THE PEDOLOGY OF SEVERAL PROFILES DEVELOPED IN THE CALCAREOUS DRIFT OF EASTERN MICHIGAN by ALLAN HERBERT A THESIS Submitted to the School of Graduate Studies of Michigan State College of Agriculture and Applied Science in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Department of Soil Science 1947 ^ ProQuest Number: 10008387 All rights reserved INFORMATION TO ALL USERS The quality of this reproduction is dependent upon the quality of the copy submitted. In the unlikely event that the author did not send a complete manuscript and there are missing pages, these will be noted. Also, if material had to be removed, a note will indicate the deletion. uest ProQuest 10008387 Published by ProQuest LLC (2016). Copyright of the Dissertation is held by the Author. All rights reserved. This work is protected against unauthorized copying under Title 17, United States Code Microform Edition © ProQuest LLC. ProQuest LLC. 789 East Eisenhower Parkway P.O. Box 1346 Ann Arbor, Ml 48106-1346 ACKNOWLEDGMENTS The author is grateful to Professor J. 0. Veatch for his encouragement, advice, and guidance in the course of conducting the research reported in this manuscript. For assistance in the more technical phases of the problem, he is indebted to Dr. Donald G. Sherman and Dr. Sherman Gillam, formerly of the Soil Science Department; also to Dr. John Young, ment; formerly of the Geology Depart­ and to Dr. Roy P. MatelskL. uishes to thank Dr. C. E. uni** Finally, he and other mem­ bers of the Soil Science Department for their sympathetic interest and help* 193312 THE PEDOLOGY OF SEVERAL PROFILES DEVELOPED IN THE CALCAREOUS DRIFT OF EASTERN MICHIGAN CONTENTS INTRODUCTION General • ..................... Review of literature Glaciology and physiography • • Soil profiles . . . . . Investigational techniques . . 5 8 12 . 14 PRESENTATION The profiles . . . . . . . Physical comparisons Volume weight and porosity • • Particle size distributions • • Color • • * » • * • Chemical comparisons Total chemical analyses . . . ................. Mineralogy Carbonate profiles • . . • 24 28 34 44 56 67 76 DISCUSSION Pedologic interpretations Podzolization.................... Heavy mineral reference . . • • Genesis of the St Clair solum . . Soil color . . . . . . . Conclusions and summary • . . . . REFERENCES 79 82 85 91 93 .............................. 95 APPENDICES I. Technique of physical analyses Volume weight and porosity . . . Particle size distributions . . . Color * • • • • » • • II. Technique of chemical analyses Total chemical analyses • . . . Mineralogical analyses . . . . III. Taxonomy and descriptive legend Key to the soils................... Profile descriptions • • • • 103 104 105 106 110 116 122 THE PEDOLOGY OF SEVERAL PROFILES DEVELOPED IN THE CALCAREOUS DRIFT OF EASTERN MICHIGAN During the past fifty years, a mass of information concern­ ing Michigan soils has been collected and documented, A major portion of these records has been collated, assembled, and inter published as soil survey maps and reports, and bulletins dealing with considerations of agronomy and husbandry. Most of these early studies were, in fact, initiated and accomplished primarily for the purpose of answering questions of immediate benefit to society in general and the farmer in particular. The science of soils that has evolved in the course of this work is therefore somewhat biased, being inherently pragmatic in conception. Investigations that are fundamentally necessary to the evol­ ution of a logical pedology have consequently suffered from a natural and understandable lack of emphasis. The question of whether or not expediency has been over-emphasized is not, of course, within the perception of present-day investigators. There exists, however, an appreciation of the need for additional data relating to soil genesis, morphology, and taxonomy. OBJECTIVES This investigation was initiated in an attempt to clarify several fundamental pedologic considerations that have so far escaped elaboration, particularly with respect to most Michigan soils. It is an outgrowth of five summers of intensive 6 study in Midland, Newaygo, and Sanilac counties in the southern peninsula. In these counties are encountered the so-called GrayBrown Podsolic soils, together with many related types bridging the transition to the Podzol region in the northern part of the State. As elsewhere in glaciated landscapes there are found here a great variety of profiles, thought to be the result of soil forming processes operating on and within a characteristic heter­ ogeneity of glacial materials deposited and, in places, reworked in many differ©at ways. this investigation attempts to supply some conclusions con­ cerning the nature of these calcareous till materials, especially with regard to those found in the eastern part of the State; to show what changes have evolved in these materials as a result of the work of soil forming processes; and to explain how these changes were brought about. At this point it must be explained that the study deals with changes that are evident in subsoils. By this is meant that con­ siderations of the surface or humus layer, technically designated as the Ai horizon, and the superimposed organic materials have not been included in the following discussion. There are several reasons for neglecting these surface layers which have already received the nearly undivided attention of agronomists. For one, vegetational differences of the series in question are not too extreme; all of the soils are hence presumed to have supported a 7 primarily deciduous vegetative cover. Differences exhibited by their respective solums are therefore thought not to be caused by variations in the nature of organic surface accumulations. Moreover, it is presumed that the humus (A^) layer differs from the A^ layer only in that the former contains certain quan­ tities of various infiltrated products derived primarily from the decomposition of plant residues returned to the soil surface. Although there is no particular evidence or precedent to support the assumption (nor, for that matter, to refute it), the findings and conclusions presented herewith are based on the belief that significant morphological differences in the profiles under study are to be found primarily in the A^ and B horizons. The validity of this assumption is enhanced by accepted theories concerning the part played by eluviation, and particularly, illuviation in profile genesis. A final reason for disregarding surface materials is the practical necessity for limiting the scope of a study of this nature which, to carry to an ultimate and final conclusion, re­ quires more than the efforts of a single individual. 8 REVIEW OF LITERATURE The broad scope of this study embraces a large body of lit­ erature dealing not only with investigational techniques but al­ so describing the history and nature of the specific area under consideration* As indicated by the appended maps, this area in­ cludes four townships located in the southeastern part of Sanilac County in southern Michigan. Situated on the west shore of Lake Huron about midway down the Thumb, this region is of considerable interest to the glaciologist owing to many evidences of post­ glacial lake fluctuations found here. The origin of the parent materials of the principal soils discussed herein and especially their manner of deposition have therefore been subjected to thor­ ough scrutiny. GLACIOLOGY AND PHYSIOGRAPHY Leverett and Taylor have devel­ oped in intricate detail the gla­ cial and post-glacial evolution of Michigan (58-42, 68). Briefly, the Pleistocene history (40) is a story of the succession of cli­ matic cycles and their resultant influence on land surfaces. Four times this region was over-ridden by continental ice-sheets. Local advances were in the form of a lobe which pushed generally southward down, and was more-or-less guided and confined by, the Huron valley. Minor westward pressures pushed the ice-sheet out over the confines of the Huron depression and onto the adjacent 9 highland shelf. Cold cycles marked by glacial advances were fol­ lowed by warm cycles when the ice front melted back; and during warm inter-glacial periods, generally longer in duration than gla­ cial periods, newly formed land surfaces weathered and eroded. The surface drift and present landscape, on the whole construc­ tive in character, are inherited from the fourth and final glacia­ tion. As the last ice sheet melted, the -waters so formed were imponded along the glacier front in the form of lakes which persis­ ted for long periods of time. The history of these lakes is now fairly well known, their various stages and basins having been deduced from many old beaches that are in some places conspicuous surface features. According to Leverett and Taylor (38, 39, 41, 42, 68) the western half of the area under consideration# is a lake-bed plain formed when debris accumulated as the ice melted in lakes conr 6-1 fined along the glacier front. The average elevation of this plain is some 150 feet above the present level of Lake Huron. In the southwest an area of greater elevation is marked by a slightly rolling surface which is thought to be representative of land-laid till. In the northern part of the lake-bed, a small portion of rolling, sandy moraine (the Juanita) forms a minor el- * See Map 1 in the endpocket for a diagram of surface features. 10 evation noted for its numerous boulder traces, which are thought to mark a relatively short stop of the ice-front* Elongated, crescent-shaped beaches distributed systematically across this plain indicate successive stages of Lake Whittlesey as it sub­ sided eastward into the Tyre-Ubly drainage channel, at one period a major outlet for glacial waters from the Saginaw ice-lobe. This major valley, now occupied by the Black River, bounds the lake-bed on the east* It is in turn confined on the east by the strongly-developed linear Port Huron moraine. This pronounced feature marks the limits of a distinct readvance of the continen­ tal ic9-front as distinguished from a mere halt in the course of its recession.* It commands the plain on its west by some 30 or 40 feet, rising to a maximum elevation of over 760 feet above sea level or 180 feet above the present Lake Huron* The Port Huron moraine falls eastward on an average slope of 50 feet per mile to the wave-cut bluffs that border the lake beaches. * A gently slop­ Irregularities on the east side of this moraine suggest that thj6;ice border withdrew to the northeast, slight readvances being marked by small lateral spurs diverging southeast from the main morainic ridge. A unique border drainage pattern (See Map 2) is formed by several small streams flowing south and then directly east into the present lake. XI ing plain thus formed is cut by minor border drainage valleys and by numerous streams that have trenched narrow, steep-sided chan­ nels.* These small youthful valleys grow progressively deeper to become confluent with the lake at the foot of the bluff which is nearly vertical in a few places and rises to an average height of about 50 feet above the present water line. Old beach ridges representing successive stages of lake subsidence are conspicuous features superimposed on this trenched plain; the highest and most prominent of these is Warren Beach,nearly 140 feet above lake level. The Port Huron moraine and the lake-bed plain on the east are underlaid by remnants of pre-Wisconsin drift which emerge in places near the bottom of the lake-shore bluff. Under the gla­ cial drifts are thinly-laminated blue shales of the Coldwater ♦ formation. On the west, these, shales are overlaid by Marshall sandstone formations. Basement rock strata dip westward. Drift depositions do not conform to rock surfaces but vary in thick­ ness, with no apparent relation to basement conformations, from about 20 to over 250 feet (25)• * Map 2 shows the intricate stream dissection that has accom­ panied the evolution of this trenched plain. 12 SOIL PROFILES A detailed study of the soils in this area re­ vealed most profiles similar to many already described in survey literature (61).* The four principal series on which this investigation is focused — ver, Napanee, and Brookston — the St Clair, Cono­ have been generally defined in terms of horizon characteristics and topography. So also have the incidental Isabella, Miami, and Bellefontaine that occasion­ ally serve as reference profiles. Miami, Conover, and Brookston profiles were all early recog­ nized in the calcareous drifts of Ohio and Indiana. Soon after they were defined (1, 8, 17) they were also encountered in Mich­ igan drifts, Miami initially appearing in a map of the Pontiac area published in 1904 (74). Bellefontaine was also first de­ fined in Ohio in 1912 (13), shortly thereafter being encountered in the gravelly moraines of Michigan. Napanee and Isabella were early separated from Miami (75, 70), the former because of its heavy texture and imperfect drainage, the latter because of its red hue. Finally, in 1929, the St Clair series was separated from Miami (15) because the St Clair appeared somewhat lighter in hue, displayed a less conspicuous color profile and occurred on what were thought to be water-laid rather than land-laid mor­ * A complete taxonomy is presented in Appendix III. 15 aines; In addition, the St Clair was thought to be distinguished by a relatively high shale content (5)• Recent descriptions of these seven profiles as they are now defined are contained in sur­ vey reports for the Michigan counties of Lenawee (67), Newaygo (50), and Ingham (71). Excepting the general and rather stylized descriptions to be found in the survey reports, there are very little data con­ cerning the chemical and physical composition of Michigan soil series developed in clayey tills. In 1925 McCool, Veatch and Spurway published the results of detailed observations of some sixteen selected Michigan profiles; they concluded that their laboratory findings pointed to fairly consistent physical and chemical differences for the separate horizons as they had been interpreted in the field (44). Analysis of some fourteen addi­ tional samples were subsequentally completed (72) to confirm these early conclusions. Marbut*s concepts (45) were based on data obtained chiefly from Ohio and Indiana in the Gray-Brown Podzolic region, and from Minnesota and Wisconsin in the Podzolic zone. In these states a rather large quantity of such information has accumulated. The work of Harmer in Minnesota is an early example of the emphasis placed on completed chemical and physical studies (25)• His con­ clusions concerning the essentially uniform chemical characteris­ tics of local drifts have been confirmed by subsequent investi— 14 gations (34^ 51). INVESTIGATIONAL TECHNIQUES The literature on chemical and mechanical analytical methods is so well-known that there is little necessity for a complete re­ view in this work. The chemical procedures used in this study are those summarized in the 4th edition of the Official Methods of the A.O.A.C. (63). Mechanical analyses were accomplished by means of the hydrometer method perfected by Botyoucos (5, 6, 7). Soil Color A far more complex problem is encountered in the quantitative measurement and expression of soil color. Soil scientists have been studying color problems for many years. So numerous are the difficulties, however, that improvements in color classification since the preliminary studies (55, 69) of nearly a quarter of a century ago have been imperceptible. The diffi­ culties are of two kinds. First of all, although advances have been made in nomenclature (29, 57, 60) there are no well-defined soil color standards to serve as a basis for comparisons. The use of such preliminary standards as have been developed is, more­ over, hampered by personal factors which necessarily enter into color comparisons. The personal equation can be eliminated only with difficulty because in any set of discrete color standards there are gaps of hue, brilliance and chroma which must be brid­ ged by interpolation. The complexities of this problem are indi­ 15 cated by the fact that the National Bureau of Color Standards and the Inter-Society Color Council have devised a color "solid* giv­ ing the three dimensional relationships of hue, brilliance and chroma, and have in this manner quantitatively named and defined 312 colors. Although this number is considered sufficient for naming colors from memory, it is estimated that an average per— son can distinguish over 10 million color surfaces (33, 57, 52). Second, the field investigator is hampered by seasonal changes within the solum, by color vagaries dependent upon tex­ ture and structure and the accompanying attributes of shadow and dispersion; and finally by the very nature of soil colors which are seldom evenly distributed but more often occur as mixtures, as for example, a matrix color modified by minute mottlings of hue, chroma, and brilliance. A lack of a definitive terminology together with the complexities of the surface to be described has naturally resulted in a confusion of descriptive terms. The problem is fundamentally physiological in nature since it depends on the perception of stimuli; any two observers cannot, therefore, expect to perceive a given set of stimuli in the same manner, let alone describe them. A psychological factor has also arisen in recent years to abet an already confused issue; this is the ever-increasing use of color in our social environment, a natural result of advances in creative chemistry and color reproduction processes, so that 16 in printed matter, for example, the encounter of all variations in hue, brilliance, and chroma have become matters of everyday experience* An appreciation of color standards has not, however, kept pace with the use of color* Indeed, the demands of our com­ petitive social system, as exemplified in the rise of the adver­ tising arts, has resulted in the development of hundreds of new color names which eventually conflict with the more conservative, little-known standard names* It is thus not uncommon to encoun­ ter in field notes the use of such terms as beige, buff, tan and similar words that have migrated from the retail fabric jargon* There are two general approaches to the problem of colorime­ try* In one, the stimulus of the color is investigated and the color is defined on the basis of wave-length intensities or fre­ quencies. In the second, surfaces are matched with secondary standards and described in terms of the color of these standards. A more valid approach to the problem at hand was considered to be afforded by the latter, which was selected because it deals with what is seen. In order to appreciate the ramifications of colorimetry it is necessary to understand that any given color is described in terms of three attributes — hue, brilliance, and chroma. Hue is the attribute which permits color to be classified as red, yel­ low, blue, green, and so forth. Brilliance defines the lightness or darkness of any color, and chroma describes its intensity (that 17 is, its weakness or strongness)* Each of these attributes is, in turn, defined by scales of psychologically graded steps which may be treated quantitatively* Using these attributes, all conceiv­ able colors are arranged in a three-dimensional system, each sep­ arated and fixed by the three ordinal values of hue, brilliance, and chroma* Important features of this concept are that five hues (red, yellow, green, blue, and purple) complete a basic cir­ cle concentric about the axis of brilliance, the latter black at one extreme and whits at the other* Chroma is the distance from the axis outward in the hue plane (53, 57). A comparative method having been selected, the next task was to devise or adapt a satisfactory technique of matching soil samples with standard colors. Already proved was the Maxwell— Munsell technique which utilizes spinning disks of standardized and calibrated colors in juxtaposition to prepared samples. Disks with radial slits, allowing several to slip together with a portion of each showing, are used* These afford a practical method of varying combinations of several color ingredients* Su­ perimposed on a calibrated base, the exposed portions of the standard disks are interpreted in terms of percentages, thus al­ lowing ready conversion to a numerical system of expression (52) . Preliminary studies have disclosed that four colors — red 4/9 (red hue, 4 in brilliance and 9 in chroma) yellow 8/8, black 1/0, and white 9/0 encompass the range of colors displayed by most 18 soil samples (57). Mineralogy Less ephemeral than the color problem (but just as complicated) are the mineralogical techniques. In this field* however, many analytical procedures have already been perfected by sedimentary geologists whose methods were readily adapted to the investigation at hand. A convenient starting point is the classification of sedimentary minerals into two groups on the basis of their specific gravities (£). The value 2.85 is gen­ erally arbitrarily accepted as dividing point between so-called light and heavy minerals. The light fraction, which includes quartz, calcite, feldspar, the clay minerals and micas, usually comprises about 98$ of a sediment. The heavy fraction, which constitutes less than 2$ of most samples, includes a much greater variety of mineral species and is therefore considered more use­ ful in describing the characteristics of a sediment or soil mate­ rial (27). Much effort has been expended in an attempt to arrange soil minerals in order of their resistance to weathering. Zircon, tourmaline, quartz, rutile and apatite are usually considered relatively stable (56, 66, 51, 27, 48), although there is some evidence that even zircon (21), and certainly garnet (27) and apatite (51), are relatively soluble under certain conditions. A number of mineralogical investigations have been made of 19 the heavy assemblages of glacial till (£2, 35), most of the stud­ ies, however, being directed towards the separation, of the various drifts of the Pleistocene period and a comparison of sediments of different geologic ages (36). A notable conclusion from Kruger's work (34) is that few mineral species are diagnostic of any one drift sheet. In other words, the same association of heavy min­ erals tends to dominate all Pleistocene drifts. Kruger concluded that a fairly certain identification of a particular drift can be obtained from a knowledge of its carbonate content and heavy min­ eral assemblage. Heavy mineral studies of the soil solum, as distinguished from parent material studies, are not numerous* In Australia, residual surface soils were found to be related to parent rocks (10) • Studies of glacial soils in England and Scotland have con­ firmed the Australian conclusions; it was also deduced that local differences in the silicate content of surface horizons were a re­ flection of variations in the local parent rocks from which a ma­ jority of the tills were known to be derived (£6, 28) • In the United States, McCaughey and Fry (43) were early petrographers who confined their efforts to pedology. Studying sand and silt fractions of many samples from every part of the country, they discovered that epidote and hornblende are common in most soils. They concluded that any common rock mineral will be found in soil, a conclusion that suggests the possibility of 20 nearly all surface soils being contaminated by windblown materials. Jeffries and White were among the first in this country to delve into the mineralogy of soil profiles (50, 51) • Their work revealed that in the eastern states soils developed from lime­ stones, dolomites, and shales were all similar in their quali­ tative mineral content. They concluded that heavy mineral spe­ cies vary more in proportion and total quantities than in number, and that a good comparison of different soils might be obtained by determining the relative percentages of only outstandingly com­ mon heavy minerals* Cady compared heavy minerals from A and C horizons of several podzol and brown podzolic forest soils to show that podzolization significantly reduces the amount of horn­ blende in solum horizons. Epidote, garnet, and magnetite appear to be little affected. Mickelson (51) investigated the heavy mineral assemblages of three soils of the Miami catena. His results indicate that weathering processes contributing to the formation of Brookston and Miami profiles in Central Ohio are probably not similar. The most conspicuous difference in the heavy mineral assemblage of these soils was in the presence of considerable apatite in all horizons of the Brookston profile; in the Miami, on the contrary, apatite was found only in relatively unweathered material. He also discusses the genesis and morphology of Miami, Bethel, and Brookston profiles as indicated