I! I III H H! :33 III FACTORS AFFECTING THE DESIGN OF A SOLAR ENERGY STORAGE UNIT Thesls Ior II): Degree oI ph. D. MICHIGAN STATE UNIVERSITY John Jett McDow 1957 515' II III “III III MI III III“ III“ llll ll IIHII ll Illlll llll [III II I ll 3 1293 20081 8155 This is to certify that the thesis entitled FACTCES fiFI’EL'I'ILIG THE DEE) ION CF A SOLAR ELERGY STORAGE UNIT presented by John Jett McDow has been accepted towards fulfillment of the requirements for Ph. D. degree infigricultural Engineering 1' l I ‘ Date e 0-169 \4' W4 ~33 wp HHHHHHc-L/l w—V‘ .— W r-—'"...‘_ f. 3" '- {.5 2 I \ a.» -".F n-g— -p .— -. .-_ FACTORS AFFECTING THE DESIGN OF A SOLAR ENERGY STORAGE UNIT By John Jett McDow AN ABSTRACT Submitted to the School for Advanced Graduate Studies of Michigan State University of Agriculture and Applied Science in partial fulfillment of the requirements fer the degree of DOCTOR OF PHILOSOPHY Department of Agricultural Engineering Year 1957 a/jW/Héawz John Jett McDow 1 ABSTRACT The objectives of this project were to (l) statistically analyze daily radiation data for East Lansing in the determination for each “ontn, as would affect ‘4. of fre e(uenc5 of various rate levels .1-J "torage of solar energy, (2) mathematical y uGS gn utilization and so P ".d construct a solar storag e unit, and (3) perform Operations at tests on the solar energy storage unit under laboratory conditions. guantity of available solar ra ittL n at any locali y is the determinin: criterion in the design of solar utilization e ui pxme t. v h) Dailv solar—enelgy data for 14 years at F“‘t Lansing were analyzed. Charts develoccd "ere monthly probas * curves and monthly co- tit-A o". ': P a 1‘ 1. r . .A\ 9"» ,— r- " ~ I'\ ‘1 . r. v - ,~‘ v“: ': r v r . v r efficients oi variatio: i r n ‘nnl, Malinda, and minimum daily rate The probability.fln~a given job is selected by balancing between the Wnortance of consistent ener " rates and the allowable investment r in equipment. Once this selection has been made, the pioaaoiiit, curves give quanti tative rates ex;>ected. The coefficients of varia- tion aid in selecting a probability and adapting solar-energy efit i' ment to other localities. A study of heat storage methods :jrov ed that rocks JOUlC be the best material for agricultural use. Analysis by heat transfer principles indicated that the A—inch diazeter rock would provide the maximum rate of heat storage at minimum pressure drop across the Thenral con ductivit5, specific heat, and denSity of a special concrete mixture were determined. The 4-inch diameter Spheres of John Jet McDow 2 this mixture were used in a laboratory storage unit. Copper-constantan thermocouples in 15 control Spheres provided information on rate of heating, retention of heat, and rate of heat recovery from the Spheres. Observations proved the spheres to react very closely to theoretical solutions. Lower mass air velocities of 320 lb per (hr)(sqft) provided the greatest heat transfer effec- tiveness and the most economical Operation. This velocity provided a surface conductance coefficient of two for the Spheres. The heating and cooling of the spheres could be considered essentially Newtonian. Tests showed that the effectiveness of the spheres in heat absorption was reduced considerably after subjected to heated air for three hours. About 68 percent of the available heat was absorbed during this period, with the top layers heating rapidly at first and then the lower layers. Up to 78.6 percent of the stored energy was calculated to be re- coverable, when using a l2-foot cube storage unit within the building where the heat was utilized. It was also found that 68 percent of the energy stored could be remaining in the storage unit after three days. Faster heat losses at ends of storage unit during storage indicated that convection currents must be reduced to conserve heat. In a prototype unit, the storage material would be of well Sized and selected A—inch diameter field rocks. Placement of the storage unit within the building where the heat is utilized will increase efficiencies. The shape should be cylindrical or cubical. Calculations showed that a 7-ft cube storage unit with stones could fUrnish a poultry house 25,700 Btu/hr for drying 16 hours a day. This was based on an 80 percent probability in January. FAC'IDRS AFFECTING THE DESIGN OF A SOLAR ENERGY S'I'ORACE UNIT By John Jett HcDow A THESIS Submitted to the School for Advanced Graduate Studies of Michigan State University of Agriculture and . Applied Science in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Department of Agricultural Engineering 1957 w ' - I; ’/y s‘-— I r I (r r" '/ / I '1' (J A CKNOWLEDGLEI J TS The author wishes to express his sincere gratitude to Dr. James S. Boyd, under whose inspiring guidance, constant supervision, and unfailing interest this investigation was undertaken. He is also greatly indebted to the other members of the guidance committee, Doctor James T. Anderson, Doctor Merle L. Esmay, Professor Ernest H. Kidder, Doctor Heinrich Larcher, Doctor Donald J. Montgomery, and Doctor Charles P. Wells, for their valuable suggeStions. Special thanks is due to Dr. Anderson for his help in the determination of the thermal conductivity and methods for analysis of data. Grateful acknowledgment is also due to Doctor Frederick H. Buelow for his helpful suggestions, especially on instrumentation, and to Doctor William D. Eaten for the valuable aid he gave on the statistical analysis. The writer is greatly indebted to Doctor Arthur W. Farrell, Head of the Agricultural Engineering Department, in obtaining the financial support for the project, and a research assistantship during the first part of the work. Acknowledgment is also due to The Southern Fellowships Fund for an advanced graduate study grant during the latter period of the undertaking. The investigator deeply appreciates the sabbatical leave of absence granted by Louisiana Polytechnic Institute, making this study possible. The author also recognizes the valuable assistance from Messrs. James B. Cawood, Anandrao Deshmukh, Joseph D. Hovanesian, Edward A. Kazarian, Cornelius Snih, and Bill A.Stout during the investigation. The writer is grateful to his wife, Dorothy, for her constant help in processing the data, and for the typing of this manuscript. ii "" VITA John Jett McDow candidate for the degree of Doctor of PhilosOphy Final examination: November 27, 1957, 3 P.M., Room 218, Agricultural Engineering Building Dissertation: Factors Affecting the Design of a Solar Energy Storage Unit Outline of Studies Major Subject: Agricultural Engineering Minor Subjects: Mathematics and Mechanical Engineering Biographical Items Born: January 6, 1925, Covington, Tennessee Undergraduate Studies: University of Tennessee, 1942-43, 1946-48, BS, 1948 Graduate Studies: Michigan State University, 1948-19, MS, 191.9, 1956-57 Experience: Active duty with the United States Navy, l9h3-h6 Graduate Teaching Assistant, Michigan State University, 19h8-49 Instructor, Michigan State University, l9h9 Instructor and Assistant Professor, Oklahoma State University, 19A9-51 Associate Professor, Professor'and Head of Agricultural Engineering Department,1£misiana Polytechnic Institute, l951-present Graduate Research Assistant, Michigan State Univ., 1956-57 Honorary Societies: Phi Kappa Phi Pi Mb Epsilon Professional Organizations: American Society of Agricultural Engineers Inuisiana Agricultural Engineering Association, President, 1955-56, Vice-President, 195A~55, Secretary-Treasurer, 1953-51. iii Registered Professional Engineer, Louisiana Louisiana Engineers Council, (served 1955-56) American Men of Science- Other Organizations: Kiwanis Club, Huston, Louisiana Active in U. S. Naval Reserve DIS-present iv TABLE OF mNTENTS PAGE I. INTmDUCTION O O O 0 O O O O O O O O O O O O 0 O O O ‘ 1 Possible Use of Solar Energy in Agriculture . . 3 II 0 OB‘JECTIVES O O O O 0 O O O 0 O O O O O O O O O O O O 5 II I O mmv OF H mmmm O 0 O O O O O O O 0 O O O O O O 6 A. Availability of Solar Energy . . . . . . . . 6 B. Storage of Solar Energy . . . . . . . . . . 7 1. General historical review . . . . . . 7 2. Characteristics of Specific mterials o o o o o e o o o o. o o o 9 a. water as storage material . . . 9 b.‘ Phase-change material . . . . . 11 c. Rocks as storage of sensible heat 0 O O O O O O C ' O O O O O 12 d. Other storage methods . . . . . 13 IV. AVAILABILITY OF SOLAR ENERGY AT EAST LANSING . . . . . 14 A. source Of Data 0 o o o o e o o e o e o o o o 15 B. AnalySiS Of Data 0 o e e o e o o e e e o o o 16 C. Results . . . . . . . . . . . . . . . . . . 20 V. DESIGN OF A REGENERATIVE SOLAR STORAGE UNIT . . . . . 28 A. Selection of Storage medium . . . . . . . 28 B. Mathematical Study of Heat Transfer in Spherical Bodies . . . . . . . . . . . . . 29 C. Determination of Thermal and Physical Characteristics for Storage Material . . 35 D. Design of the Control Sphere . . . . . . . . 37 E. Design of Heat Storage Unit . . . . . . . . an F. Plan of Tests and Measurements . . . . . . . 49 VI. RESULTS AND DISCUSSION . . . . . . . . ....... . 53 A. Determination of Surface conductance Coefficient . . . . . . . . . . . . . . . . 53 B. Effectiveness during Heating . . . . . . . . 58 C. .Effectiveness as a Storage Unit . . . . . . 71 coco. 7“ D. Heat Recovery Characteristics . . V VII. VIII. IX. X. XI. XII. TABLE OF CONTENTS (cont.) APPLICATION . . . . . . . . . . . . . . . . . . .'. P1CJcsu3>> Cost of’Operation . ....... . . . . . Storage material Used . . . . . . . . . . Container for Storage Material . . . . . . . Shape . . . . . . . . . . . . . . . . . . . Size . . . . . . . . . . . . . . . . . . . . mNCIJUSI()PJS O O I O I O O O 0 O O O O O O O O O O O a] LflfA-RY . O O O O O O O O 0 O O O O O O O O O O O O C RECOMMENDATIONS FOR FUTURE RESEARCH ON STORAGE . . . BIBLIOGRAPHY . . . . . . . . .‘. . . . . . . . . . . APPENDIX A. B. C. D O O O O O O O O O O O O O O O O O O O O O O Nomenclature . . . . . . . . . . . . . . . . Description of Instruments . . . . . . . . . Summary of Pertinent Data . . . . . Example Problem of Storage Unit Application. PAGE 83 83 85 86 87 91. 9A 95 99 100 102 103 10h '14 KO LIST OF FIGURES Cumulative probability curves for daily solar radiation rates calculated about the mean for East Lansing, 12:1.