‘ M) 4“ “4 ‘ “. N " A I‘ Au: .. v «v I . 'r—v‘, 1'9' _- ABSTRACT STRUCTURE AND BONDING IR EMAMQNE SOLUTIONS A3 DETERX’TIHED B! ELECTRON PARAMAGRETIC REWCE um OPTICAL 5PM? bytorryfioymondboltoa An extensivo study hos boon nodo of tho magnetic ond option. proportioo of oolntiono at tho man notoln diooolvod in o lumber of mine. dime. and amino-0th» oolvonto. The results of thooo studios amnesia tho difforonooo on won on tho similarities botuoon meta-min and motel mu solutions. At but two odditioml opooioo not pros-at in utol-omonio ooluttono omoortoboroqnirodtoomhinthophgflodmportiooofutd-Mno some. Tho various models for mom-amino oolntiom hovo boon one-minor! nmnghtflmowm ovidmoo. Comhtionofthoopticol and EH! result. prooludoo tho unigrnoot of tho daiblo oboorption to tho made special! mpomiblo for vaorflno apntting. A donned mlysio of hyporrmo splittings. g vduoo. opia moontrotiooo. and valuation processes has pomittod tho dovolornoot of ouni-quantitotivo modolo for tho monomeric species. Although both ototimry singlo-ototo and We anti-auto models on oonsidorod. tho dopondonco of tho nognotio pox-motors upon tmporoturo and upon Lawn-gloat! Dalton 2 mummmammmm.nmpmmm mMMooofMMdMW-hw “ninth-ohm mmummawanzmvtomozum mopootntoooootdorod. Mtomoootodmoflmthouw of thto Mot to tho oolvotod amt-(mu). detbnmduoodum-iuuotm-lu pudtWWootmdmopfln—dmmomuamuo noun-mums». hW.thoWofthoW mummwmm-Iunwummd. mwuammum mouthw- nubnnlththomwmmlr STRUCTURE AND BONDING IN MAWHE SOUJ‘I‘IOHS A53 Dmmm BY men PfiHJ‘T-AGNEI'IC MECHANCE MID OPTICAL SPECTRA by Lon-3W Dalton A THESIS Submitted to Mama-on Stoto {infinity in portal hafnium. of tho Wu for tho demo of FASTER OF S mZCE Depot-moot of Chantry 1966 Towfifomoino ACKNWJIMJTS ‘Thoouthormhootowhhdmowmtohdum J.Lmrammmumt.mmwm thomofthtomugotln. Imodoonhtothonkmoomn.n.no0omonot$toutotd “with Profoun- C. W man. 3. Brando ot thouuvordtyot Mouse. “Mason-hemofhuhigmsutommtyfanflm MWWtwfinfiu udhhlotouooudforunyhow Odom-tindiomomo ’ Inplouodtoooknododgovolmhlo mus-1m dth Proton" mumocmommwacwmammmuxmu thonkhhtorunngovdlohlopropdntootrohtodpopnu Ittooloooplooonrotooohotnodgothoodflood’mohsu smdmcmommmmwzm Motions ond oph-lotttoo um-u- than Km. 1““ mmrummmaaumummu. WWmdooV.A.lioo1y.l-D.Wt. 3.1!. magnum-anamwlm. M.mmmm1m1mhuwnyumm tumulthom. «Wdthodm.ondoutinod W. MMthvthoMtodstotuttdom cm. Io 11. IV. V. TABLE OF WHERE‘S INTRODUCTION ESTORICAL A. Rodol- fo: nun-mu Solutions B. m1- for tho noon-Ir c. PM W in Mob-Indu- m 1). Panasonic mm to m nota- MAX. A. Gloom M and Ito-soot mam B. am PM. c. Option WI D. Worn. moan-onto E. unfit: W 3mm A. mm W on Mortal-nun Solution (Raga-no PM) B. ER Room on men-un- South-o (PM W) coucmsmas A. mamamwm a. MAWdfiomW 6. WWW” D. Moor Span-Wt names» 11' “gun-up ‘fi EESESKE’ER £5555 rm GI" WEI-S - mum“ VI. mam m 0 Rib? Ila: LE‘gb 33-3 133 1212 (11!.QTTT‘ *OUHAJ W 45. XI. u-ul‘ (-. f‘. f.” " ~I‘HZ“ 1.14.41. 04. 1.414222.) IQA «C‘— ‘ f.) 1-- n.» It. .14- .3 333 t- Scuarcs V ltcs LLLn LLQLJSLS oL Loom— -Lonomer Jt“ q...'1io ria- O O O O O O O O O O O O O O O O O O O O O 0 t1 t4 . -‘ g I. IN “ . PJN‘fi‘ . O .4 “A 'f . ‘ '0 ‘ A. o‘- acion LLLLELoria Lo ouLm1cca Ire; SJLn Cor .centra- .t‘ \x .,_.‘- tionandLLS--03f'urG..C-1S oooooooooooooo cs . . 1 I q A L C!- I‘IA -" N '5‘ J".- .. .‘o — - Qc111ori1m ConscLLoL Lor cLe $01vaoion a_:d Cc'Jlex- ' n V“ $5. 0 _ .3. _f“ .- :‘In 0- 0.“ .1. —. . o .- CO 61 I 103.011 {48 O.L 271.. 13“. «LL13 141113193.“ on :4}. re 3 8101". 118an I, the TI'Io-Stato 1:06.51 o o o o o o o o o o o o o o o I II V .4. u- _l. -'_‘ - on us 0 'v o A‘- . .Clkali Le a 5 one COLVGnuS 1mo1oyed aLd tne1r Conger- .1- CialSO‘LereSooooooooooooooooooooo Reference Stancavds "sod f0" Dozo"11.ation of Spin concent-‘atiOCSoooooooooooooooooooo Qualitative Eature of the zéectron Paramab notic Reso- nance Spectra of Hotel—amino Solutions . . . . . . . . no w-r, . . n- Q...“ ._. - ,-: . .7. 1- _ , ,0. CJ- .3 A... 1:18 1.]901“; 1119 u «Lieu plus; .Ii. .5 OJ. b-4C L'IOnul.LGJ.‘.4.C U93016D 4- . 3 Q a, '- as a. June Ulon OJ. T." 'ne Hotc"cn‘ So1vcnt Employed . . . Tne nyoerfine Split ing, AL, of the ‘L--onor eric Species .. “1 . .L- ('1- . --'.', G5 a- ”metulon Of 1‘; :11p01a-bh1’3 o o o o o o o o o o o o The g-v lue, gL, of the LOLULVLLC Spec -ies as a Func- tion of Alke 11H tel ands olvent for a Numoer of Metal- -.L1flj.neSOlu-tion5ooooooooooooooooooo U 1.. The g-value, Ev. of the Monomeric Species as a Eunc- tionofTemperai’UJre. o o o o o oooo o ooo o ooo 1 0 'v Tne Sp 1n Concentration (at 23 C) of tneTL onoaeric Species as a Function of Beta: and So Lvent for a K1 be? 0:35: aturated ivuaL-...u.4...e 501 L1 {Zions o o o o o o o o L , o . , 1 Too Spin Conca raLio n(at 23 C) and g-value of the fl ‘7 fl .- ‘ Solvated Electron 1 r a ;1;:“" o: Leta1—. Jaime Sysoems w vars EPR Parameters of ice :.1s P the;n and Extra Absorption as Obtained by Coaputor Analysis . . . . . . ... . . . 0-) (D 15 21 71 72 73 78 WL’W'IE . XIX. '(Fif 1541 0 V1?" JULL o ‘Cfll o XT1II. XXIV. —“‘T .:':'::S - COll+j 9......1/1- Cd A "“ T) T‘) "‘ .1. -. .. ’1' ‘ .'.‘. ‘ . .. . 'fi‘J. - .. . x‘ . _ Am '0 ‘q ’3 y f... 'i . ,- . A n 1?. Uu'Tg'ICM- J Of .L'o... 1.9 LLG Susi. LS a. v: Ll u..L_'.. v.71 .L. 1.4 U;A“Ir.L£~Tfi.Ln.4- A O r -L’-=.~t:*no 2:13 I": 1 DCt'Lll‘GS.................. . -' ~ . a _ '3 7— ‘ ' -‘ on (< ‘ - n‘. . —- ’ -, u,‘ (-- .‘f ‘ .A Q .1.\J. V...O-4J .44414ld; ULL.‘ .L--’.J aSi“_1"__C girl 0 g-volues of So ' .-1.1.~ .0 c H...“ ~ an. :.-- Q_-v..!..' . Linerflfl Mn 04. DOC-.241..."".l .C b.2dr...€ -.......‘d HULL: v.LO.’-.'S o o o o o 0 ~. ’5 T n ’\ :‘- ~.-- “ --’ ’9‘ “A’L fl - n '— '4‘; '9 u C‘ r41££+ybls Oi I‘v‘uCLOC‘:1-:;-3.L;l 0;) ‘JlA‘v- V‘.” ‘UC‘_ . 5.14.8- J. .O;’. $0....“ 5-)ny- r '5 7‘ .. .1. “. G :xCLQL-z. 1....‘4'53 4-. T Cnia SO .LULJiOl S o o 1 fl 0 *fi. 9 -\ 'f.__ N 3-. “ ‘_!___ _ Lineeidons of tne bolVaoCQ elecoron . . . . . . . . . 'L‘ .L: H .3-.. .1... .0 7.. J... . .t. ,. n S irrary of tne OptLoaL ogececa oL Leoel—nnLne and 6931-:kmuonla SOlutiO..S o o o o o o o o o o o o o o o 1:11" VTlCI’IGCL-iamlne o o o o o o o Conductance of Sodium in 4 ' ‘ .0 1w '-fi,_--1 w... ,. ,3 J ,‘t,._ .2 VLsco 91 1es oL aetnjLaLLne dflu Lo: 1 ane . . . . . . J... ,.-- .C‘ .L‘, ‘ .— Conconoretion o: oLe S in C- 9 n lonomer b oin Concentration Heesvu=mznt by Phase Equilio 1um Constant Calculated Secfl rLin ewic v44u01ho-9000000000 The Ratio pL/(p$+ pa) Obtaino- free g-sli-St .An alySi and Indepen entLy 1301 Analys‘ Ls of Hyperiine Splitting for a Solution of Cesium in Stntlamine . . . . . . . . vii \O }_l \O K, 0 0 CD 93 V7 6’ 100 118 ”6332 Q. 7. 9o 10. no 13- 1151? 0? ”683133 mmawantmmuiufiou WWW ooo-oooooooonooo Commotion of Comment!” Gum I’m Spin 00h mmmummmmnnm o... @BWOCMIMIHWWQ oooooo Voriom of mo manta of tho mph-mu ’51 Dc o‘tclix'bczll'bcsllg dull/T oooooooo Vessel flood in Prop-r0 Sam»! of Sufi... Poussin. mudim. and Cain in his» Balm-ts for m moo-uro- mt ooooooooooooooooooooooooo Veasal Band to Papal. 1.1mm Solution! in Wfifitufld” oooooooooooonooooooooo Vowel cm to m saplo for mama-neat of uddoefEOm-AIHOSWIO ooooooooooooo MWWOOIMWMEOW W oooooooooooooooooooooooo Wmdymnomuu ooooooo mummowmmmmo “W ooooooooooooooooooooo mmdwumummn» ”duos offloflm-ninoonquom “0110!me oooooooooooonooooo Wspntun‘drmuiowuuom- “OfTWMMSOIM ooonoooooooo m Hyperfino Splitting. ‘H’ of tho We spooioo uohmctionofmzio mantel-8m W‘W ooooooooooooo 16 111 #2 “5 9‘5 67 76 mm 11%. 15. 16. 1?. 13¢ 19. 21. 22. Teapot-om 7mm of A! «pl-noun Sciatica: for mom-Anim- OOOOCODOOODOOQQO. Variation of Mano uth rm to: Sam Edd-Wain“! oooooooooooooooo A Pausdm-Eummmn 50mm Mn; tho anoofthoExh-ohboarptian a». o 0...... mmaumnmmw: We OO.‘OO.....ID0.00'C’QO Mdmmmdomm 80th Minna-”LN” mmmerpgobmmmmmodw WWWHMMW. ooo. mrmammmrumotmuh 0......COOOOOOCO meat of Deco-«position a tho rum W for of tho Mn. Qantas 'T the minted Aim unworth- nc oQfiII‘szII mm o (:34 ‘§Q.OOOOIOO0.0...OOOOO .‘IIUOOU QIOUQQOO.CIOI “thaw.” with n]! It..." :1 85 S 5 IBTRODUCTIOI Mmuomforoudyingooluumotthommm duulvdhwwtb-inh MoWWM mdehWtMWofl-odofinfid WW». Minthooolutioumoouidorodtobo Whammwvingulutodw.uto1m onddinco.utdm1om1oim.ndm1oflnoondooti~. Intho mmmm-ammummmwmamum mummamxdmnummm.wm. “mammal-3117!“. “MdtthM ammummouummuoumodmmm mommumoocmmuuouu. Wham-Vida!!!“ mmwmndmmmmmmamm. lunowootiodotondpohtthocooolntimmothtwtboouo “Wommddmhhuflhmm ti... maimmdmummhmotndydthw otolootm-ottod-outm. mmmmmudmmm-ommn mmmmmamctmummwmw tormuohmdrodyoon. Sinoomoouiywrkotm(l)nw¢doto “WMMdMomw-odmmw “ammo mmmmmnn-unuuwmobm mafia-mtmdmmmmoinuhruthoodm “monsoon-nod. 2 ”dammuwommmmmm I'Cololru‘u. M(2)WMWM~MW “autumnal-motion Mama): n’u'ma)‘ moismmmrumpmfi-mmuo’um cannon-1m nmnummwmmm ammummwammmmu umamumnum. mum-wuwoummw W Mommwruddm(3)dhm (M). mmmmm-upmwdm mmmmmnMuumw-«b Madonna-auction. nmmmmwv Mommwmmm. mint-mm mmunuumuwmmammm mmmmmdMonmo-A. mm” mwmwmmmw thufihth-do(6)oumooduh M(7)Wmmmuummivm ultimatum ”munch-Milt.