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DATE DUE DATE DUE DATE DUE 6/01 cJCIRC/DatoDue.p65-p.15 MICHIGAN STATE UNIVERSITY COLLEGE OF HQME ECOI'TOMICS 'j. _ EAST LANSENG, MICHIGAN r) ABSTRACT A/éOME RELATIONSHIPS BETWEEN ABRASION RESISTANCE AND TUFT HEIGHT IN SELECTED TUFTED CARPETS OF ONE HUNDRED PER CENT POLYPROPYLENE SURFACE YARNS by Patricia J. Murphy Three single level tufted carpets of 100 per cent polypropylene surface yarns, each having a different tuft height, were selected for this study. Other factors, including tuft density, tuft type (cut or loop), and yarn twist, were held as constant as possible. No attempt was made to control the price of the carpet or the manu- facturer of the fiber and/or carpet. The carpets selected were obtained from a manufacturer and local retail stores in Lansing, Michigan. The price of the carpets was within the medium range for polypropylene carpets; one sold for $5.95 per square yard and two for $6.95 per square yard. All laboratory testing was done under standard con- ditions using methods set forth in ASLM. Preliminary testing was performed prior to the beginning of this study, using a fourth carpet to standardize all testing procedures. The tests performed included fiber verifica- tion, by burning, solvents and cross-sectional and longi- tudinal microscopic observation; yarn twist; total carpet Patricia J. Murphy weight, pile yarn weight and backing weight; loop length; tuft density; and abrasion resistance. The specimens were abraded with the Taber Abraser for 50, 100, 300, 500, 750, 1,000, 1,500, 2,000 and 3,000 cycles and the number of cycles required to reveal the backing material. The weight loss was determined at each of these ten levels of abra- sion. The weight loss was found to be significantly different at the .05 level of confidence when an analysis of vari- ance was performed on the data. A .005 level of confi- dence was found for the weight loss at the endpoint and for the number of cycles required to reach the endpoint. The Duncan's Range Test was applied to the data to deter- mine which carpets were significantly different from the others. Although the study was too limited in scope to draw any conclusions concerning the abrasion resistance of tufted carpets of 100 per cent polypropylene surface yarns, the three carpets selected for this study were considered low in abrasion resistance, using change in visual appearance as the criterion. Approximately 150 to 200 milligrams of weight were lost at 1000 cycles of abrasion. This is within the "excellent" weight loss range of a classification set up by Thruslow; however, it does not take into consideration the fact that poly- Patricia J. Murphy propylene is the least dense of all fibers and consequently, the amount of fiber in 150-200 milligrams of polypropylene constitutes a fairly large volume. The visual appearance of the carpets changed markedly when the samples were sub- jected to very few cycles of abrasion. Even with fifty cycles of abrasion, the carpets showed broken and brittle filaments. By 100 cycles, enough dyestuff had deteriorated to cause the fiber ends to be white and the color change was very objectionable after 300 cycles of abrasion. At the 500 cycle level, the path of the calibrade abrasive wheels was worn below the surface of unabraded areas of each specimen. The difference between the loop length of the high and low carpets and the high and medium carpets used in this study was considered sufficient to reveal a signifif cant difference between the abrasion resistance of these carpets. The high and medium tuft height carpets did not show a significant difference in resistance to abrasion. This is probably not only due to the fact that the carpets of medium and high tuft heights were closer in loop length than those of medium and low tuft heights, but also to the fact that the loops of the carpet of high tuft height were leaning to one side and so received a somewhat different type of wear than those carpets with upstanding loops. SOME RELATIONSHIPS BETWEEN ABRASION RESISTANCE AND TUFT HEIGHT IN SELECTED TUFTED CARPETS OF ONE HUNDRED PER CENT POLYPROPYLENE SURFACE YARNS By Patricia J. Murphy A.PROBLEM Submitted to Michigan State University in partial fulfillment of the requirements for the degree of MASTER OF ARTS Department of Textiles, Clothing and Related Arts 1968 ACKNOWLEDGMENTS The writer would like to express sincere gratitude to all those who have made this study possible. The cooper- ation of faculty, friends and the participating manufac— turers of polypropylene carpets is especially appreciated. The writer wishes to thank Dr. Mary L. Gephart for her interest and support. The encouragement given by Dr. Gertrude L. Nygren is most appreciated. Mrs. Stephenie ‘Winkler has been very helpful in providing guidance. Mrs. Nixola F. Bayle has been especially understanding and willing to assist whenever possible. Mrs. Kathryn B. Riedel has given very generously of her time to this study and has been extremely helpful throughout its entire devel- opment. Miss Sandra J. Woolum has provided much of the necessary moral support. The continuous effort of these people and many others has led to the realization of this project. ii TABLE OF CONTENTS ACKNOWLEDGMENTS. . . . . . . . . . . . LIST OF LIST OF Chapter I. II. III. IV. V. VI. VII. TABLES O O O O O O 0 O O O O O FIGIJRES. O O O 0 O O O O O O 0 INTRODUCTION . . . . . . . . . REVIEW OF LITERATURE . . . . . DEFINITIONS OF TERMS . . . . . EXPERIMENTAL PROCEDURE . . . . Selection of Carpets . . . . Preliminary Study. . . . . Laboratory Test Methods. . . DISCUSSION OF TEST RESULTS . . CONCLUSIONS. . . . . . . . . . SWARY O O O O O O O O O O O 0 LITERATURE CITED . . . . . . . . . . . A-PPENDIX O O O O O O O O O O O O O O 0 iii Page ii iv 1% l7 l7 18 18 29 38 M2 L+5 #8 LIST OF TABLES Table Page 1. Carpet Thickness in One—Thousandth Inch Units Under 0.025 Pounds of Pressure as Measured With the Schiefer Compressometer for Three Selected Tufted Polypropylene Carpets. . . . . . . . . . . . . . . . . . . 31 2. Number of Tufts Per Inch for Three Selected Tufted Polypropylene Carpets . . . . . . . . 32 3. Average Cumulative Weight Loss in Milligrams for Three Selected Tufted Polypropylene Carpets. O O O O O O O O O O O O O O O O O O 33 H. Analysis of Variance at Selected Abrasion Cycle Levels for Three Tufted Polypropylene carpets. O O O O O O O O O O O O O O O O O O 36 5. Duncan's Range Test of Significance at Selected Abrasion Cycle Levels for Three Tufted Polypropylene Carpets . . . . . . . . 