by changes in their heavy mineral 21 species in the v&rious profile horizons. A significant trend is noted in this work, which shows the influence of Marshall and oth­ er modernists: Mickelson treats his data on a volume rather than a weight basis to reveal fallacies that were unapparent in pre­ vious comparisons. His conclusions depart in some measure from accepted concepts of soil genesis, especially in de-emphasizing the role of illuviation in the evolution of the still rather youthful profiles developing in glaciated regions. The loessial soils of the mid-western states have received considerable attention in late years (2, 27). Pertinent find­ ings are that color in loess is due to the type and quantity of clay minerals present (54), and that visual differences in loess and loessial soils are more closely associated with variations in carbonate content than with variations in texture (64). Heavy mineral studies of Michigan soils have so far been limited to sandy materials. Johnsgard (32) discovered that a sandy ground-water podzol showed a marked depletion of hornblende, augite, and actinolite minerals, as well as feldspars, throughout the solum; a half-bog profile, however, did not reflect this type of weathering. After studying seven widely separated sandy podzol profiles, Matelski (48) found no significant differences in heavy mineral assemblages over a wide area. A significant variation was discovered, however, in the relative quantities of heavy spe­ cies present in fine sand fractions. In other words heavy mineral 22 particle-size distributions were proved to be strikingly dissimi­ lar; characteristics of these distributions differed moreover, from horizon to horizon. Most resistant were garnets and opaque species; least resistant was hornblende. In these sandy profiles the B horizon organic material appeared to be an effective weather­ ing agent with respect to hornblende. B horizons were therefore found to contain smaller quantities of unweathered heavy minerals than either the A or the C horizons. The application of petrographic methods to soil studies has been summarized by Fry (19). Techniques of sampling and count­ ing have been perfected by others (47, 11, 20, 65, 46). A study of these investigations leads to the conclusion that the most practical approach is to study heavy minerals of a single size fraction (16, 24, 59) after treating with suitable reagents to insure that all interfering coatings have been removed (11, 46, 48) • Probable errors involved in accomplishing the necessary microscopic counts have been analyzed by Dryden (18) and Eittenhouse (58) who furnish useful curves to show how many grains must be counted to yield a desired degree of accuracy. This brief review of literature has disclosed an array of methods and techniques employed by numerous investigators in the past 25 years. The summarized studies have been directed towards a variety of objectives, and have dealt with different kinds of materials subjected to many kinds of weathering. With 25 regard to pedology, the information so far obtained is only frag­ mentary, although it does shed considerable light on many aspects of soil genesis, morphology, and taxonomy. In Michigan where but a few sandy profiles have been examined, pedology is not too far advanced. This study represents an application of the methods and techniques previously discussed to several fine-textured Mich­ igan profiles in the hope that information so revealed will con­ tribute to such knowledge as already exists. The selected pro­ files are of interest because they (or very similar profiles) are widely distributed in the Southern Peninsula, because they are typical of the productive and fertile soils of the State, and be­ cause they are thought to comprise the most mature drainage catena developed under the prevailing climate* The results of this study are presented in the following pages. The St Clair, Napanee, Conover, and Brookston soils on which the study is focused, are defined by brief descriptions together with such comments as are necessary to a proper under­ standing of the relationships between these four series, the accidents of position and drainage under which they have devel­ oped, and such field observations as appeared to require the separation of these closely related taxonomic units. There are also presented certain results obtained from an application of the afore-mentioned techniques and an analysis of such pertin­ ent data as have been procured. Information concerning phys- 24 ical, chemical, and mineralogical characteristics of the four selected profiles and occasional reference profiles is discussed under separate headings, And finally, the findings of these convergent lines of investigation are brought together to con­ clude the work. To facilitate the presentation, descriptions of methods and techniques have been segregated in Appendices I and II, An outline of the taxonomy of the area is presented in Appendix III, THE PROFILES There is no need to repeat here the detailed descriptions of the St Clair, Napanee, Conover, and Brookston series, and of the SO other closely related profiles that are found in the area under study, A brief review of their chief similarities and differences is, however, necessary to appreciate their inter­ relationships, Maps 1 and 3 show that the St Clair series is confined al­ most entirely to the elevated portions of the rolling uplands that comprise the Port Huron Moraine, Intimately associated with this automorphic* series are small areas of Conover and * The adjective automorphic is here used as an antonym of the 25 Brookston developed in successively lower drainage positions. The hydromorphic Brookston, hydroperiodic Conover, and auto­ morphic St Clair are all members of a single drainage catena. adjective hydromorphic» An automorphic profile is distinguished by characteristics that reflect the balanced influence of soil forming forces as opposed to the predominance of a single factor (for example, water-logged conditions which produce hydromorphic profiles)• But automorphic carries more specific implications than the term zonal for which it is sometimes loosely substituted. An automorphic profile may be a zonal profile. Its parent mater­ ial, however, must have been uniform when first exposed to soil forming agencies, and it must have been characterized by a wide range of particle sizes and a varied mineralogic content so that, once exposed, the maximum effect of soil forming forces becomes apparent. An automorphic profile thus must have contained with­ in itself the potentialities of forming widely differentiated horizons after exposure to the balanced influence of soil for­ mation factors. In this sense of the term, Coloma is not an automorphic profile even though it might be considered a zonal representative of a sand catena. Hydroperiodic describes a pro­ file that is neither automorphic nor hydromorphic, but has rather resulted from the dominant influence of a fluctuating water-table which gives rise to alternating aerobic (oxidizing) and anaerobic (reducing conditions). 26 In other words, these three soils are thought to have developed in similar parent materials under the influence of different de­ grees of drainage, different degrees of weathering, and possibly different kinds of weathering. The Conover profile attains its maximum development on the trenched lake plain east of the moraine where it is associated not so intimately with St Clair as with soils developed in sandy nonconforming materials sorted by water and in some places by wind. Brookston and Napanee are encountered on the lake-bed plain west of the Black River Valley where elaborate ditch sy­ stems have recently drained the land. There is little doubt that the Brookston profile reached its maturity in situations which, within the memory of the present inhabitants, were satu­ rated for a major portion of the year. The Napanee series, al­ though intimately associated with Brookston, developed where these lake-bed materials were elevated above the general level of the plain so that both surface and presumably subsoil layers were relatively dry. According to early settlers, all of this land supported a dense deciduous cover although there was some differentiation as to species. Beech and sugar maple with local admixtures of basswood, white oak, and pine dominated the vegetation on the St Clair soils. Brookston was characterized by elm, ash, silver 27 maple, hickory, and swamp white oak. Conover and Napanee supported a mixture of these two cover types. To the field observer there are no readily apparent lithologic differences between these four series. Fragments of shale, limestone, sandstone and a great variety of crystalline rocks ap­ pear as dominant and as variable in one parent material as in an­ other. Crystalline rather than sedimentary materials are predomi- ant among the erratic cobbles and boulders, all of which are wellrounded and polished, exhibiting evidences of much grinding and wear. Polished surfaces on many of these erratics are surprisingly well-preserved, indicating that certain of the harder minerals have been little affected by weathering forces. Small rock fragments less than 5 mm in size are dominated by soft consolidated sediments. Brown, slightly weathered shale, possibly of local origin, is very common while limestone fragments constitute between 7 and 15$ of the total bulk of these fragments. Formerly consolidated sediments are probably the source of a large proportion of the finer particles in all parent materials. In summary, the St Clair, Conover, and Brookston series to­ gether form a drainage catena. Despite essentially similar parent material characteristics, field observations indicate sufficient solum dissimilarities to justify the differentiation of these three profiles. Napanee is an anomaly in this scheme because St 28 Clair or Conover might normally be expected to develop where Napanee has been mapped* Although Napanee exhibits sane charac­ teristics of a hydroperiodic type, expecially in the mottled sub­ soil colors, and also of the automorphic type in that it has a conspicuous B horizon, it is not considered a zonal profile. In recognition of its heavy-textured B horizon, Napanee is perhaps best categorized as a planosol* Rather than the differences, it was perhaps the many similar­ ities noted to exist between these profiles that prompted a further, more detailed examination of their parent materials and solum. The remainder of this discussion is devoted to results obtained from several convergent methods of analysis and comparison. PHYSICAL COMPARISONS Characteristics often employed to describe soil and soil materials are those of mass and size. In order to determine the uniformity or lack of uniformity exhibited by the profiles in question, the volume weights, specific gravities, and particle size distributions of the Ag, B, and C horizons in each profile were measured. In addition colors were compared in an effort to reveal inter-relationships both in the proposed taxonomy and in their morphological characteristics. Details of sampling and laboratory techniques are recorded in Appendix I. 29 VOLUME WEIGHT AND POROSITY In this work volume weights are highly important because they are used for converting weight percentages into volume relationships, final conclusions being based where possible on comparisons of quantities per lOOcc of the original sample. The values listed in Table 1 are therefore of considerable interest since they con­ stitute the basis for deductions presented in later sections. Table 1 reveals that local variations in parent material densities are slight. On the other hand great differences in volume weight and specific gravity appear to have resulted from weathering. With the exception of the Brookston profile, volume weight differences between any two soils are less than differences between any two horizons of a single profile. Judging only from density changes, the Brookston series is the least weathered of the four. Changes in the other three are of a strikingly similar magnitude. An explanation of these roughly equal changes is most likely found in the fact that weathering has resulted chiefly in >a loss of carbonates, a point that will later be amplified. Tables 6 and 7 show that the carbonate content of the three par­ ent materials was about the same; it was not great enough, how­ ever, to constitute a continuous system within the matrix. Upon its removal, therefore, the structure did not collapse but merely developed a higher degree of porosity as the carbonate particles disappeared. Since the carbonate contents were similar, the 20 Table 1. Volume weight, specific gravity, and porosity of the selected profiles. Profile St Clair j Comover Drainage position Automorphic Napanee Brookston Hydromorphie Parent material (C) Volume weight* Specific gravity* Porosity*- 1.76 2*67 34.1 1.69 2.67 Eltrviated zone (A2) Volume weight* Specific gravity* Porosity-*- 1.71 1.73 2.66 2.66 36.6 35.6 34.9 1.37 2.65 48.3 1.39 2.65 47.5 1.33 2.65 49.8 2.66 1.55 2.70 1.56 1.59 2.69 40.9 1.48 2.67 44.6 1.41 46.9 niuviated zone (B) Volume weigit* Specific gravity* Porosity*- 42*6 2.69 42.0 * Average of duplicate samples, each measured twice. * Average of duplicate measurements on a single sample. + In per cent by volume, calculated from the values above. increases in porosity in the various solums were similar. In this respect Napanee appears more closely related to the auto— raorphic St Clair than to the hydromorphie Brookston, a relation­ ship that will be seen to prevail in other characteristics. These data illustrate another point of interest in that porosity is seen to decrease with depth, reaching a minimum in the parent material. If the illuviated zone truly represents a 51 zone of accumulated materials translocated downward from the leached layers above, there must have occurred some expansion in volume within the B horizon proper* In other words, since there has been no increase in density of the illuviated zone, but rather a decrease in density with respect to the parent material, then the weathering of this particular layer must have resulted in com­ plementary increases over that volume originally occupied by the unweathered materials. This aspect of illuviation has seldom been mentioned by soil morphologists, perhaps because it is a dis­ crepancy that cannot be fully explained by present theories con­ cerning podzolization in till materials. There is a possibility, of course, that some expansion has occurred within the B layer al­ though its structural characteristics lead to the deduction that contraction, rather than expansion, has been dominant* This conclusion is even more apparent when it is understood that only stable structural units are represented by the volume weight and porosity values, that major interstices resulting from shrinkage of the structural units and other spaces such as worm holes and large root channels were excluded by careful sample selection. It is thus apparent that the low values character­ izing any Ag horizon actually represent degradation caused by a loss of material from within the structural unit proper. Apply­ ing this assumption to the respective B horizons reveals that they, too, must have been subjected either to leaching or to a 32 volume increase of considerable magnitude. Of these two alterna­ tives the former appears most probable. A final deduction is of interest. It concerns the develop­ ment of the laminated structure so characteristic of eluviated materials in the Gray-Brown Podzolic soils, -and which is particu­ larly conspicuous in the St Clair solum. Consider first a theo­ retical minimum volume weight that may be attained by soil mater­ ials. If all particles are spherical in shape, equal in size, and loosely packed, their minimum volume weight value is 1.38# with a corresponding porosity of 47.7$ Volume weights of the horizons in question closely approximate this theoretical value. This close agreement indicates that these eluviated materials are approaching or have reached their minimum volume weights; if more material is lost through decay and leaching, the layer must con­ sequently contract. Minimum values for these eluviated materials were probably reached at an early stage of weathering so that con­ siderable contraction is thought to have already taken place as will later be shown. In response to gravitational forces, vertical contraction has predominated over horizontal. This action has shortened the inherited vertical interstices which were then fur­ ther obliterated by sloughing and filling. Horizontal joints and * M n m . wfliffht = Weight of unit diameter sphere, specific gravity 2.6S s Weight of unit cube with a specific gravity of 1.00 35 Table 2. Mechanical analysis of the selected and reference profiles, la per cent of oven-dry sample Heights. Fine •Coarse. Fine .Coarse. . Fine .Medium.Coarse Fine ■ clay day silt silt fine sand sand sand gravel sand j ST CLAIR 3d 31.1 19.7 &2 1B C 9.0 8.3 10.4 13«4 10.8 11.5 39.8 23.8 26.2 16.5 10.1 8*4 7.1 8.2 11.4 3.1 3.3 5.6 1.0 2d 4*4 0.5 1.4 1.7 11.6 7.2 8.4 7.3 2.9 2.8 4.2 2.2 2d 2.2 2.4 2.0 24.5 2.9 6.3 7.3 6.1 4.2 5.1 0.5 2.1 4.3 0.0 1.1 8.7 4*4 4.2 3.9 3.9 4.0 2.5 2*4 2.3 1.5 2.5 1.1 5.1 5.3 6.6 2.9 3.0 3.7 1.0 1.9 2.1 0.9 1.1 1.3 6.3 7.7 10.7 1.9 1.1 5.9 1.3 1.9 2.8 1.1 0.7 0.5 41.8 19.3 28.9 31.8 35.1 34.0 7.3 9.3 8*4 3.3 6.2 6.1 CONOVER ^2 1.5 B 26.1 C 14*4 6.3 14*1 16.5 13.9 13.2 12.3 33.5 22.5 26.1 ^2 0.0 B2 23.1 c: *11.2 8.3 9.1 15.8 10.2 18.3 17.5 13.0 5.9 30.3 ^2 4.7 B 23.3 i c 12J. 13.2 9.8 13.1 22.2 31.4 34.7 31.1 15.9 22.4 17.7 8.9 13.6 NAPANEE 21.3 6.1 11.1 BROOKSTON ---- 10.3 5.7 5.6 MTAMT 16.6 ; b !33.3 ; c 27.1 14.0 11.2 9.8 21.2 14.1 19.8 31.9 18.5 21.5 Ag 14a B 44.5 i c 25.3 : | it* 0.0 B ; 4.1 0.0 C 12.4 13.3 U.8 14.3 9.4 12.5 38.4 12.8 19.8 1.8 5.6 3.9 1.2 5.4 4.9 6.9 6.3 7.1 ISABELLA 'I ] 9.9 6.7 10.0 ■ BELLEFONTAINE Fine d a y Coarse d a y Fine silt Coarse silt 6.6 7.7 5.4 4.7 7.0 8.0 0.001mm and less Fine sand 0.001 to 0.OQ2mn Medium sand 0.002 to 0.02mm Coarse sand 0.01 to 0.05ma Fine gravel Very fine sand 0.05 to 0.10mm 0«10 0.25 0.50 1.00 to 0.25mm to 0.50mm to 1.00mm to 2.00mm ! 34 cracks were not, however, as greatly affected and have tended to persist within the mass. These inherited characteristics are mod­ ified by the development of additional horizontally oriented inter­ stices caused by an imcomplete collapse of structural units* The resulting predominance of horizontal over vertical interstices is thus a possible explanation of the laminated structure of highly eluviated materials. PARTICLE SIZE DISTRIBUTIONS In order to extract the very fine sand fractions for mineralogieal studies, representative samples were subjected to complete mechanical analyses with the results shown in Table 2. These data reveal that the profiles in question developed in materials of strikingly similar particle size dis­ tributions. Although silt dominates the St Clair profile to &.< lesser degree than the other three, all are either clay loams, or very nearly clay loams, in texture. Compared with the reference profiles, St Clair appears to resemble Isabella rather than Miami as far as their particle size attributes are concerned. All profiles exhibit definite textural horizons. Eluviated zones (AJ are relatively low in fine separates, particularly fine clay. At the other extreme are the so-called illuviated zones which are all relatively high in fine clay. The parent materials are intermediate in texture, a relationship that has been pointed out by many previous investigators. These and similar figures on 35 many other soils have appeared to justify the assumption that the fine clays have been produced and dispersed as a result of soil forming processes, and that they were then transported downward to precipitate or flocculate in a zone of accumulation. The re­ ference Beliefontaine profile is thought to reflect a fairly re­ presentative picture of the actual intensity of illuviation in this region. Here no fine clays were found in the parent material. The B horizon accumulation therefore indicates the magnitude of net changes arising from clay formation and illuviation under favorable conditions of pore size distribution and drainage. A peculiarity of this kind of data, expressed in terms of oven-dry sample weight percentages, is that it exaggerates tex­ tural differences between horizons because the value of one con­ stituent cannot decrease without a complementary increase in the value of another. This mode of expression has therefore done much to foster fallacious conclusions. An example is readily apparent in Table 2 where it may be noted, by comparing fine clay percentages, that losses from Ag horizons are equalled, and in some profiles ex­ ceeded, by apparent “gains11 in B horizons (with respect to parent materials). Comparisons of this kind have, in the past, undoubt­ edly encouraged the acceptance of translocation as a major soil formation factor and have tended to overemphasize the role it plays in illuviation* 56 Jl more valid comparison of data of this nature is thought to be obtained by expressing textural characteristics on a volume basis* Calculations can then be manipulated with respect to a more constant reference so that a clearer picture emerges. A summary of these mechanical analyses calculated to a volume basis is presented in Table 5 which integrates the volume weight values of Table 1 and the carbonate contents of the various horizons. (See Table 6.) Here it is revealed that the chief effect of soil forming processes has been the loss of carbonates from the upper horizons. Judging from the values listed in Column 4 of Table 5 soil formation has brought about only relatively small changes in mass per unit volume of materials other than carbonates. Assuming, for example, that the St Clair Ag layer developed from an equal volume of parent material similar to the present C horizon, the total loss of minerals other than carbonates is about 15 grams. Con­ currently the B horizon has lost some 4 grams of carbonate-free materials, despite the fact that a considerable quantity of car­ bonates still remains. On the other extreme, the Brookston profile exhibits a wgainu in the Ag horizon of materials other than car­ bonates. This ^gain" probably resulted from changes in structure other than mere degradation. Compaction, for example, may have resulted in an increase in density of the original surface layer. Another explanation is the afore-mentioned vertical shrinkage ac- 37 Table 3* Particle size distributions of the selected profiles, expressed in grans of carbonate-free separates per lOOce of sample volume. LHorizon. Volume weight* 2 j 1 ^2 B C 0Carbonate-free material X.CO3 . Total+. Clay . Silt . Sand 3 137 155 176 0*0 8.5 25.5 139 156 169 0.0 11.2 31.3 4 5 6 7 74.0 48.6 44.7 38.6 36.8 51.8 11.6 57.6 52.4 65.8 51.1 45.5 61.2 36.8 40.1 37.5 72.9 56.3 84.1 25.5 34.2 75.2 62.3 64.4 40.0 26.1 25.5 ST c u m 137 24.4 146 60.5 150 53.5 Gmomt 1 ^2 B C 139 145 138 B* c 133 159 171 0.0 3.3 34.2 NAPANEE 31.0 133 156 58.2 137 46.5 A2 B C 141 14-8 173 0.0 16.6 39*8 BROOKSTON 25.2 141 43.6 132 333 43.4 * Grams per lOOce calculated from the values in Table 1. * These values mill be found not to agree with similar values calculated from Table 2 because the particle size distribution of the carbonates does not resemble that of the sample as a whole. * Difference between the columns to the left, and sum of the columns to the right, in grams per lOOce. 