— Chigan O O O O O I O 0 O O 0 O O O O O I O O O O O 0 Cumulative probability curves for daily solar radiation rates summarized from 14 years of data taken at East IflnSing, Bii Chigm O O 0 I O O O O O O 0 O O O O O O O Coefficients of variation for daily solar energy rates at East Lansing, Kichigan . . . . . . . . . . . . . . Cumulative probability curves for minimum daily solar radiation rates calculated about the means for East Lansing, Lichigan . . . . . . . . . . . . . . . . . . Cumulative probability curves for maximum daily solar radiation rates calculated about the mean for East Lansing, Michigan . . . . . . . . . . . . . . . . . . Coefficients of variation for minimum and maximum daily solar energy rates for East Lansing, Michigan . . . . Theoretical cumulative heat storage in single rocks . . A view of the eguipment used in determining the thermal conductivity of the heat storage material by the ‘ded hot plate method . . . . . . . . . . . . ‘79 as 8% Theoretical accumulated heat in a single Sphere . . . . A photogra h rf Concrete Spheres used in tests . . . . Positions of thennoccuples in 15 control Spheres . . . Theoretical temperature history of points at the then ocouple locations within 4—inch diameter concrete nghCms O O O O O O O O o O O O O O O O O o a o o 0 0 Observed temper tare history of paints at the 1 '1 h 4 .- “ .. '-.' I v, q. ’ 10‘" q, o y"'_‘ thermocoupie lOCJtIuUS "Itnln a 4—-Lc» dii eter O O O O 0 O O ccruiretc, sgnexvz . . . . . . . . . . . . b Vil k3 " - 4- r ‘7. “q -. . - “0 rv- “ ‘. r - . vlgou-56CoiJCJl vie" kf tLe st.luoe unit in} its supplerent; ry components . . . . . . . . . . . . . Lrientuti n cf 8) e~(u in top layer of storage unit with not"+.i on of control sshere placement . . . . General view of the storage unit . . . . . . . . . ' w toserved cumulated heat per degree temperature jiffrJrenCe in a 5111018 8;:1‘31‘6 o o o o o o o o o o Lanirum.te.perature differences observed within sphere 3, Test A, with 198°? incoming air temperature . . Accumulated energy during heating, Test A . . . . . Accumulated energy during heating, Test 3 . . . . . Accumulated energy during heating, Test C . . . . . Accunu late d energy during heating, Test D . . . . . Accumulated energy during heating, Test E . . . . . Heat released in Q'lindrical st rage unit during 15-minute period . . . . . . . . . . . . . . . . Cumulative urrcexsu e of available heat released to spheres . . . . . . . . . . . . . . . . . . . . . Heat retention characteristics of storage unit . . Heat level during storane and cooling, Test A . . . Heat level during storage and cooling, Test 3 . . . Heat level during storage and cooling, Test C . . . Heat level during storage and cooling, Test D . . . Heat level during cooling, Test E . . . . . . . . . Cperation of storage unit . . . . . . . . . . . . PAGE A5 70 ,7 l TABLE II. III. IV. :3 LIST OF TABLES Physical and thermal characteristics of heat storage materials . . . . . . . . . . . . . . . . . . . . . . Cumulative heat storage in one cubic foot of field rocks for the specified heating periods and surface resistances . . . . . . . . . . . . . . . . . . . Placement of control spheres in system . . . . . . . . Predicted values of the surface conductance coefficient by known relationship . . . . . . . . . . . . . . . Total energy level of storage unit during tests . . . Summary of heat recovery characteristics . . . . . . . PAGE 10' 33 55 80 82 I. INTRODUCTION The energy from.the sun has in the past been the ultimate source of all mania power. It is a continuing power which will be available as long as life exists on the earth. Man has utilized this energy in a multitude of ways, always selecting the means most easily harnessed with his meager devices. Direct radiation for keeping warm, animals and vegetables fer nourishment and comfort, and fossil fuels have all been ways the solar energy provided man with the necessities for existence. Solar energy is being constantly furnished to man through photo- synthesis in plants, direct heating of surroundings, wind power, and water power. But the storage of surplus energy in fossil fuels or ‘v//» any other fonm known to man is positively not taking place at the rate energy is being utilized. The rapid depletion of these known sources of stored power has stimulated man to capture energies in other forms. Atomic energy will soon attain a respected position of furnishing useful power over wide areas; but the sources of raw I materials fer power generation by fission are limited and will eventually become exhausted. The fusion process, when fully developed, will not be limited by the lack of raw materials. Throughout the mechanical age, man, being aware of the vastness of the daily solar energy received on the earth, has devised many ways of successfully capturing and utilizing it on a broad scale. His incentive has been dampened by the availability and the abundance of cheap fossil fuels in the form of coal, oil, and gas. The wide scale use of solar energy as a direct power source is a very diffi- cult problem, but is not impossible. ,The main difficulties lie in pits wide scattering, variability, and low temperatures compared.with those under which present day machines operate.# Daniels (19) indi— cates that these restrictions are not impossible in the following statement: If a tiny fraction of the effort which has been given to atomic energy were now to be invested in research on utilization of solar energy, significant progress would certainly be forthcoming. . This can well be true when considering that the average daily supply of solar energy in the more thickly populated areas of the world is about 500 kilocalories per square foot (19) or 1985 Btu per square foot. Methods for accelerated use of solarienergy are of’a wide variety. Some of the important energy-conversion means are as follows: (1) Photosynthesis is used to store up energy in plants such as algae fer a potential fuel. The tonnage of dry matter pro- duction is about ten times that of common creps.‘ (2) Solar flat- plate collectors are the most-common means of converting the radiant energy into useful sensible heat in the low temperature ranges. (3) Solar furnaces collect the radiant energy fer higher temperatures up to 3000°C. (A) Photo-electric cells of the photovoltaic type are. used to convert the energy into electrical power, a fonm of energy readily utilized. Possible Use of Solar Energy in Agriculture _ The possibility of incorporating solar energy as a power source is not limited to any one industry or area of work.) However, owing to its availability over large geographical areas at comparatively low energy concentrations (as compared with fossil fuels), utiliza- tion of solar energy as a power source would conceivably beimore readily adapted to the rural areas. A single farming unit presents a diversified number of powerbrequiring activities scattered over a wide area in contrast to the concentration of large power require- ments in cities and industrial areas. Elimination of other uses of this diapersed form of energy is not to be implied, but accentuation is placed on the locations allowing immediate economical use of solar energy. Farm.operations and activities which could easily utilize the low-temperature solar heat are too numerous to duscuss fully here. However; the two outstanding ones which should be investigated first are mentioned. Crop drying and processing are probably the foremost functions which could well use solar energy. Although agricultural people have used the sun in drying crops in fields for centuries,. modern practices of placing the crop in protective shelter as Quickly as feasible for'higher quantity and quality of production make this practice out—dated. Concentrated energy is, therefore, needed at the building site to finish the job of drying. This energy can be provided with a solar collector, as proved by Buelow (12). Improper ventilation oftanimal shelters is an outstanding hin- drance to building preservation and sanitary conditions for the occupants. Giese 03h) states that "... ventilation should not only. improve the purity of stable air and eliminate odors, but, perhaps primarily, remove moisture and prevent condensation which may have a ldetrimental effect upon the structural elements." Additional heat is necessary to help eliminate the moisture. Some of the other possible uses of solar energy on the farm are airbconditioning (heat- ing and cooling) houses, heating and pumping water, preventing frost, and heating work areas. II. OBJECTIVES Satisfactory utilization of solar energy in agricultural work can be accomplished only after careful study of the problems involved. The boundaries of the problems studied in this work are set up in the following objectives: 1. Statistical analysis of daily solar-radiation data for East Lansing to determine frequency of various rate levels for each month of the year, as would affect utilization and storage of solar energy. 2. mathematical design and construction of a solar- energy storage unit. 3. Operational tests of solarbenergy storage unit under laboratory conditions. III. REVIEW OF LITERATURE A. Availability of Solar Energy The basic consideration in solar energy utilization is that of its availability. Only by having adequate knowledge of its intensity and frequency of occurrence can a workable collector and storage unit for a locality be properly designed. Much effort has been exerted ‘to devising maps indicating the average amount of solar _ energy received per square centimeter or per square foot in a hori- zontal plane. Baum (7) states that this is a valuable tool for gross planning, and its importance should not be minimized. But, still more important for local use, variations in the intensity and fre- quency due to atmospheric pollution, altitude, cloudiness, ground reflectivity, season, orientation, and latitude must be incorporated in the- planning. Becker (8) made a study of these factors for several localities in the United States, and his results can be used to predict the local variation. Hand (25) has developed a system of isolines denoting the average solar heat in Btu per square foot per average day for the United States. Its limitations have been pointed out; however, this should not overshadow its general benefits. These data have been further amplified by Cmbb (18) in his solar radiation investigations in Michigan, which relate the average radiation for am' one day of D the year at East Lansing with that at other localities in the United States. B. Egg-gags, 9_f. Solar Energ ‘ 1. General Historical Review Storage of solar energy for periods of cloudiness or night- time is a pressing problem, Robinson (35) states: The question oprower storage by cheap and simple methods for the time of absence of solar radiation is one of the most important problems