37 iv Figure I. LIST OF FIGURES Average Cumulative Weight Loss in Milli- grams at Selected Cycles of Abrasion for Three Polypropylene Carpets. . . . Page 35 CHAPTER I INTRODUCTION One of the most recent developments in the textile field which has had especially important implications for carpeting has been the introduction of the synthetic fiber, polypropylene. Polypropylene is a member of the chemically inert alkene (olefin) series of hydrocarbons and is composed of long-chain propylene units (-gE-CH2-). The polymerization of isotactic polypropylene was patented in 195% by professors Natta and Zeigler and the production of polypropylene as a textile fiber was begun by Monte— catini of Italy. (12,p.l7l) American manufacture of the fiber was undertaken in 1958 by Hercules Powder Company (ll,p.529), and by 1962 multifilament yarns and staple fibers were first made available for commercial use in home furnishings markets, apparel trades, and for indus- trial applications. (l2,p.180) The first polypropylene carpets were produced in 1962 by the needle felt method. Because of the extra- ordinary resistance of polypropylene to moisture absorb- tion, the carpets of polypropylene were suitable for uses uncommon to carpeting materials in previous years. Poly- propylene carpets were sold for use in kitchens and l bathrooms, where spills and stains might be frequent, as well asfor use in other rooms in the home. The introduc- tion of polypropylene as a carpeting material took carpet- ing out of doors. Being almost completely unaffected by moisture, this carpet fiber could be used on patios, around pools, on ship decks or any other area which might be subjected to water and dampness. Some manufacturers now produce a polypropylene car- pet fiber resembling grass, and these carpets are in use as lawns, golf greens and athletic fields since poly- propylene carpet yarns can withstand approximately 1,000 times as much abrasion as grass and need no care. Besides the felted and grass-like forms, polypropylene yarns presently are available in braided rugs and tufted car— pets. (9,p.25) Tufted polypropylene carpets for home use were introduced in 1965 and this construction technique has made the new fiber a competitor of nylon and acrylic carpet fibers. In 1966, polypropylene claimed h per cent of the carpet market and 2 per cent of the total synthetic fiber market. (15,p.101) According to Textile Industries, February, 1967, the consumer desires several characteristics to be present in a carpet considered suitable for residential purposes. These conditions include: reproducibility and uniformity crush resistance durability resistance to pilling and fuzzing aesthetic appeal flame resistance soil resistance lightfastness washfastness anti—static properties (15,p.98) Abrasion resistance has been chosen for this inves- tigation of polypropylene carpets. Carpet fiber dura- bility, or abrasion resistance, is dependent on the strength inherent in the fibers as well as the structural characteristics of the carpet. The structural elements important in determining the degree of resistance to abrasion are tuft density, tuft height, tuft type (cut or loop), and yarn twist. (3,p.37) The hypothesis is that carpets of a similar poly- propylene fiber content, tuft density, tuft type and yarn twist, but with a higher tuft height, have a greater abrasion resistance than carpets with a lower tuft height. The assumptions are that the carpets selected for use in the present study were of comparable construction and yarn quality and varied only in tuft height. The objec- tive of the study is to determine some relationships between abrasion resistance and tuft height in selected tufted carpets of 100 per cent polypropylene surface yarns. A review of current literature on carpets has revealed that although many testing results from studies on nylon and acrylic fibers in carpets have been made public, there are very few data available concerning the behavior of polypropylene carpets. The existing informa- tion about polypropylene as a carpet fiber is almost exclusively that published by manufacturers of polypropy— lene, especially as advertising material. The product has won its great consumer acceptance by virtue of its soil-resistant properties alone, and research is needed in all phases of polypropylene carpeting to determine its actual performance in use. CHAPTER II REVIEW OF LITERATURE The first polypropylene carpets were introduced to the consumer market in 1962. The needle felt process of entangling fibers about a woven scrim of polypropylene ribbon yarns was used. These carpets were sold for both indoor and outdoor use and were especially advertised for use in damp areas or those areas likely to be subjected to frequent stains or spills. The low absorbency of poly- propylene allows almost no penetration of moisture into the fiber; therefore, it is not harmed by dampness, and most stains and spills can easily be wiped off the fiber surface. Polypropylene is a chemically inactive sub- stance that is not damaged by most solvents, salts, acids or alkalies. Three years after the introduction of needle felt polypropylene carpets, several companies began making tufted polypropylene carpets. The backing material through which the yarns were punched was usually jute, although other substances were also used, including woven strips of polypropylene, non-woven polypropylene fibers, and non-woven glass fibers. The manufacturers of isotactic polypropylene expected the fiber to become rapidly established in many areas of the textile market because of a number of properties inherent 1. in the fiber. These properties include: High strength (h.5 - 7.0 g/denier tenacity, wet or dry). (lh,p.l) High strength is important in industrial and some apparel applications. Low specific gravity (0.9 g/cc.). (lh,p.l) With the lowest specific gravity of all natural or man-made fibers, less polypropylene by weight can be used to produce an equal bulk or cover. Good abrasion resistance. Polypropylene is superior to cotton, wool, rayon, acetate and acrylic fibers in resistance to abrasion. Superior chemical, mildew and rot resistance. Polypropylene fiber is not attacked by mildew or any other organism and is resistant to almost all chemicals. This high resistance to deteri- oration by organic materials is the most out- standing feature of polypropylene. (l,p.6) Low moisture absorbency. (0.1%) Since poly- propylene absorbs very little moisture, it allows very little of any staining substance to penetrate the fibers. (l,p.H) Lowgproduction cost. Polymerization of poly- propylene is an inexpensive process, allowing the prices of the fiber to be below the prices of the competing fibers of nylon, acrylic and polyesters. Polypropylene currently costs $0.80 per pound, while nylon is $1.17, acrylic is $1.13 and polyester is $1.15. (l9,pp.95-106) Nonallergenic. Like all synthetic fibers, poly- propylene is nonallergenic, giving it potential use in hospitals and public buildings. (l,p.8) Low rate of static build-up. (l,p.7) This is a desirable feature, especially for carpets and automobile upholstery material, since an annoy- ing shock can result from friction followed by touching metal if static build—up is high. Low rate of static build-up is due to the low mois- ture content of polypropylene fiber. Polypropylene fibers have some characteristics which are less desirable in textiles: l. Relatively low melting point. The melting point is 3330 Fahrenheit, with a softening point range from 3050 to 3150 Fahrenheit. These tem— peratures are too low for some industrial appli- cations. (lh,p.1) Loss of tensile strength through oxidative degradation caused by heat and light. This property eliminates polypropylene from some industrial uses and prevents outdoor use of the fiber in tropical areas. (lh,p.110) Early manufacturers of polypropylene saw tremendous potential for this new