“ MWodMMoWW mmdeWQ-uu. * me0.9.10)hno~nfiom modulators-ionic. Wmmnmmoohntom wmwammmmmmunm. amoummmwmummm mum.mmmmnumwuam.tmuu m 3 mwomwumnmm (11.12.13.111») hon sham o chain). ohift forth um ooo-Ito! mold(Mghtohifl)tutnodotootob1odm1eo1owtforthoW. Thou tomlto indicato mmuo doom density ot tho at!“ fl utdmldbutvuynttloolootmdwityotthomtoomlou. Inmtnottonluumotimgmooduinmm mnuwumwaummm dutdohmmiofimodomuoinbothdmitymdwwdth WWMHSJQ. mmummwumwmnummomm- gotod out-min}:(17.18.19.20)o m 001m“ oro Who oinglonookinthomWMhMalhbnodonod althoughonorgoido. Thoopoctromdethomotf-ho ammmuummnmmxmmu WdWmM mmwmumwudw WWWWMW. Mod dfiohnohnuolooooumuvo. mammmmm. tufflohgdnodooflyWRLZZ). Bothlodohmolvotho Wcmwummunamumu. oolntodoloctm.ooflntmotflotodwm. rhododiflm mmmmmummmamomumm mmm(o.oosuoa mm). Tho "my“ Iodol (21) men-amuboompmonwmmmmm in o “oovitr' ‘dflfio tho comm. Tho Boole-r. mm. win (an) manta)mmmuunauutmmumm Montddoetitooolvouonohooth. Bothudolooloomiflrthodinci- “(Wonduwtdoaflbom h ArnoldmdPottuooommhmomthoton-uhflooofthoug- mummuamnummmaowo. mainly-chug“! opodoo. mmmmmw oxtondod mama-Mamas» alum ($.25). MOW. ooddoopobhotmmthoMImodWmufiuhum booms. WIMohovodoobouobomodtodiooolnhon-baof dun. dininoo. mmamnmhmuu ”lotion. mmmmmmwumummuw «Wommmuummunmomm oquivdont to «tn-man solution“ 0W1: tho odd-organ dmmohmmmmuyrommoflymmotm Thomaoffldoprojootnobmmmmmoom- -mm-wmmmnmmmu Itvoo hopod that tho autumn}: of thooo oom- to Iota-Quail colum- mdummmnomumtammumm- .Ildbodmlopod. HISTORICAL A. MotnnM-moohhflou hopdtoofthoouplmthhoopummofM-dno nWonmmeQWoootta-otorooWo mumnmmuu-munwuamm. mum-wummouummummmm. ooo-mm. oolltiouo (21.22). BldoooadfioddanhoflormWofmoho! “mum-ammo. mm.uwmn Wmumeo-pmam-d-mm WhalvMoWthMMWod-imt on”. In Mob-ooh ooluflooo tho ”dun call of tho “do onlo- moo-mnummmuumoaumm mot-oioonoouthooQootqbiodniow. Moan “WWWodew-dtm lmotnoodblom.nfifiooonnuowomto ammonium-unwound“ nouns-Mound mummmnuomuuulmummmm “mum-sompumoumwwotm mmuwmawmaom. moot-moo- mooquoqnthmmummmntm mummmumumuaumraouuoumu nun-uranium. mum-«mummmm 5 6 momma-Manama onlodwmodooum-ho moddiphoucbudo. Thofonormoatdthooooditioom tho-dbl“ ”100:1” or. oflontd no “not a unto-11h trap to W mompwaoumunmnuummmwmso tolhOOqI). niphotiobodo.ooooufiufuthooboorpflood650h ”Sada-“1o b-nd). murmtropoiaohiohthonomMpor- mmumronmxmmway. flIoM'boldwhO‘o immobmmmmumwpmn-numuum thuhodmflmMpomom wfi(fl)fioflm~mum¢cm won-morpmnmmmnnauammmm. on» badnummwmuwmmuurm a man mud. «no.1. and? outoroin "mm... «in... emu-u .mmumomnnmu-auwwomum Mottholodolofm.mndndu(m% Cm. hon-awmw-bmbmummuomwm 'mmuuwonmuuddmuonwmmma mmoumm-«mumum.m. .Wmmmu.w¢mmwp. ammonium-(29) woo-N ooo-1h room-o! mmmm-nmmmuntmmaam anymoflflfi). Outhobooioofmoofthooikonootolo uwmmuw-(mpmmmmuu mussouns-pwmumuawumamn olootroo par-ow noon“ (m) ohm-pun tooth-stun iota- Iodinto oboowtiooo(800to900y)forludnhmooi¢htho omfifllofl’ro 7 mmu.umm(32)mM-tmmdm mmmowmmmnmmu ,WMuommWomde. mmmowummammw mmumuum. momonodthotthooolntiooom «adamant-mm. xommmmmmumumu wumummotmmMuwwm ”dung-ouch. mmmamxrummmmdmm wwwmflxp muamuqnoumnwuo mummoummwommmu Wuhan”. mmmwuuunum ummmmwmmnmmmomom bulb-ad. m-«medeuohd uumm‘ghfimmmwmmwxuc. (awn-nupoomtutmmmuumuwuam w.mmmutmummw. mun- MommWhom-Mdoonntdloioodm gnu-omenuvappoaumwumm. rumma- «gummznmmuammmmmm mummdwawmm. magnum- mmnomimdthoiookotmityotmuw Woman-(31.35.36). autumn-tummy whammmamm-imimmma mmumugwamduwumnmourmm wowwimmmmmcm memmmmnmm. emu-imam mummsmrmmamnmw nino with tho corresponding now for meta-main ”lotions lawmmnummmwmmmum out.- to tho minted am in tho opodoso (o'). (14".o'). (o'ol’oo . (fat-x"). and (Ht-f)? The” opodoo mo coauthor Mon-oz! to on "about! onetime". Ammdmtd-nfluanWM'oond m(mnnmmmmmwmmmmuo(mm mam-mmwmmwmn-o “outdmolmnthmmfimof‘mu mummuamnomuu. MW wwmmmdomocmu “mum. Itolunuootdthopooumntvtmw o-puiaootthoEPRIadoptiodopooh-ootogimoolntiooonooond Wammmdmmmum In". mmnmmuuu.umuo(mwwm dedmumuw. Cup-noon «mmdmammomammmm mmauwmwmuum WdethflS-aotmmmloh- wumumummmmumm mmbomdthomtno. Mouth-nuns: muumunmad(33)numunuthoomotth mum-mam. www.mmmmmum)mw mummmnmmwnumw. Rm 9 mthoudgmmto-odoiawoxthoumovfluotothdrdoto htmoofonodolimlflufilopooiooudouitodmopodoo. mdomumuommuuummwmw otMdeouhtioouitWthotth ottothoyotuooouidbooxploinodbythoouooodoi. Toilnotixm Wthonlouummmootthonhnoothntho mmumwuwimcmuz)mwm MduhmfimmMMIano. this mmnnmmuwwmnmfig. (menu-unmomummuuum. mono-now ion-mountain“: (o) 3%.:me u1m¢pmmuwmnwz)numu mwmmmmummmu "WIOJH. muthololuoboontiviwofthio opodoo muMquIOh-‘l-Iolo’lontor.“owned-.0011 man-roommotonyomos. mun-mama“; mmummmmuvwmmmmom thotpoodhloirthou-omodoomnmmofuiothm (b) MWotthMWomdthde wwwsmumumuumm tun-(mm. (o) mmdwwxmw mummdmmmwtmuutm 1m}m~mmnnmmmmmm Wotathoootuootrooto(31.52). (d) mamas) wwwm-ummumwmm “WWW" 10 x if“? i... nonénz staunolooh-upookhohomdhthommofmn omuu.ttoyu~othotl1d< 10‘“. Mthoorouoothottho Warnzwwummmuuotnm. Bolton 93.91:“)..112) (“flowitotohbooo (o) nth—duh W¢Wmmwotu1mafls(39)mdm. mmmmmmmwmuuaWo ”hm. doooopooittoo otudioo 1-m- 1mm (#2) doootylold mmommmu-mnnunup. mmmdqmmmomuwmumm- «mumwmmammeumwm Wmmwmuomimmwmamnm mmuuwummmm. In)... mmommmmaumwumkh ‘2; p maneunamumxm-mummm’gwk; mauWMWWWNMMCfiL mondoiofbyoondnonuumuowmnupdhth “mm-wuimuauum. non-«mm mtmmwtwcwmmmunnm caption-InmatfiOuiodmtdiooo-ocntuththouw wmmdecranWow-puanmonmrn mxmomuumonmumumuxwmnm wamtmmmhndfldfiom ommmmtathummumumw mandamus-macarmuumumum «wwwmumm» 11 WmmMufiwmudi-Am hymn... Dyo.flo1dooo-dflort(h6) Wthotoonltoofflmondflwt toboinonor. Hm.thiIMtoododtooutmthouoiu-ooth Dye-admxdm) «mmmumo comm olootroo. Although tho roooIt Itndioo in an labor-um (mugs) hon pro- vidodmpporttortboodgmootnyoondWUB)ofthoudw tomohntnotddinoroondthoiatrmdhondtooolntodolootmoom mmouuhmmmomormumnnmmhrm vidbhbondtoolkolimtnlmotobohm.thoooimootigotm hvomtohcidatodthomtmoafthoxpahouopmdhhmthowh bond. HootrommtlyJ. £3th (‘37)hooottonptodtooxp1ontho Whoofmtol-minooolntiombyoodmtofthvidbhbam to amino of stoiohimtry x“. Thin nod-1. oltlnugh «pm. of orphio- immofthoorpomdouowhmvtbfloohmw vomit. or ottolanghi. Emmi. on! Mt: (no). mums moi-o1 faults m to other Moll. Tho ”do! #11 ho diamond to groom dotoil Into:- in thio diooartotion. B. Rodd. for tho Econ-or Tho oboornti- o: hypornno opntting by o dash Iota notion (37.38) and continual: thot m not“ mom oxiot 1n nui- «olino oolutim. Tho magnitudo on! 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WW" Conduct-no- mu m utt-upbd in MM mmmummuummatwwm nwwxmmam. mmmmmuu mtuodhynmlduofio E. van-thaw mmmme-Wuwmm mmOWMMMhm.no now “unmatbmmtwhmumm mW.W~dMflnM.mr-dufimo mumm.umamww¢¢m1mmgmb. tummwm.mmmwmumnym mun-am. mwm‘uamwwuoxn mmtmmuuwmmuwmmm¢ duh-tau MMWMWWMWWMBI mmmmaummwwmmm tho-quan- I 11.},t1zjf’" (31) ”nummmfummmutuunu-u wmmmmummmm. no ammuurduuw. .....I-.. ,Vnuflgfih _ .....uanfluflhm-T .nunehflunuflfl. 49!...“ fl ... my u . 1 Qfij,# & , W J ‘ . J: . H ..J _ . n....v . i .u ...4.......H..1h4u - q\ . c .. ..v \\ ._ . a «THOCQCH "114:1? wruuflhdwu: . unfluflfiduv Wanda-nu! m . ..W an“ _ I ? ‘ .OQSPathEQH mo 20Hpozsm m ma oceaaHhswo A can ocafithonS mo moHeHuoomHP 03* :Hapflo 09 com: mSpmhagga go Ewamwfls XUOHm .HH CA '-I w.h papogoomfl> mezpmo myzop ow ocwH EZSom> . H «hdquuuiuu f... .. ....»i f I: t“ - A» MHz-M. «Ru-Lu“ ., FAHHHUUENH-EHUH. (flfithup. A -E- L..- Awmfl thwaaoaaop :fioHHoaymoo -A ‘ Q....u.-.w Q . sawmufmngxafiim '- s KENS A. E!!! Monmout- on Metal-Amino Solutions (Hognotio Pomotoro) Tho qnontotivo obsorntion of olootron pormognotio rosanonoo in tho motol-mino syntax studied by tho onthor m emu-ind 1n Tohlo H. In discussing thoso syntax: in dotdl no 811111 in gonorol group than according to portionm m We” homo. our aubhoodings ohm bo tho chuootoriotio Em obsorptiono or apooios. 1. The monomeric spooioso Tho ohmotou-iotio m oboorption of most potusim. rubidium. and ”aim-Mao solutions (0.180 obaorvod for «no oodim solutions) 1- o hwporfino pottorn arising from tho 1n- torootionofopomomotioolootmuithodngloolkflinotdnw 01m. Tho magnitude of this intonation is any! loss that tho "froo oton' film and is very omitivo to solvent on shown in Toblo VII. Ingmltholvpornnoopnttinginorouosuthorotioofnmm Minot-noose Thiooonnloobodovoduthohyporflnointorootion homing on tho oolnting power of tho solvent doorooooa. Studio: on diluto oolutiono show that tho morn!» Ipntting 1o indopmdont of notol oonoontrotion. Porhopothonoototortnngospootofthotvporfinotntomtionu its mind dopondonco upon tuporotm. Lo ooon 1n Toblo VIII. tho hypot- finoopnttingmohongowofootorofbmomhmdroddogrootu- Mango. Ao oonolooboooonfron‘roblovm ”MHz. 12. 