WEE ELECWEC MOMENZ'S Q? SQME SUBQTANCES
3 " THE VAPOR PHASE

Theszs {‘or flu: Degree a? M. 5.
MICBESM 8333?: UEEVERSE'E’Y
Lenore Ho
1957

{THESIS

 

LIBRARY

Michigan State
University

 

‘P‘."~T‘ -',"'f “C'P'VT-V ‘v'n‘hn. arm‘ fiv'n ‘ ~ f v >f‘ Irg:
0. 2 ‘ "'l .‘ ' ~‘ ,
.‘a-‘ 5.451.. 3 v :.--“.‘§L . '2‘ 3 . 1.. :J . ‘r 4 LI
0 7‘ ‘7
mvw ysiq: wus w
h. ' ‘. b» '.

 

iukmitted to
the fichool of Cr“3l?t@ itu%ies
o? Fichffi‘n 'hstn Sniva“sit¥

0? ’3ricu7ture find firWEiei ‘cience

 

Tn ?nrtial rulf‘illmant
o“ the Refiuirerenta fwr fihm 3exrea
Master of Science

7‘

. ‘wfl- :‘
Henrrtmant of Cummifitry

 

W
Lenore Ho

7x . .1 rr;
. 0‘47""! '3?“ 1)) /'.7

“quitted to
fittte 1nivnv ifiv n? fivrficultrra ~n1 iflvltvd “stem

‘1‘! W “”H" '| .W o "‘1" 3% - 1r . ‘f‘r‘u “tn. ,‘ t
l .
Ju . | J . 4 v . I a ..I 4 .. J A‘
a ‘ ; .
:‘u' ‘ 1: ‘ .3 “1““ ..‘
[in .4 t ‘ .L . .J

by

Lenore F”)

the "choral 0“ “radimtn "twigs: of Vichin'fz
n
V

in partiaj #119111m9nt 0’ the rawuiromonts

5*firavni

for the r’tvr'vee of‘

i‘.‘ “#3:? r‘m vf'! ~_-.!~-bf‘fl
’ '.' ‘. H .‘J .Ji’uxu

VQPPrtmflnt n?

..‘r 9:4 8131‘?!

YAfir 1957

.,» ~v m1 V"! - ~~ rvn - g 711 w Mn" -H
J y -, 12,1. 3; J .‘ H‘ 1 4‘14 5 '11.: ,3
v .7 gr. '- u I s'
' -. § ,.
I i It “4 'AJ

AH i?a?i‘£T

The electflc ninmnts :33“ Mar cmvnuxfls of Maryann, ni-
tmgwn my! rhmsp‘rwmn hr‘va *nm "‘erfiurod 1n the Vfififir 53712139.
The: ":12" stmcar satay-Had, mi the elacffic mam-mtg Pound in
this finve:fi*gst£an, are: isopvofiyl etFnr 1.1?3, tert-huty-
Urine 1.957), tflfiufironcnfic Pnhyifl-fe 1.433, mr‘. mow-hams:
trichoflfle 0.9973. ".an isn'pmnyl char hm“! team fitJCHEd
1n the wmor 32:41:43 r'revimmly snfi the wine reparted 1*")?
Le ‘F‘evm, 1.13”, 19 in w-‘C‘enent firmwarm with the value:
revnvtnfl Pare.

fitn elfictr‘ic "own-mt 6:“ rinsrhtmm tric?’.?oflr?e faunii
in ’39“? 9'0”}? 1’3 *hfl vnpor "t“‘ié’é Pu“? 1"“ CONVE‘TQ"! with {I}???
vn 1mm 9." 0.“)? (51;) my! 0.00"? (“3) W'mrts’fi 1n 1‘?“ liters?-

tzzre "or r?vnr—-sv-hor=m tricf’nor'lrie r‘i 13.?!)11’973 in (:3 flnn tetra-

: v‘

ddmr‘ #39 {mi *wvai-am rnsannctiveljr. Vince 9: at} Glanctric

»
romnté n“ 9*th t:.1?~wrv*..rtncas 9m 0.1-3.2": 1.0332“ in soliti'm
thnn 1n H10. ,3”; :3?"er {ink 10? ”vim." w“ r“ fiEBF'TIMWI‘Ll") trin}'~.1.3i~'1~e
19 norm}. téwt-“Iz’s‘r~.'1?r~.zine, ?.~o*-~evnr, F53 .n Irv-nu? wrwimt in
the «when? p??? 3:5 {Evan tho vrv‘us? 7.3“?) (LL) “mm“: in ‘c-cewmm
mlufitm. 7cm ‘FRGT‘F7OA” *9? W1 9?“ 110.9 VQM‘: mtxrwv‘tm! 11': sh:

“tartar-Kc? "at" Minor nrxfnés; thuri, tY‘Q eff.’zj'1!"'=fiw3 ‘rgr-as 3* r~1-v'*'v=.“.t

0' 0.11" in ”3‘” ‘-"‘““-‘:"‘7‘ 93‘3“? “’1‘3 0.07) "’ in I'ansmm 5?: 7321*}.

s)

Tm electric momnt of“ trif‘luorcrce'dc mahyddfic in
that vapor ctr-ate W98 ”aunt? in this «0:4: , ‘53 P3 MUG?‘ lower
than that remrted in tha Htcrsmre ”0r manic r-nhy:3r1 "1e
( N 79.83). The wnmnt onlcukted "cr tfif‘luorcrcetic
”Cir! f‘mn .‘nnr! mmntzz 1:; 1.1;?)- nmaxzcinrt ?;1'.'”’.7't fine Fag—:1”
”3-9-0 is 110° .1"an the r'mflxv 0-3:?) is; 1 “5" in tin? Eratéjeriflr‘c.
"drama the pyjmmant ‘rr-‘t‘cracn ammo-e anti MlcrviT’tnv? mmnta
1:! «0 mo"! tha Bout”? Isms-‘10.?» in M1 Pl'r'mmncetic r'n}73v?ri-etse 9m

‘.

wohr¥1y not “fir ”mm firm V531 1m 3: W‘Tf’»kl!‘.'h'~.‘d fibre.

The autkcr wishes to express her sincere nnfirecin-
m

tion to “rc’ecscr ". f. chera for his guificnce and 28353-

tflnce thrfiughngt the cource of th‘s work.

“nu *“s'f ‘.' A." w‘ :w «~-
.. ' ’. ~ v .4 ' « 5‘
. “.¢..l ' 3. LI . .‘2 3 _v4-.‘ L

cr'a vwa~~fi
‘JLL.I' I I‘;J"u

I I‘M“. ~g'---rr~T-‘-*v
'. .'l . , '
o -u~~-"JA~'&-=-e‘ o o o o a o c o a c o o o o 0

T1- ‘5 {Mn n ficr'x‘f ‘. .I H 1 ‘I' "'9'. "3 '
, 3,? . v- ‘3,,

A. ,Lr‘.LQ.) -."-:'UJ I‘.-4$l-‘ .'

Rev1ew o? Vethcds . . . . . . . . . . .
Hoterodyneaneat Prvfiratus . . . . . . .
General flefiign . . . . . . . . . . . .
fenstbivity and accuracy . . . . . . .
Precision Condenser . . . . . . . . .
CaliFrntion of Frflciaion Condencer . .
Dieicctric Constant Cell . . . . . . .

G35-39ni]1n: cyStflm o o o o o I 0 0 ‘

Tamnernturfi¢86nfirfllled tath o o o o 0

fl

‘7‘ .' "V7277." Tf“? ’_ V"-"“" '1 ft‘.“
.. {FE‘J 2.»..JFMU H, '.’6\ j?" .1....‘

Ta‘ra Eijcugti’DU o o o o o o o I o 0 O O I
The Calcu12t*nn 0' Elcczric Famnnts . .

A. First Fathwd for the Hefisuremcnt
0’ Pirole chcnt . . . . . . . .

’fi

. ¢aonnd Yethcd far the Razsurement

of “1:019 Tomfinfi . . . . o o o . .

IV. WAVES” 0? LITERATURE . . . . . . . . . . .
Isomrole $thcr . . . . . . . . . . . .
tart-Putylnmine . . . . . . . . . . . .

'T'fifbmroacetic 5%«nbyf":di~e o o o o o o o

FherrnregAIntor find Temperature Fen”ure-

"fiat-0000000000000...

{I}

a) he 14

*‘J '0

'VJ

\Ommm

\5)

1h

15
17
17
10
19

Lb

'U’ "I
T r
14‘ i

7'.

fhocnhorus

"_~ ‘r v‘: a H ’g 3'
>4 , ' - " ‘5'
u. n

i 1.1;“..‘é" .' 1“ '

hill-- 4" a

"1 ‘$‘ t'.“ P a '«‘l’ f‘\ v p
‘ i I , .‘ q . 3i
ia‘ .r A - -.r , x! a; 1v...’ i

E'flch10r1de o o c

'f, O?!

) ! fiz‘ :?€ 42 I 3 ,. 3

O O O O
O

tart-?utv1_enin a

PI

Tm fluorwcetic Anhyfidde '

FKOSphnrug

Isocrcnyl V

1 "f”. '1‘. FY

’ I J

.,02i‘ "‘..
.9“ {1

...¢

‘ 5’
3‘4
A -1 Al

Trichicrtde

ther .

O O
O O O
C O 0
O O 0

K)
J

RAJ
":..

\.L,"
‘L"

w
p

\d 3
‘J'!

T!?§

V

VI.
VII.

VIII.

II.

V ‘ . 7‘47 ‘zvs

I. 1.1.1.)

“I
“:3

11;?

C)

u

Uirola Fomwnt cf Fymmetric91 Tthers . o o

Dinole ancnt a? Unsynmetricpl Ethars . .
Comparison of folnr4zyt19n Data for fimines
In Fencene and Ctoxan Fnlutfon . . . .

?atn for the Califrntion of'the Gan.rc1
Radio *reciaton Concencor . . . . . . .
Dielectric Cnnn‘mnts of" finwnnia 1'3er at.
€evar31 Temperatures . . . . . . . o .
Calibration Dptaifor Eielectrfic Cell . .
Calculation or ReplaceQVIe finnecitnncc of
Cell . . . . . . . . . . . . . . . . .
Dielectric Cnnfitant Tats for ~'Isom‘ooyl
Ether . . . . . . . . . . . . . . . .
?1electric Constant fist? for tern-
@utylamina . . . . . . . . . . . . . .
Dielectric Cnnctsnt Data for TP1F1QOPD?CQ-
fiic finhyflride . . . . . . . . . . . .
nielcctric Ccnstant Tata for ?hocnhorus
Trichloridc . . . . . . . . . . . . .
Hihole ?nment CnIculatinna by'the Hefrac-
9thr . . . .

ti vity T-‘Iethnd I sopropyl

fivernga Dincle fioments In *nror Phage . .

'43:,

1:9.
1:2

1?

l“ 1

P3

".
t.

a)

\J‘!

?9

33

«- .‘vi’l‘f: :
F1, ‘ ’A.’ -I C:

I.

II.

III.

IV.

V.

VI.