fiber; however, low moisture absorb- ency prevented dyestuffs from entering the fiber. The failure to react with dyestuffs limited the new fiber primarily to industrial products. Research was concen- trated in finding a coloring method and nearly every known dyeing technique was attempted. Early coloration had to be done by solution dyeing techniques, and even this did not allow a full color range. Later, experimentation with fiber modification methods improved dye receptability and the possible dye range, but the technique proved too expensive for practical purposes. In 1963, yarn and piece dyeing methods for polypropylene were discovered, whereby the addition of residual metallic catalysts created dye sites within the fiber. (13,p.3H) This discovery afforded a possible dye range to allow the manufacture of a product acceptable to the consumer as a carpet fiber. (6,p.36) By mid-1965 dyeing methods improved sufficiently for the fiber to be entered into the market in apparel and blan- ket fabrics. (l2,p.180) Today polypropylene has found its widest acceptance as a carpeting material and is currently one of the three most competitive fibers in the synthetic carpet industry, being outsold only by nylon and acrylic fibers. (15,p.101) Other present uses of polypropylene include socks, neckties, knit sport shirts, sweaters, blankets, upholstery, patio furniture webbing, place mats, grille cloth, rope and cording, feed bags, bags for packing raw wool, and carpet backing material. The tufting of broadloom carpets began after World War II with the development of the wide tufting machine. This construction process used needles to punch yarns through a woven ground fabric to form loops on one side of the fabric. These early tufted carpets were predomi- nately made of cotton yarns tufted to nine and twelve foot widths through cotton duck backing. These carpets were generally inferior to woven carpets, the construc- tion process used for most carpets at that time. Tremendous growth has taken place in the tufting industry since 1950, especially in tufted carpets. The manufacturers of broadloom carpets began to tuft wool carpet fibers through jute backing. This process pro- duced a carpet superior to the cotton ones, although the jute was sensitive to changes in humidity. This problem was solved by the application of a secondary backing of jute held in place with a latex adhesive. Next, as carpet wool fibers became more expensive, the broadloom tufted carpet industry began to use man-made and synthetic fibers, using first rayon, then nylon, acrylic, modacrylic, poly— propylene and now polyester fibers in both staple and filament lengths. Other yarns, including acetate, metal- lic and Saran, have been used in the manufacture of tufted carpets but have proved unsatisfactory. (10,p.101) 10 A leading manufacturer of polypropylene presents a comparison of the basic properties of polypropylene with other major carpet fibers,acrylic,nylon, and wool. A rating from "poor" to "exceptional" was given to several carpet characteristics. Polypropylene was given a rating of "exceptional" on abrasion resistance, stain and soil resistance, and stain and soil removal. This fiber was classified as being "excellent” in color retention, and ”very good - excellent" in texture retention. "Very good” was the score given to resiliency, rate of electrostatic buildup before and after shampooing, and "good - very good" for pattern retention. (1,p.9) Nevin and Mumford made an evaluation of the charac- teristics of nylon, wool, acrylic and polypropylene as carpet fibers for use in volume residential, luxury resi- dential, and contract carpets. These authors stated that "soil resistance is a noteworthy advantage of polypropy- lene." This particular property is "currently precluded by the durability and crush resistant properties which limit the useful life of the carpet in even moderate domestic use." (15,p.101) Hercules Incorporated cites a test in which the polypropylene carpeting produced in their plant proved to be equal to nylon in abrasion resistance. After 700,000 revolutions in the Tetrapod Walker under conditions simu- lating severe stair wear, the only signs of wear shown by ll polypropylene or nylon carpet samples were some broken filaments. (1,p.3) Thruslow writes, in reference to abrasion resist- ance of polypropylene, that wear resistance was so outstanding that in a normal home the abrasion from walking and cleaning and gen- eral use could be resisted for many years without wearing through the carpet. However, on the edge of stair treads a particularly severe type of wear is encountered and it is important to know how the wear resistance of this new polypropylene compares to conventional carpet fibers for the stair tread type of wear. The stair wear test was conducted with a Taber Abraser using CS-17 abrading wheels for 100 per cent nylon, wool, viscose and polypropylene carpets. A rating scale was set up basing resistance to wear on weight loss: Weight Loss (milligrams) Classification Per Thousand Cycles 0-200. . . . . . . . . . . . . Excellent 200-H50. . . . . . . . . . . . Good M50-700. . . . . . . . . . . . Fair Above 700. . . . . . . . . . . Poor In this study nylon and polypropylene both rated as ”excel- lent," wool rated as ”good,” and Viscose ranked as "poor." (18,p.9t+) Laughlin and Cusick conducted a study to determine loss of weight and thickness in carpets after 50,000 revo- lutions in the Tetrapod Walker. The samples selected were of tufted nylon, wool, acrylic and polypropylene surface l2 yarns with either cut or loop pile. The pile height was constant for all samples but the pile weight was changed by varying the number of tufts per square inch. After the carpet specimens were run for 50,000 revolutions in the Tetrapod Walker, they were measured for loss of weight and thickness. Those polypropylene carpets tested revealed the same percentage of weight and height loss whether the pile was cut or loop, while loop pile lost less height and weight in all other carpet fibers tested. It was found that for all carpet fibers studied, an increase in pile weight resulted in a decrease in the percentage of pile height lost. Laughlin and Cusick did not try to make any judgments as to which fiber pro- duced the best carpet, nor did they attempt to compare the results of their study with probable results in floor trials, since they did not use an underlay nor did they add soil, which would increase the rate of carpet wear. However, floor trials were conducted later using samples from the same carpets that were used in the Tetrapod Walker. The correlation coefficient for the floor trials and the Tetrapod Walker tests was found to be 0.93, sig— nificant at the 0.0001 level. It was concluded that the Tetrapod Walker could be used to provide a quick, simul- taneous and meaningful assessment of appearance retention and thickness loss as related to actual performance in use. (H,pp.HHH-HH5) 13 A study reported in the Journal of the Textile Insti— .tutg gives the correlation coefficients for various abra- sion machines. The correlation coefficients for the Tetrapod Walker and the Taber Abraser were found to be almost perfect (0.99 and 0.95, respectively). (20,pp.371- 