7O 9' n , “H n «all. can I: a wane? all at .3.- a! no... mud-gonad: AI: .9: .45 Ala .. u . a. i o- n g nun «:56 ask.” I «in 8- a... John-no.8? OF a IE on. aha-Ewan! .15 guano .895 038. . 8.3 a; .98.: .3 can 9 u 3 a. it: via“ an 3... “no a 13 a... 188. «Emil. n «is. a. an 3 t on: I; 3.." ...! kiln" h 3...: .3 a.» no. on!» n! a a la «9.8 «I: .3 ...—an a; ...-l: 4 i, t ['8 I51... it 1 a8 g .3 OCH." 3 g I; .— .fiufil A. anon-.52! a anon-do! unab- oum Hod-a g hum Sol 3 ohm no? _ 00m. and .3 on: a; 8.3 o; as in? A any”? J pg“? 7...! cum .7...- . 9E float- M o3 193- you ”5.3 3133 38:3 3833 dual 7; a cum on: o3 non: o3 g g cum 1 CNN g 89C CHM 60.93 aha . noun." oga o3 g aha Veal I“ DH“ 63'! g an ”03 can . _ Alan o3 {flog Olg- g 6.3 09h did! an Cum ‘3 can :83 .3 ooo-unfl— onus-i 883.»: 3.88.3 ginseng §.g€u o ii 1 111 11' g 383.. 38B- 82 :23 .858 «8&8 an 33 «98 8.838 «98 2532893. 5805.33. .8 0850 8.83. «on L938 8 :85? 8 gig a. 783: you .8333.“ .36....» 352%....“ 8.83s .88 3.83. you .33.? 9H3 3838 no» 388. «9» ageing non: .838 . sodas cog com 2.33.. can Hono- _ nun 8.0.830 “om nonna- aom ~.Ff\~Fg§ 48.: 03:8 _ «ion-.93 5.53333 N , 63.... 8.6 an: as... no: .8 38.3 new «8.83» «.8 ”.88.... noon o3 528.38 183' .32 833.. can ,3... £5 .8 8.83." vow 83.85» no.8 3.383 «A 83 08:8 83 838 "3.3.: saw—8 Honmuofioa chuuifioa figgaum .Eh-«m gguu: 8.338 winning «awn B8888 533a .553 1 g; 1 2-53 1‘11 33 9H» an 716 .33 .... 39. 538.8383. can 33.39an in 3&0ng 35.85 F... .3 8358“ 3.3.331. 95 93059....“— §§3§§§§§Aanfia§ss§u$§l.§ 3533;3333 gigggtofléggfiagén 038:} 33.8.5.3: .fiigzuaufianflzagvfigfigé . 38.88838. 88.8.8.2. 3888.888} ohms-egg 3.8.34 .ét‘gfiifiigaao. J." l‘u‘l 1 4114‘ vii .Hb an. 72 7mm. mWSplnflns. 5‘.de05000000”: W 0: 000 mm and savvy: 300100-03 .7... v w 51 mm)" 801” 2380 39! A 8533 A 133a. M II'3“: 35.60 . 0.3 55.09 . 0.3 (23.0) (23' c) sum, 13.00 t 0.1 00.06 a: 0.3 120.0 a 0.0 «50’» (za‘c) (23’s) mag/14.002 5.79 t 0.1 (23°C) m2 150” t 001 33991 i 00" 171.5 * 200 ' (23%) (23%) (za'c) am: 10.25 0 0.1 99.2 a 3.0 0.0.7 . 5.0 (23%) (0%) (20%) 340’; 5.17 0 0.3 59.19 a 2.0 71M 0 1.0 (.190) (23%) Mo‘s) - ' 1.24m 2.02 t 0.3 30.55 a 0.3 07.30 . 0.6 _ (0’6) (20%) (ao'c) mm 5.15 t 0.: fi’ (10%) 1.3m 2.70 a: 0.3 30.01 t 0.3 6M? 0 0.6 (40’s) (20%) (20%) Wmmmwmm~wmmunum mun-Hod. fitnmmumquumaumm “mum. m-umpumwum-mobm-pnm wmmmwum. mmuwtmatnmm :dogautmu $015333 A".3160;A‘.82.50;AD.36303 I O «'0: (38838833 mm mm (3510:) tummy.) fl'c) human) 11°C) van”) 36.0 03 27.6 .5 10 .0 ‘ 35.9 00 25.6 .20 > 15.0 33.6 25 20.0 .25 15.0 33.0 :23 25.6 .30 13.6 31.1 :9 23.2 .00 10.0 30.0 10 21.5 .05 11.2 28.6 .3 20.0 45 6.1 ‘ cm- (1330.) ANN-m) fl'C) Auto-m) «'01 Ana-n) 80.2 22 55.7 40 20.6 03.5 22 52.8 450 13.3 78.2 7 km 43 15.2 75.0 6 15.0 43 15.0 70.2 -5 39.0 400 12.9 63.? ~12 35.8 .100 10.3 58.2 -21 33.3 52.9 ~35 26.0 735 83588888383.” W mum. (8510:) 550-000) we) Alumnus) we) tum-m) 78.8 0 139.6 ~80 55.1!» 72.3 0 03.9 -80 9.63 59.8 .10 33-5 ~80 55.78 66.5 , .20 37.6 ~90 50.21 60.1 ~30 30.1 ~90 50.71 65.0 .00 25.» ~90 50.69 61.0 ~50 20.0 .100 36.21 57.5 ~70 39.3 4.00 1394.02 5500 ~70 9.35 52.0 40 99.15 God:- (1330.) A” 1P0) Vanna) r('c) Menu) 205 19 118.8 ~30 83.25 197 10 117.8 -N 82.93 185 10 117.8 do 770” 173 0 109.6 ~50 76-90 161.8 0 10705 4’0 "071 1.9.6 0 100.6 .50 71.60 150 .2 .19 98.59 ~50 71.55 133,, 90.06 .50 70.00 lfid' .20 89-87 ~60 60.61 127.0 9°?” "° “'3‘ 127.7 ,3, 82.81 ~60 65.06 73° We) 88838 C) 8883:; 16c) 012:: “'6: 25 546001») 21.8 20.3 18.9 17.5 15.9 63016.“) 91.5 91.0 89.0 88.0 you“) 193 Aanu) 19.1! 18.5 W Pounds- (39!) 1('c) lama-I) I! 13.6 23 10.0 20 13.2 10 3.1.9 0 10.5 man (530.) We) tum”) 29 86.5 25 85.7 23 33-9 20 83.0 0.060- (1330.) r(°c) gm) 3 180 23 122 10 1!? 0 ' 153 W Patna:- (3!) 11°C) 5564-0») 23 18.3 20 17.5 16¢) .10 ‘3‘”) 9.0 0.3 7.2 6.6 “on-u) 79.1 75.0 7005 lama-m) Efi’é AH( Gnu) 15.9 13.1 c) 85822,, 5m”) 80.3 555‘“) 5.91 5.35 3.55 0.1:: you“) 3.6 37.0 35.1 32.“ 735 W and... (133.2.) rt‘c) 0,600...) We) 10 230 0 W and. (”380) we) Auto-nu) we) ~30 77.8 .02 .00 71.5 as W Pom (391) 11%) Mom) 106:) 10 3.32 .20 0 3-23 .29 0 2.61 .10 1.7: W (8510) we) 40....) «'0 25 ”.5 0 20 30.6 .10 15 29.2 .20 10 27.? you) $6.00) $9.1 59.5 560-100) 1075 2055 0310-10.) 06.6 23.9 21.9 73' mm: 1111. W. w v W WV A ..v W Guam (1336:) 11%) Autumn.) r(‘c) Menu) r('c) ANN-u!) GB 83.5 30 71.? ~10 57.5 90 82.0 10 0.3 one 38.2 03 76.7 10 ‘ 63.1 -30 50.5 no 75.5 0 60.8 mm (3’!) 11°60 Ago-nu) fl'c) tum-m) 10¢) you») 18 5.55 5 3.16 0 0.95 W Mad. (39:) we) Lama-u) «*0 Auto-...) 16°01 tum-m) 90 5.90 10 3.80 .20 2.83 00 5.35 a Mo 40 2.63 30 0.75 .10 2.72 20 0.25 .20 2.08 mum- (3550.) fl'c) “cc-m) fl'c) Mann) fl'c) 55m) ‘5 35.0 30 32.1 15 28.6 M 33.0 20 35.8 o 23.6 35 33-0 TABLE VIII. Confirmed. W Cum- (133m) fl'c) 566.100) We) Mann) fl‘c) Alma-d “ 82.5 10 6506 um 3307 to 7b.!) 0 60.5 ~30 5003 20 67.5 ~11 55-3 ~J 1"” k0 F1 'Iio 32%;.1 ' _ ---..-’ 31.1 m. -.‘-.' “41'7“ i q... ._ .3,“ --..4._ i" waxexrmnr; ; a- \u \A) i-' '1 ~3— VC7 1 “J ' ff Q “2‘ =‘"‘~ ~- J" 1 A -21, a . - ..s -o \J - -.. ~U I “9 __ . -- 0 vs- ' —¢ .J.‘L .J . v“ A J“- «In ...— -l - ,\\ "}' Lg-JJ .' ('3', £1. 3 1| 1‘ [I , ..__ l." :rvq ....) l I ?-.3, 9 ._ ‘ ... -. .fi. 1;". «.....- 1 r) L,““ ‘4 —1.L_\ ”20 ' 33 to 60 Luf“:raturg (CC 13'.~D“'5:Vifi h ~ '1 J 4.4.. V . ‘ fi‘ . 1.1V... J ...... ‘ a a ‘ 5 n . A 1 1 f f '0'!“ 'F'y 5“. ‘1 ' C .lv,‘_-‘ " '7‘ '- V‘ r. 1‘- "Y';',“C‘ d- . 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Y.-.-.? ‘ ...-.a- .- _ / 1 ll “—J O I. 1‘ l ) L‘s-g 5“ r? ‘h : p.33; 7. '. :‘ t 1 - ‘0' O ’a_ A _ V ! O ‘ ...—'3 h 'i n g- '“ \7 O O I‘ / ~_. m I. ‘ O i‘ i.‘ o/ I I, I :1 r A -r_ -‘ _.‘- 0 ll 8 In I: "i I. ".5 u- ' IV ' .2.— 'a '[ . I] Q A I . I 7 3 ._ r1 a . A .1, ._ ,A‘ n ,r~ ""~ 'x.’ ". Ltd ".."J \..' ..’.)b‘ 140 6C 80 ’f‘ _’>_ ‘_ _.L ‘.' (H‘fi‘ 2:.puca.xfe ('uj A]: ’ - . 1 ‘ N ' ""‘~""1 If." ' - r."b"-'v\r ...‘1..‘.L.'-.',.,.-... 9/140 ...,... w 74.43“ /b 6‘ ' P -. - -¢U..- --.. hj;.-._“a 31*...“; -u- cvne 13.1.1“: \ ““0 solutlons as a 1unct-. .5‘ c r1 ~.--_.. 4- r7153 "‘ -. .... r.~.-.-.J-~ ”ma )4. ~\'.;.VV.LU (...Abs 0.1.x. lv~§¥~1flnn ‘v. Ella...- q ... “I‘v‘ 3‘9 4-.-. 071/: a. .W": T.;/Ktrl.~U;§—— V . ... u '3 d 3.1"; \J-¢‘J solvw’” q. ”VIIII. uh -.‘c- — .. an; , 1 W“ .3 \. .- .. “a “.. u . n .4 u ... m. ~ “ a; A... 0.. I. .v . .. I.'VI.daV ”3.“.Maflwwrall. Ill’. 1.011 1‘ .‘ 1|.IJII.| I .f/ .. .ngutdlnafu . ,- .U . .101: . Htlwruj. 0‘ .0 Ell. n; .. I . 1‘51 O (C Ru .1). ) ‘1( ‘ y. \.1 1" .'.'.\ CF ‘J / \ .swc. ‘ 'l'AJo (I \ V l (I. n. 4 "1 P)?“““- .... ...n 4.. ‘v .a ' 0 Or" ‘09:. "‘v v“ r“ “ .0.» -- Q »\‘f."\ \-- 1.1+: -L-LA ‘l— I rs~-.~ 7" a va_J-... -C Y'lfi'r'“ \J.‘ ..l- U rag-“a )V‘. .L V OF (3 19-". Pin _ --.1- .. \.. FII Jflulfifa. .61.. JIIF c Ab IIK flv ‘105 I" r‘ A --J\’ v~‘ . ‘ .~.‘5 \a ..L ~U C!‘ O 2 o“ .L ... u.; v 0 CLOXS on?” u‘VA-a ‘ ~v.-, . O a. -| "I ~~x1~~f .. .- 1 V'ffiYfl \— VA. ‘4 'v..4 _ V . 0 75 tho function]. dopondeuoo of A" upon tonporoturo 10 not an” tho om. Emu. hmtnotoncohoothohwporflno intoroetionbooaobsorvodto 1m” with doorouing tonporoturo. Aomhoobaonodfmroblom ondl‘ig. 13. thooffoctotm- ugtwmnooorotmmuithonufinohtonoldouluoof All intonodioto botvooa tho voluoo for tho Iota). diosolvod in tho mo oolvouto. flavour. tho tuporotnro dopomdonoo of A" for tho mixed «1? vontwornoynotbotho um on forthopuro oolvonto oo oonbo ooon from ’13. 1h. Tho g-voluo of tho mono opoodoo on con ho notod fr. Toblo n oppooro to be non-1: indopomdout of tho oolvont and but ow to boootronghmotionofthoolkonnotdinvootlgotod. rho tompmturo dopondoaoo of tho g-voluo o1” vol-1oz! Ira um toutoloooonboooontmug.15ond‘roh1ox. Foroolutionootpo- tuoiminthooniuoo. guhnoorlyindopondontoftomporoturouhnotho g-volno forrubmmmd oodl- oohtiono doorooooolorhdhuithin- mmtmwnthomgofm-loo°0tomt-poromo. Thomttorofthodotopromtothoootobnoboutofodmupot- tonforrnbidimmdmim oolutionoohovorooltonpmtnro. ‘l'hog-volnoofthomorlo opooiooioindopondontotlotolooa- controtion ond 1o only slightly otfootod by tho odditiou or! monk or o oocond omino to tho oolution undor mostigotion. Tho aphmtrotionofthonmoflo opocioo 1n utmtod total-mm solutions oo o function of notol ond oolvont mod to 31m in toblo 11. Tho mutation of tho momma opocioo 1o obaorvod to doeroooo on tho temperature 18 domoood. rho rohtlvo ngxdtudo of this docrooooio oinflortothotroportodinfiof. 1&2. A Ilv ‘ <2“ '0 "' \ - 9 _ .1 A \ 8 "' \\ ‘ Q A 7 - \ . \ 6 b \ "' b. A \ 5 ~ ‘ - O\\ . 