in the exploitation of solar energy. A good solution of this problem.would enable the use of solar energy in places where this is impossible now. ‘Telkes (39) emphasizes its importance in connection with house heating: The storage of solar heat is one of the major problems to be solved; economically acceptable solu- tions must use a relatively small heat-storage volume 'within the house, because the cost of space is at a premium. Concern for storage of solar heat has been evident in all pro- jects leading up to utilization of this form oftenergy. Examination of patent claims and descriptions bears this out in early devised apparatus for handling solar energy. Calver (11.) in 1883 made claims for his "Apparatus for Storing and Distributing Solar Heat," whose actual realization would be welcomed today. Claim.l. A solar—heat storage device comprising a reservoir completely surrounded, except at the heat- supplying orifice, when open, with non-conducting material, and a non-conducting door, substantially as specified. . ‘The same principles of storing the heat were advocated in the late 19th century as are today. However, this is not to imply that improvements and progress have not been made over the models which were used then. WestonLCAI) promoted the idea of storage by a ther- mepile and storage cell in 1882. He was closely folIOwed by Cottle (17) in 1897, who also advocated converting the heat to electricity: ....a thermo-electric generator adapted and arranged to convert heat fran said body into energy of elec- tricity ... . ‘ Bit, Cottle proposed using a body of stones as a reservoir for the heat. .Many of the early workers on solar energy did not specify the exact storage material but only stated "a body of heat—retaining bmaterial." Examination of more recent'patents indicates the emphasis placed on storage material having the heat of fusion taking.p1ace at rela- tively low temperatures. Howe and Katuck (27) patented the follow- ing heat-storage material in 19553 Claim 1. A storage material consisting essentially of tetrahydrate of calcium nitrate containing a nucleating agent selected from the group consisting of barium_ ‘ hydroxide octahydrate, cadmium.hydroxide, sodium hydroxide, potassium hydroxide, and strontium hydroxide, the said nucleating agent being present in sufficient quantity to saturate said calcium nitrate tetrahydrate at a tempera- ture above the melting point thereof. Schaefer (36) defined the same year his patented heat storage material more‘specifically: A heat storage material consisting essentially of 5% to 15% by weight diphenyl ether and 30% to 50% by weight oleic acid, the balance consisting of stearic acid. 2. Characteristics of Specific laterials Application of heat-storage materials in recently constructed- solar heating systems has been limited to three kinds, rocks, water, and phase—change material. Each has shown distinct advantages and disadvantages, which govern the selection of the proper storage material for a specific application. In general, the final selection will be determined by the type of solar collector in the system, allowable space for storage, general design of system, and/or in summary the over-all cost of utilization of each material. A brief discussion is given for each material's use and, in addition, table I summarizes the governing characteristics for these materials along with some others for possible use. a. later ag’storage material water has been a popular solar-energy storage material in several of the projects undertaken in recent years. It is to be the storage material for the fourth solar-heated house sponsored by the Massachusetts Institute of Technology. Whillier (hZ) expresses the outstanding advantages of water in the statement: water was selected as a storage medium for several reasons, of which the most important are that the water k; is also to be used for removing the solar energy that is absorbed by the collector, and that the somewhat higher heat-storage capacity per unit volume of phase-change storage materials is not sufficient to justify their higher costs. ‘ Data in Table I indicate that water is superior as a sensible-heat type storage material over others listed except a phase—change . 1...... - 10 $3.038 03.33 use: no.“ .7233 «0 3.3030." 3023: 05.05 you coin one codename Add 0 ..«ooafiueawo .5050 5 eons a 03.30% 0 .anam s2 soap... no see: a e 60.35% eoxocauoooao o0 venom £003” 3 M02. no emcee 232093» 3509a“? new :33 one noeunflovoensno .302 3 «on. 38.0 20.0 R .0 3 AS ease... as as 2... .... 5.0 3 3 “masses _ QS . «R «9.8.0 «Rd 3.0 mama ..l. canto: «:3 mm: 34.0 cm 03.0 NS 39 33¢. a Mm MEN 30.0 .R .0 3.0 «Na MMW mflmmfioaoo 3 «a I: ...... H m 0 0a 38a: Angus? “Snow 0.4m .5. «30.0 m; «.0 05 SM 0 seem 00H :3 380.0 8nd 58.0 48$ 33 “San . nee scones. me .5338 33 «new .2\ a are .2 pigs mo nQBm . $988 use. 5? .3338 sfifizmaflax .afififimuano a £8: a}: 333a amass one: 182:. ocean a season 48 Heroes. 3E; Egan... .28.. mo gauge; g g gHmHmm Han. ll material. However, the fact remains that a relatively expensive heat exchanger is necessary to obtain a suitable configuration pattern fer heat transfer from water to air in the final phase of utilizing the heat. Recommendations for size of storage tank are based on collector size, with the optimum of about three gallons of water per square foot of collector (26). b. Phase-ghgggg material. . Materials having a large phase-change enthalpy within the normal storage-temperature range (90°F to 120°F) are preferable to sensible— heat type materials. On the surface Table I would seem to eliminate other materials, with the phase-change substances having a relative heat storage capacity of more than six times that of water and even more over the others. The cost of the raw material, in the range of SlO to $20 per ton, is not excessive. Telkes (39) reports several limitations of this material as experienced in tests made in the _Dover house. First, the process of recovering the stored heat is not promptly reversible as the salts may not solidify upon cooling but will undercool below their normal melting points. This delay, however, can be overcome_by the use of crystallization catalysts, or nucleating agents. A more important restriction in the use of Glaubers salts is .the limited crystallization velocity ofabout "0.02 inch per hour per °F temperature difference between the solid and liquid (39)." Relatively thin, expensive containers would be necessary to obtain a suitable geometrical configuration for sufficient heat transfer. This obstacle casts a shadow on the immediate possibility of heat of fusion materials in agricultural work. 12 c. mpg; storage of sensible h_e_a_t Rocks and the other solid materials listed in Table I do not offer highly desirable characteristics in heat storage. However, 'their low cost and other’physical characteristics constitute the advantages for their use. The shape of small rocks and their normal placement within a container produces adequate surfaceéto-volume ratio for rapid heat transfer to the circulating fluid. Solareenergy storage units have been constructed with stones in sizes from three- feurths inch diameter [Lbf (30i3 to those having an approximate. diameter of four inches Bliss (9i1. 15f (29) advocates the use of gravel about 15 inches in diameter after having made investigations with B/hs, l-, and lfi-inch size ' material. This type of storage unit is usually constructed in fonn of a column through which the air passes at a low velocity of about 1 to 2 feet per second. A heating front takes place at first at the entrance and and continues moving toward the exit end. A sufficient length of column enables the heat exchange to be very efficient since the exit-air temperature is nearly the same as the rock temperature until the heated front has reached that end. The air is usually circulated back through the collector for higher efficiency. The stratification of the heat is due mainly to a very low rate of heat transfer from pebble to pebble. Bliss (9) in a loo-percent solar-heated house near Tucson selected fourbinch diameter field stones as optimmm. The channels for air flow are larger in this case, and accordingly the 13 heat-transfer rate changes. This unit was 10 feet by 12 feet by L2 feet, and held 65 tons of stones. It provides winter heating and summer cooling of an average-size house. Bliss reports that under typical winter conditions this rock pile was adequate for heating during four cold cloudless days with its average temperature ranging from 90°F to 140°F. Under normal conditions, it was believed that there was a 25 percent heat loss which could be reduced by placing the storage unit directly under the house. ' Utilization of the heat in both cases was obtained by reversing the direction of air flow. Both designers advocated dual use of the storage unit by blowing cool air through the bed at night, and .circulating house air through the unit for day-time cooling. Auxi- liary heaters were recommended for standby condition during winter- time Operation. d. chgg storage methods The door to other methods of solarbheat storage is certainly not closed. Robinson (35) states that every energy—change process for converting solar energy to potential energy is feasible. He suggests the possibility of electrolysis of water,-if the storage problem of hydrogen and oxygen were simplified. Conversion to electrical energy would be a very deSirable means, but_the efficiency is low andthe cost is high. Photosynthesis process will continue to be explored for storage of fuel in some areas. 