m r w if w iD

Awmxmmtmmmn,

m m et rm m m m *

aku A U ^ ^ m o m m v twtmmvm

W
Da $&a@ m

A T IM 1 S

SobsalttM 1m» tli#
of Qmtoati&m 8fcn4 t«« of Michigan
8t *&* Coll#g* of Aa*ie&2tttr« &»$ Ap$lt*4 Stalosteo
in psiftiml £telfillsu»tfc of ttt*
rem its
for %h# 4 «g*«» of
OGCTO& 0?'

'dapftrtflMls of CtumUrfeiy

IfS l

ProQuest Number: 10008425

All rights reserved
INFORMATION TO ALL USERS
The quality of this reproduction is dependent upon the quality of the copy submitted.
In the unlikely event that the author did not send a complete manuscript
and there are missing pages, these will be noted. Also, if material had to be removed,
a note will indicate the deletion.

uest
ProQuest 10008425
Published by ProQuest LLC (2016). Copyright of the Dissertation is held by the Author.
All rights reserved.
This work is protected against unauthorized copying under Title 17, United States Code
Microform Edition © ProQuest LLC.
ProQuest LLC.
789 East Eisenhower Parkway
P.O. Box 1346
Ann Arbor, Ml 48106- 1346

T&® m ito r vti&hm to «Rg>ro»« hor alnttoro
•giprtetfttlttii to $r* 1©tort
8**fesfe fo r h i* $mit
hol$ftt.l f i t t o 9 maA m g g m ti^ m 0&vb®& iho $wr»>
i&mmm ©f t&i# mtte# Sit© I® ol«© in£ol*t«& to
Pmfeo* Daerio onl CwqpuQr fo r tha followEhip giT©a
to hor iortag tfe© yoor M tM & ftl*

********
#*#»##
•o
♦

337991

C0* 5S»S
Pi»S
1

KES’»0SIC A U ... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

8

OSSCTOBIOir*..

8

...........................
..........

87

pum m & tm w tm m m m tttm , ***#**•#*

ft*##««*♦#* tT

# # * # * # « * * # * * * * * * # « # **»n

t^Alfevl

<«*#*»•«#»»**##**

88

t ill* * ! * * * # * ***» » *• » *» •« *» * « # * * * ** *
i

M

. *»*•«# * #«****,# #•«•*#*• *

84

ftM tAgrtfcpi m i lM # *
m m jM m w « r .......................................................................
1 *6 A t l c ^ F ^ i t - m t o i a *

Cf f lx m t ik

1*8

( v m B m m w M w & )+ +

« # * * * » *# » # ♦ # » » « « •« « * *• » •« •« * •» * « « » # # * *# # « »

m
$?

8f

isrfejwim*«*#» *****««»*#*•* *t* 48

1*8 Allray^i&Boffe #8@rtwalleylt st mssol# hydrochloride* *«* * #*

46

1*6

40

l a m l W l k y 1t«fem m tm «»*««»«.»«•••*»
............................................

U n U f9 K S cnSQb«*»**«* * * * * * * * * * * * * * * * . * . * * * * » * »*•««•*«« «•***«*

66

l i s t W TASKS
9 A*tS
i

PAC-S
tm WjroxT«simmTrrue»Ai*:?iffap»AWfis., s i

M ir m m m b *

xx nmAi'tt a sss^ sif^ a w sp k f...............
t ix
tv

HXTB0S8*

ftstavmm

1 *0 n o m m i w

m v*nen>

Awn

80

m iw M tfm m sB m M ,**.*,* * * * * *

R A m u z . ♦ .« 40

v w w a f m am m or i,s s m c m a w «ra Awcsor^irso........
rt
m

1 .0

Awasmwrt*

81

..........................

«i

aho iU x o x x a A X R s o ra iiiF x w tK itr^ riiA S o m ....

48

arm anr m s s tm tw i.s m m m w nm tm akcot-aisso...........

T ill

1 *0 A W

W

»

4?

w o A JiE 0X X -A «S 0S T !3m »ja*fl.'F ^8A i!C >te

rif80OC8tO8S9R8*«

80

is

m w » a * m ,t m op i*r aw*wrb»iw $m HMtwMrnmm
m m tM a *n ,rm u m u ntam m tm tm s . . . . . . . . . . . . . . . . . . . . . . .

si

x

M
a c w x u s h w p s s w w Asm
T B rn A iJ o K s .... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .

88

a

SHB06W tm vm & OF 1,8 ACgT«AWWSWSTO- ATI AXXOXT*
A o s r m w c f o r a s w i^ s w ttT J in iA g o is s .. .. .... . . . . . . . . . . . . . . . . . .

88

u e r o? n m m m

1*
$U

H in
$y£rtth@ais***

AltfaKtgh t«bm#©t© its e lf dees not *ppmr to to ©hermetertsed by
*sy

?&ernnaeologi m l not loo# the in&nsdtaetlen of agtMritltttsafee

Into the I nnd © position* of the ring ehmotors lapfcrfc* d efin ite mod
to many Inetsaees ve*y pmfeiind motion© to the resulting eompsnn^o*
As satiMML by arose «sd ^enthereteue

m the result of m

eosnprsfasnsiv* ©tody of 18© tstr a ssls derivative*# the ^mimootegtoal
motion© of these ®tmpmw£® gonormtly tw elve the eentrel mrvm® system*
the aobsbesaesB exhibit sbim tebeiy or depressant notions m well m

vm pim degrees of edited etlmtlnbsty mod d«prass«nb ©cbiem*
iM hst «M eo^wer&ore ( 8 ) Imre synthesised n series of nitre- and
ns&nopheupl tsfemtolo derivative©* It m© Interesting to observe that

th® Introdootioe of & ^«eaimo|ti^rl group at either the 1 or $ position
o f th e te tm a o le n n e lm e re s u lte d I & ©empeunde hm viee p H m r lly d e p re s s

mn%

motion* fh%* else synthesised severe! l«^*tho^t^e?3yl*S«»mll^rI«-

tehraseles {?)* The present# of *

group esumed a

imr depressant offset (7)»
It Is the psrpMS of this iwesbffptlon to flgpnnd the knowledge
of the relmtlenshlp between sheet sal oonefeitetion eng jdmrmoologlenl
properties in the tetmeole *srts*« for this purpose# I t nppeered to
be deeimfcle to study the #r#fm*mtle» of n series of substituted phenyl
aibyl tetmsoles in shlsh both an, nlte^r mad an salno group were in*
eluded ms substltoonhcs In different positions on the phersyl ring*

sxssresxcAJ.

mm m m m

fh» ftrot

mm

in 16119 W

Swedish tfeondtft

<$# A* MlMin ( 9 ) 1dm 4bft«fv*di tfaAfe tfe# action of

*#14 m &i~

*p*na$h*8igrIfeyAm ntm 1 «A tn th® f«ra&tcm of a aow^onsttt
ho n».«r£M

^

f«rm ln ^i?^(€W)(Cl^)* %&a^lyai$, follow*! lay do*

o^oaylatloa* gmtn««6 m

'touring fch® f e w k c^h-^i tho trnlt,

rwMtlnod ln%*ofc throughout th® tftrafom ttn n ( 9 >* Blaltn ( 10 )
H i* wm® t * ! # * * * ! * f o r t l w

m m r i n g s tm e liw m

* iPOg - *

c^w $

**

?!

3f

fm 1899* §1*4 la ( 11 ) ti«e««ddl In gn»«p&iiing t*fcv***l* lt* * lf fey
%hm f n l M t a g » « * !« * o f fr n fc to n * #

0 Eg*i * £*m
'

?!

ti

B

M lsi& rtl*

CJL<& * W 300H
* ® i

Sf

„

$

mft*CgH *3f * CaCOOK
isitmtion

*

,

f

u

1
*W '

UWL
•

0

h -h
4 ,

1

* c*eooar

xr

)(

f

sw? * e*H

oB lA nteltm

m& 4 mtkrtgwyl*t Im

)

n

I

$

*r

fortet*** tm 1906 (IS) syss&houigod X*hyd-r«ay*6-^*B/lt*bttuii>lo bgr
ln to m o fe io n o f to*ns*tty&r*sc*w y 1 o to lo jrid *

o o d lm a s ila *

??
I*0M

M

* 0 -*»

I

110 - S\

$
H

roduofcIon

At ofemtt the &mm time* OOhreofeor (13*14) jmoeeo&od\ in <?om,©rtlog
SiiAtloviA* in to 1*$«Si pfeej^lt o&moole fey hunting the

former miih etlrer ©*14© or eoSium OtiSo* fh« ©oijetitss&loti of
phoj^liofcmeole mot w aftraoS fey tfe© aynthaoie o f thl©

from

$*i$Marl feo&atoiSyl ehloriSe mod eoSinm »aM® (i«)#

Vsf^'A
■ ©

€1

1L,

i

i

¥%^S% ***»,
Ci

^

^

% % *£ * s w ^

y*

n

$

"ti*
€a % ^ *

^

% % *o * f e - c ^

si
dohvoofeop (1#) & lm mm&m& the feehoeior o f |Air*la0hmm©# on

aromatic aliphatic ka%«m©* in ontor to Sioooror ©feotitior tfee o*yl or ifee
ftlfeyl grmtp migrated daring: tfe© reaction#

tfe© formation o f iwMwifcyl^**

ffee^itoferodolo iiaSiooitod itefe the IMwsiyi group had migrated#
Another Intern et tag «Qrt$tho*t« of l#fe SioafeottM tat tofcvMolo* In *
eotartwg the eoodeiMfttlofi of osmmct&ie

o o lt* vffeh to jrl feydimoines

©no doeorifeod fey Jtefofcfe and So monfesnollta CIS)*

An in it ia l

o f the roaotonto to form dloftdfcydMildoo m o followed ty oooroisioxi of
the lo t to r in to tetm «o lo dotlvMd&vee fey treatments with ewtooa* aSttmli#
ie&h wo®eeeyl feydvooioesi aM dio^lhydm oinee war© ones#
J U M U -C l * RM M BW SL
6
8

A lM M R w f-a -tM t'
H K

«lfe»

A**>« • 6 -S *
I
II

H
1
55

H0
i (I

0
M
A ^ W ^ w ® ’ filfe #
*
>
m%m'

II
0

d*M? * 6wH!
l
II
b
mt

S M U itt M 4 (17) AooorftfeoA fim mwrnvmMp oimplo wothod for tbo
fioororotoir «f leotoBdJi tafeo l#fi dioobotltuhod to&soaotoo* With om
©qoiwaloiit of hydraaoio aotd* hho gwodaot wot *o amid©# ?oo or m m
oqiiioolaw&t of hydro*©!© wold tod to %•© fowfcfoft of tofef**elo* along
i

-lAiitfc -ttfittft-jftoBiM BnOTjI dfeOBfittfe mfefoOfrt* 'BBOMMilliftA&il&dl,*.

1

1

) mo

11%

— *

*«c ♦ m
ii I
»

H

or

l

'* *

a-noc * im
ii ii
t

v

Nr

fho MMliORiiotA off«r*d % SoholAt to ooptata tho rme&im of hydro*
•of* ooid in tho $0000000 of dot4 ottolfoto oioomod tho formation of
fin ioOsio radical {>$$!) wttioh im ^o^oatly rooofeod with tho hofco&o to
giro nrn dotsao* Tfe© tofcMlolo f&rmt-tm mm mplmimtsd W tho tutor#*
ootfofi of » oooimd ami# of hydro*oto field with th© tmim or ®om« ©fchor
toNrofifilfit# formed hy roosmBgomanfc of tho mim»* ilpieimm oad d&otlo
( 1&)# homrort orltleisod Setaal&fc* $ mw&mnim asid ooml&dod that siotthor
hho Mtoo raditfil nor t&o m%m» mm itowtrod in tho reaction h&mmm
hermit and hydrogel© odd* later# Mfth ( 10 ) devwfagmd a m m ooo^t#»
Ohio toterfNM&afttea ood tittonmood m oautooim Ion woehejtimi for the
feraotten of tefeiMeteo in the OeMdt reaction*

l# 4 l* m m B rn m and S to d frlth (8 0 ) li^ f t y r M

(H I

W

tfe* tsatde

£ehrsM0fe«rf ® p ro e a d u r*

with hydmseto «,eid

% ® .

h

m

%

w

M

n

r

entoratofm totntlea* l%m# Ime«tl$&t©r0 tm®& $tsafc map twid© ©hlarlde#
which mmM wfc react mttli mullum ««14* yielded b*fcra*©l« dsrtetfcivefc
if

*eM m % M m mm «**&* tbm ntbsn mahetitetat mmmrntn

laid# okirnHMm nhlth wtim vM&* t w i i imdtet aside o«M %+ a#ar*rt«d
into tetfaim it# by lil# tM tittttt**

starting

#«*13tayS ar $*a*yl

th e y SKt*©##d*dt in g re yftri& tg & s a ris #

I* S d ia iy t * and

V ssiseesfir© rm&teim wlIM gbrntfkmm P»s*fe**
ehierid© mm hf&mml® acid*

n'tcxim m i

«»#eMi *%
el

&*«c *
%
*

fh# ttrs&fttag ta p -m t ©£ reseti©## m
fMtlgJli (SO) m lf t s

imi

Ii
1
s
j?
Ni?*

applied fcy rets imun m&

«£*l©ridmi In #*t©h t* wm a«M*atl© and 1 m s

titte r nllflxntl# #s? tn M llit

fhm rtsttieb itn t* in&M® mtmri&m &*»

flttd rraa bttsesaldist mi# t^H lasht by

sad

(S i) t* b#

totted an m rllm wsife by w a Wrsassa. #33# M# ©e«^Fk#re (Si«S$#34) In
iM th It mm 0mm that MUt* «&l*ridtes ©f alipbatl© M u
th e r e t * m u t l it e t p » © r m -* llg lM & le p t t f #

n

i

the ty$t

morn c h n m e t^ ria e d

by tilth reattirity that ttagr mmt€ m t b# im t&twl*
In S3HB&* Ketfett and «t*et»to«r» (SI) 4pa&h*tiftt& a grmip af twenty**
*1* | #| d&jttfeafcttoifctd thrttftititft and &«KN>&*tmt#d that the prspMfttfcltn