4 \o A i- ‘ d \ \O A A 250° 3 r- \\ O A "‘ \ Q A \‘~ 2 ' 410°C “'O-—-—__Q; l- - i O I; 1 1 L l 1 l 1 1 1 1 1 0 2 4 6 8 IO l2 l4 l6 l8 20 22 24 MOLE % NH3 Figure 13a. The hyperfine splitting, AM, of the monomeric species as a function of ammonia concentration for some potassimn-etmrlamine solutions. . .mnompsaom Anmm_v Esficwnfih meow pom cowpmnpcoocco maflofifim Ho nowpocsm m we mowomvm ofipmfiocoe mg» mo ..rd nmqupwfimm ocwmhomhn one .nna ouswam mm... m 63. . aw mm 8 3 0H 5“ NH 3 m o a m _ q _ _ _ _ _ _ _ _ _ _ 0 MN 0 QHSpmnmman 11111. Anv o 76o CI) —m .p S 93* 4) © ‘° ‘é’ \ “'1 ---10 $0. SC r- 8 \ . \ ...5 no— O\o' 0 73‘0- Temperature '- 23°C 20 —- I 'I L I I I I I h 8 12 1o 20 2h 28 32 Role % NHJ Iigure 13c. The hyperfine splitting, AM , of the monomeric species as a function of amonia concentration for some cesium-ethylamine solutions. Jl . . .35 m 305 mt? mawcwscoo mason? quogdsmfifimahfio SW 5" 553.3?” .3 :owpsfiom a now :4 mo monormomoo mkfiaggg «KS. :3: 0564mm Aoov opspeeogsoa _ _ _ _ _ _ o o\ .omopowa ammo on» hog one mmcwppwfimm ocwhaoghn one .oa om oo (semem Hg 77b 80 ... 75 -» 65 _. AM (Gauss) 55... O O 50- / . ,8 l l l l .-50 -h0 s30 -28 -10 0 Temperature ( C) for a solution of cesium in an Figure lub. The temperature dependence of Ar ethylamine-ammonia.mixture containing 3.6 mole % NHB' 77c oaspxas «finesse . nswam .mmz m odosem.ea mcwcfimwmmm ohspmnomsov 0&9 odd m 0 mo sowvsflom a you .4 mo oocop guano Iocfiswdtho no pd owl onspegoaema o AooV own 0:: om . _ _ _ (sensa) NV 78 naun. mannerdthMWuehI-Im.‘ Alkali Hotel Cd Solvent for e Huber of Edd-Anise Solutions. MA gum 1.34m u M mm ”In ”I ”a: ”3::- 1.99966 . 1.99%: a , 0.0003 0.0007 (23%) (23%) 2.001% t 1.99982 1» 1.99th t 0.000: om om (0's) (are) (23%) 2.001» t c.0002 (are) 2.0015 in 1.99979 .I. 1.99% . c.0002 om 0.0007 (23’s) are (23%) 2.0m :- 1.9999 :- 1.99% a: 0.0002 0.0006 om (23’s) (O'C) (zo’c) 2.001) a 1.997 t 0.000; 0.002 (46%) (Me) 1.996 t om (20%) 1099‘ * 0.001 (zo'c) (gT— 9298) x Io4 _ 79 I I I I I I v u b 40- - _ I .. 32- 0 - © 9 .- e - I 24: 3 _ e .‘ . - e O , V I6- 0 _ .D I A. O a Cl (3' av . _ . O l\ A O- A ‘LA A A A A '1 A A A -80 -4ofi so 314°C) Figure 15. Variation of g—value with temperature for 39LA: 85%.0: and 133n_ A 1.. -LLJ- 1-7 80a $55131. mmewofth-WWc-emd __ # Yuma-shine # __ A _ A __..... W W mm:- £9 game. 1(2) 3mm» 60 2.00157 50 2.00002 60 mm as 1.99986 fl 2.001% 50 2.00000 no 2.00100 30 1.999% 23 2.001946 23 1.99962 0 2.001350 1.998?!» .m 2.091% 0 1.99885 ~20 2.00112 .30 1.99902 ~50 2.001330 ~30 1.99921 -60 2.00135 ~30 1.99935 «‘70 2.00102 .00 2.0m ~75 2.00165 .50 2.00082 Cow. 1(2) Mu- 3519. m w 1.99005 23 1.99100 1:0 1.99511 30 1.99502 he 1.99073 20 1.991181 39 I-W 10 1.99190 so 1.99M: 10 1.991367 mm 1. Continued. Cantu m pacin- 31321 rain- 10 1.99097 ~50 1.99683 0 3.99m ~60 1.99725 0 1.99 521 .60 1.99729 ~10 1.99551 ~60 1.99721 .20 1.99 533 ~70 1.99773 .22) 1.99553 ~70 1.9.976» 1.99551 ~70 1.99767 030 1.99012 ~80 1.99%5 .30 1.996629 .80 1.99790 ~30 1.99632 430 1.99785 J40 1.9965? 40 1.9%?! .30 1.996239 «90 1.99016 .30 1.99%? .100 1.99878 -50 1.996323 ~10!) um: -50 1.99692 81 rm II. The Spin mum (at 2390) of the We Species u e Motionotfietal mdfiolmtterlmefsmm Mn- Solutimo‘. ___. +._‘._ —-.A A 7‘ A- —v—— . —r smut _ Span comm sedan- Mudu M 31141:... Coau- Home 1 x 10‘35 0 x 10'314 am: 11104: away 5310'“! M12] 2 x 10.654 ““2 ma: 9 a 10’714 e x 10411 2 z 10'"! mm: 7 : 16%! 5 x 10'63 1 1: 10'“! m1 1 x 10‘73 5 x 104:; 5 x 1o“u 1.2mm 6 x 104:4 1 x 10'5I-I 1 x 10% 1.3.9121 9 x 10'55 u x 10'524 2 x 10’324 fihmuwmuumwuumuuu ”matinee! solventpuiflodsiennud. Mauve-Inn“ nowmummmm 82 2. The eolveted electron. To dietinguieh thie ebeorptioa troll thebroed extreebeorptiondetectedbyoompnterenelyeieweehellneen by the electron ebeorption the line loceted et g :- 2.00190 :I: 0.0002 end of linearidth compereble to thet of the hyperfine pettern. The spin om- centretion of thie species end the retio of its oonoentretion to thet of the monomeric species veriee fro. eolvent to eolvent end troll netel teneteleecenbeeeentron‘reblem. Ingenereloneceneeythet thie species is revered by polerizeble or iodeing eolvente eneh ee eetlwleeine or the die-inn. the tenperetnre dependence of the epin concentretion of the eolveted electron veriee naked]: free one note]. eolution to the next. Ineolntioneotpoteeeiunintheeeineetheeoncentretienotthe eolveted electron ie observed to decreeee elightly vith deereeeing ten- pereture. 0n the other bend. the ebeorptien due to the eolveted electron ie obeerved to increeee with decreeeing tenpereture tor eolntione of ru- bidimendceeimninthe-inee. thebehevioroftheortrelineineolno ticnoflithiminethyhnineendethylenine—mfieeixtureemlbe dieeueeed leter. Ingenerelitheebeentoundthettheelectronebeorptioniete- vored by conditions indicetive of decomposition. e.g.. etending et rec tenperetnre or ebove for prolonged periods of tine. Thie could however he become equilibrim ie etteined very clad: in then eolntione. Theedditimotfunonieheetheeffeotofeuppreeeingthe eel- veted electron ebeorptien reletive to the eonoeer ebeorption. The gavelue of the eolveted electron ie independent of note]. end eolventneed. neteloonoentretion. endtenperemreee oenbeeeeetroe fehle XII. 83 1mm. msmmummza’c) «emanates-sum Electron for e Humbu- of hotel-Amine Syeteee. &17ent m A“ _ M g. 4* M 1: 2.0018 :1 2.0019 :1 “a: 0.0002 0.0002 1 x 10"}! 0 3 10’%! m2 2.0019 at 2.0019 1 2.0019 e . 0.0002 0.0002 0.0002 s x 10": s e 1041 1 e 1041: W 2.0019 1 0.0002 1"“332 2 x 16"! 3am 2.0019 e 2.0019 t 0.000: 0.0002 1 e 1041 s e 10% 1 a 1041: 1.2-?!» 2.0019 :1 0.0002 1 310411 9 xm’5n 1 no”: 1.3.1331 2.0019 1: 0.0002 1:10"n 7x16‘5x 2:10'314 81! 3. Extra ebsorption detected by computer marlin Capater enelyeie of potessim-ethvlemine-emonie solutions showed the building in of en odditionel brood ebsorpticn et higher monie concentretione (be). Theresulte otthis enelyeisonetypioelepectrmereehounin Fig. 15 end the perenctere of the extre absorption for potessim- . «Maine-name solution ere shown in Teble XIII. is sen else be centre-Fig. l6. thisebeorptioeieeleopreeeutinothereeine-enenie solutions. Atthetieeettbieuritingoonputerenelyeiehednetbeee performed upon these solutionu h. lithium-ethylenine end lithium eolntieee. Severelespects otthebehevioreflithiu-ethyleeineendethyleline- ownie solutions ere unique: hence. m... solutions will be discussed epert from other motel—mine solutions. Lithim dissolves in ethyleline to give highly concentreted solu- tions which can not be studied becenee or their deleterious effect on the cevity Q. Rescnences heve been observed tron diluted couples of these solutions. Therengeotnetelend solvent compositieeeuhichue studiedere emu-iced in Teble XIV. The quelitetive neture of these spectre see he sea in Fig. 17. it re. tenpereture the reesnence of e noderetely dilute solu- ticnotlithiminpureethyleeineieeeingleline ems-2.0019 e 0.0002oteidth0.3 genes. Theuidthofthieliaeincreeeeeeono- mm: nu: decreesing tmereture until .1». -ao°c 1c neesures 2.5 o. AprecipitonedropinthelineudthteOJG endeten-tolddecreeeein m. spinconcentreticneocure esthe solutionfreeeee Juetbelov-80° . 85a TABLE X1H.EPR parameters of hfs pattern and extra absorption as obtained by computer analysis Sample K-12 Temp e (°C) -38 -72 Sample K-ll -7 -15 -91 éample K-2S -8 -35 -68 Sample K-lo -12 -92 -75 5.8 Mole percent ammonia absorption) AF SF (hf8)‘.' ‘ 8F (extra (gauss) (gauss) (genes) 5.09b 1.25b n.2ub 1.17b 9.6 Mole percent ammonia 3.75b 2.11b 12.1b 3.66 2.19 10.3 3.66b 2.1ab 10.2”” 3.29 1.76 12.7 3.23b 1.99? 11.9b 9.9 Mole percent ammonia 3.52 2.63 9.27 3.52b 2.69b 2.29b 3.39 2.59 8.83 2.97 2.29 7.97 2.97b 2.2ab 7.95b 11.8 MoleAperccnt ammonia 2.79 2.31 ’ 6.83 2.36 1.97 5.95 1.89 1.98 “.69 ”extra/“fife 2.31 1.28 1.27b n.9u 3.39b 1.79 1.70 1.78 .1.88 9.81 6.95 7.78 TABLE XIII. ( continued) Sample K-9 Temp AF PC) (gauss) '10 2.9“ 'ul 2.5“ '69 2e2l 85b 19.2 Hole_percent ammonia 515(hf8) (gauss) 2.50 2.16 1.77 Sp(extra n Inhf8 absorption) extra (gauss) 7.145 9.77 6.51 ' 9.31 5.68 3.19 ‘%panra were fit by the superposition of two absorption patterns. One of these was 39 flw mnmsian hyperfine pattern arising from electronic interaction with the K and ulKnuclei. The other was a single absorption of Gaussian shape. The routine alternately adhnted the parameters for both of these patterns. Except as noted, initial adjustment was made on the single absorption. box. he hyperfine pattern was adjusted first. FiQUre I6. 86 A potassium-efhylamine-ammonia soiuflon showing the presence of the extra absorption 87 3191.3 119. one: or m Remte for 1191a: in Medea-Mania Rise-rec. 4A A A___.e. M *— v— swle hole Percent Estimated Hotel m W mes Commutation 4__ Holes/liter A _ 0.0 19" I. 19"“ m n.1,. 1m 2 9.: 13" to 19" m. line hfs . eagle line 3 1.3 19‘“ to 10” Blue line 1r. . single line I: 2.1 10"3 to 111". 