372) The studies cited above reveal a lack of agreement as to the degree of abrasion resistance found in poly- propylene carpet yarns. Both manufacturers of polypropy- lene carpet yarns and independent research groups report high abrasion resistance for polypropylene carpet yarns, while one independent source made reference to the poor abrasion resistance of the fiber. Polypropylene is expected to find even greater uses as a textile fiber in the future. At the present time it is primarily used as a carpet fiber, but is gradually working its way into other areas of the textile field, including blankets and apparel. Polypropylene is an inex- pensive fiber to produce and although it is now slightly cheaper than other synthetic fibers, the cost of research, especially dyestuff research, constitutes a large percent- age of the retail price. Eventually, as the research costs are reduced, the price of the fiber should be lowered, resulting in a low-cost fiber with some good qualities for textile products. "1. CHAPTER III DEFINITIONS OF TERMS A number of textile terms used in this study need to be clarified. The definitions are as follows: Abrasion Resistance is a "type of destruction resulting from frictional forces on fabrics; rubbing away of fabric by attrition which may occur as the result of friction of cloth on cloth, cloth on external objects, and friction of fibers on the dust or grit in the fabric." (17,p.137) Acrylic is a "manufactured fiber in which the fiber—forming substance is any long-chain synthetic polymer com- posed of at least 85% by weight of acrylonitrile units (-CH2-gE-)." (8,p.22) Carpet is a ”fabric for soft floor covering, especially one used for the entire floor area and fastened to it." (3,p.38) Endpoint is that point at which the primary backing mate- rial is first visible due to abrasion with the Taber Abraser. (See Plate IV of Appendix.) Isotactic is a regular form of polymerization retaining the methyl side-chain on the same side of the back— bone chain as follows: 1% 15 -gHCH2$HCH2gHCH2CHCH2............EHCH2- H3 H3 H3 CH3 H3 (12,p.175) .lppg is a ”fibrous skin forming the inner bark of an Asiatic herb. Shredded and spun, it forms an inex- pensive but strong and durable yarn used in carpet backing to add strength and stiffness.” (3ap.39) Multilevel Tuft Height is a tufted carpet construction of high and low tufts producing an embossed pattern. <3,p.27) Nylpp is a "manufactured fiber in which the fiber-forming substance is any long—chain synthetic polyamide having recurring amide groups (-C-NH-) as an integral part of the polymer chain." (8,p?23) Polypropylene is a "manufactured fiber in which the fiber- forming substance is any long-chain synthetic poly— mer composed of at least 85% by weight of propylene units.” (8,p.23) Sample is each individual carpet used in the study. Single Level Tuft Height is a tufted carpet construction in which the tufts are all the same height. Specimen is a piece of a carpet sample used for a single test. Standard Conditions are 70 degrees Fahrenheit (I 20) and 65 per cent Relative Humidity (i 2%). (2,p.l7) Textural Effects are the structural characteristics and fiber qualities which lend to the final appearance and hand of the completed fabric. Structural l6 characteristics include tuft height (single or multilevel, long or short), tuft density, tuft type, yarn diameter, yarn twist and fabric construction method. (1,p.6) Tuft Density is the number of tufts per square inch of carpet material. Tuft Height is the length of the tufts of a carpet. Tuft Type is cut or uncut loops in a tufted or pile fabric structure. Tufting is "a process of manufacturing pile by means of inserting loops into an already woven ground fab- ric." (l2,p.289) This ground fabric is generally closely woven from heavy yarns° Pile is formed by drawing a yarn "from the face through the backing and through the face again with long loops left on the surface which may be cut or uncut." (5, pp.110-111) Egg; is the ”amount of deterioration of a fabric which results from breaking, cutting or removal of fibers." (l7,p-l36) Yarn Twist is “the number of turns about its axis per unit of length observed in a yarn.” (2,p.423) CHAPTER IV EXPERIMENTAL PROCEDURE Selection of Carpets The carpets selected for this study were single level, tufted carpets of 100 per cent polypropylene sur- face yarns. The yarns of two carpets were tufted through a primary backing of woven 100 per cent jute fiber and the yarns of the third carpet were tufted through a non- woven 100 per cent polypropylene primary backing. All three carpets had a secondary backing material of woven, 100 per cent jute applied with a latex adhesive. The uncut loops of each carpet were made of 100 per cent poly- propylene bulked continuous filament fiber that was slightly twisted. One of the carpets was obtained from a manufacturer and the other two carpets were purchased at retail stores in Lansing, Michigan. An attempt was made to hold tuft density, tuft type (out or loop) and Yarn twist as con- stant as possible while varying the tuft height. Neither the carpet price nor the fiber or carpet manufacturer was considered in the controlled variables. A medium price range for single level polypropylene carpets was 17 18 selected; one carpet cost $5.95 per square yard and the other two were $6.95 per square yard. Preliminary Study A preliminary study was conducted to standardize all testing procedures. The carpet selected for the prelim- inary procedure was made with 100 per cent polypropylene surface yarns. The yarns were tufted through a primary backing of 100 per cent jute and a secondary backing of the same material applied with a latex adhesive. The uncut loops were made of 100 per cent polypropylene bulked continuous filament fiber with a slight twist and fifty- six tufts per square inch (7 by 8). The tests performed were done under standard con— ditions of 65 per cent Relative Humidity (: 2%) and included: verification of fiber content of the surface yarns, yarn twist, thickness of the total carpet, thick— ness of the backing material and pile yarns, pile weight, backing weight, loop length, and abrasion resistance. Laboratory Test Methods 1. Fiber Content Verification a. Burning Test Five surface yarns, each approximately ten inches long, were removed from each carpet and held in forceps over an evaporating dish. The results were noted as the yarn was held close to a flame 19 of a bunsen burner, when the yarn was in the flame, and after it was removed from the flame. The odor and the residue were observed. Microscopic Observation Longitudinal View--Five yarns were taken from each carpet. Each of the yarns was placed on a glass microscopic slide and the fibers were separated with a dissecting needle and covered with a glass cover slip. Microscopic examination was made at magnification powers of 10X and H3X. Cross-Sectional View--Cross—sectioning of the fibers was done with a hand microtome following the procedure set forth in the ASTM Designation: DlHHH-63, Standard Method of Test for Cross- Sectional Characteristics of Cotton Fibers. Cross-sections were made of five yarns from each carpet and were placed on glass microscope slides and covered with glass cover slips. Microscopic examination was made at the powers of magnifica- tion of 10X and 43X. Solvent Test Five surface yarns, each approximately one inch long, were removed from different areas of each carpet. Fifty milliliters of meta—Xylene were poured into a beaker containing a carpet yarn. The beaker was covered with a watch glass since 2. 