©f tsb etsaiet ;£**©» IM^bfctlbtttd ta ld ti by «©wereIon la te isa®4 ®
ehXarld## and ifa&arftttitn ©f th® la tte r with hydra*©!© ©©id m© ©u*i

booaftwi&oa m inelio&feod fey iron i w

lim it s

md

MWtgRi ($9 ) fewfc oml& few *tp&l«d maoeotafwlly to & groat ta ri «ty of
awfetfeitntod «s»i4ot Isetoitng «osi^lo%o$y nltgKuttlg typp®* fho stab ility
of tho lmi<to Ofe&orlA** mm #w«sfo that thty «*M feo

mtS'Ow#*

fatty 4m fememoR® tolwttom* ffe«y fetamft tfemfc m m with thorataM to
tintA* efelortAoo# goods nomiitt w « ©fetntimbio Whom o il w ^ . i r « that
tiirofanaA w&rtftng orton to krmkmtfo with, hy&m&olo wa$£ woro
4n mo for m p®0$thl&+

ftooiaatty* Haotmt and

{<?> msoomwtwt in

w

Sftm&tft ommwAsor* to th#

of a mrtot'sy of nt%m$i®w%i&4km*

**1*0 fw*» both

m ami iMtoyl oltoraw&lifMMU fh®y

tbs

Into th* eormgwnAtng nwAnoofeonyl**

totgfesel** fey wfeojytt* feylmgwKtion#
«&* * rooitlt of tfeolr

&M Fe*tfe*r*fco*M» (1*0$

0#4»$) bar* 4mm oortnim ©onolaolom roi&nting th# rotftttoafltiip feo*
twwas ©feomio&t *tmMJt**r» m i
tortrottr©®*

*ofe|*it of tfeo t^ m oolo

In % ««sHto* of 1 #.S ti*mb®Mtw%os! tofcaoiw&w# in mbl«h tfea

owfeotitwoat* wor* hy€rooas%om r&iioaXt* tlwgr oonOtwAwf that © «tm l
mmrmi otiwolotion m s f«*w**0 fey * %*oXoatl$ti&tio grmp in th* %

pmi%im or fey ltt*r«**i*g tfe* otto of a ®i«plo alkyl group in tho ®sm*o
pMittott* On tfeo ofefetr HaM* £o|MF«ft4m& notion mao fororod fey i mmm#
ton th« otto of m alkyl g w sf OafegtttatoA tm position @« tb® Intro*
4u*tt** of a ftonottoiMdt grwo^ omob at mr nata® grtmp at a

toanal to few a Awfetfm&niftg faotor* ifesm tha aalm gmsp m&® attach®!
dtroofely to th# t«tm roi# ring. in ftalfeimi §# eompotifid* with *utr«ty
tftiiitli&ory notion roowlt#!* I3h*a ®m or two carbon atow war# itstt?rpooo^

wOn*

feeteieea the

& m p m iI th e i M m t t ring# e t i i l in p e titio n s,

a d b te d t o M m r e m it # ! * ih ® d % r# t o f is U m t& tim i n r &#pro®«i«m b e in g

n o tifie d % thft mto&tm- & f other mhfttttftessbe in p m ttlm t»

Ta&erpee*

lug ft «yoii® eyefcee %%&mm the ma&m group md the t^fcm*©!© ring
m*dm®& th© M a ttin g ®wi®mMM w ith e degmfteesft eetten#

The ftotless

we* mere pewdy deprmftftBt when the *j&«e$iiaiorX gmnp mm ®hlft®d fnw
position $ to peettteift l«

The

appeared to be

swdemtely effeetfcre ee eedafttir* end lumlgeet® egonhe*

Msoeler* *§hag# Fm%h#r#h®n» end dree* CtB) &Xm iweetifftt^d bh©
aheorpfciei* epeehrft of * eerie® of ttdrty"«esift te b m e le derlrwfeieee end
th e ir peeetble elgt^fioftj*®® in re la tio n to the ftaiwimoologloftl action
o f th e # # e o a p ftM tft*

th e y

feeed

th a t th e

wftjerlhy

o f th e e n rre ® p ro *

eenfted km ftftadae* ©me tow&ri the h l# e r were length® # d«ei®s»ted &e M. #
J&

end one temrd the i«var iser® iwftgtMr* deeigmted aft

TMy eoaeleded

that* eltheoh ereeptloe* m&mtimmm eefteeeeiag ft faatewt end purely ottm *
latteg *ehi«* ehewI l i t t l e er ae ftbeorffcioti in the entlr© n itre rielefc
regies*
end

without

b§r the rftft&e e f the ^eelmmtL epftofcrephobosietor* Atee>
®K©ep&t©n*

eofeetiiiieee pseoeesing

ft

potent# purely

d«prft#*m n&

notion efthlMteft & ms%e& B peek* Ufte het#& of the b p o# (Ae®8t*dft&R/*)
me

pvwfMirtteaftl to the jdteeay* Ae any appreciable absorption

in the ultra vle&efc eeeorred only dim mh&tltnmk® mumble of appro©i«*
able%®»eiiftftfte mn$tt$ftbi®sf* wttfo th« tetreeele »y»t«B* wore preessat*
%h«sy te n ttttiirtly oe&elndoi % et fo r the te tre e e ie d*M *fttlr«e» Mae eob*
etltu h io e of grmp® a t peelt ion 1 et* S en the t©trft«ol© moleuft eefMtble
of ft h i# degree o f "xeemsftee oo^1op£tioi5n eeald bo conduci-sr® to the
product ion of a m&mr&ml p w e o s si^ oentrel dopr^smnt proportiee*

e7»»

The

omatmtm* of these aothoro are &pm to t o c r it is l^ that a lirait©a
m w fom o f eim&ples? w ore adU tafeei frw n a la r g e g ro u p o f m a n te s whose

#arw aool#gloal actions bad bom. studied#
n o t t o ineatwd© m m r p lm i n o tiiife a %l$h

Apparm tly mr® vm& zeroised
®£

© o r ^ g a tlo ii*

oooM bo aotlolpfeto. ohon. the giharoae&legi oat aoklot* was yriwarily »tiw *
la t o r y *

%n ife to w otfe* t o o r to * o f ollM W y

^ t m n o lm h m hm m

O^afehooiioS for %h® porpm® o f Sotioraiolsag thm offoofe of .vuyiae the
p lo t of i&too&fMt of to tt t&« &t$«r

the oatae groap to- iho pbooyl

msoloo# 3pm t&« ^om &oolofiool i&ottos® of tho om pm wlo*

fh# opeolfie

oo&pii®4« ohmm mm bo oto i§ift #4 1* fir# gampu fb® ooilootiosi of bho
$rm p$ n n to ttS 3p»m i&o ^ w m o o leg io o l

& i k m m &mlmpb®®ylm

&md m # & h m & 0 o p ^lb ® km $ o i® im & m b lw m « M tt*@ o w ilik M lit F

of popm tlos* of th *

rrn gkin lb®

or &« m m

iis&ormo&imto®*

X 1 *{ $*

)« * 8 * o llry it ofern g o l m

ffe o OOO^Nm$$SO i l l grOOf^ % O695^boB30d' 33 OSitSSO gVM Ip

33d. & oiwtttlicpy

grmif mro> to tto t*fe«**tfto ring* && ®rmo *a& fofcthorototto {$#?) hm®
n h o m t h a t $t&» fo fe o tlto tto o o f & o to g lo M ^ l o o f ^ w ^ o r & o im g to

P^otlMprtltappl grwop o* tt»o pftiMe&o ritsg oonooO tho roswtHog ec®*.
pood* to %o oootff&t merrooa ioproaoooto* i t »
(kotioo of

bobh

thangpt tfeot tho

tfeo oialsto o&d tfco m bhm y group into tbo oosso $hpr$>

oooloam n&g£t looS to

m oM ib lv®

off act.» Tho oBsyt g*m*p oafeotttotod

to tho 0 fMNiitloo mo-tftrloO £#m owsthrl to ofekylg. propyl &M ioopefgrl

to orior to oto% tho offoot of
OtSfcitl*

bh®

loiagth oM tho byHMditog of tt*o

m n*

w w

m $0 et * <# t n J n U

ft# #*% i i ttw m **

< y y t #©}*

in g?wp 11 md fcfc©#« in

g iw t 1 mi# tii# 4i#9fa«NMMfe #£ tti# 1mtehmp grmtp &"r#m the m m position
t o on# o f th # y rtfo ff f# # £ tt# **« *
t it

t * ( &* ^ $ © f e h © ^ 4 *
rm ~
■

ft#

'■■

mpls «8#1 M M A lc y lt $&m« «&$©

‘ Oft*

« s s p # i i t© g m tp H i e # a t# i# « d $ # ©Mis# g r m p m m t o tt i#

t#fcs*t##l$ ring «« **«gtt*fti with th### i m $tm m %
#m m&m g m # a#k®%4t«t#a gyt# t© %#

«&£«& ©#ssfe#£si#<t

ring* ft# src&hoaQr

g w f UM aM I© tti# ortt© position s© i s $ m # 11*
im p

IT

@tsma©l#s

b*

# ar^# c^iig «

ha &&mp I t fm4 ttm m m ^3H « of &&t&e&mmt of tho
mb&ttbobo& rn im oxd oXbm^ .group® so too

lm group I t with

tho mmvfatm bh«b m Mmor group **» tsitfOi&iooi lssfcotta of a

& mm
Q w m ftV

$ * ^ fa i* io * 4 * *»®fe.lK)«yph « *y 1 } t ^ t r m o l m

* r f '
rn ^ o

C m $W8
II
I
f?
W

%m esg* CfBg *
For

in. g rm p *# tk o asbebltuonbt * t tfao t &na $ petition®

of bho bobrtasoio ring wmo rmmooft m mmsmmi with thm® in gnwtp t«

$ovo«I mt&fo&fa to t tbo tpabhotii of tho i*S 4ioab§H4ut*A hot***
totofe hrnot bom rtvt*wt& by Boston {#«)♦ Am®$ tikom tho von irons# tbo
Plsssroth &t*a tho S M I i f^oooiStiro opf*®&r®& to to tto'MMA pret4 »£ng#

fh# von

%mm pmoo&nm

(SO) hoi

hom

woll otbsbllthoa

m

«t isothoA- for

tho profjtmbiosi of i#s tiM nti% ntoi hotm tolot (f#Sl)« i t tnrolvs® tho
InbtfOOblOsi of i!«tfttboHttafe*ft tfc$s!4 ot with fJhot|hom*r po**t««hi®ri<t® sM

tfm tiiiit of bho tssy® tbtori&o* to

tom oA

with hydra*ole ootd# Th®

otopft tnrotrod in th® no* of thin prmifitr® for tho propomttoa of bfe®
OoteviboA In bhto work nr® oatii&od i s
flp tro t* fti# Msmobh f»o®«ta*o (I t) whioh lw r t m ooopiii^ of
Mombiooi nrowsatie ooloot with m m * oM iiacyt hy&mtisot m& oyolita**

tion of feho 4 tmrity&m&i&m m tomoi in i p m

tXi&lino toXsbios t o

not bom oofaomMfy oMtiotiU Wo bowo i«r®*fcig»t«a this mothod Is ardor

m lU

to d to r w to it® Ito b to o a a *

tfew rw to io B t in v o lv e or® outlined in

figofo 0# fha Stoil dt p iM tb f* (I f) nhioh iiwro&ro* aiwply t o Ito r *
aoh to of kobonot wilh hytms&i® wolA In tho proton®® of wmeaafert&ad
to fu r ic aoM la o o to lto o d by aid# rwtolossa whioh art not oMUwi* at
f t rat glowo®# i t t o t o d ltovtoag® t o t to a b ito n i a to m art
Jtefto «# bl»# wajar p to u to t o t o t o o d by to& b itoy am tl omatoa of
b o to to a a <®£}# itiatowawra# 1m addition to 1#$ atmt^rl or M ato
tottiktoaa# tow® to t m to os my b# fo-wto (%%%$) and ohm nmyfmf&H*

#*kt kotoaoa
fin
to dotomina
^reun
*pT|FW W
ViVT»r ww^orodL
*4p>jaF=Wm-» i^»t^ir bottaM
*W 'V'I'Pwt
■■#■■# noootmrsr
iWVWtW
t’wIBHpWtV nahi&
*•#■■'•h
"*• |F
teOT^ifWt»n
wigwtot la Hi# otwg&oat itoanoo# or to oopamto talwtorot of tm m lc
p w to ta If t o w ip o tto of both grw&f® is iKtovoS* wm to * * rmmmo
to

flN M ltb iw o t o o r * w m t o

to to

w a to d w ra d a t a a a t l a t o t o y aynbhobi®

f o r o a r fa r p o im *

tho aawa aXtoywsltrwwlllaot Mtid bo tito at torblwg mb trial*

in both tho vim Umsm and t o tiwwth p^o toroa# of fcbooo# S<toto* 4*
Mtreimito® to , to »liw toto b * to a i to © # nhloh
to o dorlomMvoe of

t o iM

X to

to tho tobm*

&mmm 11 t o 111# m p to lw ly * war* atotabXa

fmot ooa^t-folal aoaroot# fh* botoaoto® in %vmp X m& IT# roc^airoi
t o fto p to to w of tto tm to to b w H to to o t o . 3**to.atototn&^ph
rm p to ito y # ©r thotr ® to &•&*«&&***«
to o m t iwootoroa war® atolabX* for t o |T@patoiom of tho r*#gair®d
w lh ttto ftto lto o ® or ftwaotooa* $H«y mar bo ooto&oto in t o groapo
(a) bhoao iwolvisi^ n it rot ions of wsdtoltiaa or f&*a®biM»®« (8?*ft£»88#
$0*81*8$*8$) t o (h) ttaao lorolrlag partial r u c tio n of M n itro to to o s

or f& otoolot {$&r®§#to »

*

18*

rxmms i

it*

r
m

j

V H ^ 'Nsscast*
*

{a * o o ) o
i—

- \ y

>

I
ro -K X

i

o r seoci

n_jr^^xusitt*a»
* T - T el

eaiki' v » • c»b*
M|
T
j I
'I
—
••___*
o
* v Mf / s

m - K^ J

- ,f

scA ^ i

m 8

---------

\
___
*
*J|fc
Pit^ M
oofcalyrtj

4» <M t*

'K '

»

Ogir y ■V c n e i

■^^SCOQB
j

s o e lg

H*
a y

e * w -r

HE *

e % e \/s

o -f" N e » Mt

Writ

*

%
Pk» catalyst

•IS*

t j 1

e jy r x x

1

nanus s
Bliwefch T«UiMia SjraHuMl*

C V k '-’y V 031

.£ J

JlJ

3
SO

_

8 »e0B3SEK0 S*

8 P

■*

&»♦

m g \/

d ll. H^COg

a ll. a m

|

*

a L o -r^ S * m
* I
iI
II

w * % .;

« 3 4 «*

.