LI '3 ""9 '1'.“'(‘."°CH.L-""
JL .1: . .L\7-J.'.-r--3

Flock Diagram Illustrnting the Principle
of fihe Hetaroéync~?eat Apnaratus . . . .
Frimary Standnrd Cfipacitorfi Used:for C811-
brating General Eafiio Precision Con-
denser . . . . . . . . . . . . . . . . .
DieIectric Constnnt Cell for Non-corro-
sive Gases . . . . . . . . . . . . . . .
Gas Handling System for Non-corrosive
Gases (Vacuum Line) . . . . . . . . . .
Tynicel Plot 0' Cell Calikration Bats;
Cnlibration of Cell at ?3.75°C . . . . .
Tyntcal Plot of Siolectrfic Canstnnt Rnta -
Calculation of IsoprouyL Ether at

23.7508 O O O O C O O C O O O O O O 0 '0

ps n“

:2 «.111:

10

27

"flue electric moment. 0" c mclcmla is 0“ immrtmcc
1n daterminfnq datfii1a of its eicntrnnic ntructxrc cc” fit?-
mic nvr“nfiemcnt. TEE ohsarvcfi electric mcmcnt may Fe C) fared
with n valuc calcwflrtcd f’mm Fan-awn hand mar-«crate; ma? Fons:
pnglea. Eiffercnccc hetwqcn the obsc?vcfl and cplcu7rtcd
electric mcmnts are then 11131 cMive cf“ mamas-”nee m" i.rs=~i'...zc-
t1 we ef‘fiacts or, in acme ran-ma, alto-mi hand cmilcc.

In the bras-mt invavtflr-mhn the m nctric mar-wants; o?
9 from‘ 0‘.“ cc mounds of rhfisrfizfirus, nit. 1'“;th rn‘i omflccn have
been dc‘amincd to o’tain inf‘ormrtion mnccming thaw

electrcnic ctrjcturws. 7%?“9 m51wc41~3 911 rre charuc.nri?cd

r

by the crecencc nP unchrrcd ncirs o? e7fictrnns on the cuntrfil

Ptom; cue}: malec.;7-»'=~.:? fimcunntly 33h ow zwncmclnu‘: c‘Icctric 2m-

filthnugjh :55 hnlc consents 23m 1419,1311}; rmrmwcd in 9‘11"}?31‘551
such 1m} am we nl'.~'*‘ys .«gubfcct ta saws: uncertain v as 5‘. rt:-
salt 0“ solvent cP’ec‘m. To cvréii rush m'Lfirwx-‘inti {M the
eiectdc mammts .0“ the cnmnczmils gamma ham ware rnr+.r::3uz‘r:*d

1n the Vf-‘rtnr {$331,243.

fl f‘tfififl'fi-1 9‘! 1| r‘fr- «'v‘f‘
’-- ‘- .5 LLI J. .,‘

T ‘ "1'" “ $ ‘! ‘1‘

J 0 ’V ‘; .4

In awnorfil mnncurcrnntc a? Jiclcctric conctfinc cre
knead on mcnrurinm thc crnncitonce Co of an empty candanser
and aha cpvacitfince C of fihc candcnacr when “iiled with the
die1octr£c rctcriml in cuertinn.

There arc three crincinnl methnds 0‘ men uring the
31919ctr1c Canstant: the crrflcitcnce-¥ridfic methnd (1-11},
the recannncc methcd (IO-1?), nnfi the heteroéyne rcthcd
(1?-?3), which was emhloyed in this investiration.

Other methods are also ured “or measurement or @1-
clectric constcnt. The micrawnvc metFGd (9L-77} which dfinends

on mercurina tho wave-1angth c? cicctromngnetic wsves in rir

and than in the dieVGCtvic *Etcrial, has Eeccfie vcry t~vortmnt.
IT. Eff:2?‘:~. iv}? ”RAJ

’cnnrnl Facing (7P). Th9 bloc% diaqrn* of the hctcrcdynn-

 

“eat cfircrctuc in rcnraéantcd 1n Vigare . Two occ111stcrs,
one rived snfi the other vcrizklc, Rave keen used t3 gflve two
d1”fcrent r9fl1n-?recucncv “ifinalc f0 Fnfi ? retract*vc1y.

Th““3 twfi rrfifluanicfi 9T0 mixc4 in thc fr cucncy mitpr tube:

than nroduce 8 Feet note of 9recucncv f - f which is than
'3

3
campfirnd with a 9t“nd¢rd L50 cvciw €roouvncy on the oscilla-

score' “y otserving the 118”jous f1; 2re.f ca'n to dnrined ns

_.= l
’c m)

 

where I 1° inéuctnnce, v is crnacitance.

If f is aremtpr than f0, than an increnze a" tottl
capac*trnce W111 cnunterhalnnce the frvqaencv of the teat
note , until f is enun! to fO (Vent frequency 12 eaunl to
yarn). fi Cfi‘st“ -t Frequency :nurca 0? LCD cycles was used
93 ra’orence in"tenfi 0’ the fiero heat, becnuae the 9:01113-
+ors tnni tn 10c“ in near zero Pent. Tho canntnflz ~‘rnnuency
*fiurce wrs campfirej with tha test Fretunncy on n orthode—
rfiv oscilloacore, tr okservin; the Lixnfioué ‘ixarn, until a
circle vrs attained.

”en:it*v{tv gnfi ficcurrqy. The ¢3M111.tor inrtbttlity
detervinaw tut nv- r—~?1 tearitivit? or the swrllefit regsurfible
csrmcitnnce chanre. The fived series candenter W“3 chnen
so thrt 9 chvnéa 0? CL]; C'v ole pwr :ficard C‘s b“ fletoctwd
on the orcilloficnfia. Thn cnnacitmnce crn +9 Fe9iurfid to
the orfier 0P0 ‘ I01 w‘crnW1nvn”*"*d. This netted hss been

used by Chipn (19).

 

 

Eixed
frequency
oscillator

 

 

 

 

Frequency
mixer

 

 

 

[i-—i%|,JOScillosocop

 

 

 

K

 

 

 

MOO cycle
standard
frequency

 

 

 

 

 

Lt will

 

Variable
frequency
oscillator

 

 

Figure 1. Block Diagram Illustrating The Principle

of The Hetenflyne-beat Apparatus

e

5
Pzefijgjog anflenaor, A General Radio precision con~
denser, type 7??, nith a. capacitance range of‘ 110.0 micromicro-
fords was used as tho standard conflensor. fnothor condenser
C7 was placad in aeries with the precision condenser to de-
crease the er'octive capacitance (see Figure I).

The total capacitance can be written as,

 

C I‘.
Ca O h?

where C3 is the atrnderi condenser. finothar condenser Q9(a.Gene-
ral iRadio tyre 390-H mica decade condenser) Wfis DIECQd in
virallol with the standard condenser to make the not conn-
cggance mora nearly linear with the roofing on the a andard

condenser. ?%arernrc the total capacitance would be,

[.2
.7

 

c : ~
(CS 5 C9 o L”)

Then differentiating with reopact to C3 gives,

 

c2
ac -.
I575 -‘T"-‘59’c75!

.8 U
rs5.1169 Cg in much larger than C8 the change of total
capacitance will ta more linear than be”ore.
Eflérr“tion g: Precision Condanaor. The onlitration
was made ponnible ty using a primary standard capacitance
(tee Firure TI) wtich consisted of a cylinier and 2 center rod,

the apposite ends or the rod had di”forent diameters. ”hen

6

fhe inner rod was waved alnn§ 1%, ”$15, a emcll incrercnt
1n cnPtcitr-n"?e was: o‘taigae d. ”The csr rm“ rod 9an 13316» drum
wan r4}_nd wit : 1&00 units rcr incr. Tfierc were 1.5”00
"’C”GM*cr~PGr~4q ccfificiffiwce chrnva p9? inch, that means
0.30V057 ricromicro’nrnda per drum unit. The center rortfon
o” the rcrle wns uced far thc cali‘rafion, a use it was the
most linear part or the rcnla. ?hia rrimnry capacitcnce
was ruin rv J. L. Ynefirs (3(1) z‘nd fie ixned by Conner (31).
The rrcctsion condencer was cnIVVracmd with Co set at 2 micro-
rnrgdg, which setting r29 used for 511 the dielectric con-
strnt meflrurewentg thrauqhout the entirc inventigrtion.
From a clot cf strndnrd condanrer readings vcrcuz capacitrnce
reading on primcry condenser, the ccpncitrnca change on intro-
ducing the gss into the cell wag ortained.

Eiglcccric.gpnstrn§ Call. ?he fiielectric constrnt
cell (see Pi cure TIT) can oan hrn‘le "r393 with low boiling
points * wh4ch are nan corrn.r ive to VI 33 or nickel. It
consisted o” a series or nickel-nlfitad corrcr cylinfiers
which ware inruVetcd by sm*VV Teflon Spacers. fine sefi of
cylinfiers were grounfied, the other W38, *t high rntnnticl.
There were tunzcten lead: necled thr ouch the class which
ware than ccnnncteV tn the hctarodyne-kect vnnarntus (37),
The renVncea‘Vc cnpnafi t nee of’thc call is nrnut 350 micro-

microfnrads. It war ncce:Sfirv to enlihvate tr? cell for

l l 1*;_J

1 2 .3 l; 5
Imfies

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

 

Figure II. Primary Standard Capacitor‘flSed fOr Calibrating
General Radio Precision Condenser.

A Coaxial c linders D Graduated drum
B Threaded .locks E Mycalex insulators
C Center rod F Grounded base and case

 

 

17//I

 

 

Y/ZT

 

 

l/I

 

 

 

 

 

 

 

 

 

 

Kl/lj
N

 

 

 

 

Inches

\

Figure III. Dielectric Gonstant
Cell for Non-corrosive
Gases.

A Themocouple well

B Connection to vacuum line

C Leads to heterodyne-beat

apparatus
D Nickel-plated copper cylinder
E Teflon insulators

each tannerature, since it was Found to chance slightly
with temperature. fimronin1 was used to calihrete the cell
at each temperature.

fias-Kenilinq "yctem. rue “193? vacuum cyctem is
shown in Figure If. The trap leading to the camp is cooled
with T"r3; Ice-Tsonropenol mixture to prevent gases entering
the numn. Another tren,wtich could he removed,was uted to
introduce gaeeS. fi Percury menomcter was used to measure
the orcecure o" the gasee under investiretion and also that
of the res need For calitretion. The syctom could he eve-
ousted.

.Iemperature-antrolled ”9th. The heating eyetem,
thermocouple and the cell were all irmersed in a copper can
which was Filled with firochlor lfihflz (chlorinated hinhenyl).
The hath was used from room temperrture to around 75°C.
“ince the vrporfl o? firochlor 19h” are toric an air hlover
was used to pull the vapors into the hood.

14.. u! "34"
ceasirement (.n .

Thermgregulator and Earnercture
5 thermistor3 (temperature-seneirive elevent) was used in a
Yheststone triage circuit. In order to central the current,

the heater was in series with e saturahle reactor. The

 

1"er the latheson 00., Inc., 32. Rutherford, 17“!”

??rom Knnesnto Chemical Comrcny, Wt. Louis, No.

