto trucks. Ostrem (1979) reports that a 2.7 kN box has only a 10 percent chance of seeing a drOp over 51 cm but, it does have a 50 percent chance of seeing a drOp in the range from zero to 25 cm. The number of drops an indi- vidual case experiences is controlled by the complexity of the distribution network and the consequent transfer Oper- ations. Since a grower has little control over his product once it leaves his facility, how can protection be provided to keep bruising to a minimum? It was reported earlier that 31 the magnitude of bruising was dependent upon the impacting surface and impact drop height, yet the grower cannot change a concrete loading dock, nor can he supervise a commercial carrier in the handling of his merchandise. These two problems of control have been addressed by the packaging industry, whereby the packing material is used to provide protection from the distribution hazards. Imple- mentation of packaging procedures requires the defining of the products fragility which is the subject of the next section. 4.1 Damage Boundary Theory Consider the process of a case of apples free-falling onto a rigid surface. Kipp (1972) reports that the abrupt deceleration of the outer package at the termination of a drop is communicated to the product inside. The nearly instantaneous velocity change which takes place at the outer surface of the package upon striking the surface is accom- panied by local accelerations of many thousands of gs. Packing or cushioning material is used to minimize the shock effects by spreading the pulse over a longer time and decreasing its magnitude. Figure 7 shows qualita- tively what happens. The outer package experiences high acceleration over a short time span. The internal packaging Spreads the outer package pulse over a longer time and decreases the magnitude of the pulse. The shaded areas are effectively the same. The unshaded area represents the Acceleration 32 Outer Package Packaged Item / Figure 7. Time Shock pulse comparison. .33 rebound off the cushioning material. The total area under the Packaged Item curve produces the damaging effects. Product sensitivity to shock is dependent upon three parameters: shock pulse shape, maximum acceleration and shock pulse velocity change. Since the designer has no con- trol over the shape of the input shock pulse a "worse case" situation provides a conservative approach to the problem. Newton (1968) reports that the trapezoidal pulse encompasses other expected shapes completely. Figure 8 graphically illustrates that the trapezoidal pulse produces more damaging effects than either the terminal peak sawtooth or half sine pulse with the same peak acceleration and velocity change. With wave shape accounted for by testing methodology, the velocity change and maximum acceleration are incorporated into a damage boundary curve defining a product fragility or susceptibility to damage. The level of damage or damage criteria represents the acceptable quality expected for the apples. Bruise diameter or percentage of bruised apples per case may be defined and then will remain constant throughout the testing procedures. This will eliminate the variable of evaluation from the testing sequence. Figure 9 is a typical damage boundary curve. The curve is defined by first experimentally determining the critical velocity change and a corresponding point of damage. The velocity change is calculated by integrating the area under the shock pulse curve similar to those in Figure 7. This value (AV) can be substituted into equation 1 to 34 .omcmco Nuflooao> oEmm pcm cowumuwawoom xmmm meow mo wowasm new mumpcson momEmn 00cmno >0HO0H0> .m whomflm mm on m HoNommu IFLI H H p. B I, \ I \ I / I \\\ \I\’\I~VA I \\ I’V\\| ’1 \ I/\| meDm wcfim MHME Ir\\ mmasm nu00u3mm xmom Hmcflfiuoa coflumuoawood game U) 0 C- . o . u-I .I.) m u o H . o o . 0 <2 \ Veloci ttttttttttt Figure 9. Damage boundary. 36 calculate the critical drOp height (hf). The 9 represents AV = I/Zghf (1) a constant of acceleration of gravity 9.8 m/sz. The only variable of equation 1 is the free-fall drop height. Therefore, varying the change in velocity is accomplished by drOpping the product from higher or lower heights usually starting with a low velocity change. If the product integrity is not affected, the velocity change is increased in increments until the damage criteria is ex— ceeded. Figure 10 graphically illustrates the procedure. The corresponding change in velocity, or critical drOp height, now defines the abscissa of the damage boundary. Drop height values greater than or equal to the critical drOp height will produce