58 companying, and resulting from, carbonate loss. Conover and Napanee exhibit "gains*1 in their respective B horizons. This is particularly true of the Napanee series which is noted in the field for its dense compact "illuviated" zone. These figures suggest that true illuviation may have been more dominant in Napanee than in the other three profiles. There is a possibility, however, that this enrichment was not transported as clay but that fine material has formed in place, a theory that will later be amplified. Whether or not the foregoing deductions are well-founded depend upon the validity of the basic premise which has already been stated that unit volumes of parent material have produced unit volumes of solum. Later evidence will indicate that this premise is perhaps fallacious and that deductions based on an assumption that volumes have remained unchanged are of little more value than conclusions based on weight percentages. Concerning changes in particle size classes within horizons, a point of initial importance are the small quantities of sand contained in the St Clair Ag layer. It appears that sand grains near the surface of this exposed soil have disintegrated as a result of soil forming processes. Disintegration of coarse particles is also evident in the B horizon although to a lesser extent than in the more exposed surface layers. Complementing 59 sand particle disintegration is an increase in the quantity of silt which is apparently an ultimate particle size in this material. It is logical to assume that the original silt may also have disinte­ grated to produce some clay even though the total amount in the Ag horizon is less than in the parent material, due presumably to weathering of the inherited clay particles. Although the Ag hori­ zon shows a net difference of about 30 grams of clay per lOOcc when compared with the C, the B horizon has only "gained11 7 grams of clay. This figure is- not insignificant but it is much smaller than has commonly been supposed from a comparison of weight values. This same relationship is shown in the clay content of the different horizons in the Conover, Napanee, and Brookston profiles. "Losses" of clay from the Ag horizons of the three relatively ex­ posed profiles are of about the same magnitude. The "gain® ex­ hibited by the B over the C horizon in Napanee, however, is twice that in the St Clair and Conover. On the opposite extreme, the Brookston profile shows a relatively small but significant "loss" of clay from the Ag horizon with no complementary gain in the B. It is therefore concluded that the heavy texture of the Brook­ ston B horizon is due only to an apparent gain of fine materials resulting from an actual loss of carbonates. This decrease in bases may also be reflected in structural changes within the B horizon which has retained its clay as compared to the Ag horizon which is depleted in clay. Dispersion is hence not physically 40 apparent in these surface layers, except as it may have contri­ buted to translocation of fine particles* A contrast of some magnitude is discovered between the automorphic profile and those which have developed in lower drainage positions when the quantities of coarse separates in their various horizons are compared. It is apparent that the St Clair solum contains less sand per unit volume than does its parent material whereas the solums of the other three contain more sand than their respective parent materials. These differences are certainly of a significant magnitude and cannot be rationalized by "weathering" hypotheses. Some other explanation must be sought. The topo­ graphic position in which these poorly-drained profiles have de­ veloped, and the post-glacial history of the land surface on which they are encountered, suggest a theory that may offer at least a partial explanation for these observed textural contrasts. The basis for this theory is found in the hypothesis of modern glaciologists who have postulated that the parent material in which the Napanee profile, for example, has developed was deposited under water and that the till plain was a lake bottom for a considerable period of time. There is little evidence to show how deep these lakes were for the major portion of their existance, but it is within the realm of possibility that their basins were subjected to wave-action during certain stages in the lake subsidence. The thesis is advanced that this wave-action accomplished con- 41 siderable sorting of surface materials before they finally became exposed to weathering forces, as the term is conventionally under­ stood, Napanee is not the only series affected by this action. Iosco, Berrien, Allendale, Arenac and several other related series are examples of an extreme degree of wave sorting, which removed nearly all clay from surface layers* Map 5 shows an intricate association of Napanee and Brookston in a lake-laid till. On this particular plain Napanee is confined to the higher and drier parts where surfaces might logically be expected to suffer a maximum amount of wave reworking. Brookston occurs in depressions which presumably may have served as settling basins during certain stages in the history of the land surface. It is thought that wave-working may have accomplished two things. First of all, on relatively high surfaces now occupied by Napanee, wave agitation was effective in removing a consid­ erable portion of the original silt and clay. These fine mater­ ials were removed laterally, however, which accounts for the apparent increase in sand in the A^ horizon of this soil. Under­ lying materials, later to become the B horizon, remained unaffected and unchanged. A second result is thought to have been a sorting of these concentrated surface sands according to their specific gravities. When the till plain was finally exposed to post­ glacial climates, the Napanee areas were hence already character­ 42 ized by a textural profile. Moreover, in the lower depths of the sandy surface horizon was a relative concentration of heavy minerals, some of which later decomposed in place to produce the relatively fine-textured B horizon that is characteristic of the present solum. The high clay content in the B layer of Napanee does not, therefore, necessarily represent a greater degree of translocation of fine materials than has occurred in the St Clair series which supposedly represents the most weathered and most mature profile in the region. This theory applied to the genesis of such an anomolous profile as Napanee appears to reconcile its topographic situation with the extreme differences of texture exhibited within its solum. The theory possesses an added advantage in that it minimizes the role of percolating water which moves very slowly in the small capil­ lary spaces of these heavy materials. This thesis a,ppears equally valid when applied to Conover and Brookston. As may be seen from a study of the maps, Conover occupies a topographic position somewhat intermediate between St Clair and Napanee. Like the latter, it occurs on a lake-bed plain that might also have been subjected to wave action. This plain is not flat and level, however, but slopes regularly to the east. It is thought that, as the lake subsided, successive areas were subjected to a maximum of wave activity. Because of its sloping nature, the plain as a whole was not wave-washed in its entirety for a long period of time as compared to the Napanee 43 areas* Thus, although there was a moderate sorting of materials and some concentration of sand in the surface layers, the action was not intensive* Moreover, as the Conover materials slowly emerged, they were concurrently trenehed~and hence better drained so that the final profile is more closely allied to St Clair than to Napanee. As applied to the Brookston areas, some sorting of materials may be attributed to wave-action, but the evidence is not as marked as in the higher parts of the plain. More important was the lateral movement of fine materials from adjacent elevations. The admixture of these fine particles which settled in the de­ pressions modified the inherited texture so that differences in the Brookston solum are not so conspicuous as in the higher areas. The increase in density of the Brookston Ag horizon over the C may be caused by this addition of fine ms.terialsj it is, therefore, not degraded in the same sense as similar layers in the other three profiles. In summary, mechanical analyses of the St Clair, Napanee, Conover, and Brookston profiles indicate they have developed parent materials showing more similarities than dissimilarities. Clay dominates their parent materials. Disintegration has been a major process within their solums, while decomposition and physical sorting are evident in the low proportion of fine particles in their surface layers. Variations in parent materials and textural differences within two other analogous profiles in the Gray-Brown Podzolic region are indicated by the Miami and Isabella series. Beliefontaine is presented as an example of an extreme textural class of materials and to show the probable extent of clay for­ mation and illuviation in this climatic zone. COLOR St Clair, the automorphic profile developed in the light brown drift which constitutes a major portion of the elevated land forms, is very similar to the Miami series from which it was early separated. One of the first taxonomic questions to arise concerned the classification of this light brown drift, which at first seemed sufficiently -different to justify its separation from the darker brown and reddish-brown drift found elsewhere in the Gray-Brown Podzolic area of the Southern Peninsula* On the other hand, separation of these drifts solely on the basis of color differences seemed of doubtful value, particularly in view of the ephemeral nature of color attri butes. Field observations of the several drifts have shown, for example, that conspicuous color differences seem to exist under natural conditions; yet when samples are placed side by side these contrasts, rather than intensifying as might logically be expected, apparently disappear. Differences between comparable samples seem so slight as to preclude any justification for es­ tablishing separate catenas on the basis of color alone. It there 45 fore appeared expedient to investigate this question by means of such quantitative techniques as were at hand. A notable lack of previous information of this character enhanced the desirability of applying colorimetric standards to the comparison of existing Michigan soil categories. Hence* an attempt was initiated to de­ termine whether or not valid color differences exist, and, if so, whether or not these differences can be expressed in mathematical terms. Exhaustive comparisons (employing the techniques described in Appendix I) resulted in the accumulation of data presented in Table 4, wherein each item is an average of eight separate measure' ments obtained from duplicate determinations on four samples. These data are presented to illustrate typical values obtained by applying the Maxwell-Munsell system to soil colors developed in a fairly restricted geographical area. The samples were se­ lected with the thought that such quantitative data would reveal natural laws concerning the development of soil colors. It was also thought that evidence might be obtained to clarify the pre­ sent vague identity and status of the tentative St Clair and Napanee series. Inspection of the values listed in Table 4 shows that the so-called Gray—Brown Podzolic colors, as well as the associated grays and olive grays of the hydroperiodic and hydromorphie 6 Eh O O pej pq o d H >» Pi Q 03 i (0 o u m Ok P CO (O CM CM CM CM CD <4* CM O h o a ts g O o Oj g a faO I cm a? CD CD is to to o> a> to CO CD m n rl M rl in to to P co H co O in I I I I i i i i • I I I i i i i M w ci w to rl in o> o CM CO CM i i i i ■P U t/3 P in rl in cm in cm o •3 /?! ■ i i i o p I C p d p p d ® Pi -n id d d O Pt ® U Pt S P I o cd £ & 3 4 -H & g © 33 o « 3 H 9 & f=t P-3 eq is in r l in in cm o rl co n CM >» Ml p o U> 2 tr « S3 o a £ +* i i i O to CM H CM tO CM rH O cm cm O in O tO to in cm Ok H O N CO M CO H Ok Ok rH rH O in CM p Ok in o rl n rl 8 in o C" Ok Ml « h O' in O rl •M* in cm to CO r l CO CO Ok P M M l rl g 0 u % CM Ml Ok o Mi CM to Is CM tO •? ■s P l>» u p to rH > tO rH rl Ml tO O CO CM CO tO Pi •d a a) CQ CM rH rH Ml tO CM rl N CD rl Ok M* CM tO E- cm in 0 p n 1 Ha •d T3 Ok CO P H H tO CM rH P O CM CM in CO fH £> o eq o 00 a> * a> •d o z> to s CM CM s to CM CO C- CO H CM in rl Ok Ml O O H to Ok CM CM Ml p Mi CO do® ° Vi a a) •d Ph Pi ® O 49 « K on® &§ a ® •p Pi O p O £ 0 >d ® Ph s; O r—1 O d P ® t—1 >1 « rH ,® lxi ® «% > ® n 1 rH 0 rH d a> P Jsl m quauocfm oo q u au o d m o o U o rH O O •d rH ^ & o 3O«J +3<0 P 13 rH ® ® K t* d P P «d W r? q u o u o d rao o Fh o rH o O ^3 O P t) p «o .M o cd ffl P rH pq ® qusuodmoo Ph T /IH a iV F I 3N0Z iMHHVd aaiviAma XTJ1BW a tio z j:aA?x iwojg a a L T IA Q T II 01 ® n o .d m p ^ +i Vh ® o ® P • n d « cjd • dP d w d d d p ® o P »d P p Pi Pi o Pt .p o ® 4> a d P +> d 3 p O d a M Pi O a ^ d . CO H O H CM tO '3 o Pi O r—1 O a o > H t ® d 3 pi ® to Ok rH CM CM tO P 11 a> >* o fH rO ffl Pi ro x i c p m e> § d Pi pq P p Ok CM O CM Ml S o d S o o o o n d ® d P o o ® o p s p A O P p p O Pi ® P P d S S-d C l) t ) C £ > d o ® O lH tJ t) ■d o d Ph 3 >d m o p ® ® d t p p -p ® >» d p d s h h P h ® >d 3 O O d t Hi Pi d P t Pi w -d ra ® p ® d P t _ td *d d S d d on ® ® © d p ^ J -P H d q p p s, p a g s <0 CO co i O tO CM P 1 !» v pi< 3 P CM M* rH CD CO a> -P ® I03 A to CO IS to H h n ® 03 i o (O Pi W l- l i •a •a M P o a in 0) a i 01 dd a) * o » 0) CM i in rl § rl -S H *■3 H CD CO is to Ml P to H -O d CM CO g tO at CO cm -MI in CO CO to r l r l lO O 9 03 CO O p O no o o> tH A o Pt A +> H3 03 o 47 members of the catenas, are mixtures of red and yellow in varying proportions, modified in strength and intensity by white and black. In all colors yellow tends to dominate red, a dominance that ap­ proaches its maximum in the olive hues of the Napanee and Brookston profiles. The lightness or darkness of the color and its relative strength is reflected in the total amount of black and white com­ ponents, and in their relationship to each other. Black appears to dominate every comparison. How moisture influences soil color is reflected in the differ­ ent values in the two vertical columns shown under each series in Table 4. In nearly every sample, moisture reduces the strength of yellow and white components while it increases the amount of black. At the same time the red component remains relatively constant. Additions of water to dry materials, therefore, have the effect of making soil colors darker and more brown. Comparing different series leads to the conclusion that the automorphic soils have developed in parent materials character­ ized by hue ingredients of about the same magnitude. In this connection the C horizon of the tentative St Clair resembles com­ parable materials in the well-defined Miami, Isabella, and Bellefontaine series although color differences, possibly of a signifi­ cant magnitude, apparently exist; particularly notable in the St Clair is the lower amount of black associated with intermediate levels of the red and yellow hues. These differences are greater 48 in dry samples than in moist samples; under the latter conditions the hues of the four materials are essentially the same. As was expected, perceptible color differences between hori­ zons are reflected by numerical differences in hue ingredients. In Miami, for example, the relative quantities of yellow as com­ pared to red decrease in the upper horizons, the smallest quanti­ ties being found in the Ap layers. Thus red is more dominant in both eluviated and illuviated horizons. The eluviated layer, however, also shows a complementary increase in white which is usually interpreted by an observer as a lighter and grayer color. Soils developed in low drainage levels are characterized by colors containing smaller absolute quantities of hue ingredients. There is, of course, a complementary rise in quantities of black and white components so that profiles not only appear darker but also more neutral. Some observers can detect relatively large amounts of yellow in these soils which are sometimes described by such adjectives as ‘'olive11. As in other research fields, the difficulty of comparing and interpreting raw values, such as are listed in Table 4, suggests a necessity for devising mathematical relationships that will enable an investigator to segregate and evaluate the three color attributes of hue, brilliance, and chroma. Fortunately, mathe­ matical expressions have already been developed in allied fields (53) 49 and it only remains to borrow and adapt them to the purpose at hand. In applying Mansell*s analysis there are several precautions that must be taken. First, a single set of disks must be used throughout the study because color standards deteriorate. For this reason it is difficult and probably misleading to compare the work of various investigators. Second, the details of viewing, lighting, and matching must be held constant. And third, the standard hues must not be more than l/lO of the hue circle apart. Because the technique of this study did not violate these pre­ cautions it is presumed that the color formulas can be validly applied. According to Nickerson (53), the hue resultant (H) is the proportion of one hue to the total. Instead, however, of using only the area proportions, brilliance and chroma are also con­ sidered to give what might be called the color "power", according to the following formula: H - Z — AyPy (Z — x) Vx -V* in which and x z A P H is the number of the first hue (red, 5) is the number of the second hue (yellow, 25) is the respective area in percentage is the power number (brilliance x chroma) is the hue resultant In this study, the general formula was simplified by insert­ ing the appropiate values to give the following equation: Substituting appropriate area values for the dry parent mat­ erial for the Miami series produces H = 25 - 17(36) + 30(64) = 25 - 4.8 - 20.2 The brilliance of any match is the area of each color multi­ plied by the square of its respective brilliance* The square is used because reflection under certain illumination bears a relat­ ion to brilliance according to the "square law". For example, half black and half white do not produce a gray that is half way between white and black; instead, the color looks to be nearer three-quarters of the way towards white. One-quarter white and 3/4 black appears very close to middle gray, or about 5/ in brill­ iance. The formula is b » v A i 5!2 + A2B22 + A3B32 + * r r 100 where B is brilliance and A is the area in per cent of each ingre­ dient. Simplified for this study the formula becomes 51 Substituting appropriate values for the dry parent material of the Miami series gives B- A 16X V VJ) * ( U X 30) * (1 x 401 ♦ (81 * 13) „ , 72 100 •* Chroma (C) is the proportion of the chromas used to the total area. The formula is C a AjGl + A202 + &3C3 + 100 'which, when simplified, becomes C - _9Ar ♦ Sky 100 For dry parent material of the Miami series ft - f l L & m + J g . * .32). „ 3.93 100 In grading various agricultural products these three attributes have sometimes been integrated by means of the following formula Color notation s H s 1 C which, for the selected sample becomes N s 20.2 x 5.72 _ 2*67 3.93 This method of analysis was applied to the data already dis­ cussed, and the values plotted in Figure 1 were obtained. — Aia UOT^EpiGp pjEpus^EJ|_lueafi ■ ■ in r y i saeasAY-H- § ^ H ■ ft ■ -m- | " l ■ ■ ■ * A * w « the legend 3 9 data. § § i N 4> lower color of IBI right. Note § * at the 1 Analysis I . 1 . — Figure g o H H B s 55 Bearing in mind that the standard hues employed in this study were arbitrarily designated a value of 5 and 25 for red and yellow, respectively, a point of initial interest is the narrow hue range encompassed by the soils studied. The reddest hue was exhibited by the Beliefontaine illuviated zone with a value of 14*2. Most yellow was the Napanee illuviated zone represented by a value of 22*6* The over-all variation in hue encountered in these ex­ treme profiles is represented by a numerical range of 8 out of a total possible difference of 20 units. A second point of interest is the small standard deviations derived from the eight measurements that comprise each value. It is thus possible to conclude that by careful sampling, stan­ dard deviations may be reduced to the extent that significant color differences can be expressed by the Maxweli-Munsell tech­ nique. Concerning the data at hand, differences in hue appear to be more significant than differences of brilliance or chroma* Of the three attributes, chroma differences appear to be least significant. When the three attributes are integrated in the form of a color notation, as indicated on the right of Figure 1, a simi­ larity is noted in the parent material colors of the automorphic Miami, Isabella, and St Clair profiles. The hydromorphie Brookston profile shows the greatest departure from a mean while Napanee occupies an intermediate position. Considering only 54 automorphic profiles, there appears to be as much variation be­ tween horizons as there is between different series* Greatest variations appear to have resulted from weathering of the JL, hori— zons of soils in low drainage positions* These large differences are due not only to hue differences but to brilliance and, in the Brookston, to chroma as well* There is less variation in the color of different parent materials than there is between parent materials and their re­ spective solums* Confirming field observations, Isabella is the most red in hue, and Miami is the most yellow* St Clair is inter­ mediate* There appears to be no relationship between hue and drainage position. Likewise there is little relation between drainage position and the brilliance exhibited by parent material colors* Chroma, on the contrary, appears to be influenced by drainage, indicated by the extremely neutral values for Brookston. As parent material changes in response to soil forming pro­ cesses color differences develop within the profile, especially in the higher and drier soils* Here colors show a tendency to become a trifle more red in hue and possibly a little stronger but, at the same time, a little more gray in brilliance* In lower drainage positions, colors in eluviated zones are definitely more yellow in hue and lighter in brilliance* The Brookston Ag horizon is distinguished by its exceedingly neutral chroma* 55 Xu illuviated zones, chroma and brilliance are of about the same magnitude for all automorphic soils* Hue* however* exhibits a definite departure towards red. It is of interest that the brown layer and incrustations found on joint crack surfaces and completely covering some structural units in the B horizons of Miami* Isabella* and St Clair is essentially the same color in all of these soils* This similarity suggests that the fine products resulting from soil forming processes are similar in these three profiles* Although these color comparisons are of doubtful value in explaining the genesis of the profiles in question* they are of some benefit in clarifying the inter-relationships of the various series* Conover* Brookston* and Napanee, for example* exhibit the greatest variations as indicated by relatively large standard deviations. From the standpoint of field interpretation, these three soils are considered, to embrace a greater range of variation than do the automorphic profiles. In other words* the automorphic soils are more precisely defined and more precisely delineated. Considering only Miami* St Clair* and Isabella it will be noted that their standard deviations are of about the same magnitude, indicating that they are fairly consistently separated in the field. However, the intermediate position of St Clair with respect to Miami and Isabella and the considerable overlapping of the wet and dry colors makes the separation of the former of doubtful utility* at least as far as color is concerned. 56 CHEMICAL COMPARISONS Even more difficult to perceive than color, because the re­ lationships are not immediately visible, are the choralca! charac­ teristics of soils and soil materials* Early investigators tended to over-emphasize total chemical analyses, especially in expressing comparisons in terms of weight percentages with little or no regard to complementary physical attributes of the materials being studied* In many instances this practice resulted in misinterpretating data and formulating fallacious conclusions* Broad use of the word illuviation in describing the Gray-Brown Podzolic Forest soils is perhaps evidence of a popular misconception of soil genesis under this particular climate, a misconception that has been fostered by difficulties of analyzing data of this nature* TOTAL CHEMICAL ANALYSES Despite the present unpopularity of total chemical analyses, such studies are valuable in determining the uniformity, or lack of uniformity, exhibited by parent materials and profiles developed in these materials* The following data are of especial interest because of a notable lack of previous information concerning heavy till materials in Michigan. Techniques and methods involved in these measurements are presented in Appendix II* Table 5 presents detailed analyses in terms of the most im­ portant and bulky constituents of the several series under dis- 57 Table 5. Total chemical analysis of the selected reference profiles, expressed as per cent of oren-dxy organic-free sample Heights. Vaises are averages of duplicate determinations• .Horizon *2 B G *2 B G a2 B C a2 B C SiOg . 1^2^ • A12p3 • Ca® . IfgO . IL* . CQfc 82.5 82.1 74a 73.4 67.4 68.9 4.2 4.0 4.6 4.8 5.1 4*6 ST CLAIR 6.6 0.7 6.7 1.3 5.8 7.4 6.4 4.5 6.1 10.5 6.6 7.4 0.4 0.5 3.5 4.0 2.0 2.2 2.1 3a 3.1 4.2 7.6 7.9 0.3 2.5 2.8 6.9 7.1 79.3 78.4 72.9 71.2 65.7 67.6 4.0 3.4 6.3 5.9 5.1 5.0 COHOVER 6.2 0.2 6.8 0.1 2.0 7.3 6.7 3.5 6.3 8.5 6.0 6a 1.2 1.2 3.3 3.2 3.8 3.9 4*6 5.1 4.9 5.1 9.3 9.1 3.7 3a 8.8 8.5 82.1 83.5 72.3 69.2 63.9 64.6 2.5 3.7 6.2 6.7 3.9 4.0 NAPANEE 7.5 1.4 7.3 0.9 1.5 11.5 11.8 1.8 6.8 7a 7.3 6.7 0.7 0.9 1.8 2.7 4.4 3.4 2.7 1.7 1.9 2.1 U.3 10.2 4*4 4.1 4.3 4a 4.7 3.5 BROOKSTON 8.6 1.1 0.9 8.9 10.2 2.8 2.8 11.4 8.8 9.2 10.3 7.9 2.8 3.9 4.1 4.5 5.5 4a 1.2 2.4 7.5 7.9 11.9 11.6 78.4 77.4 66.4 67.5 57.7 59.9 * Ignition loss — - — 0.6 0.9 9.8 9.0 — 5.2 5.4 11.7 10.5 58 Table 5. (continued) Horizon. SLQz . Fesp3 • AlgOj • CaO • HgO . 