91m. line 5 11.3 - 0"» to 10", Rice line hfs e single line 6 5.2 10" to 10" Inn. line as. LITHIUM -65- 0.0 MOLE nun, -80' fl L3 MOLE % NH; 2nd derivative presentation -75° 5.2 MOLE 2 NH; Figure 17. EPR spectra of lithium in some. ethylamine-aunmonia mixtures. 89 Below -90°c the line width increases as the temperature decreases; the spin concentration decreases over this sane region. In a more dilute solution of lithiun in an etlw’leeine-emonia mixture the author observed a spectrun consisting of nine lines spaced atintervalsofz.h5e0.10. Therelativeintensityeftheeimmer lineeindieetethatthelvperfineeplittingarieesfruinteraotionota Wetio electronwith four equivalent nitrogens. Thesentrelline isnuchnoreprominentthenenyoftheothereindicatingthepreeenceot enemtreebsorption. Containelysisshovedthegdvalueotthese‘hlo patternstobethe smegneneh.g’-g.-2.0019. Theg-Ivaluesofthe two species and the lvperfine interaction. ‘l' are indepmdeetetteepera- tureoverarengefrus-SO°to-98°. At-BO’Cthelineuidthotthe hyperfinecomponentsisobeervedtobelfihc. Thelinewidthoftheer- trelineappearstobeslightlylessthenthis. Bothinereesingtenperen tureendincreaeingeoncentraticnhavetheetfectetbroedeeingtheindi- vidmle‘inelinuendtheextralinmthelineIddthoftheutre linebeingnoresensitivetoohengesinthesepareneters. Theedditiee otnneniaappeerstoreeultineslightinoneseinthelinexidthet theseteospecies. Increasingtheomentretionotaetalelsohasthe etfeototreducingtheesplitudeotthecentrellinewithrespecttothe hyperfinepattern. Inthenostdilutesolutionstheextralinesasthe predoeinentspecies. Uponfreesing.thewperfinepatteraendextreline oonepsetoasinglelinew’ehdz 3; 3.2.0019) .1; -98’ . Uponfur- thercooling thalinesidth Wu(..g..s,-1o.9so.t .120°c)u1u. decreasing “aperture. Below-130°C it is clear that the spectral oce- sistsotasinglenerroeabsorptionsuperinposeduponabroadabsorptien. 90 The broad absorption appears to consist of unresolved hyperfine split- ting. The aim-1 intensity decreases markedly .1». ~98°c and «.11.... to decrease as the temperature lecreases. The low spin concentration node resolution 0.1.. -150°0 difficult. Upon waning. the single line re- verts back to the hyperfine pattern and extra in. at .35 to -87°C. Wmingresultsinsnearingotthehyperflnepatternandextra line so 11.1 .1: 45% only . single absorption .10: broad 1.11. 1. eh- .m. Above 0% the line width of the absorption 0.0:...» very slightly. However it appears that unresolved hyperfine splitting any be present up to +50%. Thostabilitroteursenpleswasnuchgreaterthanthatreported by other workersUIB). The samples prepared by the author were stable for over a week. During this tine they were stored at room tesperature and were heated intemittentlv to tuperatures as high as +50%. 5. Absorption of sodiuinnetlvlenine endthealhelinetale in ethlenedienine. When on]: a sings absorption is observed one is not Justifiedinassigningthisgmuthencmer. solvated electron. erenyotherparenegzetic species. Thnswewfllgroupthesespeotra together until further evidence can be presented neriting their assign- nent to any given species. The gdvalues of several single absorptions are given in Table 1?. Solutions of sodim in nethaienine give a week signe1(approxi- eeteh5x10‘6h) mmpm.g«.1u.orz.0017. 0.0002 mum. width of 1.le G. The g-velue is found to be independut of taupei'eture. Above the melting point of the solution the linewidth increases with in- W tmpcrfimres noreover. below the melting point the linewidth was observed to decrease with decreasing temperature. There is however 91 :5? [V e “£100! of Solutions inhibiting 0813_. 51m. We ...-... W‘— Solvent 1 mm A # A lithium Bodies Potassim 12an Colin 1013 2.001 a 2.0012 a 2.0012 a 2.0003 a 0.001‘ 0.0002‘3 0.0002” 0.0002‘ (23°01 (23°C) (23°C) (23°C) 11.002 2.0019 a 2.001? a ' 2.001? t 0.0002‘ 0.0002“ 0.0002“ (23°C) (23°C) (23°C) m 2.0021 * 2.001? * 2.0018 ‘ 2am * 14% t 0.0302“ 0.0002" 0.0002" 0.0005‘ 0.003" (23°C) (23°C) (23°C) (23°C) (23°C) ‘Reterenoe 68. bReference 6. 92 edisoontimntyinthebehaviorotlinewidthasafunctionottenpera- tureatthenelting point. is canbe seenfron'rablem. the present data are in excellent agreement with those obtained previously by Yes (68). The addition of ethwlanine has the effect of broadening this line. it Mficiently high etlwlenine concentrations . a composite pattem ap- pears. oonsistingofssinglenerrowline superinposeduponwlutappears to be a four-line hyperfine pattern. The hyperfine splitting arising Tron the interaction of a single paramagnetic electron with a 2311a nucleus is given in Table VII. The gdvalues of the hyperfine species and of the solvated electron are given in Tables I! and 111 respectively. At roost tuperature the concentration of the monomeric species and the solvated electron were appsnxinately the sane. ' 6. Kinetics of decomposition as studied by am. With the mop—- tions of isopropylsnine. n-butylenine. and Beethon-n-propylenine the solutionsotthealkalinetelsinaninespreparadinthis laboratory exhibited extras]: good stability. Sons of the solutions have been stablei'oraslongastwoyears. Theetabilityofthesolutions appears tedependuponthenetal. Lithimandcesim eolntionswerefoundtobe emsiderebly nore unstable than potassiua and rubidiu solutions. In general inn a natal-amine solution was observed to deouapose. the meric species exhibited a first-order decay. The decomposition of cosine solutions is particularly interesting. WWW solutions ofcesiminetlvlenineendthehigheralm- whee showonlythe eight-lineman.» patternduetothecesimnono- nor. When deoanposition begins. as indicated by the decrease in the spin cmentretionctthecesiunnonmer. thebuininginotasingleline (due presmably to the solvated electron) is observed. The electron 93 TABLET“. demmm h —— W ('9) s, (9-...) 12 a 10" (no) 21 a 10" (...) r‘“ .100 1.22” 1.75 .133 1.'n‘ 1.70 .130 1.31‘ 1.66 .120 1.09‘ 1.39 . 90 1.18" 2.59 . 60 1.23” 2.0:. . 60 1.00‘ 2.50 - 90 1.3:" 2.03 - #3 1.31“ 2.92 . 00 1.27‘ 2.96 .n nr‘ an - a 1.39“ 2.2:» . 10 1.36“ 2.21 0 1.39‘ 2.16 2.17 e 10 1.93” 2.10 o 22 1.00"“ 2.03 2.05 . be 1.59“ 1.93 ‘m. m. bRetesvneséau. 9b ebsesptioeoontimeetoinereaseaethelvperfinepatteandecreaeesin intensityuntilthetuperfinepattera cannolmerbedetected. n that point the electron absorption begins to decay. This process is has in lie. 18 for a solution of cosine in ethyl-ins. B. EPR Meanrenents on Metal-nine Solutions (Psruagnetiohelaxetien) Went of ’1 and 1'2 by the saturation nethod indicates that .Tz.etleastinthevioinityetreoet-perstue. waddlnowpreoeedtediemssthelinewidthbehaviorefthe broad extra line. the species in lithin-etlul-ine-‘enia solutions. uddnduineeMdae-otm-ineeoluuenshualreadybeengiven. 1. Themes-is spades. Oneeftheeostfasoinating features otthel’llvperfinespectraofnetel-eainesolntionsiethedependenoe etthelineudthupeemerrineeeepeneet. Thismolearspdn-dependeet relaxation appearstobepresntinsll solutions studiedinthis lab- orstory except for solutions of sodiun in eetlvl-ine-em-ine mixtures. Iteqwellbepresentietheseeolutiensbutbeebeouredbyetherre- 1m phone-Iona such as “all or gin Mange poncesses. The eflestisaostpronouneedineeeinn solutionsandbeoaeesinoreasdnglr lesspreneuneedasenegeeetethelighteralhaliaeta‘ls. Theeffeet eppecstobesiightlyeoreinevidenoeinthehighersuqiseineethse ineetm-ine.(ltisdiftioulttoasoertainthis1dthoertaietysinee theapparentefleoteayinreeaitrbeareeultotdiflesentestdoon- sentrdions.) Thedependeneeuponthemsleuminquantunuberie ddieiteiynostpronounoedinmedi-inesaseenbeseenwmering Fig. 19 tetig. 3. Morunetelrverylittle quantitative analysis“ 1'1 95 J‘wwfipm’ m Wu... fiWW 30 minutes 90 minutes 120 minutes Figure 18. Decay of the EPR absorption of a cesiumpethylamine solution. 96 H ‘I u 3 a I I .h w Cs in I 1.3-PDA 20°C I , I a I . i I ”l“ h ;; “ ti Cs in , 1,2-PD-A it 20°C 0 H 41.1 Figure 19. Cesium in 1.2- and 1.3-propanediamine. 97 this eledopendent relaxation has been performed to date. The experi. natal]: determined values of the coefficients of the expression 1'21'°0”1‘1*°2‘§*°3'i are given in Table XVII for those solutions upon which such an anal- ysisheebeenepplied. ihepredoninenteoeffioientssppeartobecoendcz. Thede- pendenoeuponaxthroughthirderderiereelbutthedevistionsfrol aq-etriepettenareso-allitisdiffioultteeeasoretheeoet. fioieete of the first and third-order tense. mmuond-onabetm-inesoluflonsofthenetals broadensthelinesendrednoestheepperentdependenoeuponer nines nest of the studies were node on «tasted solutions and the solubility isinereasednu-kecnruponaddiuoneT-ouihitisdiflisulttoeepe- rate contributions to the linewidth caused 11 Ila-dependent relaxation peeeessesesdfmthosedueuenshangereeetions. Indeed.theline- width of seeples with appreciable unis content was less for the an- sdurated than for the saturated solutions. The temperature dependence of the co coefficient vanes eel-Red]: mutate-std. rorpotsaainsolutiosscoisnesrlrindspendent otteeperahrewhileforoeeimsolutionsitisastrongmef taperature. 