3A type 1L” thermistor, manufactured Ev the T"c—z-‘srtern

Electric Company, New York, V.Y. was used.

 

 

 

 

 

 

 

 

 

4.0 38?.
15%

 

 

 

h\

e\

Emcee H<. ova»... mwsowusm mwmdoa won zosooawomwem ommmm A <wocca H953

>.w modem on damvm Sumo woe 3.33:.qu was mdogzm mwmmm 633m Sommcwmo
o owwmm oowo numvm mow vase vaoandHos
U er Homuumovnovmdow apxdcum owns
m... .5523an wow vwmmmcum Sommcwmngd
Q 8.9mm émocca Wdovooowm

 

 

 

 

ll

temperature cecal-d he con-trialled tot-{3.05%. The thermo-

reguletor was designed by nurwell, Peterson rnd Eathmenn
(33).

Tempernture meenurements were made using copper-
constentan (Ho. 92 rire) thnrnocounlesl and a precision

retentiowcter.2

f‘Ine thermocouple was immersed in the hath,
end another was rlrced in;n en ice-water mixture at a re-
ference. Cince the temperature within the cell mes slow
to rerch equilibrium, it use necessnry to wait overunizht
for temperature equilibrium. The rardinga free the poten-

tiometer were Converted to degrees Centigrade hy making a

large plot of milli"olte versus degrees (3h).

 

1The thernocnunle wires were nurchased from the ”healco
Instruments Company, Chicnco, Illinois.

'3
“A tvne K potentiometer 0? leads and Northrup Company,
Philadelphia was used.

'fivil .N-“5‘,T‘,"n? ‘f’fi‘urnfl‘WOQOO
w; .1 4M.LU .1; 1.: ~.1['f-L.‘.;auD

“9‘33 Tfiuggicg (112!"Lfi35¢minr the molecule to be 9

r4fiid syrtem o“ chardms, 22hq hotentinl ene*5y J4 0’ the

nolficule in viven F" tHe ”oliowing onustion,

where m 1: ita electric moment filong the field direction find F
is t*9 intnn‘itv of the “191d.
Fines the axis will orriinrrily mnke nn finéfjle 9 wit.

the direction 0’ P,

44:3—WFC089 (TI)

where/A4 i“ tha anolute vniqe o? the electric mamflnt. The
num¥er o? rnlequea difitr1Vuted w4th the ayes of their dinoles
“ointing in the direction Within fi $0115 finale d.fl.1s,

AIM") cu».

whara & 13 a canatnnt deranflin: on the molecules cnn914erfid,

_ . , «g 16 3 m
k 1” the waleCuTfir gas const»nt emu 1 t0 1.W‘XIU'”.}QDQ 1
the rhsalute tefinerrtu a. The fiver"ne mamant per molecule in

the Tirection 0' the "field 1‘,

   

F“ 61:9
4!,“ MT) 0 fcosaoUl.

1,449": hTJCose JJL (TIT)

 

)7]:

”flee .M = —/UF c059 (H)

13

F
“111‘ stitut‘! m: X =5 %-? (T?)
Md A, = 9-10 ('7)

since (LR. =21rp1w049 (’7?)

4'- ? hr:
1.9 ;flln-T’ t,

 

Intnqrntinq n:1:-~9mtor anti denominator Fri-'1‘ 3‘1sz11"}:1.:2, 'r-ze set,

:73 1 -¥ '
,u — {1 - ‘3': ' 3 (WI)
1! .2."
fines J4— : CMX (T25)

x-L,‘

--

.2.
“5-55“ j¢..)l‘_=-.Lcu) (ii)

For 3991.1 v.1"! 11%? o'x, H30 Cfm he saturt-"n**7‘f.i in the
geriea {35-35).

3 —.
LCX)=-;--'£-+ """" (I)

"in-€91 1'? var}: :5'1'11 .-.9 cm X“?"1"Ce Hz) ‘rzy the first.
term of the 9eries,
X 1.
LC!) 2. '5' ( T.T)
Wit‘u t)?" r9317: thf‘t,’

l .-
.2— 5 (gm)
31W 1

This mean moment FIUfi the influcad figment, which has teen
tornorartly flirrpgnrded, 99y F9 vificfl ta give the totfil mean

mmnt in the rfirz-“ction of the Hrs-1:3 whiCh is,

.. __ ,u’ = " t~:.'-.-'
m-4.F+;;§, («Hg—T» (I)

‘0

,‘w

lb

2—
If we 19:13:49 4.999 :Eisatnr‘tion 9919919951911 99:?! F
‘T

the orientrtion 901991299£9n €999 t 9 to: 1 991991999109 15,

Z.
A = do + 3 T (:0)

the more g999r91 expreseion

2394:1119.ng )

15 0Tt91n9d “99r9 h 15 $99 tqtnl pnlnrizatififl.

 

The “919919919n n? 31999919 :,montg (11)

m

9. F£r9t 99tE9fl ”or the menrurement 9f dinola mo-

 

mnnt.
The 99199 99199199ti9n F 59
__ 47M! A:
P — 3 (4° T BQT) (n37)

r 999 9190 99 991091999d frow 9999urexent of 999 flielectric can-

Sit-99f, €- rn9 the» den-951:3; ? 9.9 {9119141992

 

6-:
P = (“2:71)

m
+.
N
hulk

F 99y 99 found Pt fitffarnnt t999999t9999 9nd 919999d
as 9 function 0? 999 99919919 1/?. There 999 t 99999 of
Pehnvfior. ”ir9t, the melocnle 19 9994991 9 999 its 919ct91c
moment/kl is zero. 9W99d, ? 19 denwnfi cent on t999999“ 999
when the 99199219 19 99199. L9t the curve 99 9999999nt99 by
the f999119,

P = a + 5/1 (‘4‘???)

vhers 9 and 9 999 C9n9t9nts, then

-..-..—.. {£12 N z m
b 7 T/l (9..)

.15
"here a: - 9.091 10”

9A

rand 4‘ : 1.37X 1-0" 99.9

J" = 0.0128’fl-X/O-‘84.$.u. (W)

9. Hec9nd Yethed F99 th9 meqwuramfint of d1?°19
9099nt. (31)
L9t H9 C9n91999 t?9 *un’9999t91 9999119 ”99 “ha 99199
polarization
a
p z?” (cu-rfi-T) ("in
The 9991: (5%“)Ndo wh‘ch we c911 P0 1.9 infienmdent of

'-

r3 " {‘31 9313/ 0'20 t"*f‘.‘0~‘7?}"?"t.‘.13‘9

54

t9~99999999. I? we 999 9995-

and 09:91n Po by 999th99 m9fihod, th9n

1.11 N ‘ ._ ..
.3 “if? "P P° (~;:-—;:)

'3
“9999 II a 6.961(10'3 and ’k a 1.'s7x 1345

fl = 0.0/2.8! xzo"8,J(p.P.)r 3.3.4:. (3;;

T? we 371““: 38911313: 39"."??? 3971952 fin”) vr‘ennr: only.

'4
s4
v

z
f<.=:11 -'I A4
91-92
19 9 suitnble 99999x199t19n to ’9' ?909 the 999999 of the

(99:77)

rnfr'cfiiv9 index n me 999 ”in4 n V9199 F99 3,9hich 13 tF9
90199 99'999t199. There"or9 99 C99 091931999 999 efectric

mnmont‘/u 95 "”110wg:

 

-12 .k __
fl = 0.0128! x IO 4/(PM—R)T.e.1u,( TV)

99999 9 C911 9 999 99991 991 r 9919r§99fiicn 991 0'9 99

0| 19

99991999 ”999 999 Po“owin: 99999993999:

find

( "J )

(mm

16

WI'I "} V'A'l" y
"g- «i a.) 'a I‘

KCTTBP 3? LITERATURE

 

Isourogzl? Faker. The flirole maments of eight ethers

wara *nfiSand 1n refi?9nc rclutinn (37). Th9 mfllfir rfifrsction

9'“.

J

The dinnle mwmnnts/fil cn1cu?9ted by tha wethod or Nadeatrand

was chcu1"t¢d 1n afich nae ¢rnm the atfimic rfirrnctiong, (39)

(19) firn fi€van 1n Tabla I-in ?e¥ve unitfi. Thn mannt of
1.?“? ”or diethyl ether in kentena is in rand agreewent

WitL the vvlue 0' 1.??? given ky Hagsel anfl Uhl (AG). ?he
values a? 1.?5 and 3.2?3 0*tsinfid for di-n-kutyl other and
ethyl n-Lutyl 1n Fenzene raanctivelv, are ta fa ccflrzrad
with the vshzes. 1.92 and 1,771+?) c‘tm‘VnQd by Li an”? 3‘0??? (bl).
Craves and Jux49n (£2) rive the value 1.133 fbr the marents
or fihe normal eymmefirtChl ethyl, nroryl nnfl kutyl afihers in
the vahor fitfi a. It is interesting tw note thrt the *verrge
of the Ffififint n” the symmatri¢31 etkors (1.?9) 1% 1nrxcr than
that o” the unsywmefir§cr1 ethera (1.?79). Cymwetrv in ethere
m1Wht h? 0*p?ctfid to st¢biliwe hypersonflu?nt1 n structures.

The dflpnle mnmfinfis o? Hahn fiYfl905P1C91 rnfi unévmfétr{051 etherg

“T9 855W“ in Trr793 I gng 7:.

19

'hA'r- Y
L AJL‘ J.

Uinwle Vaments o? Vym*etr1cn1 Ethers (#3)

Ether: n i ”
M930 EtIO F10 Pr; 0 all}
1“ C5145 1.?59 1.94:} 1,127", 1.9-4.2": 14“,?)

 

(1" F7”) 9°16. 1.7%,? 1.?‘33z‘.153 1.372132. 1.?3" 1.1“n;1.:~m
"7* 1.1“” 1.17:1“: “.17“

(/umr) fauna 1.?0": 1,1:

 

‘11; my: I.-

1

3!?019 fomnnts or Uncvmfietr10”1 ithars (37)
(in Pan~ene ‘a?uttnn)

 

ut- ntnnce 3 fl "able

Mr) thyl-n- arr-3 {W} 9th 9r ‘1, 7’1;

H
O

H
11‘

Efiw'! n-hromfl e h)": at“

thhyl n~?utv1 etker 1.25
Ekth n-‘utvl athar 1, 2

J~Prnwy1 n~‘utv1 afifier 1.17

 

I t 11. ‘4‘... ill?