1L** . C02 *2 B C ^2 B C c* *2 B C UTAWT 0.7 0.9 0.8 2.8 3.6 1.2 7.9 6.1 7.9 0.5 0.6 0.4 2.5 2.1 0.9 3.9 3.2 4.5 0.4 0.9 2.5 3.6 3.4 5.5 10.8 9.1 13.7 1.6 — 0.8 81*3 80.1 *84.1 69.7 69.3 *63.7 60.3 62.5 *51.2 4.9 4.7 2.0 7.2 6.3 6.0 5.1 5.2 4.8 10.0 9.3 7.7 9.1 12.4 16.5 9.8 11.2 13.3 87.0 *88.2 85.2 *72.3 62.7 *54.2 2.8 1.6 5.5 4.2 4.2 4.7 ISABELLA 4.6 0.6 5.2 0.7 5.2 0.7 1.6 11.3 4*4 8.9 5.0 13.1 0.3 0.5 0.4 1.7 4.8 5.7 3.5 15.7 — 0.9 — 1.3 12.2 14*8 61.1 65.4 4.7 4.5 OHTGHAGON 7.6 5.1 9.1 4*1 5.8 4.6 13.2 U.6 12.3 12.0 62.4 63.4 5.3 5.1 SELKIRK 6.2 5.9 6.6 5.5 6.4 5.6 11.5 11.3 10.7 10.3 3.2 9.2 3.1 BELLBFONTAINE 0.1 5.6 0.7 4.9 8.0 4.3 0.5 3.2 1.0 0.3 0.7 5.3 1.1 87.3 79.2 77.3 _ 2.3 2.0 0.0 10.3 8.1 10.6 4*4 * Sample collected by J. 0. Veatch and analyzed by 0. B. Winter of the Michigan Agricultural Experiment Station. + SangxLe collected by James fyson and analyzed by D. 6. Sherman. • fifttnpia coUested by Gash Wonser. ** Ignition loss. 59 TatAo 6* Sunazy of the chemical analyses of the selected profiles, expressed aa per cent of the cven-dxy, organie free sample weights. Horizon • X-CC^ . *2 B C ^2 B C h. B C ^2 B C cussion. SLQg . Fe2C>3 . AI2O3 5.5 18.5 ST CLAIR 82.3 73.7 68.3 4*1 4.7 4.9 7.2 18.5 CONOVER 78.9 72.0 66.7 3.7 6.1 5.1 2.1 20.0 NAPANEE 82.8 70.8 64.2 3.1 6.5 3.9 7.4 31.7 7.0 11*2 23.0 BROOKSTON 78.1 66.9 58.9 4.2 4.2 4.1 8.8 10.9 9.8 6.6 6.9 S 8#9 I 6*5 1 7.0 i 6#7 1 All values are oven-dry, organic free weight percentages, a manner of expression that is considered of value primarily in comparing these figures with already published data, which have nearly all been organized in a similar form. Inspection of these figures illustrates that the soil materials are remarkably similar in ohftnHpal constitution despite variations in color and texture. The most variable component with respect to the profile as a whole appears to be carbonates* although silica also shows considerable variation. Extremes of composition resulting from texture may be 60 Table 7* Chemical analyses of the selected profiles summarized. as grains per lOOcc of the organic-free sample* Each item is an average of four measurements obtained from duplicate determinations on duplicate samples. Note ratios at the right* .Horizon. Total* . I'GO^ • SiOg * Fe203 • A1293 weight Ratios Si02 ^ AI2O3 FegOj Fe203 137 155 176 ST CLAIR 112.9 8.5 114*2 25*5 120.1 5.6 7.3 8.6 9.0 10.7 15.7 20.1 15.6 14.1 1.61 1.46 1.83 A2 B C 139 156 169 CONOVER 109.5 11.2 112.5 31.3 114.2 5.2 9.5 8.6 9.1 10.9 11.4 21.1 11.2 13.3 1.75 1.15 1.33 Ao B C 133 159 171 NAPANEE - * 111.1 3.3 113.6 34.2 108.6 4.1 10.3 6.7 9*8 18.6 12.0 22.3 15.6 16.4 2.23 2.08 1.79 *2 141 148 173 BROOKSTON 110.3 16.6 99.2 39.8 101.5 5.9 6.2 7.1 12.8 16.2 16.9 18.7 16.0 14.3 2.17 2.65 | 2.38 *2 B C C * From Table 1* noted by comparing the Bellefontaine and Napanee profiles. Extremes of color are exhibited by the Napanee, Brookston, and Isabella pro­ files. Another point of interest is the apparently high Fe and Al content in the B horizons of all but the St Clair profile. In order to simplify this information, values of duplicate samples have been averaged and summarized in Table 6 which more readily shows the above relationships* Here it is seen that the 61 principal difference exhibited by the horizons of the selected pro­ files is in their carbonate content* Compared with differences in carbonate levels other chemical differences are comparatively small* This table also shows a nice, but probably incidental, relationship between topographic position and the carbonate content of parent materials. A summary of greater value is presented in Table 7, wherein the chemical analyses have been weighted according to the apparent specific gravities of their respective horizons, a comparison of more significance than conventional weight percentages when con­ sidering the genesis of a particular profile. It is here even more apparent that loss of bases from the solum has been a major effect of soil forming processes. Differences between the various parent materials are seen to be not as great as they appeared when ex­ pressed as weight percentages. A notable point made clear by Table 7 is that the St Clair pro­ file exhibits no true zone of accumulation over and above its parent material inheritance. With respect to the C horizon, the B horizon also displays leaching, although not to the extent shown by the layer. The relatively heavy texture of the B horizon must result, then, from an apparent increase in clay complementing a loss of carbonates. Changes in structure may accompany the decrease in poly-valent cations within the B horizon. Consequent dispersion 62 of the clays may in turn contribute to the "heavy® field character*-* istics that distinguish this so-called illuviated zone* Table 5 has already demonstrated a concurrent change in the size of al l particles which undergo considerable reduction, so that the quantity of fine clay in the B horizon is increased* It would seem that the evidence so far indicates the bulk of this fine clay is formed in place rather than infiltrated downward from the overlying JL, layer* The Napanee and Conover profiles exhibit a slightly, and possibly significantly, greater amount of iron in their "illuviated* zones than in their respective C horizons. This is especially true of Napanee which also displays a greater quantity of alumina in its B horizon* Another characteristic of some interest is the high amount of silica in the Ag horizon of this soil, in con­ trast to St Clair and Conover which are characterized by signifi­ cantly less SiOg in their surface layers. In this regard the Brook— ston profile is also of interest since it, too, shows significantly higher amounts of silica in its Ag. These differences are summarized in Table 8* Here it is seen that horizon development in the various soils appears to bear some relationship to the topographic position in which the respective profiles have developed. Thus the older and more exposed till, represented by St Clair, is marked by great losses or by the effects of more vigorous and intensive leaching* 65 Table 8* Chemical differences between the horizons of the selected profiles, expressed in grams per lOOce of volume. ^2°3 | A -C B - -C ST CLAIR -7.2 -3.0 -5.9 -1.3 -6.7 -5.0 I f j A -C B*G CONOVER -4.7 -3.4 -1.9 +0.9 -2.3 -0.5 A -C B-G NAPANEE +1.2 -2.6 ♦3.8 +3.6 -2.2 +6.6 A-C B-C BROOKSTON +8.8 -1.2 -2.3 -0.9 -4.1 -0.7 Horizon . SiOg . FegOj • 1 [ | ! NOTE: A + sign indicates that the horizon contains more than the "parent material". She - sign means the horizon contains less. It is also seen that Napanee, Conover, and Brookston, represent­ ing lower positions in the same drainage catena, are character­ ized by losses of a much smaller magnitude* Napanee is unique in that its B horizon is characterized by larger quantities of SiOg, FegOg, and AlgOg than is its C horizon. The decreasing magnitude of these horizon differences, particularly differences in iron aluminum, primarily offers some foundation for con­ cluding that profiles are formed as a result of leaching. The 64 high amounts of silica in the A^ horizons of Napanee Brookston cannot, however, be explained on the basis of leaching, A better explanation is found in the thesis offered in an earlier section which is not refuted by this new evidence but is rather strengthened* The concept has been advanced that the surface layers of Napa­ nee were depleted in clay by the sorting action of wave-induced turbulations in the shallow waters once covering the area. It 1ms also been suggested that the sandy residues may have been gr&vimetrically separated so that heavy clay-forming minerals were concentrated in an enriched zone at some depth below the surface of the lake bottom sediments. This gravimetric sorting would simultaneously result in a chemical separation of the coarse sedi­ ments. Silica and certain potash-soda feldspars of a low specific gravity would remain on the surface while horneblende and the plagiocl&se feldspars would sift downward, contributing to an en­ richment of a zone below the surface. Subsequent weathering could be expected to produce relatively small quantities of clay in the upper silieious layers while the enriched zone would pro­ duce relatively large quantities. This concept thus accounts for both the high quartz content of the Napanee surface, and the re­ latively heavy texture of its B horizon. A profile so formed would present striking texture contrasts and yet represent a minimum of clay translocation (that is, illuviation) within the profile. 65 Table 9* Analysis of meteoric waters from eastern Michigan (49), in parts per million. "1..... I \ 1 | ! M Location Armada Almont Bad Axe Brown City Harbor Beach Imlay City Marietta Memphis Port Austin Sandusky Ubly -- - T 1 . Source . SLO2 Well Well Well Well Taira Well Well Well Well Well Well 16.4 16.8 11.2 11.2 10.0 12.0 3.8 19*2 7.6 8.0 20.8 . w Fe^ nd 2.4 1.0 nd 0.0 1.8 nd 0.7 0.4 nd tr nd 4*0 2.2 nd tr 3*8 nd 3.2 1.1 tr tr NOTE: “nd” indicates no determination; Rtrn means trace. Brookston materials represent depression sediments associated with wave-washed Napanee materials. Pursuing the proposed thesis to its logical conclusion it is necessary to suppose the surface layers of Brookston were somewhat enriched by clays separated and laterally transported from the higher surrounding areas. This action is thought to be reflected in the relatively high iron and aluminum content of the Brookston solum. Brookston sur­ face horizons exhibit a relatively high silica content, which is also explained on the basis of wave-action and consequent physical sorting of surface materials. The relative large losses of silica are of interest in con­ sidering the chemical weathering that has been accomplished in 66 tills particular climate* it study of meteoric waters throws addi­ tional light on this subject (see Table 9) since it shows that their silica content is much higher than either their iron or alumina. Moreover, Tables 8 and 9 reveal that subsurface drainage waters carry alumina -and iron in about the same ratio as they are leached from soil* The silica—sesquioxide ratio of losses from surface horizons is, however, smaller than a similar ratio for meteoric waters, the former being somewhat less than unity while the latter is in every sample greater than unity* A possible, though perhaps hasty, conclusion is that iron and alumina must be deposited somewhere within the sub-strata, somewhere other than in the so-called illuviated zone of the solum* Additional evidence will later assist in clarifying this point* To summarize, the results of chemical analyses appear to support the conclusion deduced from studying particle size distri­ butions: that soil forming processes have resulted chiefly in re— moving carbonates from the solum* Silica, iron -and alumina have also been lost and these losses are generally apparent not only in the leached zone but also in the so-called accumulation zone* An exception to this generality is encountered in the anomalous Napanee profile} it is argued, however, that these exceptional gains originated before the profile was exposed to soil forming forces therefore do not invalidate the concept that disinte— 67 gration, decomposition, and leaching have dominated the genesis of the St Clair-Napanee-Conover-Brookston catena* MINERALOGXCAL ANALYSIS It has already been shown that certain advantages are derived from expressing analytical values in terns of volume rather than weight* An application of this prin­ ciple has revealed information concerning the relative importance of certain soil forming processes in the evolution of a Gray-Brown Podzolic profile* Some idea has also been gained concerning the morphology of several selected profiles and their categorization in the pedologic taxonomy of a rather limited geographical area* Thus far, however, the argument is perhaps as misleading as earlier accounts of genesis and morphology; the fallacy here is in the assumption that present volumes are satisfactory reference criteria, despite the fact that there has already been an occasion to note that the present A^ horizon probably is much thinner than the parent material from which it evolved* An independent re­ ference by which to judge volume ehanges is, therefore, an obvious requirement* Early pedologists seized the various petrographic techniques as they have been perfected by sedimentary geologists and have used them to describe soils and soil materials. This early work, however, consisted of little more than cataloging the various 68 mineral species encountered. Not until the past decade has there been any serious attempt to correlate petrographic data with soil genesis. These efforts have been pioneered by Jeffries and Mar­ shall and it is the latter who has suggested that resistant min­ eral species may afford the necessary and vital reference for indicating changes involved in profile genesis. It has already been seen that weight and volume references have not supplied & satisfactory index of the various losses and possible gains which have evolved the profiles described herein. This section is an attempt to rationalize certain petrographic data with respect to the theory already set forth, and to discover what new light this approach may shed on the older concept of illuviation as a major soil forming force. In Table 10 are summarized the findings of a petrographic investigation into the nature of the very fine sand fractions of the selected profiles. The value of these data is considerably enhanced by a notable scarcity of such information concerning Mtplrigam surface materials. Despite the fact that underlying rocks have been rather thoroughly studied as a consequence of in­ terest in subsurface mineral resources, surface materials have been largely ignored by both the geologist and pedologist. Con­ sequently, no other comparable data, dealing with heavy calcareous tills in Michigan, can be found. It is of interest, however, to note the similarity of the sQ'OO'TOHTOtACAH O' • • * • • • • • •cm to*a tot CA -o tt Ho o ca ©E'-CMV\©CM«A'tfO' *(f\t* O' -tCAo CM *t V\p-f o•so•r•*ca •*t•cp\ o«pt\> © O'O'H CAC :* tT OTO O' CM r-lCA O' H xO -txQ TO © 0'E*»TOCM»ACA C-A • • • • • • vf•rr f QxOr-JO'C'-Q vO *A H ri *A O' CA'tCACA'Ar-fTOst’-t »• ATOO •CAO'V\P-©0'OCM ca ^ CD r-*'txQHcA't u > h C♦MP\C'C»\0'CM(»\0(P\ ******** >t • • * • • # H v o o -t r- jH okoipul wl *50 S s ®» •f <¥ • 8 o £ ^ © •H ,a »* a S-SS? J ■"fl COTOOCMO'r-ICM lAH {> C•MH *O*TO*O* 0*''*0 * O tA O *CM x O' -t H H -tH -- o oa © o o o £|S -p H H p'd-P'd ^ © a d a O' g i a i a «AJ»A*TO*-t C-*O TOCA r *'O *C*AC*A* •O -t'O O'-t O'HO'o ^ I •d © n a 3 ©«V•\x© ©xO »« «A• * ©xO rj O O'O^ I cap- & 1 3 3 1 3 &.S s SQ •3 S ? C M * A C M v O H C M *t»A*t CS******** •OP-'tCAr-l'OlOCM «t rf>An 1 1 * 1 * r 4 © « A l > C M © -t 'O C A i - 1 2 1 K«*t»*»»« * O V \xO Q O Q © C M CA H «ACM H't‘ • * AW"0't • • • • lAH •CM x CM HO C-C r-AfCACAl Ax O£'>xO HO'O'CAHP• • • • • « ©xO •rl CA«A^CM CO O »A*A •r>l 4 Si ^•CATO'tC^WjOjOrl O 0 'Pio d 3 s a O •C IA OM ' O' ©TOrlO'CM'tH'tTO _ ) • • • • • • • • O'CM •sr i t O'PHx0 • •V\CM ••O »'•U\ TO •T cO * OTOCAHxOCA *' AO' r-f H m O ©O' O CMxO P* xtH m NTvQ ^•OE'»rjO'P;«ClOCM C• "C•CAvO ••H • •«A O'O'O'*ACO H lA o i CACo"**©*©*'t'O t * * CA-tt© *** SfH tot> CMO■'* t't »A>t v *'O*O*CA t> Pj «j.x£J O CM CATO O' CM CM »A O' CM "t CM•> •-t •-t •O•'O•'• tJoJ OvO o cnpi ja»a • *Ar t Petrology of the very fine sands, expressed as the per cent of particles counted O'CAOxCACACM *••••« CM\0 tftOOrl 1 4 »A pi H H *A O' -j • • • • • • P•-CrM ca r-O'v> p*ca *>vo h m O' Table 10* 69 •O' HxO S E-tN 70 mineral assemblages herein reported to those encountered by Kruger (54) in the late Wisconsin till of Minnesota, by White (75) in the Wisconsin drift of northern Ohio, and by Mickelson (51) in the Wisconsin drift of central Ohio* Quartz, calcite, feldspars, hornblende appear to dominate most of the till assemblages re­ ported by the above authors. In eastern Michigan drift these four minerals constitute 50-51J&, 9-16^, 1£-2C$, and about respec­ tively, of the very fine sand fractions. The remainder of the fraction is dominated by rather amorphous appearing aggregates seemingly limonitic in character. The heavy fraction of the very fine sand, which is present in rather uniform quantities, is dominated by hornblende, a re­ lationship that appears to be widespread according to the above authors. Johnsgard (52) and Matelski (48) found that hornblende dominated the heavy mineral fractions of all Michigan sandy pro­ files examined. Besides hornblende, other important heavy minerals are garnet, epidote, augite, and several opaque minerals of which magnetite is the most abundant. In nearly all samples certain accessory species were also noted, the most numerous being titanite, rutile, ilmenite, leucoxene, biotite, pyrite, monazite, kyanite and chlorite. These accessory minerals are present in such small quan­ tities, however, that no attempt was made to secure quantitative measurements since the major morphological differences are found in the dominant species. 71 Considering the profiles listed in Table 10, a marked simi­ larity is found in the quantities of the various minerals present in very fine sand of the several soils. Here, as in total analyses, major differences seem to arise from the varying amounts of calcite present in parent materials, and in the apparent in­ creases in resistant minerals in the surface layers resulting from losses of calcite as a consequence of weathering. It should be borne in mind that all values listed in Table 10 are count per­ centages and that they are, therefore, representative of volume changes rather than weight changes. Since these data, as well as chemical analyses, indicate that horizon dissimilarities are chiefly caused by differences in carbonates, a more ready comparison of the profiles is obtained by recalculating all values to a ©alcite-free basis. Such a com­ parison is shown in the upper part of Table 11, Here it is seen that the quartz content in the very fine sand fraction is rela­ tively resistant, being present in greater quantities in surface layers than in the respective B or C horizons. This difference is in part only apparent, because there has been some weathering of the feldspar minerals in the JL and B horizons. On the other hand, total chemical analyses have already indicated that there has been considerable loss of silica from the surface layers, per­ haps more than was realized through the decomposition of minerals other than quartz. Although very fine quartz could not be ex— 72 pected to contribute measurable quantities to these losses, never­ theless the tendency is towards decreasing, rather than increasing, quantities of silica in the A 2 horizon. In view of insignificant losses of materials other than cal­ cite from the surface layers, it appears that the great differences in the quartz content of A and B horizons of the Conover, Napanee, Z and Brookston profiles can be accounted for only by advancing an hypothesis of a non-conformity developed as a result offpurely physical soil forming processes. Additional evidence in favor of this theory is seen in the total quantities of heavy minerals in the very fine sand fractions of the various horizons of the se­ lected profiles (see Table 10)5 the St Clair profile displays a slightly greater quantity of heavy minerals in its B horizon, whereas the other profiles, and especially the Napanee, show differences of a much higher order. In fact, the large quantity of heavy minerals found in the B horizon of the Napanee (as com­ pared with the A_ and C horizons of the same profile) cannot be Z reconciled to the probable intensity of weathering that has pre­ vailed in materials situated in this particular drainage position. Marshall (46) has recently advanced a petrographic theory for use in studies of soil genesis, a theory based on an assump­ tion that certain resistant minerals remain relatively unaffected during profile development. Two or more resistant minerals found 75 in the various separates are used as indicators of depositional or geological differences in parent materials. If the material was uniform when weathering started, the ratio between any two of these mineral species should be constant throughout the profile. Pronounced variations in this ratio indicate depositional differ­ ences within the original parent material (51). Zircon and tourmaline are generally accepted as suitable species for a valid application of this test. This selection is unfortunately of limited value in studying the data at hand be­ cause of the small number of particles counted in each sample, and because of the few zircon and tourmaline particles found therein. Moreover, only one size fraction was studied, which presents a serious obstacle in the logical interpretation of mineralogical data, as Matelski (48) has recently shown. Not­ withstanding these objections, however, an application of Mar­ shall^ theory is considered justified, providing its limitations are fully understood. In Table 11 certain ratios are therefore presented which are of interest in view of the findings of other investigators. A useful point of departure in the problem at hand is found in the recent works of Cady (9) and Chandler (12) dealing with the resistance to podzol weathering of the more important soil minerals. Their studies show that among the most resistant min­ erals are magnetite, quartz, garnet, and zircon. Moderately re— 74 © © 3o o •a o CM E - CA CM CA UA «> sO r j Q s O 0 " 0 O CA H UA CM CO iH H t H UA vO l > O' o C " > t O " 0 O CA UA I o 0 I 4 : 1 CM sO H C- Nj- CA to t> O' i 4 j H ! 2 \ CA CA UA "t sO CA CM U A C S N fU A UA O 'C A " t UA t " © CA to t> p O UA CO O O CM H UA sO to 't H s O s O CM s f t O o UA CA CM t > p-J O ' H O CM c- S0 CA O CA to to CA CA 't sO CA £ UA O CA © ■d H £> CA O ' CM O CA UA CO vO Nf'i' 't M J O' “8 o T> CM CA O ' r l s o SO t o •d it © o o a O sO OSQSCA^ C** UAO m UA r " CA CA s f 0 O 'O 's Q CA 0 0 P - r j O O CM « © 1 5 s> CO CA o H © S fv O sO ' t o Q Q O ' C** H H UA O ' U A ' t UA O CA r l UA vO UAs£> UA C A ' t H CA UA * t © 3 3 UA t> s Q CO O CM | Nf | Jj © 't a C*- 58 O' N* -t sO UA CM sO CM CO 3 *3 rj 1 o o •£ P Q © (U O ' O sO t > »tH •© «• \• t O s © * « tC M >0 H H• -sf-t© » • • \0 U A © CM H 'Q UAvO O vO • • • -f1 • sOrJO'Q' sO UA t > CM CAsO tO © O' si* UAsO CA to Nj- O' CA UAvO sO CA «•••*« O' Oj tO O CM CM CM ^WA>t'0'0 vO • O O O CM sO r-t UA CM CO 't vQ US C- O NfxO O' O' o CA CA ■sr *t •H « ■® w> m a - SN OJWl ^ § s £ UA C M CA sQ UA sO CA 'O ri 'O ua to sf C M C O CA CA • U A i 1 Analysis of the mineralogic data listed in Table 10 w *W rl 0} 4a UA 00 00 sO Table 11. o 75 sistant minerals are ipidote, orthoclase, and diopside. Easily weathered minerals are hypersthene, hornblende, plagioclase, and olivine. If these conclusions are accepted, then the ratios listed in Table 11 indicate that of the four profiles, only the St Clair has developed in materials that were uniform when first exposed to chemical weathering forces* The corresponding ratios for the various horizons of the Napanee, Conover, and Brookston profiles vary so greatly that, despite the inherently great experimental error in these determinations, their significance cannot be ques­ tioned, Evidence as to the mechanical separation of the light and the heavy minerals (by wave-washing) is seen in the quartz/ zircon ratio which is excessively high for the A 1C horizon and low for the B horizon, particularly in the anomalous Napanee, These petrographic data therefore confirm conclusions earlier deduced from studies of particle sizes and chemical analyses. It is thus possible to state with some degree of assurance that the St Clair profile represents a zonal automorphic soil developed in rather uniform parent materials. By the same token, further specu­ lation concerning the relative importance of eluviation and illu— viation in the genesis of the Napanee, Conover, and Brookston pro­ files is known to be fruitless since these studies thus far have revealed no method of reconstructing their original parent material profiles. 