A QUANTITATIVE SEDIMENTARY ANALYSIS OF THE ORDOVICIAN DEPOSITS EN THE MICHIGAN EASIN Thais {w fho Darn of M. 5., MICHIGAN STATE UNIVERSITY Laurence S. Cooke, .Ir. E956 SUPPLEM g AT m *AL INBACKOF BOOK A QUANTITATIVE SEDIMENTARY ANALXSIS OF THE ORDOVICIAN DEPOSITS IN THE MICHIGAN BASIN By LAURENCE s. QQOKE, J'R. A THESIS Submitted to the School of Graduate Studies of Michigan State University of Agriculture and Applied Science in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Department of Geology 1956 {Rs 7-10—54 ACKNOWLEDGEMENT S The author wishes to express his sincere gratitude to Dr. B. T. Sandefur. His constant encouragement was a tremendous aid in the completion of this investigation. Dr. Sandefur was extremely helpful in the editing and compiling of the final manuscript. The writer also wishes to thank Dr. W. A. Kelly for his assistance in determining the marker horizons and his constructive editing of the manuscript. Sincere appreciation is also due to Messrs. Robert M. Ives and Garland D. Ells of the Michigan Geological Survey for their great assistance in selecting the wells for this study. Dr. W. D. Baten of the Statistics Depart- ment was very generous with his time in helping with the statistical analysis. CONTENTS PAGE INTRODUCTION 000......COOOOOOOOOOOOOOOOOOOOOO0.... 1 History of Ordovician Investigation in the MiChigan BaSin 0......OOOOOOIOOOOCOOOCOOOOO... Facies Analysis ................................ Purpose ........................................ WELL SELECTION AND DISTRIBUTION .................. Stratigraphy of the Section Analyzed ........... Requirements for Well Selection ................ ~O CD (I 0‘ #7 K» F4 SBIGCtion Of wells 00.0.000000000000000000000000 LABORATORY PROCEDURE ............................. 14 Sampling MethOd ooooooooooo0.0000000000000000... lu Removal of Water Solubles ...................... 15 Removal of Acid Solubles ....................... 16 Disaggregation ................................. l7 Dispersion ..................................... l9 Sieving ........................................ 2O Pipetting ...................................... 21 Mounting and Analyzing the Sand Grains ......... 23 Laboratory Equipment ........................... 2h Errors in the Analyses ooooooooooooooooooooooooo 2a Results of the Laboratory Analyses ............. 25 LITHOLOGIC VARIATION 0.0.0....OOOOOOOOOOOOOOOOOOOO 27 Lithologic Ratios .............................. Facies Map Construction ........................ INTERPRETATION OF FACIES MAPS .................... Methods of Geological Interpretation ........... Methods of Statistical Interpretation .......... Errors Involved in Interpretation .............. Interpretations ................................ Geological Interpretation .................... Statistical Interpretation ................... REGIONAL TECTONICS ............................... Structural Relations of the Michigan Basin ..... Structural Interpretation in Relation to TeCtoniCS oooooooooooooooooooooooooooooooooooo Teetonic ASpeCt oooooooooooooooooooooooooooooooo CONCLUSIONS oooooooooooooooooooooooooooooooooooooo REERENCES 00......00.00.00...OOOOOOOOOOOOOOOOO0.. PAGE 27 29 31 31 32 36 37 37 1+5 N6 he ’47 1+9 51 52 TABLE II III IV TABLES AND FIGURES Lithology and Thickness of Section Analyzed ... Wells Used in Analysis ........................ Quantitative Analysis ......................... Lithologic Ratios ............................. Analysis of Variance of Quartz-Chart Ratios in the MiChj—gan Basin OOOOOOOOOOOOOOOOOOOOOOO FIGURE I Relations Between ISOpachs and Facies Lines ... PAGE 12 25 28 33 II III IV VI VII MAPS Outcrop Pattern and Areal Extent of the Upper and Middle Ordovician Rocks in Michigan ... Location of Wells and Partitioning of State for Statistical Analysis .................. Clastic Ratio Map .............................. Sand-Shale Ratio Map ........................... Evaporite Ratio Map ............................ ISOPaCh Map ooocoooooooooooooooooooooooooooooooo Quartz-Chart Ratio Map PAGE 10 ll Pocket Pocket Pocket Pocket Pocket INTRODUCTION History of Investigation of the Michigan Basin Subsurface investigation of the Michigan Basin has been a subject of interest for many years. But, not until the turn of the century was there enough information from deep borings to intensify the study. The main problem was the extensive cover of Pleisto- cene glacial deposits. These deposits attain a thickness of nearly 1,300 feet in certain portions of the lower peninsula. The outcrop pattern of the Paleozoic deposits is elliptical in outline, with the major axes trending north- east-southwest. Map I shows the extent of the outcrops. These sediments are arranged in concentric rings with the Pennsylvanian deposits in the center, and progress towards the outer margin through the Mississippian, Devonian, Silurian, Ordovician, and the Cambrian. Smith (1912) states, "The depth of the Basin is so small in comparison with its diameter that the