.l.llll

19

tavt-pufiv1fimina. Twn rutylflminna wor9 stidiad 1n

 

d1DM! n9 sc1ution (L9) tn 9scartrin 9999999 the molecalflr
inter9ction invOIV99 the Parmfltinn o” hv4r999n 90993 %etwnen
the nmino-hyfirmg9n atwms 994 one o" the oxygen atoms of the
919x999 9919CJ19. n-Butvlamfine nnd t9rt-hutylnmine h9ve
ru"P*cient1v low V019t111ty to nermit easy and accur9t9 mani-
ru1rt19n, find rnprnvent connoungs with the 9mino-9rou9 linked
to 9 9r4mary 999 tertifirv cnrbon atom r9999C“iV91y. The 531.
lowing are the dipole moment messwrem9nt9 in 9999999 99d

din!“nt

'n l 2"-

~4
‘

v
I
'

00999r1999 of 191 r199tion “ntn Var 591998 n
179311179219 Anti 1:133“?! 701311110?! (Ah)

 

n.-.n .m- m r” —-

 

9 9 9
P290 126K: ’/4(9) /U1u)
":99“999 :9999 9999999 “199999

 

n-Bltylr‘i mm. T18 £1.13 {10.11:} 1.3??- 0/«5

tart-ButVI9mine €1.13 (1.?9 1.322 1.322

 

It cannot he inrerr9d canclucivo1y from t9959 r9991t9 t99t

no hy9r09en bonding occur: 19twe9n $99 bu+"1“r~v99 nnfl 9199999,
hut this 9pp99r1 {mhrnb9919, 99 even in the 9199999 of m99o-
reric e’racts the snnnrent 919919 moment shou1i ch9n:je (LS }.

Tr{"199“n~9nt*9 99“v19‘99. ?%9 di919ctric Ownstrnt

 

a? tr1f1uor99C9t‘c 9nhyfiri99 999 measured (Lfi-u7). ?he

17911193 n1~t9'?n9d ( 6

than th9t ¢or trifluor09cettc

fl’n1ectr4 c can"t 9nt
is 91m€19r1y fimal?

mid ( E : 6.3 at

er tLOn the

‘5!”
.)

2.7 9t ?5“C
PCT-i (6 3 F’.7 fit. T5TC). T?‘s€3

GP 909919

O

(1

\
I o

“9?? 93“rnzim9t9 6910;}

{3191999110 60:19:99 I; o.”

is c99319er9b1y lower

rn hyArida ( é a 2.1 at

‘J

\h
C}
v

m
0
f.
(f
,\. I.
O

“tifinfi ERV@ 91:0 indic9ted

that 9&9 19*uCEiva 9F”ent CF 099 5-? dipole shoulfi lower

n

the n099nt 9' 9 99cwnd Cur 953019 9939chnd to the 9999 err-

kan 9:9: *v 99333 0.

?? (LR) t¥138 one 0.31 919919 9%9913

‘1’?

10“: er the ”“0. ln‘- or nrlczt‘TT'flr a“ (‘1 (11"!) .137? hr; {‘1‘"' ‘1‘; q.?§\X 1.53- . .. .

V9099hovu9

Prich19rifie.

The 9019? 901M.r '9t‘993 Of

9513 and fiFrB were 9999ur9d in 053 4 ~94 C"1h 9331 gtjnn (L9)

The ofiv9rv9! v91u99 in cc..9rez 7313 in Cnfin L”.2 (183).

hé. 9 (95° ) L5.9 (L93); 93131

(?S°): FTrg in Cfifig,

P9r3 in cc1h, L7.L

[43.2 (1:131
('?50) , 14.".

.r

n"3lh, 1&3. 8 (“733), 3.2 (OT )p
,- m.5 (25'),1-.~‘3.5(1.»09);

5 (00), LE.“ (?5°). Frox these

dfita the 419919 "999nts V999 fnun? to be 1.fl0“ 999 5,5?3

r9999ct3vely.

,"7'17" fl
g

’1‘5

" ‘1"- ‘f.‘:L ’3':\ a ‘ 4.. 47.
‘1‘}.{d‘i1‘ 1"
flats ”or The '9‘77r9+*99 of The
gen er 1""1 pang Frecirgion L971" W139!"

 

Units on Units on

 

Fr9ci“1on Primnrv ftrndprd Capacitnnca
Condan’nr Carsqnitnr Ar»: flflfx ’-
- ~-‘t - “I '4 - \o . 4 ’0

100 1.75’. 1 9.0

JHD

199 179“. 9 L9.? ,.137
1L0 1137. 0 93.9 9.?75
190 1L75.7 191.6 1?.195
?30 15 77. 4 2?},7 9 ,FLs
990 1599 F 7FF.5 77.1F9
919 1557. o WOL. 77.739
“F9 1396.1 7L .3 34.1L9
290 IF7h.7 339.9 b .727
700 1’71.1 917.? LL.C?

399 1707.2 h53.1 L7.F03
7L0 17L3.h h90.3 51.73?
7=F o 1?7F.3 527.? F5.19?
10“ lglfiog 53%.? 5d. 5‘

L90 1797.7 707.4 F2.7Lh
L?Q 1770.6 4?S.5 46.115
Lao 1912.0 F57.9 F9.F¢L
L60 1950.3 734.? 73.5L5
LFo 1197.? 70F.? 7L.FLS
L90 191L.9 773.9 "F.51F
590 17LL.2 737 9 7? F13
377'” 1,571 o n "‘5':- o a) if". "1&6
SLO 1377 3 731.3 q7.773
560 1330.1 737.1 F7.fi?3
EGO 126(0‘? d’q5.3 gloltf’fi
F09 1399.0 771.0 0t.1 7
5?. 1L19.3 939.0 77.17F
FLO 1L3F.5 «33.5 79.779
FAQ 1LF1.0 0/9.O 102.5?9
F90 1LFF 3 995.5. 197.7?h
"00 1 17. 2 1071.7 107.9%1

T£VLj IV (c ntSnued)

7' e. _
*nifis an units on

' I r‘ ‘ I h t (A \
:rQCFLion rinarv nt»n”ord uapxcitfince
A 5 7‘ . ‘5‘

pan aflser manscitor h»

I,“ m‘

 

760 153%,? 10a5,2 113.L7?
7L6 1530.0 19$”.o 112.¢é1
7‘0 15“?.3 1091.? 115.3 0
VAC 1‘3h.9 1113.9 117.7?0
”a“ 1477.5 11?“.5 17’.1?9
"“3 1‘30 fl 1130.? 1’“.5~1
”$7 1‘71.} 11”O.1 1 $.737
9‘0 1403.0 1ffi?,o 1?".121
“*3 1735.0 1?7L.O 1°“.?“°
030 1735.9 1?aa.n 11-.svn
0?Q 17=r.9 194h.? 133...?
Oh” 1*"7.D 1?’A.G 1?3.”7Q
9‘? ‘7“‘.D 1333.0 13fi,¢~fi
QGO 1”?”.9 137%.? 1??.”‘
12““ T“‘5.5 13h&.5 1L?.‘1L
30d?“ 13:33.7 11,6”).7 1535.725?
10%? 1“?“ ” 1379.3 148.7“?
1640 1*?¢.3 1?97.o 1&7."?
104m lQfi 3. 1 15.1%.. 1 114"“ 0 £70
7100 10“3.5 143°.5 131.&-5

‘ I" t ‘ ‘ ‘ fl "' Q , V"

*cnllnn fi sixes the notrl Dunbar as units on the pri "ry
. , 0 ~ 5" v ,~

standard cnpaaitér thnt COVPQSnnnn to the numFer 0? an to

cavered on the “r001910n ccndnnror.

fitelectric
0
fit

 

Te rm, rm ta re

CO

 

,1, .0

x“) p- \.d --O 9.) \1'1

0 C
"n m‘.“

h
.,'—'

.J
.4 3 'n'Q‘J‘P'MJ ‘5')
'h “-3 :3 H 73 "*3 ‘3 *3

O
H
-o

 

h

W?Ii”ratiun “n‘a ”fir fiieloctrfc Cell

 

_ “mo—”.1“.

“remura Cnnz'?a=:'1'=0r Car-.qrfitxtnce "re-Imire C'wnrien:nr Camcfitnncg
‘ 1

”m o :- 3;”: 31.634” n.7,. fl/‘5_x(oz rm 0 P B 'r 1934,1135? fl/df X102.

 

u.”-

 

 

C°Ii*” ~*~n st “7.7;”: Cnli¥r*ticn :: 35.75";
395 ?90.3 h?.é ?OS 1L3.5 1 .9
33° 3‘3.4 57.0 17a 173.9 1“.4
‘0; L7*.0 f~.‘ 1AA ?fi£.¢ “”.7
“L4 £1”.° ”?.3 115 P1”.’ 3¢.2
1"“ ’11.L ”’.Q 01 f7*. 7d,?
1’1 7“” “ ‘7“.‘ ‘7 10” 1 .1.0
0‘ 97¢.) 1??.‘ 3? 3&7.3 :“.d
h“ 9’1.9 1“.“ O 73‘.O ‘“.?
O 10”?,7 1L”.¢
7’5!) “4.? 7.?
950 Th‘.“ 1’.L 171 1’?.0 1,.7
”In 1G7.1 7‘.9 ILL 151.7 $9.0
179 ?“7.¢ 1“.0 115 9?",1 7,.7
1L5 °“&.0 #3.“ Q? “5 .0 P7.0
‘11 71L-1 50., ca .¢«.5 .7.L
73 ".19 0“ {30‘ O 6:301. {:30}
10 hf“.i _1.2

sa11+r~tann at L5.S°3 Csli‘rrtinn ,. 57.5”.
?rq 11’40’) 0.0 :VM ?4‘J+.£, 3:003
??# 150.3 17.5 “:4 311.9 hT.R
130 190.0 “3.7 3"“ 39?.3 5?.”
172 ??°.O 3‘.? 15” ¢L?.5 ‘?.h
11a réa.a 7.3 93 5”P.3 ¢1.?
“9 ?1‘.3 h‘.0 LS (@1.5 9?.L
6? 356.9 5L.5 O fi7?.R 193.3
1:; £565.}; ’3.“ fl. 4 . -~ . mb "I? 6"“
0 LAQ.‘ 7:.7 'I‘Ifrdhiflr‘ a .‘o ’ ‘-'
36? ’”‘.7 $7.5
1A? 152.5 11.0 ?WQ ?&1.7 L9.5
1?6 1dfi.1 :9.0 *6} ?°?.7 5“.?
”1 “1“.“ 7“.“ P17 AF”.1 “.h
A} '5“,1 35,: 745 509,w 77.5
?fi Tfii.3 L”.4 17h 57?.2 P*.0
0 2;»,1 53.3 57 {10.3 7?.5
I“; 71r’.9 11: 10.7

 

.,'.r-' .0: It?
! ."1..‘.a ‘II

7n‘cu1ntion of Henlucen%1a Cn“rritfince 0' C011

 

(5 ol) 7" 1C};

0-1
.6!""T‘-@ ratare

."J
‘V1

°K “Wrnnia

704.91 svfi? .¢*w 3LL.53
‘ nag? .14" 31A,?L
3"").Q1 9‘1" ovidlfi "“ 500.!

HHHFJH>J 5’73)
0

o
’1-
J

\1

31’.“ 5315 7 ? §?W,,
:115 07%“ '3’d._f‘3

3.3“." Lek“ .C'gf: 30::0‘n]

ahe.¢a 4593 .55” FLA.