14 IV. AVAILABILITY OF SOLAR ENERGY AT EAST LANSING Effective utilization of solar energy in a given locality can be accomplished only when adequate basic data are readily available in usable form._ The quantity of available solar energy holds the top_‘ position ahnng data which should be known fbr design work. However, variability of the solar energy available in any one locality limits the use of average quantities for any given time. .Solar radiation will vary by the hour, day, month, season, and even from year to year. Of course, for any given date in the year, the probability of not receiving the maximum.quantity of radiation will be because of cloudiness. This phase of the weather is not predictable for long periods of time, and, consequently, cannot be predicted from year to year fbr a given date. Average values could be used, but only to the extent that the average solar radiation rate for a specified date will be reached on a future day 50 percent of the time. Acti- vities utilizing solar energy may be required to Operate at an out- put level higher than one specified for 50 percent of the time. It may be necessary to Operate on a basis of 75 percent, 85 percent, ’ or some other probability. Such needs indicate that a closer examination and analysis of the solar energy are necessary. For’maximum.use of the data, it is desired to know (1) rate of energy received for any probability, (2) coefficients for the adjustment of solar energy equipment designs '15 in various localities due to difference in variation, (3) minimum and maximum rates of energy received for any probability, (A) varia- bility of minimum.and maximum which can be expected from year to year. A detailed statistical study of the solar energy data for'a given locality is necessary in order to accomplish these purposes. A. Source 2; Data Solar radiation data,obtained from the Michigan Hydrologic Research Station under the United States Department of Agriculture and Michigan State University Agricultural Experiment Station, covered the period from December 12, 191.2‘ to August 5, 1956. Failure of the pyrheliometer and/or the recording equipment owing to various, reasons, including damage by hail, prevented the maintaining of a continuous record. However, absence of data during these few days did not prevent making a statistical analysis; the results were. affected only by a slight reduction in degrees of freedom for some months. , There has been some question as to the validity Of the data during some periods, owing to a change in pyrheliometers. Notes in the records of raw data indicate that the data taken during the period January 18, 1953 to November 5, 195h, were calculated with an incorrect "factor," and the recorded data should be multiplied by a factor of 1.2h. However, a footnote in-Climatological Data -' Nations; §Eflflé£2 (LO) states with reference to the East Lansing Station: 16 A study of available information about instmme ntal equipment and radiation indicates that data pub— lished prior to November 5, 1954, are systematically low. This condition'has been corrected in data published in CDNS_for that station beginning Nov. 5, l95h. " Assuming that the data were low only for the period January l8, 1953 to November A, 1954. the prOposed correction factor was applied. to data taken in April during this period. A discrepancy in the results to follow was in most cases well below 3 percent. At any rate, the discrepancy is in the conservative direction of design when using the data. ' All data published by the above station and other united States Weather Bireau Stations are given in units of gram calories per square centimeter (one gram calorie per square centimeter equals one Langley). These data were converted to British Thermal units 3 by a multiplication factor of 3.69 to obtain units normally used in engineering work. B. Analysis 2; Da SOlar energy at East Lansing and most localities is known to vary widely from month to month. It was, therefore, desirable to study the data for each individual month. Analysis of shorter periods of time, such as bi-monthly or weekly, may prove profitable in the future in order to increase the accuracy of prediction. Calendar months were used in this analysis for simplification of presentation and utilization of data. Periods with the beginning and terminal dates in step with the vernal and autumnal equinox' 17 would slightly increase the accuracy of prediction. Analysis of shorter periods would be advantageous with the latter system. The mean,.i, and the standard deviation, s, from the lh.years of data were calculated for each month.' By using the probabilities determined from the Z—Tables in Dixon and Massey (21), calculations were made to determine points for plotting the cumulative proba- bility curves in Figure.l. These curves are classified as normal curves calculated about their'means. Confidence in the validity of these normal curves based on lh years of data was improved by analyzing data by another method. The raw data for the 14 years were tabulated in such a manner to enable construction of the cumulative probability curves for expected daily solar radiation in Figure 2. Comparisons of the radiationerate variability are possible by comparing the magnitude of the cOefficients of variation, C, where C 3 sfli. The coefficient unit is dimensionless and provides a means of comparing the variance of radiation among months or between two localities. The minimum and maximum.radiation rates for a given geographical location are someof the factors needed in the design of solar radiation equipment. The lower rate expected for a given month in some cases will be the determining criterion of design for an activity utilizing solar heat‘ in which the incoming heat rate is of a critical nature. However, an auxiliary heating system may be required under such conditions. The upper extreme rate of incoming solar heat will require an adequate air flow unit to reduce tempera- tures below the point of danger of damage to component parts of the _.‘ “ll-r- 18 535 e . .3 goes vousaaaeo eons.“ gowns?!” peace .33 you so damaged. agenda anew no.“ shes huwawnmnoaa o>wucas§6 .H .wC use use coo.“ eased» disengage: woo 3.5m ad - w 83 08a 8m -/ I! / NH . Z 0 /// b 08 .3 5H. .0 sea .3 as: .m 900 .0.” .34 .d 98 .m as: .m was. sea .m d... .M are .H ON 8H Z ‘b JO eoueianooo JO Kiutqeqoag 19 .semanefi: .wcaeeeq poem as nexus even no enema.sa soon vouaueaase sense sausage hence Dudes you noise 333398 :33 .N .mE 88 comm he see soon Bess. Hoseoeaee to room .o 88 . 83 83 , 8e ..ooa. wé poo . mom. . m3 . a€.. :3 no: kg .3: 93 new Humane OOH % ‘b J0 eoueasnooo JO Kotttqeqoag 20 system. For example, Buelow (13) experienced breakage of collector cover because of high temperatures reached. Also, some agricultural products being dried by solar heat would be damaged by air which is too hot. The cumulative probability curves for monthly minimum.and.maxi- mum.solar radiation rates were developed by a method similar to the one used with the previous probability curves. Only normal curves were deveIOped in these cases, as the variation within a given month was small with the exception of the minimums for the summer months. In like manner, the coefficients of variation for minimum and maximum daily rates were computed by the method previously described. 0- Results The primary results of this phase of work are presented in the accompanying graphs. Figures 1 and 2 both represent cumulative probability curves for daily radiation rates. The predicted normal distributions about the means have been calculated for each month in Figure 1. Whereas, the curves in Figure 2 were plotted directly from tabulated daily rates for the 14 years of data. Close comparison of the two sets of curves will indicate the closeness of the paths. for the two methods. Differences will be found mainly at the two extremes. The extreme values may be of importance in some engineer- ing design work; therefore, more detailed treatment is given to the minimum and maximum rates study. Utilization of these curves is explained in the following typical design problem. It is desired to use solar energy for the drying of corn in October. By predetermining the needs of the system, an estimation is made that the drying Operation by utilizing solar energy could operate satisfactorily if a Specified rate of heat would be available from a solar collector 75 percent of the days. From Figure 1, it is indicated that approximately 575 Btu per horizontal square foot could be obtained during the daylight hours. Knowing thetotal quantity of heat necessary for this particular job, the size, in square feet, of the solar collector can be calculated. Tilting the collector so that the rays of the sun are perpendicular to the collection plate will increase the amount of incoming heat. Such angles of tilt are discussed by Becker and.Boyd (8). Since the rate of solar energy.varies each hour, efficient utilization of heat cannot be had by channeling all heated air through the grain continuously. Near solar noon, the rate of’heat received could boost the air temperature high enough to damage the grain. During these periods of high intensity, part of the heated air could be diverted to a heat storage unit. The cumulative probability charts provide the total available-energy rates for one square foot per day in a given month for these calculations. The magnitude of the coefficients of variation for each month may be canpared in Figure 3. The bar graphs show, as might be ex- pected, that the solar radiation rates are much more variable about .their means in winter months than in summer months. Hence, a lower probability must be selected in design work fOr winter use as compared With summer use. 22 .°°U ‘ON .camagoax_.mcatsmq swam as toast amtwmw .m .mwm .538 5.3% new coaumfihg mo 3:303.“ ...... vm.um» mm .m n m m at...‘ o ‘UOtueIJeA JO uuetatsseoo 23 Cumulative probability curves for.minimum rates of solar energy (Figure l.) have a large variation fr'an month to month, with December having a minimum of less than 51 Btu per horizontal square foot for 88.5 percent of the years. The steep slopes of the curves in the colder months indicate that these low rates will be reached nearly every year. However, a month such as July will have a wide variation in minimum rates from year to year. The negative slopes of the June and July curves are much less than those of_other months. The cumulative probability curves about the means for monthly maximum rates, shown in Figure 5, do not have the variation that is found among the minimum curves. The slopes for all months are very nearly the same, although the magnitude of the maximum value for a given probability varies from month to month. The steepness of the curves indicates that maximum.radiation expected for any one month does not have a wide variation. For example, June's maximum.will always stay within the range of 2290 to 2790 Btu per horizontal square fect 80 percent of the years. Also, the December maximum will vary only fran 580 to 850 Btu per horizontal square foot for 80 percent of the years. TA study of the coefficients of variation for the minimum and maximum.values in Figure 6 will indicate several obvious factors. Minimum.expected rates for any one month vary widely fromtyear to year. This is due to the wide variation of cloudiness that may occur for any given month in one year. On the other hand, the maximum rates have a very small coefficient of variation. 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L 1. o rt 8 o ‘“°¥4?