inclination of its several memr hers is ordinarily between 25 and 50 feet per mile, and rarely exceeds 60 feet." In describing the areal extent of the Michigan Basin, Newcombe (1933) stated: The area comprising the Michigan Basin includes about 106,700 square miles and stretches from Fort Wayne, Indiana, on the south, to Whitefish Point near Sault Ste. Marie, Michigan, on the north, and from.west to east about 370 miles. The deepest portion, or center of the Basin, conforms (approximately to the center of the lower peninsula of IMdchigan. According to Pirtle (1932), the structures 'bounding the Basin are: the Wisconsin arch in the west, and two limbs of the Cincinnati arch in the south, the Kankakee arch in the southwest, and the Findley arch in the southeast. The northern boundary is the pre-Cambrian complex of the Canadian Shield, and the eastern boundary is the Algonquin arch. Because of the economic importance attached to the intra-basinal structures, they have been closely studied. Smith (1912) described the six best developed folds which occurred mainly near the margins of the Southern Peninsula and in Western Ontario. ~He depicts most of these anti- CIines as being relatively low and short. Some faulting has also occurred in the Basin with displacements gener- ally around 50 to 60 feet. Most of the information for his study was obtained by reconnaissance mapping and from a few well logs. Pirtle (1932) suggests that the folds within the Basin have a persistent northwest-southeast trend. And this 3 gnxrallelism.of folds is most evident in the central and eastern part of the state. He believes the folds in the suyuthwestern part of the state are different from.those in tflie central and eastern portions. They are much shorter and txrend to the northeast. He suggests they are related to tflae Kankakee arch. In his conclusion, he states; "It is 'believed that the principle folds now existing in the later sediments are controlled by trends of folding or lines of structural weakness which existed in the old basement rocks." Most of Pirtle's information was obtained from structural contours drawn on the top of the Trenton forma- tion of the Ordovician. Newcombe (1933) published a thorough report on the sedinwnts and structures in the basin. His conclusions followed very closely those proposed by Pirtle. His find- ings are based on both structural contour and isopach maps. Facies Analysis Moore (19h9) defines sedimentary facies as, "Any areally restricted part of a designated stratigraphic unit Which exhibits characters significantly different from those of other parts of the unit." The facies analysis Inethod of interpreting structures was used by 81033, 'Krumbein, and Dapples (19h9) in determining structural relations from.a map showing lateral variations of rock character within a certain stratigraphic interval. Moore (l9h9) defines two different types of facies; lithofacies and biofacies. Lithofacies are "groups of strata demonstrably different in lithologic aSpect from laterally equivalent rocks." Biofacies are laterally equivalent biotic assemblages differing in their biologic aSpect. A third facies is proposed by 81033, Krumbein, and Dapples (l9h9) as "tectofacies" where it is defined as, "a group of strata of different tectonic aSpect from later- ally equivalent strata." Lithofacies and biofacies maps in general express similar trends and limits. These maps also would show minor variations in sedimentary environment. A tectofacies map, on the other hand, would show the broad tectonic variations. Purpose The purpose of this paper is to attempt to determine the structures during Ordovician time in the Michigan Basin by a lithofacies analysis. Even with the scarcity of samples from wells pene- trating the Ordovician, it was felt by this writer that a reasonable interpretation of the tectonic environment of this section could be made. It was necessary that this analysis be conducted on a well defined rock system. The Ordovician system was chosen for this study 5 because of the small amount of written information avail- able on these formations throughout the Basin. It is hoped that the maps and data obtained from this analysis may add to the information found through earlier research. WELL SELECTION AND DISTRIBUTION Stratigraphy of the Section Analyzed Due to the difficulty in selecting a top and a bottom for the Ordovician system, this analysis contains some lower Silurian deposits and omits the lower Ordovician deposits. Table I describes the section analyzed. A top and bottom that were reasonably consistent throughout the well samples was chosen. The concensus of opinion among several authors place the top of the Ordo- vician at the break between the Manitoulin, which is a buff dolomite, and the dark shale of the Queenston. In many of the wells, there is no such break, showing a gradua- tional change instead. For the top, the red shale of the Cabot Head was the best marker bed that could be found. The