H»fOOH

m
W AT

:-------- y

& A — Mb
9 * -m f

m
m%

Attlrtttgfe in M i l i n t e e i i w ^ m tm of im m sm m jr U# fo iw d t

yrooodmro (a) mm m&mtoA far Hi# $ra$oio&too of tfe# r®$atsit# iofcor*
mdiot## boom## It mo abort or tn l did m t isrolvo as may oto^a*
M
o
o
#tb
,#d
tro
o
fe
iirofg
tflo
w
i#
#
# of H
i#i&
ls
m
ym
daain
e

MU orfeho*im.m ftM or#

o
r#

in p*#oisldiE# and #w$h#&#tidltt#» i t

no# m om ttol t# ooioofc eeodttioo# for tti# oltrofcioo of bboso ®mpmM®
water nhioti tb® diraotiv# isMum## of Hi# o lta y p w p mold
91a# **#■# o f *4m*nfeY#&«& m lfisrl® &®t<t m » # « ir« a t fo r tb# oibm bioa of

$M#wsi#ldlt*# «&*##* fcb# dtrmfctyo tesftem©# of Hi# omlm grcmp to iarg#
m p ie i f wm #ytlio*o»jm to m$o ### apmrmbXy to $b# £o x M tta * o f an

on^mtom loo* tM #r mmh

Oh* •rtmfeliag offoofeo of bb# atfeeay

group oad iftto imim greop m aid t# dlr#ofc#d to ifoo io n $©»lbi#a and fch®
d##tr«& B

m

o

l

M ' i l f i # mo mg&ograft for th©

d

bo tb# major product# This
of tho S«ait ro**4«amino&Msol #«

fo ovoid tfe# foimfciea of i mmvm0 i t is «#«#nftlal to rogolab# Hi# #©&*
dibtem Of nitm&i#* mrsfolty#

toot yields of

t 3r®~4~aaiinmni<*

sol# m m obtoiool ntim iM R io id io o mo dtesolvod in oomootfotodi suXforie

#ete i t #

to m tit at Hi# mm tfMprafeoro nrtttt ©t*#t #©ii

i l i i nlbfe a ioa&t oamsafe of t i l # #

$&$** %&### n a l l t o the dm

it m l i##m#r «r« ©bbfctttid to 60 par ©out yi®34* A blation with oosfclo#
p o p lM # ii?'

Mytr&S© or with laobuty'fyl ohl©H4# ltd to th©

m M ito to t ooilidos r®*$uir#d for bofcroaol© spufciioil# (Tibt© it}*
itite# tli# ofcroigbh of th© tlrw ttr# ioftuoss#© of the sad.## gimp

my atm b# rotooot by ooyiofctoto# piotoottiR ©£ the

m &m

group

in

thi#

mm&w prior to mitmtiom no# it#© iar##fci£N&#t» '***# batileity of bh©
osytmted aibfogssa mobi s t i l l i*#r*alb sa lt forsmtloii with #©mmtrat#d
sulfur!© «*t4 m timt Hi# ttr w itr # Sj#lu«m©o &t Hi# aHmor grw*P night

bo # f$ e M to
of rmofcf®m

pmdm&mk®

mm inkm m

m itr Hi©## ©©oditiom a# noil* This ooqpsn#*

fo r tb# oltrobioo ©f

orw a tt yiolds w ® bo&bor la Hit# I m te iy

febcM#*## th#
#«Pitenofel£!i** m# ooytahod

by tim tM st with ooofeto or proptaii© oHjytrid# ©ad ib© nibxo&lon mm
oorrlot out at # c** in & Mtstoro of

oooble ©old by bb# adiltlo© of

mUtati# &©M anil

ooid tllo to t with a om it osaouat of

mb#r*
ft# tifefiiot#© ©f group v iN^uiroi iMobftfeitobot amid©# of jsibrm

otiiii© *#16 a# Mwmdteti#-* Sm w it oppmook** for Hi# # m « i i i ©f
*l**o*«i<lii# ftei&s would t# (*) Hi# tt&tfition of th@ ©orrmpofttiog *lfeQ*y
fe#6K#i* acid <S?*S6#9#f40»4l«it)t (b) bit# #onr#r#l«» of aa
noiosl© by tb# Ofttttftipor iwofe!#* to Hi® o#rr«#p##dl#g «r*u© ©c^ound
fotlowod by bydm tyiis {4&*44»4fi)t and (c) the $wb*italm

mltimfotm of #3%t ©r ohloroolfcyl altnmui»#t#» (46»47#4B}» Th# ##eont
frooodur# m s of torn t*b#r*«b boo##** th© nitrmmoMlaos oblsb wor#

**»« Hftertiteg w to fte l te a bha ayateaate o f fcha
te tte ., *m M b« o o w erto l to te th« siftro an islc aeida ■obteb w ntU s«rv«
M ite m a c m *» *te la te a tea ayateasla of tna laomarlo l«ad^l«4<m uyU

btetaaoiao*
(*)
ca

-oe^ j

tm„

e x r o sjl
« »-»oa *

____ * -*

Cb)

&

^aa.

V%:3
-ooisfc
(• )

”%••*>
-------

ce!
-®2*
w%
”'b©
c

m
SSJg

ae» +

, cooa

g j£

v “— >
—

m "T\
- wv

^ ■, 'CSjCl

m
®#%r

ffe# utbmfckm of om&*&#

^

_^08

^a

m# 4M&ttefeo& oo too ®it^Xe«i ppoooto#*

was ooooo^iiohod % lioia&isgg onlolo »ci& wIA

aifcrie

o oit at f # c# too loM irf# albrafcodi omtoife o®X4is or® feo&3&l% %«■
*•&&* m*$*

c* (49) «&d *fe« $*o*sbt*®*4*
c# (49)#

OM&ttoKf&oaftoio Oftid* -*%P*

1%mMfr

tlaft nltm bioo off oitiol® aoM wm*X*l load slsaoet ooofooivolp bo tho
gHalbr«i*»4^s^h«w'b-0^0l<3 m M * lb h i ooooisofcsy to oeftaMiofe bb® lOonbiby

0# tb® ywotaiA# Btt» m® oiMio&iofe#! by

of fcfe®oasilit® oat

of th® saobtorX ©afcor* both. of otiioli hM boost f^rwloutsXy domribod to th®

OOOO Of 9wi*tbs«te4^

ooi4 (49)« Th® oub&fctbabos! *«dd«t

~ 2?«

fo r b o M to l® ^yssHiotlo m m #r«§»!r«a by brant**
KMb o f H i# # # t4 o lth kh%m$t MmtUkm bo fo r# Hm ##14 itito ry to * aisdk
tspabM ab off Hi® to b b o r *M &

o r #4Arf&ai*a#«

•fOf Hi® pt^uM tOfi off fe#lMMM&*i by Hi® lUterobb p n o b o (If)#
#

.off dio^l^arnoioo® vm **#■&**& ia M lb lo o bo Hi® aiiMiboboff

OMSnbi® orttboo*

0 t * lt * (SO) M l rmwrnmdtti th a braabaoafe off feydim lno

!)yta & ® w fH t fey## mtm off # M to ® p ^ r^ i4 o #®i M fc lo g off bit® rm o b io ii
sitobor® fo r H t#1

or 4t##®%X

J ^ a a rlo H * M

% t# » r (0 1 ) iwopMNOl d lo a y i h y ifa s tm i by iaboraobtoa off oao sm&o off

m ii *i£$tfrt4# mA 0m m ti off bydmisao typOra#* m SO par # M #$»#&*#
iotm Moa «#

0*

IM y t l^ rd M liM war®

#Off M b

by iatosoobloa off i i

bffttmb# ##ft*bt«lfe Otbt* WMftt*

pr»plo&ic

*xd$?dH4 **' on# i9w^#yrl« OMfcydrld# $ibSt «st*sor mMt%mM&m off Hi# pro*
#Mr®$ im o o m M by ibo&i# «#£ Moorl#bl& m&
’ fb# i # M

pmm&Mm for bobMot® ogMmtflr (figar® S} moo

iMLla# b# MmmhI** bfe# otbtftfb I#' bbtol* 1%oeoM b# # p #t # 4 owl mm

nt#®4 bo prorlbO '#s&. todopoasiliOSfib byn^sbboolo ffbr # ita&boff oaobor off ###»
foMt#«

M%m@k

lb M l# feo #fpli#4 %* bbo propoMtoo off l*#*Ylb®bra*

##!#» ##iy# Ht# ph## 4buNi### *bb###bi*t f t mmlb

bfa» four i « p # b #ff
iootd be

rm M w m

M i off

I f f - M i off Hilol* tobromlo M riM tim o

th e am# off tjy&mool® oolO o r «#1#ok«

4# Msorott* #**£ M y .M o tori 4looobyXby4m*i» «&S m^*boMeyl«
liy ftililtit* fo r bt*o p r M » b lo ii off

bo&imooloo* i t w m M l i M

M

l< H M y W ^ « # rb -

l g bo obady if&obbor thio p*o*&>** oooia

bo- oidM M bo Hi# oyoAMI* of obM

*tft*

th is

M r Hmmhi t# b# fo ttib i# m i

N ^ i i f U ***t

««r* pm**"* %

^

mmmm

bttHyiyl M& 44#-WmbyryX feyftavnlttt

dtfNNqtaNgrl* 44m
i #«ri«« of 6i*i#feU#l

tm tn&tnp pmStemmMtim* m*

H
a
d
'
«4bf#M
ll4ii%

w
a
ft s
#
mbo*

W I 3 p » !h I « # m m mmfrm '*n*k

fey4**#is# mm Ha#

.

ayiXliOi by kpm&rnmfo with ###«### « « it a fcy4*o«l&*»
41#S8#%1##4 MHbiMklHiMi MS* ##t»p$«di

itpsnpioisyl &mt

fe
y
&
s
n
itwm i dtoanbiM
'

nIH
* 4i*
fe
y
d
m
tta
o
# X
»m
o
bm m * b
h
#

pnpioM
# ii*awMy*yi M

w
a
r##y#ii##d%
#in#
mA
444® w
«N
af##ff>s0^ifia lHaditdfedltttMfe
^##^s**^
wbboO
M

4#tty#%
ir#
»b
y

jfl jflt mffr"P#n^iw#
ijHjmnnifct'ffruftLiBt

44#«*lw4yiyl mw& Aim&mitoAwvt bydraai## mm only allgbcbly

M ubi# in m l# # Hi®

mmki mat b* *«#fM a»b In dilute n i i t »
%w m
s
#a
**#
##
*
?

#
n
«
#
ia
g
«
a
®
w

w
s
#®
*p
rig
p
&
o
n
y
*n
y
o
rK
S
in
®
*

ft#
#41#aM
M
yiyI m %km &i*4Miy*ft

H
im &wm * It m
b

in 41 into M in n oorbmife# eolation buff arm *&th ##41im
l e M i mm rnmkm byiffm li#

ms i l l t l 4Uo$wi*# m-M% bb# 41*

##yt hy&mtfLm kmmm mlmbtm* tm %%m

M otion M tpll% b#e&

fl#o#ro
sy#
m
#
#
b
b
tyn
ib
bA
i*i#felt«&-iimli# «
n
X
*s
#
s
*w
ltti H
i#ffw
aattaa
of m
m
m
yd
n
ii'M
###
tfe
#UnMimMii m
mdim#y#li*#&t®f»» tn
«

4
®
*

rlvm
b
iro
tb
yImbM n
lb
ti d
tlis
b
®Miw MiMtd* Motion* ftmmm*

%m H
i#-pmmm&im o
ff

a*i& ( b M ^ d i i M l i t o ily or #M *##li4
H
i#

i ^ m t ^ after

fiditsMta» fe
y
ftro
a
e
itl#M
nH
tea* fH
#*#$
**&
*«
&
•m M

*19*

fe
®

b® m XM tfy mm®IMagy by Hamming bh® « M k i ntatoro bo « * c*
fn | M i l # tb Mtf fo w l bteb bmting
JmmlflPHW
iN?flifc'*%ift^njt-' jjtljlli
L'jOi bH
toK
eflf»c M
lBi'dm
b
WOTr- (jtfniijhijiljfti.jt **4t>| dfti
mttfk
ffcW

bh# *$ro$l*m%l#ft an!

jBuji*

■ffb# Imdbin^bmyW and
paM by bfc*

pp®*

proeMra gy» tfafcnt In fabl# I M M th# yioldt

iM ia ii by Hi# bom immm pwMmr® for tho

M fw & la mr# ImaMM

fo r ooap^M # In moH iM am a tb# ylmM igr bbo m %mm

ft# rm %tmm (nmwdmr# wm ®pfii#4 b® t&r §yni$»t*i off a lt bofefm*
®®ta® i«am$&®4 i» tMs$ work* ft®
w # #i% #f

for th® aynbbmim

or

mih&^-mikt&miltmm m m

W

mmida* ft®
with mitmbl® amid «n#

liydrldm or *#!& MSM&m# aM fb* amlXMm a* ffotw i wro trw to i
im m tM iM y Hbk ftimtfliom# ptmlMNftslmrli® and byteM i® mold.bo owrnrt
m m iwk-0 btio 4a®4M aXtoo^ibroi^
%%m mm M

CMtlybi# kp&m&vm*

b® mMm t&* mlbr© p m p be M m pimps*

tbmxbimff with

aoid% blit

mMm mm. pN^M d by w s rM m i of Hi# tmMt bo Hi# »«M MorMtm by
biMrmib wfbb bhtomyX M lnrld** ffottoM by Imbotmcblom of bh#
M o riia t with

p tM y « iw »

f H w l * ff®wwfei«m mm

m k in M# mmk my mm4«®#rftet for Hi# m ilM m » fk® vm*M,mm in#
m l’M in bafeh pp®###®®# mr® Mllmod i» Flgm*n t*
tm th®
par e # mmm of

m of alko ayM b in ^^ tb ^ raM m * a fftm bo t n
pwdMiafid® m# M ad b® a bom***** «***

yHMti&ft #ff 1b# Matsttm M M i® % nw w fe bb® tabbor Into bh« M4®
Ml#rl4t% fhi# ooaM m#ml% b® dten® by &titT%m$ a «iKt»r® of th®

TABtS t

M m a n b

abb

I

tl

i^WW
W
W
W
'

C
Hj

M 8« 1S8 »E

238 *288

m

m

<
3%

U ftO S t

M9,S»lS0

80

$

«*%

1* M H N * »

IM I

TO

m
m

d
S
ii*
Is
rfiL
r^
O
T
ir

SS4 «

49*

§6

6

1M M M U M M

M 9 «8» 180*S

88

tft

8*08£^*(i«&
&
08*Q^84 C
B
E
^

iv m i

1TO«6* 1? M

w

to

**0OS%*«*!%*e^, (M
g

liO*®*!*!#® 240.241

8*CC%
-4-®0g-C68gC
8%

1 1 4 .1 2 4 «S

« IU S » 1 1 9 .B

n
n

I6r*e.ie9

n

m
m
m
m

W08-Cgf?4

8*88^*80)8^

mg

n-C
gn7 llewllB
g-ecHj-A^Bj-C;^ i-c^ 7 ie?*ieg

214* 118* *

* M m M tm m m * ( t % )
‘glr^^.inanmicfcAH.iiilgm.juJt. #ttgikgtt !**»**• ittWtffli

«&&1»

e

in Itmmmm

of WMemtopt m&

mm

Ms in th$ cme

&*isii

-MuMgmiiXt*s% md tM*tri$rl &ss4

iMdfojrl Z*mit

m

m tnmtmmt *411*

®ht®r%&® wm rnnhr&k

^ ^ 0hZ^la-« uM«r %hm® t&ts&ttaa* Xvs&X«*

mM.n$* tH$t m

o&Xtts$&# mm

«& m m

pw$ma$*& t&iFsd*^# ?h# rmtmim nfagfattw m*
4tttart4# 4w^&tM%m

mm

t#

tii&

m » ( i m &it

in t& * 2««fc ism mmm# footling

t% m®

&*

l%to& #** fmrmtapmmii. of
mAw 4t«o

mm «w£t*r

«&ai mtfa Am

t&leri&oe ty^csSt

oror*

4**attie cteMitioao jr^pirm ! £or fch*jir J?wwatfticKi in H i*
n&m** m m in

4*ft&iN&

im&mQm# m m tloafe fi®Mu of th *

rm tfcM o& i*ttfo*oqstt®afe twmMmk ol.tfe.