 

 

an‘nctr4c Canstfint ‘atfi Var 'Iscprsrv1 'tfier

 

 

 

 

"resrure "no"c¥tvnc~ Vrnssura Thracitnnce
M. r 3‘ .- 2 4‘ 7
n .3 H fl/‘i’XIO mm 0 Ho fl/AfX/o‘
Fanfiureflentw at 35.7508 Venture~nncg at A5.5n3
lflh 18.9 '17h 15.6
15" "1-9 ‘1’3 0005
133 372.0 9'}. 75.0
113 34.0 79 20.9
5” #5.? 39 41.3
75 ‘7.“ 79 h4.h
o 7100 q .i‘z'roo
1? 3b.? 1?5 h,#
‘75 A0.0 157 “0.0
Rb Lh.? 13” 7b.5
.fi 51.? 1?1 ?9.?
:2’; F100 {‘3 3h."
0 71.? 91 L0.0
61 L”.?
In” 35.3 an 53.?
7” h”.0 2. 50.5
A7.L

 

 

 

Iéo -. -.--_ _.

   

 

 

 

 

 

 

 

d
2.4
Y
‘i
fined?
L)
5
E4
H
c)
S
()4db
i
o L , 1 J l 1
loo 200 300 #00 5‘00 600
PRESSURE (mm. of Hg)
Figure V. Typical Plot of Cell Calibragion.Data-
Calibration of Cell at 23.75 C
l20— ,
a
o 1 i
R i
“ {
33°- ;
a:
L)
E
3 4d“
‘d
92
L)
o 1 1 L 1 l
IUD 1&9 She 4ND 500 00

PRESSURE (mm.of Hg)

Fi-ure VI. 1c 1 lot f D1e,ectr1c Constantiflata-
g , ggfcufation o ‘Iae%ropyl Ether at 23.75°C

1... t V" I an
‘ g 7 , T
".‘.-.l J

.3”;

Cialectric Constant [fits for tart-9ltvlsmine

 

4‘ A m-ufixw-

 

r‘ a s ‘q . J‘ . ,q, . - . _
r0234~a wnpaaitauce Fraaauru Canacifihnce

m 0" H"? fif§xlol "'3'“. OP Hf: fl/I‘J’Xloa

73‘

\. '1
O

( 7‘
I}
f.)
c f
u:
C
("J

9.9 ‘t-zzremr’n
'? "4‘;
155
13“
10?

.3 E”)
.

(7N \‘n x
U!

J‘. \h ‘uJ L‘- '3\ O "3

(huh pm.» A) x)
0
00:21:30 h‘J
5-4
,‘.V k.) .
,_ u .
J
_)
O
“#‘r-‘BMQ C'P‘.)

7‘ . #1 53.

aa , A 34,

0 . 1‘ LL.

1" Air}.

1&9 ??.9 0 5h.
1°fi 30.0
1m: 37.0
7" Lidia
AS 53.0
2? $0.0
0 67.A

Veraurements at LS.S°C
153 lG.L
1‘0 ?..L
1L. ?‘.3
190 3?.6

95 fifi A

75 2.3.9

 

3",]

C4electr40 Constant Yrta far ?ri?luvrancet1c Anhylride

“revqure Canacitnnce 7ress;ra Capacitance

mm or ”0" ”Man? mm of H3 [UH Xm‘

“assuremanta at 93.7590 Fen*urwrentfi n: 35.7503

195 30.2 1¢1 3C.¢
1A4 39.5 155 3”.?
13? Snoo 1?? [3701*
67 71.5 54 6”.h
0 (”>06 0 5,507
2‘0 ?7.7 ?29 74.2
1.03 3505 1d? :‘qoh
lee us.7 15? 29.0
17’ 53.0 19. an.2
102 6a.6 91 5‘.4
6w vfi.0 SQ éfi.?
an 54.; a? 77.
0 97.h 0 ¢A.A
:"(‘p~*1 '3" L”;
2’41. [$03
151 50.0 ?99 13.0
107 57.3 177 ?1.L
95 57.7 1&0 71.7
63 7%. 1?5 A9,?
76 «459.6 71 50.3
0 7h.fi
90L 1b.?
170 57.L
115 1:014»
99 #3.?
AC, 5.7.5
24 5%.L
O 7L.fi

 

 

 

“PC-"i. 7'. Cfintinued)
“re "-3 :re Cnfiscitm ce ”raswtzr-a Capa c1. fiance
WM 4‘ I" . 4"
.- O Hg, fiflixlo‘ 3'37”) 9 H3: flp*X‘°‘-
143 13.”
13? ?1.7
105 3” ."

70 34.2
5" a? to
2? 57.n

0 If") I h

'7‘:‘. 7371': TI
K .3; ‘5,-..‘ u

“I

1.91ectric Cfiflfitflfit “n291for VFnSphorws ?rich10ride

Tranqure Capncttnnce Pressure Cavacitance

run n“ H: flfli’xlfiz .vvzm o? H: flfli’xloz

 

lé
O

Femrurements 31 57.503 10A 57.2
17% 51.7 95 £n_¢
161 53.3 67 63.¢

97 Ch.h L7 #7.?
’7 54.? 3? 71,0
7? ‘5".52 15 75.?
‘11 3.0,.5 O 7‘90
5% 3.R
$4 7 7

5

3

JR} ‘h .'h
-2 :3

A.\‘.—

. Q
I :'T
‘ I. ' >1 4“ ‘

3:17.01": “fi "” '3 W the

.31. “01 O ’ fipafEflt "a? Py‘ozcez‘ vi 9"," T"(“.1”3‘.Dfi

. W_‘
__Isntrnp¥1 “”F

 

--.-I—.

Temvernture

'k ?M

Cfifihwe (flu-HUT /;'

“/uole

)110“

AC‘ (6-!
julhf A

 

 

 

 

 

 

 

 

 

 

 

 

1fi0,0] ?,WSOQ 6K3? QSLCR 54,09 777b,? 1.1?
fl . f l‘, .- as
, .1‘n‘q (' 3“ f'5i't9é 5£.fln 7‘77~’..£' 191?
9,1933 Ara? ?5u:9 55.?5 735A.? 1.10
33¢.54 9.1455 55" “‘1L‘ 57.99 c3.71.1. 1.1:
‘5. "31,3 AIC‘O :Dflh-F‘ 53. 5 7:) P.L§ 10"“?
tPrt-Futvinw*no
339.01 ?.177 6617 25426 56.f° 13913.2 1,7?
?.15fi ““5” ?5'7” $6.?7 1““? 7 1.27
“1¢.F4 1.19? I07 ?!1AE 52.95 9Q“*.L 1,??
?.flnh 5196 Tfilufi 57.0? ¢1Ln.7 1.7,
1'31 ”‘3 tiargr‘cnfi c Art‘s? ir‘ir’e
?7‘.“1 ?.L154 7$lb ‘&?‘1 5’.‘L 13 ’7.9 1.L”
v.h31? f??? ”L741 S‘.L3 13“6?.Q 1.&?
3fi0.fi1 9.1160 6%75 ?5h?d 55.13 1?L300¢ I‘LQ
2.3”h? 6581 ?5a?” Sfioflé 13999.; 1-59
31¢.56 7.1?1h ‘3“} 9‘1h4 55.59 13055.9 1.51
r5 . i . 'l ' " ”CA '
7 VQ’I I ‘5’.) 9!}. A 5503“} 13 J' o 10 51..
Pfif‘"h"ru‘ Irin7 m1 £”§
330.31 1.1. .. L””’ 7713. 75.x? $471.? L.°?
r A "-4
1.91‘1;’,-(‘H 23,7130 [1.31.15 :‘ '7:;.1 0.0!:

 

*{eflr‘cwme v'wr‘fir'nc- m“ ce71

. 9 “GI Q10
EC) 3 3A») 0 .‘li ”Iggt 1p) .r1_0
:0 " 1:2'31’ pflfflt (j
‘1') ; r” I‘I‘q’Pt

1,, “73.?1/1/lff’t 327.05“

33

‘ ,
.4192“?! "-0 5“? fir) "av-M3 *fi ‘-‘n.,.,n. "H "a
{:5 s.‘ kl u. -. 18 b 321.1 x} ”C.) 1!} I‘ 9" -‘ f ).F) I" ‘

 

Isooi'fo nyll "”337 91“ 1
tart-mtv‘mmine 1 5
g‘f‘f “ luoros-cetic mhvfiflfie 1 .
‘nnflfinnrufi trickieriie 0 ”d
. . T, '

 

 

("9'1 .
I4 ' ‘—

1 .v . ‘ . - . ~-
. . 2
. . a ,
4 ‘ -/ ‘ "P- .3
1 § I u h -

it. . a s . -. q
‘1 ’ \ 4 " R ‘ " . . . ‘ ad}.- \ 'I" "“h ”Ra - Q .'.‘.
M . 'f . s d \n’ |~ .. A at g, ' " f . . 'v" ‘ . §U 0‘. | u-

A 1‘. a“ .4- ‘H J. p‘
._ v _
.. a .4 yo «I V

‘4‘

‘.~-‘.¢)‘
~--'~‘6 ~.i\~v

3

J. '. ,-.
"1:1“

WW

" 1" .‘o '51-‘9‘ "-
fl ‘h.-‘ '

04 .p‘

 

‘
“P‘ “

'_.-‘,.. g.

.5, 1,. 9‘;

"43¢ . 51’

_ f. . -. _.‘
Lu“ bfiLlO "V 3

 

'1

P .h?- r. "R‘-
& .JI—J'lni ~..-' 1.:st

«In
9..“

.1

I
«at “L ‘
0 av.-

. 5 u ’p ‘ n
l" #‘e a l! _ s
. -,. . .- I .3 u

19'-
i

 

‘ - . w :0 .
'h 5 ‘ “V “ n 1" 1’ " ‘ ' -‘\ ‘5- '~~ 3". r
‘ - - ‘ -.. ' l - . . . .
Mn..." ‘I’vrdfi J~~.'-..-._~ -. , _,. > . 5". ‘3...“ “-4
. ..V 2 .._ fl ‘ " . .' ’. .
y.» 1 ‘ 1 - ‘ - .‘fl'. ‘ f.’ 2 . .ntw : “‘fi'\“.." -q‘. ‘ . -,.‘ -...‘.‘ p‘ . ‘ ." ,.‘ . “P , ‘
-.! ' up . \n "l .1 \ .~ my . 1' .3 ‘. ‘2. .. "q: n. , s R‘ ... ’rL _ ‘ C... L.’ ‘2... J a; 31.“; y.”
" . . . ‘, 'I . . , t:
:5 .72. .' ... -. n— ‘ *1 .t J‘ Pl‘ .01 .1 w ’-‘ 2,... "w .‘ . .' X "\ f. ‘9“ . 1 'u.‘ 'r "v ‘
""4’ ”"’ V 9" ‘J"-" .. 'v- Vaux-n ~ -~--' Luau. «5.3-»; L". —"x a. J

 

 

‘.V m‘} f . z
’ l -
; V‘- c «iv \‘~ hH‘on

' ' $
33/". 1* ‘ "‘- ,. ~.
*- rV-‘c: Lfl'-o.ufl
I ‘
‘ a
219- u
I ~ ' .
.. ., A .9
w~.».'...’.v .1...)
'c' O‘KhIl-o-I c\_"\ f: 4*
no... t... 1., . ..-- . -
I
f'i an. ’ ' . ._- . “
,
'«l‘u -' «-v\~\‘. .
u g ' '
1 9 \ s! a
nun-.- x. V‘- V
. ..
! -'4 3 . 91‘s val“
‘9‘". «fl " ' _ ’-« .1. 'n'-‘.
7 v . '.- 4 .-' -' ‘3». ,r‘
k- kin“: 4". ‘u. 5‘.‘

