eee LIBRARY Michigan State University PLACE IN RETURN BOX to remove this checkout from your record. TO AVOID FINES return on or before date due. MAY BE RECALLED with earlier due date if requested. DATE DUE DATE DUE DATE DUE 196 ~c/CIRC/DateDue.p65-p. 14 AGA T MAGITADS A REPORT Submitted to the Faculty of the Michigan agricultural Collese By Richard Rey Leon Schroyer Candidates for the Degree of Bachelor of Science June, 1921 MAC Of SOUT INUS. Introduction . 2. 2. © © © «© «© © © © 6 2 ew ew Theory of Magnetism. .« 2 « 2 © « «© © © «© © Tne Iiportvsice or wuslity. «©. © «© « «© «© «© « wne Tisportance of Uniformity . . 2. 2. « «© «© The Yualities Of VLerhanent Lagnets . ... . the sairect of an Air Gap oetween Poles... Aging or Maturing of Mepmets . 2. « « 2. « « -e Materials of Ientufacture .« « « « «© « e « « « Analysis and Veat Vreatnents of the Steels used by some of the more Prominent Manufe ke S. Ifaenet Steel «. © ~. «© «© «© «© © © © © @ Magneto MacnetS. .« « « « «© © © © © «© «© «© © « Meagpnet Testin:r 2. « 2 «6 «© «© «© «© © © © © «© « © Testing Permanent Magnets by tne use of a Ilgepnetometer. « « « © « © « © « «© « «© « @ research Work on verrenent Masnets . ... . LOG424 ConclusionS .« »« « « e « e e @ @ ctures 16 19 rae £4 27 26 Oe 57 46 INTRODUCTION. Although a vast amount of scientific investigation has been done, and a great deal has beg written on the subject of permanent megnets, it re- mains one upon which very little practical, useful in- formation exists. ‘The reason for this is the fact that no laws have yet been discovered, fixing any relation between the qualities of the permanent magnet, and the Character of the meterials and the conditions of manufacture, upon which the megnetic qualities of the magnet depend. Any one who has the means for forming, herden- ing, and magnetizing a piece of steel, can Imke a permanent magnet of some sort, but to renufacture permanent magnets of uniform high magnetic quality, re- quires something of the scientist, the chemist and the. metallurgist, tozether with the requisite special equip- ment and an organization experienced in this class of work. The writers will endeavor to cOmpile the best data available from the more prominent scientists, chemists, and metallurgists of the day, and in addition do some research work on the production of magnets under different heat treatments of the steel. MHEORY OD MAGHEDISI. It was early suggested that magnetization is @ molecular phenomenon. ‘The fact thet a magnet mey be broken into an almost unlimited number of pieces, each of which remains a magnet with a north and south pole of its own, points very strongly in this direction. This view is also confirmed by the fact that a tube of iron filings, when placed along the poles of a strong magnet becomes megnetized, and when removed remains magnetized, until by shaking or jarring it is demagnetized. More convincing still is the fact that a long wire of soft iron may be strongly magnetized and by a slight jar lose nearly all of its magnetism. Miost striking of all, however, is the fact that @ piece of fron when raised to red heat loses its magnetic quality. (roof of the above statements can be found in any Gen. Physics). All of these facts lead us to think that magnetization is not a property of the surface of a body or of the body as a whole, but of its inermost structure. The evidence is indeed overwhelming in favor of the view that magnetism is a molecular or atomic phenomenon. The second step was made by We E. Weber, who de explained ferromagnetism by assuming thet the molecules Of iron are themselves small permanent magnets, arranged in no particular order, as indicated by Fig. below. Ew HA \% OT Ne \ 7 If these molecular magnets were perfectly free to turn, it is clear that any magnetic force acting upon them would be sufficient to bring them all into line and thus produce at once the maximum intensity of magnetization. In order to avoid this, weber imagined each molecule in its Original direction. The effect of this restraining force is represented in the Fig. below. The neagnetic field does not bring all the tiny tmgnets into perfect psrrallelisn, but merely brings them more or less into line, as there shown. ar” we NO ™ Nr AA =... ie. —_-— The third step is to develop this theory so as to enable one to include in his explanation the facts of paramagnetism and diamagnetism. This extension of the theory we owe to Rowland, J. J. Thomson, and Lagevin. A brief outline of this theory is as follows: It is well known thet a small circular electric current behsves like 4. a small magnet. In 1876, 2rofessor Xowland showed by a justly celebrated and difficult experiment that a re- volving electric charge produces the same magnetic effects as an electric current. In 1897, J. J. Thomson demonstrated the existence of sriell electric charges, having a mass about 1/1700 that of sa hydrogen aton. These small charges are negative in sizm gand can be Obtained from a great variety of sources. They are called electrons. The present view (1915) cf an atom is that it is built up, in pert ot least, of a num cr of electrons in rapid rotation about eae central nucleus of positive electrification. #ach of tue se electrons moving in its orbit is equivalent to a minute megnet. This view is supported by strong experimental evidence, such as that of the Zeeman effect. Assuming an atomic structure of this kind, P. Langevin in France has pointed out the possibility that these electronic orbits, in any one atom, may be oriented in a great variety of ways. In the case of diamagnetic substances, these Orbits are supposed to be distributed in stich a@ simnetrical way that they produce no magnetic field outside of the aton, the diamagnetic atom has no regnetic moment of its own. If, however, this diamagnetic substance be placed in a mégnetic field, lines of mepnetic force will be thrust thru any of De these orbits which are not exactly parallel to the field, and as one looks along the lines of force, those electrons which are revolving in a clockwise sense will be acceler- ated, those revolving in a counter-clockwise sense will be retarded; so that, in either event, the magnetic moment of the atom will be increased in @ sense opposite to that of the field. In other words, an atom with a perfectly symmetrical distribution of electronic orbits when placed in a msgnetic field behaves as a diaragnetic substance. In the case of a paramagnetic substance, it is supposed that the orbits of the electrons are distributed in such a wa: that they do not exactly cancel the effects, on one another; that is, these atons have a meegnetic moment of their owmm, and being little megnets will fall into alignment, more or less, when acted upon by an external field. ‘The turning of these tiny