76 CALCITE-CARBGNATE PROFILES* Soil classifications like the example out— lined, in Appendix III axe usually founded upon such physical and chemical features as c*»n be visually dis­ tinguished by the field worker* In mainng the survey of the soils shown in Map 3, preparatory to securing samples for laboratory comparisons, it soon became apparent that perhaps a major chemical difference of the four selected series was in their carbonate pro­ files* Accordingly, a field study of this feature was instituted with the results that are shown in Table 12* Obvious deductions from these data are that calcite-carbonates are encountered at greater depths in the Napanee and Brookston series than in the higher and supposedly more weathered St Clair and Conover profiles* Field observations indicate that these differences are not reflected in either the A^ or B horizons, the common depths and thicknesses of which are indicated in the table* In the St Clair and Conover series, free calcite-carbonates are commonly found just below the zone of maximum color intensity in the B horizon* This relationship was not observed in the other two profiles, although a great difficulty with these latter soils was in identifying the B horizon* * Observations along freshly dug So called because cold 1:1 HC1 was employed in the field, which produces effervescence with calcitic rather than dolomitic car­ bonates* 77 Table 12» Calcite-carbonate profiles of the selected series, indicated by the number and per cent of borings in 'which treatment with cold HG1 produced effervescence• bb 0 1 o Depth (inches) 10-14 14 — IB 18-22 i 22-26 | 26 - 30 30-34 34-38 | 38-42 Over 42 Total ST CLAIR n — 7 33 72 102 61 23 12 8 5 323 % — 2.2 * 12*4 *34.7 * 66*2 85.1 92.2 95.9 98.5 100.0 CONOVER N % _ m. — 14 * 4*9 45 - 20.9 64 I 43.2 71 68.1 43 83.2 22 90.9 12 95.1 8 97.9 6 100.0 285 NAPANEE H % — 1 2 7 13 19 20 43 28 134 — „ 0.7 * 2.2 : 7.4 * 17.1 31.3 46.2 78.3 99.2 BROOESTQN N % m. — — — ■Jr 0.5 2 * 1.3 • 4.5 ! 5 8.0 7 21 18.6 32 41.0 100.0 ; 119 198 NOTE: "N" is the number of borings in which free effervescence ■was for the first time encountered at the indicated depth. n%* is the accumulative per cent of borings in which was encountered at the indicated, or shallower, depth free effer­ vescence. Hie asterisk (*) shows the average depth and develop­ ment of the B horizon. drainage ditches, however, confirmed evidence obtained from borings to the effect that a zone of free effervescence lies somewhat below the zone of finest texture in the Napanee and Brookston series. These differences in the calcite-carbonate profiles are thought to be great enough to justify a field separation of Napanee from Conover and St Clair. It is possible, moreover, that the characteristics of this calcite-carbonate profile are related to other more subtle features not susceptible to measurement by the techniques employed in this study, but which are nevertheless in— 78 dicative of the unique appearance of the Napanee profile and its position in the taxonomy of the area in question. Possible explanations of these differences in the carbonate profiles of the selected series are found in their profile drain­ age characteristics. Napanee and Brookston developed in positions that are analogous to those described by Sherman and Thiel (62) as being susceptible to dolomitization. It is possible that the carbonate content of these two soils has not suffered great de­ pletion below the B horizon, but has merely been changed to a more dolomitic form which does not effervesce when treated with cold HC1. This explanation is strengthened by the data in the section dealing with the chemical composition of these soils, where it may be noted that even the B horizons contain some car­ bonates, and that magnesium is present in larger quantities than calcium. Another explanation of at least a contributing factor is found in the relative susceptibility of the four soils to geo­ logic erosion. Thus the carbonate-free mantle which has devel­ oped on the more exposed and higher areas is continually decreas­ ing in thickness due to a loss of materials from the surface. The low-lying soils, however, are not subjected to erosive forces and so, in . all probability, do not lose material from the surface; on the contrary, they might be expected to gain material as a result of their low position. Hence the carbonate solum in St Clair and 79 Conover has a tendency to decrease in thickness while that of Napa­ nee and Brookston increases as a result of these same forces* PEDOLOGIC INTERPRETATIONS The foregoing pages have presented the results of several lines of inquiry into the nature and genesis of the St Clair, Napanee, Conover, and Brookston series* The relationship be­ tween these four profiles and other important Gray-Brown Podzolic soils has also been pointed out. With the evidence now at hand, it becomes possible to integrate these converging approaches with a greater degree of assurance, and to speculate and draw con­ clusions concerning the processes which have given rise to the automorphic soil under study. In order to develop the argument, however, it is first necessary to review certain accepted con­ cepts, together with one or two related fallacies that are some­ times overlooked, so that a firm basis is established for the final deductions. PODZOLIZATION The generally accepted view of podzolic soil forming processes, and their affect on soil materials involves the theory of differential solution. Under conditions that encourage the formation of podzolic profiles, bases are first removed from materials exposed to soil forming 80 forces. Then iron, and possibly some alumina, becomes more soluble and is leached downward leaving the upper solum relatively high in silica. It is thus that the relatively light texture of a pod- solized Ag horizon has been explained. Some material washed out of the surface layers has been thought to move downward through the developing solum until it arrives in a zone of lesser leaching where, due to less acid conditions, it either flocculates or pre­ cipitates to produce an horizon of accumulation. It has even been supposed that certain quantities of fine clay actually disperse and infiltrate through the solum, carried by the normal downward movement of percolating water; this clay is also thought to ac­ cumulate in the B horizon either because it flocculates, with the result that particle sizes are increased, or because it reaches a place where the continuous pores are too small to permit farther passage. The A horizon is thus thought to be a zone of loss or ELUVTATION while the B horizon is primarily a zone of ILLUVIATION. This theory may satisfactorily account for the presence of organic colloids in the ortstein and orterde of certain sandy ground—water podzols. It may also account for the presence of relatively dark material which coats the exterior of a majority of structural units in heavy profiles like the Miami. It is diffi­ cult, however, to reconcile illuviation with the relatively high interior clay content of structural units in B horizons developed in heavy calcareous tills. Visual evidence shows that while some 81 organic colloids may be translocated in these profiles, they are concentrated on joint cracks and as aggregates filling shrinkage cracks. Matrix material, as indicated by color analyses, appears relatively unaffected by translocation. It is, moreover, hard to realize how clay might enter the structural units proper since water movements through this heavy material are extremely slow and probably of a very small order. From time to time investigators have cast doubt on the hypo­ thesis of large quantities of mineral clay moving through the solum as such, but direct and conclusive proof has not yet been put forward. Also, the fallacy of expressing analytical results in terms of weight rather than volume has never been widely ap­ preciated, and the customary weight percentages have exaggerated apparent differences resulting from weathering. Horizon compar­ isons on a weight basis have therefore shown such marked contrasts that it has been difficult to conceive, much less propose, an ex­ planation based on other than translocation theories to account for the large differences reported in investigative literature. A major perplexity in the past has been encountered in trying to ascertain the relationship of a solum to its underlying unweath­ ered layers; to determine whether or not the solum developed, in fact, from materials similar to the existing C horizon. This obstacle has been especially great in dealing with unconsolidated sediments which comprise most glaciated environments, where varia— 82 bility is the most conspicuous attribute of landscapes, soil mate­ rials, and soils* Studies dealing with genesis and morphology have therefore reached an impasse where they will in all likelyhood linger until some method has been devised to establish the uniformity of the original parent material. The technique re­ cently advanced by Marshall fortunately shows promise of offering -a solution to this problem. HEAVY MINERAL REFERENCE Several assumptions are involved in an application of Marshall's resistant mineral method. Important among these are: (1) that the resistant minerals se­ lected have undergone neither physical nor chemical decomposition; (2) that none or insignificantly small quantities of the selected minerals are released as a result of the decomposition or disin­ tegration of coarse separates; (S) that the resistant minerals are present in particles too large to be transported by percolating water; and (4) that the resistant minerals are not formed within the soil environment. Mickelson’s work on several Ohio profiles (51) presents a satisfactory rationalization of these difficulties, a rationalization which will not be repeated here. Although cer­ tain necessary assumptions are not entirely satisfied when the method is applied to glacial materials, Mickelson concludes that the errors involved are small enough not to discredit general trends indicated by such studies. An application of the resistant 85 mineral technique to the series discussed herein, therefore appears feasible, if not necessarily expedient. It has already been shown that the ratios between several re­ sistant minerals justify the conclusion that only one solum, the St Clair, developed in an apparently uniform parent profile. Con­ over, Napanee, and Brookston all show evidence of having developed in materials characterized by depositional differences prior to their exposure to soil forming processes. These differences, as indicated by significant variations in certain resistant mineral ratios, are confirmed by dissimilarities in particle size distri­ butions and in total chemical constituents, despite the fact that their color and other easily discernible field characteristics show no visible extremes between the several horizons. In view of the origin of their parent materials and the nature of the landscape in which Conover, Napanee and Brookston are encountered, (the many confusions of which are depicted in Map 5 and the accompanying descriptive legend in Appendix III), it is not surprising that an investigation of these three profiles has terminated in a cul-de-sac. On the contrary, it is the uni­ formity of the St Clair materials that is of note, a uniformity that has seldom been appreciated in glaciated materials. Since it can now be concluded with some justification that the and B horizons of the St Clair have developed in materials that were similar in physical, chemical, and mineralogical constitution to 84 the present underlying C horizon, it is possible to elaborate on. the genesis of this particular profile, GENESIS OF THE ST CLAIR SOLUM With the data at hand, it is possible to calculate the volume of a representative sample of each horizon associated with one gram of resistant mineral and thereby reconstruct an hypothetical parent profile represent­ ing materials as they originally existed when the present landsurface was first exposed to weathering. Marshall (2, 46, 47, 51) has proposed the equation D_= dv V where V is the volume of any particular horizon associated with one gram of resistant mineral, v is the volume of parent material containing one gram of the same mineral, and d is the present thickness of the horizon in question. D then represents the ori­ ginal thickness of the parent material required to produce the present horizon. Making use of this equation, a soil forming factor, or perhaps more precisely a weathering factor based on heavy opaque very fine sand, has been calculated for the and B horizons of the St Clair solum. Table IS outlines the logic of this line of reasoning. The results show that both the A„ and B horizons have suffered a net loss of materials, the former now representing about 60$ of the volume originally occupied by its parent material. Losses from the B horizon have been much smaller, but it is of interest that 86 Table 13* Genesis of the St Clair profile. Calculation of the probable net changes in parent mater­ ial repaired to produce equivalent horizon volumes. Procedure B 1 Per cent by weight of organic-free very fine sand In sample (from Table 2) 16.5 10.2 8.4 2 Weight in grans of lOOcc (from Table 1) 137 155 176 > 3 Grams of very fine sand per lOOec of sample (line 1 x line 2) i 22.6 15.7 14.7 4*15 4.83 4.28 .936 .759 •628 6 Per cent by weight of opaque minerals in the heavy very fine sand (Table 10) 119.3 15.9 16.2 7 Grams of heavy opaque very fine sand In lOOcc of sample (line 5 x line 6) .120 .102 833 980 4 Per cent by weight of heavy minerals in the very fine sand fraction (Table 10) !f i i 5 Grams of heavy very fine sand per lOOcc of sample (line 3 x line 4) i i i i i .181 8 Volume of soil containing i gram of heavy opaque very fine sand(l / line 7) I 9 | S C h. WEATHERING FACTOR Number of cc of parent material required to produce lcc of the present horizon i[ ! 1.77 1.18 i.oo ! 86 Table 14. Genesis of the St Glair profile, net changes being deduced from the heavy opaque very fine sand indices. Values are in grams; separates are carbon­ ate-free -weights. Fine m X-CO^ clay c^ay Silt Sand Sum** vr 61.7 94.7 79.3 91.7 11.1 23.4 73.0 38.6 50.6 71.3 6.3 53.1 310.9 135.0 174.9 312 137 175 | 41.0 63.1 52.8 61.2 48.2 60.5 48.6 36.8 -7.2 2.6 4.2 24.4 207.2 154.0 52.2 208 155 25.5 34.7 53.5 44.7 51.8 175.5 176 | Sum** vw\ A2 horizon Original weight* 45*2 Present weight 0*0 Net loss ; 45.2 i B horizon Original weight* | 30.1 Present weight 8.5 Net loss 21.6 G horizon* X*C03 SiOg FegO* AI2O3 53 1 • &2 horizon Original weight* Present weight § Net loss 45.2 0.0 45.2 213.0 312.9 100.1 15.2 5.6 9.6 27.8 9.0 18.8 301.2 127.5 173.7 3d 137 174 B horizon Original weight* Present weight Net loss 30.1 8.5 21.6 141.9 114.2 27.7 10.2 7.3 2.9 18.5 10.7 7.8 200.7 140.7 60.0 208 155 53 25.5 120.1 8.6 15.7 169.9 176 I C horizon* * Calculated weight of parent material required to produce lOOcc of the indicated horizon* Index for Ajj is 1*77; for B,1.18. ** Summation of the columns to the left* 0 Total weights calculated on the basis of the present volume weight of the C horizon. + Thft assumed parent material, used in the above calculations* 87 these changes are definite losses rather than gains. Table 14 carries these speculations a step further to show the net changes that may have brought about the evolution of the present St Clair solum. Here it is seen that both silt and sand particles in the and B horizons have diminished in size. Sand appears to have disintegrated to a greater extent than silt, in­ dicating that the ultimate grain size of the materials in question apparently falls within the silt range. Clay, and especially fine clay, constitutes the greatest loss from the A„ zone, but this does not mean that clay minerals are necessarily more sus­ ceptible to removal than carbonates which have entirely disappeared from the upper solum. Losses of clay are much greater from the Ag than from the B horizon; in fact, the loss from the A is 4 times greater than its present content, from which it is deduced that the clay now in the upper solum is not inherited from the parent material but that it has been formed in place either through syn­ thesis of decomposition products or through disintegration of larger particles. In the B horizon there has been a net increase in fine clay, a fact that might seem to support Glinka's illuviation theory. There has, however, been enough disintegration of larger particles within the B layer materials to account for this entire increase in fine clay. In this connection it is of interest to note that 88 the clay separate as a whole has shown a loss, an indication that even these small particles are undergoing a certain amount of dis­ integration and chemical attrition. Another bit of evidence is contained in Table 14 to indicate that illuviation may be responsible for some fine clay in the B horizon* This is seen in the discrepancy between the calculated loss in mass as indicated by volume weight values, and the losses obtained by adding net decreases in silica, iron, and aluminum, a difference amounting to about 7 grams. This is nearly equal to the net increase in fine clay in the B horizon, so that it may be concluded that this illuviated zone has received by translocation within the profile non-mineral clays to the extent of about 7 grams per 100 cc of volume. Field observations confirm this conclusion as far as qualitative comparisons are concerned. The ratio of silica, iron, and alumina in the calculated losses is worthy of comment because it closely resembles the ratio in which these same ingredients are found in subsurface drainage waters of this area (see Table 9). Comparing these values for the Ag and B horizons shows that initial losses of iron and alumina are relatively large. As the material becomes mor9 and more depleted in iron and alumina, silica losses appear relatively greater, perhaps because the solubility rate of silica does not decrease as rapidly as the solubilities of alumina and 89 iron, and also because silica reserves are much larger than re­ serves of the latter. Once the land surface became stabilized by a vegetational cover it is extremely unlikely that colloidal material, as such, was lost from the developing solum as a result of either lateral or vertical translocation. Evidence of the inherent stability of soil colloids is readily seen in the clearness of subsurface drain­ age waters. More probably the fine clay undergoes disintegration (in a manner similar to the larger particles) to ultimate decom­ position, after which the various components leave the soil in an ionic form. This process is naturally more rapid and more exten­ sive in the surface layers; its intensity decreases with depth al­ though chemical weathering still prevails in the B horizon. The clay of the B horizon, then, has been largely inherited from its parent material. This original clay has probably been modified by other clay formed as a result of larger particles weathering in place and possibly by additions of a more-or-less organic na­ ture carried down from the surface. It is extremely doubtful that the present B horizon is primarily a zone of illuviation, although illuviation has undoubtedly contributed to its characteristics. On the whole, the present physical nature of the B horizon has more likely been caused by a great loss of basic materials. The absence of these bases has contributed to the plastic 90 Hue ! «>* j , ^ f $ 4* H r 16 17 18 19 20 21 22 23 Hoe Figure 2* Color correlated nith chemical analysis. 91 characteristics of the inherited clay which has become more easily dispersible and therefore more subject to volume changes resulting from alternate wetting and drying. These volume changes have, in turn, promoted the development of a characteristic B horizon structure which is -also inherited from the parent material, but which has been modified by an ever-increasing number of joint cracks that form wherever a plane of weakness results. SOIL COLOR One other relationship is worthy of discussion. The data accumulated in the course of this study offers an opportunity to search for factors causing soil color differentiations. An attempt was therefore made to relate the colors to some chemical or physical attribute of the various soil materials. Early investigators in this field proved that the red hue, which was primarily of interest in this study, could be at­ tributed to iron; they also pointed out that the finer particles are of the greatest importance since it is the colloids with their immense ^covering” capacity that are responsible for the visual differentiation of horizons within the solum. Figure 2 shows the relationship or lack of relationship that exists between hue and the various ratios of iron, alumina, and silica. Of the three possible ratios only that between alumina and iron shows a significant color relationship. It is therefore concluded that the hue value, and therefore color, depends in part 92 upon the amount of replacement or adsorbed iron associated with the clay minerals. 95 CONCLUSIONS AND SUMMARY A detailed study of the physical and chemical attributes of calcareous till materials, and of certain profiles that have evolved in these materials within a rather limited geographical area, has revealed a higher degree of parent material uniformity than has commonly been attributed to glacial drift* The anomolous Napanee profile is sufficiently different from other profiles developed in this area to warrant separation as an unique series. On the other hand, the automorphic St Clair pro­ file is so similar to Miami and Isabella that a separation based only on color, particle size characteristics, and chemical con­ stituents does not appear justified. It is recognized, however, that differences in productivity, surface formation, and other field characteristics may outweigh profile similarities and that the St Clair series may therefore be justified by attributes that have not been measured or that are not measurable by existing laboratory techniques. The St Clair profile has been shown to have evolved in a rather uniformly heterogeneous parent material. On the contrary Napanee, Conover, and Brookston have developed in materials show­ ing definite dissimilarities, particularly with respect to the surface layers. An hypothesis has been advanced that these dif— 94 ferences are somewhat depositional in nature and that they may have been caused by wave action which sorted the surface layers as they emerged from the post-glacial lakes* Wave-washing is thought to have resulted not only in a lateral loss of fine materials from the topmost portions, but also in a sorting of the light and heavy minerals, thus producing both a textural and a mineralogical pro­ file before the landsurface was fully exposed to soil forming forces. In these heavy calcareous tills, soil forming processes re­ sult in the disintegration and decomposition of minerals of all sizes, accompanied by a complete removal of carbonates from the upper solum. In the so-called zone of accumulation, or illu- viated horizon, weathering and leaching are less severe but are still the dominant processes. Thus the heavy clayey character­ istics of the B horizon are not primarily caused by the deposi­ tion of clay translocated from the overlying layers; more impor­ tant is the loss of bases, complemented by apparent increases in other less soluble components of the soil mass. Horizon compari­ sons, expressed in terms of volume rather than weight, indicate that illuviation is probably not as dominant nor as effective in the formation of the Gray-Brown Podzolic profile as has commonly been supposed. 