&§!&*

i t hm hmm «t«&*£ fof w . F&ofows (885# 'Mr ««Kl Fnlr^i«& lg ($$)
fcnd iw . Bmm ra t

(M *i$ *i4 #§4)* isfa$M mafa W ^«

t)M « 4«sptv*4 f t p Bw&?*rt mmmtei® m£Am

ll

m$k®t m M tita M i nrMmmmtit fhmftwl
iattKm### iM4.®

«pitm #mM%h&* For

in okt&h F* mat

rc^aily cm

mn&. ^ « s &Hj&rMc

ott& %te» fom ftfaa of m> stll^l chloride

«&$ *& ix w ftto a itttt* (§t*fi#$4)* XmSAo
vbmm* W* mm o ttM r

m

of oli$£m$tr* &?44«»

or mn oiI|iteDfci$.gv*ep m& F*

«t*h«r alt$N&lc m a w » lle , dnmpd w w *&r« «s«wtiS>lD* th# InetD-

MXi% iwd*
MMk

^i^fX$r % a
awliw'fD m tiKitciwi^lD #M,ft tn

*£ tti«

fwmi

%tt# imi4#

^ #Kar...-<WiiiifiaL..&

cl
it

•$■£*»

ia th« fhX^wfc ^ sitio n
nitrogim# C ^D sm tioa
XM

«*!d4in#4i^o

•sateWMfttoa jw
sA
m
rtW
i {2**84,38), Th* ehssg* wild b«UtMavaO. if R

wm-'m mr% In # smtoteiag «

is «»• wfeo pontt-lont«

th» sterogw* tot ha* bmttt $w
tisfe«4w* *gr Harbst sal N«wil»n {Si)*
*h«<*s<sr**fctt>ts« ssnownteg

iHMblilir «f taMs «bS»**4«* ssre mis

faring ifhtfSs* tiwolsiag ttwlr laolsfetan sal ptrlfteaAiffS bf Atefcilte-

%
|(M| OOfillj&lHots
“ ffiwr^
“ wwpniwTgpK8T

'PW
’a^pp■ t'* np

llfoXiOiP
MW
OWil*
ais#
’B

sRrw^w™
T wwWwDir

00(00OIMOOO'^WWfrD^lipWp

teg to mm Stew1* srltwts ohuuli h wMtsbla, 4«m
Mb* prspumi
sftf
ORl®!'O
^pP ilBfc

^BSRstdj¥K

'ASoR^O'iSsD

jPk.ArtfcDftlt1j$i

Dp

ISid &
fcfeM
A isfflpmP
feMdttok mti&tm w
'ifei
Jb
^niiMAijfenfcik'ArAiMOo W& Wiw
flttntdp %SVwElw
■«rw.
m80
W- ^ fffcifi11ifi‘i%ffiihifriifrwipii P
Tirar
s&
fSiLrMpsnspiMTOvWBSB

sm
&
ffife
ttF W
tiBf1^Op*R im
M
&j&
ilitfk ini
#SW
;S/W
&■•WP’OOWSOOw* m
tm
*W*W
*O*P*P-^flR ^»Ww
SkiH
•w
®W
bf J
Otfitfttitiifc
PUV'^OK ^&
0Viifd
SWO
ffW
wWD
IJIW'
jfTW
“ W'
flfwW
Wf* IW
Jppm
W
P^r'&fcik
O*“ DIN*
w
yio & t # f

J&jMtt

rttrfitiirilt^
TRT“ t^W-'’T'J^*1lP|<*0

im foo^ o f # $ tt# iiio t e t^ i t wAimimA tfoot tfoo

iw
l'JlA
Ipplqw
WD
p^a^^ff ftliXfMri.^S
ilrR'bO^rff

S
jfe
,fi
■'iM
WiW
’^r m
^PW
.'pW*•*** i!?Wmfifammi-mm
"'™--^Rr'Tw’^^^^^**^nrrS(F^WiW
-

p^^inud Iqr

*A
"'(I ll
ff

of1
w
t” Hia

t« s 'mmm ptmM m* nm ttofood in fmfol# If#

in fnfol# | :# mm yt# i4o o f «. .m foof' o f n itro g fo ^ rlt^ fiio o iiN i

p^p&rod

A..,..-^. A:^. ^

ift*^<fcii*etei Jl. -■-.^-O--«j.Jt dMtetasik il^ttitim
•JfatTihVK
11MijftnIts M^ilrtiihiiiil' il)■ffftih'MJrf. H
M JfclAlMtMW
IiAft(M
A'YW
riflT
iwO vOU w
RISSB OOshOwBrO^® 035^ W *®w
Rf#*®W
p*f™ mwfflSW -ftrW'
OOte^B
wrw
S
I#

X%to oop^ront' Wmfo mkrn 1*m Bmm-

psro

pw&AmM

to o^rootol% hi^h y i ®£0#
ffe#

ooro
lagr

ooto%ot

)* Jtltfoooofo

r©4noo4 to

onim ^

t^iiogoootfon in mo ir^Boao® of ftn tiw o

($§) mmmtiM in ro^xolng

iafee its uAm in in fit* by fcreetnwnb
with stW
B
m
wwshlerlAe w
adhyAroefelej’ie eoti, lb MUI eppsere* swr*
4*sir*bt,s be miase the atbre gnwf eabelytlonlly m it wwld giro a
fawn1PIMmI an* ferthsrsere tbs reduetlen couMbe stepped st the at»
prejwlete stag* If obeerriisg His pressure **»t Asrtag the rednetlen.

?b*re mus aw mi#amM s f * elssmjse ef the tsbm sole rise *w taf
hyiftaregeiMtteM of th e aifcre eespoaw* eenptrsble to that ebeereedi t f Reblio
jttejHaiPMttifefeOOMWO

fJfSiBi-"fi

'*'teSiS!p& tOAjWinPt?VwDHW j||i
jfitSr
fyfvTjrM
Sli^w

AP - W^ ^ Br WPd P f ^ 0 O| p

\—

wmwH&m tm- mm& m»m# mm trnmmmrn ym m tiM -rnrnmtip to tfoomAm
JjfcQOOt|Jfeoi|iUtf|tHfci8{irafjSfcA O
kD
aim
t^.j^
aafw
.Jkm
.O
sm
dt ffw
U£2y
fei
*M
SOp S
rJS
SL.k

inoF
yffiSaw
iiHtli
fsO
lwJUtuWiiffOS**iW*lrWi

fn^tafiiWitOrth V®/
s St \ «*$*© *ei
ltib-4KiJB
&.*. J
OO
fciw
ttlMi*fLiMtiJtaAiuMf-A&MteJttdfc
r

WMtlwWerW "W3i*s®* ®K|g£lto
iUifcW
^-ailulki.' m
JMlia- nso
vK
non

M
ibiBM
M
aw
iTdM
~1awifht&-Hit' wwpm
^hTMi*!uA"Jk 0V* 0 0 iowsw®#
StO
ra-MtgnfcAfc-af

4iKiOfam<(iRoo-OtfA^®i'

IffiR^*if^

sKiV *HTvv#^ISr®>e®w" 9sh)i||®W

iS
fiRtuyak. *orso.v*®n
wh'.ul o* A
hufet^K-L-,I*J -- •ffjimyia
*i»®
0 0 *0 *0 ®

■tffrttfoinXhkfcjt'

tm&n wiJfci ff I'Dtl-ti oi^kiloMiDiolteRtiDnwfe

flooo $$mm i t oomM ®«*3iiXlr foowsMod ^ fs^r®eoing
rt*£$
#a

j®'sMhyia^ gn**■jti‘|^i^'Tr-J'rtlftiif ,
p*fl^SiSjiS$
©&i9w*^W1p♦

m# mmt&

iNllMk. ®jfcaUrtM'D nti'Ofiill rfTlfcj#UHlk#(MiK'jfeilLHi^ji

^ iWiti •!«.■*■•.-«a^.we^.'ey.Jfefc.a
TBwf ^9r®P:TOS©p ■hilfi
mskW
B^w
Wm C
W
HaUfcA®

t. ,.». .

-1-.^.. .<& Ih^iteM ^ rlir
i~M
ff JlkkSHBa ejytti^ iftiDit stk. jb<4M£rM
itaAW CIrtlfli -A'Afe-Atb Bi-^J^I*..A—
U..X...hJ>.n
Jjkjfm jUMfjl
O® fWSmw^m
*§f I®!® osnoosos.on
Vmw «J«mo
IS®®' 3.15®
r*a®
wjSSm

m %k# oidglm l m&m n ft*# %foo s®|ssjntio$i &m pirifio&tion
of m®fe^dro^loridOw

M l tfo®

tH# oorioip ^ ili^
o# isott ®»m®tr ®of^l ao^iimti^ao m i W&m*

'Ofolo^don%m mm-

tmt® not' h®m &mmlfo«®imm# iltoio*

%
®
ro»

M$k. mm

Mribmbimm m& thm Is&AmiMmrMm mrm

Utmm tfo®'
for th-a

ffo®neo^yl 4#ri®ntio®« i^r® m$&
of tfoo

«»®th®

h g M M m fU m o ftf* # r

*M i»*

M M *** **

mfam of m #

Mao- of tfa® foytroitilorMoaf hmmM* m m hy&wly*«NS wxtomim

tiwaity la n p m ® mffteM#» iaaHoMlae tt*fc tf«* oafMafanftlao laato®®
w®r® m&y wmk bmm*
In. ®4€l%4®m & graty of four

«&& i$*®

oofraafaiMtiag

laor®

M M M X yaaM triB ^^

sm& 9*M&ttodim&a% o mad X ~ s^ ltfo *

m f m® miwmp?*m%in$ &?&m &me*

SMnrl^Nnaftlsylj#

M

Ins*

only m® Iw^it;. m^b wsgt* mA

l«^osslno^i^lAP

&®4 not 1»«»* psmtmmtf 4 n n « iM »

*%«*#© aon#mm&» war®

fNfa^nrod In or&nr to p w ld ® a ba#!e M r OfKptModw In tie $M*wfe®6Mfi$«feX
toat® t® *hia& tli® g w i$ wa$ iagb$a&t*l* ft«A to m m if; * wapuiiMm of
tho B lw tfi $#$ m# ’w&» Bf^m pmm&titm with oosapwda ufam® IdwM ity
$m& hmm pmt&mtity awMfoltoMU
Stafc of ifo#

km® h®m mkati&imA fo r

of tM tr $mmmm%®0m& awHas®* ^ nr® Mi«&tfl& to ifso
M M s H fnhomtori^© of ?M$m# ftarlo ra t

M r jaN&fatoWRr r®»*

pirfc® is&iofe M i@ ili tta t tb« ooi^oaal® gpiaamtly *&&&&$ 4®or®a®a3&
oottfs&s® wpHs. Hi# ®#ntpfcl
steaM * M M *« M & r*
H tM r

.®$Ng%#aii# M l # f m # oaewiMt&i toafeodt
am natlow nloftist notion a® awakisarM by

toaarl maakmX wmm® o&istal&fsfea mt&i m pm^m^^i-mm(BsttaaotJ* m& m&mmtm

notion* ffe# mml%$ nr®

mfo noffltlaM X y PW lot® aft tfe* p&tmM f*%m t® pwMit *$so1&*i&90 #©»*
t&# affoat- of #$f®®tat** uf®& iM rm ootoglM l ao tiT lty*

*4$*

^jm
8**41/

^Wa

jfcflL*. m
Jjbtw
w&to

jji *■»»&•!,>«»TfiVfvMfiirtialA^B •^■<0oax
—-~-® Al ^wAidkhiaM
- mpwwm&RmJtyyjKMkAMbHUflLhMktiMMtAfJMlaw©
(PanA*®®*®

mfo M M mM othor f e m llk <#£««&* of
iw i

to fo# d w M of

ooaps&Mt#* fh«y

MagloidM or nmoMeid&X

notion®#

-&(***

fM.« m p t i i m& $m*$mm4 by th« t&tmiioii #t

a«

M* isttaSgr M « « (iw in tM ttbmMem t&
p fcH#

IMiift «tart*S fjrt*®

«f 4foi* n ®

tpmalii&ttt* (ft)# &*

mriUgrat

fc#r® £#* f t® $*mptvMfel«& V t&lmtifetai *£
iftufctfL'rife fttrfi
<iffcim
Wi-T
jBl'lw
ytiitw
i^ flLfli JiWittrtjaViMaiiiMjkk.
?v.M

k.J
it w
ttu
i&i
fgWmws f\ Jkir WBMJw
$>

*4ML to mmtt MvMfam o ttt
farit* « iH Omio^ ot #

0*

rilidinartn>t<f 4&&

trt

isw
ittitf&
fe
*ri®

InM 400 «&• *£ mmmfemtM

MMmm «f D90 £» (l*M smtrn) of

4

n ltrl# mM (if# gr*. S*fS) ®as$ 00 §
m

mCtt fc#

if

M m «4slot 4*0f &r Oo*0 ofc fc&i m m

«»«MIm«I f« r m hm r «ft«r Oto

&oi4
ft®

mm

*£ th* «te&i «ft* mm

Hf$m$m$%mbk* fmiwOlmai O M ® «t*$ iWO g* wt im$ * imOMifemm

tmOSljfe insKlw pNMilfiitst# i f mad*** imlifet# «i$iio&#4 * *!»* imoOwi tttlftot*
mm ftttm m l «o&