nmegnets will of course, always be in such a sense as to bring the § pole of the atom to face the N pole of the field-producing magnet. Atoms which are symmetric will therefore behave in a paramagnetic waye But superposed upon this effect will be the diamagnetic effect discussed in the preceeding paragraph. In most cases however, these diamagnetic effects ere emsll in comparison with the effect of rotating the orbits. What sort of resistence these orbits offer to rotation is entirely unknown. In the case of ferromesnetic substances, the experimentel fects of Ewing's model lead one to think that there are mituel actions between the atome or molecules. iwhen an external field is enplied to a ferromagnetic substance, the natural groupings of the molecules are changed; these elementary magnets fall into new nositions of equilibrum, one after another and we have the effects knovn as permanent regnetism, etc. The key then to ferromagnetism is the attraction and repulsion of One molecular Imgenet upon the other. By going one step farther and assuming that dia-~ magnetism is an atomic phenomenon wrile paramagnetism is @ molecular property, one may explain an important fact discovered by 2. Curie, namely, that the susceptibility of paramagnets varies inversely es the absolute temper- ature. Cn the other hand K. T. Comton end E. A. Trousdale offer experimental evidence, ootained by X-ray photograbhy, for thinking that paramagnetism is not a molecular, but an atomic, phenomenon. Te TH IIPCRTaNCS OF QUALI™Y. In the majority of cases, the purpose for which permanent magnets sre used is such thet the quality, accuracy, efficiency, or usefulness of the heachines or instruments of which they form a part, denend directly upon the megnetic qualities of the permanent magnets used. In electrical measuring and recording instruments, the maintenance of accuracy denends absolutely upon the retentivity of the mgnets. In the case of nagnetos, efficiency and successful operation sre both determined by the quality of the megnets. The qualities of the permanent megnet, that is, cheracteristics which determine its quality as a magnet, re- Main unchanged indefinitely. They are e characteristic of the particular piece of steel, in its particular state, just as its hardness, tensile strength or elastic limit. A great many neople confuse state of magnetization with magnetic quality, whereas they mean totally different things. Demarnetizing a megnet changes its state of regnetization, but dves not alter its quality; a finished piece hes, be- fore it is mepnetized, tre aqivelities which determine how good a hagnet it will be when regnetized. The quality of a fagnet can be affected only by Sone treatment which will at tne same time affect its physical charscteristics, ©.2h as by heeting or annealing. THE IMPORTANCE OF UNIFPORNIDY. The desig of a rechine or instrument in which permanent magnets are used, is, of course, based upon some known or assumed qualities of the nagmets to be used, and good desig requires that the megnet, in its design, be ade»nted to the use to be nede of it, and the conditions under which it is to operate. iwhen this hes bee@m done, it is necessary that the tegnets be uniform in quality, other- wise the finished product will very in quality, accuracy or efficiency by the same amount that the usgnets do. This uniformity of negnetic quality is esnecially important where two or more maenets are acting in parallel On the sane magnetic circuit, because so placing negnets of unequal strength and retentivity has an effect similar to that obtained by placing batteries or generators of different voltage in parallel. The same statenent holds true for isgnets made up of two or more leaves, sand in the design and renufacture of compound megnets, it is a matter of importance to see that the several portions are so related and of such uniformity that they will operate properly together. For the same reason, it follows that maximum magnetic quality in a menet of considerable cross-section, can only be odtained by the use of steel of an analysis, and a treatment, which will insure uniform quality throughout the cross-section of the megnet. It is this feature which limits the cross-section which can be successfully used, and makes necessary the use of steel of different chemical content, subjected to correspond- ingly different treatrent, if the best results are to be obtained in the mgrets of different cross-section. 10. THE QUALITIES OF PHRUSNHUT MAGNETS. Generally speaxing, there are two things which are a measure of the quality of a permanent megnet. They are: 1. The residual induction or residual magnetic flux. 2. The retentivity or coercive force. When materials have been riagnetized and the ragnetizing field is reduced to zero, a certain percentage of the initial induction, B, is retained. This is called residual induction and is designated by the symbol B. Different substances retain magnetism with varying degrees Of avidity or strength. The strength of field necessary to reduce B.. to zero, that is, to deregnetize the material, is called the coercive field and is designeted by Hcoer. or Ho: While these two qualities or characteristics are somewhat related, in so far as the conditions which affect them are concerned, the existence of rexinum residual in- duction does not necessarily imply that the retentivity is @ maximum residual induction does not necessarily imply that the retentivity is a maximum, or vice versa. The best permanent magnet is the one in which both these qualities are at the meximum. It requires long experience in the selection of steel and the utmost skill in the treatment of it to produce permanent reagnets which are ll. uniform in both residual induction and retentivity. Almost all kinds of steel which can be tempered will retain a portion of their initial remetisn if magnetized. There are, however, very few kinds of steel which raxe relatively good permanent magnets, and the quality of the megnets mde from any kind of steel depends upon a great many things. They are: 1. Chemical content. 2. Conditions under which the billets are nade. 3. Annealing. 4. Rolling conditions. 5. Furnace conditions and treatment during the forming or forging of the meegnets. 6. Conditions under which final heat treatment is done. 7. The mechanical operations performed after final heat treatment. 8. The process of maturing. 