damage, while corre5ponding values less than the critical threshold do not produce the failure criteria. It should be noted that the damage boundary only considers the effects of single drops. Multiple drops of less than critical levels may cumulatively produce fatigue or even damage. This point will be discussed later. The hf can be compared to environmental data as to whether or not a hazard of this magnitude exists in the field. If a drOp height of this severity will not be en- countered, then no further testing need be done. If values of hf or larger exist, then the critical acceleration level must be determined. The critical 37 8 4 .H K 4.) (U LI .3 0 fl Time Figure 10. Determination of critical velocity change. 38 acceleration is expressed in constant units of acceleration of gravity (9.8 m/secz). A fragility of 20 gs means that an acceleration of 20 times that of gravity is required to produce damage. Evaluation of the critical acceleration is accom- plished by first selecting a change in velocity, which is equal to the design drOp height, or the expected free-fall height present in the environment. With the drop height determined, the impacting sur- face is set to induce an acceleration level below the anti- cipated failure value. If no information is available, then a minimum acceleration level is used. The product is drOpped onto the impacting surface and then inspected relative to the damage criteria. If no damage occurs, the impacting surface is successively changed to produce a larger acceleration level. This process is repeated until damage occurs. Figure 11 graphically illus- trates the procedure. Since dr0p height is held constant, the curve areas are identical and only the shape changes. The damage producing acceleration level becomes the ordinate of the damage boundary curve. Referring to Figure 9, the two lines can be connected and their point of intersection is usually rounded. If the connecting point is of concern, it can be calculated using a format cited by Newton (1968). The shaded area in Figure 9 represents damage pro- ducing values. Theoretically the area in Figure 9 from the 39 II” IIMJ I \\ \\ Time Acceleration Figure 11. Determination of critical acceleration level. 40 y-axis to the damage boundary indicates that as long as the critical velocity change is not exceeded, the product can experience an infinite acceleration level without failure. The product is said to act as its own isolator. Once the critical velocity change is exceeded by environmental hazards, a cushioning material must be employed to account for the difference in the environmental stress, and product's ability to withstand abuse. The packing material must keep the acceleration levels transmitted to the product between the x-axis and the damage boundary. 4.2 Objective IPrevious work has been centered in establishing bruise levels and corresponding damage boundaries for full case quantities of apples. Little attention has been paid to the apple's mechanical strength or the modulus of elasti- city. Also, full case quantities allow low replication and make bruise analysis difficult. The following procedure is designed to yield a damage boundary for a single apple impacted onto another apple. This will simulate in-case conditions and simplify the analysis by concentrating on a single point of contact. 4.3 Experimental Procedure A Lansmont model 65 shock machine was used to deter- mine apple damage boundaries. The machine carriage produces vertical impacts which are essentially flat. The perfectly flat drops are a worst case situation, since all forces are 41 concentrated in the vertical direction. A nitrogen braking system arrests the carriage during rebound to provide only one drOp. The carriage surface is of sufficient strength and rigidity to remain flat and horizontal under test stresses and is guided in free-fall to prevent rotation or translation in other directions. An Endevco Model 2272 piezoelectric accelerometer was securely fastened to the shock machine carriage to sense the impacting acceleration. The accelerometer had a charge sensitivity of 2.93 pc/g and a transverse sensitivity of 0.7 percent maximum. The output of the accelerometer was fed into an Endevco Model 2718A signal conditioner. The full-scale g output was set for 500 gs per five volts. The internal low frequency and high frequency cut-off filters were set at 0.3 and 3300 Hz, respectively. The output of the signal conditioner was input to a Tektronix Model T912 storage oscilloscope. The scope was wired to an external trigger to allow capture of the tran- sient shock pulse for analysis. A Polaroid camera Model CSA was used to record the shock pulses. The maximum accel- eration and velocity change are calculated from a photo- graph of the shock pulse. Figure 12 is a sample shock pulse. The time base was set at 0.5 msec per division and the vertical scale at 50 gs per division. The change in velocity is determined by integrating the area under the curve. The area of each 42 Figure 12. Experimental half sine shock pulse. 