base of this horizon was chosen instead of a similar red bed in the Cincinnatian to include as much of the Ordovician as possible. The bottom of the Ordovician is Just as difficult to ascertain because of the deep erosion and crustal.movement during and following the deposition of the lower Ordovician deposits. There is much ambiguity as to the correlation of some of these sediments, especially the sandstone beds. In sonw areas, it is very difficult to tell whether the sand is St. Peter, New Richmond or Cambrian. For this reason, the 7 bottmm of the Black River Formation was used as the lower limit marker. It is realized that this is not an analysis of the entire Ordovician system and should not be interpreted as such. TABLE I LITHOLOGY AND THICKNESS OF SECTION ANALYZED Age Formation Lithology Average thickness Western Eastern Michigan Michigan SILURIAN Cataract Cabot Head Manitoulin ORDOVICIAN Cincinnatian Queenston Lorraine Green, greenish- gray and red Shale o Buff to light brown dolomite with some inter- bedded chert and Shale 0 Gray and red shale with thin beds of limestone and dolomite. Gray shale with thin beds of lime- stone and dolomite. no: 70: Ace! 805! .Age Formation TABLE I (Cont.) Lithology Average thickness Eastern Michigan Western Michigan Utica Trenton Black River St. Peter Prairie Du Chien Dark gray to black shale Brown and gray crystalline lime- stone and dolomite with some shale and argillaceous lime- stone. Brown and gray crystalline lime- stone and dolomite with some shale, chert and argil- laceous limestone. Well rounded quartz grains with some chert and con- glomerate. Buff dolomite, chert, sandstone and green to greenish-gray shale. J d LLOS' A15 ' 11.70 ' 230' 0' Requirements for Well Selection Krumbein and Sloss (1951) compared the cable-tool 'method.of drilling with.the rotary-tool method. Rotary-tool Samples are contaminated by "the rotation of the drill pipe and each removal and reintroduction of the tools which cause a certain amount of caving from the sides of the bore." On the other hand, cable-tool samples are relatively uncon- taminated "with a minor amount of material knocked off uneased portions of the bore by the passage of tools and the bailer." Another comparison of these two methods by Krumbein and Pettijohn (1938), draws the same conclusion; the samples for analysis are the least contaminated if obtained from cable-tool wells. Because of the scarcity of wells that penetrate the Ordovician, all of those available were used. For this reason, there was little problem in the Spacing of the wells. The wells selected in the Upper Peninsula were those where most of the lower Silurian sediments were present. Along the eastern margin of the state, from Alpena County to Claire County and in the middle of the basin, there were no wells selected. Map I gives the outcrop pattern and the areal extent of the Ordovician deposits within the state of Michigan. Select ion of Wells Half the wells selected for this study were cable- tool wells. Because of the depth at which the Ordovician is found, most of the wells are located towards the peri- Phery of the state. For each well, the section analyzed MICHIGAN MAP I Outcrop pattern and areal extent of Upper and Middle Ordovician rocks in Michigan KM. (“DIN I Dru- by Allin I. hull- “ 31m toll-u, Dori. of Tool. l he. TI— "I _J I ..._ I I ...—J.._. _..i__....¥_... 1 a 1 69’1"." "51 H MICHIGAN MAP II Location of wells and Partitioning of state KM. (onfllod I. Dun by Auto! 0. Potoldo lid. Silo“ (ollogo, Iop't. oI Tool. I Goo. for statistical analys is oo- 0" I 7’ 00' (olopfrou Copyright 1951 12 was obtained from the Michigan Geological Survey. Map II shows the location of the wells and Table II defines the wells used in this study. Included in the table ease the county and township, company and farm, location, auad.the thickness of the section studied for each well. TABLE II WELLS USED IN ANALYSIS tJell County and Company and Farm Sec. Twp. Rg. Thickness ITtunber Township Of Section 1 Alpena Charles W. Teater 18 32N 6E 1121I Long Rapids Nevins #1 ' - 2 Jackson The Taggert Co. 13 As 2E 1h12' Norvell Watkins Farm Inc. - #1 3 Monroe Dow Chemical Co. 7 SS 7E IMO?! London Loyal Grassey #1 _ £1 Barry Rex Oil and Gas Co. A 3N 9W 1139' Rutland J. and J. Robertson 0 #1 ES Cass D. B. K. Van Raalte 36 78 th 923' Calvin Wma Gemberling #1 _ 65 Schoolcraft B. P. Pettison 1h k2N 16W 577' Hiawatha Alphonse Verschure _ #1 '7 Schoolcraft Schoolcraft Dev. 31 th 13W 85h! Seul Choix Synd. . . Schoolcraft Dev. Synd. #2 8 Washtenaw Calvin and Assoc . 12 28 "(E 1579! Superior 1 w TABLE II (Cont.) 13 Lyon Gowans 22.21. #1 tfell County and Company and Farm Sec. Twp.) Rg. Thickness Thumber Township Of Section 9 Mason Dow-Brazos-Taggert 27 19N 18W 68h' Hamlin Dow-BrazosdTaggert - 10 Wayne Penna. Salt Mfg. Co. 5 ES llE 1h61' Monguagon Penna. Salt Mfg. Co. - #14 11 Ottawa Mich. Petroleum Co. 6 9N 13W 805' Chester Charley Moe #1 . 