9. Method of magnetizing. From this, it is easily seen that from the time the steel is melted until the megnet is finished, there are conditions and processes which materielly affect the final quality of the magnet. ‘The matter is still further complicated by the fact that the effect of one condition Or process on the quality of the megmet mey depend upon One or more of the other variable conditions. lie For example, the result obtained from different heat treatments may devend somewhat upon the chemical analysis. The fact that a change in one may alter the effect of a change in another condition, necessitates the keeping of continuous records of all the conditions, in order tO so control them as to produce a product of maximum quality and uniformity. In Fig. "1" are the reenetization curves of three kinds of iron; these curves show the relation be-~ tween the regnetizing force, or the magnetic fields in the air surrounding the iron, and the corresponding magnetic density in the iron itself when acted upon by the field in the air. These curves show the relative ease with which these materials are magnetized, but have nothing to do with their ability to retain magnetism. They are important nevertheless, because a permanent magnet is required to drive its magnetic flux throughout its own length, as well as thru the msgnetic Gircuit upon which it is operating. It follows therefore that any condition in manufacture which increases the magnetic resistance or reluctance of a nmegmet without a corresponding increase in the retentivity is detrimental to its quality. In Fig. "2" are shown the hysteresis curves of the same three nieces of iron. ‘Tnese curves are obtained eg Nene Gee we er Zs =—6‘ Ee | Lee Se ee ADZTION AWYENLINDIYBOYV N¥DIHOIN 13. by megnetizing the iron to a@ knovn maximum magnetic density, represented by the point"a”"on the curve. The megnetizing force is then gradi.ally redvced, the tagnetic density falling along the curve as imicated by the errow. At the ooint "B" where the curve crogses the line of zero magnetizing force, the distance O-B re- presents the strenzth of permenent megnetism. If, now, the magnetizing force ve reversed in direction and applied so as to reduce the residual magnetism, the magnetic density will cont: rue to decrease until it becones zero, where the eurve crosses the horizontal axis at "Cc". The dere pnetizing force represented by tne velue O-C is that force necessary to balance the rmégenetizing Sorce of the magnet itself; it is the messure of the difficulty of magmetizing the magnet, or of the power with which the magnet holds its magmetism. TYnis quality is known as the retentivity or coercive force. The vertical distance O-8 is therefore the measure of residual megnetism, or residual induction, and denotes the strength of the Legnet in so far as its magnetic flux is concerned, wheress the distance O-C represents the tenacity with which the imesgnet holds its magnetism. Both of these quelities are of extreme importance, and it cannot be said that one is more importent than the Other. High magnetic strength is of little value if that 14. strength is not made stable by high retentivity. Neither can a megnet ve said to be of high auality if its retentivity be high and its strength low. Referring to Hig. "2", it will be noted that the re- tentivity of hardened cast iron is approximately 75% of that of hardened tungsten steel, while the residual density of cast iron is only about 30% of that of a tungsten magnet. It should be born in mind, however, that both the magnetic strength and the retentivity of any finished regnet depend upon the varying conditions of manufacture which we have named above. Even with material of the sane analysis, it is possible to maxe magnets of the same magnetic strength, but varying . widely in retentivity. It is also possible by verying the conditions to take from the sane steel magnets of the sane retentivity, but varying widely in residual Magnetism. In fact, it is quite difficult, using the same material, to keep from making magnets which vary in one or the other quality. In tig. "2" the curves shovm are the result of carrying the magnetization and the demagnetization thru @ complete cycle, but one-fourth of this cycle is all that is required in order to determine the qualities of the menet, as shown in Fig. "3". attention is cslled \ 15. to the fact that in the foregoing curves the megnetic density if expressed in the flux or ragnetic lines per unit area, and tne coercive fvrce or the retentivity is given per wnit of length; it follows therefore, that the total ragnetic strength of a magnet having given residual flux per unit area is proportional to its cross-sectional area, and the ability of a negmet of given retentivity to hold its magnetism is proportional to its length; thet is, the length of the var from which it is made. 16. THH EEFCCT OF AN AIR GAP BETWEEN POLES. In making tests such eas are indicated in the results plotted in Fig. "2" md Fig. "3", the magnet under test constitutes the entire ragnetic circuit. The curves give the result which would be obtained if the regnet were a closed ring with no air gap be- tween the poles. In other words, they rerresent the quality of steel as a magnet, and that along. The useful flux of a permanent megnet Operating across an air gap is always less than the flux which the magnet would give with no gap between its poles, or when marnetically "short-circuited". On account of the very high reluctance or megnetic resistance of air the residual magnetism of a magnet of a given length is less@med as the air peth between tne poles is in- creased, and right here comes a very important con- sideration in the design of apparatus embcdying the use Of permanent menets. Referring to Pig. "S", it will be noted that as the demagnetizing force is increased from 0, the residual magnetism reduces very siowly at first, and that as the demagnetizing force is increased the magnetism falls more and more rapidly tntil finally it comes down along am almost vertical line. This indicates that for moderate demagnetizing forces the permanent magnetism ee Sa SP i es eee eee ee Sol. wwant rc on a = ' BVSTIOD AVYENLINGIBOVY NYOIHDIN 17. is very stable, but that if the demagnetizing action be carried beyond a certain walue the flux becomes un- stable and the mignet will not recover its strength when the deragnetizing force is removed. Since the introduction of an air gan between the poles of a permanent neégnet has the effect of partially demsgnetizing it, end the extent of demagnet- ization depends upon the relstive jength of the megnet and the air gap, it is important thet the ration of length of ragnet to length of air gap be such that the vagnet will not be demagnetized by the air gap to the point where megnetization becomes unstable. In some types of apparatus the permanent magnets used are required to operate in Opposition to a coil of wire carrying an electric current, as in the case of a magneto, the denagnetizing effect of which is added to that caused by the air gap, and in designing apparatus of this character it is important to take into account the effects of both the air gap and the