43 square centimeter is calculated by substituting the scope settings into equation 2. Using the scope (gs/div.)(sec./div.)(9.8m./sec.2) = AV (2) values, the area of each square is 0.245 m/sec. The total area under the curve is 12.4 division. Multiplying number of division by area per division yields a total velocity change of 3.04 m/sec. By subtituting 3.04 m/sec into equation 1, the equivalent drOp height of 0.47 m is calcu- lated. The maximum acceleration level is read directly off the shock pulse. The total number of vertical divisions between the baseline and the shock pulse peak are multiplied by the vertical scale sensitivity. Figure 12 has a vertical displacement of 4.2 division multipled by 50 gs/division yields a maximum of 225 gs. Most apple damage results from apple to apple con- tact, i.e., poly bags. To simulate these conditions, two apples were bound together and the bruising between the apple surfaces was investigated. Shrink wrap, 100 gauge polyvinyl chloride, was used to overwrap the apples and maintain the contact area with no slippage or multiple impacting conditions. The 100 gauge pvc did not compress the apples causing initial failure. The apples were wrapped using a Weldotron L-Bar sealer and then placed stem down on a flat surface. Heat was applied using a hand shrink gun, drawing the plastic film. By keeping the apples on a flat 44 surface during shrinking, a uniform orientation was main- tained for testing. The plastic shrink wrap energy did not pre-load or compress the apples. Figure 13 shows the apple pack mounted on the shock machine awaiting test. The orientation of the pack provides all acceleration forces to be vectorially concentrated in the vertical plane. This provides the most severe situation which can be encountered. The apples were pressed onto a metal spike to provide a consistent orientation. The apples were not restrained on the table because the size variation between apples made fixturing difficult. Also, restraining required the pre-loading of specimens providing initial compression and thus different results. Rebounding apples were caught to prevent additional impacts. Single packs of apples were tested with the procedure and equipment previously discussed in this section. The change in velocity and acceleration levels were controlled to pre—determined magnitudes. After mounting, the packages were impacted once, removed from the table and stored for 24 hours. Bruise diameter measurements were then made using a steel template with holes of 0.635, 0.952 and 1.270 cm in diameter. 4.4 Discussion of Apple Bruising Levels Red Delicious apples used in the bruise assessment had been CA stored 129 days, processed, packaged and cold- stored for six days at l.7°C. 45 Figure 13. Apple package mounted for shock testing. 46 Fifty of these apples were tested using the pro- cedure outlined in Chapter 3. They had an average modulus of elasticity of E = 2.89 MPa with a standard deviation of 0.43 MPa. The average rupture strain was 5 = 0.101 with a standard deviation of 0.0128. Table 9 contains the bruise assessments for the three free-fall drOp heights investigated. Forty apples or twenty shrink packages were dropped distances of at 0.145, 0.31 and 0.47 m. The bruise diameters were measured and placed in four groups. The percentage of bruises and a cumulative distribution were calculated for each height. Increasing the velocity change or equivalent free- fall drOp height produces bruises of larger diameter in each case. By increasing the drOp height from 0.145 to 0.47 m the percentage of apples with bruises greater than 1.270 cm increased from 10 to 65 percent, respectively. The low drop height of 0.145 m had its greatest percentage of fruit, 47.5, in the smallest bruise category. Bruising was not always the same between both apples. One apple might be bruise free while the other apple might have a bruise greater than 1.270 cm. This phenomena occurred on either top or bottom apple with no regularity. Table 10 contains bruise levels of apples drOpped from the same equivalent free-fall height of 0.69 m, but subjected to different acceleration levels. Acceleration levels of 15, 30 and 60 gs were investigated. By increasing the acceleration level from 15 to 6095 the percentage of 47 0.00H 0.m0 + OhN.H v0.m h¢.0 0.mm 0.0a chN.HINm0.0 00.m 5v.0 0.mN m.N Nm0.0Imm0.0 @0.m 50.0 m.NN m.NN mm0.0I0 v0.m 50.0 0.00H m.Nm + ohN.H 0v.N Hm.0 m.h¢ m.