12 Mason Superior Oil Co. 25 17N 16W 803' Eden M. Sippy gt_gl, #17 - 13 Wayne Woodson Oil Co. 17 18 BE 1786' Northville .Det. H. of C. #3 - 1h. Mackinaw C. Van Keuren l7 ANN 9W 766' Garfield Hiawatha Sportsman - Club 23 31. #1 15 Oakland Top 0' Mich. Dev. 22 EN 8E 1659' Springfield Co. - - Williams #1 16 Oakland C. W. Collin 35 IN 7B 1553' LABORATORY PROCEDURE Sampling Method Samples for each well were obtained from.the Michigan (}emological Survey. The Ordovician section of the wells was represented by seven to twelve trays, each containing about 225? vials. Each vial contained a sample of five to ten feet (of‘ the drilled section. In order to obtain the best results in a mechanical TallanfliS, approximately one hundred and twenty-five grams of Ehaanple are necessary (Wentworth 1926). The vertical section Ertaidied ranged from about 800 feet to 1500 feet. At one gram (DI? sample for every ten feet, the composite approaches WentworthIs figure. There were from eight to ten grams of sample in each Vtiala The selection of one-half to one and one-half gram WTNlld be a sufficient sample for analysis and would not de- tluact from.the value of the original sample. A AOO m1. beaker was weighed and labeled for each Well. As the sample from each vial was weighed, it was .Pliiced in.the beaker to form a composite sample for the Well. A small magnet was used on the composite sample to reIncve the small pieces of drill bit. If obvious contami- Ila-t; ion were present in the two rotary tool wells, it was 15 removed. To check the weighing accuracy, the net weight of the composite sample was divided by one-tenth. This should equal the number of feet sampled. None of the wells showed an error of more than one- half gram, which is not considered. significant enough to alter the results. Removal of Water Solubles Very little of the Ordovician in Michigan is composed of water soluble material. But it was necessary to include these minor amounts of electrolytes in the analysis. Weigner (1927) found that by boiling the sample in water the ionic particles will go into solution and may be removed by filtering or siphoning. Because of the small mount of electrolytes present, they caused no apparent flocculation of the fine clastics during the treatments. Each well was treated with about 200 ml. of tap water and boiled for two hours. All the fine material in the beaker was allowed to settle. Then the water was filtered and 10 m1. of the filtrate was added to a test tube. Another test tube was filled with 10 ml. of tap water. Into each, was placed about one-half gram of silver nitrate crystals. If the filtrate gave more white precipitate than the tap water, another treatment was necessary. The samples were stirred several times during each I?) A 16 treatment to insure better access of the sample to the water. Three or four treatments were sufficient to remove all the water solubles. The weight of the fine material left on the filter paper was obtained by weighing the filter paper before and after filtration. This residue was later added to the clay fraction. The sample was then dried on a hot plate and weighed. Removal of Acid Soluble The remaining portion of the non-Clastic material eras composed mostlyof limestone and dolomite. Because of the great effervescence of limestone, the first treatment was a 25 percent solution of hydrochloric ac 1d. About 100 ml. of the solution was added to the sample very slowly. The sample was then stirred until all effer- Vescence ceased. Most of the fine material was allowed. to Settle from the liquid before filtering. A 50 percent solution was used for the second treat- ITIent and a 100 percent acid solution was used for the final tI‘eatment. After effervescence stopped in the last treat- ment, the beaker was placed in a warm sand bath and stirred intermittantly until all action ceased. Because of the large amount of dolomite present, the solution was heated for several hours. Contrary to the Opinion of some, gentle bOiling did not bring about cementation. 17 Because of the hydrochloric acid content of the jliquid, the fine material in suspension flocculated very :rapidly. After the liquid was cooled and the finer mater- :ial.settled out, the liquid was filtered. The sample was ‘tlaen washed with tap water until blue litmus paper showed Iro change. Each filter paper was washed several times to Imemove as much acid as possible. The acid caused a great ijncrease in weight if it were not removed. Again the cflnange in weight of the filter paper was added to the clay .ffiraction. The sample was allowed to dry and the weight loss citie to the acid solubles was recorded. Disaggregation Most of the shale was broken down in treating the Esample for the water solubles and the acid solubles. But Esome black carbonaceous bits, probably from.the Utica for- Ination, still remained. Krumbein and Pettijohn (1938) define disaggregation 113 "the breaking down of aggregates into smaller clusters or linto individual grains." They also state; "avoid the use