coil. If the magnetization in a permanent magnet be Once reduced to the point where it becomes unsteble, the magnet will not recover, so that it is important to bear in mind that the characteristics of the magnet and the magnetic circuit on which it operates mist be such that the maximum reduction of flux under any condition of Operation must not be to a point where the flux becomes 16. unstavle. Since the retentivity of a magnet is the meesure of its stability in opposition to demagnetizing effects, the reader will readily see that this quality is of equal, if not greater importance, than the regnetic strength. It is possible, by the proper selection of steel and the use of a heat treatrent corresponding to the cheracteristics of the steel, to produce magnets of uniformly high retentivity without sacrificing i.gnet strength. It is also possible by using a heat treatment adapted to the character of the steel to obtain maxinum strength without sacrificing its re- tentivity. It is essential, for the best results, that the naeg- net be selected or designed for the magnetic circuit on which it is to opperate, and for any htegnetic circuit considered there is a cross-section and length .of permanent magnet which will give the maximum flux, with the reqiisite stability, using a minimm amoung of INagnet steel. 19. AGING OR TatURING OF MAGI ATS. In some classes of apvaratus, particularly electrical indicating, integrating snd recording instruments, the maintenance of the initial cali- bration and accuracy of the instrumj™mts, requires that the regnets be brought to as stable a magnetic condition as possible before the instrument is cali- brated. This is called sging or maturing of the magnets. Bringing a negnet into a condition where its flux wiil be stable requires two things, viz; le. A physical treatuent of the steel after quench- ing, which makes further changes in its structure, molecular condition or rapnetic quality improbable. 2- A magnetic treatment of the megnet after megnetize ation, which will make changes in its state of magnetization, uncer the conditions of ordinary oneration improbabl3. Yren a menet is hardened it, of course, under- goes very rapid structural changes, and for a time after quenching there is a change in donditions taking place, quite rapidly at first and gradually decreasing until the physical properties become stable. This stability, of structural state of the steel can be hastened by physical treatment, which process is celled aging or hte ia ere meee PTT a Be Sala ei roi 3) mae h 2) ) be) ) | 20 6 maturing. Cbviously the trentnjmt applied mst be such as to only age the steel without impairing its magnetic qualities. AS hes been already stated, it is pcescible after magnetizing a magnet to bring it to a state of hegretiz- ation, in which the totel or useful flux will not be greatly altered by such delagnetizing action as that to which the magnet will be subjected in use, provided, of course, it is properly designed for the magnetic circuit on which it is used. It should be clearly understood thet this treatment aoes not alter the retentivity of the regnet, but simply changes the magnetic State in such a meamner that the ratio of change in flux to magnetiving or demagnetizing effects is re- duced at that part of the titegnetic cycle represented by the state of residual re gnetization. In Fig. "3" we have given a curve showing the relation between residual density end regnetizing and demagnetizing forces, from the point of rmaximim magcnetia- ation to complete demagnetization, when the change from One state to another is gradual and uninterrupted. It will be noted that upon the application of a demagnetiz- ing force, the residual induction begins to drop and as the force is incressed the reduction becomes more rapid, until a point is reached where the curve is almost 21. parallel to the flux ordinate. this means thet with a megnet in this state of macnetization the flux of the magnet will very along this curve when the wagnet is subjected to eny exterior magnetizing or demagnetizing force, such as the action of a coil on stray fields, etc. In order to rake the value of the residual flux as stable as possible, it is neceasary to have the curve as nearly parallel as possible to the horizontal axis. In Pig. "5" is shown the curve of a msgnet teken as it is put through this stabilizing process. The arrows indicate the direction of megnetization or de- Magnetization. after the mgnet has been fully magnetiz- ed, a demagnetizing force is applied which removes a pore tion of the flux. It is next subjected to a nmegnetizing force, and then to a demagnetizing effect, which hes the effect of bringing the curve more nesrly yvarallel to the base line, although the residusl induction is somewhat reduced. It is obvious that this treatment should be applied after the regnetic circuit on which the hagnet is to operate has been completely assembled. Le MATERIALS OF MANUFACTURE. Permanent magnets can be made of cast iron, of steel carrying from e3 to 1.5% of carbon, or of alloy steel containing carbon, together with tungsten, molybdemum, chromium or vanadium. Cast iron magnets are used principally in galvonometers and similar apparatus, where weight is not objectionable and efficiency is not a matter of importance. CARBON STEEL MiaGN TS. For some classes of work, where snsce end weicht are not of importance, magnets msde of a good grade of onen hearth carpnon steel are used. By a careful selection of such steel with reference to its carvon, manganese, sulphur and phosphorus content, it is possible by proper heat treatment to produce magnets having a flux or magnetic strength of about 75% that of tungsten or chromium steel magnets of the same cross-section, and a retentivity of about 70% of that of the better grades of steels just named. TUNGS®T2N SPuuL. Por many years prior to the outbreax of the Huronean war the alloy steel most commonly, in fact almost universally used in the menufacture of hich grede £56 ynermanent mmagnets, was one contsining principally cer- bon, tungsten and chromium, and in which the percent- age of manganese, sulnhur and phosphorus were kept to the lowest practical limits. such an alloy, if properly made in the steel mill and intelligently processed in the magnet-rmaking plent, will produce Insgnets of high strength and vermanence. Due to the very high cost and the inability to obtain tungsten steel during the war, it was necessary to develop other alloys for use in the manufacture of permanent megmets. CHORIUM STL. By the use of chromium elloys, produced under correct conditions and treated according to processes particulsrliy adapted to them, magnets are being produced wnich, from the standpoint of both strength and retentiv- ity, are the equal to the tungsten product. It is a fact that the chromium alloys do not permit of as wide a range in the manufacturing and the heat treating conditions as the tungsten steel, but with proper and uniform conditions the product shows greater uniform- ity than was the case with the tungsten alloy. That is, the average results with echromium steel alloys are in every way equal to those obtained with tungsten steel, and the prodict does not vary from the averege by nearly so wide a margin as in the case of the tungsten alloy. 