> ohN.HINm0.0 0v.N Hm.0 0.0v m.h Nm0.0Imm0.0 0v.N Hm.0 m.Nm m.Nm mm0.0I0 0v.N Hm.0 0.00H 0.0a + 05N.H 00.H mvH.0 0.00 m.>N 05N.HINm0.0 00.H mvH.0 m.N0 0.mH Nm0.0Imm0.0 00.H mva.0 m.hv m.hv mm0.0.0 00.H mwa.0 va coflusnfluumwo va coflusnauumflo A500 omflm omfloum Aoom\av wuwooao> A50 unmwm: omwzum o>wumHSEDU omfioum cfi omcoco moan .>uflooHo> cw 00cm50IImucmEoH5mmoz omwsumII.0 manna 48 0.00H 0.mv + 00N.H 00 0.mm 0.0a 0hN.HINm0.0 00 0.0v 0.mH Nm0.0lmm0.0 00 0.mN 0.mN mm0.0I0 00 0.00H m.NH + 0hN.H 0m m.N0 0.0v 05N.HINm0.0 om m.h¢ m.NH Nm0.0Imm0.0 0m 0.mm 0.mm mm0.0I0 0m 0.00H 0.0a + 0hN.H ma 0.00 m.N 05N.HINm0.0 mH m.hm m.NH Nm0.0lmm0.0 ma 0.mh 0.mh mm0.0I0 ma COHUDDHHHmHD mmflfihm va COHflDQHHflmflQ AEUV ONHW OmHDHm ADV H0>O1H A00 m>HumHSEDU meDHm :Oflumumamood .coHumuoHoood HMOHuflnUIImucoEoHommoZ omHSHmII.0H manna 49 apples with bruises greater than 1.270 cm increased from 10 to 45 percent, respectively. The low acceleration level of 15 g had its greatest percentage of apples, 75, in the smallest bruise category. The data in Tables 9 and 10 permit a damage boundary to be drawn for a specified damage criteria. Figure 14 uses a damage criteria of 10 percent grade change from extra fancy to fancy as defined by the U.S.D.A. This means that an environmental hazard exceeding the critical velocity change of 1.68 m/sec and having a maximum acceleration equal to or greater than the critical acceleration level of 15 gs will produce damage. Ten out of every one hundred apples will have bruise diameters in excess of the U.S.D.A. criteria of 1.270 cm. Figure 15 is another damage boundary with the cri- teria of bruises with diameters greater than 0.635 cm. Two percentage curves are drawn to illustrate that as the critical velocity change and critical acceleration level are increased the number of bruises will also increase. 4.5 Conclusions Larger changes in velocity and acceleration will produce subsequent larger bruise diameters in each set. The damage boundary concept can be used to predict the effects of environmental hazards of shock on the quality of apples. Grade changes, levels, and magnitudes of bruising can be anticipated. 50 120 -— \ 110 - 100 - 90'7 DAMAGE 80 _j AREA 70... \ 60 -: I 50 _. 40 -5 30 - 20 .4 ;::\\\ 10 -1 Acceleration (9) I I I I I I I I I l 0 0.50 1.00 1.50 2.00 2.50 3.00 3.5 4.00 4.5 5.00 Change in Velocity Figure 14. Damage boundary--10 percent grade change. 120d 110- 100- 90-I 80- g) ( 60- 50. Acceleration 40‘ 30‘ 20- 10- 51 [223% Bruising 66%I&——-' Bruising 7 , \\\\ ///A O I 1 I I I I I i I I I) 0.50 1.00 1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 Figure 15. Change in Velocity (m/sec.) Damage boundary--66 and 73 percent bruising. 52 Using the damage criteria of a 10 percent grade change, the critical velocity change and the critical accel- eration level will be 1.68 m/sec and 15 gs, respectively. As the apple maturity increases it will become more susceptible to bruising and damage boundary will shift towards the origin, yielding a larger damage area. CHAPTER 5 PACKAGE DESIGN FOR MINIMIZING APPLE BRUISING The design Of a package begins with the defining Of the objectives or goals Of the user. The functions Of the package must then be Optimized to provide a feasible package form. For the grower, a number of criteria must be met by the package. First, the protection afforded the apples is Of paramount importance. If the number Of bruises exceed consumer acceptance levels, then sales will accordingly reflect dissatisfaction. Second, the package materials and construction must be economically consistent with the price the consumer is willing to pay for the product. Often the apples and package are separated before the consumer views the product and the buyer does not appreciate the additional expenditure and its associated value. It is not uncommon for the package to product cost ratio to exceed three to one for some consumer items. Third, the packing Operations must be considered to minimize labor and capital investment while maximizing output. Many growers have small production Operations limiting their capabilities. Fourth, the package 53 54 should be convenient for the consumer to handle. Fifth, the package should not present any problems Of disposal for either the retailer or the consumer. The description Of package functions could be con- tinued to include areas Of distribution, processing, motiva- tional concerns, etc. The list will be dependent on the marketing strategy which includes pricing, retailing outlets, advertising, etc., or in other words--the Objectives. 