2. Theeolvatedeleotren. Thebehaviorofthelinewidthot the sinus absorption due to the solvated electron varies nae-ken: Tree letdtenetel. Pornlutdonsofnthimnbidimandoeadminthe ninesudfldnesthelinewidthinoreaseswithinoreaeingtupere- tereaseubeaeenfrce‘rsblem. Ascend-shenanfreeTablexvm. 983 TABLE XVII . Analysis of Malena-33)“ Dependent Relaxation for Several xetxbdhdne1umixmt£bdunnenmmunns.adhfinoue. mum We c0 c1 . 02 c3 A°° 9.2: 523: 32: 9.2:: 10 7&2 ' 0.235 0.335 41.021 0 6.75 0.323 0.336 0020 .10 5.73 0.322 0.351» .0.029 ‘ .20 5.16 0.30 0.301. ~ «0.032 ~30 1095 0.327 0.006 «0.023 Jéo 4.5-3 . 0.299 0.333 «0.032 .50 0.02 0.221 0.0112 .0.019 .60 5.12 0.198 0.053 -0.022 .80 0.57 0.006 0.392 .0.001 9.2m in W 1mm (20 c1 c2 03 .05 10.79 0.37 0.600 .0.056 .50 . 9.9% 0.075 0.617 .0.006 .55 9.87 0.002 0.036 .0.015 W in W Tapes-stare co cl (:2 03 a? Game Gauss Gauss Gmss 23 3.57 0.011} 0.161 0.000 98b 10mm # fl. momawsummm w w A‘ W Winn _ r S K“ _ r Glass cesi- is mums-1m w A ”1 no (0°00 a m (we) Pet-unan- 00mm 0.2 (23%) n .. 0.0 (-35%) Ceeiu 10 was». 3’1 (0°C) . 1 6.98 (10°C) Com is mus/mm» (1] 6.” mac, ~ 5) 6 ’ h 1. .6 (23%) new: 1. Main 5.: (10°01 0mm Wann- 11.8 (20°C) casu- 1: kW 3.0 (20°C) 99 themvidthoftheextrelinedeeressesuithinmesdnztupenture for alutieus of potassim in the nines. nthetheettMsu-itiugthedependeneeeftheuidthefthe extrsliueupouneteleoueeutrstiouhsdsotheeuasoertnued. 0. Optical fissure-eats en Metal-nine Solutions The results of quelitstive eptioel spectra token in this lab- eulery and elsewhere ere sI-u-issd in Table III. met-pasture end-suadependeuooefthevisihle. red. ad infra-ed heads for solutions of rubidiu- end essim iu etlul-iue-uouis sinus-es ere smile:- to those observed for pots-sin solutions (#2). D. Meta“ mu ea Sodiu- -Ethylenedi-iue 001m». homes of Wei. diflinlties only one necesstul eon- duet-use seem-neat was ohteiusd. This velue is given is tehle n a... with the values observed by Donald (71). E. Viscosity We on minus Wain ad ”hi-ins 'l‘he densities of usual-ins and ethl-ine ere given as “actions of t-peretm'e in Tfle n1. a; Re, R... an 53 Rm 3. am a Rs 3.9 m3 8.. a. 3 80 8 no GU ufi 68 E... 3 an. . om» E- S 5 03 R... a 3 WM” .3 a do 2.... 89 _ a? 3 ~52 an 8 0R." Am a do 83 .8. u as 9s sad Ea" 3.. on 5 do 92 can 8- 3 ma .....ll... .1203 4 i A! as. 0.1 1...... ....1... I!!! so: 35 Bits... as: ooo-lo...— g ...-58 giggling-£38.63; .flug 10th .2 «.0 an.“ 8% 3.. S .8 «.5 n.“ 89 .3 «.0. 3a N~ S 89 .8 85 nu 3 «an». .3 Re 8. 5 one u com .3 0..» So .3. u 3. Run 1. NE. m3 e 89 N . 9. go on E 08 o 2.. 82 8. a... 5 03 2... no .9 .8 Re R... u emH 8m 8. Re. 8.. m cum 8 a. 8.. . «mg ...... 52: .3 as. u. , calla-m £2 95 850.88 899834 sac-task Vim in.» 1H 11. 1 a t : 6.83.8 .3 39:. 1000 AAA NNN A“ a: 00 do! VVV UV ”W AAA a: ‘0 00 .3 .8 .3 .3 .3 .3 .3 .3 .3 .3 :3 OH 0d ad ad OH OH woo no." No... .358: 3.60 .39 an... 87 u «E. “on .. .0 no no a. a. e. u u u a. 3 NE...— .33. ...-£8 ...-3308 .5 no... 10M .3. .«c .3 .03 35 .05 SC .8 .3 .2 .3 .3 .8 .3 8... a... “co 0..» MN o.“ no." 39 a. a no... 68." 3.. a. a ...... RNA ... s. n. Rm 3m 98 as 83 Sun a“. as. .0. .32 8. .l. or... .3 .... u. a .3 an in no 3.... «moan. E... « «an: Ewen... E. mom +~eg 1000 .nnv .Huv .Huo .auv .0.“ .Na. .«uv .onv .uuv .nv ”we H10 mfiofl 3 NH“ “In “To nufl n66 eta 3 ”we on" ...... 58: .sum "an. ...-aunxg. §§§§§ § '4 g §§§ §§ §§ omw § .nu..aum usages-nu .znaianwlar nu am aan1neu 3 am ,uxra. an-zugw .a-aaaunxu .guu “any“ 1001’ can in»... as w ..on 8389.. ......“ .R 8.8.83 3.3 Java .8883 .3 .8 8883.. .3 .9... BEBE .3 an gnaw .3 .3.“ £333. .3 .6... 8.88.3 .3 in 8983 .9 3.3.. an .3 .8 89.8.8 .0 can? mH an 3.35.1 g a. .3558 .3 gm 101 13:31.; II. “was. of 80:11:- 13 magi-undid». ..._‘ .._‘__ c'} a w2 gymnast Wau- me 256‘ was 25.5‘ 3.65 25.3” 3.23 25.9‘ 1.55 $13“ 'Rd'm 71. hm. m. ‘ 102 rm E. “consign of Wu!» ad Wanna. 1W nmm-uno was” ’1“ mg?» # «azimu- 296.» 0.250 296.15 0.239 $9.2 0.276 $3.2 0.299 273.2 0.236 0.323 33.2 0.285 0.333 263.2 0.291 0.3?!) 258.8 0.300 253.2 0.331 0.515 $3.2 0.372 0.136? 239.7 0.1337 2}.) OJiOO 233.2 0.182 0.588 33.2 0.1380 0.?30 223-2 0.671 217.5 0.800 213.5 0.552 33303 0.665 33.2 0.83 COICLUSIOIS A. The “figment of the Optical burpuem l. Them-redband. Themfiefmton. me. fieldenendnu't (#6) leaves little doubt u to the correctnes- ef the “tumult by Dye and Develd (33) or the nan-ma bend te the eolveted electron end .3. gregetes. . ' Aeouperleohefthe epineeheentretunetthe manna ettrl- buted to the eolnted electron with the ebeomeaee of the buffered bead Mantel thet in may ”tel-nine eolntune the electron mete largely in din-gut“ aggregates. 2. Theredbmd. Ifue nemthattheequilmmetatter therewtinn 2147-”!2 lathe e-eh eelutim he 1t1ehtbe¢uphue. nemptedietthe concentratioaetflzfrutheneemed epineeneeu- trutunetthenono-erle epedeeu. heredietedeeaeentntuhetltz 1- given in Table m: for e number of metal-cine eolntfims. The agree- nentulthezperhlent u canbe eeenbyeuupeflng Table. XIII end m1. mun-1mm. Indeeditughthmbeenexpeatedthatthem- bun: eenttnnt would hm been alanine-nth W n a reenlt of 41!- tereneee e! eolntm between H and 142. If. a: pointed out by writers in thle label-uteri (#2). the red baduetbeudcnedtetheln;4-——12;trmdflnne£theduern tutu-«ting mm mm. mm. mm. doee the ‘12,}..— :trm- title: ”our?" By marina with the higher energy transition 1t night 103 10“ rmxm. desonwmmwmw mwmwaudouma-mm 301m Dim €19an hole-lutea: “ Sodiu- Poteedun Rubidiu Cell:- # m2 6 x 10'"3 2.7 x 10" ms... 1 x 10" 3.6 x 10’” 1.6 x to" ma] u x 10"“ noun: ~sz 9 x 10" m x 10" 6.7 x 10'“ um: 7 x 10'“ a x 10" 3.3 x 10'” 34:" l x 10-6 3 x 10-6 1.6 x 10” 1.2m» 6 x 10'“ 6 1 10" 3.3 x 10‘3 L 1.3.9121 9 a 1n 2.!» x 10"“ 6.7 x 10"3 b 105 uwmtmk;+—kzunumwummm Wrench. there new Ippeu-e te'beeune experheatel evideneete abstentiete thin. As heeboeapeflnted eutto the “the: (105). the Winfreredebeorptiontdlemreuhentheredbudlepremt “mitt-absent. Hone-meethettbielednelerelytee'er- 1-pu1thth.‘n;¢——1£:umnmnmbopomodmtthau¢ overlap would mm: reenlt 1n leu tuna; er the unwanted inn-end ebeerptua. 3. mum.m..m-mwmamwot MMQmMZ)tbettheudblebeadlenetdetethewe eyed.” respondble {WW gutting. A melee! e! Tablee XI udmlndieateeneupleteleeketeemletinbetueentheepedure- Nefertheaepmeaeg Unfortundehthe ark reported in thin thesis thme little Mtuponthehemreeftheudbleepedee. mmytmumtu m1! thetthe species which gives fleet. thefllihle bend cannot elusivenoeteeehcpmmd. Medeeenetemulndethepudo Milwthettheudble Weflveerleeteebu'eedMebeu-ptua. lftbevldhle ebeerptiea hung-o" Mu upmamw aye ad herald (33). tn peedble We ebeerptzleae eenld renlt. mmddtheeeleatrlpletabeorpuonrenlfincfmtheutem- eetunettbepemecneueeleetreaefthenzeereuththeeleetun wnuonndormxgm. nn1m(56)hummm lineudthetetfipletcteteebeorptmn‘lmby 1.51 .. 1.0/10) #2082 + as - 3) [(3/2) + (SM/(1 mfg) + mmfit’ffl 106 Ihere #2 - um LID“! 2 + (16/3) unfilz + (124%) and D is the fine structure tensor. To give the reader a idea of the multitude of triplet state line width- ue uh thnt for the one of nephthelene diluted in dnrene (106) where n“ - -3 x 109 Opel n++ . n__ - -o.21 x 109 cps. g - 2.0133. end at. is taken to be 10"-1 nee. glam”. greeterthentwhnndredgnu. Itvould thneutbe e duplentterto eeethenephthdeue epeetmi- ablation. Reina (107) he: discussed thie ”able: 1! cane deteil. , Thin eeeueternleenttheudp-entefthemaeerpfiahin Manama.» eolntiene te a triplet Me Hake" specie» Sineethelineuidth «22% iaenlyeftheerdeu-efOJ sense. both the fine eta-nature interactioh and the correletien time would hm to be extremity can to mt?» the ebeerved epeetre. tor cap]... it e eon-elation time of 10-11: see is chew. the fine Mature tenor mld hm to be only 10 G. t A second possibility of an m ebeerptien arising {m the neleeule-iea would be the intereetiea of the per-unmet.