246 ANALYSES AUD HEAT TREATIENTS OF THE STEELS USED BY SOLS OF GEE MORIS PaOlincan ? MAUUPACTURIRS - NDIANA STi PACDUCWS COCliranY. Analysis. Tungsten steel Chromium steel Carbon 0.65 Carbon 0.65 Tungsten 5.75 Chromium 2.4) Heat Treatment. The steel is nerdened at the correct heat, which varies according to the size, from 1480 to 1550 degrees Fe, and quenched in water or a gcolution so that the material is hardened throughout the entire section. SLLITDORE ELECTRICAL CChYVany, Analysis-chromium steel. Caroon 0.889 Chromium £2.03 Vanadium TraceSe Heat Treatnent. The steel is heated to 148) degrees I'., and quenched in water. Mi MSPURDIN'’ COMPANY. Analysis-cnromium steel. Carbon 0.89 Phos. O.017 Sulphur 0.023 BD. Silicon eno Mans". 0.44 Chrom. 3.03 Heat Treatment. Mane steel is heated to 1525-1550 degrees F., and quenched in oil. STROMBERG-CARLSCN TRIECHCIE MaAMPacTUnING CCLPany. Analysis. Tungsten steel. Chromium steel. Carbon C.39 Carbon 0.89 Tungsten 6.0) Cnromium 2.00#2.25 liest Treatient. Chrome regnets are herdened at a temperature of about 1450 derrees i'., while the Tungsten magnets sre ~ hardened at 1550 to 1600 degrees F. Til BRITISH DLCLOCU-HCUS™CH CCiaaAny, LIMITOL. Analysis. Tungsten steel Grade l. Grade 2. Sungsten 5.960 5.460 Langanese 0.245 0.404 Carbon 0.616 0.698 Chromium stecl. Chromium 2.000 Caroon about 0.750 £56 Neat Trerptment. Tne stecl is hested to 750 degrees C, or 1360 derrees i*., and quencned in water. TiS SULIVOMO CuvUneusiC, LTp. Ci’ COAcA, Javali. This commany has recentiy petertea a new Legnetic steel contsining from 0.3 to 0.2 per cent carbon an ebout 35 per cent cobalt alloyed vith either chroniun, molybdenum, or tungsten. It is claimed thet regnet steel of tris composition will pive a coercive force apprecially over 200, coupled with @ remenence of about 10,000. ZT. Ke Se. BPAGNET STEAL. In June 1917, a new alloy steel wes discovered by ik. Honda, a Japanese scientist. This steel poesess- es a very high coercive force, and no doubt is the best magnet steel knovm. The composition of this steel is given eas Carbon 0.4 - 0.8 percent, Cobalt 30 - 40 percent, Tungsten 5 ~ 9 percent, Chromium 1.5 = 8 percent. Tetspering is best effected by heating to 950 degrees C, Or 174) degrees F., and quenching in heavy oil. Measure- ments of the residuel magnetism for specimens of diff- erent composition, give values from 92) to 620 C.G.S. units; the coercive force for the same snecimens ranged from 226 to 257 gauss. Artificial aging heating in boiling water and by repeated mechanical shock reduced the residusl magnetism only 6%. The hysteresis curve for a magnetizing force of 1,300 gauss were teken for annealed and tempered specimens; for the annesled Specimen the coercive force was 30 gauss end for harden- ed steel the coercive force was 238 gauss and the energy loss per cycle 909,000 ergs. The hardness of ennealed and temoered siecimens was fourd to be 444 and 652 respectively on the 3rinell scale and 38 and 55 on the shore scale. The miscostructure of the herdened steel Showed a finer grain than for the annealed. 28. MAGUETO Machats. As is well knovwm, the permenent nmegnets are the most important part of any megneto, and unless the nagnet be a thoroughly good one and well magnetiz- ed, the magneto will give a very poor performance on test. The manufacture of magneto regnets is attended with considerable difficulties because it is essential that the menet be finished to fine mechanical accuracy, and at the same time, the magnetic cheracter- istics must be extremely good. 3roadly speaking, the essential characteristics are: 1. The magnet must be thoroughly sound throughout its whole structure. That is, there must be no visible or incipient cracks or flaws. 2e The grinding of the pole pieces and edges must be carried out to the necessary fine limits of accuracy demaided by the desig of the negnetos. 4. The magnetic characteristics mst ress a certain mMinimm. In other words, the magnet when fitted to the magneto mst be capable of creating in the armature core a certain nurber of wagnetic lines and of mintaining these during subsequent life of the magneto. Under working conditione, the megsneto is subjected 29-6 to considerable vibration and extrene and frequent variations in temperature. any periranent magnet is liable to lose its strength when operating under such conditions, and to guard a loss of this reture, it is necessary in hardening the magnet to aim at what is termed a coercive force, not less than a certain minimum. Experience has shown that a save mininum is 55, and with certain grades of regnet steel it is quite safe to go below this fieure. The coercive force figure is simoly an indication of the power of the magnet to retain its mernetic field. That is, it is a measure of the mpnetic tenacity of the steel. It is slso desirable that the regnet should pro- duce, when fitted in place, as large a flux as possible. The actual working flux in the armature core veries be- tween 20,000 and 50,000 magnetic lines, the forrer Pisure applying to polar inductor magnetos, and the latter figure to large rotating arreture magnetos. Small rotating armature machines have an active flux much nearer the lower figure snecified. liiow the value of this flux, for a given design of mgneto, is great- ly dependent on what is called the renanence of the magnet. An average figure is 10,000 and it is desirable that the remanence should be ges high as possible. The remanence ficure is an indicetion of the flux thst would 30. circulate around the megnet if its poles were bridged with a heavy soft iron keeper, and it were then magnetized in that condition. “here has been a great deal of controversy about the coercive force ard the rersanence. It so heppens that it is only possible to increase one of tnese factors at the expense of the other. Thst is, if the coercive force be increased abnornally, as it cen be by svecial methods of hardening, the remanence will be lowered, and vice versa. It is contended in certain quarters that a regnet with a very hich coercive force (70) and a fairly low remanence (9,000 to 9,500) is better than one having sa fairly low coercive force (55) and a very high remanence (10,500 to 11,000). Prom experience, it has been shown that the best re- sults are