¥J?A JO 1UGI°IJ39°O ‘ 3 8 27 maximum daily rate of solar energy in a given month will probably be reached each year, but the minimum rates for a given month will vary widely from year to year. The limitation of the probability curves lies in the ability of the user to select a proper value of probability. If the need of heat is of a critical nature, a higher probability would be necessary. This will result in dependence on lower radiation rates, but will have assurance of obtaining that particular rate or a greater one a larger percentage of the time. The dependency upon, lower rates directly requires larger and more expensive solar equip- ment to handle the job. The selection of’a suitable probability will, therefore, depend upon the Judgment of the designer. The coefficient of variations can aid the user in the selection of the probability. 'Higher coefficients indicate that the varia- bility of the daily rates will be greater. For closer design work, it would then be desirable to select a higher probability. If a coefficient of variation for a given month in one locality is much lower than in another area, the solar equipment in the former location could be smaller and do the same job when comparing to the latter place. The coefficients of variation can, therefore, help project the experience gained in one place to other areas effectively. This will become more important as more experience is had. 28 V. DESIGN OF A REGENERATIVE SOLAR STORAGE UNIT A. Selection _f 3 Storage Medium Wise selection of a storage means in a solar-energy utilization system.requires careful study of the existing methods and some con- sideration of new ones. The existing ways include (1) biochemical conversion to vegetation by photosynthesis, (2) electrical conver- _ sion by thermopiles or semi-conductors and storage in batteries, and (3) storage directly in form of sensible heat or phase.change. For economic reasons, the third method appears more appropriate for_ application in and around farm structures. The wide choice of materials listed in Table I for this purpose is not the limit of selection. However, it does include those apparently known to be suitable at the present time. Detailed discussion earlier has covered the advantages and disadvantages. For the present study, rock was selected for the storage material in this study for the following reasons: 1. Configuration of material provides a self-contained heat exchanger. 2. Heat loss reduced due to conduction because of point- to—point contact between stones. ' 3. .Large surface area between fluid and solid.allows large heat transfer at low temperature differences. is. Allows low initial cost. 5. Minimizes depreciation,costs of maintenance, and repair of storage material. 6. Installation without skilled labor. 29 7. No maintenance when not in use. 8. Small energy consumption for forced air movement through heat exchanger. B. Mathematical M of. flea; Transfer in Spherical'gggigg Although neither field stone nor gravel is found consistently in regular geometrical shapes, they normally approach more nearly the shape of a sphere. This is in comparison to other common geometries, such as the cylinder, plate, or cube, which have been examined for heat transfer purposes. By considering the stones to be spherical, calculation of heat storage ability for various values of surface conductances, of periods of time, and of ranges of size is possible for prediction of optimum requirements. A spherical rock subjected to heating or cooling can be examined for a variety of conditions. First, consider that it has a high thermal conductivity, k, which would reduce the temperature gradient within the sphere during any heating or cooling process. The heat transfer process would be controlled mainly by the surface resistance and would be called Newtonian heating (or cooling). The temperature history of the sphere could then be expressed as 2 (l) t _ tf e—(ArO/V )(NuVO/ro) 30 or, in reduced form (2) —( 3Nua< O/ri) e t - t: as given by Schneider (37).. Definitions of symbols used in the above equations and throughout the ex1t- re manuscript ar-; gi/:n in upperdix A. The cumulative heat rate, Q, after time, 9, may be expressed as (3) _ -(3Nuo(o/r§):' Q - ch [2; - t;][:3 - e The most likely situation that will be encountered in a tran- sient heating and cooling system would be one with finite internal and surface resiStances. Schneider (37) and Boelter et al. (10) derive the temperature history of a Sphere for this condition, (a) y n 2‘ ~un2Eo‘9/I‘2 t - tfl _ 2 2e :1an -LinCoslan Sin(Mnr r t. - tf - n 3 18 -SinMnCosMn Mhr r0 1 where mm are the roots of the transcendental equation (5) Schneider presents values of the first five roots which apparently are an adequate number for solutions in normal engineering problems.‘ Boelter et al. go further and derive the cumulative heat, Q, equation for a Sphere with finite internal and surface resistance. 31 (6) :60 a): = 87rr3/pc(ti .. tr) )n2 2 .2.<-(lm «chit. O n 3 1 Mn [Mn - SinMnCosMn] The determination of an optimum size rock for a regenerative storage system.was made by Equation 6, using the physical charac- teristics given in Table I. Several reasonable values for the surface resistance, h, and time of fluid flow, 0, were selected and the results plotted in Figure 7. Note should be made that a tem- perature difference, ti - tf, is not specified but would vary and depend on the given condition. Values of the cumulative heat, Q, will naturally vary for various sizes of rocks. Tb arrive at an optimum rock size, data from Figure 7 were used to calculate the heat stored in a cubic foot of.material, considering that the spheres ~are close packed. The summary of the results is presented in Table II. . Values of the upper limit of heat stored in a cubic foot of rock vary. slightly around 25 Stg.» This small variation is owing to the vast amount of calculations involved and the limitations of slide rule accuracy. The significant point is that the size of rock at which the heat stored drops off, for a film coefficient of six, is 0-5-, 4-, and 8-inch spheres for periods of 0.1, 1.0, and 10 hours, reapectively. Collection periods of less than one hour may not ~prove feasible for storage. Therefore, the four—inch diameter Sphere would have approximately the maximum cumulative heat storage with the least amount of pressure drop of air flow through the system. If higher film coefficients and in turn high velocities of air flow are used, the optimum size rock for maximum heat 32 6.0 , 6 .. 3 1.0... O.5-—» 1 .. .n g 0e1 : 3‘ -- : ' ... 0.05 .- .. :1" __ 01m h 0 - b 1 6 0.1 d _ 2 12 0.1 3 24 0.1 -‘ h 6 1.0 '" 5 12 1.0 _ 2h 1.0 6 6 10 12 10 0.014— 21‘ 10 I I: h. “I! 0.005 :: °°°°1 1 2; J 1 1 l I _ I. b o. 1'13. 7. - Size of Rocks, Inches Theoretical mmlative heat storage in single rocks. 33 mazsamHmmm 853:5 924 @9055» UZHBE EHomnfi wasfiom HH mama. mMon a Lo 900m 938 go 2H 8555 9a EH95 . 8.200080 .00 0010 0.0.0. 2.0 00.0 0004 .0 .mm m-.~ 0.0m 0H.m 00.0 mm0.0 .0 .3 000.0 0.0m 000.0 00.0 $0.0 .0 ‘ .3 End .00 Rad Sufi 200.0 .m .00 500.0 .3. 500.0 0.3 200.0 .m .mu 8.8.0 .3 8.8.0 _ . hum 3000.0 A .00. 0~a8.0 .nm 0fi8.0 .nm A0080.0 «A .00 l .3 on.“ as as 03 , and 0.0 $0.0 . .0 .mm mums... 0.00 004 8.0 8.0 MA” 0.0 .0 .3 000.0 mam .n. 0.0 «m0 m0H.0 men 23.0 .0 .00 2.0.0 5.00 20.0 3.0 800.0 0.00 00.0 .m .00 030.0 -00 080.0 0.3 «08.0 00m $3.0 .m .00. 308.0 ..mm 0.88.0 0.5 300.0 000.0. 800.0 A .mm $300.0 ..mm 0038.0 0.8 0038.0 0 000.00 500.0 0.0 008 .80 secs .30 £8 tom soon .30 38 an 080 3a 080 .0005 30 .00... u as? 0230 use: 333.50, 0.00 _ 04 — do , 03 0 00...“. A sfldflnfinom voom Dana £00m Hdoahcfiw oosuusm moo oxeom mo 00005000 3h .mm 0«.0 0.0m 00.0 00.0 000.0 , 0.0 000.0 .0 .0« 0««.« .0« 00«.« 0«.00 , 000.0 0.00 0.0 .0 .0« . 000.0 . .0« 000.0 0&0 «00.0 «.00 0000.0 .0 .0« 00«.0 .0« 08.0 . 0.00 000.0 0.00 0«.0 .0 .0« 0000.0 .0« 0«00.0 .0« M0000 000 ‘ 0000.0 .« .0« 00000.0 .00 00000.0 0.0« 00000 0 000.« 0000.0 .0 .0« «0«08.0 .0« «0«000.0 .0« «0«000.0 0« 000.00 0000.0 0.0 0.08 .30 team .30 £8 .80 tom .30 0 .80 080 .80 80 luwfijum 30 .3 .. 0.33 0230 080 3000038- 0.00 _ 0.0 L 0.0 280 .o .800 w w w 8030030 080 0008 team 0800.00.00 0000000 000 oxoom «0 00000000 Auosnfiacoov HH mum<fi 35 transfer will, of course, increase. It was concluded, therefore, to use a four-inch diameter rock for the heat-storage bed. C. Determination 93 m and Physical @aracteristics for Storage Material A sufficient number of four-inch diameter field stones approach- ing spheres would be difficult to accumulate for the test. Also, the exact thermal concmctivity of these stones could not be measured with available equipment. ‘Ihese variabilities in the storage system were eliminated by molding the spheres from a very dry mixture of a water: cement: sand ratio of l:l.92:6.68 by weigit. This enabled an exact determination of the thermal conductivity to be made for this material. he guarded hot plate modified and calibrated by Anderson . (5) and operated under the specification of the American Society for 'lbsting Materials (3) was used to determine the thermal conductivity of two l-inch by 1.2-inch by 1.2-inch mortar plates made of the same mix as that of the Spheres. ‘Ihe value obtained was 0.372 Btu per (hr)(sq. ft)(°F) per (ft). A picture of this testing equipment in operation is shown in Figure 8. Determination of the specific heat was made by use of a calori- meter, with the resulting value of 0.210 (Btu) per (lb)(°F). An average density of 123.3 pounds per cubic foot was determined by taking the yaeight and dimensions of several geometrical shaped fignites made of this mixture. Fig. 8. A View of the equipmnt used in dete the thermal conductivity of the heat storage material by the guarded hot plate method. 