5.1 Package Forms Apple packages can be divided into primary and secondary groups. The primary grouping provides the con- tainment and is best exemplified by the polyethelene bag. This category also includes inserts or spacers, and pads. Secondary packaging starts with the corrugated box used tO assort the primary packs into economic units Of order. This continues with a pallet used to stock upwards Of forty boxes into a unit load for shipping. The minimum level Of primary packaging is the poly- ethelene bag. Its function is solely containment Of a specified quantity Of apples. It promotes efficient handling by consumer and retailer and it forms the basic unit Of purchase. It is inexpensive, but it provides no protection for the apples. Peleg (1972) reported on a shrink wrap Of four apples into stick pack. This package results in a tight unit minimizing the movement Of the apples in the secondary 55 box and subsequent contacting and resultant bruising. Peleg did find that the critical velocity change increased in stick pack over the polyethylene bags from 3.1 tO 3.5 m/sec. The equivalent free-fall drop height using equation 1 are 0.5 and 0.6 m., respectively. Premium apples are packaged in molded pulp trays providing individual cells for complete isolation from other apples. These trays can be displayed with apples at the retailer level. This package reduces the bruise level, but it is very labor intensive resulting in high packaging and subsequent apple costs. Hanna and MOhnsenin (1972) tested a polystrene package providing complete encapsulation for six apples. This pack is very expensive for both materials and labor, but it provided damage protection from a free-fall drOp height Of 0.9 m. Somewhere in between the polyethylene bag and the polystyrene package is the Optimum design. The rationale for choosing between alternative packages is the Optimiza- tion Of cost and protection afforded the apple, giving the consumer maximum utility for his dollar. 5.3 Package Design Criteria Economic considerations are important criteria in choosing the final package design. But, as long as all Of the factors contributing cost such as materials, labor, transportation and overhead are included, the decision is 56 fairly straight forward. Comparison with the retail price for apples will dictate the expenditure for packaging. Designing a package for protection has been a com- plex decision because Of product fragilities and the vast number Of packing materials and subsequent configurations to choose from. Hammerle (1966) investigated a fragility factor, which he defined as the product weight times the constant acceleration Of gravity, for four different materials. By drOpping apples from increasing heights and measuring damage he was able to show that the cushioning materials began to isolate damaging forces as the heights were in— creased. Unfortunately, the data does not provide design criteria for quantity Of cushioning material used nor dO they take into account product variation due tO maturity. Also, the data only considers apple damage and they are use- ful for only single apple configurations. Chapter 4 described the damage boundary theory and concluded that if a critical change in velocity and subse- quent free-fall drOp height were exceeded in the environ- ment, then protective packaging is required. The level Of protection is defined by the critical acceleration level for the product. The packaging material must isolate the g forces that exceed the critical threshold or the apples will exhibit the damage criteria. Packaging materials with cushioning prOperties are quantified by performance curves. Figure 16 is a sample curve. The curve shows the peak acceleration that will be 57 Peak Acceleration 9 Static Stress Pa Figure 16. Static Stress Pa. 58 transmitted for different values Of static-stress. The static—stress is the mass Of the packaged item divided by the cushion area. The curve is not confined to any specific product or damage criteria but rather can be used for an infinite number Of situations. The designer compares the critical acceleration level Of the product to the materials ability to isolate acceleration forces. The curve in Figure 16 is the threshold. Acceleration levels and corresponding static-stress values above the curve will be isolated from the packaged product. Values below the curve will be communicated to the item. Military Handbook 304 (1972) contains curves for twenty different materials. Many Of these materials are able to provide the same level Of protection thus allowing the choice Of material to be made on cost, supply, etc. Figure 17 is a static-stress curve for polyurethane ether developed for a free-fall height of 18 inches. Refering to the critical acceleration data in Chapter 4, either the 15 or 30 9 levels can be located on the curve with protection provided by either the 4, 5 or 6 inch thickness. The static- stress working range is between 0.69 and 1.4 kPa. Using a box Of apples Of 177.9 N (40 pounds) and the working static stress range, a simple algebraic manipulation gives a cushioning range Of 0.13 tO 0.26 m2. As long as we use this amount Of material spread over the load area we will isolate every thing above 15 or 30 gs and transmit only the 15 or 30 9 level depending which one we selected. 59 .ucmflon QOHO :NH .OOQN Locum ocmsuwuzxaom max mmmuum maumum .hH whomwm 93 To m.m H6 m.~ TN «.4 mm. mm. 3. mm. 3. 3. _ A t _ _ A _ _ _ _ _ o 1|.0N m I3 m d m ,1I.00 X s w IS a I 3 u ,I 2: n I. O U sI cs 5 IE: IS: H 00H 60 With the material selected, it can then be included in the package as an insert, pad or a number Of different configurations. Once assembled, the final package should be tested, so that the design criteria was not exceeded. CHAPTER 6 SUMMARY The mechanical properties Of three groups of apples Ruby, R-D and R-D-Promaline were investigated along with the effects Of CA storage on these values. The modulus Of elasticity decreased 0.60, 1.02 and 1.14 MPa for R-D, R-D-Promaline and Ruby varieties when stored over 5% months. Comparing the modulus values Of apples that were exposed tO ambient (23°C) conditions for seven days as Opposed tO two days, the values decreased on the average 0.49, 0.45 and 0.71 MPa Of the R-D, R-D-Promaline and Ruby varieties, respectively. The modulus values for the R-D-Promaline versus the R-D variety were down on the average 0.52 MPa for apples two days out Of storage and 0.48 MPa for apples seven days out Of storage. Failure strains decreased 0.017, 0.025 and 0.021 for R-D, R-D-Promaline and Ruby varieties over a 5% month CA storage period. Comparing failure strain values Of apples 61 62 two days versus seven days out Of storage, showed an increase in 75 percent Of the seven day values over all three groups. Using a damage criteria Of a 10 percent grade change from extra fancy tO fancy a damage boundary was experi- mentally determined. The critical velocity change Of 1.68 m/sec yielded an equivalent free-fall drop height of 0.145 m. The critical acceleration level for the same damage boundary was 15 gs. CHAPTER 7 CONCLUSIONS Apples placed in controlled atmosphere storage for extended periods tend tO decrease in firmness. Quantitatively this can be defined as a reduction in the modulus Of elasticity. The effect Of controlled atmosphere storage on failure strain levels is small. They do decrease, but not dramatically. Promaline spray used on Red Delicious apples tO alter growth characteristics appears to signifi- cantly reduce the modulus Of elasticity when the apples are stored in controlled atmosphere rooms. Apples stored in controlled atmosphere rooms and then conditioned for seven days at ambient condi- tions, exhibit reductions in modulus Of elasticity value when compared to the value two days after removal from storage. Apples are bruised significantly when drOpped from equivalent free-fall heights that exist in normal handling procedures. 63 64 Damage boundary procedures can be used to define critical change in velocity and critical acceleration levels which produce bruising in Red Delicious apples. Protective packaging for apples can be designed using performance curves defining the properties Of cushioning materials. The packaging requirements for apples shipped prior to CA storage are markedly different from those apples stored for extended periods. Stored apples require additional packaging to compensate for their increased sensitivity to bruising. As the storage time increases the bruise resistance decreases causing the damage boundary tO shift towards the origin and increasing the damage re- sulting area. CHAPTER 8 RECOMMENDATIONS FOR FURTHER STUDY The modulus Of elasticity values conclusively de- creased over time indicating a loss of flesh firmness. Corresponding strain values were erratic and did not conform to a set pattern. Possibly a sample Of fifty apples is tOO small to provide a smoothing effect. A sample size Of 250 apples may show a pattern Of little or no change in strain failures over storage time. The determination