“ eleetm a the 11; core with the two equivnent ma nuclei. liveleon (108) bu m thst nah intereetin m1 rum. in eeoatributioatethelineddthgimby faking) :- ROI <12) .. O\[> Figure 20. Comparison of p§ obtained from analysis 0 hyperfine data (triangles) and independently frOm g-shift analysis (circles). l _?n n 120 Thiobedutheoooeveoreoovfoeedtdththeprebluoteeou olden-inctheetteoteftheweqnilibriunpeothet-pero- tnredependonoeefthec-dtitto. Tlopoooihle atmotinoeoohentu unboundorthehightnperotnrebehoviorotthex-dzitto. Theoeu'e WMcmyinflc.Zlo i) Cooel. Blevievtheoboeovedc-dtittoobedueonotentotthe higherte-perotnreothonvonotoootheotenendmoohovioc equivelentuonntoofiglOertitelootthenetAldn-dintothoirm- (notion. Thedifferenoeiothenepitndoetthomrineinterootlon iothetuqeeieounldbeviooedinthioeeoeuerioin‘trenthe peoterentutofothixtoreefenitedoototeointhonenooer. ii) Coer. Sineethereioeondderehleoootterinthedotootuoher Witwbethotthewolneiomooeouthinereomten- poo-mo. unohoooooawomovmeWMMoudhom ammodighteontrihntdootothetotelvmcfion. Onthobooioerezimwaevimcueleppem tobethenorerealiotioefthotlo. loo—mmeuolndethetthoehoervequlittiu ads-Moonbeeupldnedenthehooioefeqonibflomm whendioopodro. Thenetueefthog-diftopenitothode- tailedopedfieotionetthomeftheoogeodoo. homunotthoioo-pdriovuoodoo ‘ffloo pair) :- l{§. vohri‘g O;(e1)} m§.iothemuonet-eleetreoinoeuityinterootin¢ onlyvoohlyvithenodaeeeotootelnclm. Mouveooouerpreooion forthec-fiitt .L”.L 4O 52. o '3' o\ o o // o; O\ .../.0... .... i O O O O 0 Case 1 «$0 «:50 3 40 ea “Tigmngn (om:) Figure 21. High temperature g-shiff behavior in light of models for the solvafed atbm. 122 Adieu pm) . (gum) [—2.— .. l] A! 113‘ or. meeting charge trenoi’er interaction !2 EUR?) ma“ mulotdonoinvelunctheevelnetienefthdoeqnetionintheluhtet word-entail evidenee io given in Agenda: 1. The motivation of the neon-er io oeen to be moon-ooo) - flaws) + (mm 4- Man) + mm . owns) A‘(10l pm) I "' wedded} Thiegiveoriooto honoree-dearerthec-ohittcivenw Adana-er) e {o £00) + hint!» e €50!) e dang [:3— .. .53.] An‘ Wolholleoon-ethot 5%— oo. Tho Adan-er) . - {o gm) . 1.13m) + ozom + 4mm} 2%- -oooom.t1.o.:th.eopoodo.oootho.opno¢.o-om inpinotrundiutoeednperdtonoteevdnotetheeentribntion leteodneftheifiOIetolndll-Iflfleclveot)emmotethotetd gin-“teeming. Thedetdloettuotreoheotmuveninlp- purist. Oontinincoevieothomtiontorthootonoo «Tc-run) - agar/(us) + mm) + W013) + Wcm 'f“’~§1é03“i’} 123 Thoditterencebotveenthotwporfineopnttingintheotonendinthe mminothotd’>>oc. Reflectanceherzetruoteroederivetortheotoo Ada...) . . {a zoo) . b' tom) hCeool. b'tzoo'IZ-d'tzo-OuhileinCooe2itiolikelythot "2" "'2' “2..., «2‘» “"2' ““2""? Whotheruenoeoototdonu'yototeereqnflibriunodel. In euqalmticnofthetwerntnredopendeneeoftheg-daiftonnot aloe onloin the tuperotnre depudeuoeefthemmne oplitung oince both oftheoe phyoicol veriohloo oreintinotoly relotedtothonotnreottho novofnnotion of the pornognetie electron. For ex-ple + 2 31 a b (.- 3> (“A”) “mum;tppendixlthelz'oeelmlotedfru¢-ohiftoeupledn thecorreetprogreodonoi’luperfinooplittincvdneofronnetnte net-d. endtrcn eolventto oolvent. The render near underuhy enlytuo oped.“ (ate-o end none-ere) venereqdredtoeaqolldnthotuperotnredependencootthemine intorutieninpotoooim-etm-ineeelutdonotilethreeqoedeome remred to eaqaledn the turpentine interaction end c-tdfto in cedin- onineoclntiono. The-cot reooonoble eupl—otiu for thin iothottho concentretion of the ion-peir io nearly are in potuoin-ethn-ine routine. In feet thio ooouption onledno the eboerved W independence of those-chino. Itolecoemoteelnldntbemmmintupero- tnredependmdopotudm-etlwldneoelntiendtadeccnpooition endrecenerotion(oeeli¢.22ondhet.lb2). Thehuild-upotdee-pooitien 124 2C) ES l Effect of dec0mposition on the temperature dependence of the hyperfine splitting for a sample containing 1.2 mole % ammonia. Circles represent the hfs values of the regenerated solution triangles those of the fresh solution. Above 35 C. identical splittings were observed for the fresh and regenerated solutions. I 1 l 1 20 4O 6O 80 TEMPERATURE (°C) ICDC) 125 m-1¢Wutmmmm.m kahuna-Mont bWuWthMcmmmucnnndacM-phfiu ..an mum.) Mom‘mdnhuuduqldnthtm mmwmumhmmmum on!» untim- than in pots-W cautions. than column- mmmamumnmmmuntm» mum-1n; ofthioa-pdrhud-mmcuuydunnltfmmm dual-outuot-omntho-huuud. “Mum ”WQhWIMRMWh-aumolmtmmm. mmmmwmmwmwuuu Mummufluhdld-npotmnn. mwpdrwuh :mwmu—uawm. mmmmnmmaum-ummuw ”Mdeg-MdWWMOBo-mdh mun-cm” column. A. bu bun mil! national (1&2) ”mu-ammunbmmuu-muonmmwm- .130. numb-anumuummu MddnfidefuMp-rhdcdmouuuhuac motor-0d. MWWofthohflndpmficmod Minoan-purisfmrdatthomudthm. Ind-edit mmmuowmmwm-oudflou-(ml). mmManmlommufltdthom Buchana- ~hnpmoqu11m-wsuhmmnmunnyappndbycu- m Ind m. (109) to M81. ”Wain-.130 calm... hfmutMomtmmmubounnnuma cannot be It but 111-31th duel-113d am the aninh‘iml nod-l. 126 mmnmm Mobmwmudthopflflmduh thbncdaWWflde-vfiml. Mgwdnofimmdhflmduthuadim “momma“. manutmnmohntotma “Mlnuahoflldfldthodimofpflfhuam «W». nm-matumambwmaam “dud-tanned. Mumudethhmw “Mostummbluofflnmofthnumm. hmldthtflofiwafihmMutbn “Mintflmwuthnthulvfiaddm. minding nfimflmdulmtiltuwunmmqfimmdmnoh thadekdiMflmunhu-Wmfrmuqd tbPM3(uM?Q-8)munnmm. 2. muivmdoim. mmmmmotw ng-Lmio.0002btbn1vadw. Mmsmmu ‘ «Manhunt: a) mwmumuutbudmrmnm(¢.. 2.0023). 250.10%ch mailman slit-13W!”- pm a» ant-nu an up ohm-d putt (Add...) - moon) mbMummdemWodm nacho-um. W.tho¢-vmo~dhuuthog-Mfthhdo- mammuuimtmwummmu W. UhWoole-Wm- utmmuummuMoWdW 127 sauna-«quantum. momma-mamma- mwuimtnmmmmmummmma an mama. W) of the mm mean... u- ...-hut «mulmnmwduthwumuonund MWMMde-u‘m. 1:) custom. ma. umtfisz)mmmmm [mfflw gums] sawdmtuu- mwxmucumnmmnmmn. In «sum. thermodthomduu [Mal/[W Mu] taWdWhtb-mmdumudom (0.3. II"). that «Wmmwmnmuuu. mmmmoruwmmu ”(-0170 + o'( n17.) <_“""_:Z ll( I011.) ammumwmmwumuum WMIthhih-Mmdammwm o) mmwmccmumunmn-m mowmmvado-m. c. Morgan-www.- norm-unufihmhmmudm WWhMWhh-dwmu mmonMtfimIWan-odw Wounds-who. nichNWMa-drdaot mmmmammmmmumo. m1... unfilwflodqlmwmo dpuflnnfinubnflodmmmmdm mucmmtmnthoumn. wommmm 128 val-Inn node].- upabh of giving the h In trap-adult W0 mm. “mm nawum-uaunum-u-«mmum'm MMfidcfiholéhmchmnM-u mmmumdwdmwunmdw. amusemmm-pmmm-nnmmnmaa. “mummm.23adnum.h.thcudfldutud mmnfiwupumummmtotmum “W. mmmmm-wmmmwmn- awm-mthuhthuumldu-tum- mummumduwumnum W(ml¢mfi~d$)dflumu§ow mum-(mptmh. 3,..uflthoqut-1llnnh Mm)uuthmm. women-Inti- wuammumwwumm. waxmmufimouuuuwmmww «mWM-umummwm m-tmomm-pmmmv. Qumran-acum- Whtbouflfidmhotthowmmuum munmummmaandmuunmmw unwodeMI-IW. tannin-Ith- Mum-uwummmmuum mdmwmumcmmmm Wmmumummmmoummdm Mulmmfl. an-mmm-uubm. muuumw¢wnmummumo (Gauss) C o 7.0 6.0 5.0 l I l I l 1.5 2.0 2.5 3.0 3.5 ' n/T x 103 Figure 23a. Variation of the residual linewidth (Co) with n/T: Cs in EtNHZ. Results are shown for three different sample preparations. 10 \O O ‘J Kl . 0.50 .5- A A A A A 0 O o 1:: U D C2 (Gauss) 0.30 CI l l l I 2.0 2.5 3.0 3.5 ' n/T x 103 Figure 23c. Variation of the coefficient of mIZ (C2) with *n/T: Cs in EtNHZ. Results are shown for three different sample preparations. l 1.5 C Gauss 3 ( > -O 001 — - 14".1‘" "M - - m 5:537 -o.02 g... ‘9'.-- . -0.03 [>l 1> ouDQ [>0 OD A Figure 23d. Variation of the r: 1.5 I“) o n/T x 103 efficient of mI3 (03) with 72/1“: Cs in mmz. 3.0 3-5 Results are shm:.. for three different sample preparations. 130 wuwuwuuww. m1}. www.demIt-mnmtanMm mmamau¢mwuwmm. MOM-(0.3.. M) mammali- Madmancntmudmmmdfluwmutb ”nonhuman-um. mammwamumm mmmmwmut-Mowmuds tspmcmtaBMMQMIfluu—IMMI! mmmmthanWm-x. numwmmmmmmWa-u- -Wm-mmm~nuwuum—um utnmiwwwwuu-m. nwnuummmmmw dfioWdM‘Wwfld-‘hwm. mwfim nmmmamnmmmnma unmmmmnoammnm-umu mummwmmum(mw) umrzurlmmmy. Mouton-I. await-ph- anauurpm-mnuwunnu MWQM.&WM~bfi-W «mwummrzuuwuuumuu- WWMhfinfltAuc-ndcmm mummumw. Munitio- lmrzmtlwmmmm 131 + " 1H“%’ 2 2 l um-mmmm-mmmumimuudmw mommmmumflocmmthoobmwdmml mutabmtdum. In «tn-13- conflu- doth: nI-dapcadut rel-nun the "mm-mmmmWWIGnmuwmm-n. mmmm herlflu-Mmddoapcumuaymcu- mutmwmmnwmwma up)”. MWflflmddhcflyhfmmA-flmcflmw' mhmdoquflibrhnnthouhoflnr. Abdel-«haunts. Mommfamlndtbummmm in. at. s.- mind museum .: um um. pom (76). ammumwmmmuwwm mummwhntadflnmplmdmm—mBJhr-B. Khulmdhinladdmptmtmdmuhhnn. .mu-awxuummqnums‘mdunnuuum manum—umnwm-uuaummmmw m1. Sim-flai'onnmlduuamdnelnuouth m5. mmnmummmuamc vnmxmmmw-Immrmmw of the molar I91: Insular manta. mwurmamwmm. amino-tam Mohammad: mucoffl+1nusuthcmqnttm I "' ’1‘; "’ ’3‘: in. ’A and p. m the prob-tuition of finding Penn 1 and B. respectively. 132 m-mtmmumqnmhnmmmm reluctant-ammo” (no) and all. front» 810d: unsun- (93) u Mdbmmtbmmcctuahm(m). nth-Bluebonnet... tor—1m. 1m. inch ”on at (mu) We. “1“!) and Leg-1):: the We! it» h- uohtod rm. ”dam. in the unit ottmm.tonmormnaq (0(5) - “Log-1) ”laugh-1) (#0) fluWhmemcmmcmwoM-a hhnluthnclomqnmmlthmhfl-nfiahnn dthmufioammmn. mm-mauuunom cough-dancmthcutbmwmofflnmrmmn. nmuummrnmmm-wmuunum tram- mm «a. $2.1"- tho-matu- of an 1am. WMiomthhmuQ-mmnu- W in gutting (80.110). ~ am’) . (gm . 1]”) (m "‘uuifunurif "93‘5"!“ mmadmmuu-drmmm»uuguenm mmm-um-Aumnmnmmmom 12%;) - viz} * 51% + V3¢< 4 “’2’ 93.2}. " P35}: "’ 'fV’APn‘fi " 5": Mo Y. - the mm We "no ad ’1’- 1113“ ’L" + T3) and rgurémmmumummownw 133 Mum-c. lcuwthd-I. unqua- uw12(-I)icthbnmmflnfortbnnmw mumuaommmm-x. rundown-cu Madamw(uun¢dcmmn 1.; m) - [rs-1m] {1 + tic-I) [w - 0(3)?}‘1 03) In Mo and nits. tho m 1: [Mu-I) - cog-1)]; .- [|v.|!2(n1)]'1. manummawmmnm mama-dun. demnmmmmu Why a, - (2H? [m up . 