95 REFERENCES 1 Allen3 E. R« Soil Survey of U.S.D.A. Soil Survey Report County, fiMr> 1915 2 Allen, V* T. Petrographic Studies Bearing on the Genesis and Morphology of Illinois Soils Proe. 2d Inter* Cong. Soil Science 1932 3 4 Baldwin, Mark Correlation Notes (unpublished) U.S.B.A. Bur. of F.I., A.E., and Soils 1937 Boswell, P. 6 . H. On the Mineralogy of Sedimentary Rocks D.Van Nostrand Co., New York 1933 5 Bouyoucos, 6 . J. 3he Hydrometer as a New Method for the Mechanical Analysis of Soils Soil Science 23:343-350 1927 6 Bouyoucos, 6 . J. A Comparison Between the Pipette Method and the Hydrometer Method for Making Mechanical Analyses of Soil Soil Science 38:335-344 1934 7 Bouyoucos, G. J. A Sensitive hydrometer for Determining Small Amounts of Clay or Colloids in Soils Soil Science 44:245-246 1937 8 Bushnell, T. M. Soil Survey of White County, Indiana U.S.D.A. Soil Survey Report 1915 9 Caty, J. G. Some Mineralogical Characteristics of Podzols and Brown Podzolic Forest Soil Profiles Proe. Soil Sci. Soc. Amer. 6:332-354 1940 10 Carroll, Dorothy Heavy Mineral Assemblages of Soils From the Gold Fields of Western Australia Geol. Mag. 73*503-511 1938 II Carroll, Dorothy Recording the Results of Heavy Mineral Analysis Jour, Sed. Petr. 8 : 3-9 1938 12 Chandler, R. F. J. The Relation of Soil Character to Forest Growth in the Adirondack Region New York (Cornell) Agr. Exp. Sta. Ann. Rpt. 54*93-94 1941 Reconnaissance Soil Survey of Chio 23 Coffey, G. N. U.S.D.A. Soil Survey Report 1912 96 14 Cogen, W. M. Sobs Suggestions for Heavy Mineral Invest­ igations of Sediments Jour, Sed. Petr. 5 :3-8 1935 15 Deeter, E. B« et al Soil Survey of St.Clair County,Michigan U.S.D.A. Soil Survey Report 1929 16 Doeglas, D. J. The Importance of Heavy Mineral Analysis to Regional Sedimentary Petrology Rpt. Comm, on Sed., Trans. Nat. Res. Council, pp. 102-121 1940 17 Dorsey, C. W. Soil Survey of Montgomery County, Ohio U.S.D.A. Soil Survey Report 1900 18 Dryden, A. L. Accuracy in Percentage Representation of Heavy Mineral Frequencies Nat.Aead.Sci*Proc. 17:233 1931 Petrographic Methods for Soils Laboratories 19 Fry, W. H. U.S.DJU Technical Bulletin 344 1933 20 Goldman, G. H. and J. M. DallaValla AnAccurate Method for the Determination of the Components of a Heterogeneous Particle Mineral System Amor. Min. 24:40-47 1939 21 Goldrich, S. S. Journal of Geology A Study in Rode Weathering 46:17-58 1938 22 Goldthwaite, J. W. New Btmjshire 23 24 Weathered Rocks Hfcand Under Drift in Geol. Soc. Amer. Bull. 49:1183-1198 1938 Gordon, H. C. Geological Report on Sanilac County Geological Survey of Michigan 1900 Grout, F. F. Accuracy of Accessory Mineral Methods Comm. Rpt., Trans. Nat. Res. Council pp. 16-30 1937 Uniformity of the Late (bray Drift of 25 Harmer, P. M. Minnesota Doctoral Thesis, University of Minnesota 1920 26 Hart, R. Studies in the Geology and Mineralogy of Soils Jour. Agri. Science 19:90-105, 802-813 1929 The Use of Heavy Miner­ 27 Baseman, J. F. and C. S. Marshall als in Studies of the Origin and Development of Soils University of Missouri Research Bulletin 387 1945 The Value of Mineralogical 28 Hendrick, J. and G. Newlands Examination in Determining Soil types Journal of Agricultural Science 13: 1—17 1923 97 29 Hutton, J. G • Soil Colors, Hieir Nomenclature Description Proc.lst Inter.Congr.Soil Sci. 4:164-172 1927 30 Jeffries, C. D. The Mineraloglcal Composition of the Very Fine Sands of Some Pennsylvania Soils Soil Sci.43:357-1937 31 Jeffries, C • D. and J* W. “ White Some Mineralogical Char­ acteristics of Limestone Soils of Different Localities Proc. Soil Sci. Amer. 5*304-308 1940 32 Jehnsgard, G. A. A Pedological Study of a Ground Water Podzol and Some Associated Soils Master’s Hiesis, Michigan State College 1938 33 Judd, D. B. and Kelly,K. Method of Designating Colors Nat. Bur. Standards Jour. Res. 23:355-385 1939 34 Kruger, F. C. A Sedimentary and Petrographic Study of Certain Glacial Drifts of Minnesota American Jour. Science 34 s 345 3631937 35 Krynine, P. D. Glacial Sedimentation of the QuinnipiacPequabuck Lowlands in Southern Connecticut American Jour. Science 33: H I - 139 1937 36 Lamor, J. E. and R. S. Grim Heavy Minerals in Illinois Sands and Gravels of Various Ages Jour, Sed. Petr.7:781937 37 Larsen, £« S. and Berman, H. Hie Microscopic Determination of the Nonopaque Minerals Geol. Surv. Bull. 848 1934 38 Leverett, Frank Glacial Formations and Drainage Features of the Erie and Ohio Drainage Basins Geol.Surv.Mono. 1902 39 Leverett, Frank Weathering and Erosion as TimeMeasures American Jour. Science 27 (4th series) 1909 40 Leverett, Frank tions of Michigan 41 Leverett, Frank Hemisphere Surface Geology and Agricultural Condi­ Mich. Geol. and Biol. Survey 1917 Pleistocene Glaciation in the Northern Geologic Society of America 1929 42 Leverett, Frank and F. B. Taylor U* S. G. S. Monograph 53 43 McCaughey, T. J. and W. H. Fry of Soil Forming Minerals Pleistocene Glaciation 1927 Microscopic Determination U.S.D.A. Bur.Soils Bull. 91 1913 98 u McGool, M. M., J. 0. Veatch and C. H« Spurway Soil Profile Studies in Michigan Soil Science 16 s 95 - 106 1923 45 Marbut, Curtis F. Atlas of American Agriculture III Soils of Die United States U. S. D. A. 1935 46 Marshall, C. E. A Petrographic Method for the Study of Soil Formation Processes Proc.Soil Sci.Soe.Amer. 5:100-103 1940 Die Correlation of Soil 47 Marshall, C. E. and C. D. Jeffries Types and Parent Materials with Supplementary Information on Weathering Processes Proc.Soil Sci.Soc.Amer.l0:397-406 1946 48 Matelski, R. P. Heavy Mineral Investigations of Some Podzol Soil Profiles in Michigan Ph. D. Diesis M. S. C. 1947 49 Michigan Department of Health Engineering Bulletin NO. 15 Municipal Water Softening 1928 Soil Survey of Newaygo County, Michigan 50 Mick, A. H. et al U.S.D.A. Soil Survey Report (in Press) (1937) Mineralogical Composition of Diree Soil 51 Mickelson, G. A. Types . . with . . Reference to Changes . . Indicated by . . Heavy Minerals Ph. D. Thesis, Ohio State University 1943 52 Munsell, A. H. D. Van Nostrand Co. A Baltimore Color Notation 1926 A Method for Determining the Color of 53 Nickerson, Dorothy Agricultural Products U.S.D.A. Technical Bull., 154 1929 54 Qefelem, R. T. Mineralogical Study of Loess Near St.Charles, Missouri Jour. Sed. Petr. 4: 36 - 44 1934 55 O’Neal, A. M. Soil Science Die Effect of Moisture on Soil Colors 16 : 275 - 279 1923 Persistency of Heavy Minerals and 56 PettiJohn, F. J. Geologic Age Journal of Geology 49: 610 - 625 1941 Preliminary Color Standards and Color 57 Rice, T. D. et al Names for Soils TJ.S.D.A. Misc, Pub. 425 1941 58 Rittenhouse, G. Curves for Determining Probable Errors in Heavy Mineral Studies Rpt. Comm. Sed, Nat. Res. Coun. 1940 99 59 Rnbey, W. W. The Size Distribution of Heavy Minerals Within A Water-Laid Sandstone Jom. Sed, Petr. 3* 3 -29 1933 60 Shaw, C, F. Proc. Soil Sci. Soc. Amer. Soil Color Standards 2 ; 431 - 436 1937 61 Shaw, C, F. and M, Baldwin U. S. D, A, (mimeographed) Bibliography of Soil Series 1938 62 Sherman, D. G, and G. A* Thiel Dolomitization in GlacioLacustrine Silts of Lake Agassiz Geol.Soc.Amer.50:1535 1939 63 Skinner, W. W, Official and Tentative Methods of Analysis of the Official Agricultural Chemists (4th edition) 1935 Variation in the Properties of Peorian Loess 64 Smith, G, D. and Their Pedological Significance Ph.D.Thesis, U.of 1111940 65 Smithson, F. Statistical Methods in Sedimentary Petrology Geol. Mag. 76: 297 -309, 348 -359, 417 - 426 1939 66 Smithson, F. Alteration of Detrital Minerals in the Mesozoic Hocks of Yorkshire 6? Striker, M. M. 8. S. D. A. Geol. Mag. 68* 97 - 112 1941 Soil Survey of Lenawee County, Michigan SoilSurvey Report (inpublication) (1946) 68 Taylor, F. B. The Glacial and Postglacial Lakes of the Great Lakes Region 69 Smithsonian Report, pp. 291 - 321 1912 Troland, L. T. Report of Colorimetry Committee for 1920-1921 Jour. Opt. Soc. Amer. and Rev. Sci. Instr. 6*527 - 596 1922 70 Veatch, J. 0. U. S. D. A. Soil Survey of Ottawa County, Michigan SoilSurvey Report 1922 71 Veatch, J. 0. 8 . D. D. A. Soil Survey of Ingham County, Michigan SoilSurbey Report 1941 72 Veatch, J. 0. and 0. B. Winter Unpublished Notes on the Ohfflqiffia-T Analysis of Selected Michigan Profiles 1925—1935 Soil Minerals as a Check on the Wisconsin73 White, G. W. IUinoian Drift Boundary Science 79: 549 - 550 1934 74 Wilder, H. J. and Geib, W. J. 8 . S. D. A. Soil Survey Reprt Survey of the Pontaic Area 1904 100 75 WLlderinuth., R. et al Soil Survey U. S* D* A. Soil Survey Report ofVanBuren County* Michigan 1922 76 Willis, E. A., F. A. Robeson and C.M. Johnston Graphical Solution of the Data Famished by the Rydrometer Method of Analysis Public Roads 12: 208 - 215 1931 77 Wintermeyer, A. M., E. A. Willisand 1. G. Thoreen Procedures for Testing Soils for the Determination of the Subgrade Soil Constants Public Roads 12: 197 - 208 1931 101 APPENDIX I TECHNIQUE OF PHYSICAL ANALYSES It is generally recognized that an investigation into the nature and properties of soils and soil materials depends largely upon the sampling techniques employed. In the final analysis, a study is only as good as the samples on which it is based* But perhaps of more importance than mere technique is the personal concept of the investigator, -who is inescapably a victim of his own attitudes and bias* A study must therefore be evaluated pri­ marily on the basis of the investigator’s experience and object­ ivity. For this reason no involved descriptions of sampling procedures are offered. It suffices to say that profiles were selected not through any scheme of randomization, but rather be­ cause each was thought to represent a typical development in tie concept of the modern taxonomist* As a concession to statistical theories, duplicate samples were obtained in order to reveal the extent of significant variations* VOLUME "HEIGHT and POEOSITY Pits were dug to expose what were thought to be representative profiles. Within these pits hor­ izon aampifts were marked out and separated from adjacent materials by narrow trenches on all sides. Without disturbing the partial 102 monolith so formed, plaster—of—paris was poured around and over it in sufficient Quantities to provide an affective support and shield* After hardening, the block and contents were removed, inverted, and transported to the laboratory, thus assuring an undisturbed sample* Two profiles were sampled to allow dupli­ cate laboratory determinations* In the laboratory, a subsample of about 200cc was selected from each block. Prom these portions, representative structural units were chosen for drying and weighing. Oven-dry units were then immersed in melted paraffin, drained and cooled. When cool their volumes were determined by displacement in water under a vacuum to remove adsorbed air* As a check on volume weight values so determined, face* the original block was leveled on its open Then all soil was removed from the plaster-of-paris mold* The soil material was oven-dried and weighed, while the mold was measured as to volume* This procedure yielded a second volume weight value which in every sample agreed well with the first. An example of the data so obtained is tabulated below: Volume weight of the St Glair Ag horizon Sample 1 Determined from block subsample Determined from block as a whole Average Sample 2 1.378 1*366 1.382 1*357 1*372 1*369 Specific gravities were measured by means of a pycnometer, two determinations being made of each sample* Porosities were 103 then calculated using the formula Per cent porosity - loo - PARTICLE SIZE DISTRIBUTIONS " g g & y ) * 100 Accumulation curves were obtained on duplicate samples of each horizon in the several profiles by the Bouyoucos hydrometer method (5, 6, 7), modified in minor details by subsequent Investigators (79; 77} • Sedimentation temp­ eratures were controlled by a constant water bath. Sodium oxalate was used as a dispersant in order to avoid carbonate losses, The resulting accumulation curves were graphically analyzed and supplemented by additional measurements obtained by fractioning coarse sediments with an automatic vertical type seive. Hie data were then converted to an oven-dry basis and organized as Table 2. Early investigators apparently gave liitle thought to the fact that calcite and dolomite, although they have disappeared from the upper solum, constitute a rather large proportion of the Gray-Brown Podzolic parent materials. In order to discover the particle size distribution of these carbonate minerals, aliquot portions of sand and silts weretreated with HC1 and boiled until effervescence ceased. dried and weighed. Hie residue was washed several times, then From these values the amount of carbonate s-h-ing as d a y was calculated. grated into Table 3» These results have been inte­ 104 Despite the quantitative nature of the foregoing determin­ ations , it is felt that their accuracy is as great as is justified by the sampling techniques. The soils in question are character­ ized by relative uniform particle size distributions. The fact that their summation curves do not exhibit sharp breaks aliens the assumption that hydrometer readings represent points rather than portions of the curve. Although more accurately expressed in the form of settling velocity curves, the data have been calculated to conventional size-frequency distribution classes, -which are more readily interpreted. It should be noted that the fine clay class in particular is subject to erroneous interpretation; it is con­ sidered sufficiently valid, however, to permit comparisons between the several soils in this study. COLOR Nickerson (53) has rather completely described the theory and application of the Maxnell-MunseU color system to this type of investigation. The following remarks are therefore confined to the adaptations that proved necessary in the course of the -work. Samples were prepared by lightly crushing soil structural units until they passed through a 20—mesh screen. This crushed material was then mounted on a gray cardboard disk, to the back of which was affixed a rubber stopper# Die mounting was accomplished by sprinkling the soil in wet rubber cement. A small electric fan motor was used to rotate this soil color disk, to which it was 105 attached by slipping the rotor shaft into a slightly under-sized hole in the afore-mentioned stopper* The purpose of rotating color samples is to eliminate surface shadows which otherwise obscure the surface* A rapidly rotating color disk presents a smooth texture to the observer* In thus el-i-mina-tring structural factors, an unknown color can be matched with a high degree of accuracy* Using these mounted samples, soil eolors were matched with four standard colors of known hue, brilliance, and chroma. Stand­ ard colors were in the form of circular disks slotted radially so that all four slipped together with a portion of each showing. Exposed areas were measured in terms of angular percentages by means of a graduated circular base. Major sources of error in this technique arise from differ­ ences of lighting and viewing. In this investigation good natur­ al daylight was available in a laboratory generously supplied with skylights. In order to minimize day-to-day variations, a complete series of samples were mounted and otherwise prepared so that actual matching might be accomplished in a minimum of time. The viewing angle was fixed by employing an improvised screen of neutral gray cardboard and a headrest} matching was done by view­ ing the juxtaposed rotating disks through small windows in the cardboard screen which also served to block out distracting fact­ ors. Six 2-hour periods were required to make the necessary 106 adjustments and readings. In order to insure equal light from period to period, a Weston photographic lightmeter was used to measure light intensities at the sere® surface. Colors were matched only under similar conditions of light intensities. The results of this analysis are presented in Table 4. APPENDIX II TECHNIQUE OF CHEMICAL ANALYSES Samples for the total chemical comparisons were set aside from the original samples described in Appendix I. Two hundred grams were allotted for determinations of the bulky constituents, and the sands from the mechanical analyses were saved for petrographic examination. TOTAL CHEMICAL ANALYSIS* The official and tentative procedures Association of Official Agricultural Chemists (63) was followed as a guide. Some departures, however, were made in order to adapt the various methods to the materials and equipment at hand. * A brief description of the analysis is here set down This work was suggested and guided by Dr. D. G. Sherman. 107 because of its simplicity and fundamental soundness. All deter­ minations were made in duplicate and their averages recorded in Table 5. Preparation of the Sample About 30 grams of sample were ground and mixed in an agate mortar. Two 5 gram subsaraples from this lot were used to determine hygroscopic moisture so that the ensuing data might be reduced to an oven-dry basis. Fusion Approximately 1 gram of the above was weighed on a scoop and transferred to a lOOcc nickel crucible. mixed 1 gram of sodium peroxide. To it was .added and The mixture was cautiously heated over a Fisher burner until the fusion had quieted. Then about 5 grans of sodium hydroxide were melted into it, the cru­ cible being heated to a barely perceptible redness and slowly rotated. After cooling the fusion was dissolved in water and transferred to a large porcelain casserole. Beterwd nation of na. The contents of the casserole were evaporated to dryness, cooled, and dissolved in absolute methyl alcohol. After several re-evaporations in alcohol, the residue was acidified and filtered through Whatman No.40 paper. Die filt­ rate was returned to the original casserole and again dehydrated with alcohol, thenacidified and filtered. ected in a beaker and set aside. The filtrate was coll­ 108 Hie silica bearing filters from the above procedure were carefully dried and charred in a muffle furnace* Then they were ignited for 30 minutes, cooled, and weighed. After re-ignition to a constant weight, the impurities were determined by solving the silica with hydrofluric acid. dis­ The residue was ig­ nited to a constant weight, and the difference between the two weights was assumed to be silica. The impurities from above were fused with a few crystals of potassium bisulfate, then dissolved in water and returned to the main filtrate. Determination of Aluminum The aluminum in this filtrate was separated by precipitating all other cations with a solution of sodium-hydroxide-carbonate. The aluminum remained in solution as sodium aluminate. The filtrate was decanted and acidified with concentrated HG1 using phenol red as an indicator. The solution was then boiled to expel COg and the pH adjusted to 7*5 with con­ centrated HH^OH. After digestion on a hot plate, the granular Al(OH)^ precipitate was separated with a Miatman N0.31 filter. The filtrate was discarded. The precipitate was dissolved and re-precipitated, then washed free of chlorides and ignited to a constant weight. The hygroscopicity of the aluminum oxide was troublesome so that the crucible had to be kept covered* 109 Determination of Iron Die precipitate separated from the sod­ ium aluminate -was dissolved -with hot HC1 and diluted to 200cc . The iron was then precipitated with NH^OH using bromthymol blue as an indicator. calcium. The filtrate was set aside for separation of The precipitate was taken up with hpt sulfuric acid and the iron determined by reduction to the ferrous state and titra­ tion with potassium permanganate. Reduction was accomplished by neutralizing with concentrated ammonia almost to the point of precipitation. The solution was heated to boiling and then am­ monium bisulfite added. Determination of Calcium The filtrate from above was heated and the calcium precipitated with ammonium oxalate. Because of the presence of large quantities of sodium salts a double precipit­ ation was considered necessaiy. After re-igniting to redness in a muffle furnace, the residue was dissolved in acetic acid. Re­ precipitated with ammonium oxalate, the quantity of calcium pre­ sent was determined by titration with potassium permanganate to a faint persistant pink. Deternn on of Mapnaajnm The filtrate from the calcium pro­ cedure was treated with di—ammonium phosphate which precipitates the magnesium as • 'Die latter salt is separated by a TShatman No.40 filter and ignited at a high heat for 30 minutes. The factor 0.3621 is used to obtain the weight of MgO from the weighed precipitate. no DeteiMnation of COg Carbonate COg was determined by treating a known sample of soil with 1 s 1 HC1, boiling the mixture to assure the reaction of dolomitic carbonates, and passing the gases which were evolved through ascarite adsorption bulbs. The increase in weight of the ascarite was reported as COj . MIHERALOGICAL ANALYSIS Petrographic studies were confined to the vezy fine sand fractions obtained from mechanical analyses. The very fine sand fraction was first separated into light and heavy fractions by means of a heavy liquid, S.tetrabromethane and nitrobenzene, adjusted to a specific gravity of 2.90. These fractions were first studied in an exploratory manner to discover what mineral species constituted the bulk of the mater­ ial. Counts were then made of the principal species in an attest to reveal essential similarities and dissimilarities. To accomplish the separation of the light and heavy miner­ als, about 2 grams of each sample were placed in a small centri­ fuge tube containing the heavy liquid. These were centrifuged for three 30-minute periods, each following a vigorous stirring of the supernatant liquid. The light minerals were decanted and the heavy fraction was transferred to a small casserole. Both fractions were washed with acetone, dried and weighed. The fractions were then spread on gelatinized slides to per­ mit the changing of immersion liquids without washing off and Ill losing the particles.* Microscopic studies of refractive indices, pleochroism, extinction angles, color, and shape were an used in identifying the various mineral species. The standard tables of Larsen and Berman (37) were employed as a reference. The results of this study are presented in Table 10. * A procedure suggested by Dr. John Young, formerly of the Geol­ ogy Department at Michigan State College, and since described by Marshall and Jeffries (47). 112 APPENDIX I H TAXGNQMI and DESCRIPTIVE LEGEND Although the following legend illustrates the general rela­ tionships between the many series depicted in Map; 3, it is empha­ sized that there is seldom a single differentiating characteristic between any two series, even when comparing, for example, such closely related units as members of the same catena. The charact­ eristics listed in the legend and the differences outlined in the key are believed, however, to constitute the principal criteria for pragmatic identification and differentiation of the various soil entities which are associated with the profiles discussed in the foregoing study. A valid appreciation of the selected pro­ files is difficult to attain without an understanding of the landscape in which they exist, ond of which they form an integral part. This appendix and supplemental map are designed to present a descrip­ tion of that landscape, and to provide a brief but systematic morphological outline of the taxonomic units comprising the land. SLOPE and RELIEF A landscape cannot be adequately described with­ out soma mention of the attitude of the land surface# The areal concept of taxonomic entities recognizes that each unit is characterized by distinctive slope gradients. For example, in the landscape under study, the Hennepin series attains 113 its typical development on steep slopes* At the other extreme are the hydromorphic series, confined to 1-anH surfaces with a nd.ni.Tm2m of gradient* All studies of this nature are founded principally on practical considerations^ hence, slope descriptions and classifications are determined by their applied a-ignifif»anr*gt In this study, five slope classes were defined, each designated by a capital letter, as shown in the following table: Surface texture Slope classes and their limits in per cent A B C D Sands, loamy sands, sandy loams, and 0 - 3 light loams 3-8 8-15 Heavy loams, silt loams, silty clay 0 - 2 loams, clay loams 2 - 6 6 - 10 10 - 20 15-25 E Over 25 Over 20 All property defined taxonomic units possess characteristics falling within a single slope class. Although some series may hare included two or more of the above classes within their normal gra­ dient range, a type is usually limited to a single slope class. A particular slope class is therefore regarded as normal for a given type, and in field mapping the normal slope sign is generally omitted from identifying symbols. For*example, the Hennepin series is defined as developing only on steep slopesj areas identified by the symbol «6“ are therefore not modified by an "E" because gradi­ ents over 20% are normal for the Hennepin soils. In some places, 114 however, a typical St Clair profile is found on steep slopes; these areas are identified by the symbol ,,14E lf since steeply wg sur­ faces are abnormal for this series. EROSION Compared with the recognition and definition of slope classes, a precise description and delineation of the work of accelerated erosion is a difficult task. Phases resulting from erosion cannot be defined in terms that are applicable to »n parts of the country, or even to all types of soil. The number of erosion phases recognized, and the degree of refinement of their definitions depaid largely on the objectives of the mapping and the scale employed. In this study, three general classes were defined, primarily on the basis of profile completeness. These classes were not, how­ ever, defined mathematically in terms of soil losses because the significance of erosion mnst be evaluated in relation to other factors, including the nature of the profile and the associated slopes. Because the greater part of the land surface in the selected area displayed little or no evidence of destruction by accelerated erosion, this condition was accepted as normal and has not been identified by a special symbol, inhere erosion symbols are