If C‘ ‘3‘ ‘
'1 x u ~\ ‘ ’ my.“ , fl '1." f. . -' \J',‘ “A .5 "31-91 ,n- .~".o...\
v-v - p . . w- u ~-. ’9 -- fl. -1 7.. \.. 10' J 5' p a. ..- 1,. . 3.. o. . VI a..- ’ .‘ . - . ‘
l I
1? 4 * ’ ‘ , “- ' ‘ v Q *
"I '. ‘ 1" ~ '-. ‘ A. ' -'\ .t "h 'x s r ' - -" ‘\ w -. .' '.‘_."\ J . "’ {H‘ “ «A s", f“ a"
‘ . ._I _ ‘._. - ‘- . v .H .1 . .4 '~. - _ . I '3... 1‘ -."-\ a! .l‘l.“ A - U {‘3' ~II-
cud-”mew. I" v -..... any—Cr a "gum-q... “navymw "
' a o a .. - . u - L a. .A u - . >
4' - . "" - »w*- 1n" .1 '2- '~.- '- " :‘..-.° n 1.3“ 4 f ~. ‘ ~~ n -~._ '-.' ,. ‘, ~. ,--. - -, ' - 1.
‘J A A. .u m'a 5-5. --' . "fl ”- ~¢ '-r' ‘v at JS. ’n‘ '4 Vi A ".3 x L ‘14 '.-'~ ' 1’ ‘us at. ._ - 'L'. - .. .. ‘n’ 's" I.-"~v‘ 93.. v v‘ . ’ -- 1- .3 w 5; «an _ .7 U ‘ 4.. ‘-
4~ ., . -. 1 ., .. . . ~‘ I . ‘h (g, 1,. -. ‘- .., “ a, '. . a. -
PW (‘9 L an. ‘4‘ . (a, , ’0‘ , ' g | . fly. . ‘ I. ‘ 1 (- f ‘I! .‘ . n 5- | v . , r ' 'Y . J. H q .- J - :9“ A‘s-1 2' 1 ".K s . fl! 4-..- ' ~-
0-; by u ‘..,' - u 'c‘ — g n v ‘9' g in!" «3 ¥h*-t ‘J "~64. v. «A: o' ‘-. 'w‘» . 'Il ;‘- ‘d‘v-J 4 mm’ 'r v r- v- 4 ~h IV 4" ... ~- ‘ 5 - 0 V g. lye-“3.: ~~vs
. . ‘N P“ \ . i“ S x g 9 q
I ‘F‘ ‘ ""i ’ u . a ' ‘« "- " :" ' "N" v r ‘ 3 -. .3 n , ... : \ .fia.‘ . ."2 u) ' ‘ '2 ."
1-" fin: ' .l . I . -- ’J I . a A» .1 - . ' . . ‘xr .9 94 at . ‘, _ .2. 4 ¢. . ‘ ‘ "J ‘ ‘ - h H_'.
#8“ M __,-, . E‘s," .f ’ '4‘ .. " l, 11 ", .’ .. ; “1‘. 1..- ‘ y» .’"u“ r.“ by L W 3f? .n. ’- in. 1‘ 3w - ""‘."1 any: -‘ 4 f" "
5.. -. ~. ."g u.) a as. 2. v . " -' m». .5: -. '- .) I .. .. awwu'. . ~-' ,- .- var w! 'I‘ an) y»- . t' . . a! s... .
~ - ' .
, . . - - s v
.. mm m «a»; ’27:. W“. a. t» aw ‘ '-‘---. - . ~ .. -.
"' _ ._. .,‘ Q... ‘. o’w’ _‘_ RI: ¢ _ ‘1 ~,.. .4 V d . -- .. “' - _ J -—- 'gJ «b J A4. -.a‘ 4 .0 4. an}. .'. L ‘4 h J a. ‘ fl ‘ L- a ' ~ w w’ - 0'
a o O C
I i, ‘ . 3 ' ' "'0 .
-- _-' , .‘ *0 .. -... .
a
- ‘f . 1 _‘, '3 2‘- . ”,5. ‘, . ' n' " An _.I .. , .: ." d r\ ’v -. .., x ‘ u ,1 ‘ . q c J- J -. -. a . _1- . A
. . _ , ., ‘ ..
‘2. .,, .V .; .r.vyj 0.0.4. d§.v q... 1 ‘..'....’. dufi. hr....: .1 ;. .4... .~ ‘ s“ 1 +4be " N‘ . ~J~~o
r . ' ,- . Q ~ - '- -
‘3 J‘. E 'l ’. -r "R 4 1 '4 I ~ -. 7 'z A. . 4 ~~ 7"? t s 1- s. ‘3 . ' ' :9 u _'- v“ ~_ - '. . A t ' 1 -,
. . t . . . ~ . ' ‘
.. fig... - '1 “ an Ia“ «I ‘ - \.. ‘4 I' ~’ a .~ IL- a. q .I ‘- —A 5 W» a- . u: ‘ ‘ v - N ‘ J -5- \r‘r'" ~ ’ “a. ' ‘A‘ - y 4 - * ¥ -' < ‘
- , 1. C q - t _ - 3 - -g
. ' '\ _ .,. , . ’ .- |.._ - m. «k», -.. .1 3.. =-_ - ‘ ‘1‘ ‘ .. . . < 7 r" . . .- -- ‘. ,. . ‘ .\‘
'J‘ , 1 '1 "H a v». "r‘ '- d .41 Ru ‘1’. at u. - . r S < " \ ~-v ‘ ' -'-- ‘- ”I \ I'" I- ”I w ' " - 5'" " ~ ' ‘ d . ! ~ ~
__._ ‘- _...... flu _. 4}.— ,u
’1“ '- . __ a a a 7 . a Q ~ . .
- ~ v =‘ . i 't ' ' ~ ' ‘- '3 . .' - ‘. . . ‘ N
“ . '0‘ v .0) I. No“ '- , .,. . g ‘ .4 . . .- c' '\ ‘I 3.9 - . ~ . .I‘ -. . -m - y '. . ..
'- ~ | "'0‘ , _u g o .|
‘,..'. ’5 \ .',I 7" ‘ .,, _ ¢ . a .~ ~ . "I w. o . ., , r ; , ‘“ ' , -‘. 4"
n. - ’w . -' ‘r u; v' _, - .n' ‘- h 0-. b *4 - .-.I ‘ -:. | k _ . L.‘ . I‘d ’ ' - . ’ .- '. dbl 5 x: "I ‘ '.~' I
‘ ‘ . a ' , - w
' - ' - ~ ! 0
v < I . s l a qn ”kl
. u ,5 . ‘ \I Q I. .4 . .
' . 1 ' ’« . M . ‘ I . '5 1’ z - ' "
, A. . we .- .. - ”v . 7‘ v . ‘ .. - nu . (.4 . , . . Q

3-- a.