2O meta—Xylene is I flammable, and the solvent was brought to a gentle boil for ten minutes. Yarn Twist--Yarn twist was measured by using ASTM designation: D1H23-62T, Tentative Method of Test for Twist in Yarns (Direct-Counting Method). Ten yarns ten inches long were carefully removed from each carpet to prevent distorting the yarn through stretching or in any other way altering the number of twists per inch. Each yarn was mounted in the clamps of the Suter Twist Tester and the twist was completely removed by turning the rotating clamp until the fibers were all parallel as deter— mined by passing a straight pin between the fibers from one clamp to the other. The direction of the twist was noted. Each yarn was measured after the twist was removed and the change in length was recorded. The average twist per specimen was calculated by using the formula: total number of turns observed in the specimen length of the specimen before untwisting Average twist per sample was calculated by using the formula: sum of the calculated twist in all specimens number of specimens The per cent change in length during untwisting was calculated for each sample as follows: 21 sum of per cent change in length in all specimens number of specimens The above procedure was followed but it was found that the latex adhered to the yarn between each tuft. A solvent was not found that would remove the latex without damaging or distorting the yarns. Each yarn in the three selected carpets was made up of two colors of multifilament fibers with all the fibers of one color being placed on one side of the yarn and all the fibers of the second color laid parallel to it on the other half of the yarn before twisting. Because of this ar— rangement of the colored fibers, it was possible to make an approximation of the yarn twist. Taking care not to alter the number of twists per inch, each yarn was placed in the Suter Twist Tester as described in the test method. By noting the posi- tion of one of the two colors at one of the clamps and counting how many times the fibers of that color returned to the starting position between the two clamps, an approximation Of the yarn twist per ten inches of yarn was made. The formulas given above were used to determine the average twist per inch and the average twist per sample. For each of the following laboratory tests the car- pet samples were cut to the proper dimensions and then placed in a conditioning room of 70 degrees Fahrenheit 22 and 65 per cent Relative Humidity for a minimum of #8 hours until a state of moisture equilibrium was reached. The point of equilibrium was determined by weighing the specimen on the analytical balance until the reading for three weighings was constant to the nearest milligram. 3. Loop Length--It was found in the preliminary study that the method provided by ASTquor determing loop length was not adequate for this study. ASTM Desig- nation: Dlh86-57T, Standard Methods of Testing Tufted Pile Floor Coverings, suggests that twenty- five yarns be removed from ten inches of each car- pet, caution being taken to avoid stretching the yarn. One end of the yarn is to be held at the zero reading of a steel measuring tape graduated in centi- meters and the other end of the yarn drawn until the tension eliminates all the crimp produced by the tufting process. The length is to be recorded to the nearest 0.1 centimeter. The average of the twenty-five readings for each carpet is to be taken as the average length of yarn from a ten-inch speci— men of carpet material. In order to determine the length of a loop, the following formula was used: average length of yarn ends length of a carpet speCimen (10 inches) number of tufts per inch of carpet material This procedure was followed except for the method by which the reading was taken. The point at which 23 the yarn was held under enough tension to lose all its crimp was found to be too arbitrary. Since the yarn was highly bulked, it could be drawn within a range of several centimeters and still be con- sidered straight. It was decided that if the yarn was held at the zero point of the steel measuring tape in a vertical position and a weight attached to the other end of the yarn, the weight lowered slowly and carefully to avoid stretching, a fairly consistent reading could be made before the yarn stretched under the weight. Several sizes of weights were tested during the preliminary study and it was found that the 100 gram weight was heavy enough to straighten the yarn without applying undue tension. Smaller weights did not remove the crimp of the tufting process and larger weights put too much stress on the yarn and tended to stretch it before a reading could be made. Total Carpet Thickness—-The total thickness of five specimens five inches square taken from different areas of each carpet was measured. The measurement was made to the nearest 0.001 inch with the Schiefer Compressometer under a pressure of 0.025 pounds per square inch using a 3-inch circular presser foot. Care was taken to avoid touching the area of the specimen to be measured and to apply the pressure slowly in order to avoid impact. A reading was 2% taken after ten seconds. The average of the five readings was taken to determine the average total thickness of each carpet. Back Thickness--The surface yarns were clipped from five specimens five inches square taken from differ- ent areas of each carpet. Each specimen was then placed under a five-inch metal embroidery hoop and a flame from a bunsen burner was directed to the area inside the ring. The surface yarns remaining after clipping were alternately charred and brushed away without damaging the carpet backing. The thickness of the backing material was measured with the Schiefer Compressometer to the nearest 0.001 inch under a pressure of 0.025 pounds per square inch, using a 1-inch circular presser foot. Care was taken to avoid touching the area of the specimen to be tested and to apply the pressure slowly in order to avoid impact. A.reading was taken after ten seconds. The average of the five readings was taken to determine the average thickness of the back- ing material for each carpet. Net Pile Thickness--The thickness of the surface yarns was the difference between the total carpet thickness and the back thickness. Weight-—All weight determinations were made according to the ASTM Designation: D1H86-63, Standard Methods of Testing Tufted Pile Floor Coverings. Linear to 25 measurements were made to the nearest 0.1 centi- meter, using a steel measuring tape. Total Cgrpet Weight--Five specimens measuring ten inches square were cut from different areas of each carpet. Each carpet was weighed to the nearest 0.1 milligram. The average of the five weights recorded was taken as an average weight of a ten-inch square of carpet material for each carpet sample. Calcu- lations were made to transform this weight into the