lacking, therefore, the land has not been sufficiently altered to require changes in current management practices, nor are special practices 115 required to prevent serious erosion losses* Land that has suffered recognizable erosion to such a degree that the thickness of the surface layers has been significantly reduced has been identified as an eroded phase” indicated by the symbol “I”* The productivity of this land has been reduced, part­ icularly with respect to crops ordinarily grown on uneroded soil* Erosion has not yet, however, forced an abandonment of the land. To restore and maintain the land productivity at its original level requires a change in management practices, and possibly the adoption of special methods. Ihere the surface layers have been totally lost through ero­ sion a "severely eroded phase” has been recognized and designated by the symbol ”2”. Hie productivity of such land has been so re­ duced that it is of no longer any agricultural value. Gullies are conspicuous features of this phase, which is confined to steep slopes. USE of SYMBOLS In order to abbreviate field notes, landscape features are indicated on the maps by means of symbols which, in turn, show the soil type, slope class, and ero­ sion phase. Each bounded area on the map is described by means of a combination of these three symbols. If erosion is not extreme in a delineated area, no erosion symbol follows the slope letter. In other words, the soil symbol 116 or soil and slope symbol, standing alone shows that the area has not been eroded* If an eroded phase is indicated, the appropriate, number is separated from the soil number by a slope letter, even though the slope of the particular area is normal for the given soil* The symbol *t12G2tt is an example* It shows that a delineated area is dominated by Conover silt loam* by slopes varying between 6 and 12$ in gradient, and that the area is so severely eroded that the 5 horizon is at or near the land surface* The symbol ”4M alone in an area indicates that it is dominated by St Clair silt loam, by surfaces varying in gradient from 2 to 6$, and that erosion has been insignificant. KEY to the SOIL TYPES The primary criterion in separating the soils of this area is that of topographic position* On this basis, all series are divided into two large groups — — those found on morainic uplands, and those found on plains. A few units are encountered in both land­ scapes and are so listed in both groups* Subgroups, classes, series, and types are separated wherever possible on the basis of inherent characteristics, rather than on superficial attributes. Hie symbol and normal gradient are indicated for each type* 117 UPLAND SOILS generally developed in morainic materials. Th** i«n^ surface is undulating or hilly, in a feu* places ksamic and rough. Surface features are constructional, existing in the same forms as when they emerged during the recession of the last ice—sheet. In some places stream cutting has slightly morH fMtarf sur­ face features. Three subgroups are recognized, on the basis of internal aeration. Well-drained # series are characterized by light brown surface lay­ ers containing small quantities of organic matter. Subsoils are bright, rather than drab, in color and exhibit conspic­ uous eluviated and illuviated horizons • • • • See A Tmperfectlv-rf^flimad • series possess gray or brownish-gray surface layers containing moderate quantities of organic matter. The development of a zonal profile has been impeded by ground­ water fluctuations at or near the surface. Subsoils are in some places drab and in other places bright although mottling, indueed by protracted periods of anaerobic conditions, is general. Eluviated and illuviated horizons are present but See B not conspicuous........................ * Poorly-drained + series have dark gray surface layers, containing much organic matter. Subsoils are mottled and waterlogged. Glei is often conspicuous See C PLAIN SOILS developed in lacustrine materials, lake-laid till, outwash, and sandy lake plains, the latter commonly underlaid by calcareous lacustrine or till clay at varying depths. X,and surfaces are plain—likej that is, they are flat or smoothly tmrivnnt.-jngj occasionally level, with various modifications in the form of micro—relief features* Surfaces are largely construction­ al, ai some areas have been modified by stream dissection. As in the above group of Upland Soils, three subgroups are found. The characteristics of the following subgroups are identical to those described above and are therefore not repeated below. Well-drained................................ * •* S®6 D Imperfectly-drained See B . . . . • • • • * • Poorly-drained........................... * Automorphic, and zonal. °f$rdroperiodic. +I^dromorphic. See f A ifcland •well-drained soils are divided, on the basis of their texture and content of calcar** eons materials, into three groups* Each of these is subdivided into series and types. 118 51 n\ vO cn <»\<*\ A o H d di'-' »H4> © 4S©' M vi O ©H hU A 3 3 ;6 O O I& I i CO io p a oj o oo ra I I X S!8 <0 © *g § >■9 P iO H ‘j' H »© rt4» ^03 HH © 1 * 1 o 18 s o © .gijn £ o •ri b © O_ P i 3 ©ffl •» o ri O O n fgii8 © © Is § s l u03 © Cl ^0 n § 0 0 )0 • §*.$ 03 H _ 1 M M b ffl © © © P O .3 g i© J O H g* © “ -p © J§ © CO &m § o 0 o © £ J* m w o j} • p * O P H P © © *ri ffl a t f8 t den o © ©p .p n © *3 © © 5 J M ^ ill 1d o till o o © © rQ £ © a . § o © 5 iffif g *Q O t0 ra s f $ ^ SI <61 f 03 CO W © CO I . °* b p ffl o o ©• § © g>*g n 5 o t> © H O HO fl* H ffl ffl O gla| r * 3. S h jg © to f ©flHO © ow d M _. § *3 S ^ s,3 a o O (0 © O CO © ■g co © 0 O 03 03 0 ti n 5 ijl & 5) °•I3 WfiS ib ©b m •© d* sa.. 1 ©5 ffl-PS fflo b &V So g e Upland are subdivided int© series and types on the "basis of the relat­ ive quantities and condition of the organic matter in the surface layers • 119 cfg g jgg O' O' O' 3 ^ 3 S3 ra g 1 ,3 © 09 o o 05 »P« S 5 5 i ra o fc s i 3 ° g a d d j ra rah rl g -p ra I « o o .rB a aft •SMQ_ II Hra Hra Jp4 o SS oo If ss 0 H H '$3 •» m ra ra g gg p p p 11 ra ra ra MMM £5 o oo gm g g rm %l r * ( m “ pt H a a Q O ■P -P £ •§» •»o ». l b , 1 £ ® ■P T" .8i5£ ra ra^ SL rN n ■P d H h lijl Ilf • b ® ra ffl B erf Pi ® ffl SB © Sr* & § i l l r-1 I 3 I 1J* I b -P B B ra f l O O g ,o § b® u o * to a5 00 ® I d • 8 E *ra 9 ra I I ® ad1 gf d a qd ra I 1!ra o d ® ©^ ra m o _ P 'o ■OH® ra*ol S 5 h ra o ra Il>f o ® Z) &O O£ tSi T s 2 ra d 1 o H P 3 •P •P ..ill ®.Q-g M •p [J O B d ra 8 ■9p o & 3 cm &® ra ra ra o d ooo 00 . HH © d n •§ ra ra p B o ® © HH & S roa ro-a © «} *§% w ca ra ° 120 Mi $ 33 C O O v 0 •s $ ■A ■Xi t § to w a f r t eg § J2j S25 S 4 3 ra to 49 3 o tn ra S I D o ra o I ra & o ^ 2 H as ra S* id • vl n m *2 ■ H w) .?i3 ’3 * ° 1 ra3o 1® _ &7 r aa 3 Is 2 t O o ra ra •co h p f c afl «i o fo o * F gl OOffl w '.© O 2 ra fl ffl po o .fl o . ra ra o *3 ra J-S ra ra *& 32 I 4 II II S? 3 ,£} W i* P 151 § ra ■3a ra*h •H I' O •V 8 i O i A £ *3 $ a a <8 tt e rO a xt fl M® ■3 *H ffl ra 1 a& I •P a® a Si •48 ra ffl § o •3 8 u ra o to »d r? q Sfl 0) ® ran o o o P UJZrato rax & § :§ & !§ w 121 I co 05 g inmin H t ra I as few 4 8■p o ra *8-8 •o3 £8 6h m H •P ra Q ^3 r3 ra ra 0) g ■fr ra o fiH «•§ 410§ c 3 •H o *H H 1| n ,dk * § 1 ^ 8 r fa l 0.0 J3 ffl*rpa ra o n ra w W ra S 1 ra-qf eo ra o ra ara*rasrs a S> p* CD CO TO p * 1 * 3 t $ w 4 & ra43 ra^9 t» i? ra 2 • ra ra « ! i ? s go j i •p ■8 ra $ 4 ra * *w •f§l ^•S'H'd'a t h r od r* ajrqa p H o o ta to* 0 3 't,£| M 4o > b fl H o • H a r a g m 0H 0o ra n o A ra fl 09 ■r8a . t n u m sg^“ d g f f S M 8‘1 ’S ra g£-3££ %ra oU .00 > I r j j l Pi ra fl o O 0 ! 3 ! 122 PROFILE DESCRIPTIONS In the following pages are described in alphabetical order the various series encountered in the areaunder study. Here are presented, in outline form, the identifying characteristics of each series, the description of a typical profile, and other in­ formation necessary in identifying and delineating each soil in the field.* ALLENDALE includes the ground-water podzols in southern Mich­ igan which developed in a thin layer of sands or sandy materials overlying olay to a depth of 3 feet. The react­ ion of the overlying sand is acid while that of the clay is neutral or slightly alkaline. These soils somewhat resemble the Saugatuck series but they are, on the whole, better drained. The B horizon in the Allendale is less firm and more fragmentary, and the clay is nearer the surface than in the Saugatuck. Profile description of Allendale fine sandy loam: 1. Forest litter and raw humus to a maximum thickness of 3 inches. 2. Dark gray single-grained fine sandy loam about 1 inch thick. 3. Gray or very light; gray loamy fine sand or fine sandy loam 5 to 10 inches thick. 4. Rusty reddish-brown fine sandy loam containing organic matter, to a maximum thickness of 10 inches. 5. Gray sand less than 4 feet thick. 6. Moderately calcareous clay till. Variations * In drainage and thickness of the various horizons. These descriptions were assembled in the course of making a soil survey ©f Sanilac County, Michigan, a project sponsored. and financed jointly by the United States Department of Agri­ culture and the Michigan Agricultural Experiment Station. 123 Topography Undulating or gently rolling plains. Drainage Good except periods of heavy rainfall when the subsoil may become temporarily water-logged because of the slow percolation through the underlying clay till. Natural Vegetation Elm, ash, and white oak with scattered white pine. Second growth is dominated by aspen. Use About 75% is clared and grows corn, hay, oats, for dairying. Moderately productive. Distribution Michigan, Wisconsin, New York, and Northern Indiana. Type Location Ottawa County, Michigan. Series Established Map Symbol ARENAC pasture Ottawa County, Michigan, 1922. 42(sepia) soils are podzols developed in non-canformimg sands over clay. Northern equivalent of Allendale. Profile description of Arenac loamy sand: 1. Brown humus covered by 2 or 3 inches of forest litter. 2. Leached, stronly acid light gray loamy sand 4 to 8 inches thick. In places, a definite lavender tint is perceptible in the color of this A2 layer. 3. Yellowish-brown medium to strongly acid loamy sand 12 to 15 inches thick. 4. Six to 8 inches of mixed yellow fane sand and loamy sand, medium acid in reaction. 5. One to 3 feet of yellow, strongly mottled acid sand. 6. Water- or ice-laid calcareous till. Variations In thickness of layers and depth to underlying till which lies at depths of 3 to 5 feet below the surface. Topography Drainage Undulating or gently rolling plains. Externally good, internally poor or fair. Natural Vegetation White pine, oak, aspen, and birch. 124 Use Undulating land is usually pastured or cropped to com, beans, bay, and grains* Ridges are pastured or are used for building sites* Distribution Northern and central Michigan. Type Location Bay County, Michigan. Series Established Map Symbol Bay County, Michigan, 1931. 43, 44 (terra cotta). BELLEFONTAINE consists of several zonal types developed in gravelly moraines, kames, and eskers. Profile description of Bellefontaine sandy loam: 1* A thin layer of forest litter and mould. 2* Sligjhtly acid loamy sand containing rather large quantities of finely divided organic materials. One to 3 inches thick. 3* Light gray loamy sand, acid in reaction, platy in structure, and 1 to 2 inches thick. 4* Slightly aeid yellowish-brown sandy loam to a depth of 2^- x>r 3 feet. 5. An extrenely irregular, discontinuous red sandy clay or reddis-brown sticky gravel, averaging 4 to 10 inches in thickness. This is the B horizon. 6. Crossbedded calcareous sands and gravels. ’ Variations Chiefly in depth to the gravelly substrata and in the ~ occurranee of deep sand pockets. The B horizon exhibits a high degree of variability in thickness, color, and depth. Topography Drainage Generally hilly, in places rough and kamic. Good to excessive, both internally and externally. Natural Vegetation Use Oaks and scattered pine. Pasture, small grains, and formerly for some fruit (apples)• Distribution Type Location Morainic and kamic areas of the Lake States. Ohio 125 Series Established Map Symbol BRADY Ohio, 1912. 3 (red). includes hydromorphic soils developed in gravelly parent materials. It is the poorly drained series of the FoxOshtemo catena. Profile description of Brady sandy loams 1. One to 3 inches of forrest litter and mould. 2. Dark gray friable 3andy loam 6 to 8 inches thick and neu­ tral in reaction. 3. Gray waterlogged gravels, in some places calcareous. 4. Till, very impervious to water movements. Variations The substrata may contain sand and clay, and may ex­ hibit a yellowish or brownish color. Topography Drainage Low flat wet plains. Poor. Vegetation Use Sometimes marshy. Elm, ash, silver maple, arbor vitae. A good general farming soil when drained. Supports only pasture or brush when undrained. Distribution Lake States. Type Location Kalamazoo County, Michigan. Series Established Map Symbol BROOKSTON Kalamazoo County, Michigan, 1922. 88 (sepia) includes the heavy-textured hydromorphic soils devel­ oped on lake plains, till plains, and in shallow,flat depressions in moraines. Profile description of Brookston silt loam: 1. Dark gray or black litter and mould, lto 2 inches thick, 12§ and neutral to slightly alkaline in reaction. 2. Light gray very fine sandy loam or silt loam, 3 to 5 inches thick, and more acid than the overlying mould. 3. Mottled gray -waterlogged silt or silt loam 5 to 7 inches thick. 4. Brightly mottles clay loam or clay, very plastic and com­ pact in structure. 5* Mottled silty clay or clay, alkaline in reaction. 6. Plastic calcareous clay till or lacustrine clays. Variations The depth, color, and reaction of the surface layers and the intensity of the subsoil mottling all vary. Topography Drainage Plat, usually level. Poor. Vegetation Use Elm, ash, silver maple, and hickory. When undrained, the chief erops are timothy, clover, mixed hay, and pasture. After artificial drainage, large yields of beets, beans, corn, and grains are obtained. Distribution Southern Michigan, Ohio, and Indiana. Type Location White County, Indiana. Series Established Map Symbol BURNED MUCK White County, Indiana, 1915. 8, 18, 28 (green). is a transitory condition large enough in area to warrant separation. The soil xs the result of overdraining flTid later burning extensive areas of org­ anic materials. Profile description of burned muck over clay: 1. A layer of ashy material of varying depth. Red in color, it been observed as much as 24 inches thick but generally does not exceed 1 or 2 inches. It is highly alkaline and effervesces freely when treated with acid. Some sand, glei, and unburned muck may be admixed. 2. Intense blue-gray plastic clay (glei). 127 Variations Even where undisturbed the condition persists only for a few decades* The tendency is towards degradation to a Brookston or Clyde-like profile* Cultivation greatly hastens this change* But even under cultivation the pecul­ iar blue-gray color persists in the surface "which, despite an admixture of plastic subsoil, remains friable air* quite easily worked# The ashy layer may be underlain by sand, marly, muck, or peat* Topography Level low-lying plains with abrupt micro-relief features caused by unequal surface burning* Drainage Poor, but not as impeded as in the original materials* Natural Vegetation Use Brushy aspen thickets, grasses, rank weeds* Grows good beets* The original surface was sometimes burned deliberately in order to increase beet yields* Distribution Lake plains of Michigan* Type location Near Capac, Michigan* Series Established Map Symbol CARLISLE St* Clair County, Michigan, 1929* 15, 150, 161, 60 (neutral)* is a well-decomposed, black, granular organio soil de­ rived from woody materials* It occurs in wet depres­ sions, filled-in lake beds, and wet plains* Profile description of Carlisle muck: 1* Dark brownish-black or black granular muck, neutral in re­ action, containing less than 12/0 of admixed mineral materials* 2* Less well decomposed brown peat and muck with a depth of more than 4 feet* Variations Individual areas are generally uniform except in depth# Some variation is seen in the extent of decomposition* Topography Plat and level* Drainage Poor* Undrained areas are covered with water for most of the year* 128 Natural vegetation Use Hardwoods* Drained areas produce good yields of beets, com, mint and assorted truck* Distribution Southern Michigan* Type location Ingham County, Michigan* Series established Map Symbol COLOMA Livingston County, Michigan, 1923* 10, 20(Gray)* developed in glacial till materials originating from sand­ stones and are thus dominated by quartz sand* Profile description of Coloma loamy sands 1* Forest litter with a maximum thickness of about 2 inches* 2* Grayish-brown loamy sand acid in reaction and about 3 inches thick* 3* Yellow to light yellowish-brown compact, acid sands* 4* Yellowish-brown or reddish-brown loose, acid sandy materials* 5* Yellow or gray sandy glacial till* Variations A few areas are gravelly and there is some variation in the color of the subsoil horizons because of differences in the degree of hydration of the occluded iron oxides* Topography Undulating to hilly* Vegetation Scattered deciduous forest dominated by oak* Use Largely cut-over pasture and waste land, locally planted tn small fruits* grapes, peaches, and special crops* Djstribution On sandy glacial till from Minnesota to New England* Type location Kent County, Michigan* Series established Map symbol 35 Waushara County, Wisconsin, 1909* (orange;* 129 CONOVER includes imperfectly drained soils in both the Miami and Hillsdale catenas that are intermediate in drain­ age condition between the automorphic and hydromorphic series* They develop in caloareous glacial till* Profile description of Conover loam: 1* Dark brownish-gray granular loam containing a high percent­ age of organic matter* medium to slightly acid* and 1 to 3 inches thick* 2* Brownish-gray friable loam* dark grayish-brown in color with a moderately developed phylliform structure* medium to strongly acid in reaction and 5 to 8 inches in thickness* 3* Light gray loam conspicuous with yellowish-brown mottling; exhibits a phylliform structure, strongly acid in reaction and 6 to 10 inches thick* 4* Tough, sticky clay loam* Heavily mottled with gray in the upper layers but almost completely brown at greater depths* 5* Grayish-brown friable calcareous loam grading into calcar­ eous glacial till at a depth of 3 or 4 feet* Variations Chiefly in color of the surface layers* Topography Nearly level to gently undulating* Drainage Vegetation Use Imperfect* Mixed forest, chiefly deciduous* Cultivated, producing medium to high yields of com, small grain, and hay* Distribution Northern Ohio and Indiana, and southern and central Michigan* Type location St* Joseph County, Michigan* Series established Miami County, Ohio, 1916* Map symbol (brown)* CLYDE 12, 22 * is a hydromorphic series similar to Brookston but contain­ ing a higher proportion of organic matter* These soils are dark gray or black and are characterized by deep sur­ face layers* Calcareous materials are encountered at 20 to 30 inches* 130 Profile description of Clyde loams 1* The cultivated layer is black granular loam, slightly acid t© slightly alkaline in reaction# 2# Gray plastic glei ranging in depth from 15 to 20 inches be­ low the surface and from 4 to 6 inches in thickness# 5# Mottled plastic gritty clay# 4# Calcareous or gritty clay at 20 to 50 inches# Variations This series represents transitional conditions bet­ ween Brookston on one extreme and shallow-phase muck on the other# Topography Drainage Flat low clay plains# Poor, both internally and externally# Natural vegetation Use Elm, ash, oak, willow, alders# Produces high yields of beans and beets# Distribution Plains of Michigan, Ohio, and Indiana# Type location Indiana# Series established Map symbol EASTPORT 9 Allegan County, Michigan, 1901# (bluej# consists of immature asonal soils developing in rec­ ently deposited sandy parent materials of the present lake beaches# Profile description of Eastport sands 1# One to 2 inches of yellow sand containing admixed undecomp­ osed organic matter# 2# Uniform yellowish sand, with no texture, color, or structure profile# Variations Gravel and day inclusions# Topography Undulating and broken ridges, with dune-like features# Drainage Good# 131 Vegetation Pse A few shrubs, oaks, and grasses. Recreation, resort sites. Distribution Beaches of the Lake States. Type Location Bay County, Michigan. Series Established Map Symbol FOX Bay County, Michigan, 1926. 75 (yellow)• is mapped on deep gravelly outwash plains in the Podzolic and Gray-Brown Podzolic regions. Profile description of Pox sandy loam: 1. One to 2 inches of forest litter and mould. 2. A thin layer of sandy loam humus soil, neutral to slightly acid in reaction. 3. Grayish-yellow loamy sand with a platy structure. Slightly acid to neutral in reaction, and 6 to 8 inches thick. 4. Ten to 12 inches of yellowish-brown, compact sandy loam. 5. Reddish-brown, sticky clayey sand and gravel from 4 to 10 inches thick. Very irregylar in depth. 6. Crossbedded calcareous sands and gravels. Variations Relatively uniform except for the development of the B horizon which reflects, in an exaggerated manner, slight differences in the texfcure, mineral content, and internal drainage of the parent material. Topography Drainage Plat to gently undulating. Good. Vegetation Use Oak, and red and white pine. General farming. Distribution Type location Lake States. Berrien County, Michigan. Series Established Columbia County, Wisconsin, 1911. 132 GENESEE includes "the alluvial soils on natural levees and first benches above the stream level* Profile description of Genesee sandy loams 1* Surface is light grayish brown or reddish-brown unconsolid­ ated sandy loam slightly aoid to neutral in reaction. 2. Subsoil and substrata are stratified sands and silts, yel­ lowish-brown in color, and slightly acid to neutral in re­ action. Tariations Chiefly in texture. Topography Level, but with a rough micro-relief. Generally separated from other soils by steep, stream-cut slopes. Drainage Imperfect to good. Natural vegetation Pse Hardwoods, hemlock, sycamore. Pasture; areas are too small, irregular, and isolated for cultivation. Distribution Azonal Type location Livingston County, New York. Series established Map symbol GILFORD 91 Livingston County, New York, 1908. (asurej. is a hydromorphic series developed in gravelly mater­ ials. It therefore is associated with the Fox and Oshtemo soils as the poorly drained member of the catena. Profile description of Gilford sandy loam. 1. A 1 to 2 inch layer of forest litter and mould. 2. 2 to 3 inches of humus soil, loam in texture, grayishbrown in color, and neutral to slightly alkaline in reaction* 3. A light gray sandy loam layer, acid in reaction and 2 or 3 inches thick. 4. Yellowish-gray or brownish-gray sandy loam grading into the underlying layer. 5. Crossbedded , stratified, waterlogged gravels and sands at depths between lg and 3 feet below the surface. 133 Chiefly in the depth to the gravelly subsoil and in internal drainage. The amount of gravel in the surface, and the color of the surface layers, also vary. £°E?ffia3?ky Low gravelly outwash plains, and depressions associated with the Pox and Oshtemo soils. Drainage Poor, internally and externally. Vegetation ?8g. Lone pine*flm and ash. General farming, the chief crops being corn, grain, and pasture. Distribution Lake States. Type location Tuscola County, Michigan. Series Estalbished Map Symbol GRANBY Tuscola County, 1938 89 (olive green). includes the hydromorphie members of catenas formed in deep sandy smears over clay. This series is found in association with the Arenac and Plainfield. Profile description of Granby sandy loam: 1. One to 2 inches of litter and leaf mould. 2. Two to 6 inches of humus soil containing ahigh proportion of finely divided organic matter. This layer is friable, black in color, and neutral in reaction. 3. Three to 6 inches of ligxt gray, harsh, loamy sand, slightly acid in reaction. 4. Dingy gray or brownish-gray loamy sand, 4 to 8 inches thick. 5. Gray waterlogged sand to depths of over 40 inches. This sub­ soil is generally alkaline although not necessarily calcar­ eous. Variations The surface may appear quite mucky. Topography Low, flat sandy plains and depressions in sandy hills. Drainage Poor. Natural vegetation Arbor vitae, willow, alder, aspen. 134 Ifg General faming, chiefly in pasture# Distribution Lake plains of Michigan Type locations Oswego County, New York. Series established Map symbol GRIFFIN Oswego County, New York, 1917. 57, 58 (olive green). include the poorly-drained alluvial soils of the first bottoms and flood plains in stream valleys. Profile description of Griffin silt loam; 1. Dark grayish-brown or brownish-gray finely granular silt loam, neutral to alkaline in reaction. 