obteined by striking a happy medium, end that it is really a retrograde move, with the megnet steels at present available, to increase the coercive force beyond a range of from 60 to 65. If an endesvor be made to vnush the coercive force beyond the upper limit, the difficulties of ran.fecture will be increased considerably, and the steel will be brougnit to such a degree cf rardness that incipient cracks are likely to develop muck more rapidly. No compensating advantesze will be obtained, and ss a mstter dl. of fact, the active flux created in the regneto arnature way tend to diminish in consequence of the lower rerianence.e It must be pointed out thet different steels behave in different ways, and while it way be quite sare to work down to a coercive force of 55 with one grade of steel, another grade having slight- ly different composition will demand s minimum figure of at least 60. This curious difference in vehaviour can be exynlained, but the explenation is outside the scope of this work. 32.6 MsGNe? THs®iInG. The testing of rmeynets to determine their Suitability for use hes been a difficult and con- tentious problem, rainiy owing to the disarreenent between leading authorities as to tne trie criterion of ragnetic quality. Guite recently is hes heen egreed by those able to pronounce judgment on this subject, that the vartictlar characteristics of a magnet which are of importance depend on three distinct factors: il. Remanence, 2e Coercive force, oe “he shave of the remanence-coercive force curve. This will be mde clear by reference to curve l, Wig. 642 If we assume thst a magnet is wound over its whole length with a magnetizing coil, and then has its poles bridged by a substantial soft iron keeper making a good contact with them, the flux density in the body or the ragnet after passing a very heavy current through the coil and again breaking the circuit, would be re- presented by B, which is called the renenence. Now if a reverse current be passed through the coil, the mgnet can be slowly demagnetized by gradually increasing the value of this qmrrent. With special apparatus, the vslue of the flux density in the regnet MICHIGAN AGRICULTURAL COLLEGE oe eS ees OF MAT reat alae] JS6 can be readily measured for any value of demagnetiz- ing current, and by plotting these readings curve l, rize 6, i8 obtained. Oorrespondcing to sone definite value of the demagnetizing current, the flux density is brought to zero. This corresponds to the point where the curve strixes the axis of abscissae. The coercive force Cp is calculated from this denagnetiz- ing current by taking into consideration the length of the magnet and the number of turns of the ooil. The important agreement on this netter thet has now been reached, relates to the ordinate CB, which is the actual flux density in the magnet at some intere- mediate voint in the demagnetizing force (EH), and can be taken as the figure of merit when comparing the magnetic quality of magnets thet are closely alike. It will be noted that it depends on the three factors already enumerated. Experience shows that if the value of the demagnetizing force (H) be fixed at approximate-= ly 35, then the corresponding value of OB, gives an accurate indication of how the magnet will perform in the instrument for which it is designed. In other words, O23) under these conditions is a figure of merit. A good method for testing magnetos is shown in Pig. 7. The apparatus used comprises a moving coil type of measuring instrument, from which the ordinary “oe CONSTANT CURRENT . IN THE Mee DEMAGNETISING COILS PSOE A | late 7 A Magnet A OP aha 34. permanent magnet has been removed, special pole pieces being provided so that the meget to be tested can be brought quickly into contact with them. With a constant current flowing thru the moving coil, the deflection of the pointer on the uniformly graduated scale gives a direct indication of the flux in the mefnet. In the testing outrit as shown diarrammatically in Fig. 7, two dermgnetizing coils are fitted to the top of the instrument case so thet these enbrace the limbs of tre regnet when it is fitted to the poles. The magnet is first rapnetized on a separate and dis- tinct magnetizing outfit. With each magnet, three readinzs are taken; 1. The first reading immediately after magnetiz- ing the imegnet and fitting it to the instrue ment. Call this a: 2e The circuit through the densgnetizing coils is then completed through a lerge variable resiste ance, and the deresnetizing current gradually increased. Corresponding to a demagnetizing force of approximately 35, the deflection is again observed. Call this do. 3. The demagnetizing current is further increased until the deflection is just zero. The demegnet- izing current is carefully noted. Call this cal. 356 By using standard nemmets of different nagnetic characteristics, it is possible to calibrate the in- strument so that the actual coercive fcrce snd re- manence figures for any magnet tested can be deduced from the readings dj and c,. Brieily, if the readings as set forth above be taxen with a set of standard Isgnets of any particular make, and it is necessary to use standards representative of each quelity of steel, the results can be plotted to give two straight lines: (a) whe first connecting dz and the rroduct (b) “Whe second connecting cz and Cr. From these calibration curves, the values of By. and Cp Tor any mernet tested, can be deduced fron the readings dy; and c by reterriny to the calibration 1? curves that have been plotted from readings given by standard pagnets of corresponding nake. But as already pointed out, B, and Cp are not the whole story, and the reading dy taxen by itself, is a criterion of megnetic quality, when testing magnets in bulk Which ere, as is usual, closely alike. Tire fallacy Of devnending entirely on the renuanence and the coercive force figures, and fortunately, dependence has been placed on figures almost entirely in the pest, is made apparent by curve © in Fig. 62. It is a hypothetical case, but assuming tnat a megnet fave such a denagnet- izing curve, it srkould be noted that the active flux in the armature core of the instrument to which it is fixed would be approximately OB,/0B, or 60 per cent of the flux produced by the other 1#gnet when fitted to the same instrument, despite the fact that the re- manence and the coercive force figures are identical. The agreehnent is that the raxilmm value of the product of flux density and demagnetizing force reéch- ed during the deliagnetizing process, can be taken as a figure of merit, provided that the rerenerce and coercive force figures are of the same order. A large number of tests have revealed the fact that on the average the minimum point on this new curve lies epproxirately along a line drawn