0,0,1]? mmmnmtmmmmmm-mmm unamumam $105) - r310) + 1< [wk-1)?) (M) M. for an oped“ W m ‘31“) " Fir-21 " ’3’: (BM-1)?) - vhf. ugh-1) - Lush-1)],z mammmmunmmnu-unm runn- for m. dnplo filo-m Ind-1. an. m- is all. applicable to “mmliodddw-(ndunmlmdunw Muaum)nmm¢um0nsw. 1'0 WWWMOIMQIMMU'mth-Uhh W mmnwwmamwa mums-mum 13. cm) - Y3 (Em) - i] [m + v) - £3) (#5) 1(0) - {$00 mwtw. (he) ans-Ina. mmmcmmdmnm.u.o. My. the We m :1“. by (110) 1510.1) . “0).; + 131(0) (m unmumamummrammummmrm. manummmomm-mumam. The mmrmauau ummmumtumuumota 2‘. 1- u‘la..k‘x‘+kaxa The nimum-mn 1‘“) . P‘ + [x‘(°) " P‘] W (”t/1)! Mo ’t. 1113“ 1" +13) nth’tk.k;1013.k;1. u pp- 1‘(~)-k3/(k‘+k,)- 11“?“ M3). Tho. mmmwmmuatu-tmmmnunhu tutti-00.01.313.157 PCAILt)-p‘+paup(-sle) mummwumnunhurmnnuutu 135 “We” ' PB [1 " ”6"”? )1 with amu- eupeedeu 1! the We epedee 1e mum: in M30 m mm... W been” vfdt') - g plan) - i] g uplvmiur) - I]. - p‘EpA + p3 m-t'l'tfl (ItA - I): + mall»B » p,L cam-um] u, - I)" + 312‘th - mum/1)] (1L,L - Ema - I) - v.93“. - aim-We) Th0 Fender trustee: of :(t') 1- tin! :(w) - varu . firth“; - 5)” ~ (#9) Mining thie medulla“. W fine In. It2. maimmmmummumu MWeduuqutueI-plmmemdm Mueududelebmmwmtmnemflm- may vmmdthefine(fl.?8.79.m). nun-o er!»- mammals-audmwmmemmu- mmuummmdmwummmd anew-n gaming. My: <(u)2)<< 1]. and mum . nultettbefenetk.371evmdfifllentmteepedneu— mummmmmotmqemmw 3(0). mmmmdubeud-pleJmndde «mwmmmmmWMoun-mm. nwmexmmunamn-mnmumnw mumwmm. mun-«41mm...» 136 mmmwmhnmm). tern-p1» ammo. tum-mummumwummuau nan. mmuummqnmfihummum at: p‘. we the one with gutting AB bee rout-1w ante-At: pa. mum-ammtmrmnm '3‘? " !.210.) "1’ * "I 21 nu. . mu- owe-don t..- the m m- a. m rz}(.)(nx) tetheudthutheebmefmmmtwfene. ”the reteehneeee.thenneehe¢eteeeneeeeullnutem. mmmwmmebmhmm qubwwmmum.mmnm Wee. Above meat temper-Mu the W "new. more uuwwuwmmm.maumm mummwmucauunnm {amended-WNW. Amwumwmmmm marmqunmeamm.ddrmau damn-uwmmmmmwm demeuenheekedeu. BeneeWeeetthemu-nne mpummmmumm(aa)ummm m¢nmum(sb)mdumuunq.m. “mm-manummdmnfiumm- mmwmnwuummmum.mum Mum-mum. 137 n. mmsmn-Wmm homesteofmmm mt addition (0.3.. 13:01- !(M) ). mmumwmwmm.mw wimfodthespmeuuunuumopumebma smuflsnmmmmmtudmmnm er melee: span-independent We. mmmzmm Mmeeee involving“ eelnted am and eelventemeh-ge anathemmmuw. WEEK!!! 1 nmummmommuumammmmam- mmmmamummww E‘. mmmmmmammimmmwimum, mwzmmmudmeeormmd-nm WMmmW. nmmnnmmmauua As‘vamummm “mow-mount. mmsaAs‘mmemumphmndumma-pmorm mummnumutmmmm» MeWh mannem. MMtWemm-efmuuMe umummmmmummwwum mem1m. mwuththeneeem E‘m nmnrmnm‘x. mxvemmuzfcmumnrm. m. 13) 1mm. OpuodAdemnz. uo'umrwmu immune-‘1) Péwfasmmntorxhgeephue K Rb Ce 11017-5 12.700.2 11.4616? igw‘igmm for H2 1: see plan 1‘2 “’2 6"2 11.6%.? 110190 new ‘17); («iii mum for H2 in no place Ia I”‘2 6"2 15-369.? 12300.2 111.551.? figs—Jig mate... for :42 1.. comes: x2 F"’2: “2 \ 11.835 11.236 9709 ‘ fps—- 5i mama for H2 in comm ‘2 “be c"2 5.3%“ 7.758‘ 5.759‘ (pa-ado) PM (Feeds) 5 mane. tee- x in new-flee I h Ce 9.686. 90% 8.1” mum-mundane: 1,; #239“ abetted“. 15-50 mu m. Puncture used in Holmiu- mam Granulation. ”.— A"'°'°°°” AfiWJ-W 42‘ a 7.813 a": AB‘teeemed) :- 7.813 a“: gag,“ I 3-57 «’1 é: (3)”1'.“ I 5.57 “-1 um A 3 I UOeOOOh A3 I 11.169 u'l g‘fih I new “.1 AlIe-Oem .1 APO9e696fl-1 “"51...“ u my) a.“ El“ I A (...-0.0008 03‘ I9.6S$ol.1 5(3) HIM-b.370- awn-36.5%.“ 3‘35’x'1'95'" Asa-0.0025 A3. .90273 .4 50(54):“. I 1 II”! E 1. A e . 4.073 A3. I 8.1% ..1 E(g)~1w . hCS7 “.1 £16m“ . 537 .4 131 Tim 1x211. Calculated Value for I at 23’! for We Present in Mal-lulu Solution» 4_._A _._.____._ _._____. A“ ww- ,w W— ..— W l Soluted neutron 0.11 Ion-«put 0.11 n e.16 Be 0.15 I 0.07 m: 0.09 Ce 0.0? 1. 2e 3. h. 5. 6. 7. 8e 9e 10. 11. 12. 13. 1a. 15. 16¢ 17o 13e 19. amass-3:3 :2. 2m. mm 13. 601(1362). c. A. but. 1. g. 3...... m“ a. 1323 (1908). 5. read and I. J. Eugenia. 1. m. m.. n. 39 (1933). 2. mm. m. we. 32' m (193). I. Easter. m. in .. 5. 133 (39%). c. 2. Wm. Jr. and e. 0. rm. 1. w. m... a. 199 (1953). 39%;)0'331133e M W MW” 0! came Chimp c. 1. nine. i. 5. w. m“ 3. 86h (1915). “Cowhletmn dhhl’m e e e 3.5113(1957). ' lawm' %'(m’)!' r. m. can a. 2.. mu. 1. m. m- m» £2. a. a. ch‘emll and c. a. fish. a. m. m... £2. 1.511(1937). 2. v. mam and x. 8. mm. 3,. m. w... .% 1693 (1962). 2.3. mean. «upwmnz. mass». :3. 8. 02.1113. .1. m. magi. 3729 (M). C.1.Kme.z.s.6mendw.6.m e 'Sw’m 32,2206(1927). ' ‘5 Wecemwh’HeHMbflewEfleefifi1(ume hc.mmtm:.hm1.a.%.m..£§.mafia). ”e 501‘! W are 1. 170m Ime g" 913 (1952), Re” 601% immatien. Mm“; If mifiml'sumq. (1962). 8.5 .. 3"“. Be: e33 «Ln-'1 J.Cersetmd6.1epeutre. “Heinz-Mew W W103.” We Ge 13%”. “I! ”e 5e We we Ae mm m9. [3w tort. 196% Pt We 1&2 3’3. :1. y. 35-. 36. 37 e 32. 39. he. ‘31. 1'53 D. 3'. Yam ‘3'!!! 3e J e 12335793361. ,2: m“ QM 2...-..mm ...—$5.3 £0 “Solvateci 21mm» aflted by 2. F. ma. 2.3.12.2. Mata. Mata. tween. roe Ce.» 1365. 125. 1. 22pm mad 2. 212223.. 3... 2 ~32. m... 3:. 12:29 (1953). gt Eff”; R. 5. I133 ”1.53%. ma B. J. “£193.. it 2:. m0. J. O to $33315 “Cid Le PM J?" i. Me $0. El; m (196:3). 2. 6.12m 0. (222mm. .222: .. 22. $212,222.22... ,2. 5.3. (3232 23. m... 22. 135 (133053! 31.» Chfle Xfi‘.’3¢e file 3791. (1%). 3. made. and J. 2:. 22225123. m. i. “*2 ...... 33. 1211 (1955). I. C. R. :ms. 1.“ fine. [3323's. '23 15223 (19‘3”: $23.23* 12. 9‘) (1332?). 2. c122: and 2. c. a. 32m. 1. 2:5. 33.. (195?). t. A. C3533” m 3. Re M £31» G7". e we; a. 6m (195;)0 G. 2:. ..A 2.222.... 233'. R. Fifi-03m. .222 If. C. R. W. 5. £32. Egg” (1’33?) 33:: . s. 2. ind-.m- end 2.. 2. 223222912. ,1. m. 1733..” '52. 12.52. (m). P. 3.. $23,222.23. B. R. 25119:. and A. a. twt. i. 22. .392” (1960) m3. .1. 1.. rye and 2:. a. 27.22121. .21. ...... gm... £5. 135 (192%). ~ 9. Tu flow Co... mm RF, 2222 G. Embers}, Mbectga g; .... ’92“. 19539. a. 2. teens: and a. 2... r2». 1. 2:3. 2:3" _:,. 1:1 (195%). a. a. 22‘122. M. *3 :22. gamma Mmmty. Maui. 195:. Lawmmanntwmbm. ”...“. .10.:“(196 ). x. Bar-£11 and 2'. 12. mm. .2... flag. 5. mg. 522. g. 352 (1963). He “Mimflbdg I. EM-vm. 3. M“. n6 1‘. 3e Tattle. he; le me we! Lug 31733 (13354}! 5 C J. Le “9‘3. L". Slob 351m. “35 E. He “Mi. "5?... -..('t3 1’30“! 33m 5.809.133 of £310 Mariam Chane-23. Maw (1533;: 3.1. 1963). De $.555e 3'36. “‘7. 2:33. '4‘). 51a 52. 53. 55. 55. 5?. 539. 60-. (21. 1332} 13.33. Dalton. ’9 Dow Egfigm MJIQLC milw 23.33» Mb. 33.359 (1343) o I. BN1}. Ind T. 32. mm. J15. in C31»- l m... 252. 2538 (19633). H. mm» and 2:. .2. am. 3,. £533. m... 52,. 13312 (12365). D.R.J.Ca2yean.h 12.333311. R.A.C®m 32:53.th 3‘3 £3.33.me «Eton H. “593%. J. P. Keene. A. J. WV. Illd ‘ . ii. 5W9. 1mm: Press. Lemma and 2139 1am 1965. p. 8&3. L. at [331105. J. I}. {23. £9 E. 331.11% m 331‘ J. 3% it w 33M») ($3 .... m was. J.- D. W mm. mm D. B. O'EJ . i. w “0. EL 13735 (193513)' no :0 93331113 d T. I'm. lo 32%. m“ .3. 3333 (1965):: Thu 911m 3 a 6.5 at 0°C and 033121111“ (2.5):1'3192: at again my 7:. the 33323333233223! of the remiss.” gamma. V912. as" used. m: We: that the Wmlomut tam Q ,, has a 1:212» at 8.7. Echill the 9W1 :3qu. m m fér «mam is m. m thawmmdngmlmformuia 0.8. RC mama. F. C. R. .3} 2...... m J. H. Tim. M 00n- {szzmaoa Chaim AWOI‘EW .‘ipinfiomm. cm. July. 7 . hmmfil.a.¢.a.£mM3.w.flpping.i.mmgb JohWDWLaE-cmm Wfimmfimmmm new. East. musing. Wat. 196.36; £- 2333. am. to ho 912211“. £0 1!. EM £0 M213 ' l 3.5- ?99 (1955’s It. 5. Vegan and a. 1. Mae. 1. 2m. 3.. E» 11:? (1960). n. amass. I.» m- u” a. 133;: (1955). I. m an 2:. Mann» 1. . m... 5.33. 194 (1966). A. J. nun-go. £31112 Sm» 3.13. 53333 (1965). h!.mton.hn.mw1.3.hmmdc.n.fimnu a. 113233133333. 3,. m" a. 10:7 (195?). A. ‘32. Gm m... mu Q; 533? (1953). 15:5 6'4. 3. Bmoka. 2:3. m.m. 1?:11 (:2) (119:). £5. 5. FM ”4 A. F. Kip. 23"" ‘50 gnu... :2. 3:27 (1'55 553 Go 90hr. M. m. Immw a: cums. Rea-m1”. 112;» 5‘50 3o 1. W. 15%.. 33.. 35,. 2'::‘3-"5 (13255). 6’?! R. ‘4! W. m. m" :3_ 31 (1?55)§ 68. E: I}. Vex-a. {1:3 :3. m Wm stats mmty. mm mm, ?". 69. r. a. yawn. n. a. Maid. and .1. 1.. ram. :Mect: gagm 9:14:13. 53,“301?m nwtmx." mm W R. 5'. WI "W33“ “um“ fiaiaa‘}. hasty. ‘: ar‘fim. 9. C... 1965. Pa 153. 1’0. 1... 1!. Fe} Emu. E: '3. 19:53.3 Pfiiclfigm 5w.» Heinz-212.3. East Im- “.38. 3.: 7‘ NI 71¢ 5.59.. 33mm: :1, E23,”: , 3»: As. Eimgm mu Hafiz-521%}. East; Lansing. 1" 3. 72. I: I». 5'7"!) M 2". L. 3532‘. rfifi ...- n 3:. 2'30 (35963). 73. a. A. Ewe-ca and 2':. ‘1‘. Ram. J,» mu £33. 919 (15:55:). 1k. 1’. mm. 3. mm as» n. c. 5mm 1.. ca- - £233.. 2: 3913 (1363). 75. cameta ”stats was W m the values on! Win Mica). @0213th an Wad by tho- Eatinnfl Mar-J 6f 5mm ..rzatimaa. 1:990th mwnmcmmumatm Renewal Erma; of SW 1mm Em Minty!» 76. e. a. ma. mm e» am 23:21» PM spam-occupy. 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