2. Stratified fine sands, silts and clays, dark in color, mot­ tled, and often calcareous. Variations The texture is seldom uniform. Topography Drainage Level with undulating or bumpy micro-relief. Imperfect to poor. Natural vegetation Use Elm, ash, maple, sycamore, basswood. Chiefly pasture because of the susceptibility of flooding. Distribution Type location Widespread throughout the United States (Azonalj. Posey County, Indiana Series established HENNEPIN Posey County, Indiana, 1902. well-drained, redaina-like soils developed on steep, stream-out slopes associated with the St. Clair, Con­ over, and Napanee series. 135 Profile description of Hennepin silt loam: 1* Dark gray humus soil neutral to alkaline in reaction and 2 to 4 inches thick* 2* Gray calcareous clay till* Variations Thickness of the surface layers vary according to the slope gradient* Topography Drainage Pound only on steep slopes* Surface drainage excellentj internal drainage is slow* Natural Vegetation Use Hardwoods* Pasture and second growth timber* Distribution Illinois, Indiana, and Ohio* Type location St. Clair County, Michigan* Series established Map symbol HILLSDALE 6 Indiana, 1928* (carmineJ* series are automorphic members of catenas developed in sandy glacial till* Profile description of Hillsdale sandy loam: 1* Forest litter and mould, 1 or 2 inches thick* 2. Dark gray humus soil neutral or slightly acid , 2 to 3 inches thick* 3* Light gray compact loamy sand, breaking into minute horiz­ ontal platesj medium acid, 6 to 10 inches thick* 4* Yellowish-brown loamy sand or sandy loam exhibiting a com­ pact blocky structure, 20 to 30 inches thick* 5* Calcareous sandy clay or clayey sand, considerable local ad­ mixture of gravel* Variations Parent material varies from compact clayey sand thru a clay loam to a fairly plastic gritty clay* Topography Undulating to hilly* 136 Drainage Good, both external and internal* Vegetation Use Hardwoods with a few red and white pines* General farming* Distribution Southern Michigan* Typo location Hillsdale County, Michigan* Series established Map symbol IOSCO 34 Livingston County, Michigan, 1923* (red;* developed in sandy materials superimposed over clay in morainie drift areas* Profile description of Iosco sandy loam: 1* Dark gray or grayish-brown sandy loam, 6 to 8 inches thick (plow soil;* 2* A leached, ashy layer which is locally white, elsewhere stained light brown* This layer is acid in reaction and averages 12 inches thick* 3* A discontinuous dark brown cemented clayey sand layer, sel­ dom more than 12 inches thick* 4* Yellowish-brown sandy loam, frequently waterlogged* 5* Calcareous clayey drift at 2 to 3 feet below the surface* Variations The most significant variation is in the depth to the relatively impervious clayey substrata; conspicuous variations are seen in the color and structure of the sandy layers* Topography Drainage Concave slopes, depressions! margins* Imperfect Natural Vegetation Use Hardwoods* General farming and garden* Distribution Type Location Central Michigan* Bay County, Michigan. 137 Series established. Map symbol JEDDG 32 Bay County, Michigan, 1931. (sepia). is associated with the Napanee soils in St. Clair County. It is hydromorphic but is dissimilar from Toledo and Brookston in that the surface and subsoil are acid, a condition attributed to the large proportion of shale in the parent material. Profile description of Jeddo silt loams 1. Under cultivation the plow soil is a light gray, acid, gran­ ular silt loam, 8 to 10 inches thick, low in organic matter. 2. Mottled gray, gritty clay. 3. A compact gray clay mottled with brown. 4. Calcareous, shaley materials at depths of 3 feet or more. Variations The surface varies in organic matter content and hence in color. Topography Plat, low plains and depressions associated with the Napanee* Drainage Poor. Natural vegetation Use Elm, ash, oak, hickory, basswood. Cultivated and in pasture; fair beans, poor beet crops. Distribution St. Clair County, Michigan. Type location St. Clair County, Michigan. Series established Map symbol KERSTON 1 St. Clair County, Michigan, 1928. (green;. series consists of one type only, a mucky alluvium as­ sociated with the Griffin and Genesee soils. 138 Profile description of Kerston mucks 1. Finely granular mucky loam or muck neutral to alkaline in reaction* 2* Stratified mucky alluvium and sand, silt, and clay* Variations Chiefly in the organic content* Topography Flat and level* Drainage Poor* Natural vegetation Dse Hydrophyllic plants, buttonbush, alder, cedar* Pasture* Distribution In stream bottoms* Type location Menominee County, Michigan* Series established Map symbol MACOMB 021 Menominee County, Michigan, 1925* (azure; includes imperfectly drained soils developed in thin, non­ conforming sandy layers over clayey calcareous glacial drift in association with Miami, Berrien, Granby, and Wauseon soils* Small stones are normally scattered from the surface downward throughout the solum, although many have been removed to facilitate cultivation* Profile description of Macomb loam* 1* Grayish-brown fine granular loam containing fine sand in many places, grading into a light grayish-brown material which contains less organic matter; slightly acid to medium in reaction; 8 to 10 inches thick* 2* Light-yellow friable clay or sandy clay which has more pro­ nounced horizontal than vertical cleavage, the layers being from |t o 1 inch thick, grading into bright yellow or mot­ tled yellow andgray sticky sandy loam or friable sandy clay; reaction slightly acid to alkaline; 14 to 18 inches thick* 3* Light yellowish-olive or yellowish-brown gritty calcareous clay loam or clay* 139 Variations g r itty Topography Drainage Underlying materials vary from a moderately compact elay loam to a fairly plastic clay* Most areas are nearly level. Fair or poor* Natural vegetation Elm* ash, some beech and maple* After artificial drainage, medium yields of oorn, oats, ■wheat, beans, sugar beets, June clover, sweet clover and alfalfa are obtained* Distribution Michigan Type location Northeastern Tuscola County, Michigan* Series established Map symbol MAUMEE 38 Fulton County, Ohio, 1922* (emerald green/* includes poorly drained black soils developed from waterlaid sandy materials which are neutral or alkaline in reaction* The acid sandy soils with similar parent material but with a lighter surface color constitute the Newton series* The maumee soils differ from the Bono soils in being developed in sands or very sandy materials, while the Bono is developed in lacustrine clays and silts* Profile description of Maumee sandy loam: 1* Organic litter from trees, brush, or grass; in places, a thin layer of muck* 2. Black sandy loam containing a high percentage of organic matter. Slightly acid to slightly alkaline, 12 to 18 inches thick* 3* A mildly alkaline to calcareous layer gray in color. In places, the normal mottling segregates into a separate brown layer* Variations In amount of lime in subsoil, and in the organic content of the surface* Topography Nearly flat, low areas. 140 Drainage Poor, covered with water unless artificially drained. Vegetation ?se Rushes, marsh grass, reeds, and water-loving trees. Game cover. Drained areas grow fair corn. Distribution Minnesota to New York. Type Location Jasper County, Indiana. Series Established Map Symbol NAPANEE Porter County, Indiana, 1916. 21 (blue). is comprised of automorphio soils developed in gray or brownish-gray drift. Profile description of Napanee silt loam: 1. One or 2 inches of leaf litter and mull. 2. Seven to 15 inches of smooth, slightly gritty silt loam, the color grading downward from dark grayish-brown to light gray, in some places stained with yellow or brown. 5. Ten to 15 inches of heavy silty clay mottled gray, yellow and brown. Plastic when wet but readily breaks into small, bard angular fragments when dry. 4. Slightly weathered and unweathered heavy drift. This parent material is stony and gritty, and varies in color from gray to brownish-gray. Variations In drainage, depending on relief; and in oompositionof the parent material which contains variable quantities of shale. Topography Level to rolling. Drfl'inafrei Imperfect because of the heavy parent materials. Vegetation Beech, maple, oak, basswood, elm. Use General faming and dairying. Pistribution Michigan, Ohio, and Indiana. Type Location St Clair County, Michigan. Series Established Map Symbol VanBuren County, Michigan, 1922. 02, 22 (violet/ 141 OSHTEMQ series includes soils developed on deep gravelly ouwash and river tenches* It is associated with hoth the Podzol and the Gray-Brown Podzolic soils* Profile description of Oshtemo sandy loams 1* About 2 inohes of forest litter and mould* 2* Two to 3 inches of friable dark gray or grayish-brown loamy sand* acid to neutral in reaction* 3* Two to 3 inches of light gray platy acid loamy sand* 4* Brownish-yellow compact sandy loam 15 to 30 inches thick* 5* A thin, irregular, discontinuous layer of reddish-brown or brown clayey sand and sticky gravel* 6* Crossbedded, stratified calcareous sands and gravels* Variations Surface variations in the texture of the parent mat­ erial regulate the rapidity of internal drainage which, in turn, has created differences in the entire solum* Topography Drainage Flat, sloping outwash plains and river benches* Good, often excessive* Natural vegetation Use Oak and pine* Grains, com, and hay furnish good or fair yields* Distribution Lake States* Type location Kalamazoo County, Michigan* Series established symbol OTTAWA 86 Kalamazoo County, Michigan, 1922* (magenta,)• includes sandy zonal profiles* These soils have devel­ oped on fine sandy glacial outwash materials like the Plainfield and Berrien, but the calcareous silt and clay strata are deeper in Ottawa than in the Berrien series* Profile description of Ottawa loamy sand: 1* Forest litter, usually without a well-developed humus mat* The thickness is rarely greater than an inch* 142 2. Very dark grayish-brown loamy fine and about 4 inches thick* Strongly acid* 3* Strongly acid, brown incoherent loamy fine sand to a depth of about 20 inches* 4* Yellowish—brown to yellow loamy sand* gradually becoming lighter at greater depths* The thickness of this layer may approach a maximum of about 2 feet* It is acid to neu­ tral in reaction* 5* Calcareous sand and fine sand with occasional thin strata of silt or clay* Variations Depth and color of solum* Topography Nearly flat* Drainage Good* Natural vegetation woods^ Use TOiite pine and a few other conifers and hard­ Forestry* vegetables* oats* com* and alfalfa* Yields* medium* Distribution Plains of Great Lakes Region* Type location Ogemaw County, Michigan* Series established Ogemaw County, Michigan* 1923* Map symbol 45 (sienna)• PLAINFIELD series occur on deep, draughty sand plains where the parent material is dominantly quarts sand* Profile description of Plainfield loamy sands 1* Forest litter ranging up to a maximum thickness of about 1 inch* 2* About 3 inches of acid, grayish-brown loamy sand* 3* About 1 foot of yellowish-brown slightly loamy sand, loose* unconsolidated* and acid* 4* Fifteen to 20 inches of bright yellow, loose, permeable acid sand* 5* Yellowish or grayish stratified sands sometimes containing gravel* 143 Variat io&s A few gravelly areas are often included. topography Plat, level plains. Drainage Excellent, excessive* natural vegetation Pse Scattered oaks and pine. Extensive pasture, reforestation. Distribution Sandy plains of the Lake States. Type location Waushara County, Wisconsin. Series established Map symbol SAUGAIUCK 47 Waushara County, Wisconsin, 1903. (yellow). is comprised of ground-water podzols developed in deep, sandy materials. Profile description of Saugatuck loamy sand: 1. Forest litter and mould, 1 to 2 inches thiek. 2. Humus layer is grayish-brown loamy sand, slightly acid in reaction and 1 to 4 inches thick. 3. A conspicuous white sandy podzolized layer, acid in react­ ion. When dry, this harsh, gritty layer exhibits slight evidence of cementation. It is 2 to 10 inches thick. 4* A firmly indurated ortstein, coffee-brown in color, acid in reaction, and 6 to 24 inches thick. 6. Dingy gray, waterlogged acid sand. Variations The ortstein layer varies in color, induration, thickness, and depth below the surface. Topography Level plains with a bumpy micro-relief of the pitand-knoll type. Drainage Imperfect. Water-table varies between 2 and 4 feet below the surface for a major part of the year. Natural vegetation Originally pine, this land has generally been cut-over and has now grown up to aspen, willow, and alder with a dense bracken ground cover. 144 JJse Litlie cultivated because it is a "coMtt soil. Some areas are planted to corn, oats and pasture. A better use is, perhaps, the production of pulpwood; or, for small areas, management as game cover. Distribution Lake plains of Michigan. TyPe Location Bay County or Midland County, Michigan. Series Established Map Symbol ST CLAIR Allegan County, Michigan, 1901. 041, 41 (grouped-with associated soils;. soils are zonal members of the Gray-Brown Podzolic Group developed in exposed, fine-texfcured, calcareous glacial till that is dominately brown in color. Profile description of St Clair loam: 1. Leaf mould from deciduous trees. This layer is fairly well decomposed, neutral or mildly alkaline in reaction, and 1 to 3 inches thick. 2. Two to 4 inches of grayish-brown loam, neutral or mildly alkaline in reaction and darkly stained by infiltrated org­ anic matter. 3. Light yellow to ligfrt gray loam. Varying in thickness from 6 to 12 inches, this layer is definitely acid, and exhibits evidence of a degraded structure. Major joints are horizon­ tal, imparting platy characteristics to the horizon. Struct­ ure junctions are vague, however, and the layer is every­ where pierced by a myriad of microscopic, angular interstices and crevices. Slight pressure completely destroys this skeletal structure, leaving a mass of harsh, ashy sand and silt particles. 4. A transition layer varying in thickness from 2 tolO inoh.es -which, in the upper part, resembles the layer above, but^ which gradual changes in character to resemble the material below. 5.A heavy-textured layer varying in thickness from 8 to 24 inches, in reaction from slightly acid in the upper part to slightly alkaline in the lower depths. This layer exhibits a conspicuous structure of well-formed angular fragments showing little orientation except for large crevices which, 145 as remains of early developed joints induced by drying tmf^ consequent shrinkage, extend vertically through the horizon to penetrate the underlying uaweathered material* Individ­ ual fragments exhibit considerable heterogeneity in that their cores appear relatively unweathered, being protected by one or more layers of very fine materials accumulated on surfaces bounding major percolation channels. Joint inter­ faces in a portion of this horizon are covered with brown colloidal materials which impart a dark shade to the entire layer, particularly when the solum is damp* Smooth stir­ faced cuts through the solum fail to exhibit these color differences because of the relative small bulk of the joint materials as compared to the exposed unweathered mass of the severed fragments* 6* A transition layer between the materials above and below* 7* Relatively unweathered buff calcareous till* This material is massive and compact, the upper portion severed by verti­ cal joint planes exbending down from the layers above* The intersection of these vertical joints impart to the till a rather massive columnar structure, the faces of the colum­ nar fragments exhibiting a whitish coating of precipitated calcareous materials that asstones a greenish tint in places* This layer is encountered at depths of 2 to 5 feet below the surface* Variations The presence of slightly mottled subsoil layers where thesurface approaches a degree of levelness* Water that otherwise would run off is forced to percolate downward, de­ creasing seration and hence oxidation* Topography Drainage Rolling and mildly dissected* Surface drainage good, internal drainage slow* Natural vegetation Use Hardwood* Mostly cultivated, supporting general farming enterprises, the more successful of which devote a high proportion of land to pasture and meadow uses* Distribution Ohio, Indiana, and Southern Michigan* Type location St. Clair County, Michigan* Series established Map symbol St* Clair County, Miohigan, 1929. 4, 14, S3 (carmine). 146 THOMAS soils developed in shallow layers of sandy materials overlying lake-laid clays. The profile is alkaline in reaction throughout and contains shell fragments in the lower horizons. Profile description of Thomas loams 1. Dark brownish-gray, grayish-brown or black loam containing large quantities of highly organic matter. Its thickness seldom exceeds 14 inches. 2. Three brown 3. Light depth to 4 inches of drab gray or mottled ©fay, yellow, and silty or sandy clay containing shell fragments. brown, yellow, and gray plastic clay extending to a of many feet. Variations In some areas a thin, mucky layer constitutes the surface. Topography Occupies relatively low, level areas. Natural vegetation Use Sedge and bluejoint grass. Beets, beans, corn, and wheat return good yields on arti­ ficially drained areas. Distribution Michigan. Type location Tuscola County, Michigan. Series established Map symbol TOLEDO Tuscola County, Michigan, 1926. 19, 29 (blue). consists of the heaviest-textured hydromorphic soils of the lacustrine lake plains. Surface layers contain high quantities of organic matter and are underlain by smooth, plastic, mottled subsoils. Neither pebbles nor coarse sand are found within the profile although a few boulders and erratics may be scattered about the surface. Profile description of Toledo clay loams 1. A thin mat of forest litter and leafmold. 2. Dark gray, neutral to alkaline, granular silty clay loam, 5 or 6 inches in thickness. This layer is friable and easily worked despite its heavy texture. 147 3. A dark gray* harsh silt loam* slightly acid in reaction nri^ 2 or 3 inches thick. 4. A highly mottled gray plastic clayey layer* slightly acid to neutral in reaction. 5. Bluish-gray plastic clay. 6. Calcareous gray clay and till materials at depths greater than 3 feet. Variations The glei (Layer 2) may directly underlie the surface. Topography Low lying flat plains. Drainage Poor* internally because of fine texture and compact structure* and externally because of the flat* level land surface. Natural vegetation Pse Elm* ash* silver maple* swamp white oak. Nearly all areas are cultivated. When drained* this soil produces high yields of beans* grains, corn* and beets. Distribution Lake plains of Ohio and Michigan. Type location St. Clair County, Michigan. Series established Map symbol WALK ILL 09 Pulton County, Ohio* 1922. (green). is a colluvial series consisting of recently eroded mat­ erials of variable thickness on top of or mixed with organic deposits. The areas occur in irregular depres­ sions in moraines. Profile description of Walkill loam: 1* Dark grayish-brown* gray or black mucky colluvium resemb­ ling a loam in texture. 2. Organic materials. Variations The surface is not uniform in either texture or color. Topography Alluvial fans and mucky colluvial wash in depressions and along the margins of flat areas of organic soils. 14$ Drainage Imperfect to poor* Natural vegetation Sedges, cattails, button bush, dogwood, arbor vitae, willows, alder, aspen* The vegetation is not truly characteristic of this soil; rather it is char­ acteristic of the organic soil over which the wash has accumulated. Pse General farming when included in rectangular fields; it is often segregated as brushy waste land* Distribution Michigan* Type location Washtenaw County, Michigan* Series established Map symbol WATJSEON 027 Sussex area, New Jersey, 1911* (indigo)* includes the hydromorphic members of catenas formed in shallow sandy smears over clay* It is associated with the Allendale and Arenac series* Profile description of Wauseon sandy loam: 1* A thin layer of forest litter and mould* 2* A thick sandy loam humus layer, 6 to 8 inches deep, neut­ ral or slightly alkaline in reaction and dark gray to nearly black in color* 3* A light gray harsh sandy layer, more acid than the overlying humus horizon* 4* A light gray, waterlogged sand* 5* Mottled gritty clay* 6* Calcareous gray clayey materials at a depth of less than 40 inches* Variations The surfaee may contain considerable organic matter, being nearly black in color, or the organic content may be low and the surface light gray* The subsoil sandy layers may also show some yellow coloring as in the Macomb series* Topography Use Plat, wet sandy plains underlain by clay* General farming* Beans and potatoes produce good yields* U9 Distribution Lake plains of southern Michigan Type locat ion Fulton County, Ohio# Series established Map symbol WKARE 48 Fulton County, Ohio, 1922# (emerald green)# includes soils developed in beach ridge material which is dominantly quartz sand# These soils are often degrad­ ing ground-water podzols possessing fragmentary ortstein layers# Profile description of Weare fine sand# 1# A thin layer of litter, mould, and humus soil# 2# 3# 4# 5# A thin layer of acid unconsolidated ashy fine sand# Loose, yellow fine sand to depths of 1 or 2 feet# A fragmentary relict ortstein# Yellowish or grayish acid fine sand# Variations Wind erosion develops many Mblow-outsM, exposing the underlying layers# Topography Drainage Low, broad, gentle, linear ridges# Good, often excessive# Natural vegetation Use Pine, cherry, oak# Reforestation, recreation# Distribution Lake plains of Michigan# Type location Bay County, Michigan# Series established Map symbol 74 Bay County, Michigan, 1926# tyellowj# Si JQRXCE tl # <***:•**«# L m FEA' UPF'S m I Ihnmm* # % # f - mad ** I ^ I / w~ " fa™*" f J$k> f'-ii' ■ Ws4#: C t e O S W E L L XINGTON LhXINGTON hEIGMTG Great L vS h o b e s L e g e n F o g m d Intermittant stream s Short steep s lo p e s -— E rra tic boulders £ stones G ravelly areas (in clay) Sandy sp o ts (o v e r clay) Clayey a re a s (in sand) JV ^r-> "J/S L in e s R e la tiv e e le v a tio n s and s u r f a c e c o n fig u r­ a t io n s a r e i n d i c a t e d b y l.a k e EuEv53i F o p m Linies at a p p r o x i ­ m ately 2.0 - foot i n t e r v a l s . Level data is from (peo/o cjic S a n i/ a c C o u nty [Gordo and road d a t a s u p p lie d by t h e Ganilac County R o a d Commission. r T to J i' C x^yn jcu A d , A F G/yi_ im o y n l^ d iu C S e a I -B u m > (W u /X i y jj? tlr o m fM u L m- 1941. cU4e?nS&iifcMluAd.pc^0M:d (/ u ddbn R eferences n c to d /x io m m > A tM m O lc n / a m d u t a l A J Leverctt G o rd o n A1o p o f S u r f a c e F o rm a tio n s G e o lo g ic a l R e p o r t o n S am lac C o u n ty U n p u b l/s h e d s o il survey data G: / L y>tC"fT- : 2 . w 0 , 0 0 0 3.21nch e S = I mile I S q u a r e — Isection . y x' i \J IM I L E \ I 1 S T Q E A M P A T T E B MAD N 2 -> ' v-/ \ 1 fe i ‘^'ti IfttfltlHIii. « L •ft 0 * a r^-V'-v, ^W'v">J\SV ; . „■ ■ . a<>S. •firs'- / •fW*1 } 1 ^;fv{,V j * * " WMttgn ■ L e g e n d Intermittont stream s Short steep slopes Q c u U b M a p ; a m p M L IMl E rratic boulders $ stor es Gravelly areas (in clay) Sandy spots (over clay) Clayey areas ( i n sand) ■" ., M 0/m j h/nru(Wih > £ dfitiidj v\''1 n o tu j JV' *2^' fv^ M i 1 9 4 /. ^ i£ & M w M L o n / I : 2 . 0 , 0 0 0 > \7 Q M M yM n , , CjC U U * C C rm h M M t S e a Ijiitj r o 4 /" WWW, ■AUTOMORPH1C HVDQOPEQIODIC H 1~F2 A N I S I T I O N A l _ U P LA N D .J S t C S O IL S (4,14.33) [H e n n e p in ( 6)] l a i r I C o n o v e r O 2. 22) j l o 5 C o ( 3 2 ) . A l l e n d a l e Uz), B r a d v ( 8 8 ) ! j H i l l s d a l e (34), B e l l e f o n t a i n e ( 3) _ B e rrie n . j _ O t t a w a (45) C O L O M A (35) (46) A ,r e n a c V D Q O C A R L I S L E M a u m M O B AZONAL- e e P h I C (10,20), H O U G H T O N ( 5 9 ) £ ly d e (9 ),T (H.2l) h o m a s ( 19.29) BROOK5TON(8.l8.28), T o L E D O (0 9 ) (43,44) W a u s e o n (48), M a c o m b o a ) IM I L E P L A S O ILS j NAPANEE (2,02.) I G ra n b y N M ISIC ELLANEOUS N T Q A Z O N A L ] F O X (85), 0 5 H T E M O ( 8 6 ) j P l a i n f i e l d (47 ) G e n e s e e IW G r i f f i n ( 9 i) ,K e r s t o n e a r e (74) [ E a s t p o r t (75)] B u rn e d m u c k (15,16,150,1so) ( 92,93) (021) 727),WALKILL (027) W aSM TE NAW(I S e e A p p e n d i x 3 (57. 5 8 i G ilf o r d (8 9 ) In te rm itta n t S h o rt ste e p s tre a m s slo p e s rr.tii Beach B o m b ynap; id) c m m a t e r ia l s c c m p M L E r r a tic boulders i stones G ravelly a re a s (in clay) Sandy spots (over clay) C la ye y areas and) s A ~ m o d a x c ’ ' V'. z C m w u x t l e n j 'OJiUCt A A &tdr / Urt.4p.ynACCc ,