«rM* m%m* ft* m%%& mm mmpm1*4 ia maMr

w l i r a ta l ai% m

i f OHM# m m m mmm&& ta m w **b I t list®

iKiltin*iu»imiiiinti'iLii-iniifrnffril"-i*'pfi^F^i^riir ifr

*

mmZymm m m

i l l ®m mrnymm&m
Jfamb feftlf i f 01*#
mm mm
% tt#

mb by Mm
mm
m
In Mi® *K$*iiMMi44& jftyt i f bhls t&mis#
mm
mb by tb# w lt#r§ th* tat*

wit

i f £k#ki#* lliln e li*

to# rnlm * ton m&m tnptntonft m

w n to ln ##&* feftor ©hilling

wm fiHtwwi bar ntsnfeinm* hmmm nito ^st^r «»& ti«#ol**

ton

#1 to tofcn** to # toto* totat&nn m * ftrtnA mm*

&#&!» imltoto

in i fiito r n t to Fmm® m$ ftoni* towiwfrto topit&ton®# to# totrnto *&&
riw
rt&^^W^Cfw^PhIi w
H[iJkjjV
rlattfi'^^jpw^
lfrtiftti m
i‘Hh
tifB
ifjv
fra4XpTw
tw
v$x S(ttr-ti
*u-*±^A Hk.. ^
W
ww%
M
p# 'W
W
£tc
wEfa^r#
E i^jt^£

fa kwiwfcit

^-M
t.ttfclllt jfc..^Tl<AiJUtiklft
*4=
S^ASiilw

tmm to ito to top.#iitot m M pvtmm* m*$# Sl4f® ©# (m w ») (S fJ M t#
»mt% mm%& ®i pm&mtM mm

Am

% ttlatolmg

to# yt#X# mm loo $# w n *
pm Mm to $$ pm- nmk #£ to# to to i^ ito l*

«pt w

fh# Mmmrnflm

m& lM *«to to *yl m&m*

mikmm&mtm m m pm&m& % mmtomfc «tf mm
ustes# m&fi

imm»H#

fstm s^

:pr#$4#mi#

m i % rnm w*fl iMUmM/H »«4toM *tiar*
ii%<m##14 •stoflNM** #&# ##«4* m * tot# ®$ Mm
mm ta s te d

mm &®i *. M i m tm #f ##M

%t% p i to#

m s iiM m m .iitotoM Ritt Imh In i# i J t l tatto©©##* pu&tontoi'ly *&#&

i»dMgr>to iMwfoy&ito #&» «mm4# ton
to- ntato ton m l i f i *

m .^ m wm m m m mm$&m$?

to# ##tstM#is m# tonn m l# # «tito#$ toto w ltr

«mi ton to tti flitnrM # ton inmtottoto* nftor mtoimg mmmmtori&p
* lto m##r# ntiM #

ttMitomnto nntonton &jwI #&tor &$&tm to

**#to

Mr

m M or

wm swni'roto&HM tmm tto mtemrn iw&i~

oofeof in ti^I# II *

tkm S n M m ^ tI
(SO i# o f

w « y M p n i % omUos ammIm

OblorM # C®*4? m&m) o ttti #&i$*r&og m & m o lin g too

* tN M M i- ioSxMon of m m CM ? nol*) o f %k®
St $*■ « f ir lo i fjprtOtno (0*80 w in )#
on Immut otOor M fto N t M M m

fOt

oommMm

S p& w lO nH & t*

m ii

lHfei»l.og mm m M m M fo r M K f

o f t t t M g r if i ctatorido# o fto r «fel*&

M M M ollfc mtoor too iio o o iw tit* irtlO lM
S0 1 o f «&* p o ta to o^#ntoot 00 % *o&16 oft ttaio ofeo**

* n i wo* ffito w o t o ff « 4 «oa&£ii*t ofttft tit* ooS.14
oftm m iloaa; of feoofttift* i^sw «

f&o « M i

o fetalM t tor
on* gor t f loft toy #o»

iifOtaiiiiMm fog* %# oo^rootoIniiositoi In M l* XI*
f&o
mm

yftyoioOl M M « i oM m ^ M I in to fo r o il toito

$#oo§rt

«** lonoMiooi

mm*'

in

fool#

11

&s$t tom*

112*

1%

tis^
M ttO tyyl f o n o f c o l o

tw tei© owl

Css)*

oit^^onofcolo mo ooffioO
IpSj&flil

w t pv*o*rwl toy %h# usatotssd o f

p^pm oiooi of (Hpwffplooafi

m%

in

m m tAm m m mw

oaf is- glirom no &

fo f tit* oltrotolon of MmotI i&mtiM&oo*

Flftoy«*otg!ift goto* (0*8 « o io ) -of 8oo*ooio«arl

im p* iS *:M # 0*)#

f mm m ^ m M M im met pmf&omlo **toyftrlOof

T

A

S

U

t

t

8«*art AmwwsmoAinsow
SWR68*
aasasgas

m **%%

&f

%?*%«

tliM

CiytWL f&m

fMwwfe

■Flu# «Mil.«§

4&tftM0&
90$

8*«0j-8«0CI%

v $

109.8*110

ft

8 » » l« 4 ^ ie a s

»*% %

181*8*189

ft

Ptfimm

i * csh7

181.8-1SE.8

if

SurII pptmm

§0$
afcfo&tasol

%%

181*8*188*8

ft

ffw aitot

$feh«gu»t
0&Ja*ml

*-o e iy *-» © #

mmmt

m$

W$

8 -O C % -8 *^

■»WV|#^w 119-119.8

ft

Pwimm

8-ocSg-e-itOg

1*kC^Hi^ IS?,8-188,6

ii

Fia*

101-101.6

4
9kdA.
vm

m-r3s*t9^
frhW
iW
brti isvtwi*®ro
n^hifl>rtlhiH^I rtrto fhi
Oirtiirtrimnhih
V'©
vfrwSmWmf

109,8*109*8

if

Sennit

M 4.S-120

■$&

fim m m tm

••O M ^ hM M l
t*OCHj»<*l50g
8—OCH^—4,??Og

C8 ^
TO—

*80*

§m

$«?vi9gMMi

b

m

»

m

$

B0
M um i

ta s k ;

m

wnraoosR mKvmm m iwum, Am w -w im v®

s» •

«*

F c n s jlft

■^oc%

r«H»suft

8*8Dg<*4«0Ca<j

%%

••w y a -o c s g

anCgJfy

» 4»g «4«ec%

l« e s%

S-OCI^-IMSOg

%%

i^ S j-e -lfO g

1>»Cgi!y
i* c s%

S»0CHg«4-W>8

e *%

8-OCHg^t-WOg

a 'tijjty

8**0C^j*4»S®g

l«Cg5%

% >% % %

H

M

fr

CIO % V 4

» *•

3$t4

11*8

U 4

U «l

U #t

12 .6

1® #4
1 **4

% % % %
% % «% 04

W

A

n *®

i* * d

m®

ju m i

U #s

11*9

tt* t

U #t

Mm
&Mp
**£ jm
&
m
fam
dM
.

f t S iif t t * * 'H fttfw a i$ $ r

m
$&m
m
. 1 ®$ $& *

a tx ta re

#f

* *f fc$ 0 &&«

**& $ *» $ & a t e** c *

4 m K tiM ’* . * f I f « & * - r f u r t t iit t awnM ( * p * g * * 1 * 4 0 * $ # #

&$

10

%
%
%
&w
m
m
m
M
®
g
%
mtfe »
m
miw
m
&m
**

m M mm mMM

mMhmixiiK m^&mMfmm
fttfefc-jfty. HHi,«>$$SwArft iftiiMI mattmmlkitttlMihSk. -tatfMiJili ilfalVi t^ifit ttIv iff

tnihriAiii> M^^ik -**■ ■■* .A-JIb. *mriiflfr mtowr
~*:A Mt*.* ^...a.
WliPllfro imu wtlwSl, piJwPlWt•*■wipJ®1
«<*$ wwEs
Jrf&iWPr pif9fll$Pi$nWR#

*Mw

iM M fe $:$$$*$&&! m t

« a* n M

^Pjfc|BiHt jiLMNk^fcjfll'dtb

a lc o h o l f
upL^. 1

« tf

m
m
ffc M

ftw jp ^ r^RJk
s^P

t I t a$ pyp a t# &

jii'M
cwtif'».

^4*

m

tw % f% |% % §
jBS)0
p ^ 8i t a

if it**^E’^M|

^flfTWw

m%
w
m
* < !» •
flfc

fluty4?

m
m

lH

* t i&

t t 1f

%
tt#

M
l Stwf

Sp^p

MM

Ap%
M0

fWWlft i f f '80lC 'Hs$
w

i 0 n l« ^

4f« I

I t i l s' j&4flfr tute&t1

m
p* W
&
*&
0 iB
Q
0 ft ®
*(mm*}*
t%
*M
*P
m
m
tm1 * it . * i*

tiwWjf
m i r # ta ^ i

-a n to r* f lin t #

ISrtit$$ 11®^$®^#
IfWyWwlwwW

ft

1 ^ % $ !$ .

#$M

wwlPlJrWtt

mfail t t «

■nW
$#N
ffc
«PfH|flW
C'^l^bit^^&
fpplf'fJP',tintfrnfintrt^ '^FW’“ wwy$,^B "SKl
PPS-tw
r^^ *V$Rl^ntW"f "J*i f l St vi Sf i f i * JwFlW^N$iwwii^
WI$* wSwi $»™r’W *'W^
1 i» » a «dlk» ta is a la .

w ^ « l» i^ U » ii f i w
ii* i* # l#

3 s« fra » l|> t* ftfe « M

A

» ^ A i*fe « a « • fllt(« p « l|.

»®Myl a l« t« h *l»

0 *#. { m r t* } #

sm iH niI. f t

*m% #

M t- («)$■
n»»,iwwwi>wrw

HW^*#

1m m

mM
i f M iM # t#*4

fr« fftfft ty

A# * * Mm&tm 0

I t lit *

tk s

i»e fcwailirai p p

Eltmtlma
wtr# ®%rm

1© f#»«vlttf& to # *

0 im itie atM (*Mfr #*!*} **# inti## in wmM

pw*Um t * f i t riU «p vtfm o tljy t& iiw i «#Mife*«*tot ftftvi# «#M
(«g» $*# ju tts lin i *&#) i*t a

jmmI
uni $ m$%m

mm mmrn
&M m

t * f$# e**

t%mfc
ft# vmwMm 0 m

%h# nAttttai «r

atiUt

tapfe at %i:a& it e r a t o r # far tn&f mu tot* # $ to #$»ap3itfe# #Mt**

tit® t f tli# iM it# mM * f t o Mum
ito&V fit# altos*# m

i^ s tto

■fiP1$|9|t9#a#*"#'wSPswr *tfi©lw“ lfcffw* WW-ww# *#gi awe**#

iM M m # M

h® i M

t t o ftito a ft ttom gi a $1*mi #$«& pat %ma t o

UmimA fc# 3 * « r t is^r Is to fa ito to «#4a$*

it o t o *

t t o lf

w-W

%#

WM«W w#p

#m*4# fito to mm pt#tffft*ft M

mM
Ww-WHi

•#•fflMfv*aP#jWVlfi

I t in flin t#

i l l mM M p m to to la g i t % m M % ii:m M m . a t o mmfet® m&&*

m& mmmmlMirn to to tM * m A m- t& m m lm lm t o to iiiiM sito # ®
C4i#$f) m m i w
tk# g w it o mm
It a

$#t*

« f # i« l

i W 0 M m 0 iw lr in to t& iliir t * mmmtm
& to twm 4 it o # w «M i t o i M l m s t t o l t o
e*» (# * ir *)# tw # ® to £ in g t# n •

i f € 1#
A# M il t o tto to * * mM t o BMlifMMwlMmtMMiii to 4 # m m

mpm^M ## to # t o mm mM$*$ $#to

€*# {£?*#£)« i t niNmii

t# pm&km nmrmmX Mmtomtotmm %h& mMtMm w t tfe# w tl^ i
M ir #f t i t uttm w ilii# # tif « w n «r«fttri
at

%# a tiilf#

©## («■»*) C49) tsa mm mm$% m&m* m %^ W iO * f

€ .* *

Im m tm )

( « ) #

^

to

mm-

w'

mM (&#)*-

i w tfe* p&pkimfotm of

mM ( W
#f

ehlortdu# f t $# of

» I t ) m t mtimM , for km hm&m with w& ml*

W Am &t

wm % tm

{f*f

tm d o r

l i m^mta

pm m um mi&

tk tm M ®
a t i r r ^ l v&tih

M -0 m l# « f # o M p t r o t w i oWmso i f c t # i i o t o t w i oo^r r o s iix m l ih lo iQ r l
# X $ # |A $ M l

p m ^ ^ M m w n o lia sw # # *

x%# o n i& o p ro O o o t

m $ th m f iM m m i #£P $n& ro o i^ o fe o iH o o d ; tw m ofelsor#
l i f ^ r l t l , # # m m rm w m i i r

h u t m m mik

m&. i i ' t f $ *# § T P ' f

f # Cf?0* r # } ( € 1* 4? ) *

^ihwwm

A ftro ft r

o«k&

iS
ftW
W
**

*K*«i« of

aaato® is»to oA-M to^ts&oo »AA #&tr*

t # m *M%w m h it$ ,m o f $ *S fto&o o f

$&»$>%iNriUw* X#

fh o - jf& O H

o h lo r M o *

■1%# ofct*ri»g mo ooi^imod for on- hour offcor tho ooo»

$&«&« iuM&ftfcoft of ol&srl owl»i»#. %o «olM
with mtmr to

oiMfeiM filto r oaA wwriMol

•8 4 -

mm

-m *
*tkpl

Mftit* m 4t» ity&nfmi&tufM*, Th* fHiwfea mm

m w iy v**y

1MA&* «f (ft* itwlwuS jHW&aefc »mM 11® wicevarw! «!%«r *»«®«rwbio». «f
t&* «HpMMW «r *»• «*h«r*»l pwti<n of tsfca Stttmfc*. *h# <m&» prodae*

m
otbmtre * is m s « llt* « a
00 *

fm

80

&£tatttatg'*»««

purm
m« *is y l

ol««fe® l«

to **d* kuhmw

» *% fc l0 r l

a , p . less * 6 *1 0 4 #8 ®

e.( c a w .)