1) Guarded hot plate Iith specimen 2) Water circulation pump (3) Constant voltage transformer (h) mutate (5) Voltneter and meter g6) Switches 7; Potentiometer 8 Ice bath (ref. thermocouple junction) (9) Water source 37 With the necessary physical characteristics determined, the cumulative heat in one sphere for one degree temperature difference was calculated by Equation 6 for time periods of the range 0.1 to 2 hours and film coefficients of 6, 12, 18, and 21.. The resulting data were plotted in Figure 9. Study of the curves in Figure 9 discloses that the rate of heating'is not increased in the same proportion as the increase in the surface conductance value. Higher velocities of air, with accompanying increased operational cost, are not necessarily justified for obtaining high h-values. For surface conductance values of 6 or more, 93 percent of the maximum storable heat is already in the sphere after one hour's operation. Again, note should be made that the difference between the initial temperature of the sphere and that of the air or fluid does not affect the rate of heating or cooling, but only the quantity of heat stored. The apparent maximum heat which can be stored per °F tem- perature difference is 0.5 Btu, which is approached asymptotically for all values of the surface conductance coefficient. D. Desng _o_f ___e Control Sphere For actual study of the heat received by the sphere, four thermocouples were placed in 16 control spheres. Placement of the thermocouples was made at the boundary layers of three concentric, equal-volume shells aboutithe center of the sphere during- the mold- ing process. Exact positions are denoted in Figure 10 and a _ photographic cut-away view of the spheres in Figure 11. The 100 1.0 ITTT l . 22.9“” 0.1 6.f 0.2 0.3 0.5 0.5 (“ti- tr) Theoretical accumulated heat in a single sphere. 89 e b c Fig. 10. A hotograph of concrete spheres used in tests. Ens, Control sphere with thermocouples b) Oxb-away View of control sphere with themocouple placement. (c) Plain sphere 1'13. 11. Position- of thermocouples in 15 control spheres. a0 The copper-constantan thermocouples were made of 30-gauge wire to give a small junction point and reduce heat loss or gain through the wire. Theoretical calculations with Equation 1., were made to study the temperature history of the thermocouple points within the sphere and plotted in Figure 12. For these calculations, an h-value of 1.65 was used for comparison with oven conditions. However, an h-value of 1.76 is produced by the following empirical equation from Brown and fires (11) for natural convection about a sphere: (7) he 3 0.63 15 (8.131310% r Definitions of symbols are given in Appendix A. A similar study was madeby placing the control spheres in an oven of an average temps rature of 208°F. Tue recording potentio- meters wereused to make the temperature history. Average values of the corresponding points for the 16 spheres at specified times were used to plot the actual temperature histories in Figure 13. No distinct differences are to be noted between the actual and the theoretical temperature histories. First, the temperature gra- dient appears to be considerably maller under actual tests. Secondly, the equilibrium temperatures are reached more quickly under the actual situation than the equation predicts. Several factors could be responsible for these discrepancies. First, it is apparent that the film condictance chosen for natural convection was slightly low in comparison with the one given by the formula. Other variables entering the formula have been measured with reasonable accuracy; 1-0 TWTIFII‘] I IF__ Des ‘— Ourve Radius, ft. __ 1 0.0000 2 0.1158 “ 3 0.11.51; h 0.1667 ’2. 0 a y 001 r— .— 5 _. _ 3" —— _ ' L— —I 3 __ OeOS '— _. >—- -— 0.0107 1 151.71 IJLILJr line, 0, hours Fig. 12. ‘lhecretical temperature history or points a the thermocouple locations within Irinch diameter concrete spheres. (t - tam. ‘tfl 1.0 l l 0.5 0e — 0.05 __ r. ._ 1 1 l 1 14 11 ‘1 1 0010.2 0.5 - 1.0 5.0 thme, 0, hours Fig. 13. Observed temperature history or point at the thermocouple locations within a Lpinch diameter concrete sphere. AB however, variations owing to time lag in.thermostat control of heater, conduction from.plates supporting the spheres, and radiation probably are the contributors to these discrepancies. Percentage of error varies from.approximately zero within the first 12 mdnutes to 53.9 percent of the theoretical at the time two hours. The high percentage discrepancy at the later time is due to the sharp drOp in the curves. 13- Pasisaeffisaimrassm A storage unit for the initial investigations was designed to be small and compact so that closer control could be had over the variables. A cross-sectional view of the cylindrical-shaped container and its supplementary components is shown in Figure la. The cylin- drical container provides the minimum axposed.surfacs to volume ratio of common geometrical shaped bodies with the exception of a sphere. This allows a minimum heat loss for a defined amount of insulation. The one-inch rock wool insulation covers both the out- side and inside of the main body. Only one layer of insulation was used on the approach and.sxhaust frustums and the pipe leading to the fan. The three-layer sheet asbestos covering over the pipe containing the heating element was primarily a safety feature to elimi- nate exposure of a hot pipe to nearby surroundings in the building. An electrical heating source was selected in order that constant control over the incoming heat was obtained. Variation of solar 6 energy through a collector airing tests would make accurate measure- ment of heat input to the storage unit more difficult. Input heat was regulated by the carbon pile rheostat in series with the heating element. A vane anemometer was used to measure the air velocities in the sixpinch pipe on the exhaust. This anemometer was feund to have a considerable error, owing to the fact that it was~calibratsd in open air rather than on.a pipe. A 2é-inch orifice plate was later constructed to fit in a nominal three-inch tube, according to Radiation Gap ‘ ' Slut bestos Gsrbonpile ” ‘ “mm 4* / {Iolts n47;- - flee Element“ Power Analyser Radiation .. .. axields ‘__- 1 ° 1c ' O... 189 1.- 11; ..g...‘ 1' Rockwool spa... ‘—°.-—~ ....‘ When. and Outside O... 1 - see-1 was» .1... * .... 0......“ 0.... T0 Beale: 3/1." 3 l' 0 Air Control 1 '\ Fan with Motor Fig. lb. (rose-sections]. vi- of the stems unit and its supplementary mounts. 1.6 specifications of Madison (33). The orifice plate with the micro- manometer was used to calibrate the vane anemometer. Flow rate values by the orifice were found to be 61.5 to 61. percent of those recorded by the anemometer. The previously recorded readings of the anemometer were corrected accordingly. 6 The unit was constructed so as to have the warm air directed into the top layer of spheres, passing through the entire unit, and exiting at the bottom after releasing the heat. The heating process will. progress on through toward the bottom layers. While in storage, any convection currents set up will have a tendency to move the heat from'ths lower layers to the t0p ones. When the heat is recovered, the air flow is reversed, bringing the cooler air over the lower temperature'Spheres first and progressively heating as it moves to the tap. To reduce radiation losses from the heater as much as possible, 7a cap was placed over the six-inch diameter intake pipe. It was necessary to install the radiation shields between the heating elements and the top layer of spheres after preliminary tests indi- cated that the top layer of spheres was heating to a higher tempera- ture than that of the air passing over them. It was evident that the spheres could "see" the higher. temperature heating element and were receiving radiant energy from the element. The shields proved to be valuable'also in that they provided sufficient turbulence of the incoming air to give approximate even distribution of the velocity and temperature pattern over the top layer of Spheres. 47 Pitot tube and thermocouple probes were made to determine this distribution. A A metal grate at the bottom.of'the unit provides support of the Spheres and a minimum drop in static pressure. The static pressure drop across the main body was found to range from 0.004 to 0.09 inches of water for the mass velocities used in the tests. The spheres were placed in layers as shown in the photo- graphic view of the top layer in Figure 15. There were nine layers with 21 spheres per layer, making a total of 189 spheres in the unit. Originally 16 control spheres with thermocouples were made. However, No. 9 was damaged in the preliminary test and was not used in the storage unit. Placement of the other control Spheres in the unit was made according to Table III. Description of the instruments used in the tests are listed in Appendix B. Fig. 15. Orientation of spheres in top layer of storage unit with notation of control sphere placement. TABLE III PLACEMENT OF CONTROL SPHERES IN SYSTEM Layer A B C D E 1 F 1 1 2 3 I. I. 5 6 7 8 7 10 11 12 13 9 15 k 11. 16 49 F. Plan of Tests and Measurements *“w” Basically, the desired infermation from the proposed tests was the effectiveness of the stone Spheres as a heat storage unit. Measurement of this effectiveness must be accomplished by measure- .ment and calculation of several heat transfer characteristics. For immediate application, optimum values or description of the follow- ing characteristics would be desirable: l. fiirfacs conductance, h. 2. Mess velocity, G. 3. Effectiveness of unit during heating period. b. Effectiveness as a storage unit. 5. Quantity of recoverable heat. 6. Dimensional ratio of a prototype bed. 7. Economical aspects of heat storage. To accomplish the above, tests were designed to have variations over the range of the equipment. The surface condictance variation was obtained by changing the mass velocity of the air within the limits of the fan. Different temperature rises of the incoming air were made possible through the variable heat input. Measurements of air temperature by thermocouples were made at the following points: (1) outside ambient, (2) approach to Spheres, (3) exit from.spheres, (h) at anemometer. Temperatures were measured in the control Spheres, which were placed according to Table III. For heat-loss determination,.thermocouples were placed on the 50 surface of (l) heater cylinder, (2) tap fmstum, (3) storage cylinder, (1.) bottom frustum. The wet and dry bulb temperatures of the out- - side air were obtained from a sling psychrometer and the air velocity with the anemometer every 30 minutes. Also, input electrical power was measured at the same time interval. The lZ—point recording potentiometer provided a reading on each point every minute. Readings of the air outside, incoming to spheres, exiting from spheres, and at the anemometer were made every minute. All other temperature readings were taken every eight minutes through the use of the switching mechanism shown in Figure 16. Barometric pressures were obtained from a mercury barometer in a nearby building. The general procechre used involved (1) a heating period, (2) aperiod for holding the heat or storage period, and (3) a cool— ing or recovery period. The length of a heating and recovery periods depended on the mass velocity of the air. At lower velocities, the period was extended to as much as five hours, while higher velocities reduced it to as little as one hour. The fan and heater were shut off when the difference between the incoming and outgoing air tem- peratures was 10 to 20°F during heating. The fan was stopped during cooling or recovery when the air temperature difference was 5 to 10°F. The main storage period curing the tests was 21., hours. During this period, checks were made at intervals to determine the heat retained. Shorter storage periods of A, 9, and 12 hours were used to provide possible comparative studies with the longer duration. 