through the abscissa whose point H equals 35. On this basis, tne ordinate OB, is approximtely a measure of the maximum product referred to, and the two methods of testing ghould therefore yield substantially the same results. —o —_———$<_—_———. ———— ———— — O7. TESTING PERUMANUNT MAGI EDS 3Y GEE USa OF A LWAGHNSTOLBTER. The epparatus used in this rethod of testing is shown in Fiz. 8 and consists of; le A magnetometer, ce A telescove witn a scale attached, 3e An appsratus for the holding of magnets to be tested with divisions merked off in cm. for obtaining the distance of the negnet from the magnetometer. ™he marnetometer consists of three small megnets mode from 3/4" lengths of a watch spring and a smell mirror about 1/2" square fastened upon a nonmagnetic holder, as shovn in the right hand corner of Vig. 8. This apysratus is suspended by a single strand of silk fibre in a box lixe structure. The silk fibre is attached to a pin which is adjustable so as to be able to raise and lower the magretometer. The box enclosing the magnetometer has a glass front facing the telescope and scale so that the deflections of the magnetometer can be caught from the mirror. The deflections of the magnetometer are read through the telescope from the scale attached. aul, ata ee cr ¢stment for mre bald Sommerer Pn OSE err magre a eal “regrre wi) i -Me d od a Dd ahahae a et eee Sold Ps Nae 4 Aah L eel ae a / | AAGHETZLES bar ee MLPA IAN nm rm rm rt ri i L. nm mt n ] ae D S Magnetomerer AT TE 358. PO SOT Up TH APLARATUS. The apparatus is set up as shown in the figure witn the watch springs remets or the regnetometer acting in the same direction as the earth's magnetic field. ‘The telescope is set at a distance of 90 cm. from the center of the menetormeter and the scele set at 25. The device for holding the magnets to be tested is placed in the same plain as the magnetoreter and at right angles to the earth's magnetic field. TOSTING TRE MAGNUTS. The center of the vegnet to be tested is placed at a distance of 100 cm. from the magnetometer with the axis of the magnet perpendicular to the earth's magnetic field from the center of the magnetometer. The lines of force from the megnet attract one pole of the watch soring magnet and repell the other thus producing an anzle between the axis of the watch spring mgnet and the earth's mmgnetic field. That is, the permanent magnet deflects the watch spring nazgnet from the action of the earth's magnetic field to the extent of the intensity of the permanent mignet. These deflections are measured from the deflections of the scale in the nirror thru the telescope. These deflections are averaged for both poles of the magnets and the mgnetic monent and the pole strength of the msgnet is obtained from the followe- 396 ing formlae: . 3 h 3 Yt ad*’ tan theta or K equals H adv tan theta H a a Pole strength equals M/l c.g.s.- Where; Kk equals the magnetic moment, H equals the horizontal component of the earth's megnetic field which was 0.173 under conditions of testing. d equals the distance of the center of the permanent maget from the center of the Ihagne tometer. tan theta equals one half the deflection read upon the scale divided by the distance of the telescope from the magnetometer. 1 equsls the length of the permanent magnet. 49. RESEARCH WORK ON PARNIANTNT MAGUS. OBJZCT: The object of this research work is to obtain the comperative pole strength of permanent regnets produced under mametization diring different heat treatinents of the steel, end to prove certain assumptions in connection with tne theories of magnetism. ASSUL@TICNS: het is the molecular theory of regnetism is true; then it is the oninion of the writers that upon heating a piece of steel, the molecules will be ina more pliable state ard therefore more easily moved. Tnet is, the freeness of movement of the molecules in- creases in some vroportion to the increase of temper- ature in the steel. Now if a piece of steel is heated to a certsin temmerature and while at this heat, the steel is mepnetized by a suitable flux, then the molecules will arrange themselves more easily and in a less distorted fashion then under ordinery megnetization of the cold steel. In fact, there should be a greater nulber Of molecules in a better alignment due to a greater freedom of motion of these molecules, snd upon bringing the temperature of the steel down to thet of the foom, the molecules should be in a less strained 41. condition than under tre ordinsry means of magnetiz- ation. With these conditions prevailing, a stronger wagnet should result from the heating, and it wes under these sssumptions that the writers experimented, the results of which follow. Of course, the electron theory has replaced the molecular theory t>) e certain degree, but the correct- ness of this theory is questioned by some of the fore- most physicists of the day. Tnis theory is, as exnvleined in a nrevious article, that the atoms of a substance are built up, in pert st least, of a number of electrons in repid rotation about e certain nucleus of positive electrification. Hach of these electrons moving in its orbit is equivalent to a minute msemet. In case of diamagnetic si..bstancec, these orbits are “supposed to be distribi.tea in such a symmetricsl way that they produce no magnetic field outside of the atom. Tne diamagnetic atom has no feenetic moment of its own. In the case of paramagnetic substances, it is supposed that the orbits of the electrons ere so distributed thet the atoms have a megnetic moment of their own, and being little magnets will fall into elignment when acted upon by an external field. In the case of ferromsegnetic substances, there seem to be mtuval actions between the atoms or molecules. when an external field is applied to a ferromagnetic substance, the neturel groupings of the 42. molecules are changed; these eleuentary nme gnets fall into new positions of equilibrium, one after the other, and we have the effects know as permanent magnetism. The key tnen to ferromagretism is the attraction and the repulsion of one nolecular negnet upon another. The theory of megnetism is that the diaragnetic effect is probably present in all substances; but in Many cases, it is masked by tne psramagnetic tuming of the molectle, and there is also present a mutual action between molecules. ‘The Same reasoning and assumptions, as were brought forth ptnder the molecular theory, can be applied to the above theory. THY Le BORATORY WORK IN wHIS CONNECYVION. The steel used in this experiment was of the following composition: Carbon . 2. « «© «6 « « « «© 04890 Chromium 2. « © « e « © «© 36030 ManganeS@. « 6 « « « « « 0.440 Phosphorus « « « « « « « O.O17 Silicon. .« . 