»t«l* 06.8 g. (68?!)
'AaaJjNii*. Cftt«*»Iafea4 fa r V ^ o V * i S* W *« * Pwisd* s* IS *3*

w»f» 110*11?®

e#

(owr#-)

n«M s o .e g. cm)
AWklya&a. ‘-ftloxla?*©d f<MP

| '?# 38 $0 # Foutrii ??# 18*3#

;

Ht® MiMH$|rt'

:

>

t o mm f n p w l % m # *& titta a o f M

tt&o&i#

m lm ©f

■%* on* *ife* #f h^ratio#
(tip *

*s#pi $& #

e« :)iM a s *•*# WrtMMc gm*t ©f ti*# ©a*

& i*|M t tli# «##il« onlijriftA* ##©$& t# M M t 1st %&rgm p&mimm* Umi
mMmk mm#wmtom& mm filto v o l# m m M i w ith ottiwr stmt vwosyw*

to ttiio t tmm

{§$■)* tU M

f#r e«fc «&$& i&Nhoij $&•$*

e* (mrr*)

*•* •« * *

fit#
too mlm mt p w ^ M #

mm

ty th# gi^taat as&£ttiem ©f

t© ob# m&l® of

*$ $ *

«**!&©

{

mtw&tm) lvittt a t e t e *

r a t e t e wtarnmm m& Mum MTIwdt

far $&# t e r t e a r a& te tft# ite & tte mm t p t e i l t l a a tfl tab#
«ff mm r a t e t e M m
M lte tita g f i t e

U t e MW*

t e f & f ia g # f* # r atefs*® *

^

rmUn® la Mm

mm t e i£ mm r il& a te a ft

t e a r ^ t e t e a t e t e t e ^ te a r aatt Mi® m
m
&&pmfimte m
m
I t t e tmm mmmm§ mm

e# (mm*) ($8)# t%®M m far a te *

tlM M te M te g t teMtena- ami $*ter«a W t e iM I t t e * f &«&
te a # «f tesA ^rl# tep&rtd# t e f V d**$ #IMi t e t e a g b# am t e a at
t e t e t e t e t e # {t§S a t e M t e !&te

#0 €* Mi# d i t e t e r t e Nrdra**

iF,*#i*6B
'J®jaitfh
?*M
tm
i'<b9iH
3L. «
,^6
6fcaiff^
atahM
tt ftla#W
{6IM‘M:ilikraw|i
^!teittfciBuil
l*8h
aiMw
W
» '| &
m
^K
®
^ii®
MiSPssw aPv®W@Sr rvv+j^
*S
attib
a*SH^amikly^wlitiMjMHMarikdkttfe^k## dkkuJi akakMkraa&t'imjdiMm.aE^M'jftimrimfrw j
VRI 4tw& aijip^ra#

m m l6 t * t e f l^ a# Im w m ) -Cil)#

i

^HFwWjfcJP^^WHf”
jfttff

ru
ffmWppRM
pm

iM
Mu
m
aM
NM
M
wfts®
1 jMugMMm ^ik'VataLt^^nLuK'M

fl# M as pm # te #

Tim 4 l« 4 te % rirl $$$i®m%m mm t e a t e i fw a W * 4# M ti**fii*n
r n

l

m

M l 'ftM tete i* aa a lr«ftea«%'

#

#

f

i

M t

e

l

f

M

s

&

r n

**» s^f»tei#& at *# m i*

flam iteteff& a mM m& te « te » a »

*Mm-

m m M m txm or f sm so iM i

lm ivm Bffiaia swathoa)

A ll tho alis8«y*«ihropfe««rl«*ll$r£h*tnanolo* wor® gwaparod Taflr th®
W H
W
ttw
i fwstoff C
tO
>« til* following dascription of fch®prop&ratlon

of

1*4 %*wftoafcbear*#*-b it r®

«t ra»ol ®f w $«*^bbo^^td t

tatyxvtalild® iXii&otmtoti tli® $m»mt piwwMfchuP# employ®^ for toko oyofcho**
#1# o f smvt of tho protest# Xiot«6 is tmhl« HX*-

ro«^tm%rs»IXi4o <$&*$ g*» 0*$® sol#) m* «*t«flMMiM

is $00 ml« of 4«y b««8MW® In ft S H tor -thfmoiocifettt mwad bottom fl&ak*
fitM t with a o tirsw with a bsmoeso ««»1 aod a rofissc omtitaaoor our*
am&odt hr a oaloium ohio?!®* tub®* It# third opo&isg m i coin «sot«d to
a $00 ml#

flank oot&ai**l»g $$ g* (0*$? vein) of phosphors®

posta&hXorMo*

fh®

bnasno&o notation

m#

ntirrml «hU* tbo phosphors#

m t addnft porhiosiflso* fho ptos^r**# pos%sohl#ri4o mmoA
thn «nro1sti<m«f hr&ro§#&ohXorldo* fho stirrisg w
as osnfelannd aafcil a

olo&r astwtto# was for#*** tfeo ^rlossorar flank wa» thos ropl&eod hr a
iropptsg ftamoi through ahloh ISO #&* of a bassos# solution of hrdmnolo

#»$?**

aald (IS £# #f h jd m o u mrn par to® *&«)

to u g* {©*48

*»!#) of hrdratola ftota m» nd&#& la mmtl portion#* Tho roast loa aftx*
taro mo thou mwod grodool% to tb» h olllfg point ©a a wofcor bath m&
nfclaioin«4 at th is t m m t a f * oafeil hp&mgoa ohtorido woluticm ooeood*
Th#

OM t a t r« a r« 4 «**ior rofoooi pcmimr® and ik o rooidsio m s

trootod with it© n|« of iso water and 8© *&♦ of oonooafcratod hydro*
ohiori# ©old# Bio

woo k oiloi aodor rafltsK for ©no hour In *c4or

to fy tiolp i# ©tty awrowfcoi assist©* Iho iofemooi® woo ©aly slig h tly
oolshio la th# ®*$aoos*« ooid sod to t flttorod-off affeor dhtlHog tho *$mm*
pwmim* Afhor making tho orsdo prodsot Itarongfcly with mbor# It woo

roospoMti&ooA twin© tmm 8® for ©«®fc ©thyl oloohol frot which it
©op&ap&toi m long# oo-lorlooo

m+p* Ka«*141*S® c* (o©rr*)# thm

yl®M ta t 4©*l g* ooolmlout to 88 for ooofc of tho theoretical#
Th©mn&m fomod hr hrd«o%alo of tho wBrmahoi ©
&
S
4©w
oo ao&ihl*
la tho dlltt&o ©spasmfcold oat. owl* ho rooororoft by nflo&mllsfttlon of

tho ootuiion*
tn m ot lm^m®m$ tho ftrafcotitotod osaldoo worn ©mmrhodl i$&® M&©
ohlorldoo %f s tirrin g w ith {ftm ftw riio gmatoshlorldo o t m m tonifom taro*
^«*ororf la tho oo»® o f $«*&©«%t o*sd

Jkwftih

hootlag va® mmmmtf to o ta ft tho roaoH«a m& in tho ooo# of $"Mfchyi

m& IMfbhyt

to ilin g wo® ropsiroA*

Tho M Uto

ohloHdoo m m mltibl® in tho hmmmm oxeopt thooo dorlwod froso 3 -a itro *
4m4»hos^btt«tafillSdio ©«& S ^ itro ^ m o th o a rP ^ p lo a o o iiM o which wars

00%

©©iwhlo im bmmmn at

torapemtsiro* Tho addition of

hpd*a*©l* ooid to tho MUi© ohXoridl© ©©autism oouolly mmnfc tho

aap&mbtem

(ft «*e>114 pfssdstaib isMah diMalved mboa the reaction mixture

m» HmImMI

boiltiig* In *11 imfomamt ®£t&r &a addition of hydras*!*

a c ll calotte* %ar* was- capteta <sr©!uiios of fgrtnoggaa chloride vfam the
reaction

m * h*M

tfea n it r©$&*«mylb®bra»©la* m& tha

e*

p
re
p
a
re
din 1&
it m m w t are1
1
®
%
*! I®table J
Ta
w
! table t to
g
eth
er w
ith

parttaanfe physical and iau&i^tei data*

WWSJiSC08*

mu*

4

& rm p

#f ban atb#af$i4*$yl*» an! alkaay^ibresfeanylt aferaaate m*»

«£•* prapred by the 3teai$* pw edara (le>#

¥2to* prqpf*%l«» * f

tmm di*o«fcyl 4iy&r*&ime

la daacrtha! m a byatoal m&m?l®m

as*4

to * iHlsrbare of Z M g* {0*0$ aala) &i $«assi?io**S«*iaitro«misol e im
14 mi* «f t Wl^im chtari* acid kept at d* C*# a ttolubioa of 1*44 g*
(0*01% mala) &t *#Altn& n itrite Im a ml* #£ m ate man added gr&daatly
*% the i i i i t« p iik p « *

fbe dlaaontoua flo r id * aalatiam $&& tkm

traatwd m l* 5 g* «*£ sodium aeatabo am! 10 $&* ^ S f aodtea hydros?id »
m liM m w

TASKS 17
i*e sn.»F® m «* km isxam x m it m M h rtu m x & ztm M
Ml » Ml*

A

*»

*U
P
. 0 c,
(«w»)

C
S

180*161

r %Aik*;1
.............
|H)
(M i ®
>
t)
4 *W
g

#

n«w

*

Fla# &
«
#
d
d
fc
#
ii

C
g
%184.8*1 8 8 .8

m
m
n

hmtftwfaw
Pfimm
tt«4l m

C
l^
, 140,8*1 8 0 *8

O
f

c
8 ii8 na.is-iai

66

C
s% lXS*t38« 8

m
m

«-C
s% 1)
0 6 .8 *1 0 8
i-C
g?!, 148*1 4 4 .0

n

C
llg 1T
4 4 ?
»
«
«

MK%fcM6j|

C
g
H
g16?
»
8»iS8 .B
a
»
C
s
J
i?140*1 4 1 ,8
g*oe%^Hcg

1*C
3% 148*1 8 3 *8

C
H
S 14 0 ,8*1 4 1 *8

n
n

ebhnml
athaaal

08$ #
tth
&
n
o
i

£mmm nm&Xm 08$ t&lmml
0M^f#p&a$X
lm£tofe»
riii# &
#
$
&
&
#
# 00$ &$mmt
Fla# nm&tm
®^mpmp&rnl
mw&Um 0 $$ss&haneX
%mg mm&m 08$
lm®¥n&Mm 8®$
m: efetmml
ImSt&m
fill# iM
M
ll##

0>
«
C
g
!!<
jr 1 1 8 *1 1 0

n

1-C
S
U
7 167*188

n

C
o
ilP
M«l##H
l4M
I 00?
?o
fe
h
o
a
#
!

C
% 1 4 8,8 *1 4 7
C
g
'T
g180*13 0 *8

—

m
m
n

06$

w%mmm&lm
Primm

ryig iie*ll8 ,e
t«'6C%
»M
9Q
|

mm

H
O

o% m*m«6

S^C
s*4^Cr^

&
*3f#$*t

00$g
*$ro
p
ft&
6l
9G^*#^paml

m
m

Tim amiXe#

8Q
$
fe
*p
m
p
s
ta
o
X

m

t<m%a##$X#«

08$

s*

F
la® a#«iX*f!

00$ ©
fc
h
iw
io
X

99

^rnp^0ip$mt

.....................
■
^
o
ca.

.O
B
g
C
g
%

1UMIMI
>
C
€
%

8 4 .6 *0 8

•%Vm

TASK r

m ttm m m itm m m

i,«

m m m m n * mn
8*9 » MS>
1
f
% SK

MU,
s • -c „n r
8
'•(G J & fc .)
w fast)

m

r a m i*

J » 3 W f« . % N
fm x *

W

W

®%

«#»% %

G* %

Cl A

1-C g %

V a

8 8 .0

8 1 .7

8 9 .8

8 9 .5

9 8 .1

8 6 .0

c il% s s 8%

8 6 .6

8 6 .7

C llT tlS % °S

8 6 .6

8 0 .8

3 9 .8

8 9 .6

l S8 °8

C%

W

€8%

C10% 1% %

8 6 .1

8 7 .9

3& *% %

c l l al 8s 8c 8

8 8 .6

IM

$.**% %

c u Hi 8* « 0s

8 6 .6

8 6 .6

S9 .8

s o .o

Gi# it * s %

8 8 .1

8 7 .9

c l l a lS % °S

8 6 .6

8 6 .6

c l l a 18s 8d 8

8 6 .6

8 6 .6

8 6 .1

8 8 .4

CH K1S% ° 3

8 6 *8

8 6 .9

W « °8

89.8

89.6

G10>1lt%"8

88*1

88. S

f*O C ^ *W K & g

ro 8

id o c n ^ M N ii^

%%

*« % %

W

« °»

e %

U M fy d M M t
ci%

t

■mmm • ,

a» * -c«%

^-oc%
C8#

8»5TC>a«4-OG%

CgHg S»Kng<»4«OC:Kg

•*41*’

ffc#tim m km m
totM
# tnlstionw
maM
o
d1
&imll portion* to *
nnlattira of i*§

{0*081 a
m
i©
) of d
io
o
o
&
y
l h^rw
sinoin 4
9nl* of U8 9

••**»** o«****** notation feopi fcetw # 0* Without tho iootntion of tfeo
Im to m o iio to dlooofoydmftifte tb M i oopoaoiM to n ^in o la s iM ofetho pro*
o lfitt& o * 4© at# o f 9 I « *6 ta t 8or6i«xl4o so lu tio n mm M doi w ith o ttrrlo K *
4 nttm * ttfto lio * *o « *lt« ft o fto r t t # t M tfm o f sodlu» hydroxido
omMfeotm m m l* thnt «©gm#at*i tffcor

n»« ftltorod off# m
M
$hod

wt%im
h
o
r«
w
tdd
lo
o
o
lo
o
d in tot mmmfamMvi. fc
y
d
;ro
o
h
t©
rioacid* fh
o
-o
o
id
notationm
» fiitofod not d
H
o
fe
o
dw
ithm
o
to
r*n
«
r«
ti$
io
ifttho to
fc
m
n
o
lo

It© om
lo pm
doot wm roeryotnUlnoft tmm m po*m
o
o
t ofchyl
otm&ol* Hold it l $« (4V#),nmp# i40#©*i4t#B° e* (m m *)*
ftt 4b<op*#rmt«Atr«m
o- modifind In norormt togNni* in th« pnopom*
ti#mof «om
aottor toiitnolo dofimafelron* in tfc©pmpnmtion of 8m
»*
progfi and

im
f»«fcih»t®d totnanolon# <Mtt rant©of tfco &l*t»

M&ojri* or 4l*l^tar«yt toribmito non limit m
m
ponslni in 80 ml* of 1 w
©odium«MrtNmfc* imtailon# M tm th# addition of to f* nr oo&taat «*«t*to»
i t «©&io®tqribMM# notation m
moddof dam
ptsr dropmith aocKnfoanl
t&nm
ttm
f until tto 41*«grl hrdtm
olisohmmm onfcivilp nolublo* 4ppam«4mteiy
4*8 nit of § $ oo&tmtyt&wmMm to&nttot ms ro^irod* m* notationm
m

ttkom oootod to # C* and ootipliug with 0«of m In ©# a i m ^ 41onaoiom
n&fawido at thn »«&» *«or***to** nan eo®pl©hod no aoo©f*lh«d sibasm Thn
dl*moMl**«i4*o mfiioli oogm
M
fcoAoffcnr ooapUm
gworn fittorad off in m
oot
of tt« m&m an
dfcw
m
todw
ith 49m
l* of 6 I ©
odiumS
^
im
m
ld
©notationto
offffonfc tfco ^ M ssfelm *

In thn ^rnpnfntinsi of M t

nod

tv fc m w lm *

ollar nr

pms&m*

« *t» r th # a c t io n a f »adtu» hydrosife

g#iateia«ft H it# fmfai&m wtm aaarartiMt I«ft» at>lia« tegr ImnM^s tte® ra*
aateitoi Hfatu***# tea 6 # C*
tai## an

la Hi# aaa# #i*

m
g&
m
tai ah
io
hmiU aat te
* a«MM ia
fe
at&
a

« # iM «%#%# ter

krn&tm*

hmm&t* m&M te* otetaiaaf ter

A «#U&

«
»
ttfe
&
a
**tf*3
g
r «»ta#U
fc H
»
* #«
^
o
te
y
4
s
a
&
M
* altt* a * m
lfiast tegtilratta «*ft»*

tla a .ia * m&to*k- 'ffim avai* W tm m lm war# vmmltp t%**fc
*#14 aaf H i# ml%$» ifciefe « « p n t« & fv a i

fa «s#&€wfe¥*t<!Hf

%fca a#IH £ fli* a t# a$&& d ilu tio n w ita m t t r w ar*
a r teasataa*

fra a

l%« trmfemm* aftte

l^ iiiiM la irl# a&IA an# aa&itiiKt t f i&® m rit#

M

il#

as# aafy

a ltilitir artaraA m m m i t mm #*% allgfefef? talatel# fa mmmtm&oA
l^ ia ^ ia s rl# . m m $ $ ia ti*a «

tte# atear* pcm ^rm a r# lia te a i fa
»•■**** -**cw
*r

attun
'5
Rp>^r jfcAk.