0 51 Fig. 1.6. General view of the storage unit. Storage unit 'memeouple switchee Recording potentiometer fining peyehrometer Vane mmter and stop watch Power analyzer Gubon pile rheoetet Fen 52 A total of nine tests was. completed. However, the first four were eliminated from use, because the radiation shields were not in place. The latter five tests provided data forra wide range of air flow rates and quantities of heat stored. 53 VI. RESULTS AND DISCUSSION A. Determination gt; the gztrfape Conductance Coeffigcent Several methods are available for determining the surface con- ductance, h, under forced convection conditions. 15f and Hawley (31) recommend the relation 0.7 (8) h = 0.79 (go/d) for the determination of the surface conchctance coefficient in "builder's gravel." Application of Equation 8 to the proposed heat storage system appeared impractical as extremely high surface con- ductance values are obtained when calculating for the 4-inch diameter. As the equation was, develOped for a small size rock, an error for use with a larger rock is quite possible. McAdsms (32) recommends for a single Sphere a relationship which was derived from data of several investigators in the form of 0.6 (9) E“ Da = 0.37 D8 G kf Mf that holds true in the range of D8 G/loLf from 17 to 70,000. However, the spheres in the storage unit act more like a bank of staggered tubes with an effective diameter being determined by (10) LzL'tL. D6 D8 , DS 5A The recommended formula for nine layers of Spheres then becomes 0.553 (11) hm Di 2 0.1.92 De 0 “r . Mr where De G ranges from 2,000 to [0,000. Mr The h—values predicted by Equations 9 and ll for the five tests are presented in Table IV for both heating and cooling conditions. The values given by the latter equation are ll. to 25 percent higher, which would be expected for staggered banks of spheres as compared to a Single. It is, therefore, expected that the surface conchctance coefficients calculated by Equation 11 would best predict the con- ditions actually occurring around the Spheres. The values ranged from 2.51 to 6.09 for the heating phases of the tests. This range approaches the one found by the subsequent method. . An alternative method for determining the surface conductance coefficients is by constructing curves similar to the theoretical ones in Figure 9 from data obtained in tests. Data for No. 3 Sphere in the top layer were used for this determination, as the temperature of the incoming air was known and was approximately constant. Resulting curves are presented in Figure 17. Relative positions of these curves are according to the mass velocity, with the higler velocities allowing the sphere to reach maximum possible heat absorption first. Qualitative characteristics of the curves are very such the same as the theoretical ones in Figure 9. The curves plotted from observed data approach asympto- tically a value of'0.55 Btu per 0? difference; whereas, the TABLE IV PREDICT'ED VALUES OF THE SURFACE CONDUCTANCE COEFFICIENT BY KNOWN RELATIONSHIPS ‘ Test Process ' lean tr I, G hm hm °F #/hr Hewitt-.2) Eq. 9 liq-11 A Heat 122.5 1A7 320 1.87 2.51 0001 80.0 238 518 2.39 2.97 B Heat 120.1 309 67A 2.87 3.51. Cool 73.1 532 ' 1160 3.83 b.56 C Heat 95-5 39h 859 3.h1 3.96 0001 79.0 h7h 1033 3.62 A.32 D Heat 100.8 559 1220 h.06 b.83 ’ 0001 73.3 705 1538 h-83 5-36 E Heat 87.5 863 1883 5.22 6.09 0001 85.7 965 2105 5.55 6.41 Time, 0, hours 56 5.9 1.d_ TV! 0.1 .05 Fig. 17. 0J.2 J 01.1. I 4.6 Q/te Observed emulated heat per degree temperature difference in single sphere. 57 theoretical value approaches 0.5 in the same manner. Several factors could be responsible for this discrepancy. (1) Radiation from the heating coils could be reflected by the shields and frustum. (2) heaSurement of the thermal and physical characteris- tics, such as Specific heat, density, or thermal conchctivity, may not be of sufficient accuracy, although the same corresponding values appeared in both the observed and theoretical data. By superimposing the observed results in Figure 17 over the theoretical in Figure 9, it could be noted that the entire set of observed data would fall approximately between the curves having h-values of two to Slightly beyond six. This range of coefficients fits very closely to the one obtained by Equation 11. Basically, the two methods produced comparatively close results, which give confidence in the validity of the data. \The importance of these findings is that only a Slight advantage is obtained by producing high surface conductance coefficients by means of high air velocities. The lowest mass-velocity rate allowed the spheres to receive 72.8 percent of the asymptotic value in one hour. On the other hand, the highest velocity rate, 5.9 times greater than that of the lowest rate, almost reached the asymptotic value at the end of the same period. This vast increase in power requirement for moving the air is not justified when considering that the lower velocity system will have 92 percent of the maximum possi- ble heat stored in one additional hour. It Should be noted from these OJPVGS that the effectiveness as a heat exchanger does not depend on the temperature difference between \f‘ (T) the incoming air and initial temperature of the sphere. The mean temperature difference varied from 33°F at the highest velocity to l230F for the lowest velocity. The time required for the Sphere to reach asymptotic condition depends on the surface conductance and notAt. Such characteristic would allow the solar collector to operate at the lower air temperature rise which gives a higher Operating efficiency (13). Compatibility between the storage unit and the collector is obtained in this respect. 8. Effectiveness during Heating Although the mass velocity and surface conductance study pro- duced a qualitative view of the unit's effectiveness, the quantita- tive sepect is of eQual importance. Ultimately, the quantity of heat which is later recoverable for use is the primary objective. Control spheres were placed in the unit at various locations in order that reliable observations could be made on heat absorp- tion and release throughout the unit and.within a Sphere. Tempera- ture gradients within the spheres proved to be important only at the beginning of a cooling or heating period. This gradient was as high as 260F difference between the surface and center in top layer spheres, but always less than 10°F difference in the lower layers. However, the larger difference occurred only when higher incoming air temperatures were used. hax'num temperature gradients observed during all the five tests are plotted in Figure 18. This family of gradients mes plotted from sphere 3 data during Test A when the Temperature indicated by thermocouples, 0F F: o T I 1\\\\\\ x 200 120 9O 60 45 3O 15 80 L— 0 Minutes 1 1 l L l l I l J 50 1 2 Center Surface Distance from center, inches Fig. 18. Maximum temperature differences observed within sphere 3, Test A, with 198°? incoming air temperature. 60 incoming air temperature was 198°F. Note should be made of the gradient being maximum at lS-minutes and reducing on to practically zero after 300 minutes. A.mathematical check was made to determine the value of using all four thermocouple readings within a sphere, as compared with only the center and surface ones, for calculating the heat absorbed; 'At most, the error, when using only the two, was less than 5%. The curves in Figure 18 Show that averaging will always give values too high. The gradient within the Sphere when making oven tests was generally larger; however, this was probably because of radiation it received from the insulated walls. Determination of total heat absorbed in the storage unit was. made by projecting the quantity absorbed by control spheres into the other spheres according to their location. Figure 15 shows that the spheres can be thought of being arranged roughly in two concentric circles around a central sphere. The outside ring has 13 Spheres, while the inner circle is made of seven spheres. At least one control sphere was located in the two rings and at the center for Layers l, h, and 7. Layer 9 has three control spheres located in the inner ring. After calculating the quantity of heat each control Sphere ab- sorbed for each 15-minute period of heating, heat absorbed by plain Spheres in a given layer was found.by assuming that they receive the same amount of heat as a control sphere in that corresponding ring. Summation of individual heat quantities gives the total energy received in one layer. Values for Layers l, h, 7, and 9 61 were plotted at 15-minute intervals in Figures 19 through 23 for the five heating tests, respectively. Curves were then drawn through the known points, which made it possible to pick off the quantity of heat absorbed at other layers. It is noted that Layer 1 is the top section in the storage unit. The initial temperatures on the graphs are for layers 1, A, 7, and 9 in each case. Temperatures of the incoming air over the top layer and the mass velocities are also listed on each of the five graphs. Operational characteristics, such as incoming air temperature, mass velocity, and initial temperature of the spheres, are different for each tests. Although this prevents making direct comparisons between graphs to a certain extent, it provides a means of pre— ldicting the reaction within a storage unit. Results of Test A are presented in Figure 19. The mean incoming air temperature of 187OF was the highest for all tests,and the mass velocity was the lowest. Initial temperatures of the Spheres varied only 5°F from the top to the bottom layer. The quantity of heat stored was higher for this test because of high temperature of incoming air. Qualitative results derived from Figure 19 are as follows: (1) The top layers heated at the.most rapid rate during the first part of the tests, with an increase of heating rate for the other layers after about 90 minutes. The heating rate can be distinguished by the spacing between the time lines, with the wider Spacing representing higher heating rates. (2) Only a Small quantity of heat was added during the last two hours (180 to 300 minutes) 62 1600 l I [ Increase in energy per layer, Btu's 1200 ~— J 1 3 so ' 3 2 800 _ 0 h 90 —_' 75 so 1.00 — as I l l l ' I REE?