Of apple damage boundary is a difficult process. Due to the variation in apple mechanical prOperty, a much larger sample than twenty pairs Of apples should be tested. This could provide some insight as to the actual distribution within each group. Due to the complexity Of shock-testing equipment and its limited availability, a more universal method of evaluating apple bruise resistance is needed. Future investigations should center around damage boundary testing Of apple groups with varying modulus Of elasticity values. Once this relationship is defined, the 65 66 percentage Of bruising can be predicted by the quantitative description Of the apple flesh firmness or modulus Of elasticity. Experimental calculation Of modulus values can be done with a compression tester. This analysis will give rapid feedback to the grower as tO the level Of protective packaging needed to insure product quality. Bruising Of apples is not only due to impact forces, but also other environmental hazards such as over-the-road vibration and compression. These hazards in combination contribute to the failure Of packaging and subsequent apple bruising. Goff (1974) investigated the effects Of a sequence Of tests modeled after the distribution environment on a group of packages. The packages were inspected at various points to measure the contribution Of each hazard to damage with a final evaluation used to evaluate the total survival rate. ASTM D-10 Committee on Packaging has developed a series Of sequences modeling the distribution environment. The apple testing should include an evaluation using a sequence including shock, vibration and compression which models a typical grower's situation. This type Of test will tie all types of package characteristics to provide protec- tion into a successful and cost effective design. BIBLIOGRAPHY Bittner, D. 1967 Goff, J. W. 1974 Hanna, M. A. 1972 BIBLIOGRAPHY R., H. B. Manbeck, and N. N. Mohsenin A method Of evaluating cushioning materials used in mechanical harvesting and handling Of fruits and vegetables. ASAE paper 66-634, St. Joseph, Michigan. U.S. Department Of Commerce, project NO. 4-35711. Michigan State University, East Lansing, Michigan, Project NO. 3108. and N. N. Mohsenin Pack handling Of apples. J. Agric. Engng. Research (1972), 17, 154-167. Horsfield, B. C., R. B. Fridley, and L. L. Claypool 1972 Kipp, W. I. 1971 Kipp: W. I. 1972 Murase, H., 1979 Application of theory Of elasticity to the design Of fruit harvesting and handling equip- ment for minimum bruising. Transactions Of the ASAE, 15(4):746-750. Feasibility study shock and vibration testing Of agricultural products. Lansmont Corporation, Montorey, California, Report 22. Product fragility assessment. Lansmont Corpora- tion, Monterey, California. G. E. Merva, and L. J. Segerlind Failure mode Of vegetative tissue. ASAE paper 79-3064, St. Joseph, Michigan. Nelson, C. W. and N. N. Mohsenin 1968 Maximum allowable static and dynamic loads and effect Of temperature for mechanical injury in apples. J. Agric. Engng. Research (1968), 13(4), 305-317. 67 '68 Newton, R. E. 1968 Fragility assessment theory and test procedure. Prepared for Monterey Research Laboratory, Inc. O'Brien, M. 1964 Fruit handling and it's associated damage. ASAE paper 64-001, St. Joseph, Michigan. Ostrem, F. E. 1979 An assessment of the common carrier shipping environment. Forest Products Laboratory, Madison, Wisconsin, Technical Report FPL 22. Peleg, K. 1972 Development Of an improved retail package for Michigan apples. Michigan State University Project MICL03069. Schoorl, D. and W. T. Williams 1972 Prediction Of drOp-testing performance of apple packs. Queensland Journal Of Agricultural and Animal Science, 29(1):187-197. Schoorl, D. and W. T. Williams 1973 Robustness Of a model predicting drop-testing performance Of fruit packs. Queensland Journal Of Agricultural and Animal Sciences, 30(3): 247-253. Schoorl, D. and J. E. Holt, 1974 Bruising and acceleration measurements in apple packs. Queensland Journal Of Agricultural and Animal Science, 31(1):83-92. Segerlind, L. J. and I. D. Fabbro 1978 A failure criterion for apple flesh. ASAE paper 78-3556, St. Joseph, Michigan. GENERAL REFERENCES Brown, G. K. and L. J. Segerling 1975 The location probabilities Of surface injuries for some mechanically harvested apples. Transactions Of the ASAE, 18(1):57-59. Foley, J. T. 1972 Transporation shock and vibration description for package designers. Sandia Laboratories Report SC-M-72 0076, July. Friedman, W. F. and J. J. Kipness 1977 Distribution packaging. Robert E. 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