#kab‘

mlDKiflk.

w>
naf1
if<
»Wy# wmm
j^^Mja aA
te.teb©
i^s<irAp®R*®M
Jkai
Ju.a
raitP
ji^iB
B>liM
ftT
rpR
a ^PSJ"te(I|jl(R^F^96a

a iH i te a # ^ ta la a A %mteb# vm ®mm pmmofimrn*, Mthesagfe aaaira®# a n
.3®#%. aagviat ant m tte# #e#pH*s*t» pragarai ter bb# Mawfefe srathod# Hi®

paaAiMite* m m fetmfciaaf witb #i# CM$rr#$iHWi&&£#l aa^npaaafa
vm ®mm «M»t ml
a t**a attte

tap bba

u
b
m
w
t m a®
ara*»i*»*f tb«mMln® tataft w
h
«
a

ffef $

mmpmt&tt mm

propuM

hf

th® mfcatyti* hydrogemtioa

#ff bfe®

aaeaiHia® b® th# pm*

M n m #f BM mk%m i

(&)» fk® prapamtiaa ®#

§*m®Am^#wi )*6M i^b*ims®!l# I# 4m#rib*6 a# $tt mmmA® ®£ %k® m*

MAI## ®# «&

» dMvwfetr**

f® a ®as®nrftta *f $*i m l® (ta*9 §*) «# %*4%*

t»

tm

rogiiaiQrt)«»

wl* ®r gl&®t&£ ®mti® «tf* 14® *ng# #r ^ a t t a a

m*&&#$!* ' ft# mlHbiam m s Mtemft fa bh» fnrgmM'fctr
te ptm m m

m

nnmmtT*# at **s Initial fepAm
gm prmmm ot

?m
M
«pm

*wm&* last «ni bh#mtmbiMm
®

w
ltkima
®

mJIHtos4jt*;pfeis #Ws■
njAAfrlto Jsfl®i4*1
4t®4 •i®mntiisnSfcifm K
i* Msbmmu&sii
rtfsfS
' Hifi'Wint jitnimasti #41
»b
H HP® A
4^fmsm^iHlftiitfs-iriifbtwasW

m*ttt

%t

th® mMy*®.# th®

m ftrm P

mi J^bBA®
4ilAklnm
bwi®^y*iF

m s d istills* #££ a*«i®r m&nm&

i»f%, Ik® M l^ a l m tsrlfei m s Mem «rp fa

pvw**

«&* ®tf h®b mfcw m *

taints^ %t s
&
« #f aaatiiH te
p
4
*®
®
k
io
rf®a®
i4* b
#4f#4 far a f«ww
ls
s
*
atm* igktll*$ m4 f llW

b
®mt« m
y«
m
1
1wm&m ®
£®
e
MInm
lnkl®

mAmM* $k® s^ lIM fitbmb® m s m£# alk&lin® t® H tm a wfbte ®ip«®*»*
mmm&m

and Hi# M m mieti

n t# t

Hk® am*®® la## m

®tmk®i

fw m

m

«m& m #M with

romyitalltft®! W s t fim 80

pm

e s f mhyl

HkW* ft ®®p**»MI a# mtavbsm *•«&«»* a*&fei«tg at Uttw

f t # g« («*«**)» fli# yl#l& m s 18«4 $» mfrsspsMing % ?$ pm ®mb ®T
tb# Hbmmbtmais
X
a«a»#H
i#

in

$%mt»3L

m
sm
bm
npM
w
iy

aestie a#M# bk# m il# m s

®#m&# a#i4 #»* th#

r«£n
«H
o
n«nrri#4

s«sp«d#i in glml&i
mb a# namai« Th# snli4 4iss#lwn4

a® tb# bpdm®«witi«» pmgJWMitw!

InsHi to th® Hs# in tb®

b
a
n
g
w
&
b
n
#
©©
ff thm

mMmm mm

b
©K
b
* raftntbl««©
£tlw
»ultra

tv * * * b© m m&m m m *

Im iM i liufaaMMNt* infemnly w iarai r u c tio n iaft>*$srafc« -war# I M U
ft&a oftlasmtMi WiM a©s*«lty b« g « M

% Imrmmtm sligh tly bfe*

m rab ©f pt&klmm m%&m mHS&mk m tm%& be rm&rm by tbe e«® w tie»
©f Ms© ®u?&&© is*St© tfee bgn|y«MblttVl4© jubnI llb e re tlo n a t th e m in t
e fte r

#.e Mi© hy&roohloHde,

« w *i^ ©£ tin© ©S*«m bit© w in© «©» H I M

m * ftd& blen ©f m i l

In hy&rot&tarics «tci4 © © M ien

m « fr©q©#mt% H lp fn l in rm s ln g ©(deration*

flit

t W s i H f f f p f d in th is wmmor mm li«b#$ in

,ftb t© $t nisi ^nbl© v n b©^©feh©!* nibls yaiblnanb s^sy©i© nl n&$i ©im lytI©nl

Win*

fhm

fcpWW^eHne*

t it

the

l*B

warm pro#mm& tyr gMtlng &*y hy&mgm alilerMn ®»s iafee n ©elution ©£
the batiwwilt In ebmrihte U » w l nleelael* X£ tt*e ^£©ehl©ri&n
*©gatM&*ft frm bis© nlW Hlin ©elaftten# n© in the ©nee ©£ m»fsb mi the

nmm n
M m im w rnn * m®
&*?? «* o«*&*
»
t

,

8*

(0 Aik.)
®r„

(• im )

(i«r* 6)
**% <***• «>
4*WRg (®ef. 6)
**»%

u » *3 t4

74

f in ® 8flM & l«e

IIS * M 1 8

64

n * w a ® «A t® i

itefe«r

X4#*14IS

60

M i l l a® fidl® 8

'Swaisw™
ffe^-ffcijHhirifc

4$

CA

*M^«4tfQC8g

?i*l4 Cfpffeftl F<*r» Bfclrasfe
S.

PH«sa*

U tta r
M «p
3® $
^ ts m l
80$

%

110*$*%$®*®

77

c
8%

T g .S - 7 5 .6

64

FI**®* tt**£X w a

•M M U S

60

9*001**

66

PT&®*£>
S m a ll

»<%%

a^c^**wsfi^,

c-%

X8CML89

t§

fcp0CSg*4W8%

%%
«*es«?

1 7 3 *4 7 5

76

i-Cjily
Ci-jj

Wfcfc**
30$
ssthattol
gftbaaoll
90$

n
il

' M i l l e w t it t w

I4 4 @

60

F I m aaadXas

*M S

63

tm tiHtafe*

74

?%m t t » « ! l* f t

1 1 8 « *« 3 9 **S

79

H «e61«0

is e ^ M s c M i

70

o m l l t>s*ins»

U M 0Q

79

F la n tio a d la a

183.6-184*5

71 fmXX awMlXwi

ftto a M U **

80$
.m a is f ll

^n6%
m4L.nvtt
tw

ta $

t«#00g#4«^^

fr

.jftJW
t-|*wn

«
® 3

«**

%%
&#$}$%

U%
s tlM u n il
tm
s&him©X
ttk ta r
30t
^thasaol

^ ST»'ig

^OCS.

W
iiH*>wrii
* '■f■'w
niti*nhMU
:^i*W'A
w4&»

w

ethanol
50*
>tha.nol

tA 2 U « i

x tfm w B xunm or i,e AwsmnMMm awi?
TUB •

M i*

,>

S
wiwiii!"»i,h«i>111wnfmmmwi

-CgTJg

vV

(0 Aik.)

^{■■JW
sfliWnw»nyi
dW

or (1)
<
w
n
^

w %

5f*0

$7*0

Vl*%®

$4
*1

34*6

m*®

31*6

c
ll%»%
e

80*0

$0*0

ttH
jg
S
g
O
i#c%
% C

M.a

$0*$

V*

8
«
8
8
g
«
4
»
0
C
!?
j,

• «%

S
-B
B
g
-rf-O
C
H
ig

%
*%

S4%^<K%^

ttw
O
g
O
y

8*0es^*8*w
8

c
«
»

C
9%lV

$4.1

$4*1

®
g
%

C
1
0
H
1
8
3
8°

9»
*o

$8*1

$0*0

$0
*0

C
|1
%
S
%
0

s
o
*o

$0*4

%

G
»
S
U
%
0

$4*1

$3.9

Vi

W W

$1*0

$£.0

$0*0

m *t

$0*0

$»•?

M
U
0

$3*4

ctt*i$V

$0*0

$0*8

V fo W 1

34.1

34,8

ci#iaT
i's
c

ss.o

33.1

n
»
C
g
%
i-cg
%
'W
S
C
itg
-M
S
^

8
-tK
?
H
3
»*.W
^

»
<
O
g
% C
U
^16S
3
®
c
ll%
8%
0

8*06^g*4*]^j
S
*0
C
g
H
g
<
»
IM
tf3
g
|

o
%

S
.O
C
j^
g
-O
-S
^

C
»
i%

1

«■** mCJSm
°5

t#mniyo*|w|••*?W
M
PI

*M|T«*

t&tttMM&m* thw iiy6imKl*rt&w

m

with

%m*0k. m it,f
wtm taft#

< m w &M

m
*%o f
If

m

% 4 M *t '«aMtk.«i w it h

mtotorfl

tb w

m
tvm
skm
mwvwgMttwt?«£ m
&h h *

hydmfe&*i&&*

#ol**Mo*i m<* dt&wfcwl with

*Mkm+

Wfehyl

r m id t m l

mfc a ftw Pooling# tto*

th® hy&#wohXo*d4£ pmoljplfcfth* mm fll»

m
hmmi

itm*m^ p

iia w t

aiesohoX, lUNrtton* mai

nfehwr mm»«i only th*
h®

f r m t&mtih&m

i» m m th© hydmwhlopist* did not ««$**«&♦ im m th * tm praflyl
m liu t lm *

tt#n *f

mw^wMftiMI

mm 111*

of

hmmmm
m

In

mam

p d « i«

tfc* addition

oily pr©da«&* th® pmdtaat

m£

m m li

m & solid hy decanting th® miwrmtaiih limpid m i pwrntttg

m &%m mrrmxt of i*y a ir ®w®r th® m ild**® . ^abfciiag wlsfc a x m lt w w tfc

-#f *$«&*&* m i also hoXpfed 1m u r n tmtmwmm th® ®rad« pmdaoh m

thm

tm wfeh«r# filtwr*!* m&bod with w&har n il *w®*y«talli*«I

fx
w
w
i ms&W9*toto* stoat mlwmlM (to* f&
h
l®vtii) w
ith fc
h
#additionif a
fw
wto
w
#i «f w
fe
h
a
r

w
ithiq
p
to
w
g
mffelo
#ld
wte mmmwm th« pmm*

m m *£ u t i l w ild *
*fewt #f th *

this® hawiiag a m t& yl $«m$k

m
fc
ftfc
M
n
fc
w
t1
m
vw
w
ltU
* I or t if th* t«M
M
M
twrin
g
# amw
**s
r *®
W
M
L
w

I * w lm to l* « M # tX y « *

in mm®m wad m&& m m

sligh tly »wt**ti# la brn»M *wd psftswlwi* w&Hwr* % dl««ofcrt&g tho
§ty0rmhXorld® lm a i w l l w iw m i f WNtfcyl *X&*hol or n ntw m i r a talwWam
mi b
^
thw
ith «
i^
iw
p
«
m
few
ddltimif hmmmm m i $mv*U% m m ^m titm of

t$s#

m iit ilo m lrm ti* m wultafol* mirtsrs i f mlwmtw tisually ro*

m ltw l finwi whloh til® hydw shloriiee mp&mboi m fim o *ystale.

%©

4rt$d t© co a sta l wsight m&r vkim^h^mt

m

iwaafewid# a t 61® C-4* (h*n* ©f #& 0*afafnt) «n& 2- « f prasaar© 1m «a
Ayytfj& plot© !*
I q r d r a f e l o i l d t t t r w U sst-M i s

uttte g»wttawg&

V'feblw V j n

aad I k b l© IX to ^ w th w i"

&M unaVtl^wa data*

ffi ** 0P$k*

0«*si
i.M.W»f>

1

(o ytsjgo

Tfcw* m^Kfl d*riwwfeiir«« wes-@ p«par®& by

©si?®

0? owlwo*

with 1#&g* «f iw
sw
fci©anhydiid©# 3t« r**cfci«madxtar*

dltsxtwd with » t^ r# &&i thw **lt& that s<™mt^l mu fil&arwS «ol
waahai with « t » .
mtwr ©
**

fk#

i$Mtoet m© th«n «wai^$ti&Xl&0d M m trm

ig^propyl mlmlml md driod to iw^taafc w
vdgbfc ®rrw
a t 100® c * * & M IS mu prmmtr® in m AMwtiml&m

dxwim pMv&*
fm * e r i p l

a r t . l l w t t d l a T a t la X t M

with #«rtiawra& ghy»i««X « $ mmt^timX data*

«40w

m f c l* x i t © £ « t h * r

IX

m rm m m

or m

tM m m w m m j m

m o z im t e n m m m w *

SMf «• CmlX*
i

i

*w t
WllW ^ »«*>*>

&» *c*%
v{& Alte*}
nwnm
nwm
m)i>*^ lw»it<>?
l^w'j■■(%)...
MiiW
^<iiW
ivtii'ii«i^

4*®ij

s«^wi«ae%
5«HBs-4-eCJ?a ' • .