average weight of the total carpet per square yard. Pile Yarn Weight--The surface yarns were clipped from five specimens measuring ten inches square, cut from different areas of each carpet sample. The yarns were weighed on the analytical balance to the nearest 0.1 milligram. The average of the sum of the five weights recorded was taken as the average weight of the surface yarns. Calculations were made to convert this weight to the average weight of the surface yarns per square yard. Backing Weight--Five specimens measuring ten inches square were cut from different areas of each carpet. The surface yarns were removed by clipping and those fragments of yarn which remained were removed by charring and brushing the area within a metal ring without damaging the backing material. The backing material was weighed on the analytical balance to the nearest 0.1 milligram. The average of the sum 26 of these five weights recorded was taken as the average weight of the backing material. Dissection Loss--The difference between the average pile yarn weight and the average backing weight from the total carpet weight is the fiber loss during dissection. This weight was divided equally between the weights of the surface yarns and the backing material. The above procedures were followed for determining carpet weight; however, the results showed little uniformity. While the original carpet specimens were very similar in weight for each carpet sample, there was a wide difference in weight for the speci— mens of each carpet sample after the tufts were removed. This happened because the tufts could not be clipped evenly from the surface of the specimens and very dissimilar readings were obtained. 6. Tuft Density--Tuft Density was determined by counting the number of tufts in a 10—inch square of carpet material and dividing this number by 100 to find the number of tufts per square inch. 7. Abrasion Resistance--Abrasion resistance was deter- mined according to ASTM Designation: D1175-61T, Tentative Recommended Practices for Operating Machines for Testing Abrasion Resistance of Textile Fabrics, Section D, Rotary Platform, Double Head 27 Method. The instrument used was the Taber Abraser, Research Model E-hOlO using H-l8 calibrade wheels and the Taber Vacuum Pump, model E-HOO9. Five specimens of each carpet sample were cut into h-l/M inch circles, vacuumed lightly with the vacuum instrument of the Taber Abraser to remove any fibers or adhesive loosened by cutting the speci— mens from the carpets and conditioned for a minimum of #8 hours until standard conditions were reached. The specimens were given numbers from 1 to 15, with the specimens from the carpet with the lowest tuft height being 1-5, the specimens of middle tuft height being 6—10, and the specimens with the high- est tuft height being ll-l5. A table of random numbers was used to random order the specimens. Each sample was then weighed, run to 50, 100, 300, 500, 750, 1000, 1500, 2000, 3000 cycles and to the endpoint, with weighings being made at each of these stopping points. The endpoint was determined as that point at which the backing material was first visible. During the testing procedure the vacuum pump was started and the nozzle placed over the car- pet specimen before the abraser was turned on. Care was always taken that the abrasion wheels were lowered gently onto the surface of the specimen in order that fibers were not lost due to the initial impact. The loose fibers which collected on the “‘3 28 abrasion wheels were removed with a brush after 300, 500, 750, 1000, 1250, 1500, 1750, 2000, 2350, 2700, 3000 cycles and every 300 cycles to the end point. The ASTM test method suggests that the lint be brushed from the abrading wheels every 300 cycles throughout the testing procedure in order that the abrasiveness of the wheels not be decreased by lint clinging to the surface. The researcher decided that it would be likely that more fibers would be lost during the first rotation of the abrading wheels than during each individual cycle thereafter. Therefore, it seemed more advantageous to stop the abraser to clean the wheels at points closest to every 300 cycles, where reweighing was to be done. This prevented additional stops and starts and the possibility of unnecessary weight loss. Visual Appearance Changes-A subjective measurement was used to note the change in visual appearance of a specimen after various levels of cycles of abra- sion with the Taber Abraser. A comparison was made between the abraded carpet specimen and the original carpet sample for changes in tuft type (broken fila- ments), tuft height, yarn color and yarn texture. Record was made of visual changes when they first appeared and when they became intense. The measure was made under the fluorescent lighting of the con- ditioning room; no special lighting was used. CHAPTER V DISCUSSION OF TEST RESULTS Laboratory testing of any textile material is likely to reveal some inconsistencies due to the lack of uniform— ity in fiber, yarn and fabric production. An insufficient number of carpets was used in this study in order to make generalizations about the abrasion resistance of tufted polypropylene carpet yarns. The results of the laboratory tests suggest some differences in the abrasion resistance of carpets with varying tuft heights. The fiber content was verified as polypropylene through the burning test, microscopic examination, and solvents. It was noted during the burning test that the yarns shrank and fused as they were moved close to the flame of a bunsen burner, curling away from the flame. When the yarns were placed in the flame, they melted and burned, giving off a black smoke and a chemical odor and leaving a hard, black residue. The results are character- istic of synthetic fibers. Microscopic examination revealed the yarns to be synthetic. The longitudinal view appeared round and 29 3O smooth, with some delustering dots present. The cross- section of the fibers was round. The solvent used was boiling meta-Xylene, a solvent for polypropylene. The yarns from all specimens were completely dissolved. The yarn twist for the yarns of each carpet was found to be approximately 0.5 twists per inch. All yarns were twisted in the "S" or right-hand direction. The average length of yarn used to form a single loop was 1.3662 centimeters for the carpet of low tuft height, 1.7869 centimeters for the carpet of medium tuft height and 1.9785 centimeters for the carpet of high tuft height. The standard thickness of each carpet was measured with the Schiefer Compressometer to the nearest one— thousandth inch under 0.025 pounds of pressure per square inch with a three-inch presser foot. The tufts were removed and the thickness of the backing material was measured under similar conditions, except that a one-inch presser foot was used. The results of this test are found in Table l. The thickness of the carpet referred to as ”HIGH” gave a slightly lower thickness reading than the carpet having medium tuft height, when measured with the Schiefer Compressometer. Both visual observation and the loop length test revealed a greater length of yarn per loop for the carpet of high tuft height than for the carpets 31 of medium or low tuft heights. (See