2. « « « « « Oe250 sulphure «© «6 « © © © « « 04023 Yhe steel had been hardened by heating to 1525 - 1550 degrees F., and quenching in oil. 43. CrLTVICAL POINT. A piece of the steal was annealed at 1450 degrees I'., sO as to be able to rechine it. a 3/16" hole was drilled in one end of a piece 1-1/2" long to e depth of 3/4". The piece was then placed in the Brom critical point determination apperatus. Tne resulting graph is shovm on the following page from which the Critical point was founac to be at 1250 degrees F. HMAT TRHAYMIONY AND MACHSTIZATION. There were seversl plans considered for the hest treatment and repnetizetion bit the writers finslly come to the conelusion that tne best method was to heat the steel to the right temmerature, pass a flux thru the bar by means of a lerge electro-tagnet f.r several seconds, and then to quencn the bar while it was still being magnetized. To build an apparatus to do these three things, heat and steel quench and mgmetize, in one unit would be a very difficult and unsatisfectory plan, so it was decided to régnetize end quench the Steel outside of the furnace. The steel (3/8" x 3/4" cross section) wes cut in 6" lengths and numbered 1,2,3,4,5,6,7,8,1]1 and 12. The bars were heated to the following temperatures: me se ¥ it var a 66 se. 3 ie 2 RE ae Sted. =, = J Md SES KS OT a. 408 ih om By ' : rt RS bapa a / ia my Pere rae eee bet tL a a Aus iW 44a. Bar WOe. 1 « «© «© «© © «© «© ¢ HKHOOM Vempereture " NB 0 eo © ow ew ew he he TOD degrees }. " MB ww ww wee ew 6 BUD " " " WA 6 ww ew we ew GOD " " " " Bow ew ew ew ew ew ew 2 LOOYD " " " "6 6 6 6 6 6 e e 0 L100 " " " " 7 e @ e e e e e eL200 " " " " 8 e e e e e e e ~1 300 " " Bars ll and 12 were heated to 1200 and 1300 de- grees ., resvectively for checx bars. “he bars were heated to their respective tenper- atures and held at this heet for rive minutes to insure a uniform heat throughout the bar. The bars were in- Stantly placed between the poles of a large electro- magnet and magnetized for 1) seccnds while they were at- heat. ‘his process should have helped the formetion of the elignment of the molectlar regnets. The bsrs were then quenched witn w:ter while they were still being magnetized keeping tre flux flowing thru bar for 50 seconds. TASTING. the pole strengths of the vegnets were found by the use of the megnetonueter anparatus which is fully described in the preceding erticie on testing pertenent Magnets. The bars were placed at a distunce of 1V0 cm. 456 from the magnetometer end an sverage deflection wes taken for both ooles of the naeznet. Fron these de- flections, the mwgnetic moment and the pole density were figured. Yhe formulae used for conputing the Inagcne tic moment end the pole density were; Ji; de tan theta sna pole strensth equals i H - Tem) Bar No. Pemnerature Deflection of Fkole strength of the bar Magnetometer in c.g.8. L room temp. 729935 249.8 2 70) 7.5200 240.0 3 890 700589 £058 4 909 5.4630 174.5 5 LOVO 6.8760 219.8 6 1100 65620 209.6 7 1200 6.4950 207.0 8 1300 5.1000 165.0 il 1200 6.9346 e115 12 13509 4.8962 156.3 a=x@s tne Wwe Abe = BZOSINIOS AWUNLINDI¥SOV NYSIHDIN re 46. OCH OLUSICNS eRe PeTene) atWe The results as shown in the table and grenph prove to be quite the opposite from wnet was expected. According to the assumptions, the feasi- bility of which has not been denied by any of the phzrrsicists with which the writers have consulted, the steel should increase in magnetic density, to a certain extent at least, witn a specified magnetiz- ation under a rise in temperature. This, however, was not the case bit quite tne onvnosite. Tne greeter the temperature at which the steel was rmegnetized the lower the pole density obtained. The question arrises as to tne effect of heat upon tre ratnetism of a piece of steel from the well known fact thet heat destrovs magnetism. This fact, however, dves not tend to tesr dovn the sssumptions made, but auite the contrary. The sinple exnerirrent of heating a regnet hus been shown to everyone wi:o has tuken ea course in physics and it not only substantiates the molecular theory but shows that the tmnolecules hsve been distorted from their normal position during the process of megnetization and that heat does have an effect upon the rovement of these molecules. What more proof does anyone want thet the assumptions wer logical?Is it not reasonable to suppose 47. tnat if this exneriment were reversed ana the heet used to mexe the molecules anpliable, ard a hagnetize ing force be tren avplied, and the material quenched, thet it would produce stronrer magnets with greater retentivity? There remsins but one other conclusion to the results and that is that the fundsmental idea or the moleculer theory is incorrect. ‘To decisively prove tnis would be a very laborious and difficult problem but the writers believe that they khaeve one of the most important ste»ping stones in tne process cf destroying the molecular theory. 48. Che writers wish to thank the following men for their interest and assistance in tniS work. Henry Lantz sublow, B.S., Chen. ng. Assistant rrofessor of Chemistry, Liichigean agricultural College. ndwin Jiorrison, Ji.5S. Assistant vrofessor of rhysics, Wichigean Agricultural Collese. Charles Willis Chepman, A.3B., Bs. 2rofessor of physics, Lichigan agricultural College. 7A Arthur xodney Sawyer, 3-Se, eile 2rofessor of Electrical Hnrineering, Michigen Agricultural College. Ae Ge iianover, Stromberg Carlson Telenhone ianufecturing Co. He. ike Curran, Indiana Steel Products Co. H. BH. Lrause 9 Splitdorf Hledtrical Co. Je Se Shunk, “he Shunk Manuracturing Co. Je we “SSterline, The osterline Co. 49. DO BIBLICGRALHY. Weaenetos - - - A. P. Young, ilistory or the Yheories of nether ana LMlectricity - Wnittaizer. Manufecture of liagneto lagnets - - - p. lk. Neldt, Keb. 3, 1921, Autonuobile Industries. Mlections - - - ‘xn. Inst. Jan. 1Y16&, Theories of lagnetism - - - §. 3ushren, G.h.R., ©>+ liayy, L9lo. wv Y Theory of Magnetism - - - Stradling, Journsl Fr. Inst. A J Trust ’ 1915. oteel for Verionent Magnets - - - S. B. Thompson, Journal Inst. wu, Vol. 50, pe 80, 1913. rerieanent Nagnets - - «= J. A. Mathews, iroce A.S.TeLi. Vol. 15, p. 50, 1914. ~ Permanent Marnets - - - F. C. xelley, Gu. Kev., Vole 20, pe 7, July, 1917. Pertkanent Magnets in neory and rypractice - - - me bvershed. Journal Inst. 3. os. Serte. 1920. liagsnet Steel - - - Uiataro Honda. U. S.~ Late 1, 256, 1352, 133, 154, Ape 27, Llc. Sl. Stability of Nesidusl liagnetism - - - Ne. H. Willisus, rphnyse ieve Vay 19135. pe 36d. Criterion for Testing Iissneto Vagnets - - - Je De WOorsan, London flect. Jan. 2, 1920. Pe 4. Method of Testing - - - McLachlan. wroc. Phys. Part 3, Apr. 15, 1920. U. Se 3ureau of Standards, Cir. 17. “ng ineering Vol. 107, April 25, 1919, p. 525. Dlectricul world. Vol. 15, ®Peb. &, 1Y19. p. 267. olectrician - - - tov. 17, 1916. SOC. 32, PP isa cn