'7 W
n 0‘ v a , § . v A . ,— -
.fl '1‘ .- :‘5. "I HQ w‘, C a «L .2 .\ .5 fl. _. _ V" _.' I w! . n, 4 . ’ g .“ ’1 r‘ 3‘ PH . ‘~ A" k P5“ A“. _- 1...”,
-.. “3'. .4. .“s4\ " v c L? '3 'v—a U_;l :3» A -— ab‘t' a £4 - a \z‘ .2 ,J M... 3...! .“ 34‘ :g‘ -1... «a. ; w. "... 5* q .7,
v
I,
. Q .2. p. “3.. a {a , ‘f‘n. . .- .Jr. ‘7 , ”fl 5! t .. a f) . __ .§\ 3‘ '1 A. _’_\ p i'.‘ -. L 3 ._‘ 1‘. 3. ‘ . ‘5
" \'\I ~ it: 5’ \¢ r' . lu‘l ~‘: ' t "d' a . u. V.I s,~'rJ \ ‘4' . I ’ “ . ’9' «4‘ .~ . ..I ~’ .I“ .. 1 ~‘.-' . M -. r..~- hi L\§‘- a. .l L: . ' ‘_l-
.00. A ‘1»- A‘Ju. M l- u «no «I A'fi 1:. ' -4 0- "fi 8, ’4‘ ‘. q 4'": v" _-a :5. 3 .5 fit a‘ p: n t r 7‘ ’J'r{(‘ 'DQ’A- ‘ 3 l. A v.' 1 .6 3‘ A. ..~,-.‘ ‘3‘ f" &
«4 .1-. ~. ‘-.....4 ..-:~ ', . ... . n. ‘r.- a. “I . n. . ‘ .4 «J .5. .. bi « ... v u. -‘ I» J .4 < u" a x. 'I -‘ «. -- J » .-._.. "n “I 43...- 'v .
Q -- ‘
§ ' . - _
(‘1 2" .fi ' 0' ’1‘: y.” 'fi r‘ }-‘._/\ 1 u‘ a a" 4’ .5 m 'g' y. ‘1 0'1 .1 s 1- ‘Q 4 . 'I (1. f‘ a u“ ‘I'- n 3' M, ‘A .m i- . -. ,n'
=0 — - ‘-- a“ -"- w." .- 1'! - ’.—‘ #‘ M; M .J - - . —I‘ .‘i f ‘- A. 1‘ $- u“ I. -a‘.a . . 56'. A; h I; — '— .- - r. ~ - - ’ ‘6', . ‘0'
l t ‘ "‘ Ft ‘2 ‘3: " ‘ 1* 'l" “5 '7 "' .1 ‘5‘ f'“ .l. \' 1‘ 1‘ "~' 3”" P". I“\ t “'2 '2‘ ' "a“ ‘l I ‘t m ‘. r"' a it .5 "s
- J ' c v~ II' o. '4 0 V. \ ‘9 I ... . 1 M” -. ‘0 ‘ -. v h: -. u) i . _. '. -.— vt - - -.~ . .- . v. .. .. .4 ‘ .4- .“ .4. . , .
.I‘- r\ '- 0 \ ‘? .~ .v‘ 7",? " h‘ A'. ‘0 ‘>q a c :« 'aa‘ P. 5A.-I_" -~ '( Ham-4 as é. ’ b¢ ‘ .fi «sf- O‘ P a r‘“ 3-: ... -‘ (M‘- O A .. rug 5" '.‘ _-“.'a
. n-w‘ r.‘ who VQJ 5" -A‘rq“ U . — i ‘r ‘0‘; .‘.:: .4: «a : 4 w In , »_c v a In r1 0‘ --¢ ‘..' .. g‘ - - --r ~ v \ \ n‘ 1, ‘.r u n J. ‘4
s: 9
b ‘O A - «I § 6 - 4
'" '- > :t'u‘r“ " aw , ~~.,-,~ '~ rat-'3 1‘ I"; . 1 ”'“":“ "“3" '1’." {Hf ; 1- ".- ’ f " '"
4 -) ,4! ‘a‘ ‘ " - :- ng * _ '1 ~ ‘1- ~v ,, ”I . J." V 4 ' ‘ - ’r.‘ ‘ I- .u' ‘ ~I- .. r’w. : "‘ ’c“ .. 4,4' ‘24
. ... . I
Q J1 ' r’ . 4‘- ‘," ' T‘ . 3" L'- ' a. h; I‘ ‘. J‘ t'. A ‘L T " .-- " " 1‘ .A q. .q ‘ ' _f*. *. . . 5' 1 ‘1‘ ‘5 a ~' 1 -.-
‘ _-‘. U 0 .-' m «a N 's.‘ a) - n/ {- ‘su' ' - .4 ‘U'4 '9 Ah“ .g ." ' “34 a. An”. k 5-} ' ._ ' .
J ‘V’ r
“I‘-
I; ‘n ox ‘- -(- Q). on a, n a . .v- .\ a .3 A I .- I ‘1‘) ’ _-". ‘L 4,», .‘ .3 .‘ ‘,. rfio... .. .1, .'K 1 5" .' - v. |
‘ . . ‘ .
I ~, .r "o ’I. u. ' ‘d —‘ ~.’ - -§ 1.. - .4. '.r I. '2’ - E .fil a . I, u
”4*.o'ww4a *mmm "
- ‘ _o.
‘~-’ .. " 'r§ 7" ’ i ' ‘k ‘ 'fir". Mk ' ““5 ", Q """‘ F". l"-‘ 7 3’3; . ’v' ‘¢-‘. 3 " ““1 '. ‘ .fi $‘ .3 '9 : _‘: ‘9 "‘ .9" " 3‘ 7 ’i "‘ -,v'
3" 5‘ J :9: ‘.¢ ‘ ‘2 r ‘ if : ‘ .4- - ~.~' .‘- ' '$ >0“. -' j: a “J " . -; - . 5 n -i "- 1' i~ o y n“ “r' ‘I ""|' . \. “
-A b. «‘J _ ~
A 5“" '4 ""31 3‘...‘ ~W"‘«n ‘5 ““5 m'y-J‘. 9-1;» "' 3';- m,» .4 .»- » ~T- "'rs-fi i. ("" ‘1
luh - ‘J “I '0‘ .-~.‘ J\- A l i -O n- u r ‘1’ . o 'u' \- we 4* v-" — ‘ n' a ‘.o r' <' ‘-~ - ‘é . ' 3' ' ’J ‘o‘ I. n u “'- ‘ ‘ -L --J K -. I
v w’ --
‘E o.‘ v .. _‘, - f. ”N a I" am...‘ A“ 1* 0‘ In .1. 2‘ . p 0.. ‘v ;. (a .45 u-\ ’11: ‘. ¢ .5 I- 9 7 _n‘ A . .‘. at t "w‘ ‘ .. . ‘_ £ .,. '1
‘ . , . , . _ . . . . . - ’ . ,
- h v~.‘ ‘ ( 1 r x. a &. .. Q I». u- u 9. .5 ‘4 1" .- .. v A q- 'v’ ~.~ - a 'V*' -1"-I. a .- 1v H - on . - r In ~I .-. > -O'-'— '01" " L 4 'fi
‘. ' - . & fl u' _ ' “ Q ' 'O
f: ’5‘ ' ‘ " 7“ -'-‘ w "9 "‘ ,0 f‘ f" ‘ "k. '5 ’3 Q a ‘v’fid‘ ' 1 ',- "fl: ‘ "E ' " z "I '7 ’ 1f“. ‘ "f - . {'5 If“ “ ‘ '
L.‘-.- ..' 2 ~’ ‘3: .. ‘L"( |-\ 2 .3} - i ‘0‘ H‘ A '3’ I it 2: '9' "- “ ', a. f . '. "“i J ._ ‘ ‘-v - ' ‘4’ ~'; 0 “ " ‘~'
‘0‘ - “T . . " j“ 1.:- .4 1.5 ‘~ I . A, {Q 9 - f I" r. I": a a. ., t 11 9 . Ir. . .
, .w... _ z 49...! ,_..~ .. ..‘r a ~ V~.;..‘ . --nc:'-\.. .-.
‘ . - ,.
. '\ r" '~-...u '. J. b. .s 1 fit. _px, \r. M Y N. ( '44., A 3', fly ’4, A k Tu. \m. uu 5‘ ‘M v - 4‘ “'V. I; In ..I u‘. - p j a "’
u r ru'v J. ‘J. .. «I. .u—Q . —. v iv v' -.v a . Q~ ’. -v-..- ‘0 .1: «v v w 6 'un - b a Q n w -.r - -..- ut‘ at - 'm .. w . ‘ - u‘
. .' p a, o . .» .. ,-' 4" 7‘ ‘a. .4 . u. .1. n.- -L 0. _.-§ .-- 9 \‘~ 1 .0“. ’ rah" . n -J'I_~ f‘ -g f ‘_ g ”9‘ .v‘ . . .3 A ‘ I‘ ‘9 ? 0-.
. , - .. . '. . . n . _ ' - '
. a y. - . ‘ 7 3}"- '-~.: .3 -. ‘- J w '\ c k .t . ' ' ' ~J . “0 ~.,- .a. y. A" q -e~I-‘- o D '9- u .. A. u. .'. »._~ "v ‘ 04 4. ‘w s A
O
. ' n. .. ‘I n
14 ‘=~ - r ‘ 9 - a _r 9“ p- 1 N 1'“ - :u ' ?-¢ '5 fl . '? .1. pg of}? Q A“, ~. ‘. 7'- *ywa‘ «‘«unv‘ 4-" | o a» ~-. 5 g p, .A in. r .o of .2
“I ,1 4 . .. , y .\.a ;-. NC -A. 0- gig 'r \v- 4 .‘va -!._t .5 w-J ,. J (5 I 3 '5- 4- n S. 3"" e EL... k- 2 -‘-'o 9' --I .w ' ‘ ~' ‘1' ‘ 9" ' "90’ ~‘- V
~. . ~. . v - - “
‘; "-3"? ' w - ‘ - 3 m; «. v 3‘ a. Z 5 .~‘~‘ ~fl us u- p», «nu .' ' tun " 7 A, ( ‘ ~~ A . 5 “w .-«. my}
. . . . - . .. . . .-
w .p’ . .9. l-- v - . .\ --— ., ... 5. ~. - — ‘5 I4 .9 - "K j .5 V” . .. . L '.r 014' a , ‘i. - an A-‘L ~.. ‘ u‘ ~‘u ~¢ . ~. a. - .- § 3!
‘ i i q ‘q _-
.~_ 1‘ g. ' ._ I" ”'0. $ ’ f ,2“? . 1; ‘1 ”31;" "If“ f. . an 'i' ‘ 1-? _ “3”.“ 1 . .3: ‘ ‘ t. -v_ ' 5 _ . u - I
-r-' "3 -' a 0‘ ".3. ‘0' non' ’— ...' “1&1’13 a - ‘4“:- u' ‘1' vb J *1; 1“.” L a» N'- “I .’ '5" '5: :3.“ .3. ~ . a 4'. 3 i, ‘
=2 C a 1' ”'2. + a I. ) W . H
‘1 l1 ,
3-1wv 7.1.27», 204:1) *5!
. o

Womuwr av mu! .‘

Iole

 

. l Dc ‘. u .

. .: ... .', w ., . ,. . .4 n. 1. ~- s
-- ~~ 0 a N no- ‘

.. J j g Q 1.. ~—*. . .... ., y‘. . .

3 ((O-KU“ «- (0-8:? + 2(0-XI)(

ran

.. .
.u ' _ ~ .- .‘
“3 .. V. A. . I ‘. I
Q
- ‘ ‘ - - ,A
“I n. . u .g In" .

Th» calcu1fitad Vfl‘ue is higher thfin the valun abserved.

Thin 19 rra*9*1v €13 tn avme nth?” effbcta, such as influctiva
e'fiact or interactions katween tha Fonfi dipclos in thS.
phnrua tfl ch70?! de.

Tannnnryl»ithnr.h The dinofle mamant a? isnprnnyl

 

ether rennrtfid in t?is mar? 13 1.1?3. ?%e isannnyl atfler
moment earees very weYI with Targley rnd Le FevrQYS value
(L3), 1.139 in gas.

It is elfio interawtina tn knnw thnt the rvarn'fi a?
the moment of tha ayarntrical ethavs (1.???) is Xavier thnn
that o? the unsy~mntrtca1 othefis (1.177). iymmétry in $fi¥0r3
mfight %a eruwcted to fitnPi112e hyper cnnjugntinn structurn9
which represent polfirizntion 0? aka alkyl group of oxygen.

Isopronvl ether vroknPly has the F-C-G-C-R arrflnze-
ment “19$, with the hydrngmn ptoma clefie tarefihQr. (c9. 1.7
A Fetwaen cefitorw). However thia nrrnnpe~ent is atericnlly
allnva+1a. ?hore 15 31cm rrmFmVXV some fleyibility of the

alkyl raiicnls.

 

LWfiW:5uflwwn Wflrwic 3%W1C‘1TnfitifhinHFNh?uCts
1 If 1"!

O 'f I: q "‘ ‘ . — _. - , . ~‘an -
122411i5tr5r3, ;:’3Ch‘?‘~~fi'?r ). . . .;i.f";-,1-}n or jgt-jrfn KO‘fik hr).

CI": IZEWLT‘L VII

"N‘V \JT flil ’ is. :35?

NM: electric mnmmts 0“ Four comm'znfirs a? oxygen,
nitrmfien fin»! n‘vor'phorua h'wm hem 1710.9311er in the W “m"
vhf-1:739. The su‘vstflnces gunned, Pnti the el actflc mormnts
found in t‘ris inirmrmmtinn, are: irsam‘off‘yl at}??? 1.173.
tart-Hitvlfi‘mine 1.?53, tri Qunrorswtic anhy'iride 1.16%}, an“? phat-2..
nhorus tr! chlofiéa 0.0973. {mly ir‘orsmrwl efhar hfd “can stu-
M ed in the vans)!“ state nmvfimsly and the value mmrted by
Le ?evre, 1.133, is in excellent agreement wit. tha vniue
refinrted hem.

The electric moment 0-" phomphorus tflchloride found
in this agar}: in the arr-nor state may *9 cornwrad with th
”11193 0" 0.51777) (51.) 9nd 0.9017) (55) reported in film liters--
mm “or nhomphorua trichlorifie dissolved in cxrhm tetra-
chlorifia 2M kenvma, rnsarectively. 571nm! the electric n29-
mnts M" meat smkstrnces rare 0.1-0.?3 lower in mlution than
in the gas phage the F-ehavior 0“ phnsnhnrus trichlortie 13
nor-m. tart-“utvlnmine, however, has! a Ila-“er moment in
the warm!- phsme 12th the value 1.32:? (LL) found in traumas
snlution. mm anomrlous Mhavior has Ir-—-erm v‘onorte! in the
literature '01“ other 93511195; thug, triathylremine has a moment

of 0.9?“ in the who? 531.59qu but 0.053712 1n *enzima solut inn.

3f!