Appendix, Plates I and II.) The tufts of the carpet with high tuft height leaned to one side rather than standing upright as the tufts of the other two samples did. This leaning resulted in a lower reading with the Compressometer than was given for the carpet of medium tuft height. Table 1. Carpet thickness in one-thousandth inch units under 0.025 pounds of pressure as measured with the Schiefer Compressometer for three selected tufted polypropylene carpets. Tuft Height LOW Medium High Backing 151 152 1A3 Tufts 118 195 193 Total 269 3H7 336 The number of tufts per square inch, the tuft den- sity, is recorded in Table 2. Tuft density is known to have an important effect on abrasion resistance. (15, p.101) An attempt was made to hold the number of tufts per square inch as constant as possible. The abrasion resistance at selected cycle levels was determined by the weight loss in milligrams from the original weight. The weight loss for the three carpets at each selected abrasion cycle level was very similar until the 3000 cycle level was reached. (See Table 3.) At this point a significant difference, at the .05 level 32 of confidence, was found between the carpets of low and high tuft heights. The carpet with low tuft height had been abraded nearly to the endpoint when it had undergone 3000 cycles of abrasion, and consequently the tufts had become very short. Any fibers broken off from this car— pet somewhat before this point would be very short and weigh very little. The fibers being broken from the other two carpets as the 3000 cycle level of abrasion was approached were longer, since the tuft height was con- siderably higher and, therefore, weighed more than the fibers lost from the carpet of low tuft height. Table 2. Number of tufts per inch for three selected tufted polypropylene carpets. Tuft Height Low Medium High Length (t1) (Direction of Tufting) 7.7 7.1 6.5 Width ' 8.1 7.8 8.0 Tufts per Square Inch (t1 X t2) 62.37 55.38 52.00 The weight loss at the endpoint was found to be sig— nificantly different at the .005 confidence level. At 3000 cycles of abrasion, the carpet of low tuft height was only 258 cycles from the endpoint of 3258 cycles, so the difference in weight loss between these two levels of abrasion was slight. tinued to withstand more than 1200 additional cycles 33 beyond the 3000 cycle level. However, the other two carpets con- The type of wear was slightly different for the carpet with the longest tufts than it was for the other two carpets. The loops on this carpet slanted to one side so that rather than breaking off the part of the fibers on the top of a loop, the abrasion wheels broke the part of the fiber on the side of a loop. The wheels were rubbing along a larger area of a loop, thus resulting in a greater total weight loss for the car- pet with the longest loop length. Table 3. Average cumulative weight 1053 in milligrams for three selected tufted polypropylene carpets. Number of Cycles Tuft Height of Abrasion Low Medium High 50 8.1 3.1 7.4 100 13.8 15.1 15.9 300 A8.A 38.2 57.2 500 82.9 69.8 95.0 750 133.0 110.H 150.8 1000 176.2 153.2 202.9 1500 253.7 231.0 289.7 2000 307.2 320.7 386.1 3000 AA7.9 A8o.6 55AL8 Endpoint 486.6 656.3 77H.9 (3258-A2u8) 3H The number of cycles of the Taber Abraser required to expose the backing material was found to be signifi- cantly different at the .005 level for the carpets of low and medium tuft height, and the low and high tuft height. The loop lengths of the carpets of medium and high tuft heights were sufficiently longer than the loop length of the carpet of low tuft height to require approximately 30 per cent more abrasion cycles to wear these two carpets to the endpoint. The number of cycles required to reveal the primary backing on the carpets of medium and high tuft height was almost exactly the same. Since the loops of the carpet with highest tuft height were slanted, the abrasion wheels struck the loops along the side instead of wearing them down from the top. This caused the loops to lose fibers near the base of the loop, resulting in an earlier exposure of the backing material than would have occurred if the loops had been upright. Table 3 and Figure I show the weight loss at various cycles of abrasion. Table H gives the analysis of vari- ance tests which were done to determine whether or not there was a significant difference between weight losses for the three carpets at various intervals. Duncan's Range Test (7,p.136) was performed on data which gave significant results for the analysis of variance test, and was done to show which of the carpets were signifi- cantly different from one another at various cycles of 35 ..Medium Tuft Height ---Low Tuft Height ——-——High Tuft Height - N200 . 3000 L 2000 1500 I _ lOOO . 700 - 500 300 - 100 7000 6000 A 5000 _ 000 A 000 1 a- (h SWBJSIIIIW 2000 - 1000 - 600 A 200 Figure l.--Average cumulative weight loss in milligrams at selected cycles of abrasion for three polypropylene carpets. 36 Table 4. Analysis of variance at selected abrasion cycle levels for three tufted polypropylene carpets. Sums of Degrees of Squares of Source Squares Freedom Means F 100 Cycles Between 11.58 2 5.790 Within 204.34 12 17.028 Total 215.92 14 .340 1000 Cycles Between 6207.30 2 3103.649 Within 12942.71 12 1078.559 Total 19150.01 14 2.87 33000 Cycles Between 39844.93 2 19922.465 Within 55049.08 12 4587.423 Total 94894.01 14 4.3342* 88:28.. Cycles) Between 209941.11 2 104970.554 Within 52895.38 12 4407.948 Total 262836.48 14 23.81*** Number of Cycles to Endpoint Between 2855429.20 2 l4277l4.600 Within 1586711.20 12 132225.930 Total 4442140.40 14 10.797*** *Significant at .05. ***Significant at .005. 37 abrasion. The findings of Duncan's Range Test are reported in Table 5. Table 5. Duncan's Range Test of significance at selected abrasion cycle levels for three tufted polypro- pylene carpets. Weight Loss at 3000 Cycles l 2 3 Value Required 447.9 MG 480.6 MG 554.8 MG for Significance 1 42.7MG 106.9MG* 95.00 (.05) 2 74.2 90.79 (.05) Endpoint Weight Loss 1 2 3 Value Required 486.6 MG 656.3 MG 774.9 MG for Significance 1 169.7MG** 288.3*** 187.77( .001) 127.88(.001) 2 118.6* 91.23 (.05) Number of Cycles to Endpoint 1 2 3 3258 4235 4248 Value Required Cycles Cycles Cycles for Significance 1 977** 990** 731.13 (.01) 2 13 701.26 (.01) *Significant at .05. **Significant at .01. ***Significant at .001. CHAPTER VI CONCLUSIONS In this study abrasion resistance was found to be high for the selected tufted polypropylene carpets if determined according to weight loss and very low if deter- mined by visual observation. According to the classifica— tion used by Thruslow (18,p.93), a carpet is rated as having "excellent" abrasion resistance when the weight loss is 0-200 milligrams after 1000 cycles of abrasion on the Taber Abraser. Using this system, the selected poly- propylene carpets were found to be highly resistant to abrasion. However, the appearance change after a very few cycles of abrasion could be considered objectionable. After fifty cycles of abrasion for all specimens tested, wear had become apparent due to broken filaments, stiffening of the fiber ends, and a whiteness at the end of each broken filament caused by deterioration of the dyestuff (see