**«Sg*6<«wag

«8%

01#©

00*9

CHg

09*0

£0*6

r*a%
mC^f

»n#

27.4

« *« *« % »

an t

£0*0

«1I%«61%0

06*0

00*0

%

00*©

00*0

%%

07*4

«m

S^»%»8«*g
a*oa!a«a-mij

i*Cg?%

««¥>¥
Cl|!%gCW80

06*0

te*©

£4*0

00*0

8->aMg-4»WHg

ah

%%€S5%0

80*©

00*6

*-CC!!s«4~m3g

%%

H & u P **0

07*4

tn s

£0*0

f6«S

S-.0<:-'T3*4-i,f!%

W^%

06*0

ii«0

£.OCjj%-S-’?:!a

c%

zn4

•T#i

CttSuP»go

£0*0

08*0

«W »«V
%>%4ClV

29*©
87*4

09*4

«A
$JjL*

g

«j»» -Ca%
■"<3CBj|

C.%

!MS%-<M5Caj|

07*0

turn** x

i,® M&nrtumwrnmm* mu
S$*f m
n

/"

131

a*

9fc».*C,

f Aik. )

»r (g)

??■
£xgr«Ml Fen*

( Co o p . }

W
O-itwHilTiW
^lulHiHW
nfrM

4-wwsoa^

ca%

138-158

PHmm

JwnwocTtj^ocsjg

ca3

aoo-aoo.6

Isft£l«fe»

s-srscocag-^CHg

%%

166,7-167

llt « f

*«M»OC%i4-0<U%

187-1*8

Plaa $®«IX08

8-WJCOCHg-O-OCag

164*6-166

H m oaadtaa

a-oaSg-R-SKCocs^

ci%

191-108

&9k 11 neadl®®

a-oes^-e-saeocBg

%%
H*€$%

i64*e-i6».s

n m lt mm&tm

178*6-174.8

V m ll laafl<3to

s«oc%*«*wicoa%
8-0e%^6»ssiC0e»s8

30$
8*pPopm^L

187*188

trim m

Smoewgwtmmcocsg

%%

141—
149,8

r im n w & lm

8«-0C%**»8t!C0C3s

H-%%

160.8-161.8

V im mmOlm '

188,6-189.6*

Fvimm

176-177

% m tl madloa

168—168.6

^mXl mm&lm

o%

8«Oe8%-6!®:e0e%

%%
iWilWWliww8'ttlitM
IW
W
.iW
HM
L
■W?«€%

B

« *• «% %

i». *i«iiirri'ni ir‘1miv i

«SL

% b«r
80$
2«»pmpaaol
mt
t«*$r®f«us©X
soes
&»progftiioi
30$
S^pvafttnot

a

-Tr1“‘rhif;1r~"i i iniiffiiii ifnimim

nig a»VHcact!f**BCBto
€3 % samcwijs^-ocHa
*

Water
so#*
S^ittpaaoil
80$
80$
8«prapaa@i

0%

awocgRg-s^irotHg

30$

3-pproj»»oI
90$

180.8-188,6** Vrimm

a-ee%'4w«eee38

s<*oc%»4^me»c%

80$

about §8® C*

Fin® flftadlft*

trnmu 0

P rt** i

$*t«r
80$

tiyata&liitad ms a hydrate taftltlisg ttxtahiurply at

** Dv&«4 or»r ohoftpfcoru® p&sitossl&a at 111® C# &?&! 15 usmpswMRir* la a
drying platal*

XI

wm wa

or

%t$ mwajmimmmh* Am atjrorr*.

A ^ r n n ^ m m m ^ m ^ m n ^ z j^ u n
w r * wa*
f
#

_ _ _ _ _ _

a» *c fl% ......... 8
" {0 A ik .)
...........
« r in )

_

n*

i'o m ila

it a ly * is $ W
Calm ljpbta

F<m&4

^-sarocsfg

CgHg

«11% V

80*3

30*1

S*1<3C0R^**»QC8S

C%

ClS al»V ? ®

it* s

£ 9 .4

s-rsicoci!g»«»cc«g

Cg%

CM % S % °8

$6*8

ZM

8»W!S«!%«4«OCJ!s

C18®1T*8®8

S0*4

ZM

w m e o c ^ -4 -o e i%

cts % # 8 ° 8

@6*6

8«0®S.«S-®*OC%

0%

cl l al*% ^ 8

@0*8

@8*6

t*0G !^4M R {C «C ^

%%

®18%B%e8

t*« S

«6*T

CjgJfjyBgOg

$5*4

$6*6

S-OClfg-S-SBCOCBg
s^ooRgwM Reoa^

1-Cj®y

C l*5*!?8©6®

$6*4

tM T

S-OCHg»4-*m!tfiCi5s

%

CU ‘% 3% °8

$8*3

$8*4

**0C8j«**8eO C*i(g

c *%

c18% 6% %

@0*0

$6*0

g-0CHS«4-reiC0C!lg

iW 'gH f

cis % 7 % fja

$5*4

66*4

r lS'r!17HBeS

$8*4

@6*0

«»

C18% 8W8°S

@6*0

sm

r * !%
oa^

cl» a17s8®S

@5*4

86*6

a^ C B ^ w ras o ca L
g -o C g S j-w s e o W jj
S « ^ % *8 » w e 0 c a 8
I

*% %

ch#

l-r o c o c r ^ w x fftj

CllHjjBgClg

*6»S

$6*5

C8%

fcrfraCCC%«*»OC%

CjgHjgHgOg

@6*0

f? .l

m w rnt

mmmt
t* A bm lm of

mm

md I&m3ky%

M i hm&

&@ ii&mrm&to&m to t th®

'OmpmmMm &t & pm gvmp «f t-mrntollo <mp*xaft*«
t* t fnmft ftf fttseiftfta nm &*ft «&te^watt^k^X-^'Sl^rlt«ffem m lm hm

h*m pm^wrn % &bk* m 9mm p s ^ s w miob iavoiro® th© infror*
of fegfeh tko Sfeftoyi

ifmnilime &M tfeo s?**l>grl

ulijh iteaifeavus $osfdsa#JorMo asad %rmts«89fe

of tk« AA te €MorA4e*f
ft* A gitm^ o f fttfttw i m

iNm

$0

Jfonwd vrtfch hy&ttMoie &et4*

if f

ofereutoiea hcu»

% aatftiytio ^dregomtioa #f %h# #orow$«Bllftg nibm

Ao^ewfeftroff*
4« A ®pmp <*£ tm t

*m& Hh# earra© i^liag

h$at «&eo bmn frog* rod bf •M l* r
p&mw$mrm* Of

m ly tfc» Impmnlbrm^mpt** and the

g h e s ^ ^ o m g r A f c h m mb hmm prmrttm&y deeertked*
§* th* t^*ttofcil«f’i&«ft &M %$m mm&pl 4«w$vatitr«* of a il fctw a*w alkaa^
and t&«

«&»e &eaa

if fke SJAwrcifcti p o e e tw fes* th« ^opaawftloa of i#as!§ri^i*w»ofeliyltetrazole
ftp rno mrfttlftft of 6Sft**tlt«A mmmbU m inm with diaeet^i fyrdxmftliMi

..Hit...

i

w A lea tim of the dtftgatifdmldec g® tm*m% in aqueous &13mline
m h & lm bag %®m wsbmAmt bo the

of

£*&#»* A gamp of t »

hag bmm $r*gwur*&

efeleh tm&u&m me $muri&fl*
w ftitaM li tofemetfXs**

Xtebra.**

*«& s*l«#pm3fX #ab*

The o fotlbtb ioo ®t MmdtoytomiAm 1st© t«feii«

**&*» ma ht mNfte*ifea& by he&blng* The .yield* of bofc**a«oleg ©h*
ff©oetor% teww«r# a*% Aoeer Mitm, tkoee ft*#

t& i« l bf mo
t&iaed % the m

f* The

?im*& £rm**torft»

mi p m ^ m tM m *

been tiMM$fe*6»

m

aM e»X*i« ee$4 hr*

tnmxrmsenm

ur&uetmz e m a
t*

*• 3* «ttd

8* a», <J„ Piawu «a& Sstp* Then*.,

IX * 891-8 (19*#).

! • 3mmm« a , o« «m r«a*it«M*m» *• * ' SIS** I2>
8» OrM«*
i* **#,
||,

sbw

4#

m ** ivm u

B
#e
r#wl F
*ttfetar*fc*g
i» «• ib, n ^ * jft*

(m e}#

§* ft****# ft* $# m&

* • * . &$$»♦ a *

< tw )*

4 * !**%#%* l b % # ftftfrfftt*# Q# W#

Oftm# 1# ?# F#

fftunrltt# is* I*;

'*1* Off* t e i la $*«•.**
f* tftHteft* ft* %*

««ramaieatl#n*

ft* ftta*t*t *f* 4#, *«*»»-1|* tftfttett (in s )*
ft* M
M
fta# 4 « 4 *, ftm
fe* J§*
10 # tfta ftttt* 4 * 4 # , B ar** | | #

(IM}»

ftftftM M tt ( 1 8 0 0 )#

I I * B la B ta * J # 4 * , Star*# I I # l 4 ll « f t ( 3S 9 S}*

IS* Pwm^m* ft* §#, 4# ftfea** t e *
It*

3 * &***•* <IW}#

M f w f e f t r * § * , ft* * # * 4 | * ftS S te ft ( Ift& O *

14* mhmmwt* «** »•*** Jg*

(lso»)«

HU

(Ifttt)#

0 *j Bar**. J 4 # lft 0 $«ft

l i # Uiiarotl** 0 * *as& 4 a ^ w s t e U i a # 0 *, Bar*# 4 g# f t f t t e l f t (IfttO )*
I f . M n U t b *♦ I*** & * » # £ ( t ) *
If*

C ltM ).

% 1 * *«& J ta ftftlb F* tm , $ * to * €&«&* t e « # gg# B« < * 4 0

(*«•*)*
1ft*

0 # 4 # ft#, 4 # to # €$&**# ft**## f 0 #

{ 104 ft)#

SO# r m Mmm§ 3 * mM %4<ilffe* W*5 fur#* jW # 364*fg (1091)*
fti* S f t f H I t # i # it*# t e f e a t * R* % # m m i v ® r , Mm €* to st

*1# 0*"®* 0IMSS&*. Ift* eOS^f® ClftftO)*

~$0m

C* w*f

ft* vm

J** 4*ate* f*

ft* von ft«aw*» 4*# «raf

&#, Bar*# m * MMOf (Its?),

n*pmm JW
, te#*

489*13 (I9f$)»

.0

i f * im a te n * * **# ana sethmmm* $ *, te * # jgB# f iM M

(Its © )*

ftf* teittfW * F* w## te g * % e#f F te te s te * # B* % ana te a t* i* a*,
<y* teiteti.# ant &«$» temp*# g|> fee*9i (iw )#

if* trnmm*#* ft*, te n * tar*# ||# m i (in f)#
0mmm tam fe m * im

f f * te ta to r
it m h

ft# ftfeffctib 0# A#>tr*, Pli* O
#
it&fca ©aitaga*
St.*

®bam# te b * ?©<!)* t i n
mm

la* fff*

‘Bnpf* af C
txssa** l&m
a

4*, Bar** JT# iftiUf flit*)#

SO* .te4«ftww,®«r# M
* u f tewfe** W
* A*, 4# to* C
%
aiss# $&e## 41# IW^ff
<!•»»)*
~
it* ftmrtMMt* r* «aft
$ft« V fM b $** %

mmm* r*. Bar** &»- MM? {Iff®}#
te rn ** F* I#, te * ter* C
IM
U
b
** ©g* ieWto

mmh
ff« Farkatd*# F* I*# faatfaw# I* * teterg* % ant tea** 0* 8# »*,
te * fmw* ten*# g * itefft <104?)#
.$$* ittisNM* 4* 4*»tehi fiwra teat** jgp §88*4 (Zte )•
$f* tefaaff* F* ®
U
#m
pn ftjtlb e* F#
II* M#*f0 ( M ) *
36. tarte** fb I*

w#, te» Twwr* Obim*#

m i teftes# «•# te * ter* cite** j§,* *«w> (104a)*

s r* m $m m n* n *. to®** tg |» m * c u m 5*
ft# towwara* F*, Bar## SO
#

St* fttoMftnn* J* I,* am9 t e * w* s*f J* tern* te« # in # SEftO#f© Cltl?}*
40# FranlithiMr* T# «M CA«f J* B#, <?
# Ch^a* te*# Itl*
91* Ittag#
4f#

(19ft)#

tw
at itoM
&ft# $£* 0#, 9# 0b.an# Saa*# 1*1?* tiff *81 {19265#
B*4

Hi@a# Twar* CM
U
ss## 4fl*

«mrn

4SS*

?*, 8m * Tifersr. Chlfe*. 4S, 707-86 <19S4).

44* Bailor, A* f «, tMfcta, I* «• and 8allr«r, J«, «J. Ohm. Sm», 688*40
(194C
).

48* SfcaffcM, 4* w, l»# ?M Uii| I* «, tod r«Uwr. JU, <?• chew, Soe««
1084*89 {194?).
48* filfenan*?* w
a
domO
m
b* P
#
.b
«k
.»H* w t

(m«)*

4ft* to*l«3r*
ft** tefela# W
* II# aaS
iiw i cm
®
)#

1* , *
’* C
b
o
n
* too**

98* toolaft# lb# Allard# <1*# tefcooo* <1# «»4

mirn* 1 4* 266*4101 (1W )»

40. HoJUbros*# I* 1# ,
Pimm*

SO#

Y*, Bull# ft©®#

Qxf®r& t^ir*

Ofsaalo

tw York* i t 41# toi* in # p« at#

*» 8«r*t g * t*>« (lift)#

$1# tofcoartobh* W* &s&§ $$!««•# ft*, far## a # 1®?«® (1901)*
it* «*& Faclwaiwn# 1*, &#*•* S3* 613*6 (IMft)#
it* Id
g
r* If# a
n
djS
Q
&
a
n
ra
ta
o
ts
#$
♦, ta
r#
#
.g
£
# 1144 (1968)*

84* ran

«?*

ftfctilar# C«, tar*# $£#

(1966)*

4
K
»M
4fcl*6» 8*. am# g# Mm (im)*
St* tellit* »
*a
*#
, mitoa**
ft**
P
*s* a
®
*
J* to
# (ta
rn
#S
o
a
** g* iO
O
M cm
©)*

4* ft#,

St# 4® bsmg% % ft*., Kao# Taw* ttiiai#* 48* 29»60 (Iff6)*
St* *ftotl«tot«o tadht»«& tar OrgwliroSi« ©homlo#* mh od«# tal* II*
846.#

M00M