7‘7'243 63‘-*--ct.ric wom'rn”; 0" tdf‘lucrwcetfic ranEEy'Fr‘i'Fe in
t‘m ‘.-'".".'_.‘?‘ -t"tfi. was 4‘93?!" in ’21“: work, ‘73 Ema 12inch lax-fir :1”. w
t’rvt rewwtn". in the Sitar-”9:22:19 for Fanatic nnhv’ir‘fla ( ~'?.8 ).
The For-fin:- ca‘czz‘étnd f‘nr tri ”mare-“ca".fc *cid “mm “my? mo-

mnnts 13 1.1."? Marvin: Hex-#9.: the 911"“? (2-3-5? 1?; 1109 and the
~21:an 0-0:!) 1'. 1.950 in the! rnhyifirée. -!me the .9 Tor-want.
Fpt'sran O‘:'"'=P.1’"."="'} 9111: cflculfited WWW)???“ ‘1‘: “.3 {75913 13110 hand

”Ta-{Inf} ‘1': tr! fluomncnfic nnhy~§rfi49 hm r‘rJ‘I'mHy not, rm»

Prat": the v"1'h§3 fiswtmrad rM'w-e.

(‘1)

(‘J

('7)

(“‘3

(0)
(m)

(1’)

(13)
(1h)

3?

t 4
tn.
'9”,
’ a
1

‘n'

q q 01': ‘11., H. in. '9 N,H . . '7
p. . . unni'fl-, ,. «'1'fict’lflcpl 9.1.3._I"V‘&'§f1,~§71-’h,’ '1 \? gr‘.‘.',-n“i1’1

‘ "0 ' Q ‘? 5‘ Y
r00?! '-»*'_‘z"‘~‘;“-"-‘?‘.§’. Trad. , F2112»: 5:11.41, 79’”, 1-591“. ‘1”.

"'. “Mink. "Sinaificfl ”gamma-1W??? 1m" 131111 :rfvv?

_I
‘ .
u-r

Invfruwvz‘zrz," ”3113111111 1111.1 "firm, Lon-31111, 1’3140, “’11'1. 1

3:. "“"*“‘ ‘I‘n.”“1-11'311-P1‘11r112mc1: P‘ecr.u?~mfienf:..c~,” John
11‘”? "7‘04 5733153. 71%., {117-1111 Yar‘a I‘m, 311%. KI.

. Parana, " 1tem1'1 11; (Ever at 'T'Hf'a .‘"s:>t?‘.’1a"?r;,"
1tW‘n ‘m‘? 113. ”Minn 1“”.

'1" ~33

F‘. '1'. Farr?! 11;. "ibctficrrl ’"es-‘mwmvmnta,” John "11w

"nd fifinfi, Inc,. 93V ank. 105?, Chng. 15.

:1 a n - fl- ' ‘— g". . ~ “ "" f W IVI
p. .., .2111“. :11 an? .1. - . ‘eftitr. 1211513231"? m‘c .- 11:---~u. 1-1-
1m .n*.'-‘1," P'c'YN-wa-Hin 371103! 3-3., 371.13.311.11 fork, 1953’,
1"
. Hf‘h 1

- O .1.

"?. “H111 :n’. '1". "’. “roan, Jr. R1111. '61. Imam, 7.",
”.9 (1’13“).

v n w w n . fl , fl , ~ 7 '
o ". --n'mmf' -. 1"”‘9 7.1-? ‘4. a 9 "'«ho ‘ o "‘0
'o w " .n A.“
‘19". can. u...’ '0 1} ’3 (1 ’1" °

7‘. “6}"1’9’ rhvpiko z o. ___'_’ 97 (131 )0

p. v‘nb'le. "E'rvoz'fiy‘lfih ”qr {T‘fif 3'1 fll 1-1! q"’ (3.31.: rx) “rf‘\iq-
1111121111.. V1314f1?°‘1_f;05=a‘.1r“1-“"19~’t 13“}? ., 10H???) 1”,?91,
C3197). 1n.

‘5. “19}.1‘90. ”T.t‘~1fir‘ *‘ollécl‘ER-‘q ’” (31:10,“.1 0'71 1:1‘QPH’P‘S: (:0. . Y‘nw
V0246. 19"“).
Unwtw‘nrn npq ”. H. 'D*?. J. Tflrt. LTnct, ‘fiérfl.

r.
(men), :3. '59" (1793‘).

J. 'qy'fi"n. rhy‘fio ”(I-"1'0. L2. (‘7‘; (193“).

C . ’1‘ ‘7FV‘T-3‘1 . "139 Mott?! c 7531?)? 1d. m" '11?! Strut: Curr? ,

0
.w

VcTrww-V111 “09k Co.,-Irc., flew *ork, 1?31.

(w
(3.7)

(1")
(1")

(7’0)

(7'!)

(2?)
(7‘3)

(NH)

US)

(9,4,

(1"?)
(9")

(an)

L0

1?. “‘Yrrnie‘vn T 3' P'amwewa 'tn". .7 H. 73‘113‘251’h "fix-

. ' o . o .
PM“! ”mt-"1- Wif’fiicfil (”‘qu trv, ' hth a'io. I cdrws-
”111 77’0‘3k 1:00 . INC. 3 ' ew ‘. OT‘ 7 . 1:}igng Strip. Afr-TY.

J. Itwmchs. n. ”lav. Ici. Instr” :1, 331; (1331»

a. 1"? a, *. L“ {and C. n. filfifft“. . 1?. C,- ‘ QT... Yflh‘FSQ ’ 1’
3

(1“7’9).
Jen-Ywn Wilma. .7, ~.-:".c'-':. 3344mm 21:: 1:7?!» (173.17).

. ..‘ .5 . ‘ 1 ”1... . 7'
:n‘ 'U. P. "niyt‘n. J. "in. ‘Jtvqan‘. m. ’

Jo ”- Jelatis. 3- finnlied *hys..712. L19-75 (19nd)

C. q. :.:/)n:‘:'"f}fif~5r}r. ”'r6c'!o:nir‘ ‘9 or ‘1CNWP‘V‘3 {Keflsurac
wants FIT finfifiation La’GFFEOVV .erflfi 9 we rah-

H111 {00; ”0., Inc., New York, teav, V01. 11,
:Zh'HT“. b GP 10.

L. 1. u. t!» 1,..15“: "' ""9 Glide 5;.” 2719 179C?! 11"“ (Tom-
phny. Exam Yov‘kh, 10.17.

5“,, 5", F'nUr-rd mm“ .7. .1". Kurtevmt. "3 iérwnvos m1"
Rnfisr FlactrOfiiCO," John "ilnv fin! laws, Inc., Raw

. “in”. 9''77“t')1"t’.--X-:-'-‘are fifl’iflfiion Thnndenfip” Yefirnw-
V111 rock ‘5. Inc. New York 1¢§?,
O a o

'33. Gordy. Row-3. 3")". ”Wm” 33.: 6‘" MOM)"

V‘inhnr‘i D. T‘matt, “21.571. "1-.=:7ert-'r«tion, E'Lic’nijtpn ”.‘tr‘te
:izn1_1.ngge, 1cm,

J. ”. ‘Thrm'torv, 3‘3. -"'. ’fhznmn, 7". 7". ".henhrzn, “a". who-
H*knv, rnfi U. V. ”out, J. Chem. ”Ey3., 1?, liéh (1951).

.7. 1.. r'roa'eira, 'mm‘fl‘lshgd tori“.

#1

(31) Jo 7- COEDQP. ZlflCtvnnics. at 950 (lfifil).

(3?) Fax T. Enrars and Jahn D. Rakerts. J. Am. Chem. 700.,
‘5 ”a? (3QL7)
*Iv . ' . ' .

‘3
(1’

“'-
m3

3
,1

I
u»

(33) Q. L. nurwellg Jro. £0 ITo
Raw. Jci. Infltr., 1°, 63d

(7.1;) Th Ware. ace Tan-.9 "or Thermomuflfie, Vatican???“ Parana

0‘ bt°nfifi"3? Circu2°r SC“.
(35) V. anyvvin. J. vhy$., (k) 3, 579 (17C5).
(1%) ?. Lsnzevin. inn. éhim. at phva., (’)‘2, 73 (1¢35).

(37) A. Cnarr and "wit1in. J. 3m. Chem. ”00.. 2:, L???
(1950).

(14) y£n4¢1t-Pgrngtn1n, "?hysikalisch--“hww£sche Tz¥ellen,"
Pi‘th Edition, Julian “firinfifir, Tfi”l1n, 1936.

(1'0) 7". “sariastffi‘fid. 1‘. 'Dhyffiik. (71193.. :3, 11.7.39 (19.777),

(50) 0. H9929, "n1 A. H. Uhl, *. rhvrik. Chem., P9, 1’7

uh—

(L1) “0 Cl 0' Iii fan? To “30 Term. "’0 £57.90 (35037“. 7‘00 D 7:),

(L?) J. G. flrnvq sn’ *. "uqden. J. C$er. 33c., 17?? (1937).

(A3) G. ‘. “qwclfiy fiai R. J. 7. Le “evre. J. Chem. ”“C-a

1513.3 (1957").
(LA) A. v. 70w «n4 J. ”. 7w1th. J. C%@"u "nc.. "’53 (IOAO).
(L5) Hnwvick, V0“r1* fin4 Tutton. J. Che”. FOC.. 1755 (IQBY).
(M) J. “redder. .1. Chem. r'f-oc. , NM» (195A).

(AV) pourne, “andles, Titlgw, find ”eddnr, fiaturp, 145,
(1°51).

(5‘) C. T‘. rth-ho J. 51". ska". :GC. ’ :2, Q1175 (10.71).

(LO) V. ”tr-an:R rn’ ’. Katera. J. Chem. ~00. J pan, ?ure
Chew Ioct.. "“ llfi-IR flab“).

, at
. “It ’

(51.)

{57)

(’3)
(91.)

(‘1‘?)

7O
/

'nfl Tutorkock enfi da Clinfieleir. rhyiic”: 3h 5

_.:
(1’3”:

~, ~' - n (h .rv '
w v. ’funrt. ”inlekuTfitruktur J. Jrrifi 9”: qulin’

1'33]. 9, 737";

K r
J. anle Fm" Ix. 7.7:. TNCk'JWYQ J. Am. Chemo QC. 0 £0

6% (10M).
:3. T. "’ahn. Physik 6., 13, 570 (1913).

rem-{mun n-M 1.. Hwel, 9 phi-1’. C'n'm. $711, 57?.“
): "1‘3. P3 ( 1:331).

J. H. "with. 77".”‘Tit3o Q’Ffv'o ’OC. (L’mo). “(II-7‘7: 151‘: :5573 (17-132)’

Demco-293

CHEMISTRY LIBRARY

Date Due

 

 

 

 

CHEMISTRY LIBRARY
‘ Thesis

c.1 Ho, Lenore

‘ The electric moments of some
substances in the vapor phase.
M.S. 1957

mm! LIBRARY

Thesis
c.1 Ho. Lenore

The electric moments of some
substances in the vapor phase.
M.S. 1957

‘Psf’éf‘lluse’ Lianegrfifffiffl- W..-“

3':

 

 

 

 

 

\\\W\E\\Wfifl\WIWWW\l

 

_ 312930244 8609 .