“ temperature 60° 59° tin - 187°? 0 - 320#/(hr)(sqft) 15 Minute 1 l 1 l l l 5 7 9 Layer Fig. 19. Accumulated energy during heating, Test A. 63 as compared to the quantity received during the first three hours. This shows a marked drop in the efficiency of heat transfer which will be explained more in detail later. (3) The low mass velocity allowed the upper layers to continue to have an increase in heat level even after five hours. This is demonstrated by the substan- tial negative slope of the heat level line even after 300 minutes. In Test E, Figure 20, the mean incoming temperature has been reduced and the mass velocity increased. Initial temperature variation.of'the spheres is somewhat reversed with the higher tem- peratures in the lower layers. A similar type of heating process was had as in Test A, with the exception that the heating rate drOps off after only two hours. Only about 10 percent additional heat was added during the third hour as compared with that which had been absorbed during the first two hours. Note should be made also that the heat level line began to approach more of a horizontal line than did the curves in Figure 19. This is primarily because of the higher'velocities. The distinguishing change seen in the curves for Test C, Figure 21, is the flattening of the heat level curves at a very rapid rate. This characteristic is due to two factors. First, the heat level line at any one layer is based on the initial temperature as a reference point. Note that the initial temperature of the upper layer is 10°F higher than the lower layer. It is evident that the lower layers have more storage potential for a given incoming air temperature as compared to the upper layers. This is the reason that Increase in energy per layer, Btu's 1600 6h -—-1 a —— _ l l T l l e— t1 - thOF G - 67A#/(hr)(sqft) Initial temperature 62° 63° 66° 65° 1200 _._ co 8 l a 120 5 O 5 O O 9 — 7 L00 _ — as f— 30 .— 15 Minutes 0111111111 3 5 7 Layer ...: Fig. 20. Accumulated energy during heating, Test B. Increase in energy per layer, Btu's 65 I T I T l I I r f tin - 109°? G - 859#/(hr)(sqrt) 6oo __ __ Initial temperature *— 73° 72° 6ao 63° —' h00+—— / 105 75 \ 60 L— ———J 45 20G-- \\\\\\\\\\\\\\\\\\\\\“‘~22———‘—-‘-~“‘~‘-. -‘ L— —. 15 Minutes _____‘fl_, 0 J 1 gr I i_lg l _fiLi l l 1 5 7 9 Layer Fig. 21 Accumulated energy during heating, Tbst C. 66 heat level lines can be higher for the lower section after a period of receiving heat. The second reason for the lines flattening out Quickly is the higher mass velocity, which gives the heated air a shorter'period of time to release the heat in the upper layers. Air will remain at a higher temperature while going through the storage unit. This allows the lower spheres acceSs to higher temperature air and a possibility of receiving more heat. Whereas, at lower velocities, only lower temperature air reached the bottom Spheres. Test D, Figure 22, had a very pronounced heat level increase for Layers 6, 7, 8, and 9. This resulted from the high initial tem- perature gradient of 15°F, which was greater than for any other test. Test E in Figure 23 approached the same qualitative results found in Test C. The initial temperature gradient was not as pro— nounced,and the heat level lines had a tendency to become horizontal after 90 minutes of operation. The effectiveness of the regenerative storage unit during heating periods was determined quantitatively on the basis of the percent of available heat the air releases to spheres during the progress of storage. The available heat was based on the difference between the incoming air and initial Sphere temperatures, and the, mass velocity of air. TWO sets of plots were made of this study: (1) percent of available heat released during any 15-minute period, and (2) the cumulative percentage of’available heat released up to any time during the operation. These results are presented in Figures 2A and 25, respectively. Increase in energy per layer, Btu's 600 #00 200‘ 6? l‘T T l T 1 I I tin - 115°? C — 1220#/(hr)(sqft) Initial temperature 690 670 580 no 15 Minutes H w \R “Q \0 Layer Fig. 22. Accumulated energy airing heating, Test D. Increase in energy nor layer, Btu'a 111Tl‘l'l t - 95°F 600 -— oi? 1833a’#/(hr)(sqft) 63 63° 61° 59° \ zoo,— _. #— .... .... h h—-. _ .... Initial temperature "" H— w \n x) o Layer fig. 23. Accumulated energy during heating, Test E. 69 63..th sands-.3 weaken p.25 omens... Hmoflefiaho 5 vmnmoaoh vac: 3N .ME 28: .o .05... o.n o.¢ o.m o.~ o.H oo _ J _ a . J a _ a _ m :1 om a .L 3 .J L 8 83 a l MMNH a m o .5 m om own < 3355: 5 ea. / / p _ F F _ _ a _ _ _ OCH 3 ‘peseeteu qeeq etqetteuv 70 532% cu veamcaoa amen oflnmawmpm no $3833 2.33356 .23: .o .5 o.m 0.4 o.m o.N 0mm emu 0.." A A 7 a A % n3." ONNH mmm Cenxévk .e _ 00H 3; ‘peeeetu mm Oman?” 71 The points at the end of the first 15-minute period were erratic because of the transient heating conditions. However, the succeed- ing points plotted into relatively smooth curves. The most out— standing feature these curves present is that higher efficiencies of heat absorption were obtained with low mass velocities. The instan- taneous efficiency (Figure 24) for the air mass velocity of 320 lb per (hr)(sqft) was 70 percent at the end of 1% hours. For the ' velocity of 1883 lb per (hr)(sqft), it was only 13 percent at the end of the same period. The values of efficiency for the intermediate tests range accordingly between these two extremes. Cumulative efficiencies of available heat released present a similar picture in Figure 25, but the sharpness of drOp is not so pronounced, as would be eXpected. The heat released after 1% hours operation is 79 percent of available heat fer the lowest velocity, as compared to 33 percent for the highest velocity. Lower velocities, therefore, appear to be more suitable from the standpoint of higher efficiency of heat release and lower cost for moving the air through the system. C. Effectiveness gg‘g Storage Unit Heat retention of a storage unit during the holding period will depend essentially on four factors: (1) temperature gradient between the spheres and the surrounding medium, (2) the insulation effectiveness of the material enclosing the storage unit, (3) the length of holding period, and (h) the ratio of the storage material bordering the sides of the container to the total volume. 72 In the storage tests presented in Figure 26, the temperature gradient did not appear to have the effect on the heat retention characteristics as might be expected. The gradient was much higher in Test B; however, the percent of heat retained was slightly greater during the same period of 12 hours. Length of holding period has a considerable effect on the percent of heat retained in storage. For this small unit, the percent retained dropped to 55 after 12 hours, and then to 33 after 2h hours of storage. This low percentage of retention after 2h hours lies to the fact that 81 percent of the spheres in this small unit make up the outside boundary, which allows heat loss to be at a relatively higher rate than in a larger whit. This factor will be projected into the larger unit in the section devoted to application. Additional study of the storage was made of the layer profile with regard to the heat retained in Figures 27 through 30. The distinguishing change of layer profile during storage was a more rapid cooling of top and bottom layers as compared with center layers. A hump or higher heat level appears after about four hours of storage as a result of convection cooling in the tOp and bottom of the unit. In each of the four storage periods, heat loss was more pronounced on the lower side. rmess curves indicate that convection at the areas where air enters or exits must be kept at a minimum to reduce storage losses. 73 .35 cuckoo» No agioaoehefi 53:3: use: .3 .mfl Pusan «owdhovu Mo SHE. I, I, l l .l l I l I l/ rl I, I: Im— / ll / m / / II / / / / / I. / . / F. m I. condo? see: u T. .9219 0:035 033:0 dads mousse: no .93» see: and I I..- L r _ P _ _ _ _ h r _. 3 8 o 3 Jo ..dmoq quomme opteqno pue awn 083.103,: 30 .33.“, °dme¢ S ‘PO‘J'FEQOJ $99“ 130-1048 :5 so 8 .4 74 D. Heat Recovegy Characteristics #3E9_99§EEEEX or heat recovered after storage is_the most im— . portant factor governing justificatienmfpr.e.unit. The cooling or .._‘, heat recovering curves are given in Figures 27 through 31 for the five tests. These curves present qualitative characteristics during heat recovery. As the air flow has been reversed and cold air is coming up through the bottom layers first, it is expected that this section will cool at a faster rate. The disappearance of the storage "hump" in the heat level curves takes place at a rapid rate. .The curves then approach a straight line, which at the end of each test has only a small slope. Summation of heat levels for each layer at a Specified time in Figures 27 through 31 will give the total Quantity of heat in the system. These total energy levels are listed in Table V for the beginning of the storage period, end of storage period, end of cool- ing period, and total energy recovered. Note should be made that the Btu level in the unit depends on some reference. All calculations of the cumulative energy were made on the basis of initial temperature of spheres, which had to be adjusted to the incoming air temperature at time of cooling to give a true picture of recovery. Comparisons between tests can more easily be made by heat recovery characteristics which are summarized in Table VI. On the basis of available heat in the unit at end of Energy per layer, Btu's 75 1500 'lllll __ 0 hr (storage) 1200 —— 9 hr (storage) 800 ___ 0 min (cooling) A00 -—- ... 0 ~—- __ lllllllll 1 3 5 7 9 Layer Fig. 27. Heat level during storage and cooling, Test A. Energy per layer, Btu's 76 1200 -— __ — 0 hr (storage) "* 8m— _. 1.00— ._ 0 Layer Heat level during storage and cooling, Test B. Fig. 28. 600 ‘2; Energy per layer, Btu'e 'e’ 77 0 hr (storage) \__/ 14» hr (storage) 0 min (cooling) 15 min (cooling) 30 Fig. 29. Layer Heat level during storage and cooling, Test C. 800 . 600— x ' 5 n L— '5 __ 5 I: 9. . .3 1‘00— 12hr(storage) _ g. 0 min cooling) s a 0 L5. 15 ) zoo—- __ /\ A... “5 __‘ /\ o L L l 1 l 1 l 1 l 1 3 5 7 9 LBW Fig. 30. 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