Appendix, Plate III). The path followed by the abrasion wheels was noticeably depressed below the surface of the unabraded parts of the specimen after 500 cycles of abrasion and the loss of color was very 38 39 objectionable by the time 300 cycles of abrasion had been reached. The statistical analysis shows that the amount of abrasion required to wear the selected carpets to the backing material is significantly different for the car- pets with low and medium, and low and high tuft heights. The researcher believes that although the carpets with medium and high tuft heights were somewhat closer in loop length than the carpets with low and medium tuft heights, it is likely that the variation in height would have been sufficient to show a significant difference in abrasion resistance if the loops of the carpet with the longest tuft height had been standing upright throughout the testing rather than leaning to one side. Although no generalizations can be made concerning the abrasion resistance of tufted polypropylene carpets, the three tufted polypropylene carpets selected for this study must be considered as being low in abrasion resist- ance. The average weight loss ranged from 153.2 milli— grams to 202.9 milligrams at 1000 cycles of abrasion, which would classify the carpets used as having excellent resistance to abrasive action. (18,p.93) However, it also must be taken into consideration that polypropylene is the least dense of all fibers; therefore even though the weight loss seems small, the actual volume of fiber loss was rather large. The appearance of the carpets even after a few cycles of abrasion was changed, due 40 to the breaking of filaments and the brittleness of the fibers. The height of tufts was found to be important in determining the amount of abrasion required to expose the primary backing material. The additional 0.6 centimeter in the loop length of the carpet with medium tuft height over the carpet with low tuft height was sufficient to increase the abrasion resistance by approximately 30 per cent in this study. Since textile fabrics are generally used only as long as they retain their original appearance, the researcher feels that these particular tufted polypro- pylene carpets might have limitations in household use. Several suggestions can be made for future testing of the relationships between abrasion resistance and tuft height in tufted carpets of 100 per cent polypropylene surface yarns. First, more samples of additional tuft heights need to be used to help locate the point at which additional tuft height will make a significant dif— ference in abrasion resistance. Second, methods need to be improved for determining the weight of the pile and the backing material and for determining loop length. Third, the chance of multiplying any errors made in deter- mining the weight 1035 to abrasion would be eliminated if a new specimen were abraded to each of the levels of abra- sion selected for weighing, rather than weighing a specimen and continuing the abrading process until the next level of abrasion was reached. A new scale for measuring weight 41 loss due to abrasion needs to be devised, in which the density oftflxaparticular fiber content is taken into account. CHAPTER VII SUMMARY Three single level tufted carpets of 100 per cent polypropylene surface yarns, each having a different tuft height, were selected for this study. Other factors, including tuft density, tuft type (cut or loop), and yarn twist, were held as constant as possible. No attempt was made to control the price of the carpet or the manufac— turer of the fiber and/or carpet. The carpets selected were obtained from a manufacturer and local retail stores in Lansing, Michigan. The price of the carpets was within the medium range for polypropylene carpets; one sold for $5.95 per square yard and two for $6.95 per square yard. All laboratory testing was done under standard con- ditions using methods set forth in.A§TM. Preliminary testing was performed prior to the beginning of this study, using a fourth carpet to standardize all testing procedures. The tests performed included fiber verifica— tion, by burning, solvents and cross-sectional and longi- tudinal microscopic observation; yarn twist; total carpet weight, pile yarn weight and backing weight; loop length; tuft density; and abrasion resistance. The specimens 42 43 were abraded with the Taber Abraser for 50, 100, 300, 500, 750, 1,000, 1,500, 2,000, and 3,000 cycles and the number of cycles required to reveal the backing material. The weight loss was determined at each of these ten levels of abrasion. The weight loss was found to be significantly dif- ferent at the .05 level of confidence when an analysis of variance was performed on the data. A .005 level of con- fidence was found for the weight loss at the endpoint and for the number of cycles required to reach the endpoint. The Duncan's Range Test was applied to the data to deter— mine which carpets were significantly different from the others. Although the study was too limited in scope to draw any conclusions concerning the abrasion resistance of tufted carpets of 100 per cent polypropylene surface yarns, the three carpets selected for this study were considered low in abrasion resistance, using change in visual appear- ance as the criterion. Approximately 150 to 200 milligrams of weight were lost at 1000 cycles of abrasion. This is within the "excellent" weight loss range of a classifica- tion set up by Thruslow; however, it does not take into consideration the fact that polypropylene is the least dense of all fibers and consequently, the amount of fiber in 150-200 milligrams of polypropylene constitutes a fairly large volume. The visual appearance of the carpets changed markedly when the samples were subjected to very few cycles m. of abrasion. Even with fifty cycles of abrasion, the carpets showed broken and brittle filaments. By 100 cycles, enough dyestuff had deteriorated to cause the fiber ends to be white and the color change was very objectionable after 300 cycles of abrasion. At the 500 cycle level, the path of the calibrade abrasive wheels was worn below the surface of unabraded areas of each specimen. The difference between the loop length of the high and low carpets and the high and medium carpets used in this study was considered sufficient to reveal a signifi- cant difference between the abrasion resistance of these carpets. The high and medium tuft height carpets did not show a significant difference in resistance to abrasion. This is probably not only due to the fact that the car- pets of medium and high tuft heights were closer in loop length than those of medium and low tuft heights, but also to the fact that the loops of the carpet of high tuft height were leaning to one side and so received a somewhat different type of wear than those carpets with upstanding loops. LITERATURE CITED 100 ll. 12. LITERATURE CITED Architect/Designer's Guide to Carpets of Herculon. Wilmington, Delaware: Hercules Incorporated, 1966. ASTM Standards on Textile Materialp. Philadelphia: American Society for Testing Materials, 1965. Carpets and Rugs. North Canton, Ohio: The Hoover Company, 1966. 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